1,2-Epoxy-4-vinylcyclohexane supplier

Name
1,2-Epoxy-4-vinylcyclohexane
EINECS 203-436-1
CAS No. 106-86-5
Article Data52
CAS DataBase
Density 1.06 g/cm³
Solubility
Melting Point -100oC
Formula C₈H₁₂O
Boiling Point 169 °C at 760 mmHg
Molecular Weight 124.183
Flash Point 48.1 °C
Transport Information UN 3271 3/PG 3
Appearance Transparent Liquid
Safety 53-16-23-36/37/39-45
Risk Codes 45-10-20/21/22
Molecular Structure
Hazard Symbols T
Synonyms Epoxide 101;NSC 35409;Unoxat epoxide 101;Vinyl-3,4-epoxycyclohexane;7-Oxabicyclo[4.1.0]heptane,3-vinyl- (6CI,8CI);Cyclohexane, 1,2-epoxy-4-vinyl- (7CI);7-Oxabicyclo[4.1.0]heptane,3-ethenyl-;1-Ethenyl-3-cyclohexene oxide;1-Vinyl-3,4-epoxycyclohexane;3,4-Epoxycyclohexylethylene;3-Ethenyl-7-oxabicyclo[4.1.0]heptane;3-Vinyl-7-oxabicyclo[4.1.0]heptane;4-Vinyl-1-cyclohexene-1,2-epoxide;4-Vinylcyclohexane 1,2-epoxide;4-Vinylcyclohexane-1-oxide;4-Vinylcyclohexene monoepoxide;4-Vinylcyclohexeneoxide;Cyracure VCMX-C;
PSA 12.53000
LogP 1.73990

Synthetic route

: 100-40-3
4-ethenylcyclohexene

: 106-86-5
1,2-Epoxy-4-vinylcyclohexane

Conditions

Conditions	Yield
With [(C18H37)2(CH3)2N]3[SiO4H(WO5)3]; dihydrogen peroxide In ethyl acetate at 59.84℃; for 2h; Green chemistry;	99%
With tert.-butylhydroperoxide at 79.84℃; Reagent/catalyst; Temperature; Green chemistry;	95%
With 3-chloro-benzenecarboperoxoic acid In benzene at 20℃; for 0.5h;	94%

: 632-21-3
1,1,3,3-tetrachloropropanone

: 100-40-3
4-ethenylcyclohexene

A: 106-87-6
4-vinylcyclohexene dioxide

B: 106-86-5
1,2-Epoxy-4-vinylcyclohexane

C: 5116-65-4
7,8-Epoxy-1-Cyclohexene

D: 78950-58-0
tetrachloroacetone hydrate

Conditions

Conditions	Yield
With disodium hydrogenphosphate; dihydrogen peroxide In chloroform for 24h; Ambient temperature;	A 2% B 60% C 2.5% D n/a
With disodium hydrogenphosphate; dihydrogen peroxide In chloroform for 24h; Ambient temperature;	A 2% B 60% C 1.5% D n/a

...Expand

: 100-40-3
4-ethenylcyclohexene

A: 106-86-5
1,2-Epoxy-4-vinylcyclohexane

B: 31646-64-7
3,4-dihydroxy-1-vinylcyclohexane

Conditions

Conditions	Yield
With dihydrogen peroxide; magnesium sulfate; methyltrioxorhenium(VII) In tert-butyl alcohol at 15℃; for 2h;	A 50% B 40%
With dihydrogen peroxide; magnesium sulfate; methyltrioxorhenium(VII) In tert-butyl alcohol at 15℃; for 2h;	A 40% B 50%
With dihydrogen peroxide; acetic acid In water at 70℃; for 4h; Temperature;

