1,3-Dichloropropene supplier

Name
1,3-Dichloropropene
EINECS 208-826-5
CAS No. 542-75-6
Article Data30
CAS DataBase
Density 1.175 g/cm³
Solubility water: <0.01 g/100 mL at 16.5 °C
Melting Point -60 °C
Formula C₃H₄Cl₂
Boiling Point 108.4 °C at 760 mmHg
Molecular Weight 110.971
Flash Point 27.8 °C
Transport Information UN 1992 3/PG 3
Appearance clear yellowish to brownish liquid
Safety 36/37-45-60-61
Risk Codes 10-20/21-25-36/37/38-43-50/53
Molecular Structure
Hazard Symbols T,N
Synonyms Propene,1,3-dichloro- (8CI);1,3-D;1,3-Dichloro-1-propene;1,3-Dichloro-2-propene;1,3-Dichloropropylene;3-Chloroallyl chloride;3-Chloropropenyl chloride;D-D 92;DD 95;Dorlane II;NSC 6202;Telone;Telone92;Telone II;Telone II-B;a,g-Dichloropropylene;g-Chloroallyl chloride;
PSA 0.00000
LogP 1.97770

Synthetic route

: 187737-37-7
propene

A: 557-98-2
2-chloropropene

B: 26198-63-0, 78-87-5
1,2-Dichloropropane

C: 542-75-6
E/Z-1,3-Dichloropropene

D: 75-29-6
isopropyl chloride

E: 590-21-6
propenyl chloride

F: 107-05-1
3-chloroprop-1-ene

Conditions

Conditions	Yield
With aluminum oxide; copper dichloride; dibenzoyl peroxide at 489.9℃; for 0.000555556h; Product distribution; Mechanism; also other temperatures (503 K - 753 K) and initiators (chloral dioxyperoxide);	A 0.7% B 3.3% C 0.8% D 1.8% E 0.9% F 91.4%

...Expand

: 96-23-1
1,3-Dichloro-2-propanol

: 542-75-6
E/Z-1,3-Dichloropropene

Conditions

Conditions	Yield
With phosphorus pentoxide
With phosphorus pentaoxide
With trichlorophosphate
at 350℃; Reagent/catalyst; Temperature; Inert atmosphere;
at 350℃; Reagent/catalyst; Temperature; Inert atmosphere;

: 96-18-4
1,2,3-trichloropropane

A: 78-88-6
2,3-Dichloroprop-1-ene

B: 542-75-6
E/Z-1,3-Dichloropropene

: 563-57-5
3,3-dichloropropene

: 542-75-6
E/Z-1,3-Dichloropropene

Conditions

Conditions	Yield
With hydrogenchloride at 100℃;

: 187737-37-7
propene

: 107-05-1
3-chloroprop-1-ene

: 542-75-6
E/Z-1,3-Dichloropropene

Conditions

Conditions	Yield
With chlorine at 510℃; technische Darstellung;
With chlorine at 510℃; technische Darstellung;

: 624-65-7
2-propynyl chloride

A: 78-88-6
2,3-Dichloroprop-1-ene

B: 542-75-6
E/Z-1,3-Dichloropropene

Conditions

Conditions	Yield
With hydrogenchloride; mercury dichloride In acetic acid

: 10026-13-8, 874483-75-7
phosphorus pentachloride

: 107-02-8
acrolein

A: 542-75-6
E/Z-1,3-Dichloropropene

B: 563-57-5
3,3-dichloropropene

...Expand

: 10026-13-8, 874483-75-7
phosphorus pentachloride

: 107-02-8
acrolein

A: 542-75-6
E/Z-1,3-Dichloropropene

B: 20395-25-9
1,1,3-trichloropropane

C: 563-57-5
3,3-dichloropropene

...Expand

: 7647-01-0
hydrogenchloride

: 563-57-5
3,3-dichloropropene

: 542-75-6
E/Z-1,3-Dichloropropene

Conditions

Conditions	Yield
at 100℃;

: 563-57-5
3,3-dichloropropene

: 7705-08-0
iron(III) chloride

: 542-75-6
E/Z-1,3-Dichloropropene

Conditions

Conditions	Yield
Isomerisierung;

