1,1-DICHLOROPROPANE supplier

Name
1,1-Dichloropropane
EINECS
CAS No. 78-99-9
Density 1.13 g/mL at 25 °C(lit.)
Solubility
Melting Point
Formula C₃H₆Cl₂
Boiling Point 88 °C(lit.)
Molecular Weight 112.987
Flash Point 45 °F
Transport Information
Appearance
Safety Mildly toxic by ingestion, inhalation, and skin contact. An eye irritant. A very dangerous fire hazard when exposed to heat, flame, or oxidizers. When heated to decomposition it emits toxic fumes of Cl⁻. See also PROPYLENE DICHLORIDE; and CHLORINATED HYDROCARBONS, ALIPHATIC.
Risk Codes R20/21/22; R36/37/38; R40; R11
Molecular Structure
Hazard Symbols F,Xn
Synonyms Propane, 1,1-dichloro-;PROPYLIDENE CHLORIDE;propylidenchlorid;dichloro-1,1propane;1,1-Dichlorpropan;r270fb;Propylidene dichloride;dichloro acid ethyl ester;1,1-dichloro-propan;dichloropropane;propane,1,1-dichloro;1,1-dichloro-propane;
PSA 0.00000
LogP 2.20010

Synthetic route

: 74-98-6
propane

: 78-99-9
1,1-dichloropropane

Conditions

Conditions	Yield
at 400℃; bei der Chlorierung;

: 74-98-6
propane

A: 26198-63-0, 78-87-5
1,2-Dichloropropane

B: 594-20-7
2,2-dichloropropane

C: 78-99-9
1,1-dichloropropane

D: 142-28-9
1,3-Dichloropropane

Conditions

Conditions	Yield
at 400℃; Product distribution; thermische Chlorierung;
at 400℃; Product distribution; thermische Chlorierung;

...Expand

: 123-38-6
propionaldehyde

: 78-99-9
1,1-dichloropropane

Conditions

Conditions	Yield
With phosphorus pentachloride

: 590-21-6
propenyl chloride

: 78-99-9
1,1-dichloropropane

Conditions

Conditions	Yield
With hydrogenchloride; iron(III) chloride at 25℃; im Dunkeln;

: 75-27-4
bromodichloromethane

: 74-85-1
ethene

: 78-99-9
1,1-dichloropropane

Conditions

Conditions	Yield
Irradiation;

: 540-54-5
1-Chloropropane

A: 26198-63-0, 78-87-5
1,2-Dichloropropane

B: 78-99-9
1,1-dichloropropane

C: 142-28-9
1,3-Dichloropropane

Conditions

Conditions	Yield
With chlorine In 1,2-dichloro-benzene at 0℃; Product distribution; oth. temperatures;
With N-chloropiperidine; 2,2'-azobis(isobutyronitrile) In trifluoroacetic acid at 30℃; Product distribution; Rate constant; Irradiation; relative rate constants, position selectivity, substrate selectivity;
With chlorine In benzene at -10.1℃; Product distribution; dependence of the selectivity of chlorination on the conc. of benzene;
With sulfuryl dichloride; dibenzoyl peroxide
With chlorine Ambient temperature; Irradiation;

...Expand

: 123-38-6
propionaldehyde

A: 78-99-9
1,1-dichloropropane

B: 26551-86-0
N-chlorocarbonyl-carbonimidic acid dichloride

Conditions

Conditions	Yield
With iron(III) chloride; perchloro-2-aza-1-propene

: 540-54-5
1-Chloropropane

A: 78-99-9
1,1-dichloropropane

B 1,2-dichloro-propane and 1,3-dichloro-propane: 1,2-dichloro-propane and 1,3-dichloro-propane

Conditions

Conditions	Yield
With chlorine at 305℃;

: 74-98-6
propane

: 7782-50-5
chlorine

: 78-00-2
tetraethyllead(IV)