: 79-21-0
peracetic acid

: 100-40-3
4-ethenylcyclohexene

: 106-86-5
1,2-Epoxy-4-vinylcyclohexane

: 100-40-3
4-ethenylcyclohexene

A: 106-87-6
4-vinylcyclohexene dioxide

B: 106-86-5
1,2-Epoxy-4-vinylcyclohexane

C: 5116-65-4
7,8-Epoxy-1-Cyclohexene

Conditions

Conditions	Yield
With dimethylammonium tetrakis(diperoxotungsto)phosphate; dihydrogen peroxide In benzene at 60℃; for 1h;	A 3 % Chromat. B 83 % Chromat. C 2 % Chromat.
With dihydrogen peroxide; cetylpyridinium bromide; H3PMo10W2O40 In acetonitrile at 60℃; for 3h; Product distribution; Further Variations:; Catalysts; Solvents; Temperatures;

...Expand

: 100-40-3
4-ethenylcyclohexene

A: 106-86-5
1,2-Epoxy-4-vinylcyclohexane

B: 5116-65-4
7,8-Epoxy-1-Cyclohexene

C: 31646-64-7
3,4-dihydroxy-1-vinylcyclohexane

Conditions

Conditions	Yield
With [π-C5H5N(+)(CH2)15CH3]3(PMo12O40)(3-); dihydrogen peroxide; magnesium sulfate In chloroform at 60℃; for 24h; Yield given. Yields of byproduct given;

...Expand

: 100-40-3
4-ethenylcyclohexene

A: 106-86-5
1,2-Epoxy-4-vinylcyclohexane

B: 5537-04-2
4-Vinylcyclohex-1-en-4-ol

: 88301-28-4
trans-4-Vinylcyclohex-1-en-3-ol

: 64248-92-6, 81457-32-1, 88301-27-3
trans-4-Vinylcyclohex-1-en-6-ol

: 64248-92-6, 81457-32-1, 88301-27-3
cis-4-Vinylcyclohex-1-en-6-ol

: 88301-29-5, 88301-30-8
cis-3-Vinylcyclohex-1-en-6-ol

Conditions

Conditions	Yield
With oxygen; sodium sulfite Product distribution; multistep reaction: 1) 80 deg C, 15 h, 101.3 kPa;	A 0.6 % Chromat. B 15.2 % Chromat. C 15.1 % Chromat. D 22.6 % Chromat. E 45.0 % Chromat. F n/a

...Expand

: 100-40-3
4-ethenylcyclohexene

A: 106-86-5
1,2-Epoxy-4-vinylcyclohexane

: 24779-55-3
trans-3-Hydroperoxy-4-vinylcyclohex-1-en

: 24779-57-5
cis-6-Hydroperoxy-3-vinylcyclohex-1-en

D: 3736-26-3
4-Hydroperoxy-4-vinylcyclohex-1-en

: 24779-56-4
trans-6-Hydroperoxy-4-vinylcyclohex-1-en

: 24779-56-4
cis-6-Hydroperoxy-4-vinylcyclohex-1-en

Conditions

Conditions	Yield
With oxygen at 80℃; under 759.8 Torr; for 15h; Product distribution; autoxidation;	A 4 % Chromat. B 13 % Chromat. C 6 % Chromat. D 13 % Chromat. E 18 % Chromat. F 45 % Chromat.

...Expand

: 100-40-3
4-ethenylcyclohexene

: 64-19-7
acetic acid

A: 106-86-5
1,2-Epoxy-4-vinylcyclohexane

B: 31646-64-7
3,4-dihydroxy-1-vinylcyclohexane

C: 4-vinylcyclohexanediol-1,2 monoacetate

Conditions

Conditions	Yield
With MoOBr3; dihydrogen peroxide at 70℃; for 6h; Product distribution; other cyclohexene derivatives; other molybdenum complexes;

