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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

sec-Butyllithium Manufacturer/High quality/Best price/In stock

Cas:598-30-1

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Sec-Butyllithium supplier in China

Cas:598-30-1

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply sec-butyllithium

Cas:598-30-1

Min.Order:1

Negotiable

Type:Other

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

sec-Butyl lithium

Cas:598-30-1

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

SEC-BUTYLLITHIUM

Cas:598-30-1

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

Para Butyl Lithium

Cas:598-30-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Pharmaceutical Grade CAS 598-30-1 with competitive price

Cas:598-30-1

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by email in time prod

reasonable price 598-30-1 sec-Butyllithiumsec-Butyllithium solution manufacturers

Cas:598-30-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

1)quick response within 12 hours; 2)quality guarantee: all products are strictly tested by our qc, confirmed by qa and approved by third party lab in china, usa, canada, germany, uk, italy, france etc. 3) oem/odm available; 4) rea

S-BULICAS NO.:598-30-1

Cas:598-30-1

Min.Order:1 Gram

FOB Price: $4.0 / 5.0

Type:Lab/Research institutions

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

sec-Butyllithium 598-30-1

Cas:598-30-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

Organic catalytic reaction,SEC-BUTYLLITHIUM CAS: 598-30-1

Cas:598-30-1

Min.Order:1 Kilogram

FOB Price: $23.2 / 27.4

Type:Trading Company

inquiry

Qingdao Beluga Import and Export Co., LTD

SEC-BUTYLLITHIUM CAS:598-30-1 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermedia

SEC-BUTYLLITHIUM CAS:598-30-1

Cas:598-30-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

C4H9Li SEC-BUTYLLITHIUM 598-30-1

Cas:598-30-1

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

s-BuLi

Cas:598-30-1

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

sec-Butyllithium solution 1.4M in cyclohexane

Cas:598-30-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality Sec-Butyllithium

Cas:598-30-1

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

C4H9Li SEC-BUTYLLITHIUM 598-30-1

Cas:598-30-1

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality Appearance:clear yellowish solution Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:Used as Pharmaceutical Intermediates Transpor

SEC-BUTYLLITHIUM

Cas:598-30-1

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Siwei Development Group Ltd.

Product name: Sec-Butyllithium CAS No.:598-30-1 Molecule Formula:C4H9Li Molecule Weight:64.06 Purity: 96.0% Package: 50kg/drum Description:Colorless or light yellow transparent liquid Manufacture Standards:Enterprise Standard

High Quality Sec-Butyllithium on hot selling

Cas:598-30-1

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Shanghai Minstar Chemical Co., Ltd

SEC-BUTYLLITHIUM Chemical Properties density 0.769 g/mL at 25 °C Fp 1 °F storage temp. 2-8°C form Liquid color Clear colorless Sensitive Air & Moisture Sensitive BRN 3587206 InChIKey VATDYQWILMGLEW-UHFFF

sec-Butyllithium

Cas:598-30-1

Min.Order:1 Gram

FOB Price: $66.0

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

s-BuLi

Cas:598-30-1

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

s-BuLi

Cas:598-30-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

s-BuLi

Cas:598-30-1

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

lithium,butane

Cas:598-30-1

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

s-BuLi

Cas:598-30-1

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

Hebei Mojin Biotechnology Co.,Ltd

1, High quality with competitive price:2, Fast and safe delivery3.Excellent pre-sales and after-sales service4. Well-trained and professional technologist and sales with rich experience in the field for 5-10 yearsAppearance:see detailed specification

Lithium,(1-methylpropyl)-

Cas:598-30-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

SEC-BUTYLLITHIUM cas no. 598-30-1 98%

Cas:598-30-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

sec-Butyl lithium

Cas:598-30-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Lonwin Chemical Group Limited

Shanghai Lonwin Chemical company is a subsidiary of Lonwin Industry Group Limited, was established in 2011 and is headquartered in Shanghai, adjacent to China National Convention and Exhibition Center and Hongqiao transportation hub.Lonwinchem is

Best price Sec-Butyllithium 598-30-1

Cas:598-30-1

Min.Order:100 Kilogram

FOB Price: $100.0 / 150.0

Type:Other

inquiry

JINHUA HUAYI CHEMICAL CO., LTD.

