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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 2,6-Dimethylbenzoicacid supplier in China

Cas:632-46-2

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem’s R&D center offer custom synthesis according to the contract research and development services for t

High purity 2,6-Dimethylbenzoic acid 98% TOP1 supplier in China

Cas:632-46-2

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

2,6-Dimethylbenzoic acid

Cas:632-46-2

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Factory direct supply CAS 632-46-2 with best quality

Cas:632-46-2

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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LIDE PHARMACEUTICALS LIMITED

Advantage : LIDE PHARMACEUTICALS LTD. is a mid-small manufacturing-type enterprise, engaged in pharmaceutical intermediates of R&D, custom-made and production, and also involving trading chemicals for export. We have established the R&amp

2,6-Dimethylbenzoic acid/ LIDE PHARMA- Factory supply / Best price

Cas:632-46-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

2,6-Dimethylbenzoic acid 632-46-2

Cas:632-46-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1, High quality with competitive price: 1) Standard:BP/USP/EP/Enterprise standard 2) All Purity≥99% 3) We are manufacturer and can provide high quality products with factory price. 2, Fast and safe delivery 1)

2,6-Dimethylbenzoic acid.

Cas:632-46-2

Min.Order:1 Gram

FOB Price: $1.0 / 5.0

Type:Trading Company

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

2,6-Dimethylbenzoic acid

Cas:632-46-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:632-46-2

Cas:632-46-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hebei Mojin Biotechnology Co.,Ltd

1. Customs clearance 1) By Express: Normally there is no specical need for the recipient to clear the customs. If the customs has an objection,our rich experienced and professional group will help you clear the customs. 2) By Air and by Sea: Our

Best Price CAS 632-46-2 2,6-Dimethylbenzoic acid C9H10O2 99%

Cas:632-46-2

Min.Order:20 Kilogram

FOB Price: $10.0 / 25.0

Type:Trading Company

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

2,6-Dimethylbenzoicacid

Cas:632-46-2

Min.Order:0

Negotiable

Type:Manufacturers

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

2,6-Dimethylbenzoic acid

Cas:632-46-2

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 2,6-Dimethylbenzoic acid

Cas:632-46-2

Min.Order:0 Metric Ton

Negotiable

Type:Other

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Hangzhou Lingrui Chemical Co.,Ltd.

Direct Manufacturer 2,6-Dimethylbenzoic acid 632-46-2 in bulk supply 2,6-dimethylbenzoic acid is a white solid powder under normal temperature and pressure. During the organic synthesis and conversion, the carboxyl group in 2,6-dimethylbenzoic acid

Direct Manufacturer 2,6-Dimethylbenzoic acid 632-46-2 in bulk supply

Cas:632-46-2

Min.Order:1 Gram

Negotiable

Type:Other

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

2,6-Dimethylbenzoic acid

Cas:632-46-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Henan Tianfu Chemical Co., Ltd.

Product Name: 2,6-Dimethylbenzoic acid Synonyms: M-XYLENE-2-CARBOXYLIC ACID;TIMTEC-BB SBB007881;RARECHEM AL BO 0401;VIC-M-XYLYLIC ACID;2,6-dimethyl-benzoicaci;2,6-DIMETHYLBENZOIC ACID;Benzoic acid, 2,6-dimethyl- (7CI,8CI,9CI);Benzoic acid, 2,6-di

TIANFUCHEM--632-46-2--2,6-Dimethylbenzoic acid

Cas:632-46-2

Min.Order:1 Metric Ton

FOB Price: $5.0

Type:Lab/Research institutions

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

2,6-Dimethylbenzoic acid

Cas:632-46-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Minstar Chemical Co., Ltd

2,6-Dimethylbenzoic acid Chemical Properties Melting point 114-116 °C (lit.) Boiling point 160 °C / 17mmHg density 1.0937 (estimate) refractive index 1.5236 (estimate) form Crystalline Powder pka pKa: 3.362(25°C) co

