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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

2-Fluoro-6-nitrotoluene

Cas:769-10-8

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 2-Fluoro-6-Nitrotoluene with high purity

Cas:769-10-8

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Jinan Finer Chemical Co., Ltd

Product description: Product name 2-Fluoro-6-nitrotoluene CAS number 769-10-8 Assay ≥99% Appearance Yellowish Liquid Capacity 100mt/year Application Organic intermediate

2-Fluoro-6-nitrotoluene

Cas:769-10-8

Min.Order:10 Gram

FOB Price: $12.0

Type:Lab/Research institutions

inquiry

Hebei yanxi chemical co.,LTD.

Hebei Yanxi Chemical Co., Ltd. is a professional research, development and production of lead acetate benzene acetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low car

2-Fluoro-6-nitrotoluene

Cas:769-10-8

Min.Order:1 Metric Ton

FOB Price: $1.0 / 2.0

Type:Manufacturers

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Appearance:Solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Intermediates Transportation:by air or by sea Port:shanghai

2-Fluoro-6-nitrotoluene

Cas:769-10-8

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

COLORCOM LTD.

Colorcom is a global leader in industrial chemical manufacturing and is continuously innovating and transforming to exceed client expectations and industry standards. Colorcom prides itself on superior customer and technical focus, while focusing on

2-Fluoro-6-Nitrotoluene

Cas:769-10-8

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

2-Fluoro-6-nitrotoluene

Cas:769-10-8

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Top Purity CAS 769-10-8 with fast shipping

Cas:769-10-8

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

2-Fluoro-6-nitrotoluene 769-10-8

Cas:769-10-8

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:769-10-8

Cas:769-10-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

2-Fluoro-6-nitrotoluene

Cas:769-10-8

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

2-Fluoro-6-Nitrotoluene

Cas:769-10-8

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

2-FLUORO-6-NITROTOLUENE

Cas:769-10-8

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

2-Fluoro-6-nitrotoluene

Cas:769-10-8

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

2-Fluoro-6-nitrotoluene

Cas:769-10-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 2-Fluoro-6-nitrotoluene

Cas:769-10-8

Min.Order:0 Metric Ton

Negotiable

Type:Other

inquiry

Hangzhou Lingrui Chemical Co.,Ltd.

769-10-8 2-Fluoro-6-nitrotoluene Appearance:clear liquid Storage:Sealed in dry,Room Temperature Package:according to customers' requirements Application:2-fluoro-6-nitrotoluene can be used as an intermediate in pharmaceutical synthesis. For example,

2-Fluoro-6-nitrotoluene

Cas:769-10-8

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Chemlyte Solutions

Chemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff

Featured products 2-Fluoro-6-nitrotoluene

Cas:769-10-8

Min.Order:100 Gram

Negotiable

Type:Other

inquiry

Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

2-Fluoro-6-nitrotoluene

Cas:769-10-8

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Siwei Development Group Ltd.

Product name: 2-Fluoro-6-Nitrotoluene CAS No.:769-10-8 Molecule Formula:C7H6FNO2 Molecule Weight:155.13 Purity: 98.0% Package: 25kg/drum Description:White powder Manufacture Standards:Enterprise Standard TESTING IT

High Quality 2-Fluoro-6-Nitrotoluene on stock

Cas:769-10-8

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 6 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so

TIANFUCHEM--769-10-8--2-Fluoro-6-nitrotoluene

Cas:769-10-8

Min.Order:1 Metric Ton

FOB Price: $500.0

Type:Lab/Research institutions

inquiry

Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

2-Fluoro-6-nitrotoluene

Cas:769-10-8

Min.Order:1 Milligram

Negotiable

Type:Trading Company

inquiry

Shanghai Minstar Chemical Co., Ltd

Product Name: 2-Fluoro-6-nitrotoluene Synonyms: 2-FLUORO-6-NITROTOLUENE;2-Fluoro-6-nitrotoluene 98%;2-Fluoro-6-nitrotoluene98%;1-FLUORO-2-METHYL-3-NITRO-BENZENE;1-FLUOR-2-METHYL-3-NITROBENZENE;2-methyl-3-fluoronitrobenzene;2-NITRO-6-FLUOROTOLUE

2-Fluoro-6-nitrotoluene 769-10-8 C7H6FNO2

Cas:769-10-8

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

2-Fluoro-6-nitrotoluene

Cas:769-10-8

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Hangzhou Zhongqi chem Co.,Ltd.

