Conditions | Yield |
---|---|
With sulfur trioxide at 8 - 35℃; Temperature; | 92.2% |
Stage #1: acrylonitrile With sulfuric acid In water at -10 - -7℃; for 2h; Stage #2: isobutene With acetic acid at 10 - 70℃; for 1.5h; Temperature; | 92.09% |
With methanesulfonic acid; sulfuric acid at 0 - 45℃; under 760.051 Torr; for 1h; Reagent/catalyst; Temperature; | 82.3% |
acrylonitrile
isobutene
A
N-tert-Butylacrylamide
B
2-acrylamido-2-methylpropanesulfonic acid
C
2-propenamide
Conditions | Yield |
---|---|
With sulfuric acid at 20℃; for 2h; | A n/a B 87% C n/a |
1-vinylimidazole
2-acrylamido-2-methylpropanesulfonic acid
C7H13NO4S*C5H6N2
Conditions | Yield |
---|---|
In methanol at 20℃; for 4h; | 100% |
2-acrylamido-2-methylpropanesulfonic acid
tetra(n-butyl)ammonium hydroxide
2-acrylamido-2-methylpropane sulfonic acid tetrabutylammonium salt
Conditions | Yield |
---|---|
In methanol at 200℃; | 100% |
2-acrylamido-2-methylpropanesulfonic acid
2-propenamide
polymer, Mw 61 kDa, sulfur content 6.97%, 2-acrylamido-2-methylpropanesulfonic acid units content 22.0 mol%; monomer(s): acrylamide; 2-acrylamido-2-methylpropanesulfonic acid
Conditions | Yield |
---|---|
With 2,2'-azobis(isobutyronitrile) In ethanol at 50℃; for 24h; | 99.8% |
2-acrylamido-2-methylpropanesulfonic acid
2-propenamide
polymer, Mw 36 kDa, sulfur content 6.16%, 2-acrylamido-2-methylpropanesulfonic acid units content 18.5 mol%; monomer(s): acrylamide; 2-acrylamido-2-methylpropanesulfonic acid
Conditions | Yield |
---|---|
With 2,2'-azobis(isobutyronitrile) In ethanol at 50℃; for 24h; | 99.8% |
2-acrylamido-2-methylpropanesulfonic acid
2-propenamide
polymer, Mw 19 kDa, sulfur content 6.18%, 2-acrylamido-2-methylpropanesulfonic acid units content 19.1 mol%; monomer(s): acrylamide; 2-acrylamido-2-methylpropanesulfonic acid
Conditions | Yield |
---|---|
With 2,2'-azobis(isobutyronitrile) In isopropyl alcohol at 50℃; for 24h; | 99.8% |
2-acrylamido-2-methylpropanesulfonic acid
2-propenamide
polymer, sulfur content 9.42%, 2-acrylamido-2-methylpropanesulfonic acid units content 37.6 mol%; monomer(s): acrylamide; 2-acrylamido-2-methylpropanesulfonic acid
Conditions | Yield |
---|---|
With 2,2'-azobis(isobutyronitrile) In ethanol at 50℃; for 24h; | 99.7% |
2-acrylamido-2-methylpropanesulfonic acid
2-propenamide
polymer, Mw 16 kDa, sulfur content 5.86%, 2-acrylamido-2-methylpropanesulfonic acid units content 17.3 mol%; monomer(s): acrylamide; 2-acrylamido-2-methylpropanesulfonic acid
Conditions | Yield |
---|---|
With 2,2'-azobis(isobutyronitrile) In ethanol at 50℃; for 24h; | 99.6% |
2-acrylamido-2-methylpropanesulfonic acid
2-propenamide
polymer, Mw 28 kDa, sulfur content 7.16%, 2-acrylamido-2-methylpropanesulfonic acid units content 22.8 mol%; monomer(s): acrylamide; 2-acrylamido-2-methylpropanesulfonic acid
Conditions | Yield |
---|---|
With 2,2'-azobis(isobutyronitrile) In ethanol at 50℃; for 24h; | 99.2% |
2-acrylamido-2-methylpropanesulfonic acid
Tris(3,6-dioxaheptyl)amine
Conditions | Yield |
---|---|
at 25℃; for 8h; | 99% |
2-acrylamido-2-methylpropanesulfonic acid
2-propenamide
polymer, Mw 23 kDa, sulfur content 6.07%, 2-acrylamido-2-methylpropanesulfonic acid units content 18.2 mol%; monomer(s): acrylamide; 2-acrylamido-2-methylpropanesulfonic acid
Conditions | Yield |
---|---|
With 2,2'-azobis(isobutyronitrile) In isopropyl alcohol at 50℃; for 24h; | 98.8% |
