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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

2-Bromoethylbenzene Manufacturer/High quality/Best price/In stock

Cas:1973-22-4

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 2-Bromoethylbenzene supplier in China

Cas:1973-22-4

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Hebei yanxi chemical co.,LTD.

hebei yanxi chemical co., LTD who registered capital of 10 million yuan, nearly to $2 million, we have a pharmaceutical raw materials factory production of pharmaceutical raw materials, and a reagent r&d center, and we do research and developm

2-Bromoethylbenzene CAS NO.1973-22-4

Cas:1973-22-4

Min.Order:1 Metric Ton

FOB Price: $1.0 / 3.0

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

1-Bromo-2-ethylbenzene

Cas:1973-22-4

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

High purity CAS 1973-22-4 2-Bromoethylbenzene in stock Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...) 2.Organic Phosphine Ligands (Tert-butyl-phosphine.Cyclohexyl-phosphine...) 3.OLED intermediates (Fluore

High purity CAS 1973-22-4 2-Bromoethylbenzene in stock

Cas:1973-22-4

Min.Order:1 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

2-Bromoethylbenzene CAS 1973-22-4

Cas:1973-22-4

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Wholesale price CAS 1973-22-4 with best price

Cas:1973-22-4

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Benzene,1-bromo-2-ethyl- 1973-22-4

Cas:1973-22-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Factory Supply High Quality CAS 1973-22-4 ,2-Bromoethylbenzene

Cas:1973-22-4

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

2-Bromoethylbenzene

Cas:1973-22-4

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Fonlynn Health Technology Co., Ltd.

Packing: According to customer requirements Delivery time: In stock or depands Port of shipment: Ningbo/Shanghai/Qingdao OEM/ODM:Welcome Sample:We can offer our existing samples at once Transportation:Express/Sea/Air Port:Ningbo/Shanghai/Qingd

2-Bromoethylbenzene

Cas:1973-22-4

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

2-Bromoethylbenzene

Cas:1973-22-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

2-Bromoethylbenzene

Cas:1973-22-4

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providing h

Factory Supply o-Bromoethylbenzene

Cas:1973-22-4

Min.Order:0

Negotiable

Type:Other

inquiry

Henan Wentao Chemical Product Co., Ltd.

We are leading fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...)

2-Bromoethylbenzene CAS NO.: 1973-22-4

Cas:1973-22-4

Min.Order:1 Kilogram

FOB Price: $5.0

Type:Lab/Research institutions

inquiry

Shanghai Minstar Chemical Co., Ltd

2-Bromoethylbenzene Basic information Product Name: 2-Bromoethylbenzene Synonyms: 2-ETHYLBROMOBENZENE;1-BROMO-2-ETHYLBENZENE;O-BROMOETHYLBENZENE;1-Ethyl-2-brombenzol;1-Ethyl-2-bromobenzene;2-Bromo-1-ethylbenzene;benzene,1-bromo-2-ethyl-;o-ethy

2-Bromoethylbenzene

Cas:1973-22-4

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

2-Bromoethylbenzene

Cas:1973-22-4

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Wuhan BJM Pharm Inc.

Our company focuses on the future and the world, and will continue to devote itself to technological progress and the development of new products in the future, hoping to work hand in hand with new and old friends at home and abroad to create a bett

Manufacturer Supply High Quality 2-Bromoethylbenzene

Cas:1973-22-4

Min.Order:0 Metric Ton

Negotiable

Type:Trading Company

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

2-Bromoethylbenzene

Cas:1973-22-4

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

2-Bromoethylbenzene

Cas:1973-22-4

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

1-Bromo-2-ethylbenzene

Cas:1973-22-4

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

2-Bromoethylbenzene

Cas:1973-22-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

2-Bromoethylbenzene

Cas:1973-22-4

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

2-Bromoethylbenzene

Cas:1973-22-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stockAppearance:To be subject to the object Package:Customized Application:pharmaceutical intermediates Transportation:Air Port:Shanghai;Guangzhou

1-BroMo-2-ethylbenzene

Cas:1973-22-4

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

1-BroMo-2-ethylbenzene

Cas:1973-22-4

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

2-Bromoethylbenzene

Cas:1973-22-4

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Xi`an Eastling Biotech Co., Ltd.