2,6-Dimethylbenzoic acid

Cas:632-46-2

Min.Order:1 Gram

FOB Price: $66.0

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

2,6-Dimethylbenzoic acid

Cas:632-46-2

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

2,6-Dimethylbenzoic acid

Cas:632-46-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

2,6-Dimethylbenzoic acid

Cas:632-46-2

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

2,6-Dimethylbenzoic acid

Cas:632-46-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

2,6-dimethylbenzoic Acid

Cas:632-46-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

2,6-Dimethylbenzoic acid

Cas:632-46-2

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

2,6-dimethylbenzoic acid cas no. 632-46-2 98%

Cas:632-46-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

2,6-Dimethylbenzoic acid

Cas:632-46-2

Min.Order:0

Negotiable

Type:Other

inquiry

Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stockAppearance:To be subject to the object Package:Customized Application:pharmaceutical intermediates Transportation:Air Port:Shanghai;Guangzhou

2,6-DiMethylbenzoicacid

Cas:632-46-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

GIHI CHEMICALS CO.,LIMITED

high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,Pharmaceutical intermediates Transportation:air,sea,courier

2,6-Dimethylbenzoic acid

Cas:632-46-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

JINHUA HUAYI CHEMICAL CO., LTD.

Jinhua huayi chemical co., ltd. is dedicated to the development, production and marketing of chemicals. On the basis of equality and mutual benefit, and under the principle of customer first, credit first, quality first, we are ready to join hands

2,6-Dimethylbenzoic Acid

Cas:632-46-2

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

inquiry

DB BIOTECH CO., LTD

Q1: Are you a manufacturer Answer: Yes, we are factory founded on 2012.Q2: How to contact with us Click "contact supplier" And then send us message the product you interest in, you will get reply within 12 hours.Q3:Which kind of payment terms do you

2,6-Dimethylbenzoic acid

Cas:632-46-2

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

4-methoxybenzyl 2,6-dimethylbenzoate

4-methoxybenzyl 2,6-dimethylbenzoate

ethylene glycol
107-21-1

ethylene glycol

A

2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

B

2-(4-methoxybenzyloxy)ethanol
13807-89-1

2-(4-methoxybenzyloxy)ethanol

Conditions
ConditionsYield
at 140℃; for 4h;A 96%
B n/a
carbon dioxide
124-38-9

carbon dioxide

2-Bromo-m-xylene
576-22-7

2-Bromo-m-xylene

2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

Conditions
ConditionsYield
Stage #1: 2-Bromo-m-xylene With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1h; Inert atmosphere;
Stage #2: carbon dioxide In tetrahydrofuran; hexane at -78 - 20℃;
93.2%
Stage #1: 2-Bromo-m-xylene With ethyl bromide; magnesium In diethyl ether Grignard reaction; Inert atmosphere; Reflux;
Stage #2: carbon dioxide In diethyl ether at 20℃; Grignard reaction; Inert atmosphere;
54%
(i) Mg, (ii) /BRN= 1900390/; Multistep reaction;
(i) Mg, EtBr, Et2O, (ii) /BRN= 1900390/; Multistep reaction;
carbon dioxide
124-38-9

carbon dioxide

2,6-dimethylbenzene boronic acid
100379-00-8

2,6-dimethylbenzene boronic acid

2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

Conditions
ConditionsYield
With chloro[1,3-bis(2,6-di-i-propylphenyl)imidazol-2-ylidene]copper(I); potassium methanolate In tetrahydrofuran at 70℃; for 24h; Schlenk technique; Sealed tube;88%
2,6-dimethylphenyl trifluoromethanesulphonate
86364-02-5

2,6-dimethylphenyl trifluoromethanesulphonate

2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

Conditions
ConditionsYield
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; potassium acetate In 1,4-dioxane; water at 50℃; for 12h; Schlenk technique; Inert atmosphere; chemoselective reaction;82%
2,6-dimethyl-N-(quinolin-8-yl)benzamide
1609401-42-4

2,6-dimethyl-N-(quinolin-8-yl)benzamide

2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

Conditions
ConditionsYield
With sulfuric acid; water at 120℃; for 24h;80%
2,6-dimethylphenyl 2,3,4,5,6-pentafluorobenzenesulfonate

