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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

Hexabutyldistannane Manufacturer/High quality/Best price/In stock

Cas:813-19-4

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Hebei yanxi chemical co.,LTD.

chengdu and import and export trade co., LTD., who registered capital of 10 million yuan, nearly to $2 million, we have a pharmaceutical raw materials factory production of pharmaceutical raw materials, and a reagent r&d center, and we do res

Hexabutyldistannane

Cas:813-19-4

Min.Order:1 Kilogram

FOB Price: $1300.0 / 1500.0

Type:Trading Company

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Hexabutylditin

Cas:813-19-4

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

HEXABUTYLDITIN Basic information Product Name: HEXABUTYLDITIN Synonyms: 1,1,1,2,2,2-Hexabutyl-distannane;Distannane,hexabutyl-;Hexa-n-butyldizinn;BIS(TRIBUTYLTIN);BIS[TRIBUTYLTIN(IV)];BI

HEXABUTYLDITIN

Cas:813-19-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

Distannane,hexabutyl-.

Cas:813-19-4

Min.Order:1 Gram

FOB Price: $12.0 / 15.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 813-19-4 with best quality

Cas:813-19-4

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

Distannane,1,1,1,2,2,2-hexabutyl-

Cas:813-19-4

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

HEXABUTYLDITIN

Cas:813-19-4

Min.Order:5 Gram

FOB Price: $290.0

Type:Trading Company

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Qingdao Beluga Import and Export Co., LTD

HEXABUTYLDITIN CAS: 813-19-4 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermediat

HEXABUTYLDITIN CAS: 813-19-4

Cas:813-19-4

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Distannane,1,1,1,2,2,2-hexabutyl-

Cas:813-19-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:813-19-4

Cas:813-19-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Hexabutylditin

Cas:813-19-4

Min.Order:0 Metric Ton

Negotiable

Type:Other

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Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

HEXABUTYLDITIN

Cas:813-19-4

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

Hexabutyldistannane

Cas:813-19-4

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

Hexabutyldistannane

Cas:813-19-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Minstar Chemical Co., Ltd

HEXABUTYLDITIN Basic information Product Name: HEXABUTYLDITIN Synonyms: 1,1,1,2,2,2-Hexabutyl-distannane;Distannane,hexabutyl-;Hexa-n-butyldizinn;BIS(TRIBUTYLTIN);BIS[TRIBUTYLTIN(IV)];BIS(TRI-N-BUTYLTIN);ditin;Hexa-n-butyL CAS: 813-19-4 MF:

HEXABUTYLDITIN

Cas:813-19-4

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

813-19-4 CAS NO.813-19-4

Cas:813-19-4

Min.Order:1 Metric Ton

FOB Price: $7.0 / 8.0

Type:Trading Company

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Hangzhou Zhongqi chem Co.,Ltd.

Located in Hangzhou National Hi-Tech Industrial Development Zone, zhongqichem is a technical company mainly focus on the Custom synthesis, manufacturing, sales of chemicals to various industries. Benefiting from the outstanding customer service an

Hexabutyldistannane

Cas:813-19-4

Min.Order:1 Gram

Negotiable

Type:Other

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Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

Hexa-n-butyldistannane

Cas:813-19-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

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GIHI CHEMICALS CO.,LIMITED

high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,or Intermediates,fine chemicals Transportation:air,sea,courier

Hexabutylditin

Cas:813-19-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec Hexabutyldistannane 100g

Cas:813-19-4

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

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Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

Hexa-n-butylditin, 98%

Cas:813-19-4

Min.Order:0

Negotiable

Type:Manufacturers

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM is one of China's leading providers of integrated fine chemical services including offering, research and development, Custom manufacturing business, as well as other Value-added customer services, for diversified range products of chemicals

HEXABUTYLDITIN

Cas:813-19-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Xian Changyue Biological Technology Co., Ltd.

best seller Application:API

HEXABUTYLDITIN

Cas:813-19-4

Min.Order:0

Negotiable

Type:Manufacturers

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Hunan chemfish Pharmaceutical co.,Ltd

Hunan chemfish Pharmaceutical co.,Ltd.located in Lugu High-tech industral park ,Hunan province . with its own R&D center and more than 10000㎡manufacture plant . Chemfish owns 40 reactors from 1000L to 8000L. With complete auxiliary equipment as

Hexabutylditin

Cas:813-19-4

Min.Order:0

Negotiable

Type:Manufacturers

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Wuhan Circle Star Chem-medical Technology co.,Ltd.

1,we produce and sell good chemicals around the world.2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%.3,our staff consists of highly qualified in

HEXABUTYLDITIN

Cas:813-19-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Distannane,1,1,1,2,2,2-hexabutyl-

Cas:813-19-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

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HANGZHOU TIANYE CHEMICALS CO., LTD.

