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Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

Avobenzone

Cas:70356-09-1

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Avobenzone

Cas:70356-09-1

Min.Order:1

Negotiable

Type:Other

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Wuhan BJM Pharm Inc.

We have two factories in Dezhou , Shandong and Xianning, Hubei. The factory covers an area of 48,000 square meters with the building area of 26,000 square meters. We are specialized in the manufacture of pharmaceutical intermediates and cosmetic addi

Avobenzone CAS No: 70356-09-1 PARSOL1789 Benzoyl ketone UV absorbent Oil soluble sunscreen

Cas:70356-09-1

Min.Order:25 Kilogram

Negotiable

Type:Trading Company

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Qingdao Jade New Material Technology CO.,Ltd

■POLYMER ADDITIVES JADEWIN UV1789 CHEMICAL COMPONENT COMPONENT 4-T-BUTYL-4'-METHOXY-DIBENZOYLMETHANE CAS 70356-09-1 MOLECULAR C20H22O3 M.W 310.50 SPECIFICATION AND PHYSICAL

UV ABSORBER 1789

Cas:70356-09-1

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

Avobenzone Manufacturer/High quality/Best price/In stock

Cas:70356-09-1

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Avobenzone supplier in China

Cas:70356-09-1

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

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Hangzhou Dingyan Chem Co., Ltd

Items Standard Result Assay (Ursolic acid) 98%min 98.22% ----------------------------------------------------------------

High purity 70356-09-1 Avobenzone

Cas:70356-09-1

Min.Order:1 Gram

FOB Price: $100.0 / 500.0

Type:Trading Company

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Hubei Vanz Pharm Co.,Ltd

Hubei Vanz Pharm Co. Ltd. is located in Wuhan, Hubei province. We are one of the most professional company in pharm/chmecial industry for more than 10 years. We export to many countries and area with very competitive price, high quality, good ser

Avobenzone high purity 99%

Cas:70356-09-1

Min.Order:1 Gram

FOB Price: $10.0

Type:Manufacturers

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Jinan Finer Chemical Co., Ltd

Product description: Product name Avobenzone CAS number 70356-09-1 Assay ≥99% Appearance Yellowish to off-white powder Capacity 200mt/year Application Ultraviolet absorber fo

Avobenzone

Cas:70356-09-1

Min.Order:10 Gram

FOB Price: $12.0

Type:Lab/Research institutions

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Wuhan Fortuna Chemical Co.,Ltd

1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; ...... Appearance:Off-white to yellowish crystal powder Storage:Store at RT

Manufacturer supply Avobenzone CAS 70356-09-1 with high quality

Cas:70356-09-1

Min.Order:25 Kilogram

FOB Price: $20.0 / 30.0

Type:Trading Company

inquiry

Xi'an Quanao Biotech Co., Ltd.

We are: Focus on the research, production and sale of Plant and Animal extract, Medical intermediate, complete coverage six industries. Product grade: Medicine, Health care product, Cosmetics, Food,Feed, Biopesticide. Hot selling market: Europe,

Avobenzone CAS 70356-09-1

Cas:70356-09-1

Min.Order:1 Kilogram

FOB Price: $75.0 / 80.0

Type:Manufacturers

inquiry

Hefei TNJ chemical industry co.,ltd

Specifications Hot Selling UV Absorber Avobenzone 1. top qaulity 2. best price 3.fast delivery Appearance:White to off-white crystalline powder Storage:dry environment Package:25kg/drum or as your needs Application:Cosmetic Raw Mat

Avobenzone 70356-09-1

Cas:70356-09-1

Min.Order:25 Kilogram

Negotiable

Type:Trading Company

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Appearance:White or off white powder Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai

1-(4-tert-Butylphenyl)-3-(4-Methoxyphenyl)-1,3-propanedione

Cas:70356-09-1

Min.Order:1 Gram

Negotiable

Type:Manufacturers

inquiry

Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price Anti UV Avobenzone 70356-09-1 Manufacturer