Located in Hangzhou National Hi-Tech Industrial Development Zone, zhongqichem is a technical company mainly focus on the Custom synthesis, manufacturing, sales of chemicals to various industries. Benefiting from the outstanding customer service and h

2-Fluoro-6-nitrotoluene

Cas:769-10-8

Min.Order:0

Negotiable

Type:Other

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

2-Fluoro-6-nitrotoluene

Cas:769-10-8

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

SAGECHEM LIMITED

SAGECHEM is a chemical R&D, manufacturing and distribution company in China since 2009, including pharmaceutical intermediates, agrochemical, dyestuff intermediates, organosilicone, API and etc. We also offer a full range of services in custom synthe

SAGECHEM/2-Fluoro-6-nitrotoluene

Cas:769-10-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

2-fluoro-6-nitrotoluene

Cas:769-10-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Golden Pharma Co., Limited

GOLDEN PHARMA CO.,LIMITED.is a professional pharmaceutical company,our team have more than 20years expereince in pharmaceutical production and sales. we are a professional technical enterprise specializing in the R & D, production,QA regulation

2-Fluoro-6-nitrotoluene

Cas:769-10-8

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

Beijing Greenchem Technology Co.,Ltd. ( Panjin Greenchem Technology Co.Ltd .)

Capability on chemical synthesis1. Beijing High-Tech Enterprises2. Strong R&D Team3. 8 years of experiences in R & D of high-tech Catalyst;4. 5000 production techniques, 69 items of national patents, and 360 kinds of products on sales;5. The producti

2-Fluoro-6-nitrotoluene

Cas:769-10-8

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Synthetic route

2-Fluorotoluene
95-52-3

2-Fluorotoluene

A

5-nitro-2-fluorotoluene
455-88-9

5-nitro-2-fluorotoluene

B

1-fluoro-2-methyl-3-nitrobenzene
769-10-8

1-fluoro-2-methyl-3-nitrobenzene

Conditions
ConditionsYield
With nitric acid
2-methyl-3-nitrobenzenediazonium tetrafluoroborate

2-methyl-3-nitrobenzenediazonium tetrafluoroborate

1-fluoro-2-methyl-3-nitrobenzene
769-10-8

1-fluoro-2-methyl-3-nitrobenzene

Conditions
ConditionsYield
With sand at 300℃;
at 250℃;
3-nitro-o-tolylamine
603-83-8

3-nitro-o-tolylamine

1-fluoro-2-methyl-3-nitrobenzene
769-10-8

1-fluoro-2-methyl-3-nitrobenzene

Conditions
ConditionsYield
Ueberfuehrung in das Diazopiperidid und Erhitzen mit Fluorwasserstoff-Fluorkalium;
(i) NaNO2, HBF4, (ii) (thermolysis); Multistep reaction;
(i) (diazotization), BF4-, (ii) (pyrolysis); Multistep reaction;
Stage #1: 3-nitro-o-tolylamine With sulfuric acid; sodium nitrite at 0 - 20℃; for 2h;
Stage #2: With copper (I) fluoride Sandmeyer reaction; Further stages.;
2-Fluorotoluene
95-52-3

2-Fluorotoluene

1-fluoro-2-methyl-3-nitrobenzene
769-10-8

1-fluoro-2-methyl-3-nitrobenzene

Conditions
ConditionsYield
With nitric acid
1-methyl-2-nitrobenzene
88-72-2

1-methyl-2-nitrobenzene

A

1-fluoro-2-methyl-3-nitrobenzene
769-10-8

1-fluoro-2-methyl-3-nitrobenzene

B

1-(fluoromethyl)-2-nitrobenzene

1-(fluoromethyl)-2-nitrobenzene

Conditions
ConditionsYield
With pyridine; hydrogen fluoride at 25℃; for 0.81h; electrochemical synthesis: Pt electrodes, applied potential 2.40 V, frequency square wave alternating current of 0.033 Hz, passed charge of 2.00 F mol-1; Yield given. Yields of byproduct given;
2-Fluorotoluene
95-52-3