Jinhua huayi chemical co., ltd. is dedicated to the development, production and marketing of chemicals. On the basis of equality and mutual benefit, and under the principle of customer first, credit first, quality first, we are ready to join hands

Sec-Butyllithium

Cas:598-30-1

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

s-butyl chloride
78-86-4, 53178-20-4

s-butyl chloride

s-butylmagnesium chloride
15366-08-2

s-butylmagnesium chloride

lithium
7439-93-2

lithium

A

sec.-butyllithium
598-30-1

sec.-butyllithium

B

di-sec-butylmagnesium
17589-14-9

di-sec-butylmagnesium

Conditions
ConditionsYield
In tetrahydrofuran; toluene at 20 - 25℃; for 3.75 - 4.58333h; Product distribution / selectivity;A n/a
B 97.8%
In tetrahydrofuran at 10 - 35℃; for 3.41667 - 4.58333h; Product distribution / selectivity;A n/a
B 93%
s-butyl chloride
78-86-4, 53178-20-4

s-butyl chloride

sec.-butyllithium
598-30-1

sec.-butyllithium

Conditions
ConditionsYield
With sodium; lithium In hexane at 20 - 40℃; under 217.522 Torr; for 6.5h;41.8%
With lithium; Petroleum ether
With lithium In cyclohexane at 0℃; for 0.5h;
With lithium In tert-butyl methyl ether; cyclohexane; pentane at 20 - 50℃; Inert atmosphere;
With lithium; Petroleum ether
s-butyl chloride
78-86-4, 53178-20-4

s-butyl chloride

lithium

lithium

petroleum ether

petroleum ether

sec.-butyllithium
598-30-1

sec.-butyllithium

1,5-dichlorohexamethyltrisiloxane
3582-71-6

1,5-dichlorohexamethyltrisiloxane

sec.-butyllithium
598-30-1

sec.-butyllithium

1,5-di-sec-butylhexamethyltrisiloxane

1,5-di-sec-butylhexamethyltrisiloxane

Conditions
ConditionsYield
In diethyl ether at -78℃; for 2.5h;100%
sec.-butyllithium
598-30-1

sec.-butyllithium

1,1-bis{3-[(tert-butyl(dimethyl)silyloxy)methyl]phenyl}ethylene

1,1-bis{3-[(tert-butyl(dimethyl)silyloxy)methyl]phenyl}ethylene

(chain-end-(3-bromomethyl)phenyl)polystyrene

(chain-end-(3-bromomethyl)phenyl)polystyrene

polystyrene, functionalized with two 3-[(tert-butyl(dimethyl)silyloxy)methyl]phenyl groups at one end

polystyrene, functionalized with two 3-[(tert-butyl(dimethyl)silyloxy)methyl]phenyl groups at one end

Conditions
ConditionsYield
Stage #1: sec.-butyllithium; 1,1-bis{3-[(tert-butyl(dimethyl)silyloxy)methyl]phenyl}ethylene
Stage #2: (chain-end-(3-bromomethyl)phenyl)polystyrene
100%
sec.-butyllithium
598-30-1

sec.-butyllithium

1,1-bis{3-[(tert-butyl(dimethyl)silyloxy)methyl]phenyl}ethylene

1,1-bis{3-[(tert-butyl(dimethyl)silyloxy)methyl]phenyl}ethylene

polystyrene functionalized with four 3-(bromomethyl)phenyl groups at one end

polystyrene functionalized with four 3-(bromomethyl)phenyl groups at one end

polystyrene, functionalized with 8 3-[(tert-butyl(dimethyl)silyloxy)methyl]phenyl groups at one end

polystyrene, functionalized with 8 3-[(tert-butyl(dimethyl)silyloxy)methyl]phenyl groups at one end

Conditions
ConditionsYield
Stage #1: sec.-butyllithium; 1,1-bis{3-[(tert-butyl(dimethyl)silyloxy)methyl]phenyl}ethylene
Stage #2: polystyrene functionalized with four 3-(bromomethyl)phenyl groups at one end
100%
sec.-butyllithium
598-30-1

sec.-butyllithium

1,1-bis{3-[(tert-butyl(dimethyl)silyloxy)methyl]phenyl}ethylene

1,1-bis{3-[(tert-butyl(dimethyl)silyloxy)methyl]phenyl}ethylene

polystyrene functionalized with two 3-(bromomethyl)phenyl groups at one end

polystyrene functionalized with two 3-(bromomethyl)phenyl groups at one end

polystyrene, functionalized with 4 3-[(tert-butyl(dimethyl)silyloxy)methyl]phenyl groups at one end

polystyrene, functionalized with 4 3-[(tert-butyl(dimethyl)silyloxy)methyl]phenyl groups at one end

