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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

2-Iodo-1,3-dimethylbenzene

Cas:608-28-6

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 2-Iodo-1,3-Dimethylbenzene WITH HIGH PURITY

Cas:608-28-6

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Hebei yanxi chemical co.,LTD.

Hebei Yanxi Chemical Co., Ltd. is a professional research, development and production of lead acetate benzene acetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low car

2,6-Dimethyliodobenzene

Cas:608-28-6

Min.Order:1 Metric Ton

FOB Price: $1.0 / 2.0

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

2-Iodo-m-xylene

Cas:608-28-6

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Factory direct supply CAS 608-28-6 with best quality

Cas:608-28-6

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Purity 97% CAS 608-28-6 Application Syntheses Material Intermediates Appearance clear green-brown to brown liquid Name

2-Iodo-1,3-Dimethylbenzene

Cas:608-28-6

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

inquiry

Henan Wentao Chemical Product Co., Ltd.

1)quick response within 12 hours; 2)quality guarantee: all products are strictly tested by our qc, confirmed by qa and approved by third party lab in china, usa, canada, germany, uk, italy, france etc. 3) oem/odm available; 4) reasonable & compet

2-Iodo-1,3-dimethylbenzeneCAS NO.:608-28-6

Cas:608-28-6

Min.Order:100 Gram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Benzene,2-iodo-1,3-dimethyl- 608-28-6

Cas:608-28-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At present

2-Iodo-1,3-dimethylbenzene

Cas:608-28-6

Min.Order:1 Gram

FOB Price: $29.0

Type:Trading Company

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

2-Iodo-1,3-dimethylbenzene

Cas:608-28-6

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

2-Iodo-1,3-dimethylbenzene

Cas:608-28-6

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 2-Iodo-m-xylene

Cas:608-28-6

Min.Order:0 Metric Ton

Negotiable

Type:Other

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Benzene,2-iodo-1,3-dimethyl-

Cas:608-28-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Henan Tianfu Chemical Co., Ltd.

Tianfu Chemical, built in 2009, is a professional supplier for API materials in China. With 10 years development, we have bulit our own factory and lab to produce a certain of products. And we have established stable business relationships with ma

TIANFU 608-28-6 2-Iodo-1,3-dimethylbenzene

Cas:608-28-6

Min.Order:1 Kilogram

FOB Price: $200.0

Type:Lab/Research institutions

inquiry

Shanghai Minstar Chemical Co., Ltd

Product Name: 2-Iodo-1,3-dimethylbenzene Synonyms: 1,2-Dimethyl-2-jodbenzol;1-Iodo-2,6-dimethylbenzene;2,6-Dimethyl-1-iodobenzene;2-iodo-1,3-dimethyl-benzen;2-Jod-m-xylol;Benzene,2-iodo-1,3-dimethyl-;m-Xylene, 2-iodo-;I**2-IODO-M-XYLENE CAS:

2-Iodo-1,3-dimethylbenzene

Cas:608-28-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

2-Iodo-m-xylene

Cas:608-28-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

SAGECHEM LIMITED

SAGECHEM is a chemical R&D, manufacturing and distribution company in China since 2009, including pharmaceutical intermediates, agrochemical, dyestuff intermediates, organosilicone, API and etc. We also offer a full range of services in custom synthe

SAGECHEM/2,6-Dimethyliodobenzene

Cas:608-28-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

2-iodo-1,3-dimethylbenzene

Cas:608-28-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Golden Pharma Co., Limited

GOLDEN PHARMA CO.,LIMITED.is a professional pharmaceutical company,our team have more than 20years expereince in pharmaceutical production and sales. we are a professional technical enterprise specializing in the R & D, production,QA regulation

2-Iodo-1,3-diMethylbenzene

Cas:608-28-6

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

Beijing Greenchem Technology Co.,Ltd. ( Panjin Greenchem Technology Co.Ltd .)

Capability on chemical synthesis1. Beijing High-Tech Enterprises2. Strong R&D Team3. 8 years of experiences in R & D of high-tech Catalyst;4. 5000 production techniques, 69 items of national patents, and 360 kinds of products on sales;5. The producti

2,6-Dimethyliodobenzene

Cas:608-28-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Changzhou Anchor Biological Technology Co., Ltd.