: 96-23-1
1,3-Dichloro-2-propanol

: 10025-87-3, 12599-09-6, 63736-95-8
trichlorophosphate

: 542-75-6
E/Z-1,3-Dichloropropene

benzenesulfonic acid-<β.β'dichloro-isopropyl>-ester: benzenesulfonic acid-<β.β'dichloro-isopropyl>-ester

: 542-75-6
E/Z-1,3-Dichloropropene

Conditions

Conditions	Yield
at 240 - 250℃;

: 96-23-1
1,3-Dichloro-2-propanol

phosphoric acid anhydride: phosphoric acid anhydride

: 542-75-6
E/Z-1,3-Dichloropropene

: 96-23-1
1,3-Dichloro-2-propanol

phosphorus pentoxide: phosphorus pentoxide

: 542-75-6
E/Z-1,3-Dichloropropene

symm. dichlorohydrin: symm. dichlorohydrin

: 542-75-6
E/Z-1,3-Dichloropropene

Conditions

Conditions	Yield
With trichlorophosphate
With phosphorus pentoxide

: 96-18-4
1,2,3-trichloropropane

potash: potash

A: 78-88-6
2,3-Dichloroprop-1-ene

B: 542-75-6
E/Z-1,3-Dichloropropene

...Expand

: 107-02-8
acrolein

A: 542-75-6
E/Z-1,3-Dichloropropene

B 3.3-dichloropropene-(1); 1 1 3-trichloro-propane: 3.3-dichloropropene-(1); 1 1 3-trichloro-propane

Conditions

Conditions	Yield
With phosphorus pentachloride

: 17232-07-4
benzenesulfonic acid-(β,β'-dichloro-isopropyl ester)

A: 7647-01-0
hydrogenchloride

B: 542-75-6
E/Z-1,3-Dichloropropene

C: 98-11-3
benzenesulfonic acid

D sulfur dioxide: sulfur dioxide

Conditions

Conditions	Yield
at 240 - 250℃;

...Expand

: 187737-37-7
propene

A: 78-88-6
2,3-Dichloroprop-1-ene

B: 26198-63-0, 78-87-5
1,2-Dichloropropane

C: 542-75-6
E/Z-1,3-Dichloropropene

D: 108-90-7
chlorobenzene

E polychlorinated dibenzofuranspolychlorinated dibenzodioxins: polychlorinated dibenzofuranspolychlorinated dibenzodioxins

Conditions

Conditions	Yield
With hydrogenchloride; air; fly ash at 349 - 548℃; for 0.000277778h; oxychlorination; Further byproducts given;

...Expand

: 74-87-3
methylene chloride

: 540-59-0
1,2-Dichloroethylene

: 542-75-6
E/Z-1,3-Dichloropropene

Conditions

Conditions	Yield
at 420℃; under 14206.3 Torr; Product distribution / selectivity;

: 542-75-6
E/Z-1,3-Dichloropropene

: 277317-27-8
1-(tert-butyloxycarbonyl)-5-[(tert-butyloxycarbonyl)amino]-7-(benzyloxy)-4-iodoindole

: 277317-31-4
7-benzyloxy-5-[tert-butoxycarbonyl-(3-chloro-allyl)-amino]-4-iodo-indole-1-carboxylic acid tert-butyl ester

Conditions

Conditions	Yield
With sodium hydride In N,N-dimethyl-formamide at 25℃; for 1h; Alkylation;	100%

: tert-butyl 1-bromo-7-cyano-2-naphthylcarbamate

: 542-75-6
E/Z-1,3-Dichloropropene

: tert-butyl 1-bromo-7-cyano-2-naphthyl(3-chloro-2-propen-1-yl)carbamate

Conditions

Conditions	Yield
With sodium hydride In N,N-dimethyl-formamide at 0 - 20℃; for 2h;	100%

: 454713-47-4
tert-butyl (1-bromonaphthalen-2-yl)carbamate

: 542-75-6
E/Z-1,3-Dichloropropene

: 454713-48-5
tert-butyl N-(1-bromo-2-naphthyl)-N-(3-chloroprop-2-enyl)carbamate

Conditions

Conditions	Yield
With potassium carbonate In N,N-dimethyl-formamide at 70 - 80℃; for 4h; Reagent/catalyst; Solvent;	100%
Stage #1: tert-butyl (1-bromonaphthalen-2-yl)carbamate With sodium hydride In N,N-dimethyl-formamide; mineral oil at 0 - 20℃; for 0.5h; Stage #2: E/Z-1,3-Dichloropropene In N,N-dimethyl-formamide; mineral oil at 20℃; for 4h;	97%
Stage #1: tert-butyl (1-bromonaphthalen-2-yl)carbamate With sodium hydride In N,N-dimethyl-formamide at 0 - 20℃; for 0.5h; Stage #2: E/Z-1,3-Dichloropropene In N,N-dimethyl-formamide at 0 - 20℃; for 4h;	97%