We product this chemical more than 10 years . We are very experience to export it to many countries, Our superior & stable quality , competitive price gain warm reception from our customers. Application:Chemical intermediate

Hexabutyldistannane

Cas:813-19-4

Min.Order:0

Negotiable

Type:Trading Company

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Guangdong Juda Chemical Industrial Co.,Limited

Appearance:solid or liquid Storage:sealed in cool and dry place Package:As customer's requested Application:Pharma Intermediate Transportation:by courier/air/sea Port:Any port in China

HEXABUTYLDITIN CAS No.813-19-4

Cas:813-19-4

Min.Order:0

Negotiable

Type:Trading Company

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DB BIOTECH CO., LTD

best seller Application:API

HEXABUTYLDITIN

Cas:813-19-4

Min.Order:0

Negotiable

Type:Trading Company

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Synthetic route

bis(trimethylsilyl)mercury
4656-04-6

bis(trimethylsilyl)mercury

tributyltin methoxide
1067-52-3

tributyltin methoxide

A

Methoxytrimethylsilane
1825-61-2

Methoxytrimethylsilane

B

bis(tri-n-butyltin)
813-19-4

bis(tri-n-butyltin)

C

mercury

mercury

Conditions
ConditionsYield
In benzene 25°C; 0.1 h;A 95%
B 98%
C 96%
tri-n-butyl-tin hydride
688-73-3

tri-n-butyl-tin hydride

tributyltin tert-butoxide
2724-79-0

tributyltin tert-butoxide

bis(tri-n-butyltin)
813-19-4

bis(tri-n-butyltin)

Conditions
ConditionsYield
With t-C4H9OH at 110°C (200 h);98%
In not given reaction for 200 h at 110°C;;
In not given reaction for 200 h at 110°C;;
1-bromo-octane
111-83-1

1-bromo-octane

tri-n-butyl-tin hydride
688-73-3

tri-n-butyl-tin hydride

lithium diisopropyl amide
4111-54-0

lithium diisopropyl amide

A

octane
111-65-9

octane

B

bis(tri-n-butyltin)
813-19-4

bis(tri-n-butyltin)

Conditions
ConditionsYield
In hexane; cyclohexane to 1-bromooctane (1 mmol) and Bu3SnH (1 mmol) in hexane at 0°C added LDA (1 mmol, in cyclohexane) under Ar, stirred for 20 min, quenched; analyzed by GLPC;A 97%
B 0%
bis(trimethylsilyl)mercury
4656-04-6

bis(trimethylsilyl)mercury

bis(tri-n-butyltin)oxide
56-35-9

bis(tri-n-butyltin)oxide

A

bis(tri-n-butyltin)
813-19-4

bis(tri-n-butyltin)

B

Bu3SnOSiMe3
17908-18-8

Bu3SnOSiMe3

Conditions
ConditionsYield
In hexane byproducts: Hg; 2:1; 25°C; 0.2 h;A n/a
B 97%
In benzene byproducts: Hg; 2:1; 25°C; 0.2 h;A n/a
B 97%
In benzene byproducts: Hg; 2:1; 25°C; 0.2 h;A n/a
B 97%
In hexane byproducts: Hg; 2:1; 25°C; 0.2 h;A n/a
B 97%
dichlorobis(acetylacetonato-O,O')titanium(IV)

dichlorobis(acetylacetonato-O,O')titanium(IV)

tri-n-butyltin lithium
4226-01-1

tri-n-butyltin lithium

A

titanium(III) tris-acetylacetonate

titanium(III) tris-acetylacetonate

B

Ti(CH3COCHCOCH3)2(Sn(CH3(CH2)3)3)2

Ti(CH3COCHCOCH3)2(Sn(CH3(CH2)3)3)2

C

tri-n-butyl-tin hydride
688-73-3

tri-n-butyl-tin hydride

D

bis(tri-n-butyltin)
813-19-4

bis(tri-n-butyltin)

Conditions
ConditionsYield
In tetrahydrofuran byproducts: LiCl, Ti(Sn(C4H9)3)1.7; addn. of Bu3SnLi to Ti-compound in soln. (-78°C), stirred, mixt. brought to 20°C, soln. became blue; evapn. in vac., residue washed with pentane, sublimation (10**-3 Torr, 90°C); elem. anal., chromy.;A 90%
B 0%
C 30%
D 96%
N-[(1R)-2-hydroxy-1-phenylethyl]-N-[(1S)-1-(tributylstannyl)but-3-en-1-yl]benzenesulfonamide
1175712-18-1, 1175712-19-2

N-[(1R)-2-hydroxy-1-phenylethyl]-N-[(1S)-1-(tributylstannyl)but-3-en-1-yl]benzenesulfonamide

A

(R)-Phenylglycinol
56613-80-0

(R)-Phenylglycinol

B

bis(tri-n-butyltin)
813-19-4

bis(tri-n-butyltin)

Conditions
ConditionsYield
With tetra(n-butyl)ammonium hydrogensulfate In acetonitrile Inert atmosphere; Electrolysis;A 96%
B n/a
tri-n-butyl-tin hydride
688-73-3

tri-n-butyl-tin hydride

lithium diisopropyl amide
4111-54-0

lithium diisopropyl amide

A

hydrogen
1333-74-0

hydrogen

B

bis(tri-n-butyltin)
813-19-4

bis(tri-n-butyltin)