A: 540-54-5
1-Chloropropane

B: 75-29-6
isopropyl chloride

C: 78-99-9
1,1-dichloropropane

Conditions

Conditions	Yield
at 136 - 140℃; Product distribution;
at 136 - 140℃; Product distribution;

...Expand

: 74-98-6
propane

: 7782-50-5
chlorine

A: 540-54-5
1-Chloropropane

B: 78-99-9
1,1-dichloropropane

C: 7789-89-1
1,1,1-trichloropropane

D: 812-03-3
1,1,1,2-tetrachloropropane

Conditions

Conditions	Yield
at 360 - 395℃;

...Expand

: 74-98-6
propane

: 7782-50-5
chlorine

copper (II)-chloride /silicon dioxide: copper (II)-chloride /silicon dioxide

A: 540-54-5
1-Chloropropane

B: 78-99-9
1,1-dichloropropane

C: 7789-89-1
1,1,1-trichloropropane

D: 812-03-3
1,1,1,2-tetrachloropropane

Conditions

Conditions	Yield
at 230 - 347℃;

...Expand

: 74-98-6
propane

: 7782-50-5
chlorine

iron: iron

A: 540-54-5
1-Chloropropane

B: 78-99-9
1,1-dichloropropane

C: 7789-89-1
1,1,1-trichloropropane

D: 812-03-3
1,1,1,2-tetrachloropropane

Conditions

Conditions	Yield
at 230 - 347℃;

...Expand

: 540-54-5
1-Chloropropane

: 7782-50-5
chlorine

A: 26198-63-0, 78-87-5
1,2-Dichloropropane

B: 78-99-9
1,1-dichloropropane

C: 142-28-9
1,3-Dichloropropane

...Expand

: 78-99-9
1,1-dichloropropane

: 63721-05-1
methyl 3,3-dimethyl-4-penteneoate

: C11H20Cl2O2

Conditions

Conditions	Yield
With diacetyl peroxide at 80℃; for 6h; Inert atmosphere; Autoclave; Green chemistry;	98.1%

: 78-99-9
1,1-dichloropropane

: 106-53-6
para-bromobenzenethiol

: 1,1-di(4-bromophenylthio)propane

Conditions

Conditions	Yield
With 1,8-diazabicyclo[5.4.0]undec-7-ene at 150℃; for 0.333333h; microwave irradiation;	95%

: 78-99-9
1,1-dichloropropane

: Mo(N[((t)Bu)(3,5-C6H3Me2)])3

: tris[N-(tert-butyl)(3,5-dimethylphenyl)amido]molybdenum(VI) propylidyne

Conditions

Conditions	Yield
With Mg In tetrahydrofuran; pentane to soln. of Mo(N(t-Bu)(3,5-C6H3Me2))3 in THF added CH3CH2CHCl2 under Ar;mixt. stirred for 1.5 h at room temp. in presence of magnesium; solvent removed in vac. and residue redissolved in pentane; ppt. removed by filtration and filtrate concd. in vac.; elem. anal.;	91%
With magnesium In tetrahydrofuran at 20℃; for 2.58333h; Inert atmosphere;	54%
With magnesium In tetrahydrofuran treatment of Mo(N(t-Bu)C6H3Me3)3 with excess 1,1-dichlopropane (2 equiv.) in the presence of Mg in THF at room temp.;

: lithium aluminium

: 102301-10-0
(4S,5S)-Dimethyl 2-(2-chlorophenyl)-1,3-dioxolane-4,5-dicarboxylate

: 78-99-9
1,1-dichloropropane

: 102301-11-1
2-O-(2-chlorobenzyl)-D-threitol

Conditions

Conditions	Yield
With sodium hydroxide; aluminium trichloride In dichloro-1-propanol; water	81%

...Expand

: 78-99-9
1,1-dichloropropane

: 108-98-5
thiophenol

: 15486-58-5
1,1-bis(phenylthio)propane

Conditions

Conditions	Yield
With 1,8-diazabicyclo[5.4.0]undec-7-ene at 150℃; for 0.333333h; microwave irradiation;	79%