...Expand

: 100-40-3
4-ethenylcyclohexene

A: 106-87-6
4-vinylcyclohexene dioxide

B: 106-86-5
1,2-Epoxy-4-vinylcyclohexane

Conditions

Conditions	Yield
With tert.-butylhydroperoxide; silica gel; molybdenum trioxide In decane at 50℃; for 12h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
With air; bis(hexafluoroacetylacetonato)cobalt; isobutyraldehyde In 1,2-dichloro-ethane at 20℃; under 7600 Torr; for 24h; Product distribution; Further Variations:; Reagents; Pressures;	A 20 % Chromat. B 80 % Chromat.
With air; bis(hexafluoroacetylacetonato)cobalt; isobutyraldehyde In 1,2-dichloro-ethane at 20℃; under 7600 Torr; for 24h;	A 20 % Chromat. B 80 % Chromat.
With [Mn(CF3SO3)2(H,MePyTACN)]; dihydrogen peroxide; acetic acid In acetonitrile at 0℃; for 1.5h; chemoselective reaction;

(+-)-4-vinyl-hexene: (+-)-4-vinyl-hexene

: 106-86-5
1,2-Epoxy-4-vinylcyclohexane

Conditions

Conditions	Yield
With Perbenzoic acid; chloroform

: 100-40-3
4-ethenylcyclohexene

A: 106-86-5
1,2-Epoxy-4-vinylcyclohexane

B: 5116-65-4
7,8-Epoxy-1-Cyclohexene

Conditions

Conditions	Yield
With dihydrogen peroxide; TBA-[γ-SiW10O34(H2O)2]4- In acetonitrile at 31.85℃; for 4h; Product distribution; Further Variations:; Catalysts; Reagents;	A 94 % Chromat. B 4 % Chromat.
With peracetic acid; Mn3(2-pyridinal-1-phenylethylimine)2(OAc)6 In acetonitrile at 25℃; for 0.3h; Title compound not separated from byproducts;
With dihydrogen peroxide; teterabutylammonium In acetonitrile at 31.85℃; for 4h;
With iodosylbenzene; iron(III) tetraphenylporphyrin In dichloromethane at 25℃; for 0.5h; Product distribution; Further Variations:; Catalysts;

: 67-56-1
methanol

: 100-40-3
4-ethenylcyclohexene

A: 106-87-6
4-vinylcyclohexene dioxide

B: 106-86-5
1,2-Epoxy-4-vinylcyclohexane

C: 5116-65-4
7,8-Epoxy-1-Cyclohexene

D: 24480-99-7
cyclohex-3-enyl acetaldehyde

E: 7353-76-6, 62393-63-9, 84049-10-5, 109583-33-7
3-cyclohexenyl-2-ethanone

F: 2-Methoxy-5-vinyl-cyclohexanol

G: 1243451-21-9
C9H16O2

Conditions

Conditions	Yield
With dihydrogen peroxide In water at 64.84℃; for 2h; regioselective reaction;

...Expand

: 100-40-3
4-ethenylcyclohexene

A: 106-86-5
1,2-Epoxy-4-vinylcyclohexane

B: 100-52-7
benzaldehyde

Conditions

Conditions	Yield
With [bis(acetoxy)iodo]benzene; 2BF4(1-)*C30H32N8O3Ru(2+) In dichloromethane at 20℃; for 24h; Inert atmosphere; Darkness; regioselective reaction;

: 67-56-1
methanol

: 100-40-3
4-ethenylcyclohexene

A: 106-87-6
4-vinylcyclohexene dioxide

B: 106-86-5
1,2-Epoxy-4-vinylcyclohexane

C: 5116-65-4
7,8-Epoxy-1-Cyclohexene

D: 2-Methoxy-5-vinyl-cyclohexanol

E: 1243451-21-9
C9H16O2

F: 100-50-5
3-Cyclohexene-1-carboxaldehyde

Conditions

Conditions	Yield
With dihydrogen peroxide In water at 65℃; for 1.5h;

...Expand

: 106-86-5
1,2-Epoxy-4-vinylcyclohexane

: 154455-22-8
1,1,3,3-tetramethyl-1-(2-trimethylsilanylethyl)disiloxane

: 1400684-08-3
3-{2-[1,1,3,3-tetramethyl-3-(2-trimethylsilanylethyl)disiloxanyl]ethyl}-7-oxabicyclo[4.1.0]heptane