Cas:70356-09-1

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Avobenzone

Cas:70356-09-1

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

Avobenzone Basic information Product Name: Avobenzone Synonyms: AVOBENZONE;EUSOLEX(R) 9020;4-tert-butyl-4'-methoxy-dibenzoylmethane;4-T-BUTYL-4'-METHOXY-DIBENZOYLMETHANE;1-(4-(1,

Avobenzone--

Cas:70356-09-1

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

UV Absorber Materials CAS 70356-09-1 Avobenzone

Cas:70356-09-1

Min.Order:1 Gram

FOB Price: $12.0 / 15.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Name: Butyl Methoxydibenzoylmethane CAS No.: 70356-09-1 Molecular Formula: C20H22O3 Molecular Weight: 310.39 EINEC No.: 274-581-6 Appearance:White Powder Storage:Store in cool

Butyl Methoxydibenzoylmethane CAS:70356-09-1

Cas:70356-09-1

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

New production CAS 70356-09-1 with best quality

Cas:70356-09-1

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Leader Biochemical Group

PRODUCT DETAILS Avobenzone ■POLYMER ADDITIVES BIONUTRICHEM UV1789 CHEMICAL COMPONENT COMPONENT 4-T-BUTYL-4'-METHOXY-

China Largest Manufacturer factory sales Avobenzone CAS 70356-09-1

Cas:70356-09-1

Min.Order:1 Kilogram

FOB Price: $1.0 / 2.0

Type:Lab/Research institutions

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Hubei Langyou International Trading Co., Ltd

Advantages: Hubei XinRunde Chemical Co., Ltd is a renowned pharmaceutical manufacturer. We can offer high quality products at competitive price in quick delivery with 100% custom pass guaranteed. Never stop striving to offer our best service is

Avobenzone CAS NO70356-09-1

Cas:70356-09-1

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

Hangzhou Sartort Biopharma Co., Ltd

Appearance:White to yellow powder Storage:room temperature Package:25kg/drum Application:sedative, neurosedative Transportation:Express/Sea/Air Port:any port in china

Avobenzone factory price

Cas:70356-09-1

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Avobenzone 70356-09-1

Cas:70356-09-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Xi'an Faithful Biotech Co., Ltd.

We are the manufacturers and suppliers of API in China, and warehouse in Germany and USA of California, which can quickly and safely deliver to your address 1.High quality and competitive price. 2.Free sample for your evaluation. 3.Promptly delivery

HANWAYS CHEMPHARM CO.,LIMITED

Wuhan hanweishi Pharmchem Co., Ltd(Hanways chempharm) is a specialized company concentrating on the R&D, production, marketing and technical service of APIs and pharmaceutical intermediates. The leading products range are APIs, Hormones, Peptides

Avobenzone CAS 70356-09-1

Cas:70356-09-1

Min.Order:100 Kilogram

FOB Price: $1.0 / 5.0

Type:Trading Company

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At present

Sedative drugs Avobenzone/CAS:70356-09-1

Cas:70356-09-1

Min.Order:1 Kilogram

FOB Price: $32.0 / 47.0

Type:Trading Company

inquiry

Qingdao Beluga Import and Export Co., LTD

Avobenzone CAS: 70356-09-1 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermediates

Avobenzone CAS: 70356-09-1

Cas:70356-09-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Avobenzone

Cas:70356-09-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Mojin Biotechnology Co.,Ltd

Company information: Hebei Mojin Biotechnology Co., Ltd, Our company is a professional in carbomer,carbopol,lead acetate,meglumine diphenyl ethylamine and other chemical raw materials and chemical reagents research and development production ente