: 922506-90-9
ethyl 4-(benzyloxy)-7-iodo-1H-indole-2-carboxylate

: 542-75-6
E/Z-1,3-Dichloropropene

: 1078151-50-4
ethyl 4-(benzyloxy)-1-(3-chloroallyl)-7-iodo-1H-indole-2-carboxylate

Conditions

Conditions	Yield
With potassium carbonate; sodium iodide In N,N-dimethyl-formamide at 50℃; for 19h;	100%

: tert-butyl 1-bromo-7-cyano-2-naphthylcarbamate

: 542-75-6
E/Z-1,3-Dichloropropene

: 885229-81-2
tert-butyl 1-bromo-7-cyano-2-naphthyl(3-chloro-2-propen-1-yl)carbamate

Conditions

Conditions	Yield
Stage #1: tert-butyl 1-bromo-7-cyano-2-naphthylcarbamate With sodium hydride In N,N-dimethyl-formamide; mineral oil at 0℃; Stage #2: E/Z-1,3-Dichloropropene In N,N-dimethyl-formamide; mineral oil at 0 - 20℃; for 2h;	100%

: 542-75-6
E/Z-1,3-Dichloropropene

: 1350890-85-5
4-bromo-5-tert-butoxycarbonylamino-indole-1-carboxylic acid tert-butyl ester

: 1350890-86-6
4-bromo-5-[tert-butoxycarbonyl-(3-chloro-allyl)amino]-indole-1-carboxylic acid-tert-butyl ester

Conditions

Conditions	Yield
Stage #1: 4-bromo-5-tert-butoxycarbonylamino-indole-1-carboxylic acid tert-butyl ester With sodium hydride In N,N-dimethyl-formamide; mineral oil at 0℃; for 0.75h; Inert atmosphere; Stage #2: E/Z-1,3-Dichloropropene In N,N-dimethyl-formamide; mineral oil for 3h; Inert atmosphere;	100%
Stage #1: 4-bromo-5-tert-butoxycarbonylamino-indole-1-carboxylic acid tert-butyl ester With sodium hydride In N,N-dimethyl-formamide; mineral oil at 0℃; for 0.25h; Inert atmosphere; Stage #2: E/Z-1,3-Dichloropropene In N,N-dimethyl-formamide; mineral oil at 0 - 20℃; Inert atmosphere;	64%

: 542-75-6
E/Z-1,3-Dichloropropene

: tert-butyl (7-(benzyloxy)-4-bromo-2-methylbenzo[d]oxazol-5-yl)carbamate

: tert-butyl (7-(benzyloxy)-4-bromo-2-methylbenzo[d]oxazol-5-yl)(3-chloroallyl)carbamate

Conditions

Conditions	Yield
With potassium carbonate In N,N-dimethyl-formamide at 80℃; for 7h;	100%

: 542-75-6
E/Z-1,3-Dichloropropene

: 100-97-0
hexamethylenetetramine

: 1-(3-chloroallyl)-3,5,7-triaza-1-azoniaadamantane chloride

Conditions

Conditions	Yield
In chloroform at 60℃; for 12h;	99.9%

: 542-75-6
E/Z-1,3-Dichloropropene

: 577705-94-3
1-benzyloxy-3-(tert-butyloxycarbonyl)amino-4-iodoisoquinoline

: 577705-95-4
3-[N-(tert-butyloxycarbonyl)-N-(3-chloroprop-2-en-1-yl)amino]-1-benzyloxy-4-iodoisoquinoline

Conditions

Conditions	Yield
Stage #1: 1-benzyloxy-3-(tert-butyloxycarbonyl)amino-4-iodoisoquinoline With sodium hydride In N,N-dimethyl-formamide at 0℃; for 0.5h; Stage #2: E/Z-1,3-Dichloropropene With tetra-(n-butyl)ammonium iodide In N,N-dimethyl-formamide at 25℃; for 3h;	99%
With tetra-(n-butyl)ammonium iodide; sodium hydride In N,N-dimethyl-formamide at 0 - 25℃; for 3h;	99%