Conditions
ConditionsYield
In diethyl ether; cyclohexane byproducts: i-Pr2NH; Bu3SnH in Et2O cooled to 0°C under Ar, LDA in cyclohexane (1.6 M) added via syringe, stirred for 60 min at room temp., hydrolysis;A 90%
B 94%
tri-n-butyl-tin hydride
688-73-3

tri-n-butyl-tin hydride

bis(tri-n-butyltin)
813-19-4

bis(tri-n-butyltin)

Conditions
ConditionsYield
((tBuC5H4)2Y(μ-H))2 In benzene byproducts: H2; (Ar); stirring (70°C, 30 min);91%
In benzene Ar-atmosphere; stirring (70°C, 0.5 h);91%
[(κ2-P,N)-3-(N,N-dimethylamino)propyldiphenylphosphino]dimethylplatinum(II) In not given byproducts: H2;
tributyltin chloride
1461-22-9

tributyltin chloride

bis(tri-n-butyltin)
813-19-4

bis(tri-n-butyltin)

Conditions
ConditionsYield
In tetrahydrofuran Electrolysis; electrolysis carried out galvanostatically at 25-28°C in an atm.of dry N2, electrolyte 0.4 M LiClO4/THF; hexane added to electrolyte, ppt. filtered off, filtrate analyzed for product by GC;90%
With samarium; samarium diiodide In tetrahydrofuran chlorostannane added to soln. of SmI2 in THF (cat. SmI2/Sm-mixed system); mixt. stirred for 24 h at room temp.; mixt.poured into 1.5N hydrochloric acid; extracted (diethyl ether); washed two times with aq. NaHCO3 then aq. NaCl; dried over MgSO4; filtrated; evapd.; purified by recycling HPLC wit CHCl3;85%
With magnesium; samarium diiodide In tetrahydrofuran chlorostannane added to soln. of SmI2 in THF (cat. SmI2/Mg-mixed system); mixt. stirred for 24 h at room temp.;mixt. poured into 1.5N hydrocloric acid; extracted (diethyl ether); washed two times with aq. NaHCO3 then aq.NaCl; dried over MgSO4; filtrated; evapd.; purified by recycling HPLC with CHCl3;82%
Ti(OC(CH3)3)2(Sn(C4H9)3)2
131551-96-7

Ti(OC(CH3)3)2(Sn(C4H9)3)2

A

titanium bis(tert-butoxide)

titanium bis(tert-butoxide)

B

bis(tri-n-butyltin)
813-19-4

bis(tri-n-butyltin)

Conditions
ConditionsYield
In xylene starting material in soln. heated at 150°C for 6h;A n/a
B 90%
diethyl phenyl orthoformate
14444-77-0

diethyl phenyl orthoformate

isopropylmagnesium chloride
1068-55-9

isopropylmagnesium chloride

tri-n-butyl-tin hydride
688-73-3

tri-n-butyl-tin hydride

A

bis(tri-n-butyltin)
813-19-4

bis(tri-n-butyltin)

B

tetra-n-butyltin(IV)
1461-25-2

tetra-n-butyltin(IV)

C

diethoxymethyltributylstannane
79411-58-8

diethoxymethyltributylstannane

Conditions
ConditionsYield
In diethyl ether grignard reagent in Et2O adding to Sn hydride soln. in Et2O, resulting Bu3SnMgCl adding dropwise to orthoformate in Et2O, stirring for 3 h, hydrolyzing, org. phase sepg.; purified by distn. in vacuo; NMR, IR and mass spectra;A n/a
B <1
C 90%
tri-n-butyltin lithium
4226-01-1

tri-n-butyltin lithium

titanium dichloride bis(tert-butoxide)
17022-82-1

titanium dichloride bis(tert-butoxide)

A

titanium(IV) tetrabutoxide

titanium(IV) tetrabutoxide

B

Ti(OC(CH3)3)2(Sn(C4H9)3)2
131551-96-7

Ti(OC(CH3)3)2(Sn(C4H9)3)2

C

bis(tributylstannyl)titanium

bis(tributylstannyl)titanium

D

bis(tri-n-butyltin)
813-19-4

bis(tri-n-butyltin)

E

lithium chloride

lithium chloride

Conditions
ConditionsYield
In tetrahydrofuran; hexane Sn-compound in THF added to Ti-compound (-78°C) in hexane, temp. raised to room temp., soln. became dark-brown; solvent evapd. in vac., residue dissolved in pentane, filtered, pentane evapd. under vac., distd.; elem. anal.;A 80%
B 0%
C 37%
D 75%
E 90%
lithium aluminium tetrahydride
16853-85-3

lithium aluminium tetrahydride

tributyltin chloride
1461-22-9

tributyltin chloride

bis(tri-n-butyltin)
813-19-4

bis(tri-n-butyltin)

