2-methylnon-8-enenitrile
non-1-ene
Conditions | Yield |
---|---|
With potassium; tert-butyl alcohol In N,N,N,N,N,N-hexamethylphosphoric triamide; diethyl ether at 0℃; for 3h; | 98% |
heptyl-thiirane
non-1-ene
Conditions | Yield |
---|---|
With tri-n-butyl-tin hydride; 2,2'-azobis(isobutyronitrile) In benzene Heating; | 95% |
2-Hydroxy-nonyltrimethylsilan
non-1-ene
Conditions | Yield |
---|---|
With hydrogen fluoride In acetonitrile for 2h; Ambient temperature; | 93% |
Conditions | Yield |
---|---|
With potassium tert-butylate In N,N-dimethyl-formamide at 20℃; for 1h; Temperature; Inert atmosphere; | 91% |
Conditions | Yield |
---|---|
copper acetylacetonate In tetrahydrofuran at 20℃; for 20h; | 85% |
Conditions | Yield |
---|---|
With sodium formate; PdCl22 In n-heptane; water for 6h; Heating; | A 82% B 17% |
dichloromethane
n-octylmagnesium chloride
A
non-1-ene
B
hepatdecane
Conditions | Yield |
---|---|
With C31H37ClN3NiO2(1-)*Li(1+) In tetrahydrofuran at 25℃; for 0.333333h; Inert atmosphere; Overall yield = 95 %; | A 82% B 13% |
Conditions | Yield |
---|---|
With trifluoroacetic anhydride | 81% |
dibromo-1,1 nonane
non-1-ene
Conditions | Yield |
---|---|
With n-butyllithium In diethyl ether at -30 - -25℃; | 81% |
ethene
(3R,8S)-falcarindiol
A
non-1-ene
B
(3R,8S)-Deca-1,9-diene-4,6-diyne-3,8-diol
Conditions | Yield |
---|---|
tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride In dichloromethane at 20℃; for 16h; | A n/a B 81% |
(Z)-non-3-en-1-ol
non-1-ene
Conditions | Yield |
---|---|
Stage #1: (Z)-non-3-en-1-ol With n-butyllithium; zirconocene dichloride In diethyl ether; hexane at -50 - 34℃; Stage #2: With hydrogenchloride In diethyl ether; hexane at 20℃; | 80% |
(Z)-1-methoxy-3-nonene (Z)-3-Nonenyl acetate (Z)-3-Nonenyl acetate (Z)-3-Nonenyl acetate (Z)-3-nonenyl acetate
non-1-ene
Conditions | Yield |
---|---|
Stage #1: (Z)-1-methoxy-3-nonene (Z)-3-Nonenyl acetate (Z)-3-Nonenyl acetate (Z)-3-Nonenyl acetate (Z)-3-nonenyl acetate With n-butyllithium; zirconocene dichloride In diethyl ether; hexane at -50 - 34℃; Stage #2: With hydrogenchloride In diethyl ether; hexane at 20℃; | 80% |
Conditions | Yield |
---|---|
With dilithium tetrachlorocuprate; triphenylphosphine In octane at 50℃; for 5h; | 78% |
Conditions | Yield |
---|---|
In diethyl ether for 15h; from 0 degC to 20 degC; | 75% |
Conditions | Yield |
---|---|
With potassium tert-butylate In N,N-dimethyl-formamide at 20℃; for 0.5h; Reagent/catalyst; Inert atmosphere; | 75% |
1-Chlorononane
triethylbenzylammonium ethanolate
A
2-(1-nonyloxy)-1-ethanol
B
non-1-ene
Conditions | Yield |
---|---|
at 20 - 25℃; for 1h; | A 42% B 67% |
Conditions | Yield |
---|---|
Stage #1: butyl magnesium bromide With copper(l) chloride In tetrahydrofuran at 20℃; for 0.0833333h; Schlenk technique; Inert atmosphere; Stage #2: 1-Bromononane at 20℃; for 0.166667h; Time; Schlenk technique; Inert atmosphere; | A 66% B 26% |
2-nonenyl alcohol
A
nonane
B
non-1-ene
C
2-nonene
D
nonyl alcohol
Conditions | Yield |
---|---|
With methanol; toluene-4-sulfonic acid at 25℃; for 5h; Reagent/catalyst; Inert atmosphere; Sealed tube; UV-irradiation; | A n/a B n/a C 65% D n/a |
1-Bromononane
n-octylmagnesium chloride
A
nonane
B
non-1-ene
C
oct-1-ene
D
hepatdecane
Conditions | Yield |
---|---|
Stage #1: n-octylmagnesium chloride With copper(l) chloride In tetrahydrofuran at 20℃; for 0.0833333h; Schlenk technique; Inert atmosphere; Stage #2: 1-Bromononane at 20℃; for 0.166667h; Schlenk technique; Inert atmosphere; | A 64% B 30% C 57% D 6% |