Conditions
ConditionsYield
Stage #1: sec.-butyllithium; 1,1-bis{3-[(tert-butyl(dimethyl)silyloxy)methyl]phenyl}ethylene
Stage #2: polystyrene functionalized with two 3-(bromomethyl)phenyl groups at one end
100%
1,1-bis(4-trimethylsilylphenyl)ethylene

1,1-bis(4-trimethylsilylphenyl)ethylene

vinyl-4-tolylsulfoxide
36832-47-0

vinyl-4-tolylsulfoxide

sec.-butyllithium
598-30-1

sec.-butyllithium

poly(4-methylphenyl vinyl sulfoxide), Mn=12400, Mw/Mn=1.07; monomer(s): 4-methylphenyl vinyl sulfoxide; 1,1-bis(4-trimethylsilylphenyl)ethylene; sec-butyllithium

poly(4-methylphenyl vinyl sulfoxide), Mn=12400, Mw/Mn=1.07; monomer(s): 4-methylphenyl vinyl sulfoxide; 1,1-bis(4-trimethylsilylphenyl)ethylene; sec-butyllithium

Conditions
ConditionsYield
Stage #1: 1,1-bis(4-trimethylsilylphenyl)ethylene; sec.-butyllithium In tetrahydrofuran at -78℃; under 1E-05 Torr; for 0.5h;
Stage #2: With lithium bromide In tetrahydrofuran at -78℃; under 1E-06 Torr; for 0.166667h;
Stage #3: vinyl-4-tolylsulfoxide In tetrahydrofuran at -78℃; under 1E-06 Torr; for 20h;
100%
1,1-bis(4-trimethylsilylphenyl)ethylene

1,1-bis(4-trimethylsilylphenyl)ethylene

vinyl-4-tolylsulfoxide
36832-47-0

vinyl-4-tolylsulfoxide

sec.-butyllithium
598-30-1

sec.-butyllithium

poly(4-methylphenyl vinyl sulfoxide), Mn=12500, Mw/Mn=1.11; monomer(s): 4-methylphenyl vinyl sulfoxide; 1,1-bis(4-trimethylsilylphenyl)ethylene; sec-butyllithium

poly(4-methylphenyl vinyl sulfoxide), Mn=12500, Mw/Mn=1.11; monomer(s): 4-methylphenyl vinyl sulfoxide; 1,1-bis(4-trimethylsilylphenyl)ethylene; sec-butyllithium

Conditions
ConditionsYield
Stage #1: 1,1-bis(4-trimethylsilylphenyl)ethylene; sec.-butyllithium In tetrahydrofuran at -78℃; under 1E-05 Torr; for 0.5h;
Stage #2: With lithium chloride In tetrahydrofuran at -78℃; under 1E-06 Torr; for 0.166667h;
Stage #3: vinyl-4-tolylsulfoxide In tetrahydrofuran at -78℃; under 1E-06 Torr; for 16h;
100%
1,1-bis(4-trimethylsilylphenyl)ethylene

1,1-bis(4-trimethylsilylphenyl)ethylene

vinyl-4-tolylsulfoxide
36832-47-0

vinyl-4-tolylsulfoxide

sec.-butyllithium
598-30-1

sec.-butyllithium

poly(4-methylphenyl vinyl sulfoxide), Mn=9300, Mw/Mn=1.16; monomer(s): 4-methylphenyl vinyl sulfoxide; 1,1-bis(4-trimethylsilylphenyl)ethylene; sec-butyllithium

poly(4-methylphenyl vinyl sulfoxide), Mn=9300, Mw/Mn=1.16; monomer(s): 4-methylphenyl vinyl sulfoxide; 1,1-bis(4-trimethylsilylphenyl)ethylene; sec-butyllithium

