6-Methyl-1,3,5-triazine-2,4-diamine supplier

Name
6-Methyl-1,3,5-triazine-2,4-diamine
EINECS 208-796-3
CAS No. 542-02-9
Article Data29
CAS DataBase
Density 1.391 g/cm³
Solubility 11.2g/L at 20℃
Melting Point 274-276 °C(lit.)
Formula C₄H₇N₅
Boiling Point 443 °C at 760 mmHg
Molecular Weight 125.133
Flash Point 252 °C
Transport Information
Appearance white solid
Safety 26-36
Risk Codes 36/37/38
Molecular Structure
Hazard Symbols Xi
Synonyms s-Triazine,2,4-diamino-6-methyl- (6CI,8CI);2,4-Diamino-6-methyl-1,3,5-triazine;2,4-Diamino-6-methyl-s-triazine;2,6-Diamino-4-methyl-s-triazine;2-Methyl-4,6-diamino-s-triazine;6-Methylguanamine;Acetoguanamine;ENT 50715;NSC 257;
PSA 90.71000
LogP 0.50680

Synthetic route

: 1973-04-2
2,4-dichloro-6-methyl-1,3,5-triazine

: 542-02-9
2-methyl-4,6-diamino-1,3,5-triazine

Conditions

Conditions	Yield
With ammonia In acetone at 40 - 45℃;	87%

: 127099-85-8, 780722-26-1
dicyandiamide

: 75-05-8
acetonitrile

: 542-02-9
2-methyl-4,6-diamino-1,3,5-triazine

Conditions

Conditions	Yield
With potassium hydroxide In ethanol at 80℃; for 24h;	85%

: 10581-62-1
6-(chloromethyl)-1,3,5-triazine-2,4-diamine

: 542-02-9
2-methyl-4,6-diamino-1,3,5-triazine

Conditions

Conditions	Yield
With hydrogenchloride; Lindlar's catalyst Hydrogenation;

: 5699-40-1
acetylguanidine

: 542-02-9
2-methyl-4,6-diamino-1,3,5-triazine

: 949-42-8
2,4-bis(trichloromethyl)-6-methyl-1,3,5-triazine

: 542-02-9
2-methyl-4,6-diamino-1,3,5-triazine

Conditions

Conditions	Yield
With ammonia; N,N-dimethyl-formamide

: 108-24-7
acetic anhydride

: 33668-48-3
Biguanide acetate

: 542-02-9
2-methyl-4,6-diamino-1,3,5-triazine

: 108-24-7
acetic anhydride

: 56-03-1
BIGUANIDE

: 542-02-9
2-methyl-4,6-diamino-1,3,5-triazine

: 141-78-6
ethyl acetate

: 56-03-1
BIGUANIDE

: 542-02-9
2-methyl-4,6-diamino-1,3,5-triazine

: dicyanamide; compound with acetamidine

: 98-95-3
nitrobenzene

: 71-43-2
benzene

: 542-02-9
2-methyl-4,6-diamino-1,3,5-triazine

...Expand

: 124-42-5
acetamidine hydrochloride

: 127099-85-8, 780722-26-1
N-Cyanoguanidine

: 542-02-9
2-methyl-4,6-diamino-1,3,5-triazine

Conditions

Conditions	Yield
at 225 - 230℃;

: 127099-85-8, 780722-26-1
N-Cyanoguanidine

: 75-05-8
acetonitrile

: 542-02-9
2-methyl-4,6-diamino-1,3,5-triazine

Conditions

Conditions	Yield
at 225 - 230℃;
With piperidine
With ethylenediamine

: 57-13-6
urea

: 75-05-8
acetonitrile

: 542-02-9
2-methyl-4,6-diamino-1,3,5-triazine

Conditions

Conditions	Yield
With ammonia at 350℃;

acetate_of guanidine: acetate_of guanidine

: 542-02-9
2-methyl-4,6-diamino-1,3,5-triazine

Conditions

Conditions	Yield
at 228 - 230℃;

: 64-17-5
ethanol

: 143-37-3
acetamidine

sodium dicyano-amide: sodium dicyano-amide

: 542-02-9
2-methyl-4,6-diamino-1,3,5-triazine

Conditions

Conditions	Yield
Erhitzen des Reaktionsprodukts in einem Benzol-Nitrobenzol-Gemisch;