Best price UV Absorber Avobenzone CAS 70356-09-1

Cas:70356-09-1

Min.Order:1 Kilogram

FOB Price: $20.0 / 30.0

Type:Trading Company

inquiry

Hubei Jiutian Bio-medical Technology Co., Ltd

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists

Avobenzone 70356-09-1

Cas:70356-09-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

methyl 4-tert-butylbenzoate
26537-19-9

methyl 4-tert-butylbenzoate

1-(4-methoxyphenyl)ethanone
100-06-1

1-(4-methoxyphenyl)ethanone

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione
70356-09-1

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione

Conditions
ConditionsYield
With potassium methanolate In toluene at 110℃; under 750.075 Torr; for 2h; Product distribution / selectivity;95%
With potassium methanolate; sodium methylate In methanol; toluene at 105 - 108℃; for 3.5h; Temperature;92.8%
With sodium amide In 5,5-dimethyl-1,3-cyclohexadiene at 95 - 100℃; for 5h; Concentration;78%
Stage #1: 1-(4-methoxyphenyl)ethanone With sodium amide In toluene at 80℃; for 0.25h; Claisen Condensation;
Stage #2: methyl 4-tert-butylbenzoate In toluene at 80℃; for 6h; Claisen Condensation;
Stage #3: With hydrogenchloride In water; toluene at 20℃; Claisen Condensation;
67%
With sodium hydride In tetrahydrofuran at 60℃; for 18h; Claisen condensation; Inert atmosphere;48%
tert-butyl 4-(tert-butyl)benzoate
92279-83-9

tert-butyl 4-(tert-butyl)benzoate

1-(4-methoxyphenyl)ethanone
100-06-1

1-(4-methoxyphenyl)ethanone

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione
70356-09-1

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione

Conditions
ConditionsYield
With potassium methanolate In toluene under 750.075 Torr; for 1.75h; Product distribution / selectivity; Heating;91%
3-((4-t-butyl)phenyl)-1-(4-methoxyphenyl)-2-propen-1-one
258497-50-6

3-((4-t-butyl)phenyl)-1-(4-methoxyphenyl)-2-propen-1-one

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione
70356-09-1

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione

Conditions
ConditionsYield
Stage #1: 3-((4-t-butyl)phenyl)-1-(4-methoxyphenyl)-2-propen-1-one With palladium(II) trifluoroacetate In toluene at 40 - 50℃; for 7h;
Stage #2: With tert.-butylhydroperoxide In toluene; tert-butyl alcohol for 1.5h;
89.1%
4-(1,1-dimethylethyl)-benzylidene-4'-methoxyacetophenone

4-(1,1-dimethylethyl)-benzylidene-4'-methoxyacetophenone

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione
70356-09-1

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione

Conditions
ConditionsYield
With hydrogenchloride; sodium methylate; chlorine In methanol; 5,5-dimethyl-1,3-cyclohexadiene85%
4-methoxybenzonitrile
874-90-8

4-methoxybenzonitrile

2-bromo-1-(4-(tert-butyl)phenyl)ethanone
30095-47-7

2-bromo-1-(4-(tert-butyl)phenyl)ethanone

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione
70356-09-1

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione

Conditions
ConditionsYield
Stage #1: 4-methoxybenzonitrile; 2-bromo-1-(4-(tert-butyl)phenyl)ethanone With chloro-trimethyl-silane; zinc In 1,4-dioxane for 6h; Blaise Reaction; Reflux; Inert atmosphere;
Stage #2: With hydrogenchloride In 1,4-dioxane; water at 100℃; for 0.5h; pH=2; Blaise Reaction; Inert atmosphere;
70%
(Z)-1-(4-tert-Butyl-phenyl)-3-hydroxy-3-(4-methoxy-phenyl)-propenone
133931-49-4

(Z)-1-(4-tert-Butyl-phenyl)-3-hydroxy-3-(4-methoxy-phenyl)-propenone

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione
70356-09-1

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione

Conditions
ConditionsYield
In [D3]acetonitrile Product distribution; Irradiation; determination by NMR;
In hexane at 25℃; Kinetics; Equilibrium constant;
In hexane for 3h; Quantum yield; UV-irradiation;
1-(4-methoxyphenyl)-vinyl 4-tert-butylbenzoate

1-(4-methoxyphenyl)-vinyl 4-tert-butylbenzoate

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione
70356-09-1

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione

Conditions
ConditionsYield
In methanol at 35℃; for 0.166667h; Product distribution / selectivity; UVB irradiation;
1-(4-tert-butylphenyl)-vinyl 4-methoxybenzoate