Conditions

Conditions	Yield
With buffer; Karstedt's catalyst In toluene at 80 - 90℃;	100%
With dihydrogen hexachloroplatinate at 75 - 85℃; for 2h;

: 106-86-5
1,2-Epoxy-4-vinylcyclohexane

: 998-30-1
Triethoxysilane

: 10217-34-2
(2-(7-oxabicyclo[4.1.0]heptan-3-yl)ethyl)triethoxysilane

Conditions

Conditions	Yield
With platinum-containing olefin organic polymer catalyst at 25℃; for 3h;	99%
With (TFAPDI)Co(2-ethylhexanoate)2 In neat (no solvent) at 23℃; for 1h;	96%
With (1-mesityl-3-methylimidazol-2-ylidene)Co(N(SiMe3)2)2 In neat (no solvent) at 20℃; for 8h; Inert atmosphere; Glovebox; chemoselective reaction;	94%
With graphene nanoplates-supported platinum nanoparticles In neat (no solvent) at 80℃; for 2h; Catalytic behavior;	92%

: 106-86-5
1,2-Epoxy-4-vinylcyclohexane

: 1873-88-7
1,1,1,3,5,5,5-heptamethyltrisiloxan

: 3-(2-(7-oxabicyclo[4.1.0]heptan-3-yl)ethyl)-1,1,1,3,5,5,5-heptamethyltrisiloxane

Conditions

Conditions	Yield
With graphene nanoplates-supported platinum nanoparticles In neat (no solvent) at 80℃; for 2h; Catalytic behavior;	98%
With dihydrogen hexachloroplatinate at 75 - 85℃; for 2h;	96%
With dihydrogen hexachloroplatinate at 75 - 85℃;	96%

: 106-86-5
1,2-Epoxy-4-vinylcyclohexane

poly(methylhydrosiloxane): poly(methylhydrosiloxane)

poly[methyl(4-ethylcyclohexyl-1,2-epoxide)]siloxane: poly[methyl(4-ethylcyclohexyl-1,2-epoxide)]siloxane

Conditions

Conditions	Yield
With platinum In benzene at 20℃; for 34h;	98%

: 106-86-5
1,2-Epoxy-4-vinylcyclohexane

: 3277-26-7
1,1,3,3-Tetramethyldisiloxane

: C12H26O2Si2

Conditions

Conditions	Yield
With chloro(1,5-cyclooctadiene)rhodium(I) dimer In neat (no solvent) at 50℃; for 2h;	98%

: 106-86-5
1,2-Epoxy-4-vinylcyclohexane

: 3277-26-7
1,1,3,3-Tetramethyldisiloxane

: 18724-32-8
1,3-bis(2(3,4-epoxycyclohexyl)ethyl)-1,1,3,3-tetramethyldisiloxane

Conditions

Conditions	Yield
In ethanol; toluene at 65℃; for 0.333333h; Temperature; Solvent; Reagent/catalyst; Inert atmosphere; Molecular sieve; Microwave irradiation;	97.8%
In tetrahydrofuran; ethanol at 75℃; for 4h; Reagent/catalyst; Temperature; Solvent; Molecular sieve; Inert atmosphere;	96.9%
2C8H18S3Cl(1-)Rh(3+) In ethanol; hexane at 82℃; for 3h; Heating / reflux;

: 106-86-5
1,2-Epoxy-4-vinylcyclohexane

: 1000-05-1
1,1,3,3,5,5,7,7-octamethyltetrasiloxane

: 151110-81-5
(1,7-bis(1,2-epoxycyclohexyl-4-ethyl))-1,1,3,3,5,5,7,7-octamethyltetrasiloxane

Conditions

Conditions	Yield
polymer-bound Wilkinson's catalyst In toluene at 100 - 115℃; for 48h; Heating / reflux;	96%