...Expand

: 420-04-2
CYANAMID

: 63071-29-4
N1-acetyl-N3-cyanoguanidine

: 7732-18-5
water

: 542-02-9
2-methyl-4,6-diamino-1,3,5-triazine

...Expand

: 542-02-9
2-methyl-4,6-diamino-1,3,5-triazine

: 100-52-7
benzaldehyde

: 2-amino-4-benzylideneamino-6-methyl[1,3,5]triazine

Conditions

Conditions	Yield
In neat (no solvent) for 0.0583333h; Microwave irradiation;	95%

: 542-02-9
2-methyl-4,6-diamino-1,3,5-triazine

: 134293-22-4
1H,1′H-5,5′-bistetrazole-1,1′-diolate

: bis-2,4-diamino-6-methyl-1,3,5-triazin 1H,1'H-5,5'-bistetrazole-1,1'-diolate

Conditions

Conditions	Yield
In water at 20℃;	90%

: 542-02-9
2-methyl-4,6-diamino-1,3,5-triazine

: 1079-66-9
chloro-diphenylphosphine

: C28H25N5P2

Conditions

Conditions	Yield
With triethylamine In tetrahydrofuran Reflux; Inert atmosphere;	89%

: 542-02-9
2-methyl-4,6-diamino-1,3,5-triazine

: 714-87-4
3,9-dichloro-2,4,8,10-tetraoxa-3,9-diphospaspiro <5,5>undecane 3,9-dioxide

: C13H20N10O6P2

Conditions

Conditions	Yield
With triethylamine In N,N-dimethyl-formamide at 90℃; for 6h;	89%

: 542-02-9
2-methyl-4,6-diamino-1,3,5-triazine

: 83726-80-1
2-chloro-4-(1,3-thiazol-2-yl)pyrimidine

: 6-methyl-N2-(4-(thiazol-2-yl)pyrimidin-2-yl)-1,3,5-triazine-2,4-diamine

Conditions

Conditions	Yield
With sodium t-butanolate In tetrahydrofuran at 10 - 20℃; for 2h;	89%

: 542-02-9
2-methyl-4,6-diamino-1,3,5-triazine

: 2,4-diamino-6-methyl-1,3,5-triazinehydrochloride

Conditions

Conditions	Yield
With hydrogenchloride In water Further stages;	86%

: 7647-01-0
hydrogenchloride

: 542-02-9
2-methyl-4,6-diamino-1,3,5-triazine

: bismuth (III) nitrate pentahydrate

: 7732-18-5
water

: 3C4H7N5*3H(1+)*H2O*BiCl6(3-)

Conditions

Conditions	Yield
In ethanol at 20℃;	80%

...Expand

: 542-02-9
2-methyl-4,6-diamino-1,3,5-triazine

: 321-14-2
5-chloro-2-hydroxybenzoic acid

: C7H5ClO3*C4H7N5*H2O

Conditions

Conditions	Yield
In methanol; water at 20℃; for 336h;	79%

: 542-02-9
2-methyl-4,6-diamino-1,3,5-triazine

: 110-94-1
1,5-pentanedioic acid

: 1401592-22-0
C18H22N10O4

Conditions

Conditions	Yield
With hydrogenchloride In ethanol; water at 85 - 90℃;	78%

: 542-02-9
2-methyl-4,6-diamino-1,3,5-triazine

: 124-04-9
Adipic acid

: 1401592-24-2
C20H26N10O4

Conditions

Conditions	Yield
With hydrogenchloride In ethanol; water at 85 - 90℃;	78%

: 542-02-9
2-methyl-4,6-diamino-1,3,5-triazine

: 64-17-5
ethanol

: 605-70-9
naphthalene-1,4-dicarboxylic acid

: silver nitrate

: bis(2,4-diamino-6-methyl-1,3,5-tetrazine)(naphthalene-1,4-dicarboxylate)dicopper(II) - ethanol (1/2)

Conditions

Conditions	Yield
With NH3 In methanol; ethanol Sonication; AgNO3, 2,4-diamino-6-methyl-1,3,5-triazine and naphthalene-1,4-dicarboxylic acid (1:1:1) in CH3OH/C2H5OH in the presence of NH3 sonicated at 50°C; crystd. at room temp. for 1 week, washed (H2O), dried (air), elem. anal.;	77%