Conditions
ConditionsYield
dichloro bis(acetonitrile) palladium(II) In diethyl ether; water treatment stannic chloride with LiAlH4 (Et2O, 20°C, 4 h), addn. of water, addn. of catalyst, treatment (15 min);89%
dichloro bis(acetonitrile) palladium(II) In diethyl ether addn. of Bu3SnCl in ether to soln. of LiAlH4 in ether (stirring), stirring (20°C, 4 h), addn. of water, addn. of catalyst to intermediate (15 min); sepn. of org. layer (decantation), washing of residue (ether), drying of extract (over Na2SO4), removal of ether (vac.), extn. (pentane), chromy. (silica thin layer), removal of pentane, distn.;89%
vanadocene

vanadocene

tributyltin acetate
56-36-0

tributyltin acetate

A

{(η5-cyclopentadienyl)vanadium diacetate}2

{(η5-cyclopentadienyl)vanadium diacetate}2

B

bis(tri-n-butyltin)
813-19-4

bis(tri-n-butyltin)

C

cyclopenta-1,3-diene
542-92-7

cyclopenta-1,3-diene

Conditions
ConditionsYield
In neat (no solvent) molar ratio Cp2V/Sn-compound 1/2, sealed ampoule, 120°C, 16 h; elem. anal.;A 89%
B 10.07%
C 58.5%
tri-n-butyltin lithium
4226-01-1

tri-n-butyltin lithium

chloro(tristertbutoxy)titanium
5915-86-6

chloro(tristertbutoxy)titanium

A

titanium(IV) tetrabutoxide

titanium(IV) tetrabutoxide

B

bis(tri-n-butyltin)
813-19-4

bis(tri-n-butyltin)

Conditions
ConditionsYield
In tetrahydrofuran soln. of Sn-compound added to soln. of Ti-compound at -78°C, temp. increased to 20°C, mixt. became dark-brown; solvent evapd. in vac., residue dissolved in pentane, distd.;A 45%
B 88%
bis(trimethylsilyl)mercury
4656-04-6

bis(trimethylsilyl)mercury

tributyltin acetate
56-36-0

tributyltin acetate

bis(tri-n-butyltin)
813-19-4

bis(tri-n-butyltin)

Conditions
ConditionsYield
In benzene byproducts: (CH3)3SiOOCH3, Hg; at 25°C, 0.5 h;87%
In benzene byproducts: (CH3)3SiOOCH3, Hg; at 25°C, 0.5 h;87%
vanadocene

vanadocene

tributylstannyl isothiocyanate
5035-65-4

tributylstannyl isothiocyanate

A

vanadocene monoisothiocyanate

vanadocene monoisothiocyanate

B

bis(tri-n-butyltin)
813-19-4

bis(tri-n-butyltin)

Conditions
ConditionsYield
In hexane a mixture of the Sn compd. and the V compd. in hexane was held in an evacuated ampul for 48 h at 20°C; pptn., react. soln. contained 77% of (Sn(C4H9)3)2; elem. anal.;A 87%
B n/a
Ar, 20°C, 48 h.; Elem. anal.;A 87%
B 77%
vanadocene monoisothiocyanate

vanadocene monoisothiocyanate

tributylstannyl isothiocyanate
5035-65-4

tributylstannyl isothiocyanate

A

bis(η5-cyclopentadienyl)vanadium diisothiocyanate

bis(η5-cyclopentadienyl)vanadium diisothiocyanate

B

bis(tri-n-butyltin)
813-19-4

bis(tri-n-butyltin)

Conditions
ConditionsYield
In toluene mixt. heated in an evacuated sealed ampul at 150-180°C for 15h;A 80%
B 87%
bis(trimethylsilyl)mercury
4656-04-6

bis(trimethylsilyl)mercury

Bu3SnOSiMe3
17908-18-8

Bu3SnOSiMe3

A

Hexamethyldisiloxane
107-46-0

Hexamethyldisiloxane

B

bis(tri-n-butyltin)
813-19-4

bis(tri-n-butyltin)

C

mercury

mercury

Conditions
ConditionsYield
In benzene 80°C; 16 h;A 72%
B 76%
C 83.5%
In benzene 80°C; 16 h;A 72%
B 76%
C 83.5%
bis(tri-n-butyltin)oxide
56-35-9

bis(tri-n-butyltin)oxide

bis(tri-n-butyltin)
813-19-4

bis(tri-n-butyltin)

Conditions
ConditionsYield
With sodium tetrahydroborate In benzene stirring (2 h); H2O addn., extg. (CH2Cl2), drying (MgSO4), filtering, concg., distg. (vac.);83%
With potassium In toluene reaction with a stoich. amt. of potassium (2 mol for 1 mol of ditin oxide);71%
With titanium In tetrahydrofuran reaction with a freshly prepared titanium slurry;70%
vanadocene

vanadocene

(C4H9)3SnNHC6H4SO2NHSn(C4H9)3
206437-65-2

(C4H9)3SnNHC6H4SO2NHSn(C4H9)3

A

N-(η(5)-cyclopentadienylvanadio)-p-(η(5)-cyclopentadienylvanadioamino)benzenesulfonamide
206437-66-3

N-(η(5)-cyclopentadienylvanadio)-p-(η(5)-cyclopentadienylvanadioamino)benzenesulfonamide

B

bis(tri-n-butyltin)
813-19-4

bis(tri-n-butyltin)