Conditions
ConditionsYield
Stage #1: 1,1-bis(4-trimethylsilylphenyl)ethylene; sec.-butyllithium In tetrahydrofuran at -78℃; under 1E-05 Torr; for 0.5h;
Stage #2: With lithium bromide In tetrahydrofuran at -78℃; under 1E-06 Torr; for 0.166667h;
Stage #3: vinyl-4-tolylsulfoxide In tetrahydrofuran at -78℃; under 1E-06 Torr; for 20h;
100%
8,9-dioxa-8a-borabenzo[fg]tetracene

8,9-dioxa-8a-borabenzo[fg]tetracene

sec.-butyllithium
598-30-1

sec.-butyllithium

C22H20BO2(1-)*Li(1+)

C22H20BO2(1-)*Li(1+)

Conditions
ConditionsYield
In tetrahydrofuran; cyclohexane at -78 - 20℃; for 0.166667h; Inert atmosphere;100%
In tetrahydrofuran at -78 - 20℃; Inert atmosphere;
sec.-butyllithium
598-30-1

sec.-butyllithium

methyldiphenylphosphine borane complex

methyldiphenylphosphine borane complex

α-lithium methylenediphenylphosphine borane
452969-86-7

α-lithium methylenediphenylphosphine borane

Conditions
ConditionsYield
In tetrahydrofuran BuLi adding into THF soln. of phosphine borane at -78°C, according to Imamoto et al. J. Am. Chem. Soc. 112 (1990) 5244;99%
1-aza-5-stanna-5-chloro-bicyclo{3.3.3}undecane
93253-73-7

1-aza-5-stanna-5-chloro-bicyclo{3.3.3}undecane

sec.-butyllithium
598-30-1

sec.-butyllithium

5-(1-methylpropyl)-1-aza-5-stannabicyclo[3.3.3]undecane
142509-27-1

5-(1-methylpropyl)-1-aza-5-stannabicyclo[3.3.3]undecane

Conditions
ConditionsYield
In diethyl ether; cyclohexane at -78℃; for 3h; Inert atmosphere;99%
In tetrahydrofuran at 0 - 20℃; for 12.25h; Inert atmosphere;
4-methyl-pent-3-en-2-one
141-79-7

4-methyl-pent-3-en-2-one

sec.-butyllithium
598-30-1

sec.-butyllithium

4,4,5-trimethyl-heptan-2-one
66018-00-6

4,4,5-trimethyl-heptan-2-one

Conditions
ConditionsYield
Stage #1: sec.-butyllithium With tellurium In tetrahydrofuran; hexane at -78 - 20℃;
Stage #2: 4-methyl-pent-3-en-2-one With boron trifluoride diethyl etherate at -78 - 20℃;
98%
(i) CuBr*Me2S, Me2S, Et2O, cyclohexane, (ii) /BRN= 1361550/, Et2O; Multistep reaction;
sec.-butyllithium
598-30-1

sec.-butyllithium

2-(2-methoxy-1-naphthyl)oxazoline
94321-29-6

2-(2-methoxy-1-naphthyl)oxazoline

2-(2-sec-butyl-1-naphthyl)oxazoline
137869-12-6

2-(2-sec-butyl-1-naphthyl)oxazoline

Conditions
ConditionsYield
In tetrahydrofuran Ambient temperature;98%
sec.-butyllithium
598-30-1

sec.-butyllithium

acetophenone
98-86-2

acetophenone

3-methyl-2-phenyl-pentan-2-ol
33484-93-4

3-methyl-2-phenyl-pentan-2-ol

Conditions
ConditionsYield
With cerium(III) triiodide In tetrahydrofuran; hexane at -65℃; for 3h; Product distribution; var. temp., time; also without CeI3;98%
With cerium(III) triiodide In tetrahydrofuran; hexane at -65℃; for 3h;98%
With cerium(III) triiodide in THF, 1) -65 deg C, 30 min., 2) -65 deg C, 3h; Yield given. Multistep reaction;
1-(4-(3-bromopropyl)phenyl)-1-phenylethylene
221343-17-5