2-acrylamido-2-methylpropanesulfonic acid
trimethylamine
Conditions | Yield |
---|---|
With hydroquinone In water at 25℃; for 24h; | 95% |
2-acrylamido-2-methylpropanesulfonic acid
2-propenamide
polymer, sulfur content 9.13%, 2-acrylamido-2-methylpropanesulfonic acid units content 33.1 mol%; monomer(s): acrylamide; 2-acrylamido-2-methylpropanesulfonic acid
Conditions | Yield |
---|---|
With 2,2'-azobis(isobutyronitrile) In ethanol at 50℃; for 24h; | 95% |
2-acrylamido-2-methylpropanesulfonic acid
2-propenamide
polymer, Mw 14 kDa, sulfur content 7.21%, 2-acrylamido-2-methylpropanesulfonic acid units content 23.0 mol%; monomer(s): acrylamide; 2-acrylamido-2-methylpropanesulfonic acid
Conditions | Yield |
---|---|
With 2,2'-azobis(isobutyronitrile) In ethanol at 50℃; for 24h; | 94.8% |
2-acrylamido-2-methylpropanesulfonic acid
Conditions | Yield |
---|---|
With sodium hydroxide In water at 50℃; for 5h; Kinetics; Activation energy; Further Variations:; Temperatures; Reagents; | 85% |
2-acrylamido-2-methylpropanesulfonic acid
Conditions | Yield |
---|---|
In methanol at 20℃; for 0.25h; | 84% |
1,4-diaza-bicyclo[2.2.2]octane
2-acrylamido-2-methylpropanesulfonic acid
Conditions | Yield |
---|---|
With hydroquinone In water at 20℃; for 24h; | 82% |
In water at 20℃; for 24h; Addition; | 81.7% |
2-acrylamido-2-methylpropanesulfonic acid
2,7-dibromo-9H-fluorene
Conditions | Yield |
---|---|
Stage #1: 2,7-dibromo-9H-fluorene With tetrabutylammomium bromide; potassium hydroxide In water; dimethyl sulfoxide at 4℃; for 1h; Stage #2: 2-acrylamido-2-methylpropanesulfonic acid In water; dimethyl sulfoxide for 10h; Michael Addition; | 79% |
2-acrylamido-2-methylpropanesulfonic acid
3-(diphenylphosphino)propionic acid
Conditions | Yield |
---|---|
In acetonitrile at 20℃; for 48h; | 79% |
2-acrylamido-2-methylpropanesulfonic acid
benzyltri(n-butyl)ammonium chloride
benzyltributylammonium 2-acrylamido-2-methyl-1-propanesulfonate
Conditions | Yield |
---|---|
In water at 20℃; for 0.0833333h; | 73% |
2-acrylamido-2-methylpropanesulfonic acid
2-methyl-acrylic acid 3-dimethylamino-propyl amide
Conditions | Yield |
---|---|
With hydroquinone In water at 20℃; for 72h; Addition; | 71% |
With hydroquinone In water at 70℃; Kinetics; Concentration; |
2-acrylamido-2-methylpropanesulfonic acid
tetraethylammonium hydroxide
diphenylphosphane
Conditions | Yield |
---|---|
With ditertbutylphenol In water; acetonitrile for 4h; Ambient temperature; | 70% |
2-acrylamido-2-methylpropanesulfonic acid
(11-Methacryloyl-amino)undecansaeure
Conditions | Yield |
---|---|
With sodium hydroxide In methanol at 60℃; for 21h; Product distribution / selectivity; | 69.2% |
2-acrylamido-2-methylpropanesulfonic acid
12-(methacrylolamino)dodecanoic acid
Conditions | Yield |
---|---|
With sodium hydroxide; 2,2'-azobis(isobutyronitrile) In methanol at 60℃; for 21h; Product distribution / selectivity; | 67.5% |
2-acrylamido-2-methylpropanesulfonic acid
Conditions | Yield |
---|---|
With 2,2'-azobis(isobutyronitrile) In ethanol at 50℃; for 24h; | 59.7% |
1,4,8,11-Tetraazacyclotetradecane
2-acrylamido-2-methylpropanesulfonic acid
Conditions | Yield |
---|---|
With 2,4-di-tert-Butylphenol In chloroform for 336h; Ambient temperature; | 59% |
2-acrylamido-2-methylpropanesulfonic acid
Conditions | Yield |
---|---|