1-(4-tert-butylphenyl)-vinyl 4-methoxybenzoate

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione
70356-09-1

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione

Conditions
ConditionsYield
In methanol at 35℃; for 0.166667h; Product distribution / selectivity; UVB irradiation;
1,1-(4-tert-butyl-benzoyl)(4'-methoxybenzoyl)butane
1262100-39-9

1,1-(4-tert-butyl-benzoyl)(4'-methoxybenzoyl)butane

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione
70356-09-1

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione

Conditions
ConditionsYield
In acetonitrile at 21.84℃; Activation energy; Kinetics; Quantum yield; Mechanism; Reagent/catalyst; Temperature; Norrish type II reaction; UV-irradiation;
3-(4-tert-butylphenyl)-3-hydroxy-1-(4-methoxyphenyl)-propan-1-one
955359-34-9

3-(4-tert-butylphenyl)-3-hydroxy-1-(4-methoxyphenyl)-propan-1-one

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione
70356-09-1

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione

Conditions
ConditionsYield
UV-irradiation;
difluoroboron avobenzone
175086-57-4

difluoroboron avobenzone

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione
70356-09-1

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione

Conditions
ConditionsYield
at 22.84℃; Kinetics; Temperature;
With water In dimethyl sulfoxide Kinetics;
C20H22O3

C20H22O3

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione
70356-09-1

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione

Conditions
ConditionsYield
In dimethyl sulfoxide for 2h; Irradiation;
toluene
108-88-3

toluene

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione
70356-09-1

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: aluminum (III) chloride / 1.42 h / 23.5 °C
2: potassium permanganate / 8.5 h / 85 °C
3: methanesulfonic acid / 8 h / Reflux
4: sodium amide / 5,5-dimethyl-1,3-cyclohexadiene / 5 h / 95 - 100 °C
View Scheme
4-tert-butyltoluene
98-51-1

4-tert-butyltoluene

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione
70356-09-1

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: potassium permanganate / 8.5 h / 85 °C
2: methanesulfonic acid / 8 h / Reflux
3: sodium amide / 5,5-dimethyl-1,3-cyclohexadiene / 5 h / 95 - 100 °C
View Scheme
4-(1,1-dimethylethyl)benzoic acid
98-73-7

4-(1,1-dimethylethyl)benzoic acid

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione
70356-09-1

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: methanesulfonic acid / 8 h / Reflux
2: sodium amide / 5,5-dimethyl-1,3-cyclohexadiene / 5 h / 95 - 100 °C
View Scheme
4'-t-butylacetophenone
943-27-1

4'-t-butylacetophenone

methyl 4-methoxybenzoate
121-98-2

methyl 4-methoxybenzoate

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione
70356-09-1

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione

Conditions
ConditionsYield
Stage #1: 4'-t-butylacetophenone With sodium amide In tetrahydrofuran at 20℃; for 1h;
Stage #2: methyl 4-methoxybenzoate In tetrahydrofuran at 50 - 60℃; for 2h;
4'-t-butylacetophenone
943-27-1

4'-t-butylacetophenone

ethyl 4-methoxybenzoate
94-30-4

ethyl 4-methoxybenzoate

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione
70356-09-1

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione

Conditions
ConditionsYield
With sodium hydride In tetrahydrofuran for 4.5h; Reflux;
1-phenyl-propan-1-one
93-55-0

1-phenyl-propan-1-one

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione
70356-09-1

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione

2-(4-(tert-butyl)benzoyl)-1-(4-methoxyphenyl)-5-phenylpentane-1,5-dione

2-(4-(tert-butyl)benzoyl)-1-(4-methoxyphenyl)-5-phenylpentane-1,5-dione

Conditions
ConditionsYield
With [2,2]bipyridinyl; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; copper diacetate In 1,2-dichloro-benzene at 120℃; for 24h; Inert atmosphere; Schlenk technique;97%
1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione
70356-09-1