: 542-75-6
E/Z-1,3-Dichloropropene

: 1613154-15-6
C21H22BrNO5

: C24H25BrClNO5

Conditions

Conditions	Yield
With tetra-(n-butyl)ammonium iodide; sodium hydride In N,N-dimethyl-formamide at 20℃;	99%

: 110-69-0
butyraldehyde oxime

: 542-75-6
E/Z-1,3-Dichloropropene

: O-(3-chloro-2-propenyl)hydroxylamine

Conditions

Conditions	Yield
With 1-methyl-1H-imidazole; 1-bromo-butane; sodium hydroxide In dichloromethane; acetonitrile at 55 - 70℃; for 1.5h; Reagent/catalyst; Temperature;	99%

: 542-75-6
E/Z-1,3-Dichloropropene

: 161646-53-3
tert-butyl (4-(benzyloxy)-1-iodonaphthalen-2-yl)carbamate

: (4-Benzyloxy-1-iodo-naphthalen-2-yl)-((E)-3-chloro-allyl)-carbamic acid tert-butyl ester

Conditions

Conditions	Yield
With sodium hydride In N,N-dimethyl-formamide at 25℃; for 1h;	98%

: 542-75-6
E/Z-1,3-Dichloropropene

: 452921-69-6
4-benzyloxy-2-(tert-butyloxycarbonylamino)-1-iodo-5,6,7,8-tetrahydronaphthalene

: 452921-84-5
(4-benzyloxy-1-iodo-5,6,7,8-tetrahydro-naphthalen-2-yl)-(3-chloro-allyl)-carbamic acid tert-butyl ester

Conditions

Conditions	Yield
Stage #1: 4-benzyloxy-2-(tert-butyloxycarbonylamino)-1-iodo-5,6,7,8-tetrahydronaphthalene With sodium hydride In N,N-dimethyl-formamide at 20℃; for 0.5h; Stage #2: E/Z-1,3-Dichloropropene In N,N-dimethyl-formamide at 20℃; for 14h; Further stages.;	98%

: 885227-51-0
tert-butyl 1-bromo-7-(methylsulfonyl)-2-naphthyl(3-chloro-2-propen-1-yl)carbamate

: 542-75-6
E/Z-1,3-Dichloropropene

: tert-butyl 1-bromo-6-(methylsulfonyl)-2-naphthyl(3-chloro-2-propen-1-yl)carbamate

Conditions

Conditions	Yield
With sodium hydride In N,N-dimethyl-formamide at 0 - 20℃; for 7h;	97%

: methyl 8-bromo-7-[(tert-butoxycarbonyl)amino]-2-naphthoate

: 542-75-6
E/Z-1,3-Dichloropropene

: methyl 8-bromo-7-[(tert-butoxycarbonyl)(3-chloro-2-propen-1-yl)amino]-2-naphthoate

Conditions

Conditions	Yield
With sodium hydride In N,N-dimethyl-formamide at 0 - 20℃; for 1h;	97%

: 885227-93-0
tert-butyl 1-bromo-7-(methylsulfonyl)-2-naphthylcarbamate

: 542-75-6
E/Z-1,3-Dichloropropene

: tert-butyl 1-bromo-7-(methylsulfonyl)-2-naphthyl(3-chloro-2-propen-1-yl)carbamate

Conditions

Conditions	Yield
With sodium hydride In N,N-dimethyl-formamide at 0 - 20℃; for 6.5h;	97%

: 885227-51-0
tert-butyl 1-bromo-7-(methylsulfonyl)-2-naphthyl(3-chloro-2-propen-1-yl)carbamate

: 542-75-6
E/Z-1,3-Dichloropropene

: 885227-52-1
tert-butyl 1-bromo-7-(methylsulfonyl)-2-naphthyl(3-chloro-2-propen-1-yl)carbamate

Conditions

Conditions	Yield
Stage #1: tert-butyl 1-bromo-7-(methylsulfonyl)-2-naphthyl(3-chloro-2-propen-1-yl)carbamate With sodium hydride In N,N-dimethyl-formamide; mineral oil at 0 - 20℃; for 1h; Stage #2: E/Z-1,3-Dichloropropene In N,N-dimethyl-formamide; mineral oil at 20℃; for 6h;	97%