: 106-86-5
1,2-Epoxy-4-vinylcyclohexane

: 31646-64-7
3,4-dihydroxy-1-vinylcyclohexane

Conditions

Conditions	Yield
With water at 20℃; for 5h; Conversion of starting material;	95%
With water; Amberlyst 15 resin at 20℃; for 24h; Conversion of starting material;	95%
With sulfuric acid In water at 20℃;	85%

: 106-86-5
1,2-Epoxy-4-vinylcyclohexane

: 881829-77-2
1-dimethylsiloxy-3,5,7,9,11,13,15-heptakis(trimethylsiloxy)pentacyclo[9.5.1.1(3,9).1(5,15).1(7,13)]-octasiloxane

: 1-[2-(3,4-epoxycyclohexyl)ethyl]dimethylsiloxy-3,5,7,9,11,13,15-heptakis(trimethylsiloxy)-pentacyclo[9.5.1.1(3,9).1(5,15).1(7,13)]octasiloxane

Conditions

Conditions	Yield
1,3-di(η2-vinyl)-1.1.3.3-tetramethyldisiloxane platinum(0) In toluene at 20℃; for 2h;	95%

: 106-86-5
1,2-Epoxy-4-vinylcyclohexane

: C26H68OSi7

: C50H104O4Si7

Conditions

Conditions	Yield
With platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex In toluene at 40℃; for 12h; Schlenk technique;	95%

: 106-86-5
1,2-Epoxy-4-vinylcyclohexane

: ethylcyclohexene oxide

Conditions

Conditions	Yield
With 2,6-bis[1-(2,6-diisopropylphenylimino)ethyl]pyridine cobalt(II) dichloride; diethoxymethylane; sodium triethylborohydride In toluene at -78 - 20℃; for 5h;	95%

: 106-86-5
1,2-Epoxy-4-vinylcyclohexane

: 18033-75-5
dimethylmethoxysilane

: (2-(7-oxabicyclo[4.1.0]heptan-3-yl)ethyl)dimethylsilane

Conditions

Conditions	Yield
With C24H30ClN3NiO2; sodium t-butanolate In tetrahydrofuran at 20℃; for 6h; Inert atmosphere; Glovebox;	93%

: 106-86-5
1,2-Epoxy-4-vinylcyclohexane

: 4-vinylcyclohex-1-ene sulfide

Conditions

Conditions	Yield
With aluminum oxide; thiourea In water at 25℃; for 2h; Inert atmosphere;	93%

: 106-86-5
1,2-Epoxy-4-vinylcyclohexane

: 98-54-4
para-tert-butylphenol

: C18H26O2

Conditions

Conditions	Yield
With potassium hydroxide In toluene at 20 - 105℃; for 18h; Reagent/catalyst; Temperature; Solvent;	93%

: 106-86-5
1,2-Epoxy-4-vinylcyclohexane

: 1-dimethylosiloxy-3,5,7,9,11,13,15-heptacyclohexylpentacyclo[9.5.113,9.15,15.17,13]octasiloxane

: C38H82O14Si9

Conditions

Conditions	Yield
With platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex In 5,5-dimethyl-1,3-cyclohexadiene; toluene at 90℃; for 3h;	92%

: 106-86-5
1,2-Epoxy-4-vinylcyclohexane

: 789-25-3
HSiPh3

: C26H28OSi

Conditions

Conditions	Yield
With C77H70N2OPtSi2 In toluene at 80℃; for 24h; Catalytic behavior; Reagent/catalyst; Inert atmosphere; Sealed tube; regioselective reaction;	91%

