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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply (-)-3,7-dimethyloct-6-en-1-ol

Cas:7540-51-4

Min.Order:1

Negotiable

Type:Other

inquiry

Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Natural Extract 98% BETA-RHODINOL 7540-51-4 HACCP Manufacturer

Cas:7540-51-4

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

inquiry

Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem’s R&D center offer custom synthesis according to the contract research and development services for the fine c

High purity (-)-beta-Citronellol 98% TOP1 supplier in China

Cas:7540-51-4

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

L-Citronellol

Cas:7540-51-4

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

BETA-RHODINOL

Cas:7540-51-4

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

New production CAS 7540-51-4 with best quality

Cas:7540-51-4

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

High purity B-Rhodinol CAS NO.:7540-51-4 CAS NO.7540-51-4

Cas:7540-51-4

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages ♦ High purity, all above 98.5%, no impurities after dissolution ♦ We will test each batch to ensure quality ♦ OEM and private brand services designed for free ♦ Various cap colors available ♦ W

BETA-RHODINOL CAS7540-51-4

Cas:7540-51-4

Min.Order:1 Kilogram

FOB Price: $289.0 / 499.0

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

(-)-beta-Citronellol 7540-51-4

Cas:7540-51-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Changchun Artel lmport and Export trade company

Price, service, company and transport advantage: 1.place of origin china with super quality by reasonable price. 2. it's customers' right to choose the package (ems, dhl, fedex, ups); 3. it's customers' right to

BEST PRICE/High purity B-Rhodinol CAS NO.7540-51-4

Cas:7540-51-4

Min.Order:100 Gram

Negotiable

Type:Trading Company

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

(-)-β-Citronellol

Cas:7540-51-4

Min.Order:1 Kilogram

FOB Price: $24.0 / 30.0

Type:Trading Company

inquiry

Qingdao Beluga Import and Export Co., LTD

BETA-RHODINOL CAS:7540-51-4 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermediate

BETA-RHODINOL CAS:7540-51-4

Cas:7540-51-4

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

(-)-beta-Citronellol

Cas:7540-51-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:7540-51-4

Cas:7540-51-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

(s)-(-)-b-Citronellol

Cas:7540-51-4

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Triumph International Development Limilted

Appearance:off-white to white solid Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Used for Synthesis API and Research Transportation:As customer request Port:Qingda

BETA-RHODINOL 7540-51-4

Cas:7540-51-4

Min.Order:1 Kilogram

FOB Price: $10.0

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High purity (-)-beta-Citronellol

Cas:7540-51-4

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

High purity B-Rhodinol CAS NO.:7540-51-4 CAS NO.7540-51-4

Cas:7540-51-4

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

High purity B-Rhodinol CAS NO.:7540-51-4 CAS NO.7540-51-4

Cas:7540-51-4

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

High purity B-Rhodinol CAS NO.:7540-51-4 CAS NO.7540-51-4

Cas:7540-51-4

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

BEST PRICE/High purity B-Rhodinol CAS NO.7540-51-4 CAS NO.7540-51-4

Cas:7540-51-4

Min.Order:1 Metric Ton

FOB Price: $7.0 / 8.0

Type:Trading Company

inquiry

Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

(-)-beta-Citronellol

Cas:7540-51-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

High purity B-Rhodinol CAS NO.:7540-51-4 CAS NO.7540-51-4

Cas:7540-51-4

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

Hebei Mojin Biotechnology Co.,Ltd

We produce carbomer by our own factory,carbomer 940 is our best seller.It is used for cosmetic and medical.And we also become agent for lubrizol.Our carbomer 940 get high viscosity and good transparency.The price will depond on the market,surely supp

6-Octen-1-ol,3,7-dimethyl-, (3S)-

Cas:7540-51-4

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Henan Tianfu Chemical Co., Ltd.