Our company is engaged in customizing the benzene ring and pyridine derivative organic intermediates, and the quantity is flexible according to customer's needs. It mainly provides high-quality intermediates for domestic and foreign pharmaceutical an

2-Iodo-1,3-dimethylbenzene Manufacturer/High quality/Best price/In stock CAS NO.608-28-6

Cas:608-28-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

1,3-Dimethyl-2-Iodobenzene cas no. 608-28-6 98%

Cas:608-28-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

2-Iodo-1,3-dimethylbenzene

Cas:608-28-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

2-Iodo-M-xylene

Cas:608-28-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

2-Iodo-1,3-Dimethylbenzene

Cas:608-28-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city?in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new api,?intermediat

2-Iodo-1,3-dimethylbenzene

Cas:608-28-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Chemsigma International Co.,Ltd.

bulk productiongoods in stockswe have the best competitive price in the marketmeantime,we are committed to service to our every customer Chemsigma International Co.,Ltd. is a chemical manufacturer, specialize in custom synthesis and organic chemical

2-Iodo-1,3-dimethylbenzene

Cas:608-28-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Nanjing Fred Technology Co.,Ltd.

Fredchem focus on CRO/CMO business and its own R&D of API/Intermediates Package:Grams, Kilograms Application:Pharmaceutical field Transportation:According to customer request Port:Shanghai

2-Iodo-1,3-dimethylbenzene

Cas:608-28-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages? High purity, all above 98.5%, no impurities after dissolution? We will test each batch to ensure quality? OEM and private brand services designed for free? Various cap colors available? We can also provide MT1 peptide powder2.

2-Iodo-1,3-dimethylbenzene

Cas:608-28-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

2-Iodo-M-xylene

Cas:608-28-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

potassium 2,6-dimethylphenyltrifluoroborate

potassium 2,6-dimethylphenyltrifluoroborate

2,6-dimethyliodobenzene
608-28-6

2,6-dimethyliodobenzene

Conditions
ConditionsYield
With chloroamine-T; sodium iodide In tetrahydrofuran; water at 20℃; for 0.25h;84%
2,6-dimethylbenzene boronic acid
100379-00-8

2,6-dimethylbenzene boronic acid

2,6-dimethyliodobenzene
608-28-6

2,6-dimethyliodobenzene

Conditions
ConditionsYield
With iodine; potassium carbonate In acetonitrile at 80℃; for 12h; Inert atmosphere; Schlenk technique; Sealed tube;78%
1,3-dichloro-2-iodobenzene
19230-28-5

1,3-dichloro-2-iodobenzene

(2,6-dimethylphenyl)magnesium bromide
21450-64-6

(2,6-dimethylphenyl)magnesium bromide

A

2,6-dimethyliodobenzene
608-28-6

2,6-dimethyliodobenzene

B

2,6,2'',6''-tetramethyl-1,1':3',1''-terphenyl
83909-08-4

2,6,2'',6''-tetramethyl-1,1':3',1''-terphenyl

Conditions
ConditionsYield
In tetrahydrofuran for 3h; Heating;A n/a
B 70%
2,6-dimethylaniline
87-62-7

2,6-dimethylaniline

2,6-dimethyliodobenzene
608-28-6

2,6-dimethyliodobenzene

Conditions
ConditionsYield
Stage #1: 2,6-dimethylaniline With tert.-butylnitrite; acetic acid; saccharin In ethanol at 0℃;
Stage #2: With tetraethylammonium iodide In ethanol; water at 0 - 20℃;
67%
Diazotization.Behandlung der Diazoniumsalz-Loesung mit KI;
Diazotization.Umsetzung der Diazoverbindung mit Kaliumjodid;
bis(trifluoromethanesulfonyl)amide
82113-65-3

bis(trifluoromethanesulfonyl)amide

2,6-dimethylaniline
87-62-7

2,6-dimethylaniline

2,6-dimethyliodobenzene
608-28-6

2,6-dimethyliodobenzene

Conditions
ConditionsYield
Stage #1: bis(trifluoromethanesulfonyl)amide With tert.-butylnitrite; acetic acid In ethanol Cooling with ice;
Stage #2: 2,6-dimethylaniline With tetraethylammonium iodide In water at 20℃;
67%
2,6-dimethylbenzoic acid
632-46-2