Conditions
ConditionsYield
In toluene byproducts: cyclopentadiene; 120 to 130°C, 24-30 h, evacuated sealed ampule; black ppt. washing (toluene, vacuum), drying; elem. anal.;A 74%
B 82%
bis(tri-n-butyltin)oxide
56-35-9

bis(tri-n-butyltin)oxide

A

bis(tri-n-butyltin)
813-19-4

bis(tri-n-butyltin)

B

tetra-n-butyltin(IV)
1461-25-2

tetra-n-butyltin(IV)

Conditions
ConditionsYield
With magnesium In tetrahydrofuran a soln. of ditin oxide in dry THF was added dropwise to a suspn. of a magnesium powder, activated by BrCH2CH2Br or I2, in dry THF, mixt. was heated at reflux for 15 h; petroleum ether was added, filtered, solvents evapd., residue was distilled;A 81%
B 0%
With sodium In neat (no solvent) stoich. amt. of sodium (2 mol for 1 mol of ditin oxide), 120°C, 48 h; unreacted Bu6Sn2O was removed by filtration in pentane through a short SiO2 column, Bu4Sn was removed by distn.;A 71%
B 1-5
bromobenzene
108-86-1

bromobenzene

tributyltin chloride
1461-22-9

tributyltin chloride

A

bis(tri-n-butyltin)
813-19-4

bis(tri-n-butyltin)

B

tributylphenylstannane
960-16-7

tributylphenylstannane

Conditions
ConditionsYield
With magnesium; ethylene dibromide In tetrahydrofuran at 35℃; for 1h; Barbier Coupling Reaction; Sonication; Inert atmosphere;A n/a
B 78%
tributyltin formate
5847-51-8

tributyltin formate

A

tri-n-butyl-tin hydride
688-73-3

tri-n-butyl-tin hydride

B

bis(tri-n-butyltin)
813-19-4

bis(tri-n-butyltin)

C

tetra-n-butyltin(IV)
1461-25-2

tetra-n-butyltin(IV)

Conditions
ConditionsYield
heating 11.5 h at 150 to 185°C;A 6.9%
B 77.5%
C 5.2%
heating 11.5 h at 150 to 185°C;A 6.9%
B 77.5%
C 5.2%
In neat (no solvent) byproducts: CO2; heating for 11.5 h at 150-185°C under N2;;A 6.9%
B n/a
C n/a
n-Butyl chloride
109-69-3

n-Butyl chloride

tributyltin chloride
1461-22-9

tributyltin chloride

A

bis(tri-n-butyltin)
813-19-4

bis(tri-n-butyltin)

B

tetra-n-butyltin(IV)
1461-25-2

tetra-n-butyltin(IV)

Conditions
ConditionsYield
In tetrahydrofuran Electrolysis; electrolyte 0.4 M LiClO4 in THF; electrolysis carried out galvanostatically at 25-28°C in atm. of dry N2; hexane added to electrolyte, ppt. filtered off, filtrate analyzed for the products by GC;A 20%
B 76%
oct-1-ene
111-66-0

oct-1-ene

tri-n-butyl-tin hydride
688-73-3

tri-n-butyl-tin hydride

A

bis(tri-n-butyltin)
813-19-4

bis(tri-n-butyltin)

B

n-octyltriethyltin
16216-27-6

n-octyltriethyltin

Conditions
ConditionsYield
dimeric bis(tert-butylcyclopentadienyl)(μ-methyl) yttrium In benzene (Ar); stirring (room temp., 30 min); elem. anal.;A n/a
B 74%
vanadocene

vanadocene

tributyltin acetate
56-36-0

tributyltin acetate

bis(tri-n-butyltin)
813-19-4

bis(tri-n-butyltin)

Conditions
ConditionsYield
In neat (no solvent) byproducts: (C5H5V(OOCCH3)2)2, C5H5; in evacuated ampule, at 120 ° C, 16 h, without solvent;72%
In neat (no solvent) byproducts: (C5H5V(OOCCH3)2)2, C5H5; in evacuated ampule, at 120 ° C, 16 h, without solvent;72%
vanadocene monochloride

vanadocene monochloride

tributylstannyl isothiocyanate
5035-65-4

tributylstannyl isothiocyanate

A

bis(η5-cyclopentadienyl)vanadium diisothiocyanate

bis(η5-cyclopentadienyl)vanadium diisothiocyanate

B

tributyltin chloride
1461-22-9

tributyltin chloride

C

bis(tri-n-butyltin)
813-19-4

bis(tri-n-butyltin)

Conditions
ConditionsYield
In toluene molar ratio V-complex/Bu3SnNCS=1:2, evacuated sealed ampul (120°C, 2 h); collection (filtn.), washing (toluene), drying (vac.); elem. anal.;A 71%
B 65%
C 11%
vanadocene

vanadocene

tributylstannyl 4-(tributylstannylamino)benzenesulfonate
153627-98-6

tributylstannyl 4-(tributylstannylamino)benzenesulfonate

A

η(5)-cyclopentadienevanadio-p-(η(5)-cyclopentadienylvanadioamino)benzenesulfonate
206437-68-5

η(5)-cyclopentadienevanadio-p-(η(5)-cyclopentadienylvanadioamino)benzenesulfonate