Our advantage:Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientif

TIANFU-CHEM BETA-RHODINOL

Cas:7540-51-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

(-)-beta-Citronellol

Cas:7540-51-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stock Package:1kg Application:pharmaceutical intermediates

6-Octen-1-ol,3,7-dimethyl-, (3S)-

Cas:7540-51-4

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec S-(-)-β-Citronellol 100ml

Cas:7540-51-4

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

(-)-Citronellol

Cas:7540-51-4

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

(S)-(-)-B-Citronellol

Cas:7540-51-4

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Synthetic route

Geraniol
106-24-1

Geraniol

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

Conditions
ConditionsYield
With bis(norbornadiene)rhodium(l)tetrafluoroborate; (RC,SFc,SP)-1-[2-(1-N,N-dimethylaminoethyl)ferrocen-1-yl]phenylphosphino-1'-dicyclohexylphosphinoferrocene; hydrogen In dichloromethane at 20℃; under 19001.3 Torr; for 20h; Inert atmosphere; Autoclave; enantioselective reaction;99%
With [RuCl(p-cymene)((R)-Tol-BINAP)]Cl; potassium hydroxide In isopropyl alcohol for 2h; Inert atmosphere; Reflux;70%
Multi-step reaction with 2 steps
1: in Ficus retusa Linn.
2: in Ficus retusa Linn. nach Injektion
View Scheme
3,7-dimethyl-2,6-octadienal
141-27-5

3,7-dimethyl-2,6-octadienal

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

Conditions
ConditionsYield
With dichloro(1,5-cyclooctadiene)ruthenium(II); (R)-(+)-2,2',6,6'-tetramethoxy-4,4'-bis(diphenylphosphino)-3,3'-bipyridine; niobium pentachloride; HSiPh3 In toluene at 40℃; for 3h; Catalytic behavior; Reagent/catalyst; Solvent; Temperature; Glovebox; Sealed tube; Inert atmosphere; enantioselective reaction;98.59%
With (η4-cyclooctadiene)((R)-2,2'-bis(diphenylphosphanyl)-1,1'-binaphthyl)rhodium(I) tetrfluoroborate; hydrogen In methanol at 60℃; under 33753.4 Torr; for 5h; Autoclave; enantioselective reaction;88%
Carbonic acid (S)-3,7-dimethyl-oct-6-enyl ester 2,2,2-trichloro-ethyl ester

Carbonic acid (S)-3,7-dimethyl-oct-6-enyl ester 2,2,2-trichloro-ethyl ester

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

Conditions
ConditionsYield
With indium; water; ammonium chloride In methanol for 1h; Heating;98%
(S)-Citronellal
5949-05-3

(S)-Citronellal

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

Conditions
ConditionsYield
With lithium aluminium tetrahydride In diethyl ether96%
With lithium aluminium tetrahydride In diethyl ether94%
With sodium tetrahydroborate In ethanol at 0℃;93%
Trichloro-acetic acid (S)-3,7-dimethyl-oct-6-enyl ester

Trichloro-acetic acid (S)-3,7-dimethyl-oct-6-enyl ester

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

Conditions
ConditionsYield
With indium; water; ammonium chloride In methanol for 0.5h; Heating;95%
(R)-2-(3,7-dimethyloct-6-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

(R)-2-(3,7-dimethyloct-6-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

Conditions
ConditionsYield
With sodium perborate; water In tetrahydrofuran at 20℃; for 4h; enantioselective reaction;95%
2,2-dimethyl-propionic acid (3S)-3,7-dimethyl-oct-6-enyl ester
93041-00-0

2,2-dimethyl-propionic acid (3S)-3,7-dimethyl-oct-6-enyl ester

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

Conditions
ConditionsYield
With sodium hydroxide In methanol Ambient temperature;94%
(S)-8-(allyloxy)-2,6-dimethyloct-2-ene

(S)-8-(allyloxy)-2,6-dimethyloct-2-ene

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

Conditions
ConditionsYield
Stage #1: (S)-8-(allyloxy)-2,6-dimethyloct-2-ene With C12H37NiP4(1+)*C2F6NO4S2(1-) In tetrahydrofuran at 20℃; for 0.5h; Glovebox; Schlenk technique; Inert atmosphere;
Stage #2: With toluene-4-sulfonic acid In tetrahydrofuran for 1.5h; Glovebox; Schlenk technique; Reflux; Inert atmosphere;
94%
(S)-3,7-Dimethyl-oct-6-enoic acid (1S,2R,3S,4R)-3-(2,2-dimethyl-propoxy)-4,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl ester
89156-40-1