: 106-86-5
1,2-Epoxy-4-vinylcyclohexane

: 3-methacryloxypropyltrichlorosilane

: 2487-90-3
trimethoxysilane

: 3388-04-3
trimethoxy[2-(7-oxabicyclo[4.1.0]-hept-3-yl)ethyl]silane

Conditions

Conditions	Yield
chloroplatinic acid	90%

...Expand

: 106-86-5
1,2-Epoxy-4-vinylcyclohexane

: 124-38-9
carbon dioxide

: 5-vinylhexahydrobenzo[d][1,3]dioxol-2-one

Conditions

Conditions	Yield
With tetrabutylammomium bromide In neat (no solvent) at 100℃; for 18h; chemoselective reaction;	90%
In neat (no solvent) at 90℃; under 3750.38 Torr; for 24h; Autoclave;	83%
With C37H41FeN6O2(1+)*I(1-); bis(triphenylphosphine)iminium chloride In neat (no solvent) at 80℃; under 3750.38 Torr; for 24h; Autoclave;	76%

: 106-86-5
1,2-Epoxy-4-vinylcyclohexane

: 124-38-9
carbon dioxide

: cis-5-vinylhexahydrobenzo[d][1,3]dioxol-2-one

Conditions

Conditions	Yield
With C20H13FeN2O5; tetrabutylammomium bromide at 100℃; under 3750.38 - 7500.75 Torr; for 18h; Sealed tube;	90%

: 106-86-5
1,2-Epoxy-4-vinylcyclohexane

: 97-53-0
4-allylguaiacol

: octakis(dimethylsiloxy)octasilsesquioxane

: C88H152O32Si16

Conditions

Conditions	Yield
Stage #1: 4-allylguaiacol; octakis(dimethylsiloxy)octasilsesquioxane With bis(1,5-cyclooctadiene)diiridium(I) dichloride; Karstedt's catalyst In toluene at 90℃; Stage #2: 1,2-Epoxy-4-vinylcyclohexane In toluene at 90℃;	89%

...Expand

: 106-86-5
1,2-Epoxy-4-vinylcyclohexane

: 775-12-2
diphenylsilane

: 2-(7-oxabicyclo[4.1.0]heptan-3-yl)ethyldiphenylsilane

Conditions

Conditions	Yield
With [(N(C6H4N(CH3)2)2)Ni(OCH3)] In tetrahydrofuran at 20℃; for 6h; Inert atmosphere; Glovebox; Sealed tube; chemoselective reaction;	88%
Stage #1: 1,2-Epoxy-4-vinylcyclohexane; diphenylsilane With bis(acetylacetonate)nickel(II) In tetrahydrofuran at 20℃; for 0.0166667h; Inert atmosphere; Stage #2: With sodium triethylborohydride In tetrahydrofuran at 20℃; for 4h; Inert atmosphere;	83%
With sodium methylate In tetrahydrofuran Heating;	76%

: 106-86-5
1,2-Epoxy-4-vinylcyclohexane

: 78-08-0
Triethoxyvinylsilane

: octakis(dimethylsiloxy)octasilsesquioxane

: C80H176O36Si20

Conditions

Conditions	Yield
Stage #1: 1,2-Epoxy-4-vinylcyclohexane; octakis(dimethylsiloxy)octasilsesquioxane With bis(1,5-cyclooctadiene)diiridium(I) dichloride; Karstedt's catalyst In toluene at 90℃; Stage #2: Triethoxyvinylsilane In toluene at 90℃;	88%

...Expand

: 106-86-5
1,2-Epoxy-4-vinylcyclohexane

: 111-81-9
Methyl 10-undecenoate

: octakis(dimethylsiloxy)octasilsesquioxane

: C96H192O32Si16

Conditions

Conditions	Yield
Stage #1: Methyl 10-undecenoate; octakis(dimethylsiloxy)octasilsesquioxane With bis(1,5-cyclooctadiene)diiridium(I) dichloride; Karstedt's catalyst In toluene at 90℃; Stage #2: 1,2-Epoxy-4-vinylcyclohexane In toluene at 90℃;	87%