2,6-dimethylbenzoic acid

2,6-dimethyliodobenzene
608-28-6

2,6-dimethyliodobenzene

Conditions
ConditionsYield
With potassium phosphate; iodine In acetonitrile at 100℃; for 9h; Temperature; Solvent; Glovebox; Inert atmosphere; chemoselective reaction;55%
m-xylene
108-38-3

m-xylene

A

1-iodo-2,4-dimethylbenzene
4214-28-2

1-iodo-2,4-dimethylbenzene

B

2,6-dimethyliodobenzene
608-28-6

2,6-dimethyliodobenzene

Conditions
ConditionsYield
With tetrafluoroboric acid; [bis(pyridine)iodine]+ tetrafluoroborate In diethyl ether; dichloromethane Ambient temperature; Yield given. Yields of byproduct given;
With sulfuric acid; iodine In acetonitrile at 0℃; for 0.5h; Electrolysis; Overall yield = 86 %; regioselective reaction;
2-dichloroiodanyl-1,3-dimethyl-benzene
116599-63-4

2-dichloroiodanyl-1,3-dimethyl-benzene

acetic acid
64-19-7

acetic acid

A

2,6-dimethyliodobenzene
608-28-6

2,6-dimethyliodobenzene

B

chlorine
7782-50-5

chlorine

Conditions
ConditionsYield
at 25℃; Equilibrium constant; sowie bei 46grad;
2-Bromo-m-xylene
576-22-7

2-Bromo-m-xylene

2,6-dimethyliodobenzene
608-28-6

2,6-dimethyliodobenzene

Conditions
ConditionsYield
Stage #1: 2-Bromo-m-xylene In 1,2-dimethoxyethane for 2h;
Stage #2: With iodine In tetrahydrofuran at 20℃; for 3h;
1,4-diiodo-2,6-dimethylbenzene
4102-48-1

1,4-diiodo-2,6-dimethylbenzene

phenol
108-95-2

phenol

A

2,6-dimethyliodobenzene
608-28-6

2,6-dimethyliodobenzene

B

2-iodo-1,3-dimethyl-5-phenoxybenzene
1227681-30-2

2-iodo-1,3-dimethyl-5-phenoxybenzene

C

3,5-dimethylphenyl iodide
22445-41-6

3,5-dimethylphenyl iodide

Conditions
ConditionsYield
Stage #1: phenol With sodium hydride In tetrahydrofuran at 20℃; for 0.5h; Inert atmosphere;
Stage #2: With copper(l) chloride In tetrahydrofuran at 20℃; for 0.5h; Inert atmosphere;
Stage #3: 1,4-diiodo-2,6-dimethylbenzene Further stages;
A 7 %Chromat.
B 86 %Chromat.
C 8 %Chromat.
2,6-dimethyliodobenzene
608-28-6

2,6-dimethyliodobenzene

carbon monoxide
201230-82-2

carbon monoxide

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

2,2',6-trimethylbenzophenone
14252-17-6

2,2',6-trimethylbenzophenone

Conditions
ConditionsYield
With [1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene](3-chloropyridyl)palladium(II) dichloride; caesium carbonate In chlorobenzene at 80℃; under 760.051 Torr; for 24h; Inert atmosphere;99%
With [1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene](3-chloropyridyl)palladium(ll) dichloride; caesium carbonate In 1,4-dioxane at 140℃; under 3102.97 Torr; for 24h; Pressure reactor;93%
2,6-dimethyliodobenzene
608-28-6

2,6-dimethyliodobenzene

carbon monoxide
201230-82-2

carbon monoxide

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

(4-methoxyphenyl)(2,6-dimethylphenyl)methanone
52629-41-1

(4-methoxyphenyl)(2,6-dimethylphenyl)methanone

Conditions
ConditionsYield
With [1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene](3-chloropyridyl)palladium(II) dichloride; caesium carbonate In 1,4-dioxane at 140℃; under 3102.97 Torr; for 24h; Inert atmosphere;99%
With [1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene](3-chloropyridyl)palladium(ll) dichloride; caesium carbonate In 1,4-dioxane at 140℃; under 3102.97 Torr; for 24h;92%
peracetic acid
79-21-0

peracetic acid

2,6-dimethyliodobenzene
608-28-6

2,6-dimethyliodobenzene

(2,6-dimethylphenyl)-λ3-iodanediyl diacetate
123084-61-7

(2,6-dimethylphenyl)-λ3-iodanediyl diacetate

Conditions
ConditionsYield
In acetic acid at 20℃; for 20h;99%
With acetic anhydride; acetic acid at -10 - 20℃;69%
2,6-dimethyliodobenzene
608-28-6