(S)-3,7-Dimethyl-oct-6-enoic acid (1S,2R,3S,4R)-3-(2,2-dimethyl-propoxy)-4,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl ester

A

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

B

(1R,2S,3R,4S)-2-(2,2-dimethylpropoxy)-1,7,7-trimethylbicyclo<2.2.1>heptan-3-ol
85695-96-1

(1R,2S,3R,4S)-2-(2,2-dimethylpropoxy)-1,7,7-trimethylbicyclo<2.2.1>heptan-3-ol

Conditions
ConditionsYield
With lithium aluminium tetrahydrideA 88%
B 81%
(S)-((3,7-dimethyloct-6-enyloxy)methyl)benzene
84237-05-8

(S)-((3,7-dimethyloct-6-enyloxy)methyl)benzene

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

Conditions
ConditionsYield
With ammonia; lithium In tetrahydrofuran at -30℃; for 0.666667h;82%
(S)-8-(2,3-dimethyl-but-2-en-1-yloxy)-2,6-dimethyloct-2-ene

(S)-8-(2,3-dimethyl-but-2-en-1-yloxy)-2,6-dimethyloct-2-ene

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

Conditions
ConditionsYield
With (PhSO2)2; water In dichloromethane at 80℃;82%
(S)-Citronellal
5949-05-3

(S)-Citronellal

A

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

B

(S)-(-)-citronellic acid
2111-53-7

(S)-(-)-citronellic acid

Conditions
ConditionsYield
With Fusarium concentricum In dimethyl sulfoxide at 28 - 30℃; for 120h; Reagent/catalyst; Microbiological reaction;A 76%
B 5%
With Fusarium fujikuroi In dimethyl sulfoxide at 28 - 30℃; for 120h; Microbiological reaction;A 36%
B 43%
With endosperms of Triticum aestivum L. cv Dariel wheat seeds In water at 27℃; Reagent/catalyst; Concentration; Darkness; Enzymatic reaction; enantioselective reaction;
Nerol
106-25-2

Nerol

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

Conditions
ConditionsYield
With 1,1′-binaphthalene-2,2′-diylbis[bis(4-methylphenyl)phosphine]; potassium hydroxide at 100℃; for 2h; Inert atmosphere; optical yield given as %ee; enantioselective reaction;70%
With hydrogen; BINAP-Ru(II) dicarboxylate In methanol at 18 - 20℃; Yield given;
With hydrogen; BINAP-(Ru(II) dicarboxylate In methanol at 18 - 20℃; Product distribution; examination of enantioselectivity; various complexes;
(S)-(-)-citronellic acid
2111-53-7

(S)-(-)-citronellic acid

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

Conditions
ConditionsYield
With lithium aluminium tetrahydride In tetrahydrofuran at 0 - 25℃; for 3h; Inert atmosphere;69%
(S)-Citronellal
5949-05-3

(S)-Citronellal

A

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

B

(1S,3R,4S)-p-menthane-3,8-diol
19956-48-0

(1S,3R,4S)-p-menthane-3,8-diol

D

(−)-neo-isopulegol
122517-60-6

(−)-neo-isopulegol

E

(+)-isopulegol

(+)-isopulegol

Conditions
ConditionsYield
With Penicillium paxilli In dimethyl sulfoxide at 28 - 30℃; for 120h; Microbiological reaction;A 10%
B 50%
C 20%
D 5%
E 2%
(S)-citronellyl propionate

(S)-citronellyl propionate

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

Conditions
ConditionsYield
With potassium chloride; water In acetone48%
3,7-dimethyl-oct-6-enal
106-23-0, 26489-02-1

3,7-dimethyl-oct-6-enal

A

(R)-Citronellal
2385-77-5

(R)-Citronellal

B

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

Conditions
ConditionsYield
With baker's yeastA 21%
B 33%
(S)-(-)-3,7-dimethyl-6-ocyten-1-yl diphenylmethylsilyl ether