B

bis(tri-n-butyltin)
813-19-4

bis(tri-n-butyltin)

Conditions
ConditionsYield
In toluene byproducts: cyclopentadiene; 160 to 170°C, 48 h, evacuated sealed ampule, double excess of V-compd.; black ppt. washing (hot THF), drying; elem. anal.;A 70%
B 60%
tributyltin formate
5847-51-8

tributyltin formate

bis(tri-n-butyltin)
813-19-4

bis(tri-n-butyltin)

Conditions
ConditionsYield
In hexane; N,N-dimethyl acetamide Electrolysis; hexane layer was placed for extn. of product; concn. of hexane layer in vac., column chromy. (silica gel, hexane);68%
In N,N-dimethyl acetamide Electrolysis;68%
m-iodobenzaldehyde
696-41-3

m-iodobenzaldehyde

bis(tri-n-butyltin)
813-19-4

bis(tri-n-butyltin)

3-(tri-n-butylstannyl)benzaldehyde

3-(tri-n-butylstannyl)benzaldehyde

Conditions
ConditionsYield
tetrakis(triphenylphosphine) palladium(0) In 1,4-dioxane for 3.5h; Heating / reflux;100%
succinic acid anhydride
108-30-5

succinic acid anhydride

bis(tri-n-butyltin)
813-19-4

bis(tri-n-butyltin)

bis(tributyltin)succinate
4644-96-6

bis(tributyltin)succinate

Conditions
ConditionsYield
In not given at 60°C;100%
iodobenzene
591-50-4

iodobenzene

bis(tri-n-butyltin)
813-19-4

bis(tri-n-butyltin)

tributylphenylstannane
960-16-7

tributylphenylstannane

Conditions
ConditionsYield
With palladium diacetate; tricyclohexylphosphine In neat (no solvent) at 110℃; under 760.051 Torr; for 24h; Sealed tube;99%
With dichloro bis(acetonitrile) palladium(II) In N,N,N,N,N,N-hexamethylphosphoric triamide at 20℃; for 2.33333h; Product distribution; other reagents, reaction time, reactants' ratio dependence; also with other R4Sn (R = Et);92 % Chromat.
bis(tri-n-butyltin)
813-19-4

bis(tri-n-butyltin)

methyl iodide
74-88-4

methyl iodide

methyltributyltin
1528-01-4

methyltributyltin

Conditions
ConditionsYield
Stage #1: bis(tri-n-butyltin) With naphthalene; lithium In tetrahydrofuran at 20℃; for 3h; Inert atmosphere;
Stage #2: methyl iodide In tetrahydrofuran at 20℃; for 1h; Reagent/catalyst; Inert atmosphere; Schlenk technique;
99%
With dichloro bis(acetonitrile) palladium(II) In N,N,N,N,N,N-hexamethylphosphoric triamide at 20℃; for 0.0833333h; Product distribution;98 % Chromat.
palladium (1,1,3,3-tetramethylbutyl isocyanide)2

palladium (1,1,3,3-tetramethylbutyl isocyanide)2

bis(tri-n-butyltin)
813-19-4

bis(tri-n-butyltin)

palladium (1,1,3,3-tetramethylbutyl isocyanide)2(SnBu3)2

palladium (1,1,3,3-tetramethylbutyl isocyanide)2(SnBu3)2

Conditions
ConditionsYield
In benzene 20°C, 1.5 h;99%
bromobenzene
108-86-1

bromobenzene

bis(tri-n-butyltin)
813-19-4

bis(tri-n-butyltin)

tributylphenylstannane
960-16-7

tributylphenylstannane

Conditions
ConditionsYield
With palladium diacetate; tricyclohexylphosphine In neat (no solvent) at 110℃; under 760.051 Torr; for 24h; Sealed tube;99%
tetrakis(triphenylphosphine) palladium(0) In toluene byproducts: Bu3SnBr, PhPh; heating at 80°C with stirring under Ar atm., reaction completed when color of the soln. changed to black; solvent evapd., biaryl filtered off after recrystn., filtrate washed with aq. KF, organic layer extd. with benzene, dried over sodium sulfate, product chromd.;89%
5-bromo-1H-indole
10075-50-0

5-bromo-1H-indole

bis(tri-n-butyltin)
813-19-4

bis(tri-n-butyltin)

5-(tributylstannyl)-1H-indole
143724-34-9

5-(tributylstannyl)-1H-indole

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); tricyclohexylphosphine In 1,4-dioxane at 110℃; for 3h; Reagent/catalyst; Inert atmosphere;99%
methyl propargyl alcohol
764-01-2

methyl propargyl alcohol

bis(tri-n-butyltin)
813-19-4

bis(tri-n-butyltin)

(2E)-3-methyl-3-tributylstannylprop-2-en-1-ol
121882-41-5, 124607-17-6, 850354-34-6