2,6-dimethylphenyl 2,3,4,5,6-pentafluorobenzenesulfonate

2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

Conditions
ConditionsYield
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; potassium acetate In 1,4-dioxane; water at 50℃; for 12h; Schlenk technique; Inert atmosphere; chemoselective reaction;79%
ortho-methylbenzoic acid
118-90-1

ortho-methylbenzoic acid

dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

Conditions
ConditionsYield
With dipotassium hydrogenphosphate; silver carbonate; p-benzoquinone; palladium diacetate In tert-butyl alcohol at 100℃; for 3h;75%
carbon dioxide
124-38-9

carbon dioxide

C10H14Si

C10H14Si

2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

Conditions
ConditionsYield
Stage #1: carbon dioxide With bis(1,5-cyclooctadiene)nickel (0); 1,3-bis-(2,6-diisopropylphenyl)-imidazol-2-ylidene In 1,3,5-trimethyl-benzene at 20℃; under 760.051 Torr; for 0.166667h; Schlenk technique;
Stage #2: C10H14Si In 1,3,5-trimethyl-benzene at 160℃; for 20h; Schlenk technique;
58%
dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

sodium o-toluate
17264-71-0

sodium o-toluate

2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

Conditions
ConditionsYield
With silver carbonate; p-benzoquinone; palladium diacetate In tert-butyl alcohol at 100℃; for 3h;50%
dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

2-methylbenzoic acid potassium salt
16463-31-3

2-methylbenzoic acid potassium salt

2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

Conditions
ConditionsYield
With silver carbonate; p-benzoquinone; palladium diacetate In tert-butyl alcohol at 100℃; for 3h;48%
ortho-methylbenzoic acid
118-90-1

ortho-methylbenzoic acid

di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

Conditions
ConditionsYield
With potassium acetate; palladium diacetate at 80℃; under 760.051 Torr; for 24h;48%
With potassium acetate; palladium diacetate at 80℃; for 24h; Schlenk technique;48%
2-fluoro-m-xylene
443-88-9

2-fluoro-m-xylene

carbon dioxide
124-38-9

carbon dioxide

2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

Conditions
ConditionsYield
Stage #1: 2-fluoro-m-xylene With C78H70Al2Cl4N6P4Rh2; magnesium; ethylene dibromide In tetrahydrofuran at 50℃; for 22h; Inert atmosphere; Glovebox;
Stage #2: carbon dioxide In tetrahydrofuran at 20℃; under 760.051 Torr; for 0.5h;
48%
1,2,3-trimethylbenzene
526-73-8

1,2,3-trimethylbenzene

A

2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

B

2,3-dimethylbenzoic acid
603-79-2

2,3-dimethylbenzoic acid

Conditions
ConditionsYield
With air; acetic acid; 1N,3N,5N-trihydroxy-1,3,5-triazin-2,4,6[1H,3H,5H]-trione; cobalt(II) acetate; manganese(II) acetate at 100℃; under 760 Torr; for 1h;A 13%
B 36%
carbon monoxide
201230-82-2

carbon monoxide

2,6-dimethylbenzenediazonium tetrafluoroborate
2192-33-8

2,6-dimethylbenzenediazonium tetrafluoroborate

A

2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

B

N-(2,6-dimethylphenyl)acetamide
2198-53-0

N-(2,6-dimethylphenyl)acetamide

C

2,6-Dimethylbenzoic anhydride
73368-14-6

2,6-Dimethylbenzoic anhydride

Conditions
ConditionsYield
With sodium acetate; palladium diacetate In acetonitrile under 6619.6 Torr; for 1h; Ambient temperature;A 28%
B 16%
C 3%
2,5-dimethylbenzamide
55321-98-7

2,5-dimethylbenzamide

2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

Conditions
ConditionsYield
With phosphoric acid at 145 - 150℃;
4-amino-2,6-dimethyl benzoic acid
16752-16-2

4-amino-2,6-dimethyl benzoic acid

2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

Conditions
ConditionsYield
Diazotization.Reaktion ueber mehrere Stufen;
2,2,2-trichloro-1-(2,6-dimethyl-phenyl)-ethanone
99184-32-4

2,2,2-trichloro-1-(2,6-dimethyl-phenyl)-ethanone

A

2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

B

(2,6-dimethyl-phenyl)-hydroxy-acetic acid
99186-43-3

(2,6-dimethyl-phenyl)-hydroxy-acetic acid

Conditions
ConditionsYield
With sodium hydroxide
(2,6-dimethyl-benzyl)-dimethyl-amine
54521-25-4