...Expand

: 106-86-5
1,2-Epoxy-4-vinylcyclohexane

: 694-53-1
phenylsilane

: (2-(7-oxabicyclo[4.1.0]heptan-3-yl)ethyl)(phenyl)silane

Conditions

Conditions	Yield
With nickel(II) chloride hexahydrate; potassium tert-butylate In tetrahydrofuran at -30℃; for 1h; Schlenk technique; Inert atmosphere; Sealed tube;	87%

: 106-86-5
1,2-Epoxy-4-vinylcyclohexane

: 591-50-4
iodobenzene

: C14H18O

Conditions

Conditions	Yield
With potassium phosphate; tris-(dibenzylideneacetone)dipalladium(0); tetramethylammonium formiate; triphenylphosphine In water; N,N-dimethyl-formamide at 80℃; for 4h; Heck Reaction; regioselective reaction;	86%

: 106-86-5
1,2-Epoxy-4-vinylcyclohexane

: 124-38-9
carbon dioxide

: cis-5-vinylhexahydrobenzo[d][1,3]dioxol-2-one

Conditions

Conditions	Yield
With C21H12Cl6NO4V; tetrabutylammomium bromide In neat (no solvent) at 85℃; under 7500.75 Torr; for 18h;	82%
With calcium iodide In neat (no solvent) at 70℃; under 15001.5 Torr; for 24h; diastereoselective reaction;	77%
With C68H70Co3N16O8; tetrabutyl-ammonium chloride In neat (no solvent) at 80℃; under 15514.9 Torr; for 4h; Inert atmosphere; Autoclave;

: 106-86-5
1,2-Epoxy-4-vinylcyclohexane

: 78-70-6
3,7-dimethylocta-1,6-dien-3-ol

: octakis(dimethylsiloxy)octasilsesquioxane

: C88H176O28Si16

Conditions

Conditions	Yield
Stage #1: 3,7-dimethylocta-1,6-dien-3-ol; octakis(dimethylsiloxy)octasilsesquioxane With bis(1,5-cyclooctadiene)diiridium(I) dichloride; Karstedt's catalyst In toluene at 90℃; Stage #2: 1,2-Epoxy-4-vinylcyclohexane In toluene at 90℃;	82%

...Expand

: 106-86-5
1,2-Epoxy-4-vinylcyclohexane

: 4-vinyl cyclohexene dioxide

Conditions

Conditions	Yield
With oxygen; copper(II) bis(trifluoromethanesulfonate); dimethyl sulfoxide; bismuth at 100℃; for 1.3h;	77%

: 106-86-5
1,2-Epoxy-4-vinylcyclohexane

: 766-77-8
Dimethylphenylsilane

: 20988-14-1
<2-(3,4-Epoxy-cyclohexyl)-aethyl>-dimethyl-phenyl-silan

Conditions

Conditions	Yield
With (4s,6s)-2,4,5,6-tetra(9H-carbazol-9-yl)isophthalonitrile; N-ethyl-N,N-diisopropylamine; triisopropylsilanethiol In 1,4-dioxane at 20℃; Schlenk technique; Sealed tube; Inert atmosphere; Irradiation;	77%
Stage #1: 1,2-Epoxy-4-vinylcyclohexane; Dimethylphenylsilane With C11H13Cl2CoN5 In toluene at 80℃; for 0.5h; Schlenk technique; Stage #2: With sodium triethylborohydride In toluene at 80℃; for 24h; Schlenk technique;
With C77H70N2OPtSi2 In toluene at 80℃; for 8h; Catalytic behavior; Reagent/catalyst; Inert atmosphere; Schlenk technique; regioselective reaction;	99 %Chromat.