: 78-99-9
1,1-dichloropropane

: 1244-58-2
cannabidiolic acid

: 2-ethyl-7-hydroxy-8-((1R,6R)-3-methyl-6-(prop-1-en-2-yl)cyclohex-2-en-1-yl)-5-pentyl-4H-benzo[d][1,3]dioxin-4-one

Conditions

Conditions	Yield
With potassium phosphate In N,N-dimethyl-formamide at 130℃; for 4h; Sealed tube;	23%

: 23978-85-0
tetrahydrocannabinolic acid

: 78-99-9
1,1-dichloropropane

: (8aR,12aR)-2-ethyl-8,8,11-trimethyl-5-pentyl-8a,9,10,12a-tetrahydro-4H,8H-benzo[c][1,3]dioxino[4,5-f]chromen-4-one

Conditions

Conditions	Yield
With potassium phosphate In N,N-dimethyl-formamide at 130℃; for 4h; Sealed tube;	7%

: 26198-63-0, 78-87-5
1,2-Dichloropropane

: 594-20-7
2,2-dichloropropane

: 78-99-9
1,1-dichloropropane

: 594-90-1
octachloropropane

Conditions

Conditions	Yield
durch Einleiten von Chlor unter Belichtung und allmaehlicher Erhoehung der Reaktionstemperatur auf 200grad;

...Expand

: 78-99-9
1,1-dichloropropane

: 74-98-6
propane

Conditions

Conditions	Yield
With alkali metalammonium; ammonia

: 78-99-9
1,1-dichloropropane

: 430-61-5
propylidene difluoride

Conditions

Conditions	Yield
With hydrogen fluoride; mercury(II) oxide
With pyridine; hydrogen fluoride; mercury(II) oxide

: 78-99-9
1,1-dichloropropane

: 430-55-7
1-chloro-1-fluoro-propane

Conditions

Conditions	Yield
With hydrogen fluoride; mercury(II) oxide

: 78-99-9
1,1-dichloropropane

: 598-77-6
1,1,2-trichloropropane

Conditions

Conditions	Yield
With chlorine im Sonnenlichte;
With chlorine
With antimonypentachloride

: 78-99-9
1,1-dichloropropane

: 590-21-6
propenyl chloride

Conditions

Conditions	Yield
at 100℃; alkoh.Kali;

: 78-99-9
1,1-dichloropropane

: 85925-71-9
1-bromo-2,2-dichloropropane

Conditions

Conditions	Yield
With N-Bromosuccinimide In dichloromethane at 15℃; Irradiation; competition reaction with neopentane and tert-butyl chloride; relative rate constants for mediated brominations; additives - Br2, CH2CCl2, BrCCl3;

: 78-99-9
1,1-dichloropropane

A: 16136-85-9
trans-1-Chloropropen

B: 26198-63-0, 78-87-5
1,2-Dichloropropane

C: 16136-84-8
cis-1-chloropropene

D: 107-05-1
3-chloroprop-1-ene

Conditions

Conditions	Yield
With potassium chloride; sodium chloride; zinc(II) chloride at 400℃; for 0.5h; Product distribution; other gem-dichloroalkanes; var. molten salt catalysts; var. temps.;	A 8.8 % Chromat. B 12.8 % Chromat. C 19.4 % Chromat. D 3.0 % Chromat.