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione

2-bromo-1-(4-tert-butyl-phenyl)-3-(4-methoxy-phenyl)-propane-1,3-dione

2-bromo-1-(4-tert-butyl-phenyl)-3-(4-methoxy-phenyl)-propane-1,3-dione

Conditions
ConditionsYield
With N-Bromosuccinimide In dimethyl sulfoxide at 20 - 65℃;95%
With N-Bromosuccinimide; Dithioglycoluril In methanol at 20℃; for 0.0833333h;80%
With N-Bromosuccinimide In neat (no solvent) for 0.833333h;76%
1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione
70356-09-1

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione

4-tert-butylbenzoyl-4′-methoxybenzoylchloromethane

4-tert-butylbenzoyl-4′-methoxybenzoylchloromethane

Conditions
ConditionsYield
With N-chloro-succinimide In dimethyl sulfoxide at 20℃; for 0.666667h;92%
1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione
70356-09-1

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione

C20H21O3I

C20H21O3I

Conditions
ConditionsYield
With N-iodo-succinimide In dimethyl sulfoxide at 20℃; for 2h;90%
1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione
70356-09-1

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione

1-(4-(tert-butyl)phenyl)-3-(4-hydroxyphenyl)propane-1,3-dione
132944-34-4

1-(4-(tert-butyl)phenyl)-3-(4-hydroxyphenyl)propane-1,3-dione

Conditions
ConditionsYield
With boron tribromide In dichloromethane at -78 - 20℃;89%
With hydrogen bromide; acetic acid In water for 16h; Inert atmosphere; Reflux;62.9%
With Hexanethiol; potassium tert-butylate In N,N-dimethyl-formamide at 5 - 110℃;
bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]
12354-84-6, 12354-85-7

bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione
70356-09-1

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione

C30H36ClIrO3

C30H36ClIrO3

Conditions
ConditionsYield
Stage #1: 1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione With potassium hydroxide In methanol at 20℃; for 1h;
Stage #2: bis[dichloro(pentamethylcyclopentadienyl)iridium(III)] In methanol at 20℃; for 24h;
89%
Stage #1: 1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione With potassium hydroxide In methanol at 20℃; for 1h;
Stage #2: bis[dichloro(pentamethylcyclopentadienyl)iridium(III)] In methanol at 20℃; for 24h;
76%
dimethyl 2-(4-methoxyphenyl)cyclopropane-1,1-dicarboxylate
75073-97-1

dimethyl 2-(4-methoxyphenyl)cyclopropane-1,1-dicarboxylate

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione
70356-09-1

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione

dimethyl 2-(3-(4-(tert-butyl)benzoyl)-2,4-bis(4-methoxyphenyl)-4-oxobutyl)malonate

dimethyl 2-(3-(4-(tert-butyl)benzoyl)-2,4-bis(4-methoxyphenyl)-4-oxobutyl)malonate

Conditions
ConditionsYield
With scandium tris(trifluoromethanesulfonate) In dichloromethane at 25℃; for 24h;89%
dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer

dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione
70356-09-1

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione

C30H36ClO3Rh

C30H36ClO3Rh

Conditions
ConditionsYield
Stage #1: 1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione With potassium hydroxide In methanol at 20℃; for 1h;
Stage #2: dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer In methanol at 20℃; for 24h;
86%
trifluoromethylsulfinyl chloride
20621-29-8

trifluoromethylsulfinyl chloride

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione
70356-09-1

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione

1-(4-(tert-butyl)phenyl)-2-chloro-3-(4-methoxyphenyl)-2-((trifluoromethyl)thio)propane-1,3-dione

1-(4-(tert-butyl)phenyl)-2-chloro-3-(4-methoxyphenyl)-2-((trifluoromethyl)thio)propane-1,3-dione

Conditions
ConditionsYield
With pyridine In dichloromethane at 20℃; for 0.183333h; Inert atmosphere;84%
C52H33Cl2Ir2N4S4