1-(4-(3-bromopropyl)phenyl)-1-phenylethylene

styrene
292638-84-7

styrene

1,1-Diphenylethylene
530-48-3

1,1-Diphenylethylene

sec.-butyllithium
598-30-1

sec.-butyllithium

DPE-chain-end-functionalized polystyrene, Mn=9600, Mw/Mn=1.02; monomer(s): styrene; sec-butyllithium; 1,1-diphenylethylene; 1-(4-(3-bromopropyl)phenyl)-1-phenylethylene

DPE-chain-end-functionalized polystyrene, Mn=9600, Mw/Mn=1.02; monomer(s): styrene; sec-butyllithium; 1,1-diphenylethylene; 1-(4-(3-bromopropyl)phenyl)-1-phenylethylene

Conditions
ConditionsYield
Stage #1: styrene; sec.-butyllithium In tetrahydrofuran at -78℃; under 1E-06 Torr; for 0.5h;
Stage #2: 1,1-Diphenylethylene In tetrahydrofuran at -78℃; under 1E-06 Torr; for 1h;
Stage #3: 1-(4-(3-bromopropyl)phenyl)-1-phenylethylene In tetrahydrofuran at -78℃; under 1E-06 Torr; for 0.166667h;
98%
styrene
292638-84-7

styrene

dimethylmonochlorosilane
1066-35-9

dimethylmonochlorosilane

sec.-butyllithium
598-30-1

sec.-butyllithium

polystyrene, α-dimethylsilyl-terminated, ω-(but-2-yl)-terminated, Mn 2.2E3 g/mol, Mw/Mn 1.04; monomer(s): sec-butyllithium; styrene; chlorodimethylsilane

polystyrene, α-dimethylsilyl-terminated, ω-(but-2-yl)-terminated, Mn 2.2E3 g/mol, Mw/Mn 1.04; monomer(s): sec-butyllithium; styrene; chlorodimethylsilane

Conditions
ConditionsYield
Stage #1: styrene; sec.-butyllithium In cyclohexane; benzene for 12h;
Stage #2: dimethylmonochlorosilane In cyclohexane; benzene for 11h; Further stages.;
98%
Triisopropyl borate
5419-55-6

Triisopropyl borate

sec.-butyllithium
598-30-1

sec.-butyllithium

A

sec-butyldiisopropoxyborane

sec-butyldiisopropoxyborane

B

(C2H5CH(CH3))2B(OCH(CH3)2)
148058-17-7

(C2H5CH(CH3))2B(OCH(CH3)2)

Conditions
ConditionsYield
With hydrogenchloride In diethyl ether under N2; to cold (-78 °C) soln. of boron compd. in Et2O slowly added BuLi, stirred for 0.5 h, warmed to room temp., stirred for 0.5 h,Li(BMe4) detected by (11)B NMR, cooled to 0 °C, added soln. of HCl in Et2O, stirred for 15 min, warmed; not isolated, monitored by (11)B NMR;A 98%
B 2%
ferrocenyl p-tolyl sulphide

ferrocenyl p-tolyl sulphide

water-d2
7789-20-0

water-d2

sec.-butyllithium
598-30-1

sec.-butyllithium

A

Fe(C5H4(2)H)(C5H4SC6H4CH3)

Fe(C5H4(2)H)(C5H4SC6H4CH3)

B

Fe(C5H5)(C5H3(2)HSC6H4CH3)

Fe(C5H5)(C5H3(2)HSC6H4CH3)

C

Fe(C5H5)(C5H3(2)HSC6H4CH3)
693833-12-4

Fe(C5H5)(C5H3(2)HSC6H4CH3)

Conditions
ConditionsYield
In tetrahydrofuran to soln. of ferrocenyl sulfide-pTol in anhydrous THF under Ar added dropwise at -10°C soln. of s-BuLi; soln. stirred at 0°C for 7 h; trapping with D2O gave deuterated compds.; not isolated, detected by NMR(2)H;A n/a
B n/a
C 98%
1-Bromonaphthalene
90-11-9