2,6-dimethyliodobenzene

phenylacetylene
536-74-3

phenylacetylene

2,6-dimethyl-1-(phenylethynyl)benzene
180783-48-6

2,6-dimethyl-1-(phenylethynyl)benzene

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; (triphenylphosphine)gold(I) chloride; triethylamine In N,N-dimethyl-formamide at 80℃; for 1h; Sonogashira type cross-coupling; Inert atmosphere;98%
With (triphenylphosphine)gold(I) chloride; bis(triphenylphosphine)palladium(II) chloride; triethylamine In N,N-dimethyl-formamide at 80℃; for 1h; Sonogashira Cross-Coupling; Inert atmosphere;98%
With C20H29Cl2N5O2Pd; potassium carbonate In ethanol at 80℃; for 2h; Sonogashira Cross-Coupling;94%
2,6-dimethyliodobenzene
608-28-6

2,6-dimethyliodobenzene

4-bromo-N,N-diisopropylbenzamide
79606-46-5

4-bromo-N,N-diisopropylbenzamide

C21H27NO

C21H27NO

Conditions
ConditionsYield
Stage #1: 2,6-dimethyliodobenzene With tert.-butyl lithium In diethyl ether; pentane at -78℃; for 0.5h; Inert atmosphere;
Stage #2: With dimethylaluminum chloride In diethyl ether; hexane; pentane at -78 - 0℃; for 0.5h; Inert atmosphere;
Stage #3: 4-bromo-N,N-diisopropylbenzamide In tetrahydrofuran at 110℃; for 24h; Inert atmosphere; chemoselective reaction;
98%
2-aminopyridine
504-29-0

2-aminopyridine

2,6-dimethyliodobenzene
608-28-6

2,6-dimethyliodobenzene

N-(2,6-dimethylphenyl)pyridin-2-amine
376353-22-9

N-(2,6-dimethylphenyl)pyridin-2-amine

Conditions
ConditionsYield
With copper(l) iodide; potassium tert-butylate In 1,4-dioxane at 110℃; for 24h; Ullmann Condensation; Sealed tube; Inert atmosphere;97%
With copper(l) iodide; potassium tert-butylate In 1,4-dioxane at 110℃; for 24h; Inert atmosphere; Sealed tube;
2,6-dimethyliodobenzene
608-28-6

2,6-dimethyliodobenzene

4-(4-methoxyphenyl)-2-methyl-2-phenylbut-3-ynoic acid

4-(4-methoxyphenyl)-2-methyl-2-phenylbut-3-ynoic acid

2-(1-(4-methoxyphenyl)-3-phenylbuta-1,2-dien-1-yl)-1,3-dimethylbenzene

2-(1-(4-methoxyphenyl)-3-phenylbuta-1,2-dien-1-yl)-1,3-dimethylbenzene

Conditions
ConditionsYield
With caesium carbonate; bis(dibenzylideneacetone)-palladium(0) In benzene at 110℃; for 2h; Schlenk technique;97%
tributyl((1E,3E)-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)buta-1,3-dienyl)stannane

tributyl((1E,3E)-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)buta-1,3-dienyl)stannane

2,6-dimethyliodobenzene
608-28-6

2,6-dimethyliodobenzene

4,4,5,5-tetramethyl-2-((1E,3E)-4-(2,6-dimethylphenyl)buta-1,3-dienyl)-1,3,2-dioxaborolane

4,4,5,5-tetramethyl-2-((1E,3E)-4-(2,6-dimethylphenyl)buta-1,3-dienyl)-1,3,2-dioxaborolane

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); P(furyl)3 In 1-methyl-pyrrolidin-2-one at 50℃; for 24h; Stille cross-coupling reaction;96%
2,6-dimethyliodobenzene
608-28-6