2-Fluorotoluene

nitric acid
7697-37-2

nitric acid

A

5-nitro-2-fluorotoluene
455-88-9

5-nitro-2-fluorotoluene

B

2-fluoro-4-nitrotoluene
1427-07-2

2-fluoro-4-nitrotoluene

C

1-fluoro-2-methyl-3-nitrobenzene
769-10-8

1-fluoro-2-methyl-3-nitrobenzene

6-nitro-toluenediazonium-(2)-tetrafluoroborate

6-nitro-toluenediazonium-(2)-tetrafluoroborate

1-fluoro-2-methyl-3-nitrobenzene
769-10-8

1-fluoro-2-methyl-3-nitrobenzene

Conditions
ConditionsYield
at 150 - 250℃;
2,6-dinitrotoluene
606-20-2

2,6-dinitrotoluene

1-fluoro-2-methyl-3-nitrobenzene
769-10-8

1-fluoro-2-methyl-3-nitrobenzene

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 4>2S
2: (i) (diazotization), BF4-, (ii) (pyrolysis)
View Scheme
4-Amino-2,6-dinitrotoluene
19406-51-0

4-Amino-2,6-dinitrotoluene

1-fluoro-2-methyl-3-nitrobenzene
769-10-8

1-fluoro-2-methyl-3-nitrobenzene

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: (i) (diazotization), (ii) (reduction)
2: 4>2S
3: (i) (diazotization), BF4-, (ii) (pyrolysis)
View Scheme
1-fluoro-2-methyl-3-nitrobenzene
769-10-8

1-fluoro-2-methyl-3-nitrobenzene

1-fluoro-2-methyl-3,4-dinitro-benzene

1-fluoro-2-methyl-3,4-dinitro-benzene

Conditions
ConditionsYield
With sulfuric acid; uronium nitrate at 0 - 20℃; Nitration;94%
formaldehyd
50-00-0

formaldehyd

1-fluoro-2-methyl-3-nitrobenzene
769-10-8

1-fluoro-2-methyl-3-nitrobenzene

2-(2-fluoro-6-nitrophenyl)ethanol
118665-03-5

2-(2-fluoro-6-nitrophenyl)ethanol

Conditions
ConditionsYield
With potassium hydroxide In ethanol; dimethyl sulfoxide for 72h; Ambient temperature;89%
1-fluoro-2-methyl-3-nitrobenzene
769-10-8

1-fluoro-2-methyl-3-nitrobenzene

N,N-dimethyl-formamide dimethyl acetal
4637-24-5

N,N-dimethyl-formamide dimethyl acetal

3-fluoro-trans-2-[β-(dimethylamino)vinyl]nitrobenzene

3-fluoro-trans-2-[β-(dimethylamino)vinyl]nitrobenzene

Conditions
ConditionsYield
With copper(l) iodide; N,N-dimethyl-formamide at 180℃; under 6000.6 - 7500.75 Torr; for 0.333333h; microwave irradiation;85%
With triethylamine In N,N-dimethyl-formamide at 110℃; for 20h;
1-fluoro-2-methyl-3-nitrobenzene
769-10-8

1-fluoro-2-methyl-3-nitrobenzene

dimethyl 2-(4-methoxybenzylidene)malonate
7443-25-6

dimethyl 2-(4-methoxybenzylidene)malonate

2-[2-(2-Fluoro-6-nitro-phenyl)-1-(4-methoxy-phenyl)-ethyl]-malonic acid dimethyl ester

2-[2-(2-Fluoro-6-nitro-phenyl)-1-(4-methoxy-phenyl)-ethyl]-malonic acid dimethyl ester

Conditions
ConditionsYield
With 4 A molecular sieve; tetrabutyl ammonium fluoride; potassium carbonate In tetrahydrofuran for 0.5h; Ambient temperature;82%
1-fluoro-2-methyl-3-nitrobenzene
769-10-8