(2E)-3-methyl-3-tributylstannylprop-2-en-1-ol

Conditions
ConditionsYield
Stage #1: bis(tri-n-butyltin) With n-butyllithium; copper(l) cyanide In tetrahydrofuran; hexane at -78 - -40℃; for 0.583333h; Inert atmosphere;
Stage #2: methyl propargyl alcohol In tetrahydrofuran; methanol; hexane at -78 - -10℃; Inert atmosphere;
99%
With n-butyllithium; copper(l) cyanide In tetrahydrofuran; methanol at -78 - 20℃;99%
bis(tri-n-butyltin)
813-19-4

bis(tri-n-butyltin)

sodium 4-acetamidobenzenesulfinate
15898-43-8

sodium 4-acetamidobenzenesulfinate

N-(4-(tributylstannyl)phenyl)acetamide

N-(4-(tributylstannyl)phenyl)acetamide

Conditions
ConditionsYield
With bis(tri-t-butylphosphine)palladium(0); silver carbonate In N,N-dimethyl acetamide at 140℃; for 1h; Inert atmosphere;99%
methyl 6-iodo-5-methoxy-4-oxo-4H-chromene-2-carboxylate

methyl 6-iodo-5-methoxy-4-oxo-4H-chromene-2-carboxylate

bis(tri-n-butyltin)
813-19-4

bis(tri-n-butyltin)

methyl 5-methoxy-4-oxo-6-(tributylstannyl)-4H-chromene-2-carboxylate

methyl 5-methoxy-4-oxo-6-(tributylstannyl)-4H-chromene-2-carboxylate

Conditions
ConditionsYield
With lithium chloride; bis(dibenzylideneacetone)-palladium(0); tri tert-butylphosphoniumtetrafluoroborate In 1,4-dioxane at 50℃; for 4h; Inert atmosphere;99%
methyl propargyl alcohol
764-01-2

methyl propargyl alcohol

bis(tri-n-butyltin)
813-19-4

bis(tri-n-butyltin)

3-(tributylstannyl)but-2-en-1-ol
850354-34-6, 121882-41-5, 124607-17-6

3-(tributylstannyl)but-2-en-1-ol

Conditions
ConditionsYield
With n-butyllithium; copper(l) cyanide In tetrahydrofuran at -10℃; Inert atmosphere; regioselective reaction;99%
bis(tri-n-butyltin)
813-19-4

bis(tri-n-butyltin)

C15H22INO5

C15H22INO5

C27H49NO5Sn

C27H49NO5Sn

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); N-ethyl-N,N-diisopropylamine In isopropyl alcohol at 23℃;99%
bis(tri-n-butyltin)
813-19-4

bis(tri-n-butyltin)

A

tributyltin iodide
7342-47-4

tributyltin iodide

B

methyltributyltin
1528-01-4

methyltributyltin

Conditions
ConditionsYield
With methyl iodide; dichloro bis(acetonitrile) palladium(II) In N,N,N,N,N,N-hexamethylphosphoric triamide 20°C, molar ratio distannane/halide 1.3:1, 5 min;A n/a
B 98%
o-nitroiodobenzene
609-73-4

o-nitroiodobenzene

bis(tri-n-butyltin)
813-19-4

bis(tri-n-butyltin)

2-(tri-n-butylstannyl)-1-nitrobenzene
79062-30-9

2-(tri-n-butylstannyl)-1-nitrobenzene

Conditions
ConditionsYield
tetrakis(triphenylphosphine) palladium(0) In toluene byproducts: (C4H9)3SnI; soln. of Bu3SnSnBu3, Pd(PPh3)4, aryl iodide in toluene heated to 80°C for 72 h under Ar; evapd., washed with aq. KF, extd. (C6H6), dried over Na2SO4, chromd. (SiO2, hexane); elem. anal.;98%
With palladium diacetate; tricyclohexylphosphine In neat (no solvent) at 110℃; under 760.051 Torr; for 24h; Sealed tube;67%
bis(tri-n-butyltin)
813-19-4

bis(tri-n-butyltin)

sodium 3-chlorobenzenesulfinate
15946-37-9

sodium 3-chlorobenzenesulfinate

tributyl(3-chlorophenyl)stannane
24344-58-9

tributyl(3-chlorophenyl)stannane

Conditions
ConditionsYield
With bis(tri-t-butylphosphine)palladium(0); silver carbonate In N,N-dimethyl acetamide at 140℃; for 1h; Inert atmosphere;98%
n-butyllithium
109-72-8, 29786-93-4

n-butyllithium

(+)-(2S)-N-[cyclohex-2-en-1-yliden]-2-(methoxymethyl)pyrrolidin-1-amine
72170-87-7

(+)-(2S)-N-[cyclohex-2-en-1-yliden]-2-(methoxymethyl)pyrrolidin-1-amine

bis(tri-n-butyltin)
813-19-4

bis(tri-n-butyltin)

(S,S)-3-tributylstannylcyclohexanone-(S)-1-amino-2-methoxymethylpyrrolidine-hydrazone

(S,S)-3-tributylstannylcyclohexanone-(S)-1-amino-2-methoxymethylpyrrolidine-hydrazone