2,6-dimethyliodobenzene

2-fluoro-m-xylene
443-88-9

2-fluoro-m-xylene

Conditions
ConditionsYield
With copper(I) trifluoromethanesulfonate bis(trimethylacetonitrile) complex; silver fluoride In N,N-dimethyl-formamide at 140℃; for 22h; Inert atmosphere;96%
2,6-dimethyliodobenzene
608-28-6

2,6-dimethyliodobenzene

2-(dimethylamino)malononitrile
19555-13-6

2-(dimethylamino)malononitrile

2,6-dimethylbenzonitrile
6575-13-9

2,6-dimethylbenzonitrile

Conditions
ConditionsYield
With copper(II) orthophosphate In N,N-dimethyl-formamide at 120℃; for 24h; Inert atmosphere; Sealed tube;96%
2,6-dimethyliodobenzene
608-28-6

2,6-dimethyliodobenzene

carbon monoxide
201230-82-2

carbon monoxide

(2,6-dimethoxyphenyl)boronic acid
23112-96-1

(2,6-dimethoxyphenyl)boronic acid

(2,6-dimethoxyphenyl)(2,6-dimethylphenyl)methanone
1082070-20-9

(2,6-dimethoxyphenyl)(2,6-dimethylphenyl)methanone

Conditions
ConditionsYield
With [1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene](3-chloropyridyl)palladium(II) dichloride; caesium carbonate In chlorobenzene at 80℃; under 760.051 Torr; for 24h; Inert atmosphere;95%
With [1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene](3-chloropyridyl)palladium(ll) dichloride; caesium carbonate In chlorobenzene at 80℃; for 24h;95%
2,6-dimethyliodobenzene
608-28-6

2,6-dimethyliodobenzene

carbon monoxide
201230-82-2

carbon monoxide

phenylboronic acid
98-80-6

phenylboronic acid

2,6-dimethylbenzophenone
1139-60-2

2,6-dimethylbenzophenone

Conditions
ConditionsYield
With [1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene](3-chloropyridyl)palladium(II) dichloride; caesium carbonate In chlorobenzene at 80℃; under 760.051 Torr; for 24h; Inert atmosphere;95%
With [1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene](3-chloropyridyl)palladium(ll) dichloride; caesium carbonate In 1,4-dioxane at 140℃; under 3102.97 Torr; for 24h; Pressure reactor;95%
Methyl 2-acetamidoacrylate
35356-70-8

Methyl 2-acetamidoacrylate

2,6-dimethyliodobenzene
608-28-6

2,6-dimethyliodobenzene

methyl (Z)-2-acetamido-3-(2',6'-dimethylphenyl)-2-propenoate
126312-79-6

methyl (Z)-2-acetamido-3-(2',6'-dimethylphenyl)-2-propenoate

Conditions
ConditionsYield
With palladium diacetate; triethylamine; tris-(o-tolyl)phosphine In acetonitrile for 24h; Heating;94%
[2-(hydroxymethyl)phenyl](dimethyl)phenylsilane
853955-69-8

[2-(hydroxymethyl)phenyl](dimethyl)phenylsilane

2,6-dimethyliodobenzene
608-28-6

2,6-dimethyliodobenzene

2,6-dimethyl-1,1′-biphenyl
3976-34-9

2,6-dimethyl-1,1′-biphenyl

Conditions
ConditionsYield
With N-cyclohexyl-1-[2-(diphenylphosphanyl)phenyl]methanimine; potassium carbonate; palladium dichloride In water; dimethyl sulfoxide at 50℃; for 13h;94%
2,6-dimethyliodobenzene
608-28-6

2,6-dimethyliodobenzene

2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

2,6-dimethylphenyl 2-methyl-2-propyl sulfide
16463-11-9

2,6-dimethylphenyl 2-methyl-2-propyl sulfide

Conditions
ConditionsYield
With (R)-1-[(SP)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine; palladium diacetate; sodium t-butanolate In 1,2-dimethoxyethane at 110℃; for 8h; Inert atmosphere;94%
2,6-dimethyliodobenzene
608-28-6