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:Beijing or Guangzhou

2-Bromoethylbenzene

Cas:1973-22-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

1-BroMo-2-ethylbenzene

Cas:1973-22-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen AmoyChem Co.,Ltd

Amoychem is committed to providing the top-quality chemical products and services Internationally. We offer our customers with friendly, professional service and reliable, high performance products that have been manufactured according to the accredi

2-Bromoethylbenzene

Cas:1973-22-4

Min.Order:0

Negotiable

Type:Other

inquiry

Synthetic route

2-bromostyrene
2039-88-5

2-bromostyrene

1-bromo-2-ethylbenzene
1973-22-4

1-bromo-2-ethylbenzene

Conditions
ConditionsYield
With methanol; palladium diacetate; 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane In dichloromethane at 25℃; for 12h; Schlenk technique; Inert atmosphere;99%
With methanol; palladium diacetate; 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane In dichloromethane at 25℃; for 12h; Sealed tube; Inert atmosphere; chemoselective reaction;70%
With hydrogen In ethanol at 80℃; under 15001.5 Torr; Flow reactor; Green chemistry; chemoselective reaction;18%
With platinum; benzene Hydrogenation;
With sodium acetate trihydrate; toluene-4-sulfonic acid hydrazide In tetrahydrofuran at 80℃; for 12h; Inert atmosphere;
ethylbenzene
100-41-4

ethylbenzene

A

1-bromo-4-ethylbenzene
1585-07-5

1-bromo-4-ethylbenzene

B

1-bromo-2-ethylbenzene
1973-22-4

1-bromo-2-ethylbenzene

Conditions
ConditionsYield
With oxygen; sodium bromide In dibutyl ether at 45℃; under 760.051 Torr; for 5h; Schlenk technique;A 83%
B 9%
With carbon dioxide; bromine at 40℃; under 187519 Torr; for 2h; Supercritical conditions; Green chemistry;A 64%
B 36%
With ammonium nitrate; N-Bromosuccinimide In acetonitrile for 8h;A 53%
B 30%
ethyl bromide
74-96-4

ethyl bromide

bromobenzene
108-86-1

bromobenzene

A

1-bromo-4-ethylbenzene
1585-07-5

1-bromo-4-ethylbenzene

B

1-bromo-2-ethylbenzene
1973-22-4

1-bromo-2-ethylbenzene

Conditions
ConditionsYield
With aluminium at 80℃;
ortho-ethylaniline
578-54-1

ortho-ethylaniline

1-bromo-2-ethylbenzene
1973-22-4

1-bromo-2-ethylbenzene

Conditions
ConditionsYield
With hydrogen bromide; copper(I) bromide; sodium nitrite
With hydrogen bromide; copper; sodium nitrite
(i) aq. HBr, NaNO2, (ii) Cu; Multistep reaction;
(i) NaNO2, aq. HBr, (ii) Cu; Multistep reaction;
(i) (diazotization), aq. HBr, (ii) Cu; Multistep reaction;
bromobenzene
108-86-1

bromobenzene

ethene
74-85-1

ethene

A

1-bromo-4-ethylbenzene
1585-07-5

1-bromo-4-ethylbenzene

B

1-bromo-2-ethylbenzene
1973-22-4

1-bromo-2-ethylbenzene

C

1-bromo-3-ethylbenzene
2725-82-8

1-bromo-3-ethylbenzene

Conditions
ConditionsYield
H-ZSM-5 catalyst at 400℃; Product distribution; alkylation of benzene and momosubstituted benzenes with ethylene over H-ZSM-5 and mordenite-H catalysts; isomerization of ethylarenes over H-mordenite;
1-bromo-4-ethylbenzene
1585-07-5

1-bromo-4-ethylbenzene

A

1-bromo-2-ethylbenzene
1973-22-4

1-bromo-2-ethylbenzene

B

1-bromo-3-ethylbenzene
2725-82-8

1-bromo-3-ethylbenzene

Conditions
ConditionsYield
H-mordenite at 250℃; Product distribution; alkylation of benzene and momosubstituted benzenes with ethylene over H-ZSM-5 and mordenite-H catalysts; isomerization of ethylarenes over H-mordenite;
ethylbenzene
100-41-4