(S)-(-)-3,7-dimethyl-6-ocyten-1-yl diphenylmethylsilyl ether

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

Conditions
ConditionsYield
With potassium (4-methylphenyl)trifluoroborate In dimethyl sulfoxide at 37℃; for 24h; Inert atmosphere;18%
ethanol
64-17-5

ethanol

(S)-Citronellal
5949-05-3

(S)-Citronellal

EtOMgCl

EtOMgCl

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

(E/Z)-3,7-dimethyl-2,6-octadienal
5392-40-5

(E/Z)-3,7-dimethyl-2,6-octadienal

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

Conditions
ConditionsYield
in Ficus retusa Linn. nach Injektion;
Nerol
106-25-2

Nerol

A

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

B

(3R)-citronellol
1117-61-9

(3R)-citronellol

Conditions
ConditionsYield
With hydrogen; <(+)-CyBINAP>-RhN In benzene under 15200 Torr; Ambient temperature; Yield given. Yields of byproduct given;
With hydrogen; ClO4 In benzene under 7600 Torr; for 8h; Ambient temperature; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
With hydrogen; Ru2Cl4-((S)-2,2'-bis[di(p-tolyl)phosphino]-1,1'-binaphthyl)2NEt3 In methanol at 19.9℃; under 1807.6 Torr; Product distribution; different pressure and temperature;
With 1,2-bis(2,5-diisopropylphospholano)benzene; potassium hydroxide at 100℃; for 24h; Inert atmosphere; optical yield given as %ee; enantioselective reaction;
Geraniol
106-24-1

Geraniol

A

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

B

(3R)-citronellol
1117-61-9

(3R)-citronellol

C

(R)-3,7-dimethyloctan-1-ol
1117-60-8

(R)-3,7-dimethyloctan-1-ol

Conditions
ConditionsYield
With hydrogen; {RuI((R)-2,2'-bis(diphenylphospino)-1,1'-binaphthyl)(p-cymene)}I In methanol; water at 20℃; under 76000 Torr; for 8h; Yield given. Yields of byproduct given;
Geraniol
106-24-1

Geraniol

A

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

B

(3R)-citronellol
1117-61-9

(3R)-citronellol

Conditions
ConditionsYield
With <<(-)-2,2'-bis(diphenylphosphino)-4,4',6,6'-tetramethyl-3,3'-bibenzothiophene>Ru(p-cumene)I>I; hydrogen In methanol at 25℃; under 7355.08 Torr; for 88h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
With ((S)-(6,6'-dimethylbiphenyl-2,2'-diyl)bis(diphenylphosphine))Ru(O2CCF3)2; hydrogen In methanol at 20 - 25℃; under 45003.6 Torr; for 1h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
With hydrogen; <(+)-BINAP>RhN In benzene under 22800 Torr; Ambient temperature; Yield given. Yields of byproduct given;
(R)-1-[(R)-3-(1-Hydroxy-1-methyl-ethyl)-pyrrolidin-1-yl]-3,7-dimethyl-oct-6-en-1-one

(R)-1-[(R)-3-(1-Hydroxy-1-methyl-ethyl)-pyrrolidin-1-yl]-3,7-dimethyl-oct-6-en-1-one

A

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

B

(3R)-citronellol
1117-61-9

(3R)-citronellol

Conditions
ConditionsYield
With lithium triethylborohydride In tetrahydrofuran Ambient temperature; Yield given;
With lithium triethylborohydride In tetrahydrofuran Ambient temperature; Yields of byproduct given;
N,N-diethyl-N-{1-[(3S),7-dimethylocta-1,6-dienyl]}amine
67392-54-5

N,N-diethyl-N-{1-[(3S),7-dimethylocta-1,6-dienyl]}amine

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

Conditions
ConditionsYield
With oxonium; hydrogen
(S)-(+)-dihydromyrcene
2436-90-0

(S)-(+)-dihydromyrcene

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

Conditions
ConditionsYield
With sodium hydroxide; sodium tetrahydroborate; 2-methyl-but-2-ene; boron trifluoride; dihydrogen peroxide 1.) THF, room temp., 3 h.; 2.) 50 deg C, 1.5 h; Multistep reaction;
γ-geraniol
13066-51-8