1-Bromonaphthalene

sec.-butyllithium
598-30-1

sec.-butyllithium

2-(1-naphthyl)butane
1680-58-6

2-(1-naphthyl)butane

Conditions
ConditionsYield
With bis(tri-t-butylphosphine)palladium(0); water; sodium chloride In cyclohexane at 20℃; for 0.00555556h; pH=6; Schlenk technique;98%
With bis(tri-t-butylphosphine)palladium(0) In toluene at 20℃; for 1h;90%
With Pd-PEPPSI-IPent-Acenapht In toluene at -62℃; for 1h; Catalytic behavior; Reagent/catalyst; Temperature; Schlenk technique; Inert atmosphere;89%
Stage #1: 1-Bromonaphthalene With bis(tri-t-butylphosphine)palladium(0); oxygen In toluene at 20℃; for 0.0166667h; Schlenk technique;
Stage #2: sec.-butyllithium In toluene at 20℃; for 0.0333333h; Schlenk technique;
61%
1-bromo-2-ethylbenzene
1973-22-4

1-bromo-2-ethylbenzene

sec.-butyllithium
598-30-1

sec.-butyllithium

1-sec-butyl-2-ethylbenzene

1-sec-butyl-2-ethylbenzene

Conditions
ConditionsYield
With bis(tri-t-butylphosphine)palladium(0); water; sodium chloride In cyclohexane at 20℃; for 0.00555556h; pH=6; Schlenk technique;98%
carbon disulfide
75-15-0

carbon disulfide

1,1-Diphenylethylene
530-48-3

1,1-Diphenylethylene

sec.-butyllithium
598-30-1

sec.-butyllithium

benzyl bromide
100-39-0

benzyl bromide

C26H28S2
1433762-83-4

C26H28S2

Conditions
ConditionsYield
Stage #1: 1,1-Diphenylethylene; sec.-butyllithium In tetrahydrofuran at -80℃; for 0.25h; Inert atmosphere;
Stage #2: carbon disulfide In tetrahydrofuran at -80℃; for 0.333333h; Inert atmosphere;
Stage #3: benzyl bromide In tetrahydrofuran at -80 - 20℃; for 0.5h; Inert atmosphere;
97.9%
sec.-butyllithium
598-30-1

sec.-butyllithium

buta-1,3-diene
106-99-0

buta-1,3-diene

isoprene
78-79-5

isoprene

4,1-polyisoprene-b-1,2-polybutadiene diblock copolymer, Mn 1.13E4 (SEC/NMR), PDI 1.02-1.09 (SEC), fPB 0.355 (SEC/NMR), 94.3 mol percent 4,1-polyisoprene, 98.6 mol percent 1,2-polybutadiene (NMR); monomer(s): isoprene; sec-butyllithium; 1,3-butadiene

4,1-polyisoprene-b-1,2-polybutadiene diblock copolymer, Mn 1.13E4 (SEC/NMR), PDI 1.02-1.09 (SEC), fPB 0.355 (SEC/NMR), 94.3 mol percent 4,1-polyisoprene, 98.6 mol percent 1,2-polybutadiene (NMR); monomer(s): isoprene; sec-butyllithium; 1,3-butadiene

Conditions
ConditionsYield
Stage #1: sec.-butyllithium; isoprene In cyclohexane at 40℃; for 4h;
Stage #2: buta-1,3-diene With 1,2-dipiperidinoethane In cyclohexane at 18℃; for 3h;
97.6%
sec.-butyllithium
598-30-1

sec.-butyllithium

buta-1,3-diene
106-99-0

buta-1,3-diene

isoprene
78-79-5

isoprene

4,1-polyisoprene-b-1,2-polybutadiene diblock copolymer, Mn 1.18E4 (SEC/NMR), PDI 1.01-1.07 (SEC), fPB 0.284 (SEC/NMR), 94.3 mol percent 4,1-polyisoprene, >99 mol percent 1,2-polybutadiene (NMR); monomer(s): isoprene; sec-butyllithium; 1,3-butadiene

4,1-polyisoprene-b-1,2-polybutadiene diblock copolymer, Mn 1.18E4 (SEC/NMR), PDI 1.01-1.07 (SEC), fPB 0.284 (SEC/NMR), 94.3 mol percent 4,1-polyisoprene, >99 mol percent 1,2-polybutadiene (NMR); monomer(s): isoprene; sec-butyllithium; 1,3-butadiene