: methyl 8-bromo-7-[(tert-butoxycarbonyl)amino]-2-naphthoate

: 542-75-6
E/Z-1,3-Dichloropropene

: 885227-67-8
methyl 8-bromo-7-[(tert-butoxycarbonyl)(3-chloro-2-propen-1-yl)amino]-2-naphthoate

Conditions

Conditions	Yield
With sodium hydride In N,N-dimethyl-formamide; mineral oil at 0 - 20℃; for 1h;	97%

: 542-75-6
E/Z-1,3-Dichloropropene

: 198708-96-2
N-(tert-Butyloxycarbonyl)-3-iodo-4-(methoxymethoxy)-2-naphthylamine

: ((E)-3-Chloro-allyl)-(3-iodo-4-methoxymethoxy-naphthalen-2-yl)-carbamic acid tert-butyl ester

Conditions

Conditions	Yield
With tetra-(n-butyl)ammonium iodide; sodium hydride In N,N-dimethyl-formamide at 25℃;	96%

: 542-75-6
E/Z-1,3-Dichloropropene

: 227084-62-0
[N-(tert-butyloxycarbonyl)amino]-2,4-dimethoxy-6-iodo-5-(methoxymethoxy)-3-methylbenzene

: 252204-14-1
[N-(tert-butyloxycarbonyl)-N-(3-chloro-2-propen-1-yl)amino]-2,4-dimethoxy-6-iodo-5-(methoxymethoxy)-3-methylbenzene

Conditions

Conditions	Yield
With tetra-(n-butyl)ammonium iodide; sodium hydride In N,N-dimethyl-formamide at 25℃;	96%

: tert-butyl (1-bromo-6-cyanonaphthalen-2-yl)carbamate

: 542-75-6
E/Z-1,3-Dichloropropene

: tert-butyl 1-bromo-6-cyano-2-naphthyl(3-chloro-2-propenyl)carbamate

Conditions

Conditions	Yield
With sodium hydride In N,N-dimethyl-formamide at 0 - 20℃; for 6.5h;	96%

: tert-butyl (1-bromo-6-cyanonaphthalen-2-yl)carbamate

: 542-75-6
E/Z-1,3-Dichloropropene

: 885229-79-8
tert-butyl 1-bromo-6-cyano-2-naphthyl(3-chloro-2-propenyl)carbamate

Conditions

Conditions	Yield
Stage #1: tert-butyl (1-bromo-6-cyanonaphthalen-2-yl)carbamate With sodium hydride In N,N-dimethyl-formamide; mineral oil at 0 - 20℃; for 0.5h; Stage #2: E/Z-1,3-Dichloropropene In N,N-dimethyl-formamide; mineral oil at 20℃; for 6h;	96%

: 542-75-6
E/Z-1,3-Dichloropropene

: 1187567-14-1
1-(benzyloxy)-4-bromo-3-((tert-butyloxycarbonyl)-amino)phenanthrene

: 1187567-15-2
3-[N-(tert-butyloxycarbonyl)-N-(3-chloroprop-2-en-1-yl)amino]-1-(benzyloxy)-4-bromophenanthrene

Conditions

Conditions	Yield
Stage #1: 1-(benzyloxy)-4-bromo-3-((tert-butyloxycarbonyl)-amino)phenanthrene With tetra-(n-butyl)ammonium iodide; sodium hydride In N,N-dimethyl-formamide; mineral oil at 0℃; for 0.25h; Inert atmosphere; Stage #2: E/Z-1,3-Dichloropropene In N,N-dimethyl-formamide; mineral oil at 20℃; for 2h; Darkness;	96%

: 542-75-6
E/Z-1,3-Dichloropropene

: 1381964-03-9
tert-butyl (4-(benzyloxy)-5-bromo-1-iodonaphthalen-2-yl)carbamate

: 1381964-04-0
tert-butyl (4-(benzyloxy)-5-bromo-1-iodonaphthalen-2-yl)-(3-chloroallyl)carbamate

Conditions

Conditions	Yield
Stage #1: tert-butyl (4-(benzyloxy)-5-bromo-1-iodonaphthalen-2-yl)carbamate With tetra-(n-butyl)ammonium iodide; sodium hydride In N,N-dimethyl-formamide; mineral oil at 0℃; for 0.5h; Stage #2: E/Z-1,3-Dichloropropene In N,N-dimethyl-formamide; mineral oil at 20℃; for 1h;	96%