γ-geraniol

A

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

B

(3R)-citronellol
1117-61-9

(3R)-citronellol

Conditions
ConditionsYield
With Ru2Cl4-((S)-2,2'-bis[di(p-tolyl)phosphino]-1,1'-binaphthyl)2NEt3; hydrogen In methanol at 19.9℃; under 3750.3 Torr; Title compound not separated from byproducts;
With hydrogen; Ru2Cl4-((S)-2,2'-bis[di(p-tolyl)phosphino]-1,1'-binaphthyl)2NEt3 In methanol at 19.9℃; under 1807.6 Torr; Product distribution; other pressure and temperature;
With 1,1′-binaphthalene-2,2′-diylbis[bis(4-methylphenyl)phosphine]; potassium hydroxide at 100℃; for 6h; Inert atmosphere; optical yield given as %ee; enantioselective reaction;
(3S)-3,7-dimethyl-6-octen-1-yl acetate
67601-05-2

(3S)-3,7-dimethyl-6-octen-1-yl acetate

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

Conditions
ConditionsYield
Stage #1: (3S)-3,7-dimethyl-6-octen-1-yl acetate With sodium hydroxide In ethanol at 90℃; for 3h; Alkaline hydrolysis;
Stage #2: With Pichia kluyveri IFO 1165 at 30℃; for 48h;
vinyl acetate
108-05-4

vinyl acetate

Citronellol
106-22-9

Citronellol

A

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

B

(3R)-citronellol
1117-61-9

(3R)-citronellol

C

(R)-1-citronellyl acetate
20425-54-1

(R)-1-citronellyl acetate

D

(3S)-3,7-dimethyl-6-octen-1-yl acetate
67601-05-2

(3S)-3,7-dimethyl-6-octen-1-yl acetate

Conditions
ConditionsYield
With porcine pancreatic lipase In hexane for 24h; Title compound not separated from byproducts;
With porcine pancreatic lipase In hexane for 48h; Title compound not separated from byproducts;
Geraniol
106-24-1

Geraniol

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

Conditions
ConditionsYield
With bis(norbornadiene)rhodium(l)tetrafluoroborate; (RC,SFc,SP)-1-[2-(1-N,N-dimethylaminoethyl)ferrocen-1-yl]phenylphosphino-1'-dicyclohexylphosphinoferrocene; hydrogen In dichloromethane at 20℃; under 19001.3 Torr; for 20h; Inert atmosphere; Autoclave; enantioselective reaction;99%
With [RuCl(p-cymene)((R)-Tol-BINAP)]Cl; potassium hydroxide In isopropyl alcohol for 2h; Inert atmosphere; Reflux;70%
Multi-step reaction with 2 steps
1: in Ficus retusa Linn.
2: in Ficus retusa Linn. nach Injektion
View Scheme
3,7-dimethyl-2,6-octadienal
141-27-5

3,7-dimethyl-2,6-octadienal

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

Conditions
ConditionsYield
With dichloro(1,5-cyclooctadiene)ruthenium(II); (R)-(+)-2,2',6,6'-tetramethoxy-4,4'-bis(diphenylphosphino)-3,3'-bipyridine; niobium pentachloride; HSiPh3 In toluene at 40℃; for 3h; Catalytic behavior; Reagent/catalyst; Solvent; Temperature; Glovebox; Sealed tube; Inert atmosphere; enantioselective reaction;98.59%
With (η4-cyclooctadiene)((R)-2,2'-bis(diphenylphosphanyl)-1,1'-binaphthyl)rhodium(I) tetrfluoroborate; hydrogen In methanol at 60℃; under 33753.4 Torr; for 5h; Autoclave; enantioselective reaction;88%
Carbonic acid (S)-3,7-dimethyl-oct-6-enyl ester 2,2,2-trichloro-ethyl ester

Carbonic acid (S)-3,7-dimethyl-oct-6-enyl ester 2,2,2-trichloro-ethyl ester

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

Conditions
ConditionsYield
With indium; water; ammonium chloride In methanol for 1h; Heating;98%
(S)-Citronellal
5949-05-3

(S)-Citronellal

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

Conditions
ConditionsYield
With lithium aluminium tetrahydride In diethyl ether96%
With lithium aluminium tetrahydride In diethyl ether94%
With sodium tetrahydroborate In ethanol at 0℃;93%
Trichloro-acetic acid (S)-3,7-dimethyl-oct-6-enyl ester