1-fluoro-2-methyl-3-nitrobenzene

phenylboronic acid
98-80-6

phenylboronic acid

3-fluoro-2-methyl-N-phenylaniline

3-fluoro-2-methyl-N-phenylaniline

Conditions
ConditionsYield
With triethylphosphine In m-xylene at 120℃; for 16h; Inert atmosphere; Schlenk technique; Sealed tube;82%
Dimethyl oxalate
553-90-2

Dimethyl oxalate

1-fluoro-2-methyl-3-nitrobenzene
769-10-8

1-fluoro-2-methyl-3-nitrobenzene

methyl 3-(2-fluoro-6-nitrophenyl)-2-oxopropanoate
912819-08-0

methyl 3-(2-fluoro-6-nitrophenyl)-2-oxopropanoate

Conditions
ConditionsYield
With sodium hydride In N,N-dimethyl-formamide at 0 - 25℃; for 19h;80%
Stage #1: 1-fluoro-2-methyl-3-nitrobenzene With sodium hydride In N,N-dimethyl-formamide at 0℃; for 0.166667h;
Stage #2: Dimethyl oxalate In N,N-dimethyl-formamide at 0 - 25℃; for 13h; Further stages.;
80%
pyrrolidine
123-75-1

pyrrolidine

1-fluoro-2-methyl-3-nitrobenzene
769-10-8

1-fluoro-2-methyl-3-nitrobenzene

N,N-dimethyl-formamide dimethyl acetal
4637-24-5

N,N-dimethyl-formamide dimethyl acetal

1-(2-(2-fluoro-6-nitrophenyl)vinyl)pyrrolidine
344790-94-9

1-(2-(2-fluoro-6-nitrophenyl)vinyl)pyrrolidine

Conditions
ConditionsYield
for 48h; Reflux;80%
In N,N-dimethyl-formamide at 40 - 100℃; for 1h; Inert atmosphere;
pyrrolidine
123-75-1

pyrrolidine

1-fluoro-2-methyl-3-nitrobenzene
769-10-8

1-fluoro-2-methyl-3-nitrobenzene

N,N-dimethyl-formamide dimethyl acetal
4637-24-5

N,N-dimethyl-formamide dimethyl acetal

1-[(E)-2-(2-Fluoro-6-nitro-phenyl)-vinyl]-pyrrolidine

1-[(E)-2-(2-Fluoro-6-nitro-phenyl)-vinyl]-pyrrolidine

Conditions
ConditionsYield
In N,N-dimethyl-formamide for 3h; Heating;77%
PE

PE

1-fluoro-2-methyl-3-nitrobenzene
769-10-8

1-fluoro-2-methyl-3-nitrobenzene

2-(2-fluoro-6-nitrophenyl)ethanol
118665-03-5

2-(2-fluoro-6-nitrophenyl)ethanol

Conditions
ConditionsYield
With paraformaldehyde In dimethyl sulfoxide; ethyl acetate; SiO2; tert-butyl alcohol71%
1-fluoro-2-methyl-3-nitrobenzene
769-10-8

1-fluoro-2-methyl-3-nitrobenzene

polyoxymethylene

polyoxymethylene

2-(2-fluoro-6-nitrophenyl)ethanol
118665-03-5

2-(2-fluoro-6-nitrophenyl)ethanol

Conditions
ConditionsYield
With potassium tert-butylate In dimethyl sulfoxide at 70℃; for 1h; Inert atmosphere;69%
1-fluoro-2-methyl-3-nitrobenzene
769-10-8

1-fluoro-2-methyl-3-nitrobenzene

2-(bromomethyl)-1-fluoro-3-nitrobenzene
1958-93-6

2-(bromomethyl)-1-fluoro-3-nitrobenzene

Conditions
ConditionsYield
With N-Bromosuccinimide; dibenzoyl peroxide In tetrachloromethane at 90℃; for 14h;66%
44%
With N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile) In tetrachloromethane Heating;22%
1-fluoro-2-methyl-3-nitrobenzene
769-10-8