: 542-75-6
E/Z-1,3-Dichloropropene

: 105-44-2
4-methyl-pentan-2-one oxime

: O-(3-chloro-2-propenyl)hydroxylamine

Conditions

Conditions	Yield
With sodium hydroxide at 80 - 90℃; Temperature;	95.5%

: 885227-38-3
methyl 2-[(tert-butoxycarbonyl)amino]-1-bromo-6-naphthoate

: 542-75-6
E/Z-1,3-Dichloropropene

: methyl 2-[(tert-butoxycarbonyl)(3-chloro-2-propen-1-yl)amino]-1-bromo-6-naphthoate

Conditions

Conditions	Yield
With sodium hydride In N,N-dimethyl-formamide at 0 - 20℃; for 4.5h;	95%

: tert-butyl 1-bromo-7-[(dibenzylamino)sulfonyl]-2-naphthylcarbamate

: 542-75-6
E/Z-1,3-Dichloropropene

: tert-butyl 1-bromo-7-[(dibenzylamino)sulfonyl]-2-naphthyl(3-chloro-2-propen-1-yl)carbamate

Conditions

Conditions	Yield
With sodium hydride In N,N-dimethyl-formamide at 0 - 20℃; for 12h;	95%

: 885227-38-3
methyl 2-[(tert-butoxycarbonyl)amino]-1-bromo-6-naphthoate

: 542-75-6
E/Z-1,3-Dichloropropene

: 885227-39-4
methyl 2-[(tert-butoxycarbonyl)(3-chloro-2-propen-1-yl)amino]-1-bromo-6-naphthoate

Conditions

Conditions	Yield
Stage #1: methyl 2-[(tert-butoxycarbonyl)amino]-1-bromo-6-naphthoate With sodium hydride In N,N-dimethyl-formamide; mineral oil at 0 - 20℃; for 0.5h; Stage #2: E/Z-1,3-Dichloropropene In N,N-dimethyl-formamide; mineral oil at 20℃; for 4h;	95%

: tert-butyl 1-bromo-7-[(dibenzylamino)sulfonyl]-2-naphthylcarbamate

: 542-75-6
E/Z-1,3-Dichloropropene

: 885228-03-5
tert-butyl 1-bromo-7-[(dibenzylamino)sulfonyl]-2-naphthyl(3-chloro-2-propen-1-yl)carbamate

Conditions

Conditions	Yield
Stage #1: tert-butyl 1-bromo-7-[(dibenzylamino)sulfonyl]-2-naphthylcarbamate With sodium hydride In N,N-dimethyl-formamide; mineral oil at 0℃; Stage #2: E/Z-1,3-Dichloropropene In N,N-dimethyl-formamide; mineral oil at 0 - 20℃; for 12h;	95%

: 542-75-6
E/Z-1,3-Dichloropropene

: 227084-56-2
methyl 8-(benzyloxy)-6-(N-(tert-butyloxycarbonyl)amino)-5-iodoquinoline-3-carboxylate

: 280573-11-7
methyl 8-(benzyloxy)-6-[N-(tert-butyloxycarbonyl)-N-(E-3-chloro-2-propenyl)amino]-5-iodoquinoline-3-carboxylate

Conditions

Conditions	Yield
With sodium hydride In N,N-dimethyl-formamide at 25℃;	94%

1,3-Dichloropropene Consensus Reports

NTP 10th Report on Carcinogens. IARC Cancer Review: Group 2B IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 7 (1987),p. 195.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Human Inadequate Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 41 (1986),p. 113.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Sufficient Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 41 (1986),p. 113.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) . NTP Carcinogenesis Studies (gavage); Clear Evidence: mouse, rat NTPTR* National Toxicology Program Technical Report Series. (Research Triangle Park, NC 27709) No. NTP-TR-269 ,1986. . Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. Community Right-To-Know List.