C52H33Cl2Ir2N4S4

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione
70356-09-1

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione

C46H37IrN2O3S2

C46H37IrN2O3S2

Conditions
ConditionsYield
With sodium carbonate In 2-ethoxy-ethanol for 24h; Reflux;81%
potassium hexafluorophosphate
17084-13-8

potassium hexafluorophosphate

bis(2,2'-bipyridine)dichlororuthenium(II) dihydrate

bis(2,2'-bipyridine)dichlororuthenium(II) dihydrate

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione
70356-09-1

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione

[Ru(2,2′-bipyridyl)2((1-(4-tert-butylphenyl)-3-(4-methoxyphenyl)propane-1,3-dione)(1-))]PF6

[Ru(2,2′-bipyridyl)2((1-(4-tert-butylphenyl)-3-(4-methoxyphenyl)propane-1,3-dione)(1-))]PF6

Conditions
ConditionsYield
Stage #1: bis(2,2'-bipyridine)dichlororuthenium(II) dihydrate; 1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione With triethylamine In ethanol; water at 100℃; for 2h; Sealed tube; Inert atmosphere;
Stage #2: potassium hexafluorophosphate In ethanol; water
81%
[ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2
52462-29-0

[ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione
70356-09-1

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione

[(cymene)Ru(1-(4-tert-butylphenyl)-3-(4-methoxyphenyl)propane-1,3-dione)Cl]

[(cymene)Ru(1-(4-tert-butylphenyl)-3-(4-methoxyphenyl)propane-1,3-dione)Cl]

Conditions
ConditionsYield
Stage #1: 1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione With potassium hydroxide In methanol at 20℃; for 1h;
Stage #2: [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2 In methanol at 20℃; for 20h;
80%
Stage #1: 1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione With potassium hydroxide In methanol at 20℃; for 1h;
Stage #2: [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2 In methanol at 20℃; for 24h;
79%
[(hexamethylbenzene)RuCl2]2

[(hexamethylbenzene)RuCl2]2

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione
70356-09-1

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione

[(hexamethylbenzene)Ru(1-(4-tert-butylphenyl)-3-(4-methoxyphenyl)propane-1,3-dione)Cl]

[(hexamethylbenzene)Ru(1-(4-tert-butylphenyl)-3-(4-methoxyphenyl)propane-1,3-dione)Cl]

Conditions
ConditionsYield
Stage #1: 1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione With potassium hydroxide In methanol at 20℃; for 1h;
Stage #2: [(hexamethylbenzene)RuCl2]2 In methanol at 20℃; for 20h;
74%
p-Chlorothiophenol
106-54-7

p-Chlorothiophenol

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione
70356-09-1

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione

C26H25ClO3S

C26H25ClO3S

Conditions
ConditionsYield
With rose bengal; sodium iodide In acetonitrile at 20℃; for 48h; Irradiation;74%
1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione
70356-09-1

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione

3-(4-tert-butylphenyl)-5-(4-methoxyphenyl)-1H-pyrazole
1393380-37-4

3-(4-tert-butylphenyl)-5-(4-methoxyphenyl)-1H-pyrazole

Conditions
ConditionsYield
With hydrazine hydrate In ethanol for 3h; Reflux;72%
[iridium(III)(μ-chloro)(2-phenylpyridine)2]2

[iridium(III)(μ-chloro)(2-phenylpyridine)2]2

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione
70356-09-1

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione

C42H37IrN2O3

C42H37IrN2O3

Conditions
ConditionsYield
With sodium carbonate In 2-ethoxy-ethanol for 24h; Reflux;69%
bis[2-(2,4-difluorophenyl)pyridinato-N,C6']iridium(III) chloride dimer

bis[2-(2,4-difluorophenyl)pyridinato-N,C6']iridium(III) chloride dimer

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione
70356-09-1

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione

C42H33F4IrN2O3

C42H33F4IrN2O3

Conditions
ConditionsYield
With sodium carbonate In 2-ethoxy-ethanol for 24h; Reflux;69%
acetone
67-64-1

acetone

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione
70356-09-1

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione

2-(4-(tert-butyl)benzoyl)-1-(4-methoxyphenyl)pentane-1,4-dione

2-(4-(tert-butyl)benzoyl)-1-(4-methoxyphenyl)pentane-1,4-dione

Conditions
ConditionsYield
With tert.-butylhydroperoxide; tetra-(n-butyl)ammonium iodide In water at 50℃; for 2h; Schlenk technique; Green chemistry;68%
1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione
70356-09-1