...Expand

: 542-02-9
2-methyl-4,6-diamino-1,3,5-triazine

: 118-41-2
Eudesmic acid

: C10H12O5*C4H7N5

Conditions

Conditions	Yield
In water; acetone at 20℃; for 336h; Sealed tube;	77%

: 542-02-9
2-methyl-4,6-diamino-1,3,5-triazine

: 89-00-9
Pyridine-2,3-dicarboxylic acid

: C7H5NO4*C4H7N5

Conditions

Conditions	Yield
In ethanol; water; N,N-dimethyl-formamide at 20℃; for 240h;	76%

: 542-02-9
2-methyl-4,6-diamino-1,3,5-triazine

: 652-36-8
2,3,5,6-tetrafluoroterephthalic acid

: C8H2F4O4*2C4H7N5

Conditions

Conditions	Yield
In 1,4-dioxane; water for 0.25h;	75%

: 542-02-9
2-methyl-4,6-diamino-1,3,5-triazine

: 3724-52-5
cyclopentane-1,2,3,4-tetracarboxylic acid

: C9H10O8*2C4H7N5

Conditions

Conditions	Yield
In water; acetone at 20℃; for 336h; Sealed tube;	75%

: 542-02-9
2-methyl-4,6-diamino-1,3,5-triazine

: 100-21-0
terephthalic acid

: C8H6O4*2C4H7N5

Conditions

Conditions	Yield
In methanol; water at 20℃; for 240h; Sealed tube;	75%

: 542-02-9
2-methyl-4,6-diamino-1,3,5-triazine

: 88-99-3
benzene-1,2-dicarboxylic acid

: 1293397-54-2
C4H7N5*C8H6O4

Conditions

Conditions	Yield
In methanol; water at 20℃; for 336h;	74%
In water at 120℃; for 72h; Autoclave;	58.4%

: 542-02-9
2-methyl-4,6-diamino-1,3,5-triazine

: 364-44-3
picryl fluoride

: 121105-41-7
6-methyl-[1,3,5]triazine-2,4-diyldiamine; picrate

Conditions

Conditions	Yield
In dimethyl sulfoxide at 80℃; for 48h;	73%

: 542-02-9
2-methyl-4,6-diamino-1,3,5-triazine

: 141-82-2
malonic acid

: 1401592-18-4
C14H14N10O4

Conditions

Conditions	Yield
With hydrogenchloride In ethanol; water at 85 - 90℃;	72%

: 542-02-9
2-methyl-4,6-diamino-1,3,5-triazine

: 110-15-6
succinic acid

: 1401592-21-9
C16H18N10O4

Conditions

Conditions	Yield
With hydrogenchloride In ethanol; water at 85 - 90℃;	70%

: 542-02-9
2-methyl-4,6-diamino-1,3,5-triazine

: 40244-90-4
Chlorodiisopropylphosphane

: N2,N4-bis(diisopropylphosphanyl)-6-methyl-1,3,5-triazine-2,4-diamine

Conditions

Conditions	Yield
With triethylamine In tetrahydrofuran at 0 - 60℃; for 16h; Glovebox; Inert atmosphere; Sealed tube;	70%
With triethylamine In tetrahydrofuran at 0 - 60℃; Inert atmosphere; Sealed tube;
With triethylamine In tetrahydrofuran at 60℃; Inert atmosphere; Sealed tube;

: 542-02-9
2-methyl-4,6-diamino-1,3,5-triazine

: 17422-74-1
3-Formylchromone

: 1020416-75-4
3-[(E)-2-(4,6-diamino-1,3,5-triazin-2-yl)vinyl]-4H-chromen-4-one

Conditions

Conditions	Yield
With chloro-trimethyl-silane In N,N-dimethyl-formamide Heating;	67%

: 542-02-9
2-methyl-4,6-diamino-1,3,5-triazine

: 874-42-0
2,4-dichlorobenzaldeyhde

: 131454-72-3
2,4-diamino--6-<2-(2,4-dichlorophenyl)ethenyl>-1,3,5-triazine

Conditions

Conditions	Yield
With methanesulfonic acid at 110℃; for 2.5h;	66%

: 542-02-9
2-methyl-4,6-diamino-1,3,5-triazine

: 3282-30-2
pivaloyl chloride

: 180986-97-4
N-[4-(2,2-Dimethyl-propionylamino)-6-methyl-[1,3,5]triazin-2-yl]-2,2-dimethyl-propionamide