1-fluoro-2-methyl-3-nitrobenzene

N,N-dimethyl-formamide dimethyl acetal
4637-24-5

N,N-dimethyl-formamide dimethyl acetal

2-fluoro-6-nitrobenzaldehyde
1644-82-2

2-fluoro-6-nitrobenzaldehyde

Conditions
ConditionsYield
Stage #1: 1-fluoro-2-methyl-3-nitrobenzene; N,N-dimethyl-formamide dimethyl acetal at 135℃; for 12h;
Stage #2: With sodium periodate In water; N,N-dimethyl-formamide at 20℃; for 3h;
23%
1-fluoro-2-methyl-3-nitrobenzene
769-10-8

1-fluoro-2-methyl-3-nitrobenzene

oxalic acid diethyl ester
95-92-1

oxalic acid diethyl ester

3-(2-fluoro-6-nitrophenyl)-2-oxopropanoic acid
7593-91-1

3-(2-fluoro-6-nitrophenyl)-2-oxopropanoic acid

Conditions
ConditionsYield
Stage #1: 1-fluoro-2-methyl-3-nitrobenzene; oxalic acid diethyl ester With ethanol; sodium for 0.75h; Reflux;
Stage #2: With water In ethanol
21%
1-fluoro-2-methyl-3-nitrobenzene
769-10-8

1-fluoro-2-methyl-3-nitrobenzene

3-fluoro-2-methylaniline
443-86-7

3-fluoro-2-methylaniline

Conditions
ConditionsYield
With hydrogenchloride; tin(ll) chloride
With hydrogenchloride; tin(ll) chloride
With hydrogenchloride; tin(ll) chloride at 0 - 50℃; for 2h;
1-fluoro-2-methyl-3-nitrobenzene
769-10-8

1-fluoro-2-methyl-3-nitrobenzene

6-fluoro-2-nitrobenzoic acid
385-02-4

6-fluoro-2-nitrobenzoic acid

Conditions
ConditionsYield
With nitric acid
With potassium permanganate
Multi-step reaction with 3 steps
1: NBS, (PhCO)2O2 / CCl4
2: aq. Na2CO3
3: aq. H2SO4, K2Cr2O7
View Scheme
With potassium permanganate In water11.81 g (40%)
With potassium permanganate; potassium carbonate In water
1-fluoro-2-methyl-3-nitrobenzene
769-10-8

1-fluoro-2-methyl-3-nitrobenzene

oxalic acid diethyl ester
95-92-1

oxalic acid diethyl ester

4-fluoro-1H-indole-2-carboxylic acid
399-68-8

4-fluoro-1H-indole-2-carboxylic acid

Conditions
ConditionsYield
With diethyl ether; potassium ethoxide Behandeln des Reaktionsprodukts mit wss. NH3 unf FeSO4;
Stage #1: 1-fluoro-2-methyl-3-nitrobenzene; oxalic acid diethyl ester With sodium ethanolate In diethyl ether at 35 - 38℃; for 18h;
Stage #2: With ferrous(II) sulfate heptahydrate In aq. ammonia; water
tris(piperidino)-methane
22630-08-6

tris(piperidino)-methane

1-fluoro-2-methyl-3-nitrobenzene
769-10-8

1-fluoro-2-methyl-3-nitrobenzene

4-fluoroindole
387-43-9

4-fluoroindole

Conditions
ConditionsYield
With iron; silica gel 1) 120 deg C, 3 h, under vacuum 2) 1 h reflux in toluene-acetic acid; Yield given. Multistep reaction;
1-fluoro-2-methyl-3-nitrobenzene
769-10-8

1-fluoro-2-methyl-3-nitrobenzene

oxalic acid diethyl ester
95-92-1

oxalic acid diethyl ester

ethyl (6-fluoro-2-nitrophenyl)pyruvate

ethyl (6-fluoro-2-nitrophenyl)pyruvate

Conditions
ConditionsYield
With potassium ethoxide In ethanol for 6h; Heating;
Stage #1: oxalic acid diethyl ester With potassium tert-butylate In diethyl ether for 0.166667h;
Stage #2: 1-fluoro-2-methyl-3-nitrobenzene In diethyl ether at 20℃;
1-fluoro-2-methyl-3-nitrobenzene
769-10-8