Trichloro-acetic acid (S)-3,7-dimethyl-oct-6-enyl ester

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

Conditions
ConditionsYield
With indium; water; ammonium chloride In methanol for 0.5h; Heating;95%
(R)-2-(3,7-dimethyloct-6-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

(R)-2-(3,7-dimethyloct-6-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

Conditions
ConditionsYield
With sodium perborate; water In tetrahydrofuran at 20℃; for 4h; enantioselective reaction;95%
2,2-dimethyl-propionic acid (3S)-3,7-dimethyl-oct-6-enyl ester
93041-00-0

2,2-dimethyl-propionic acid (3S)-3,7-dimethyl-oct-6-enyl ester

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

Conditions
ConditionsYield
With sodium hydroxide In methanol Ambient temperature;94%
(S)-8-(allyloxy)-2,6-dimethyloct-2-ene

(S)-8-(allyloxy)-2,6-dimethyloct-2-ene

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

Conditions
ConditionsYield
Stage #1: (S)-8-(allyloxy)-2,6-dimethyloct-2-ene With C12H37NiP4(1+)*C2F6NO4S2(1-) In tetrahydrofuran at 20℃; for 0.5h; Glovebox; Schlenk technique; Inert atmosphere;
Stage #2: With toluene-4-sulfonic acid In tetrahydrofuran for 1.5h; Glovebox; Schlenk technique; Reflux; Inert atmosphere;
94%
(S)-3,7-Dimethyl-oct-6-enoic acid (1S,2R,3S,4R)-3-(2,2-dimethyl-propoxy)-4,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl ester
89156-40-1

(S)-3,7-Dimethyl-oct-6-enoic acid (1S,2R,3S,4R)-3-(2,2-dimethyl-propoxy)-4,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl ester

A

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

B

(1R,2S,3R,4S)-2-(2,2-dimethylpropoxy)-1,7,7-trimethylbicyclo<2.2.1>heptan-3-ol
85695-96-1

(1R,2S,3R,4S)-2-(2,2-dimethylpropoxy)-1,7,7-trimethylbicyclo<2.2.1>heptan-3-ol

Conditions
ConditionsYield
With lithium aluminium tetrahydrideA 88%
B 81%
(S)-((3,7-dimethyloct-6-enyloxy)methyl)benzene
84237-05-8

(S)-((3,7-dimethyloct-6-enyloxy)methyl)benzene

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

Conditions
ConditionsYield
With ammonia; lithium In tetrahydrofuran at -30℃; for 0.666667h;82%
(S)-8-(2,3-dimethyl-but-2-en-1-yloxy)-2,6-dimethyloct-2-ene

(S)-8-(2,3-dimethyl-but-2-en-1-yloxy)-2,6-dimethyloct-2-ene

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

Conditions
ConditionsYield
With (PhSO2)2; water In dichloromethane at 80℃;82%
(S)-Citronellal
5949-05-3

(S)-Citronellal

A

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

B

(S)-(-)-citronellic acid
2111-53-7

(S)-(-)-citronellic acid

Conditions
ConditionsYield
With Fusarium concentricum In dimethyl sulfoxide at 28 - 30℃; for 120h; Reagent/catalyst; Microbiological reaction;A 76%
B 5%
With Fusarium fujikuroi In dimethyl sulfoxide at 28 - 30℃; for 120h; Microbiological reaction;A 36%
B 43%
With endosperms of Triticum aestivum L. cv Dariel wheat seeds In water at 27℃; Reagent/catalyst; Concentration; Darkness; Enzymatic reaction; enantioselective reaction;
Nerol
106-25-2

Nerol

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

Conditions
ConditionsYield
With 1,1′-binaphthalene-2,2′-diylbis[bis(4-methylphenyl)phosphine]; potassium hydroxide at 100℃; for 2h; Inert atmosphere; optical yield given as %ee; enantioselective reaction;70%
With hydrogen; BINAP-Ru(II) dicarboxylate In methanol at 18 - 20℃; Yield given;
With hydrogen; BINAP-(Ru(II) dicarboxylate In methanol at 18 - 20℃; Product distribution; examination of enantioselectivity; various complexes;
(S)-(-)-citronellic acid
2111-53-7