(E)-1-methoxy-3-nonene
non-1-ene
Conditions | Yield |
---|---|
Stage #1: (E)-1-methoxy-3-nonene With n-butyllithium; zirconocene dichloride In diethyl ether; hexane at -50 - 34℃; Stage #2: With hydrogenchloride In diethyl ether; hexane at 20℃; | 60% |
Conditions | Yield |
---|---|
In diethyl ether for 20h; from -15 degC to 20 degC; | 59% |
Conditions | Yield |
---|---|
With zinc; Co-complex 3 In N,N-dimethyl-formamide at 20℃; | 57% |
Conditions | Yield |
---|---|
With dilithium tetrachlorocuprate; triphenylphosphine In octane at 50℃; for 5h; | 56% |
Conditions | Yield |
---|---|
With iron(III) chloride; copper(I) bromide | 55% |
Conditions | Yield |
---|---|
With chloro-trimethyl-silane; zinc In tetrahydrofuran at 50℃; for 3h; | 54% |
Conditions | Yield |
---|---|
With Me3Co(CN)2Li3 In tetrahydrofuran for 18h; Product distribution; for -78 deg C to r.t., variation of reagent; | A 3% B 36% C 51% |
Conditions | Yield |
---|---|
With cobalt(II) oxide; N,N,N,N,-tetramethylethylenediamine; oxygen In water at 100℃; under 13501.4 Torr; for 35h; | A 32% B 50% |
(Z)-2-nonen-1-ol
A
nonane
B
non-1-ene
C
cis-2-nonene
D
nonyl alcohol
Conditions | Yield |
---|---|
With methanol; toluene-4-sulfonic acid at 25℃; for 5h; Reagent/catalyst; Inert atmosphere; Sealed tube; UV-irradiation; | A n/a B n/a C 48% D n/a |
Conditions | Yield |
---|---|
With P, S at 170 - 200℃; for 6.5h; Product distribution; | A 14.9% B 24.3% C 21.2% |
Conditions | Yield |
---|---|
Stage #1: (3Z)-1-chloro-3-nonene With n-butyllithium; zirconocene dichloride In diethyl ether; hexane at -50 - 34℃; Stage #2: With hydrogenchloride In diethyl ether; hexane at 20℃; | A 20% B n/a |
lithium aluminium tetrahydride
non-1-ene
aluminium bromide
1-dibromoaluminiononane
Conditions | Yield |
---|---|
In diethyl ether; benzene Ar, LiAlH4 in ether added to benzene under stirring, most of the solvent removed, benzene and AlBr3 in benzene added, stirred at 20°C for 1 h, org. compound in benzene added dropwise under stirring, warmed to30-40°C for 5-10 min; NMR; | 100% |
Conditions | Yield |
---|---|
Stage #1: triphenyl phosphite With bis(p-dimethylaminophenyl)methanone at 120℃; for 1h; Inert atmosphere; Stage #2: non-1-ene at 130 - 140℃; under 750.075 Torr; Reagent/catalyst; Temperature; Pressure; UV-irradiation; Autoclave; | 99.56% |
Conditions | Yield |
---|---|
With Pd(II)(15-crown-5-phen)Cl2; dinitrogen monoxide In N,N-dimethyl acetamide; water at 150℃; under 2250.23 Torr; for 18h; | 99% |
With palladium 10% on activated carbon; oxygen; copper dichloride In tetrahydrofuran; water Wacker oxidation; Reflux; | 73% |
With oxygen; copper dichloride; palladium dichloride; cadmium In water at 60℃; for 8h; | 62% |
Conditions | Yield |
---|---|
With water; zinc; chloro(1,5-cyclooctadiene)rhodium(I) dimer In 1,4-dioxane at 90℃; for 20h; | 99% |
With magnesium; palladium on activated charcoal In methanol Ambient temperature; | 86% |
With carbon monoxide; hydrogen; dimethyl amine In N,N-dimethyl-formamide at 150℃; under 9000.9 Torr; for 3h; Autoclave; | 17% |
non-1-ene
dimethylphenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silane
dimethyl(1-octyl)(phenyl)silane
Conditions | Yield |
---|---|
With [Cu(P,P′-(9,9-dimethyl-9H-xanthene-4,5-diyl)bis[N,N,N′,N′-tetraethyl-phosphonousdiamide])(2,9-dimethyl-1,10–phenanthroline)]PF6; potassium carbonate In water; acetonitrile at 30℃; Inert atmosphere; Flow reactor; Irradiation; | 99% |