1-fluoro-2-methyl-3-nitrobenzene

nitric acid
7697-37-2

nitric acid

6-fluoro-2-nitrobenzoic acid
385-02-4

6-fluoro-2-nitrobenzoic acid

1-fluoro-2-methyl-3-nitrobenzene
769-10-8

1-fluoro-2-methyl-3-nitrobenzene

methyl 3-(2-fluoro-6-nitrophenyl)-2-oxobut-3-enoate
912819-11-5

methyl 3-(2-fluoro-6-nitrophenyl)-2-oxobut-3-enoate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: NaH / dimethylformamide; various solvent(s) / 0.17 h / 0 °C
1.2: 80 percent / dimethylformamide; various solvent(s) / 13 h / 0 - 25 °C
2.1: NaH / tetrahydrofuran; various solvent(s) / 1 h / 0 °C
2.2: 74 percent / tetrahydrofuran; various solvent(s) / 12 h / 25 °C
View Scheme
Multi-step reaction with 2 steps
1: 80 percent / sodium hydride / dimethylformamide / 19 h / 0 - 25 °C
2: 74 percent / sodium hydride / tetrahydrofuran / 13 h / 0 - 25 °C
View Scheme
1-fluoro-2-methyl-3-nitrobenzene
769-10-8

1-fluoro-2-methyl-3-nitrobenzene

methyl 4-fluoro-1-hydroxy-3-(2-methyl-3-oxopentyl)-1H-indole-2-carboxylate

methyl 4-fluoro-1-hydroxy-3-(2-methyl-3-oxopentyl)-1H-indole-2-carboxylate

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: NaH / dimethylformamide; various solvent(s) / 0.17 h / 0 °C
1.2: 80 percent / dimethylformamide; various solvent(s) / 13 h / 0 - 25 °C
2.1: NaH / tetrahydrofuran; various solvent(s) / 1 h / 0 °C
2.2: 74 percent / tetrahydrofuran; various solvent(s) / 12 h / 25 °C
3.1: 61 percent / SnCl2*2H2O; molecular sieves 4 Angstroem / 1,2-dimethoxy-ethane / 1.5 h / 40 °C
View Scheme
Multi-step reaction with 3 steps
1: 80 percent / sodium hydride / dimethylformamide / 19 h / 0 - 25 °C
2: 74 percent / sodium hydride / tetrahydrofuran / 13 h / 0 - 25 °C
3: 61 percent / tin(II) chloride dihydrate; molecular sieves 4 Angstroem / 1,2-dimethoxy-ethane / 1.5 h / 40 °C
View Scheme
1-fluoro-2-methyl-3-nitrobenzene
769-10-8

1-fluoro-2-methyl-3-nitrobenzene

methyl 4-fluoro-1-hydroxy-3-[(2-oxocyclohexyl)methyl]-1H-indole-2-carboxylate

methyl 4-fluoro-1-hydroxy-3-[(2-oxocyclohexyl)methyl]-1H-indole-2-carboxylate

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: NaH / dimethylformamide; various solvent(s) / 0.17 h / 0 °C
1.2: 80 percent / dimethylformamide; various solvent(s) / 13 h / 0 - 25 °C
2.1: NaH / tetrahydrofuran; various solvent(s) / 1 h / 0 °C
2.2: 74 percent / tetrahydrofuran; various solvent(s) / 12 h / 25 °C
3.1: 44 percent / SnCl2*2H2O; molecular sieves 4 Angstroem / 1,2-dimethoxy-ethane / 1.5 h / 40 °C
View Scheme
Multi-step reaction with 3 steps
1: 80 percent / sodium hydride / dimethylformamide / 19 h / 0 - 25 °C
2: 74 percent / sodium hydride / tetrahydrofuran / 13 h / 0 - 25 °C
3: 44 percent / tin(II) chloride dihydrate; molecular sieves 4 Angstroem / 1,2-dimethoxy-ethane / 1.5 h / 40 °C
View Scheme

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