...Expand

: 695-56-7
1,4-dioxaspiro[4.4]non-6-ene

: 78-99-9
1,1-dichloropropane

: 6-Chlor-6-ethylbicyclo<3.1.0>hexan-2-on-ethylenacetal

Conditions

Conditions	Yield
With n-butyllithium In hexane; pentane 1.) -40 - -30 deg C; 2.) -30 deg C to -10 deg C, 3 h;	1.06 g

: 78-99-9
1,1-dichloropropane

: 7732-18-5
water

iron: iron

: 7647-01-0
hydrogenchloride

Conditions

Conditions	Yield
Geschwindigkeit;

...Expand

: 78-99-9
1,1-dichloropropane

NaHCO3: NaHCO3

: 7647-01-0
hydrogenchloride

Conditions

Conditions	Yield
Geschwindigkeit;

: 78-99-9
1,1-dichloropropane

: 7664-41-7
ammonia

alkali metalammonium: alkali metalammonium

: 74-98-6
propane

...Expand

: 78-99-9
1,1-dichloropropane

: 7664-39-3
hydrogen fluoride

mercury (II)-oxide: mercury (II)-oxide

: 430-61-5
propylidene difluoride

...Expand

: 78-99-9
1,1-dichloropropane

: 7664-39-3
hydrogen fluoride

mercury (II)-oxide: mercury (II)-oxide

: 430-55-7
1-chloro-1-fluoro-propane

...Expand

1,1-DICHLOROPROPANE Chemical Properties

IUPAC Name: 1,1-Dichloropropane
The MF of 1,1-Dichloropropane (78-99-9) is C₃H₆Cl₂.

The MW of 1,1-Dichloropropane (78-99-9) is 112.99.
Synonyms of 1,1-Dichloropropane (78-99-9): Dichloropropane ; 1,1-Dichloropropane ; alpha,alpha-Dichloropropane ; alpha,alpha-Propylene dichloride ; Propane, 1,1-dichloro- ; Propylidene chloride
Product Categories: Alkyl;Halogenated Hydrocarbons;Organic Building Blocks
Form: Colorless watery liquid with a sweet odor
Index of Refraction: 1.419
EINECS: 201-165-3
Density: 1.116 g/ml
Flash Point: 7.2 °C
Boiling Point: 85.2 °C
Merck: 13,7953

1,1-DICHLOROPROPANE Production

Halogenated aliphatic compounds, such as 1,1-DICHLOROPROPANE, are moderately or very reactive. Reactivity generally decreases with increased degree of substitution of halogen for hydrogen atoms. Low molecular weight haloalkanes are highly flammable and can react with some metals to form dangerous products. Materials in this group are incompatible with strong oxidizing and reducing agents. Also, they are incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides.

1,1-DICHLOROPROPANE Toxicity Data With Reference

1.	eye-rbt 500 mg	AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. 10 (1954),61.
2.	eye-rbt 500 mg open	AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. 10 (1954),61.
3.	orl-rat LD50:6500 mg/kg	AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. 10 (1954),61.
4.	ihl-rat LCLo:4000 ppm/4H	AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. 10 (1954),61.
5.	skn-rbt LD50:14 g/kg	AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. 10 (1954),61.

1,1-DICHLOROPROPANE Safety Profile

Mildly toxic by ingestion, inhalation, and skin contact. An eye irritant. A very dangerous fire hazard when exposed to heat, flame, or oxidizers. When heated to decomposition it emits toxic fumes of Cl⁻. See also PROPYLENE DICHLORIDE; and CHLORINATED HYDROCARBONS, ALIPHATIC.Safety information of 1,1-Dichloropropane (78-99-9):
Hazard Codes F,Xn
Risk Statements
20/21/22 Harmful by inhalation, in contact with skin and if swallowed
36/37/38 Irritating to eyes, respiratory system and skin
40 Limited evidence of a carcinogenic effect
11 Highly Flammable
Safety Statements
16 Keep away from sources of ignition - No smoking
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36/37/39 Wear suitable protective clothing, gloves and eye/face protection
45 In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
RIDADR UN 1993 3/PG 2
WGK Germany 3
RTECS TX9450000
HazardClass 3.1
PackingGroup II

Product Name

1,1-Dichloropropane

Synthetic route

1,1-DICHLOROPROPANE Chemical Properties

1,1-DICHLOROPROPANE Production

1,1-DICHLOROPROPANE Toxicity Data With Reference

1,1-DICHLOROPROPANE Safety Profile

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