ethylbenzene

A

bromobenzene
108-86-1

bromobenzene

B

1-bromo-4-ethylbenzene
1585-07-5

1-bromo-4-ethylbenzene

C

1-bromo-2-ethylbenzene
1973-22-4

1-bromo-2-ethylbenzene

Conditions
ConditionsYield
With hydrogen bromide; dihydrogen peroxide at 50℃; Product distribution; Kinetics; Thermodynamic data; oth. temperature, var. stirring rate, var. ratio of reactants, E(activ.), ΔH(activ.), ΔS(activ.), ΔG(activ.);A 1.6 % Chromat.
B 73.3 % Chromat.
C 22.2 % Chromat.
With hydrogenchloride; sodium hypochlorite; sodium bromide In water at 19.85℃; for 5h; Product distribution; Further Variations:; Temperatures;
ethylbenzene
100-41-4

ethylbenzene

A

1-bromo-4-ethylbenzene
1585-07-5

1-bromo-4-ethylbenzene

B

1-bromo-2-ethylbenzene
1973-22-4

1-bromo-2-ethylbenzene

C

1-bromo-3-ethylbenzene
2725-82-8

1-bromo-3-ethylbenzene

Conditions
ConditionsYield
With bromine; iron(III) chloride In acetic acid at 25 - 75℃; Rate constant; Product distribution; other solvents (nitromethane, acetic anhydride), k (rel. to benzene);
1-bromo-2-(2-iodoethyl)benzene
113163-19-2

1-bromo-2-(2-iodoethyl)benzene

A

1-bromo-2-(2-bromoethyl)benzene
1074-15-3

1-bromo-2-(2-bromoethyl)benzene

B

ethylbenzene
100-41-4

ethylbenzene

C

1-bromo-2-ethylbenzene
1973-22-4

1-bromo-2-ethylbenzene

D

2-phenethyl iodide
17376-04-4

2-phenethyl iodide

E

2-bromostyrene
2039-88-5

2-bromostyrene

F

1-phenyl-2-bromoethane
103-63-9

1-phenyl-2-bromoethane

Conditions
ConditionsYield
With methanol; tert.-butyl lithium In tetrahydrofuran at -98℃; Product distribution; Mechanism;
(4-Bromo-3-ethyl-phenyl)-trimethyl-silane

(4-Bromo-3-ethyl-phenyl)-trimethyl-silane

1-bromo-2-ethylbenzene
1973-22-4

1-bromo-2-ethylbenzene

Conditions
ConditionsYield
With potassium fluoride In N,N-dimethyl-formamide at 50℃; for 3h; Yield given;
biphenyl
92-52-4

biphenyl

1-ethyl-2-bromo-4-tert-butyl-benzene
57190-08-6

1-ethyl-2-bromo-4-tert-butyl-benzene

1-bromo-2-ethylbenzene
1973-22-4

1-bromo-2-ethylbenzene

Conditions
ConditionsYield
With aluminium trichloride In tetrachloromethane; nitromethane
ethyl bromide
74-96-4

ethyl bromide

bromobenzene
108-86-1

bromobenzene

aluminium

aluminium

A

1-bromo-4-ethylbenzene
1585-07-5

1-bromo-4-ethylbenzene

B

1-bromo-2-ethylbenzene
1973-22-4

1-bromo-2-ethylbenzene

ethylbenzene
100-41-4

ethylbenzene

bromine
7726-95-6

bromine

A

1-bromo-4-ethylbenzene
1585-07-5

1-bromo-4-ethylbenzene

B

1-bromo-2-ethylbenzene
1973-22-4

1-bromo-2-ethylbenzene

ethylbenzene
100-41-4

ethylbenzene

bromine
7726-95-6

bromine

iodine
7553-56-2

iodine

A

1-bromo-4-ethylbenzene
1585-07-5

1-bromo-4-ethylbenzene

B

1-bromo-2-ethylbenzene
1973-22-4

1-bromo-2-ethylbenzene

2-Ethyl-1,4-bis-trimethylsilanyl-benzene
128254-32-0

2-Ethyl-1,4-bis-trimethylsilanyl-benzene

1-bromo-2-ethylbenzene
1973-22-4

1-bromo-2-ethylbenzene

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: Br2
2: KF / dimethylformamide / 3 h / 50 °C
View Scheme
4-ethyl-tert-butylbenzene
7364-19-4

4-ethyl-tert-butylbenzene

1-bromo-2-ethylbenzene
1973-22-4

1-bromo-2-ethylbenzene

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: Fe, Br2 / CCl4
2: AlCl3 / CCl4; nitromethane
View Scheme
ortho-bromobenzaldehyde
6630-33-7

ortho-bromobenzaldehyde

1-bromo-2-ethylbenzene
1973-22-4

1-bromo-2-ethylbenzene

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: potassium tert-butylate / tetrahydrofuran / 0.5 h / 0 - 25 °C / Inert atmosphere
2: toluene-4-sulfonic acid hydrazide; sodium acetate trihydrate / tetrahydrofuran / 12 h / 80 °C / Inert atmosphere
View Scheme
2-bromostyrene
2039-88-5