1,3-Dichloropropene Standards and Recommendations

OSHA PEL: TWA 1 ppm (skin)
ACGIH TLV: TWA 1 ppm (skin); Not Classifiable as a Human Carcinogen
DFG MAK: Animal Carcinogen, Suspected Human Carcinogen
DOT Classification: 3; Label: Flammable Liquid

1,3-Dichloropropene Specification

The 1,3-Dichloropropene is an organic compound with the formula C₃H₄Cl₂. The systematic name of this chemical is (1E)-1,3-dichloroprop-1-ene. With the CAS registry number 542-75-6, it is also named as 1,3-Dichloro-1-propene. The product's categories are Pharmaceutical Raw Materials; Nematicides; Pesticides; Pesticides & Metabolites; Alpha sort;D; DAlphabetic; DIA - DICPesticides & Metabolites; API's; Alkenyl; Halogenated Hydrocarbons; Organic Building Blocks. Besides, it is clear yellowish to brownish liquid, which should be stored in a cool dry and ventilated place. It is used mainly in farming as a pesticide, specifically as a preplant fumigant and nematicide. It widely used in the US and other countries, but in the process of being phased out in the European Union.

Physical properties about 1,3-Dichloropropene are: (1)ACD/LogP: 2.01; (2)ACD/LogD (pH 5.5): 2.01; (3)ACD/LogD (pH 7.4): 2.01; (4)ACD/BCF (pH 5.5): 19.94; (5)ACD/BCF (pH 7.4): 19.94; (6)ACD/KOC (pH 5.5): 296.5; (7)ACD/KOC (pH 7.4): 296.5; (8)#Freely Rotating Bonds: 1; (9)Index of Refraction: 1.456; (10)Molar Refractivity: 25.7 cm³; (11)Molar Volume: 94.4 cm³; (12)Polarizability: 10.18×10^-24cm³; (13)Surface Tension: 27.1 dyne/cm; (14)Density: 1.175 g/cm³; (15)Flash Point: 27.8 °C; (16)Enthalpy of Vaporization: 33.28 kJ/mol; (17)Boiling Point: 108.4 °C at 760 mmHg; (18)Vapour Pressure: 30.4 mmHg at 25°C.

Uses of 1,3-Dichloropropene: it can be used to produce trichloro-(3-chloro-allyl)-silane. It will need reagent trichlorosilane. The yield is about 76%.

When you are using this chemical, please be cautious about it as the following:
It is flammable and harmful by inhalation, in contact with skin and if swallowed. Itmay cause sensitisation by skin contact and very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. In case of accident or if you feel unwell seek medical advice immediately (show the label where possible). Besides, this chemical is irritating to eyes, respiratory system and skin. When you are using it, wear suitable protective clothing and gloves. This material and its container must be disposed of as hazardous waste.

You can still convert the following datas into molecular structure:
(1)SMILES: Cl[C@H]=CCCl
(2)InChI: InChI=1/C3H4Cl2/c4-2-1-3-5/h1-2H,3H2/b2-1+
(3)InChIKey: UOORRWUZONOOLO-OWOJBTEDBJ
(4)Std. InChI: InChI=1S/C3H4Cl2/c4-2-1-3-5/h1-2H,3H2/b2-1+
(5)Std. InChIKey: UOORRWUZONOOLO-OWOJBTEDSA-N

The toxicity data is as follows:

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
guinea pig	LCLo	inhalation	400ppm/7H (400ppm)		American Industrial Hygiene Association Journal. Vol. 38, Pg. 217, 1977.
mouse	LC50	inhalation	4650mg/m³/2H (4650mg/m³)		"Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 48, 1982.
mouse	LD50	oral	640mg/kg (640mg/kg)		Fundamental and Applied Toxicology. Vol. 8, Pg. 562, 1987.
rabbit	LD50	skin	504mg/kg (504mg/kg)		Dow Chemical Company Reports. Vol. MSD-405,
rat	LCLo	inhalation	1000ppm/2H (1000ppm)	SENSE ORGANS AND SPECIAL SENSES: LACRIMATION: EYE	American Industrial Hygiene Association Journal. Vol. 38, Pg. 217, 1977.
rat	LD50	intraperitoneal	175mg/kg (175mg/kg)		Toxicologist. Vol. 5, Pg. 2, 1985.
rat	LD50	oral	470mg/kg (470mg/kg)		Dow Chemical Company Reports. Vol. MSD-405,
rat	LD50	skin	775mg/kg (775mg/kg)		Farm Chemicals Handbook. Vol. -, Pg. C103, 1991.

Product Name

1,3-Dichloropropene

Synthetic route

1,3-Dichloropropene Consensus Reports

1,3-Dichloropropene Standards and Recommendations

1,3-Dichloropropene Specification

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