(2,6-dimethyl-benzyl)-dimethyl-amine

2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

Conditions
ConditionsYield
With sodium hydroxide; potassium permanganate
2,6-dimethylbenzoyl chloride
21900-37-8

2,6-dimethylbenzoyl chloride

2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

Conditions
ConditionsYield
With water In acetone at -20℃; Rate constant;
2,6-dimethylaniline
87-62-7

2,6-dimethylaniline

2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

Conditions
ConditionsYield
1) diazotation; Multistep reaction;
Multi-step reaction with 2 steps
1: (i) (diazotization), aq. HBr, (ii) Cu
2: (i) Mg, (ii) /BRN= 1900390/
View Scheme
Multi-step reaction with 2 steps
1: (i) NaNO2, aq. HBr, (ii) CuBr
2: (i) Mg, EtBr, Et2O, (ii) /BRN= 1900390/
View Scheme
Multi-step reaction with 2 steps
1: (i) NaNO2, aq. HCl, (ii) /BRN= 4652394/, CuSO4, aq. NH3, benzene
2: aq. H2SO4 / Heating
View Scheme
bis(2,6-dimethylbenzoyl) peroxide
96436-29-2

bis(2,6-dimethylbenzoyl) peroxide

A

2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

B

m-xylene
108-38-3

m-xylene

C

2,6-dimethylphenyl 2,6-dimethylbenzoate

2,6-dimethylphenyl 2,6-dimethylbenzoate

Conditions
ConditionsYield
With 2,4,6-tri-tert-butylphenoxol In acetonitrile Ambient temperature; Irradiation; laser flash photolyses with 308-nm laser puses; Yield given. Yields of byproduct given;
With 2,4,6-tri-tert-butylphenoxol In acetonitrile Ambient temperature; Irradiation; Yield given. Yields of byproduct given;
In acetonitrile Product distribution; Mechanism; Irradiation; in the presence or absence of 2,4,6-tri-tert-butylphenol and/or dibenzoyl peroxide; structural and solvent effect upon decarboxylation investigated of various 2,6-disubstituited benzoyloxy radicals;
ethanol
64-17-5

ethanol

2,6-dimethylbenzoyl chloride
21900-37-8

2,6-dimethylbenzoyl chloride

A

2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

B

2,6-dimethylbenzoic acid ethyl ester
36596-67-5

2,6-dimethylbenzoic acid ethyl ester

Conditions
ConditionsYield
With water at 10℃; Kinetics; Thermodynamic data; Product distribution; solvolysis examined; var. solvents and ratio of ones; mechanism; ΔH(excit.), ΔS(excit.);
2,6-dimethyliodobenzene
608-28-6

2,6-dimethyliodobenzene

carbon dioxide
124-38-9

carbon dioxide

2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

Conditions
ConditionsYield
(i) Mg, EtBr, I2, (ii) /BRN= 1900390/; Multistep reaction;
2,6-dimethylbenzonitrile
6575-13-9

2,6-dimethylbenzonitrile

2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

Conditions
ConditionsYield
With sulfuric acid Heating;
Multi-step reaction with 2 steps
1: concentrated sulfuric acid / 75 - 80 °C
2: phosphoric acid / 145 - 150 °C
View Scheme
4-chloro-2,6-dimethyl benzoic acid
35887-72-0

4-chloro-2,6-dimethyl benzoic acid

2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

Conditions
ConditionsYield
With sodium hydroxide; nickel
methanol
67-56-1

methanol

methyl 2,6-dimethylbenzoate
14920-81-1

methyl 2,6-dimethylbenzoate

A

7-methyl-3H-isobenzofuran-1-one
2211-84-9

7-methyl-3H-isobenzofuran-1-one

B

2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

C

2-Methoxymethyl-6-methylbenzoesaeure

2-Methoxymethyl-6-methylbenzoesaeure

Conditions
ConditionsYield
With sodium hydroxide; N-Bromosuccinimide 1.) CCl4, reflux, 3 h, irradiation, 2.) reflux, 35 h; Yield given. Multistep reaction. Yields of byproduct given;
methylammonium carbonate
15719-64-9, 15719-76-3, 97762-63-5