2,6-dimethyliodobenzene

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

2,2',6'-trimethylbiphenyl
10273-87-7

2,2',6'-trimethylbiphenyl

Conditions
ConditionsYield
Stage #1: 2,6-dimethyliodobenzene In water for 0.166667h;
Stage #2: 2-Methylphenylboronic acid With potassium phosphate In water at 105℃;
94%
pyrrole
109-97-7

pyrrole

2,6-dimethyliodobenzene
608-28-6

2,6-dimethyliodobenzene

carbon monoxide
201230-82-2

carbon monoxide

(2,6-dimethylphenyl)(1H-pyrrol-1-yl)methanone
1357477-16-7

(2,6-dimethylphenyl)(1H-pyrrol-1-yl)methanone

Conditions
ConditionsYield
With potassium phosphate; allylchloro[1,3-bis(2,6-di-isopropylphenyl)imidazol-2-ylidine]palladium(II) In toluene at 90℃; for 19h;93%
2,6-dimethyliodobenzene
608-28-6

2,6-dimethyliodobenzene

trimethylsilylacetylene
1066-54-2

trimethylsilylacetylene

1-(trimethylsilyl)-2-(2,6-dimethylphenyl)ethyne
384850-46-8

1-(trimethylsilyl)-2-(2,6-dimethylphenyl)ethyne

Conditions
ConditionsYield
With copper(l) iodide; tetrakis(triphenylphosphine) palladium(0) In diethylamine at 50℃; for 24h; Substitution;92%
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; diisopropylamine In tetrahydrofuran Sonogashira coupling;92%
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine In tetrahydrofuran at 60℃; Sonogashira coupling; Inert atmosphere;
2,6-dimethyliodobenzene
608-28-6

2,6-dimethyliodobenzene

2-(3-ethynylphenyl)benzofuran
1356364-32-3

2-(3-ethynylphenyl)benzofuran

2-(3-((2,6-dimethylphenyl)ethynyl)phenyl)benzofuran

2-(3-((2,6-dimethylphenyl)ethynyl)phenyl)benzofuran

Conditions
ConditionsYield
With potassium carbonate at 20℃; for 1h; Sonogashira Cross-Coupling;92%
2,6-dimethyliodobenzene
608-28-6

2,6-dimethyliodobenzene

phenylmagnesium bromide
100-58-3

phenylmagnesium bromide

2,6-dimethyl-1,1′-biphenyl
3976-34-9

2,6-dimethyl-1,1′-biphenyl

Conditions
ConditionsYield
In tetrahydrofuran; toluene at 110℃; for 24h; Inert atmosphere;91%
2,6-dimethyliodobenzene
608-28-6

2,6-dimethyliodobenzene

diphenyl acetylene
501-65-5

diphenyl acetylene

bis(pinacol)diborane
73183-34-3

bis(pinacol)diborane

(E)-2-(2-(2,6-dimethylphenyl)-1,2-diphenylvinyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
1612245-94-9

(E)-2-(2-(2,6-dimethylphenyl)-1,2-diphenylvinyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Conditions
ConditionsYield
With C18H33P*CuCl; sodium t-butanolate In toluene at 120℃; for 24h; Inert atmosphere; Glovebox;91%
2,6-dimethyliodobenzene
608-28-6

2,6-dimethyliodobenzene

N-(2-pyridyl)indole
3419-91-8

N-(2-pyridyl)indole

2-(2,6-dimethylphenyl)-1-(pyridin-2-yl)-1H-indole

2-(2,6-dimethylphenyl)-1-(pyridin-2-yl)-1H-indole

Conditions
ConditionsYield
With copper(l) chloride; lithium hexamethyldisilazane In neat (no solvent) at 120℃; for 16h; Sealed tube; Inert atmosphere; regioselective reaction;91%
2,6-dimethyliodobenzene
608-28-6

2,6-dimethyliodobenzene

2-(tetrahydro-2H-pyran-2-yl)-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2H-1,2,3-triazole
1415312-45-6

2-(tetrahydro-2H-pyran-2-yl)-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2H-1,2,3-triazole

4-(2,6-dimethylphenyl)-2-(tetrahydro-2H-pyran-2-yl)-2H-1,2,3-triazole
1415312-48-9

4-(2,6-dimethylphenyl)-2-(tetrahydro-2H-pyran-2-yl)-2H-1,2,3-triazole

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; cesium fluoride In methanol at 120℃; for 0.333333h; Suzuki-Miyaura Coupling; Inert atmosphere; Microwave irradiation;90%
2,6-dimethyliodobenzene
608-28-6