1,2-Epoxy-4-vinylcyclohexane Chemical Properties

The molecular structure of 1,2-Epoxy-4-vinylcyclohexane (CAS NO.106-86-5):

IUPAC Name: 3-Ethenyl-7-oxabicyclo[4.1.0]heptane
Molecular Weight: 124.18028 g/mol
Molecular Formula: C₈H₁₂O
Density: 1.06 g/cm³
Boiling Point: 169 °C at 760 mmHg
Flash Point: 48.1 °C
Index of Refraction: 1.564
Molar Refractivity: 38.1 cm³
Molar Volume: 117.1 cm³
Surface Tension: 36.7 dyne/cm
Enthalpy of Vaporization: 38.88 kJ/mol
Vapour Pressure: 2.09 mmHg at 25 °C
XLogP3-AA: 1.7
H-Bond Acceptor: 1
Rotatable Bond Count: 1
Exact Mass: 124.088815
MonoIsotopic Mass: 124.088815
Topological Polar Surface Area: 12.5
Heavy Atom Count: 9
Canonical SMILES: C=CC1CCC2C(C1)O2
InChI: InChI=1S/C8H12O/c1-2-6-3-4-7-8(5-6)9-7/h2,6-8H,1,3-5H2
InChIKey: SLJFKNONPLNAPF-UHFFFAOYSA-N
EINECS: 203-436-1
Product Categories of 1,2-Epoxy-4-vinylcyclohexane (CAS NO.106-86-5): Industrial/Fine Chemicals; Monomers; Polymer Science; Vinyl Halides, Amines, Amides, and Other Vinyl Monomers

1,2-Epoxy-4-vinylcyclohexane Toxicity Data With Reference

1.		skn-rbt 10 mg/24H open MLD		AIHAAP American Industrial Hygiene Association Journal. 23 (1962),95.
2.		eye-rbt 20 mg/24H MOD		85JCAE Prehled Prumyslove Toxikologie; Organicke Latky Marhold, J.,Prague, Czechoslovakia.: Avicenum,1986,775.

1,2-Epoxy-4-vinylcyclohexane Consensus Reports

Reported in EPA TSCA Inventory.

1,2-Epoxy-4-vinylcyclohexane Safety Profile

Hazard Codes: Toxic T
Risk Statements: 45-10-20/21/22
R45:May cause cancer.
R10:Flammable.
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed.
Safety Statements: 53-16-23-36/37/39-45
S53:Avoid exposure - obtain special instructions before use.
S16:Keep away from sources of ignition.
S23:Do not breathe vapour.
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
RIDADR: UN 3271 3/PG 3
WGK Germany: 3
RTECS: RN8770000
HazardClass: 3.2
PackingGroup: III
Experimental reproductive effects. A skin irritant. Flammable liquid when exposed to heat, sparks, or flame. To fight fire, use foam, alcohol foam, mist. When heated to decomposition it emits acrid smoke and irritating fumes.

1,2-Epoxy-4-vinylcyclohexane Specification

1,2-Epoxy-4-vinylcyclohexane (CAS NO.106-86-5) is also named as 1-Vinyl-3,4-epoxycyclohexane ; 3,4-Epoxycyclohexylethylene ; 3-Vinyl-7-oxabicyclo(4.1.0)heptane ; 4-17-00-00314 (Beilstein Handbook Reference) ; 4-Vinyl-1,2-epoxycyclohexane ; 4-Vinylcyclohexane monoepoxide ; 4-Vinylcyclohexane, 1,2-epoxide ; 4-Vinylcyclohexene monoxide ; 4-Vinylcyclohexene oxide ; 4-Vinylcyclohexene-1,2-epoxide ; AI3-26045 ; BRN 0107390 ; EP-101 ; Epoxide 101 ; NSC 35409 ; Unoxat epoxide 101 ; Vinylcyclohexane monoxide ; Vinylcyclohexene monoxide .

Product Name

1,2-Epoxy-4-vinylcyclohexane

Synthetic route

1,2-Epoxy-4-vinylcyclohexane Chemical Properties

1,2-Epoxy-4-vinylcyclohexane Toxicity Data With Reference

1,2-Epoxy-4-vinylcyclohexane Consensus Reports

1,2-Epoxy-4-vinylcyclohexane Safety Profile

1,2-Epoxy-4-vinylcyclohexane Specification

Related Products

Hot Products