2-bromostyrene

hydrogen
1333-74-0

hydrogen

1-bromo-2-ethylbenzene
1973-22-4

1-bromo-2-ethylbenzene

Conditions
ConditionsYield
With [Ir(6-Neo)(COD)Cl] In ethanol under 3750.38 Torr; for 1h;69 %Spectr.
carbon monoxide
201230-82-2

carbon monoxide

2-bromostyrene
2039-88-5

2-bromostyrene

A

1-bromo-2-ethylbenzene
1973-22-4

1-bromo-2-ethylbenzene

B

C9H9BrO

C9H9BrO

C

C9H9BrO

C9H9BrO

D

3-(o-bromophenyl)propanal
107408-16-2

3-(o-bromophenyl)propanal

Conditions
ConditionsYield
With {(R)-binap}PtCl2; hydrogen; tin(ll) chloride In toluene at 40℃; under 30003 Torr; for 128h; Autoclave; Schlenk technique; enantioselective reaction;A n/a
B n/a
C n/a
D n/a
With {(R)-binap}PtCl2; hydrogen; tin(ll) chloride In toluene at 100℃; under 30003 Torr; for 24h; Temperature; Autoclave; Schlenk technique; enantioselective reaction;A n/a
B n/a
C n/a
D n/a
1-bromo-2-ethylbenzene
1973-22-4

1-bromo-2-ethylbenzene

2,4,6-trimethylaniline
88-05-1

2,4,6-trimethylaniline

2,4,6-trimethylphenyl-2'-ethyldiphenylamine

2,4,6-trimethylphenyl-2'-ethyldiphenylamine

Conditions
ConditionsYield
With palladium diacetate; bis[2-(diphenylphosphino)phenyl] ether; sodium t-butanolate In toluene at 100℃; for 12h;99%
With bis[2-(diphenylphosphino)phenyl] ether; sodium t-butanolate; palladium dichloride In toluene at 80℃; for 18h;97%
With palladium diacetate; sodium t-butanolate; tri-t-butylphosphonium tetraphenylborate complex In toluene at 110℃; for 3h; Inert atmosphere;30 g
With palladium diacetate; sodium t-butanolate; tri-t-butylphosphonium tetraphenylborate complex In toluene at 110℃; for 3h; Inert atmosphere;30 g
1-bromo-2-ethylbenzene
1973-22-4

1-bromo-2-ethylbenzene

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

2-ethylbenzaldehyde
22927-13-5

2-ethylbenzaldehyde

Conditions
ConditionsYield
Stage #1: 1-bromo-2-ethylbenzene In dichloromethane; cyclohexane at -78 - -75℃; for 1.5h;
Stage #2: N,N-dimethyl-formamide In dichloromethane; cyclohexane for 1h; Solvent;
99%
Stage #1: 1-bromo-2-ethylbenzene With n-butyllithium In tetrahydrofuran; hexanes at -78℃; for 3h;
Stage #2: N,N-dimethyl-formamide In tetrahydrofuran; hexanes at -78℃; for 3h;
96%
Stage #1: 1-bromo-2-ethylbenzene With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 3h;
Stage #2: N,N-dimethyl-formamide In tetrahydrofuran; hexane at -78℃; for 0.5h;
85%
Stage #1: 1-bromo-2-ethylbenzene With n-butyllithium
Stage #2: N,N-dimethyl-formamide Further stages.;
Stage #1: 1-bromo-2-ethylbenzene With magnesium In tetrahydrofuran for 2h; Heating / reflux;
Stage #2: N,N-dimethyl-formamide In tetrahydrofuran at 0℃; for 0.5h;
Stage #3: With hydrogenchloride; water In tetrahydrofuran
1-bromo-2-ethylbenzene
1973-22-4