With sodium hydroxide; 2,2'-azobis(isobutyronitrile) In methanol; water at 60℃; for 12.5h; | 53.71% |
2-acrylamido-2-methylpropanesulfonic acid
poly{(2-acrylamido-2-methyl-1-propanesulfonic acid)-co-[2-(acrylamidomethyl)-18-crown-6]}, Mn 47000 g/mol, PDI 1.68; monomer(s): 2-acrylamido-2-methyl-1-propanesulfonic acid, 80 mol percent; 2-(acrylamidomethyl)-18-crown-6, 20 mol percent
Conditions | Yield |
---|---|
With 2,2'-azobis(isobutyronitrile) In tert-butyl alcohol for 19h; | 47% |
2-acrylamido-2-methylpropanesulfonic acid
Conditions | Yield |
---|---|
With sodium disulfite; potassium peroxomonosulphate; sorbitan monostearate In hexane; water at 60℃; for 1h; pH=9; Kinetics; Product distribution; Polymerization; | 41% |
Molecular Structure of 2-Acrylamide-2-methylpropanesulfonic acid (CAS NO.15214-89-8):
IUPAC Name: 2-methyl-2-(prop-2-enoylamino)propane-1-sulfonic acid
Molecular Formula: C7H13NO4S
Formula Weight: 207.25
H bond acceptors: 5
H bond donors: 2
Freely Rotating Bonds: 4
Polar Surface Area: 72.06 Å2
Index of Refraction: 1.502
Molar Refractivity: 48.34 cm3
Molar Volume: 163.6 cm3
Surface Tension: 46.5 dyne/cm
Density: 1.266 g/cm3
Melting point: 195-200 °C (dec.)(lit.)
Flash Point: 160 °C
Storage temp: 2-8°C
Water Solubility : 1500 g/L (20°C)
Sensitive : Hygroscopic
InChI
InChI=1/C7H13NO4S/c1-4-6(9)8-7(2,3)5-13(10,11)12/h4H,1,5H2,2-3H3,(H,8,9)(H,10,11,12)
Smiles
O=C(NC(CS(=O)(=O)O)(C)C)C=C
Solublility: Soluble Diformamide, partly soluble in methanol, ethanol, acetone insoluble.
EINECS: 239-268-0
Product Categories: Industrial/Fine Chemicals; monomer; Organic Chemicals; Acrylamide and Methacrylamide; Acrylic Monomers; Monomers
1. Use raw material of acrylonitrile, isobutene reacts with fuming sulfuric acid.
2. In the presence of solvent, firstly sulfonating isobutene to obtain sulfonated intermediates; Then in the presence of sulfuric acid reacts with acrylonitrile.
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
rat | LD50 | oral | 5400mg/kg (5400mg/kg) | BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD BEHAVIORAL: ATAXIA | Toksikologicheskii Vestnik. Vol. (3), Pg. 34, 2000. |
Hazard Codes: C
Risk Statements: 34-21/22 (Causes burns; Harmful in contact with skin and if swallowed)
Safety Statements: 26-36/37/39-45 (In case of contact with eyes, rinse immediately with plenty of water and seek medical advice; Wear suitable protective clothing, gloves and eye/face protection; In case of accident or if you feel unwell, seek medical advice immediately)
RIDADR: UN 2585 8/PG 3
WGK Germany: 1
RTECS: TZ6658000
HazardClass: 8
PackingGroup: III
HS Code: 29241900
Low toxicity by ingestion. When heated to decomposition it emits toxic vapors of NOx and SOx.
2-Acrylamide-2-methylpropanesulfonic acid , with CAS number of 15214-89-8, can be called 1-propanesulfonic acid, 2-methyl-2-[(1-oxo-2-propen-1-yl)amino]- ; 2-(Acryloylamino)-2-methyl-1-propanesulfonic acid . It is a white powder, 2-Acrylamide-2-methylpropanesulfonic acid (CAS NO.15214-89-8) is an important monomer. Its copolymers or homopolymers with different molecular weight can be widely used in textile, oil drilling, water treatment, papermaking, dying, coating, cosmetics, electronics, etc. because of its unique formular structure—containing sulfonic acid group and unsaturated radical, thus showing excellent properties in many aspects.
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