methylammonium carbonate

2,6-dimethyl-phenyl magnesium bromide

2,6-dimethyl-phenyl magnesium bromide

2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

methylammonium carbonate
15719-64-9, 15719-76-3, 97762-63-5

methylammonium carbonate

2,6-dimethyl-phenyl magnesium iodide

2,6-dimethyl-phenyl magnesium iodide

2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

diazotized 2-amino-m-xylene

diazotized 2-amino-m-xylene

potassium cuprocyanide

potassium cuprocyanide

2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

Conditions
ConditionsYield
durch Verseifung;
2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

2,6-dimethylbenzyl alcohol
62285-58-9

2,6-dimethylbenzyl alcohol

Conditions
ConditionsYield
With Trimethyl borate; dimethylsulfide borane complex In tetrahydrofuran for 72h; Ambient temperature;100%
Stage #1: 2,6-dimethylbenzoic acid With borane-THF In tetrahydrofuran at 0 - 20℃; for 64.3333h;
Stage #2: With methanol In tetrahydrofuran
99%
With borane-THF In tetrahydrofuran at 0 - 20℃; for 64.3h;99%
2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

dimethyl sulfate
77-78-1

dimethyl sulfate

methyl 2,6-dimethylbenzoate
14920-81-1

methyl 2,6-dimethylbenzoate

Conditions
ConditionsYield
With potassium carbonate In acetone at 20℃;100%
With potassium carbonate In acetone at 20℃; for 4h;93%
With potassium hydroxide
With potassium carbonate at 25℃; for 1h;
2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

methylamine
74-89-5

methylamine

2,6-dimethyl-N-methylbenzamide
223554-22-1

2,6-dimethyl-N-methylbenzamide

Conditions
ConditionsYield
100%
2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

C82H102N4O28Pt8

C82H102N4O28Pt8

C124H138N4O28Pt8

C124H138N4O28Pt8

Conditions
ConditionsYield
In methanol; dichloromethane at 20℃; for 6h;100%
2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

tetramethyl ammoniumhydroxide
75-59-2

tetramethyl ammoniumhydroxide

C9H9O2(1-)*C4H12N(1+)

C9H9O2(1-)*C4H12N(1+)

Conditions
ConditionsYield
With water In ethanol at 0 - 20℃; for 0.0833333h;100%
2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

1-ethoxyacetylene
927-80-0

1-ethoxyacetylene

2,6-Dimethyl-benzoic acid 1-ethoxy-vinyl ester

2,6-Dimethyl-benzoic acid 1-ethoxy-vinyl ester

Conditions
ConditionsYield
With [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2 In toluene at 0 - 20℃; for 5h;99.9%
norborn-2-ene
498-66-8

norborn-2-ene

2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

C8H11O2C6H5CH2CH2

C8H11O2C6H5CH2CH2

Conditions
ConditionsYield
silver trifluoromethanesulfonate; iron(III) chloride In 1,2-dichloro-ethane at 80℃;99%
2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

diphenyl acetylene
501-65-5

diphenyl acetylene

C23H20O2

C23H20O2

Conditions
ConditionsYield
With [{Au(IPr)}2(μ-OH)][BF4] In neat (no solvent) at 80℃; for 15h; regioselective reaction;99%
2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

2,6-dimethyl-3-nitrobenzoic acid
6307-70-6

2,6-dimethyl-3-nitrobenzoic acid

Conditions
ConditionsYield
With sulfuric acid; nitric acid at 0℃; for 1.5h;98%
With sulfuric acid; nitric acid at 0℃; for 1h;
With nitric acid; acetic acid In (2S)-N-methyl-1-phenylpropan-2-amine hydrate; sulfuric acid
2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

cyanoacetic acid
372-09-8

cyanoacetic acid

cyanomethyl 2,6-dimethylbenzoate

cyanomethyl 2,6-dimethylbenzoate

Conditions
ConditionsYield
With tert.-butylhydroperoxide; sodium acetate; tetra-(n-butyl)ammonium iodide In tetrahydrofuran; water at 80℃; for 12h;98%
With tert.-butylhydroperoxide; sodium acetate; tetra-(n-butyl)ammonium iodide In tetrahydrofuran; water at 80℃; for 12h;96%
2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