Conditions
ConditionsYield
Stage #1: sec.-butyllithium; isoprene In cyclohexane at 40℃; for 4h;
Stage #2: buta-1,3-diene With 1,2-dipiperidinoethane In cyclohexane at 18℃; for 3h;
97.6%
cyclopent-2-enone
930-30-3

cyclopent-2-enone

sec.-butyllithium
598-30-1

sec.-butyllithium

3-sec-butylcyclopentanone
91523-76-1

3-sec-butylcyclopentanone

Conditions
ConditionsYield
With s-Bu(Me)Cu(CN)Li2 In tetrahydrofuran at 0℃; for 0.5h;97%
sec.-butyllithium
598-30-1

sec.-butyllithium

(+/-)-(2R,3S,4S)-2-fluoro-3-tosylmethyl-2-trifluoromethyl-4-pentanolide

(+/-)-(2R,3S,4S)-2-fluoro-3-tosylmethyl-2-trifluoromethyl-4-pentanolide

(2S,3S,4R,5R)-2-sec-Butyl-3-fluoro-5-methyl-4-(toluene-4-sulfonylmethyl)-3-trifluoromethyl-tetrahydro-furan-2-ol

(2S,3S,4R,5R)-2-sec-Butyl-3-fluoro-5-methyl-4-(toluene-4-sulfonylmethyl)-3-trifluoromethyl-tetrahydro-furan-2-ol

Conditions
ConditionsYield
In diethyl ether at -78℃; for 0.5h;97%
sec.-butyllithium
598-30-1

sec.-butyllithium

3-methoxy-2,3-diphenyl-1-trimethylsilyl-1-propanone

3-methoxy-2,3-diphenyl-1-trimethylsilyl-1-propanone

6-methoxy-3-methyl-5,6-diphenyl-4-trimethylsilyl-4-hexanol

6-methoxy-3-methyl-5,6-diphenyl-4-trimethylsilyl-4-hexanol

Conditions
ConditionsYield
In tetrahydrofuran; hexane at -78℃;97%
sec.-butyllithium
598-30-1

sec.-butyllithium

(-)-(2S,4R,5S)-3,4-dimethyl-2,5-diphenyl-1,3,2-oxazaphospholidine-2-borane

(-)-(2S,4R,5S)-3,4-dimethyl-2,5-diphenyl-1,3,2-oxazaphospholidine-2-borane

(RP)-(s-butyl)[(1S,2R)-(N-ephedrino)](phenyl)phosphine-P-borane

(RP)-(s-butyl)[(1S,2R)-(N-ephedrino)](phenyl)phosphine-P-borane

Conditions
ConditionsYield
In tetrahydrofuran at -20 - 0℃;97%
sec.-butyllithium
598-30-1

sec.-butyllithium

1,1,1,6,6,6-hexakis(phenylthio)hexane
83711-09-5

1,1,1,6,6,6-hexakis(phenylthio)hexane

A

1-methylpropyl phenyl sulfide
14905-79-4

1-methylpropyl phenyl sulfide

B

1,1,6,6-tetrakis(phenylthio)hexane
70871-25-9

1,1,6,6-tetrakis(phenylthio)hexane

Conditions
ConditionsYield
In tetrahydrofuran; cyclohexane at -45℃; for 1h;A 89.7%
B 96.2%
sec.-butyllithium
598-30-1

sec.-butyllithium

(1R,2S,5S,8S,10R)-5,8,11,11-tetramethyl-7-methylene-3-oxatricyclo<8.1.1.02,8>dodecan-4-one
81550-54-1

(1R,2S,5S,8S,10R)-5,8,11,11-tetramethyl-7-methylene-3-oxatricyclo<8.1.1.02,8>dodecan-4-one

(1R,2S,5S,8S,10R)-5,8,11,11-tetramethyl-7-methylene-4-(1-methylpropyl)-3-oxatricyclo<8.1.1.02,8>dodecan-4-ol
83152-48-1

(1R,2S,5S,8S,10R)-5,8,11,11-tetramethyl-7-methylene-4-(1-methylpropyl)-3-oxatricyclo<8.1.1.02,8>dodecan-4-ol

Conditions
ConditionsYield
In tetrahydrofuran; hexane at -78℃; for 0.75h;96%
Decyl-oxiran
2855-19-8

Decyl-oxiran

sec.-butyllithium
598-30-1

sec.-butyllithium

(E)-3-methyl-4-pentadecene

(E)-3-methyl-4-pentadecene

Conditions
ConditionsYield
In tetrahydrofuran -70 deg C to -50 deg C, 20 min;96%

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