1-bromo-2-ethylbenzene

2-bromophenyl methyl ketone
2142-69-0

2-bromophenyl methyl ketone

Conditions
ConditionsYield
With Iron(III) nitrate nonahydrate; 1-hydroxy-pyrrolidine-2,5-dione; oxygen In benzonitrile at 90℃; for 21h;99%
With Iron(III) nitrate nonahydrate; N-hydroxyphthalimide In benzonitrile at 100℃; for 20h;95%
With tert.-butylhydroperoxide In acetonitrile at 25 - 35℃; for 20h; Sealed tube; Irradiation;75%
1-bromo-2-ethylbenzene
1973-22-4

1-bromo-2-ethylbenzene

1-(tert-butoxycarbonyl)-4-aminopiperidine
87120-72-7

1-(tert-butoxycarbonyl)-4-aminopiperidine

1-tert-butoxycarbonyl-4-[(2-ethylphenyl)amino]piperidine
933056-02-1

1-tert-butoxycarbonyl-4-[(2-ethylphenyl)amino]piperidine

Conditions
ConditionsYield
With sodium t-butanolate; DavePhos; tris-(dibenzylideneacetone)dipalladium(0) In xylene at 130℃; for 24h;98%
1-bromo-2-ethylbenzene
1973-22-4

1-bromo-2-ethylbenzene

1-(2-bromophenyl)ethanol
5411-56-3

1-(2-bromophenyl)ethanol

Conditions
ConditionsYield
With wild type cytochrome P450 CYP102A1(P450Bm3); oxygen; NADPH Reagent/catalyst; Enzymatic reaction;98%
With Mn(II)T(p-Cl)PP; oxygen In neat (no solvent) at 140℃; under 13501.4 Torr; for 6h; Sealed tube;10.5%
Multi-step reaction with 2 steps
1: sodium anthraquinonesulfonate; air / water; acetonitrile / 18 h / 20 °C / Irradiation
2: sodium tetrahydroborate; methanol / 20 °C
View Scheme
Multi-step reaction with 2 steps
1: dihydroxy-methyl-borane; lithium carbonate; N-fluorobis(benzenesulfon)imide; bathophenanthroline; copper (I) acetate / chlorobenzene / 16 h / 55 °C / Glovebox; Inert atmosphere
2: 1,1,1,3',3',3'-hexafluoro-propanol; water / chlorobenzene; dichloromethane / 16 h / 20 °C / Sealed tube
View Scheme
n-butyllithium
109-72-8, 29786-93-4

n-butyllithium

1-bromo-2-ethylbenzene
1973-22-4

1-bromo-2-ethylbenzene

2-(n-butyl)ethylbenzene
42548-38-9

2-(n-butyl)ethylbenzene

Conditions
ConditionsYield
With bis(tri-t-butylphosphine)palladium(0); water; sodium chloride In cyclohexane at 20℃; for 0.00555556h; pH=6; Schlenk technique;98%
1-bromo-2-ethylbenzene
1973-22-4

1-bromo-2-ethylbenzene

sec.-butyllithium
598-30-1

sec.-butyllithium

1-sec-butyl-2-ethylbenzene

1-sec-butyl-2-ethylbenzene

Conditions
ConditionsYield
With bis(tri-t-butylphosphine)palladium(0); water; sodium chloride In cyclohexane at 20℃; for 0.00555556h; pH=6; Schlenk technique;98%
1-bromo-2-ethylbenzene
1973-22-4

1-bromo-2-ethylbenzene

phenyllithium
591-51-5

phenyllithium

2-ethyl-1,1'-biphenyl
1812-51-7

2-ethyl-1,1'-biphenyl

Conditions
ConditionsYield
With bis(tri-t-butylphosphine)palladium(0); water; sodium chloride In dibutyl ether at 20℃; for 0.00555556h; pH=6; Schlenk technique;98%
1-bromo-2-ethylbenzene
1973-22-4

1-bromo-2-ethylbenzene

(beta-bromoethyl)monobromobenzene
62384-31-0

(beta-bromoethyl)monobromobenzene

Conditions
ConditionsYield
With N-Bromosuccinimide; dibenzoyl peroxide In tetrachloromethane for 3h; Heating / reflux;97%
With carbon tetrabromide; (4,4'-di-tert-butyl-2,2'-dipyridyl)-bis-(2-phenylpyridine(-1H))-iridium(III) hexafluorophosphate In dichloromethane at 20℃; for 36h; Schlenk technique; Inert atmosphere; Irradiation;
With N-Bromosuccinimide; dibenzoyl peroxide In tetrachloromethane Inert atmosphere; Reflux;
diethylchlorophosphine
686-69-1

diethylchlorophosphine

1-bromo-2-ethylbenzene
1973-22-4

1-bromo-2-ethylbenzene

diethyl(o-ethylphenyl)phosphane
1085850-79-8

diethyl(o-ethylphenyl)phosphane

Conditions
ConditionsYield
Stage #1: 1-bromo-2-ethylbenzene With n-butyllithium In diethyl ether at -10 - 0℃; for 3h;
Stage #2: diethylchlorophosphine In diethyl ether at 20℃; Further stages.;
97%
1-bromo-2-ethylbenzene
1973-22-4