methyl iodide
74-88-4

methyl iodide

methyl 2,6-dimethylbenzoate
14920-81-1

methyl 2,6-dimethylbenzoate

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 24h; Inert atmosphere;97%
With potassium carbonate In N,N-dimethyl-formamide at 0 - 25℃; for 5h; Inert atmosphere;95%
With potassium carbonate In N,N-dimethyl-formamide at 0 - 20℃; for 16h; Inert atmosphere;89%
styrene
292638-84-7

styrene

2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

2-bromo-1-phenylethyl 2,6-dimethylbenzoate

2-bromo-1-phenylethyl 2,6-dimethylbenzoate

Conditions
ConditionsYield
With C19H27NO2 In n-heptane at 23℃; Darkness; Green chemistry;97%
With N-Bromosuccinimide; C25H44NO2PS In chloroform at 25℃; for 20h; Darkness; regioselective reaction;90%
2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

N-Cyclohexyl-2-hydroxy-2-(S)-pyrrolidin-2-yl-acetamide; hydrochloride

N-Cyclohexyl-2-hydroxy-2-(S)-pyrrolidin-2-yl-acetamide; hydrochloride

N-cyclohexyl-(RS)-2-hydroxy-2-{(S)-2-[1-(2,6-dimethylbenzoyl)pyrrolidinyl]}acetamide

N-cyclohexyl-(RS)-2-hydroxy-2-{(S)-2-[1-(2,6-dimethylbenzoyl)pyrrolidinyl]}acetamide

Conditions
ConditionsYield
With benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine In N,N-dimethyl-formamide Ambient temperature;96.3%
2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

2,6-dimethylcyclohexa-2,5-diene-1-carboxylic acid
31673-42-4

2,6-dimethylcyclohexa-2,5-diene-1-carboxylic acid

Conditions
ConditionsYield
With ammonia; sodium In ethanol at -50℃; Birch reduction;96%
With tert-Amyl alcohol; lithium In tetrahydrofuran; ammonia Birch Reduction; Reflux; liquid NH3;90%
With N,N'-Dimethylurea; tris(pyrrolidino)phosphine oxide; lithium bromide In tetrahydrofuran Electrochemical reaction;90%
2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

2,6-Dimethylbenzoic anhydride
73368-14-6

2,6-Dimethylbenzoic anhydride

Conditions
ConditionsYield
With 2,6-dimethylpyridine; tris(2,2'-bipyridyl)ruthenium dichloride; carbon tetrabromide; N,N-dimethyl-formamide at 25 - 30℃; for 12h; Inert atmosphere; Photolysis;96%
With potassium carbonate; p-toluenesulfonyl chloride In dichloromethane; acetonitrile at 20℃; for 48h;94%
With copper(II) bis(trifluoromethanesulfonate) at 80℃; for 0.5h;81%
ethanol
64-17-5

ethanol

2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

2,6-dimethylbenzoic acid ethyl ester
36596-67-5

2,6-dimethylbenzoic acid ethyl ester

Conditions
ConditionsYield
With sulfuric acid at 100℃; for 12h; Sealed tube;95%
2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

(R)-[1-(naphthalen-2-yl)ethyl]amine
1201-74-7, 3082-62-0, 3906-16-9, 64234-21-5

(R)-[1-(naphthalen-2-yl)ethyl]amine

2,6-dimethyl-N-[(R)-1-(2-naphthyl)ethyl]benzamide
1184301-95-8

2,6-dimethyl-N-[(R)-1-(2-naphthyl)ethyl]benzamide

Conditions
ConditionsYield
With benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; N-ethyl-N,N-diisopropylamine In N,N-dimethyl-formamide at 0 - 23℃; Combinatorial reaction / High throughput screening (HTS); Inert atmosphere;94%
2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

propionyl chloride
79-03-8

propionyl chloride

2,6-dimethylbenzoic propionic anhydride

2,6-dimethylbenzoic propionic anhydride

Conditions
ConditionsYield
With triethylamine In tetrahydrofuran at 0 - 20℃; Inert atmosphere;94%
2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