Conditions
ConditionsYield
With NH4Cl In tetrahydrofuran addn. of the distannane to n-BuLi in abs. THF, react. for 15 min, cooling to -100°C, warming within 3 h to -78°C, dropwise addn. of the pyrrolidine compd. and addn. of satd. NH4Cl; evapn., dissolving in Et2O, washing with H2O and satd. NaCl soln., drying (MgSO4), concn. and column chromy. (silica gel, petroleum ether-Et2O); de 42 %;97%
6-bromo-1H-indole
52415-29-9

6-bromo-1H-indole

bis(tri-n-butyltin)
813-19-4

bis(tri-n-butyltin)

6-(tributylstannyl)-1H-indole

6-(tributylstannyl)-1H-indole

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); tricyclohexylphosphine In 1,4-dioxane at 110℃; for 3h; Reagent/catalyst; Inert atmosphere;97%
para-bromotoluene
106-38-7

para-bromotoluene

bis(tri-n-butyltin)
813-19-4

bis(tri-n-butyltin)

A

tributyltin bromide
1461-23-0

tributyltin bromide

B

tributyl(p-tolyl)stannane
31614-66-1

tributyl(p-tolyl)stannane

Conditions
ConditionsYield
With palladium diacetate; tricyclohexylphosphine In neat (no solvent) at 110℃; under 760.051 Torr; for 24h; Sealed tube;A n/a
B 97%
sodium benzenesulfonate
873-55-2

sodium benzenesulfonate

bis(tri-n-butyltin)
813-19-4

bis(tri-n-butyltin)

tributylphenylstannane
960-16-7

tributylphenylstannane

Conditions
ConditionsYield
With bis(tri-tert-butylphosphine)palladium(0); silver carbonate In N,N-dimethyl acetamide at 140℃; for 1h; Temperature;97%
With bis(tri-t-butylphosphine)palladium(0); silver carbonate In N,N-dimethyl acetamide at 140℃; for 1h; Solvent; Temperature; Reagent/catalyst; Inert atmosphere;97%
bis(tri-n-butyltin)
813-19-4

bis(tri-n-butyltin)

sodium 4-methylbenzenesulfinate
824-79-3

sodium 4-methylbenzenesulfinate

tributyl(p-tolyl)stannane
31614-66-1

tributyl(p-tolyl)stannane

Conditions
ConditionsYield
With bis(tri-tert-butylphosphine)palladium(0); silver carbonate In N,N-dimethyl acetamide at 140℃; for 1h;97%
With bis(tri-t-butylphosphine)palladium(0); silver carbonate In N,N-dimethyl acetamide at 140℃; for 1h; Inert atmosphere;97%
iodobenzene
591-50-4

iodobenzene

bis(tri-n-butyltin)
813-19-4

bis(tri-n-butyltin)

A

biphenyl
92-52-4

biphenyl

B

tributylphenylstannane
960-16-7

tributylphenylstannane

Conditions
ConditionsYield
tetrakis(triphenylphosphine) palladium(0) In toluene byproducts: Bu3SnI; at 115°C for 15 h in sealed thick wall Pyrex glass ampoules;A 3.5%
B 96%
bis(triphenylphosphine)palladium dibromide In toluene byproducts: Bu3SnI; at 115°C for 15 h in sealed thick wall Pyrex glass ampoules;A 2%
B 94%
bis(tri-n-butyltin)
813-19-4

bis(tri-n-butyltin)

6-bromo-2-octyl-1H-benzo[de]isoquinoline-1,3(2H)-dione

6-bromo-2-octyl-1H-benzo[de]isoquinoline-1,3(2H)-dione

2-octyl-6-(tributylstannyl)-1H-benzo[de]isoquinoline-1,3(2H)-dione

2-octyl-6-(tributylstannyl)-1H-benzo[de]isoquinoline-1,3(2H)-dione

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0) In toluene for 96h; Reflux; Darkness; Inert atmosphere;96%
bis(tri-n-butyltin)
813-19-4

bis(tri-n-butyltin)

sodium 4-fluorobenzenesulfinate
824-80-6

sodium 4-fluorobenzenesulfinate

tributyl(4-fluorophenyl)stannane
17151-47-2

tributyl(4-fluorophenyl)stannane

Conditions
ConditionsYield
With bis(tri-tert-butylphosphine)palladium(0); silver carbonate In N,N-dimethyl acetamide at 140℃; for 1h;96%
With bis(tri-t-butylphosphine)palladium(0); silver carbonate In N,N-dimethyl acetamide at 140℃; for 1h; Inert atmosphere;96%
methyl 4-(6-iodo-5-methoxy-4-oxo-4H-chromen-2-yl)butanoate

methyl 4-(6-iodo-5-methoxy-4-oxo-4H-chromen-2-yl)butanoate

bis(tri-n-butyltin)
813-19-4

bis(tri-n-butyltin)

methyl 4-[5-methoxy-4-oxo-6-(tributylstannyl)-4H-chromen-2-yl]butanoate

methyl 4-[5-methoxy-4-oxo-6-(tributylstannyl)-4H-chromen-2-yl]butanoate

Conditions
ConditionsYield
With lithium chloride; bis(dibenzylideneacetone)-palladium(0); tri tert-butylphosphoniumtetrafluoroborate In 1,4-dioxane at 50℃; for 4h; Inert atmosphere;96%
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