1-bromo-2-ethylbenzene

N-(4-chlorobenzylidene)-N-(1,1,1-trimethylsilyl)amine
85654-07-5

N-(4-chlorobenzylidene)-N-(1,1,1-trimethylsilyl)amine

(4-chlorobenzylidene)(2-ethylphenyl)amine

(4-chlorobenzylidene)(2-ethylphenyl)amine

Conditions
ConditionsYield
With 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate; tris(dibenzylideneacetone)dipalladium (0) In toluene at 90℃; for 14h;96%
1-bromo-2-ethylbenzene
1973-22-4

1-bromo-2-ethylbenzene

phenylboronic acid
98-80-6

phenylboronic acid

2-ethyl-1,1'-biphenyl
1812-51-7

2-ethyl-1,1'-biphenyl

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; potassium carbonate In 1,2-dimethoxyethane; water at 80℃; Inert atmosphere;96%
With C25H29FeI2N3OPd; sodium carbonate In N,N-dimethyl-formamide at 100℃; for 19h; Suzuki-Miyaura Coupling; Schlenk technique; Sealed tube;
With potassium carbonate In ethanol; water at 70℃; for 0.75h; Suzuki Coupling;72 %Chromat.
With C36H36Cl2Fe2NPPd; sodium carbonate In N,N-dimethyl-formamide at 100℃; for 18h; Suzuki-Miyaura Coupling; Inert atmosphere; Schlenk technique;57 %Chromat.
1-bromo-2-ethylbenzene
1973-22-4

1-bromo-2-ethylbenzene

N-trimethylsilyl(4-methoxy)benzaldimine
64187-51-5

N-trimethylsilyl(4-methoxy)benzaldimine

(2-ethylphenyl)(4-methoxybenzylidene)amine

(2-ethylphenyl)(4-methoxybenzylidene)amine

Conditions
ConditionsYield
With 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate; tris(dibenzylideneacetone)dipalladium (0) In toluene at 90℃; for 14h;95%
styrene
292638-84-7

styrene

1-bromo-2-ethylbenzene
1973-22-4

1-bromo-2-ethylbenzene

1-ethyl-2-styrylbenzene

1-ethyl-2-styrylbenzene

Conditions
ConditionsYield
With N-[2-(pyrazol-1-yl)phenyl]-N'-benzylimidazol-2-ylidene palladium chloride; potassium carbonate In water; N,N-dimethyl-formamide Reagent/catalyst; Heck Reaction;95%
With dichlorobis(tri-O-tolylphosphine)palladium; N-Methyldicyclohexylamine; 4,4'-di-tert-butylbiphenyl; tetrabutyl-ammonium chloride In N,N-dimethyl acetamide at 80℃; for 24h; Reagent/catalyst; Heck Reaction; Glovebox;
With N,N-dimethyl-cyclohexanamine; tetrabutyl-ammonium chloride; palladium diacetate; triphenylphosphine In N,N-dimethyl acetamide at 80℃; for 24h; Heck Reaction;18 %Spectr.
1-bromo-2-ethylbenzene
1973-22-4

1-bromo-2-ethylbenzene

copper(l) cyanide

copper(l) cyanide

o-ethylbenzonitrile
34136-59-9

o-ethylbenzonitrile

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 150℃; for 12h;95%
1-bromo-2-ethylbenzene
1973-22-4

1-bromo-2-ethylbenzene

2,3-dihydro-2-methyl-1H-inden-1-one
17496-14-9

2,3-dihydro-2-methyl-1H-inden-1-one

(S)-2-(2-ethylphenyl)-2-methyl-2,3-dihydro-1H-inden-1-one

(S)-2-(2-ethylphenyl)-2-methyl-2,3-dihydro-1H-inden-1-one

Conditions
ConditionsYield
With (R)-BIDIME; palladium diacetate; sodium t-butanolate In toluene at 80℃; for 24h; Schlenk technique; Glovebox; Inert atmosphere; enantioselective reaction;95%
1-bromo-2-ethylbenzene
1973-22-4