non-1-ene
1,2-dibromononane
Conditions | Yield |
---|---|
With Oxone; sodium bromide In tetrachloromethane; water at 0℃; | 98% |
With bromine at -12 - -5℃; |
Conditions | Yield |
---|---|
With {Au(dppm)}2Cl2; trifluoroacetic acid In methanol Inert atmosphere; UV-irradiation; | 97% |
non-1-ene
2-heptyl-1,2,4-trioxolane
Conditions | Yield |
---|---|
With oxygen; ozone In dichloromethane at -78℃; for 0.0333333h; | 96% |
With ozone In dichloromethane at -78℃; | 90% |
non-1-ene
1,2-dichloro-n-nonane
Conditions | Yield |
---|---|
With Oxone; sodium chloride In tetrachloromethane; water at 0℃; | 96% |
Conditions | Yield |
---|---|
With ([(Me3Si)2NC(N-cyclohexyl)2]2Lu(μ-H))2 In hexane for 12h; | 96% |
With C37H57N4ScSi2 In benzene-d6 at 20℃; for 12h; Reagent/catalyst; |
Conditions | Yield |
---|---|
With zinc borohydride; silica gel In 1,2-dimethoxyethane for 0.5h; Ambient temperature; | 95% |
With zinc borohydride; silica gel In 1,2-dimethoxyethane for 0.5h; Ambient temperature; other alkenes: regioselective anti-Markovnikov hydration; | 95% |
With zinc borohydride; silica gel In N,N-dimethyl-formamide for 0.5h; Ambient temperature; | 75% |
Conditions | Yield |
---|---|
Stage #1: non-1-ene With oxygen; ozone In tetrahydrofuran at 0℃; Stage #2: With semicarbazide hydrochloride In tetrahydrofuran at 0 - 20℃; Inert atmosphere; | 95% |
Stage #1: non-1-ene With ozone In dichloromethane; acetic acid at 0℃; Stage #2: With semicarbazide hydrochloride In dichloromethane; acetic acid at 0 - 20℃; | 95% |
With Oxone; osmium(VIII) oxide In N,N-dimethyl-formamide; tert-butyl alcohol at 20℃; for 3h; | 90% |
Conditions | Yield |
---|---|
zirconocene dichloride In benzene (Ar); mixture of Zr complex, olefine and soln. of organoaluminum compd. diluted with benzene, stirred at 20 °C for 5 h; | 95% |
With hydrogenchloride; meso-Me2C(2-Me-4-But-C5H2)2ZrCl2 In water; benzene at 0 - 20℃; Reagent/catalyst; Inert atmosphere; |
non-1-ene
4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane
Conditions | Yield |
---|---|
Stage #1: non-1-ene; 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane With 6-di-tert-butylphosphinomethyl-2,2'-bipyridine In tetrahydrofuran for 0.0166667h; Inert atmosphere; Glovebox; Schlenk technique; Stage #2: With sodium triethylborohydride In tetrahydrofuran at 25℃; for 0.166667h; Inert atmosphere; Glovebox; Schlenk technique; | 95% |
With (iPrPNN)CoCl2; sodium triethylborohydride In tetrahydrofuran; toluene at 25℃; for 0.25h; Time; Reagent/catalyst; Inert atmosphere; Glovebox; Schlenk technique; chemoselective reaction; | 95% |
With C20H22AlN2PSe In neat (no solvent) at 30℃; for 8h; Schlenk technique; Glovebox; Inert atmosphere; chemoselective reaction; | 95% |
Conditions | Yield |
---|---|
With ([(Me3Si)2NC(N-cyclohexyl)2]2Lu(μ-H))2 In hexane for 24h; | 94% |
Conditions | Yield |
---|---|
With 2,2-dimethoxy-2-phenylacetophenone In methanol; dichloromethane at 20℃; for 8h; Sealed tube; Inert atmosphere; Irradiation; regioselective reaction; | 94% |
non-1-ene
1,2-epoxynonane
Conditions | Yield |
---|---|
With [(C18H37)2(CH3)2N]3[SiO4H(WO5)3]; dihydrogen peroxide In ethyl acetate at 59.84℃; for 3h; | 93% |
With C10H12NO(1+)*BF4(1-) In dichloromethane for 2h; | 91% |
With C10H12NO(1+)*BF4(1-) In dichloromethane for 2h; Ambient temperature; | 91% |
Conditions | Yield |
---|---|
With potassium acetate; manganese triacetate In acetic acid at 70℃; electrochemical reaction; | 92% |