2,6-dimethyliodobenzene

4-methoxyphenylacetylen
768-60-5

4-methoxyphenylacetylen

2-((4-methoxyphenyl)ethynyl)-1,3-dimethylbenzene
1243249-31-1

2-((4-methoxyphenyl)ethynyl)-1,3-dimethylbenzene

Conditions
ConditionsYield
With C20H29Cl2N5O2Pd; potassium carbonate In ethanol at 80℃; for 2h; Sonogashira Cross-Coupling;90%
2-Methylthiophene
554-14-3

2-Methylthiophene

2,6-dimethyliodobenzene
608-28-6

2,6-dimethyliodobenzene

2-methyl-5-phenylthiophene
5069-26-1

2-methyl-5-phenylthiophene

Conditions
ConditionsYield
With [Pd(η1-acetato)(Ph)(triphenylphosphine)]2 In tetrahydrofuran at 65℃; for 2h; Solvent;90%
2,6-dimethyliodobenzene
608-28-6

2,6-dimethyliodobenzene

pyridine-2-boronic acid N-phenyldiethanolamine ester
882521-96-2

pyridine-2-boronic acid N-phenyldiethanolamine ester

2-(2,2-dimethylphenyl)pyridine
10273-91-3

2-(2,2-dimethylphenyl)pyridine

Conditions
ConditionsYield
With palladium diacetate; potassium carbonate; triphenylphosphine; copper(l) iodide In tetrahydrofuran Suzuki-Miyaura cross-coupling reaction; Heating;89%
peracetic acid
79-21-0

peracetic acid

2,6-dimethyliodobenzene
608-28-6

2,6-dimethyliodobenzene

acetic acid
64-19-7

acetic acid

(2,6-dimethylphenyl)-λ3-iodanediyl diacetate
123084-61-7

(2,6-dimethylphenyl)-λ3-iodanediyl diacetate

Conditions
ConditionsYield
at 0 - 20℃;89%
2,6-dimethyliodobenzene
608-28-6

2,6-dimethyliodobenzene

2.6-dimethylphenol
576-26-1

2.6-dimethylphenol

Conditions
ConditionsYield
With sodium hydroxide In water; dimethyl sulfoxide at 120℃; for 16h;89%
Stage #1: 2,6-dimethyliodobenzene With copper(l) iodide; 2-methyl-8-quinolinol; tetra(n-butyl)ammonium hydroxide In water; dimethyl sulfoxide at 100℃; for 10h;
Stage #2: With hydrogenchloride In water; N,N-dimethyl-formamide at 20℃;
88%
With glycolic Acid; copper hydroxide; sodium hydroxide In water; dimethyl sulfoxide at 120℃; for 6h; Inert atmosphere; Schlenk technique;87%
2,6-dimethyliodobenzene
608-28-6

2,6-dimethyliodobenzene

5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2-methylthiophene
476004-80-5

5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2-methylthiophene

2-(2,6-dimethylphenyl)-5-methylthiophene
1382179-43-2

2-(2,6-dimethylphenyl)-5-methylthiophene

Conditions
ConditionsYield
With allyl(cyclopentadiene)palladium(II); tetrabutylammomium bromide; triphenylphosphine; potassium hydroxide In water; toluene at 80℃; for 10h; Inert atmosphere; Schlenk technique;89%
2,6-dimethyliodobenzene
608-28-6

2,6-dimethyliodobenzene

p-trifluoromethylphenyl bromide
402-43-7

p-trifluoromethylphenyl bromide

2,6-dimethyl-4'-(trifluoromethyl)-1,1'-biphenyl

2,6-dimethyl-4'-(trifluoromethyl)-1,1'-biphenyl

Conditions
ConditionsYield
Stage #1: 2,6-dimethyliodobenzene With tert.-butyl lithium In diethyl ether; pentane at -78℃; for 0.5h; Inert atmosphere;
Stage #2: With dimethylaluminum chloride In diethyl ether; hexane; pentane at -78 - 0℃; for 0.5h; Inert atmosphere;
Stage #3: p-trifluoromethylphenyl bromide In tetrahydrofuran at 110℃; for 24h; Inert atmosphere; chemoselective reaction;
89%

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