1-bromo-2-ethylbenzene

propionaldehyde
123-38-6

propionaldehyde

1-(2-ethylphenyl)propanol
67541-89-3

1-(2-ethylphenyl)propanol

Conditions
ConditionsYield
Stage #1: 1-bromo-2-ethylbenzene With iodine; magnesium In tetrahydrofuran at -5 - 5℃; for 2h;
Stage #2: propionaldehyde In tetrahydrofuran at 20℃;
95%
1-bromo-2-ethylbenzene
1973-22-4

1-bromo-2-ethylbenzene

2-{[allyl(benzyl)amino]methyl}-N-(4-methoxyphenyl)aniline
1284151-57-0

2-{[allyl(benzyl)amino]methyl}-N-(4-methoxyphenyl)aniline

4-benzyl-2-(2-ethylbenzyl)-1-(4-methoxyphenyl)-2,3,4,5-tetrahydro-1H-benzo[e][1,4]diazepine
1284151-70-7

4-benzyl-2-(2-ethylbenzyl)-1-(4-methoxyphenyl)-2,3,4,5-tetrahydro-1H-benzo[e][1,4]diazepine

Conditions
ConditionsYield
With dichloro bis(acetonitrile) palladium(II); cyclohexyldiphenylphosphine; sodium t-butanolate In 5,5-dimethyl-1,3-cyclohexadiene at 135℃; Inert atmosphere;94%
isopropylboronic acid
80041-89-0

isopropylboronic acid

1-bromo-2-ethylbenzene
1973-22-4

1-bromo-2-ethylbenzene

1-ethyl-2-isopropylbenzene
18970-44-0

1-ethyl-2-isopropylbenzene

Conditions
ConditionsYield
With potassium phosphate monohydrate; bis[chloro(1,2,3-trihapto-allylbenzene)palladium(II)]; C20H34O3P2 In toluene at 100℃; Suzuki-Miyaura Coupling; Inert atmosphere;94%
1-bromo-2-ethylbenzene
1973-22-4

1-bromo-2-ethylbenzene

n-hexyllithium
21369-64-2

n-hexyllithium

1-ethyl-2-hexylbenzene
71521-85-2

1-ethyl-2-hexylbenzene

Conditions
ConditionsYield
With bis(tri-t-butylphosphine)palladium(0); water; sodium chloride In hexane at 20℃; for 0.00555556h; pH=6; Schlenk technique;94%
1-bromo-2-ethylbenzene
1973-22-4

1-bromo-2-ethylbenzene

N-(2-furylmethylidene)-N-(1,1,1-trimethylsilyl)amine
83948-29-2

N-(2-furylmethylidene)-N-(1,1,1-trimethylsilyl)amine

(2-ethylphenyl)(furan-2-ylmethylene)amine

(2-ethylphenyl)(furan-2-ylmethylene)amine

Conditions
ConditionsYield
With 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate; tris(dibenzylideneacetone)dipalladium (0) In toluene at 90℃; for 14h;92%
1-bromo-2-ethylbenzene
1973-22-4

1-bromo-2-ethylbenzene

methyl thioisocyanate
556-61-6

methyl thioisocyanate

2-ethyl-N-methylthiobenzamide
489470-19-1

2-ethyl-N-methylthiobenzamide

Conditions
ConditionsYield
Stage #1: 1-bromo-2-ethylbenzene With magnesium In tetrahydrofuran
Stage #2: methyl thioisocyanate In tetrahydrofuran at 20℃; for 16h;
91%
1-bromo-2-ethylbenzene
1973-22-4

1-bromo-2-ethylbenzene

N-(2,4,6-trimethylphenyl)-1,2-diaminoethane
444325-38-6

N-(2,4,6-trimethylphenyl)-1,2-diaminoethane

N1-(2-ethylphenyl)-N2-mesitylethane-1,2-diamine

N1-(2-ethylphenyl)-N2-mesitylethane-1,2-diamine

Conditions
ConditionsYield
With (2R)-1-[(1R)-1-[bis(1,1-dimethylethyl)phosphino]ethyl]-2-(dicyclohexylphosphino)ferrocene; palladium diacetate; sodium t-butanolate In 1,2-dimethoxyethane at 80℃; for 17h; Glovebox; Inert atmosphere; Sealed tube;91%
1-bromo-2-ethylbenzene
1973-22-4