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione

methyl iodide
74-88-4

methyl iodide

1-(4-tert-butylphenyl)-3-(4-methoxyphenyl)-2-methylpropane-1,3-dione

1-(4-tert-butylphenyl)-3-(4-methoxyphenyl)-2-methylpropane-1,3-dione

Conditions
ConditionsYield
With potassium carbonate In acetone at 40 - 50℃; Inert atmosphere;67%
potassium hexafluorophosphate
17084-13-8

potassium hexafluorophosphate

[Ru(4,7-diphenyl-1,10-phenanthroline)2Cl2]

[Ru(4,7-diphenyl-1,10-phenanthroline)2Cl2]

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione
70356-09-1

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione

[Ru(4,7-diphenyl-1,10-phenanthroline)2((1-(4-tert-butylphenyl)-3-(4-methoxyphenyl)propane-1,3-dione)(1-))]PF6

[Ru(4,7-diphenyl-1,10-phenanthroline)2((1-(4-tert-butylphenyl)-3-(4-methoxyphenyl)propane-1,3-dione)(1-))]PF6

Conditions
ConditionsYield
Stage #1: [Ru(4,7-diphenyl-1,10-phenanthroline)2Cl2]; 1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione With triethylamine In ethanol; water at 100℃; for 2h; Sealed tube; Inert atmosphere;
Stage #2: potassium hexafluorophosphate In ethanol; water
65%
propargyl bromide
106-96-7

propargyl bromide

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione
70356-09-1

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione

(+/-)-1-(4-methoxyphenyl)-2-propargyl-3-[(4-tert-butyl)phenyl]-1,3-propanedione

(+/-)-1-(4-methoxyphenyl)-2-propargyl-3-[(4-tert-butyl)phenyl]-1,3-propanedione

Conditions
ConditionsYield
Stage #1: 1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione With potassium carbonate In acetone at 20℃; for 0.5h;
Stage #2: propargyl bromide In acetone at 20℃;
61%
1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione
70356-09-1

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione

difluoroboron avobenzone
175086-57-4

difluoroboron avobenzone

Conditions
ConditionsYield
With boron trifluoride diethyl etherate In dichloromethane at 60℃; for 1h; Inert atmosphere;59%
2,2,2,-trichloroethoxycarbonyl azide

2,2,2,-trichloroethoxycarbonyl azide

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione
70356-09-1

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione

2,2,2-trichloroethyl {1-[4-(tert-butyl)phenyl]-3-(4-methoxyphenyl)-1,3-dioxopropan-2-yl}carbamate

2,2,2-trichloroethyl {1-[4-(tert-butyl)phenyl]-3-(4-methoxyphenyl)-1,3-dioxopropan-2-yl}carbamate

Conditions
ConditionsYield
Stage #1: 1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione With α,α,α-trifluorotoluene; C20H21Cl3IrNO; zinc trifluoromethanesulfonate; sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate at 20℃; for 0.0833333h; Inert atmosphere; Glovebox;
Stage #2: 2,2,2,-trichloroethoxycarbonyl azide at 10℃; for 24h; Inert atmosphere; Sealed tube; chemoselective reaction;
59%
ethyl acrylate
140-88-5

ethyl acrylate

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione
70356-09-1

1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione

A

ethyl 5-(4-methoxyphenyl)-5-oxopentanoate
25305-58-2

ethyl 5-(4-methoxyphenyl)-5-oxopentanoate

B

ethyl 5-(4-(tert-butyl)phenyl)-5-oxopentanoate
101577-33-7

ethyl 5-(4-(tert-butyl)phenyl)-5-oxopentanoate

Conditions
ConditionsYield
With potassium carbonate In ethanol at 85℃; Sealed tube;A 57%
B 40%
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