(S)-(-)-citronellic acid

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

Conditions
ConditionsYield
With lithium aluminium tetrahydride In tetrahydrofuran at 0 - 25℃; for 3h; Inert atmosphere;69%
(S)-Citronellal
5949-05-3

(S)-Citronellal

A

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

B

(1S,3R,4S)-p-menthane-3,8-diol
19956-48-0

(1S,3R,4S)-p-menthane-3,8-diol

D

(−)-neo-isopulegol
122517-60-6

(−)-neo-isopulegol

E

(+)-isopulegol
104870-56-6

(+)-isopulegol

Conditions
ConditionsYield
With Penicillium paxilli In dimethyl sulfoxide at 28 - 30℃; for 120h; Microbiological reaction;A 10%
B 50%
C 20%
D 5%
E 2%
(S)-citronellyl propionate

(S)-citronellyl propionate

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

Conditions
ConditionsYield
With potassium chloride; water In acetone48%
3,7-dimethyl-oct-6-enal
106-23-0, 26489-02-1

3,7-dimethyl-oct-6-enal

A

(R)-Citronellal
2385-77-5

(R)-Citronellal

B

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

Conditions
ConditionsYield
With baker's yeastA 21%
B 33%
(S)-(-)-3,7-dimethyl-6-ocyten-1-yl diphenylmethylsilyl ether

(S)-(-)-3,7-dimethyl-6-ocyten-1-yl diphenylmethylsilyl ether

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

Conditions
ConditionsYield
With potassium (4-methylphenyl)trifluoroborate In dimethyl sulfoxide at 37℃; for 24h; Inert atmosphere;18%
ethanol
64-17-5

ethanol

(S)-Citronellal
5949-05-3

(S)-Citronellal

EtOMgCl

EtOMgCl

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

(E/Z)-3,7-dimethyl-2,6-octadienal
5392-40-5

(E/Z)-3,7-dimethyl-2,6-octadienal

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

Conditions
ConditionsYield
in Ficus retusa Linn. nach Injektion;
Nerol
106-25-2

Nerol

A

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

B

(3R)-citronellol
1117-61-9

(3R)-citronellol

Conditions
ConditionsYield
With hydrogen; <(+)-CyBINAP>-RhN In benzene under 15200 Torr; Ambient temperature; Yield given. Yields of byproduct given;
With hydrogen; ClO4 In benzene under 7600 Torr; for 8h; Ambient temperature; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
With hydrogen; Ru2Cl4-((S)-2,2'-bis[di(p-tolyl)phosphino]-1,1'-binaphthyl)2NEt3 In methanol at 19.9℃; under 1807.6 Torr; Product distribution; different pressure and temperature;
With 1,2-bis(2,5-diisopropylphospholano)benzene; potassium hydroxide at 100℃; for 24h; Inert atmosphere; optical yield given as %ee; enantioselective reaction;
Geraniol
106-24-1

Geraniol

A

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

B

(3R)-citronellol
1117-61-9

(3R)-citronellol

C

(R)-3,7-dimethyloctan-1-ol
1117-60-8

(R)-3,7-dimethyloctan-1-ol

Conditions
ConditionsYield
With hydrogen; {RuI((R)-2,2'-bis(diphenylphospino)-1,1'-binaphthyl)(p-cymene)}I In methanol; water at 20℃; under 76000 Torr; for 8h; Yield given. Yields of byproduct given;
Geraniol
106-24-1

Geraniol

A

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

B

(3R)-citronellol
1117-61-9

(3R)-citronellol

Conditions
ConditionsYield
With <<(-)-2,2'-bis(diphenylphosphino)-4,4',6,6'-tetramethyl-3,3'-bibenzothiophene>Ru(p-cumene)I>I; hydrogen In methanol at 25℃; under 7355.08 Torr; for 88h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
With ((S)-(6,6'-dimethylbiphenyl-2,2'-diyl)bis(diphenylphosphine))Ru(O2CCF3)2; hydrogen In methanol at 20 - 25℃; under 45003.6 Torr; for 1h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
With hydrogen; <(+)-BINAP>RhN In benzene under 22800 Torr; Ambient temperature; Yield given. Yields of byproduct given;
(R)-1-[(R)-3-(1-Hydroxy-1-methyl-ethyl)-pyrrolidin-1-yl]-3,7-dimethyl-oct-6-en-1-one