2,3-dimethyl-N-(quinolin-8-yl)benzamide

2,3-dimethyl-N-(quinolin-8-yl)benzamide

3,4-dimethyl-2-(quinolin-8-ylcarbamoyl)phenyl 2,6-dimethylbenzoate

3,4-dimethyl-2-(quinolin-8-ylcarbamoyl)phenyl 2,6-dimethylbenzoate

Conditions
ConditionsYield
With silver carbonate; cobalt acetylacetonate In 1,2-dichloro-ethane at 100℃; for 3h;94%
2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

carbonic acid dimethyl ester
616-38-6

carbonic acid dimethyl ester

methyl 2,6-dimethylbenzoate
14920-81-1

methyl 2,6-dimethylbenzoate

Conditions
ConditionsYield
With tributyl-amine In N,N-dimethyl-formamide at 285℃; under 112511 Torr; for 0.05h;93%
With sulfuric acid at 80 - 85℃; for 8h; Neat (no solvent);74.5%
1-ethenyl-4-methylbenzene
622-97-9

1-ethenyl-4-methylbenzene

2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

2-bromo-1-(p-tolyl)ethyl 2,6-dimethylbenzoate

2-bromo-1-(p-tolyl)ethyl 2,6-dimethylbenzoate

Conditions
ConditionsYield
With C19H27NO2 In n-heptane at 23℃; Darkness; Green chemistry;93%
2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

3-methoxy-2-methyl-N-(quinolin-8-yl)benzamide

3-methoxy-2-methyl-N-(quinolin-8-yl)benzamide

4-methoxy-3-methyl-2-(quinolin-8-ylcarbamoyl)phenyl 2,6-dimethylbenzoate

4-methoxy-3-methyl-2-(quinolin-8-ylcarbamoyl)phenyl 2,6-dimethylbenzoate

Conditions
ConditionsYield
With silver carbonate; cobalt acetylacetonate In 1,2-dichloro-ethane at 100℃; for 3h;92%
4-vinylbenzyl chloride
1073-67-2

4-vinylbenzyl chloride

2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

2-bromo-1-(4-chlorophenyl)ethyl 2,6-dimethylbenzoate

2-bromo-1-(4-chlorophenyl)ethyl 2,6-dimethylbenzoate

Conditions
ConditionsYield
With C19H27NO2 In n-heptane at 23℃; Darkness; Green chemistry;92%
alpha-D-glucopyranose
492-62-6

alpha-D-glucopyranose

2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

1-O-(2,6-dimethylbenzoyl)-β-D-glucopyranoside

1-O-(2,6-dimethylbenzoyl)-β-D-glucopyranoside

Conditions
ConditionsYield
With di-isopropyl azodicarboxylate; triphenylphosphine In 1,4-dioxane at 20℃; for 0.5h; Mitsunobu Displacement; Inert atmosphere; stereoselective reaction;92%
2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

C21H38BrN3O4

C21H38BrN3O4

C30H47N3O6

C30H47N3O6

Conditions
ConditionsYield
With potassium fluoride In acetonitrile at 20℃; for 12h; Cooling with ice;91%
1-bromo-4-ethenyl-benzene
2039-82-9

1-bromo-4-ethenyl-benzene

2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

2-bromo-1-(4-bromophenyl)ethyl 2,6-dimethylbenzoate

2-bromo-1-(4-bromophenyl)ethyl 2,6-dimethylbenzoate

Conditions
ConditionsYield
With C19H27NO2 In n-heptane at 23℃; Darkness; Green chemistry;91%
Methyl trichloroacetate
598-99-2

Methyl trichloroacetate

2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

methyl 2,6-dimethylbenzoate
14920-81-1

methyl 2,6-dimethylbenzoate

Conditions
ConditionsYield
With 18-crown-6 ether; potassium carbonate at 90 - 150℃; for 2h;90%
1,4-dioxane
123-91-1

1,4-dioxane

2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

C13H16O4
1284251-40-6

C13H16O4

Conditions
ConditionsYield
With tert.-butylhydroperoxide; tetra-(n-butyl)ammonium iodide In water; ethyl acetate at 80℃; for 12h;90%

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