1-bromo-2-ethylbenzene

DL-3-aminohexahydro-1H-azepin
69154-03-6

DL-3-aminohexahydro-1H-azepin

3-[(2-ethylphenyl)amino]hexahydroazepine

3-[(2-ethylphenyl)amino]hexahydroazepine

Conditions
ConditionsYield
With 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate; tris-(dibenzylideneacetone)dipalladium(0) In xylene at 130℃; for 24h;90%
1-bromo-2-ethylbenzene
1973-22-4

1-bromo-2-ethylbenzene

1,1-diphenyl-2-methyl-2-propen-1-ol
29291-01-8

1,1-diphenyl-2-methyl-2-propen-1-ol

2-(2-ethylphenyl)methyl-2-methyl-3,3-diphenyloxirane
1116366-33-6

2-(2-ethylphenyl)methyl-2-methyl-3,3-diphenyloxirane

Conditions
ConditionsYield
With tris(dibenzylideneacetone)dipalladium (0); sodium t-butanolate; ruphos In toluene for 6h; Inert atmosphere; Reflux;90%
1-bromo-2-ethylbenzene
1973-22-4

1-bromo-2-ethylbenzene

Methyl cinnamate
103-26-4

Methyl cinnamate

A

Methyl (Z)-3-(2-ethylphenyl)-3-phenylacrylate

Methyl (Z)-3-(2-ethylphenyl)-3-phenylacrylate

B

Methyl (E)-3-(2-ethylphenyl)-3-phenylacrylate

Methyl (E)-3-(2-ethylphenyl)-3-phenylacrylate

Conditions
ConditionsYield
With N-Methyldicyclohexylamine; tetraethylammonium chloride; palladium diacetate In N,N-dimethyl acetamide at 85℃; for 60h; Arylation; Heck arylation;A n/a
B 89%
1-bromo-2-ethylbenzene
1973-22-4

1-bromo-2-ethylbenzene

(1R,4S,6S)-bicyclo<2.2.2>octane-6-ol-2-one
129100-39-6

(1R,4S,6S)-bicyclo<2.2.2>octane-6-ol-2-one

(1R,2R,4S,6S)-2-(2-ethylphenyl)bicyclo[2.2.2]octane-2,6-diol
1067234-14-3

(1R,2R,4S,6S)-2-(2-ethylphenyl)bicyclo[2.2.2]octane-2,6-diol

Conditions
ConditionsYield
Stage #1: 1-bromo-2-ethylbenzene In tetrahydrofuran
Stage #2: (1R,4S,6S)-bicyclo<2.2.2>octane-6-ol-2-one In tetrahydrofuran; diethyl ether at 25℃; for 1h; Grignard reaction; Further stages.;
89%
1-bromo-2-ethylbenzene
1973-22-4

1-bromo-2-ethylbenzene

diphenyldisulfane
882-33-7

diphenyldisulfane

2-ethylphenyl phenyl sulfide
23075-79-8

2-ethylphenyl phenyl sulfide

Conditions
ConditionsYield
With C40H32N4O7Ti2(2+)*2C8F17O3S(1-); zinc In toluene at 35℃; for 10h;89%
1-bromo-2-ethylbenzene
1973-22-4

1-bromo-2-ethylbenzene

(E)-tert-butyl 3-(4-((6-methoxybenzo[b]thiophen-3-yl)oxy)phenyl)acrylate
1622308-34-2

(E)-tert-butyl 3-(4-((6-methoxybenzo[b]thiophen-3-yl)oxy)phenyl)acrylate

(E)-tert-butyl 3-(4-((2-(2-ethylphenyl)-6-methoxybenzo[b]thiophen-3-yl)oxy)phenyl)acrylate
1622308-65-9

(E)-tert-butyl 3-(4-((2-(2-ethylphenyl)-6-methoxybenzo[b]thiophen-3-yl)oxy)phenyl)acrylate

Conditions
ConditionsYield
With chloro[2-(dicyclohexylphosphino)-3 ,6-dimethoxy-2’,4’, 6’-triisopropyl- 1,1’-biphenyl] [2-(2-aminoethyl)phenyl]palladium(II); potassium carbonate; Trimethylacetic acid In N,N-dimethyl acetamide at 150℃; for 2h; Microwave irradiation; Sealed tube; Inert atmosphere;89%

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