(R)-1-[(R)-3-(1-Hydroxy-1-methyl-ethyl)-pyrrolidin-1-yl]-3,7-dimethyl-oct-6-en-1-one

A

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

B

(3R)-citronellol
1117-61-9

(3R)-citronellol

Conditions
ConditionsYield
With lithium triethylborohydride In tetrahydrofuran Ambient temperature; Yield given;
With lithium triethylborohydride In tetrahydrofuran Ambient temperature; Yields of byproduct given;
N,N-diethyl-N-{1-[(3S),7-dimethylocta-1,6-dienyl]}amine
67392-54-5

N,N-diethyl-N-{1-[(3S),7-dimethylocta-1,6-dienyl]}amine

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

Conditions
ConditionsYield
With oxonium; hydrogen
(S)-(+)-dihydromyrcene
2436-90-0

(S)-(+)-dihydromyrcene

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

Conditions
ConditionsYield
With sodium hydroxide; sodium tetrahydroborate; 2-methyl-but-2-ene; boron trifluoride; dihydrogen peroxide 1.) THF, room temp., 3 h.; 2.) 50 deg C, 1.5 h; Multistep reaction;
γ-geraniol
13066-51-8

γ-geraniol

A

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

B

(3R)-citronellol
1117-61-9

(3R)-citronellol

Conditions
ConditionsYield
With Ru2Cl4-((S)-2,2'-bis[di(p-tolyl)phosphino]-1,1'-binaphthyl)2NEt3; hydrogen In methanol at 19.9℃; under 3750.3 Torr; Title compound not separated from byproducts;
With hydrogen; Ru2Cl4-((S)-2,2'-bis[di(p-tolyl)phosphino]-1,1'-binaphthyl)2NEt3 In methanol at 19.9℃; under 1807.6 Torr; Product distribution; other pressure and temperature;
With 1,1′-binaphthalene-2,2′-diylbis[bis(4-methylphenyl)phosphine]; potassium hydroxide at 100℃; for 6h; Inert atmosphere; optical yield given as %ee; enantioselective reaction;
(3S)-3,7-dimethyl-6-octen-1-yl acetate
67601-05-2

(3S)-3,7-dimethyl-6-octen-1-yl acetate

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

Conditions
ConditionsYield
Stage #1: (3S)-3,7-dimethyl-6-octen-1-yl acetate With sodium hydroxide In ethanol at 90℃; for 3h; Alkaline hydrolysis;
Stage #2: With Pichia kluyveri IFO 1165 at 30℃; for 48h;
vinyl acetate
108-05-4

vinyl acetate

Citronellol
106-22-9

Citronellol

A

(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

B

(3R)-citronellol
1117-61-9

(3R)-citronellol

C

(R)-1-citronellyl acetate
20425-54-1

(R)-1-citronellyl acetate

D

(3S)-3,7-dimethyl-6-octen-1-yl acetate
67601-05-2

(3S)-3,7-dimethyl-6-octen-1-yl acetate

Conditions
ConditionsYield
With porcine pancreatic lipase In hexane for 24h; Title compound not separated from byproducts;
With porcine pancreatic lipase In hexane for 48h; Title compound not separated from byproducts;
(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

S-(-)-dihydrocitronellol
68680-98-8

S-(-)-dihydrocitronellol

Conditions
ConditionsYield
With palladium on activated charcoal; hydrogen100%
With palladium on activated charcoal; hydrogen In methanol; ethyl acetate at 25℃; for 18h; Inert atmosphere;98%
With palladium 10% on activated carbon; hydrogen In ethyl acetate at 20℃; for 0.25h; Inert atmosphere;96%
(S)-3,7-dimethyl-6-octen-1-ol
7540-51-4

(S)-3,7-dimethyl-6-octen-1-ol

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

(S)-3,7-dimethyl-6-octenyl tosylate
41144-01-8, 67214-54-4, 93303-23-2, 116661-43-9

(S)-3,7-dimethyl-6-octenyl tosylate

Conditions
ConditionsYield
With pyridine at 0℃; for 12h; Tosylation;100%
With pyridine at 0℃; for 72h;100%
With pyridine100%

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