Conditions | Yield |
---|---|
With hydrogenchloride; sodium sulfate; OsO4 In ethyl acetate; N,N-dimethyl-formamide; tert-butyl alcohol | 90% |
non-1-ene
(3S,4aR,6R,7R,8S)-3-allyl-6,7-bis(benzyloxy)-8-(benzyloxymethyl)hexahydropyrido[1,2-c][1,3]oxazin-1(3H)-one
(3S,4aR,6R,7R,8S)-6,7-bis(benzyloxy)-8-(benzyloxymethyl)-3-(dec-2-en-1-yl)hexahydropyrido[1,2-c][1,3]oxazin-1(3H)-one
Conditions | Yield |
---|---|
With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride In dichloromethane at 20℃; for 24h; | 90% |
Conditions | Yield |
---|---|
With N-iodo-succinimide at 45℃; for 2h; Molecular sieve; Inert atmosphere; | A 90% B 90% |
Conditions | Yield |
---|---|
With 2,2-dimethoxy-2-phenylacetophenone In methanol at 20℃; for 8h; Sealed tube; Inert atmosphere; Irradiation; regioselective reaction; | 90% |
Conditions | Yield |
---|---|
Stage #1: non-1-ene With 2,2'-azobis(isobutyronitrile); Thiophosphorsaeure-O,O-diethylester In tetrahydrofuran Heating; Stage #2: Decan-2-one With sec.-butyllithium In tetrahydrofuran at -78 - 20℃; Horner-Wadsworth-Emmons reaction; | 89% |
Conditions | Yield |
---|---|
With H5PV2Mo10O40; oxygen; sodium sulfite In acetic acid at 65 - 110℃; under 750.075 Torr; for 11h; Temperature; Time; | A 11% B 89% |
non-1-ene
carbon monoxide
2-methylnonanoic acid
Conditions | Yield |
---|---|
With propionic acid under 37503.8 Torr; for 1.5h; Pressure; Reagent/catalyst; Koch-Haaf Carboxylation; Autoclave; Heating; | 89% |
Conditions | Yield |
---|---|
Stage #1: methanol; non-1-ene With oxygen; ozone at 0℃; Stage #2: With 4-hydroxybenzoic acid hydrazide at 0 - 20℃; for 72h; | 89% |
Stage #1: methanol; non-1-ene With oxygen; ozone at 0℃; Stage #2: With benzoic acid hydrazide at 0 - 20℃; for 72h; | 73% |
Molecular Structure of 1-Nonene (CAS No.124-11-8):
Molecular Formula: C9H18
Molecular Weight: 126.2392
CAS No: 124-11-8
IUPAC Name: Non-1-ene
H bond acceptors: 0
H bond donors: 0
Freely Rotating Bonds: 6
Polar Surface Area: 0 Å2
Index of Refraction: 1.418
Molar Refractivity: 43.47 cm3
Molar Volume: 172.1 cm3
Surface Tension: 23.5 dyne/cm
Density: 0.733 g/cm3
Flash Point: 46.1 °C
Enthalpy of Vaporization: 36.79 kJ/mol
Boiling Point: 146.8 °C at 760 mmHg
Vapour Pressure: 5.77 mmHg at 25°C
InChI: InChI=1/C9H18/c1-3-5-7-9-8-6-4-2/h3H,1,4-9H2,2H3
InChIKey: JRZJOMJEPLMPRA-UHFFFAOYAK
Std. InChI: InChI=1S/C9H18/c1-3-5-7-9-8-6-4-2/h3H,1,4-9H2,2H3
Std. InChIKey: JRZJOMJEPLMPRA-UHFFFAOYSA-N
Product Categories: Industrial/Fine Chemicals;1-Olefins (GC Standard);Analytical Chemistry;Standard Materials for GC;Alpha Sort;Hydrocarbons;N;NeatsAlphabetic;NJ - NZGasoline, Diesel,&Petroleum;N-OChemical Class;Olefins;Substance classes;Volatiles/ Semivolatiles;Acyclic;Alkenes;Organic Building Blocks
Hazard Codes: Xn,F
Risk Statements: 10-36/37/38-65
R10:Flammable.
R36/37/38:Irritating to eyes, respiratory system and skin.
R65:Harmful: may cause lung damage if swallowed.
Safety Statements: 26-36-62
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36:Wear suitable protective clothing.
S62:If swallowed, do not induce vomitting; seek medical advice immediately and show this container or label.
RIDADR: UN 3295 3/PG 3
WGK Germany: 3
HazardClass: 3.2
PackingGroup: III
Hazardous Substances Data: 124-11-8(Hazardous Substances Data)
1-Nonene (CAS No.124-11-8), its synonyms are 1-Nonene (petroleum derived) ; 1-Nonene [Standard Material] ; 1-Nonylene; alpha-Nonene; alpha-Nonylene .
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