Conditions

Conditions	Yield
With pyridine for 1.25h; Heating;	66%

: 542-02-9
2-methyl-4,6-diamino-1,3,5-triazine

: 830-03-5
4-nitrophenol acetate

A: 100-02-7
4-nitro-phenol

B: 30355-53-4
N-(amino-methyl-[1,3,5]triazin-2-yl)-acetamide

Conditions

Conditions	Yield
In dimethyl sulfoxide at 100℃; for 17.5h;	A n/a B 60%

...Expand

: 542-02-9
2-methyl-4,6-diamino-1,3,5-triazine

: 10203-08-4
3,5-dichlorobenzaldehyde

: 131454-65-4
2,4-diamino--6-<2-(3,5-dichlorophenyl)ethenyl>-1,3,5-triazine

Conditions

Conditions	Yield
With methanesulfonic acid at 110℃; for 2.5h;	59%

: 542-02-9
2-methyl-4,6-diamino-1,3,5-triazine

: 447-61-0
2-Trifluoromethylbenzaldehyde

: 139979-25-2
2,4-diamino--6-<2-(2-trifluoromethylphenyl)ethenyl>-1,3,5-triazine

Conditions

Conditions	Yield
With methanesulfonic acid at 110℃; for 2.5h;	54%

: 500-22-1
3-pyridinecarboxaldehyde

: 542-02-9
2-methyl-4,6-diamino-1,3,5-triazine

A: 131454-55-2
2-amino-4-hydroxy--6-<2-(3-pyridyl)ethenyl>-1,3,5-triazine

B: 124173-70-2
2,4-diamino--6-<2-(3-pyridyl)ethenyl>-1,3,5-triazine

Conditions

Conditions	Yield
With methanesulfonic acid at 110℃; for 2.5h;	A n/a B 51%
With methanesulfonic acid at 110℃; for 2h;	A 12% B n/a

...Expand

6-Methyl-1,3,5-triazine-2,4-diamine Chemical Properties

IUPAC Name: 6-Methyl-1,3,5-triazine-2,4-diamine
Synonyms of 1,3,5-Triazine-2,4-diamine,6-methyl- (CAS NO.542-02-9): 6-Methyl-1,3,5-triazine-2,4-diamine ; 2,4-Diamino-6-methyl-1,3,5-triazine ; 2,4-Diamino-6-methyl-s-triazine ; Acetoguanamine ; s-Triazine, 2,4-diamino-6-methyl- (8CI)
CAS NO: 542-02-9
Molecular Formula: C₄H₇N₅
Molecular Weight: 125.13
Molecular Structure:
H bond acceptors: 5
H bond donors: 4
Freely Rotating Bonds: 0
Polar Surface Area: 45.15 Å²
Index of Refraction: 1.675
Molar Refractivity: 33.82 cm³
Molar Volume: 89.9 cm³
Surface Tension: 92.6 dyne/cm
Density: 1.391 g/cm³
Flash Point: 252 °C
Enthalpy of Vaporization: 70.06 kJ/mol
Boiling Point: 443 °C at 760 mmHg
Vapour Pressure: 4.79E-08 mmHg at 25°C
Melting point: 274-276 ºC
Stability: Stable. Incompatible with oxidizing agents, acids.
Appearance: 1,3,5-Triazine-2,4-diamine,6-methyl- (CAS NO.542-02-9) is white solid.
SMILES: n1c(nc(nc1C)N)N
InChI: InChI=1/C4H7N5/c1-2-7-3(5)9-4(6)8-2/h1H3,(H4,5,6,7,8,9)
InChIKey: NJYZCEFQAIUHSD-UHFFFAOYAD
Std. InChI: InChI=1S/C4H7N5/c1-2-7-3(5)9-4(6)8-2/h1H3,(H4,5,6,7,8,9)
Std. InChIKey: NJYZCEFQAIUHSD-UHFFFAOYSA-N

6-Methyl-1,3,5-triazine-2,4-diamine Safety Profile

Hazard Codes: Irritant Xi
Risk Statements: 36/37/38
R36/37/38: 1,3,5-Triazine-2,4-diamine,6-methyl- (CAS NO.542-02-9) is irritating to eyes, respiratory system and skin.
Safety Statements: 26-36
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36: Wear suitable protective clothing.
WGK Germany: 2

Product Name

6-Methyl-1,3,5-triazine-2,4-diamine

Synthetic route

6-Methyl-1,3,5-triazine-2,4-diamine Chemical Properties

6-Methyl-1,3,5-triazine-2,4-diamine Safety Profile

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