• Name

  Acetyl iodide

• EINECS
• CAS No. 507-02-8
• Article Data31
• CAS DataBase
• Density 2.193g/cm³
• Solubility
• Melting Point
• Formula C2H3 I O
• Boiling Point 105.5°Cat760mmHg
• Molecular Weight 169.95
• Flash Point 17.6°C
• Transport Information
• Appearance
• Safety A toxic, corrosive material. Reacts with water or steam to produce toxic and corrosive fumes. Dangerous to use. When heated to decomposition it emits toxic fumes of I⁻. See also IODIDES.
• Risk Codes 34
• Molecular Structure
• Hazard Symbols Strong irritant to eyes and skin.
• Synonyms Acetyliodide;95%
• PSA 17.07000
• LogP 0.96790

Synthetic route

108-21-4

Isopropyl acetate

507-02-8

acetyl iodide

Conditions

Conditions	Yield
With diiodosilane; iodine In chloroform-d1 at 50℃; for 15h;	100%

79-20-9

acetic acid methyl ester

A

507-02-8

acetyl iodide

B

2754-27-0

trimethylsilyl acetate

Conditions

Conditions	Yield
With trimethylsilyl iodide; iodine In chloroform-d1 at 50℃; for 2h;	A 5% B 95%
With trimethylsilyl iodide; iodine In chloroform-d1 at 50℃; for 1.15h;	A 5% B 95%

123-86-4

acetic acid butyl ester

A

507-02-8

acetyl iodide

B

2754-27-0

trimethylsilyl acetate

Conditions

Conditions	Yield
With trimethylsilyl iodide; iodine In chloroform-d1 at 50℃; for 2h;	A 6% B 94%

122-79-2

Phenyl acetate

507-02-8

acetyl iodide

Conditions

Conditions	Yield
With diiodosilane; iodine In chloroform-d1 at 50℃; for 7h;	82%

79-20-9

acetic acid methyl ester

A

507-02-8

acetyl iodide

B

127421-46-9

C2H5IO2Si

Conditions

Conditions	Yield
With diiodosilane; iodine In chloroform-d1 at 50℃; for 15h;	A 80% B 10%
With diiodosilane; iodine In chloroform-d1 at 50℃; for 2.5h;	A 40% B 35%

108-21-4

Isopropyl acetate

A

507-02-8

acetyl iodide

B

127421-46-9

C2H5IO2Si

Conditions

Conditions	Yield
With diiodosilane; iodine In chloroform-d1 at 50℃; for 1.5h;	A 66% B 32%

123-86-4

acetic acid butyl ester

A

507-02-8

acetyl iodide

B

127421-46-9

C2H5IO2Si

Conditions

Conditions	Yield
With diiodosilane; iodine In chloroform-d1 at 50℃; for 15h;	A 58% B 34%

75-36-5

acetyl chloride

507-02-8

acetyl iodide

Conditions

Conditions	Yield
With trimethylsilyl iodide	46%
With pyridine; tributyltin iodide at 40℃; Thermodynamic data; Equilibrium constant;
With hydrogen iodide

618-38-2

benzoyl iodide

122-79-2

Phenyl acetate

A

93-99-2

benzoic acid phenyl ester

B

507-02-8

acetyl iodide

Conditions

Conditions	Yield
In dichloromethane for 3h; Heating;	A 18% B 34%

...Expand

463-51-4

Ketene

507-02-8

acetyl iodide

Conditions

Conditions	Yield
With hydrogen iodide; pyrographite

108-22-5

Isopropenyl acetate

507-02-8

acetyl iodide

Conditions

Conditions	Yield
With diethyl ether; hydrogen iodide at 10℃;

127-08-2

potassium acetate

507-02-8

acetyl iodide

Conditions

Conditions	Yield
With iodophosphorus durch Destillation;

108-24-7

acetic anhydride

507-02-8

acetyl iodide

Conditions

Conditions	Yield
With phosphorus; iodine

diacetyl-phenyl-arsine

74-88-4

methyl iodide

A

507-02-8

acetyl iodide

B

7301-41-9

trimethyl-phenyl-arsonium iodide

Conditions

Conditions	Yield

...Expand

Acetic acid iodo-phenyl-methyl ester

A

507-02-8

acetyl iodide

B

100-52-7

benzaldehyde

Conditions

Conditions	Yield
In chloroform-d1 at 20℃; Equilibrium constant;

507-02-8

acetyl iodide

7787-60-2

bismuth(III) chloride

7787-64-6

bismuth(III) iodide

Conditions

Conditions	Yield
In benzene slow addition of an excess of (10 %) acetyl iodide to a mixture of BiCl3 in benzene with stirring;;	100%
In benzene slow addition of an excess of (10 %) acetyl iodide to a mixture of BiCl3 in benzene with stirring;;	100%

1852-17-1

3,4,5,6-tetrahydropyrimidin-2(1H)-one

507-02-8

acetyl iodide

1,3-diacetylhexahydropyrimidin-2-one dihydroiodide

Conditions

Conditions	Yield
at 50 - 60℃; for 1h;	100%

32993-05-8

chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium (II)

507-02-8

acetyl iodide

34692-10-9

[ruthenium(II)I(η5-C5H5)(P(C6H5)3)2]

Conditions

Conditions	Yield
at 50℃; for 3h;	100%

32993-05-8

chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium (II)

507-02-8

acetyl iodide

A

34692-10-9

[ruthenium(II)I(η5-C5H5)(P(C6H5)3)2]

B

75-36-5

acetyl chloride

Conditions

Conditions	Yield
In benzene-d6 at 20℃; for 2.5h; Glovebox;	A 100% B 100%

...Expand

507-02-8

acetyl iodide

108-95-2

phenol

122-79-2

Phenyl acetate

Conditions

Conditions	Yield
With iridium(III) chloride; triphenylphosphine In acetonitrile at 20℃; for 8h;	99%
	50%

507-02-8

acetyl iodide

149-30-4

2-Mercaptobenzothiazole

1356914-78-7

N-acetyl-2-sulfanyl-1,3-benzothiazolium iodide

Conditions

Conditions	Yield
In diethyl ether at 50 - 55℃; for 5h;	99%

507-02-8

acetyl iodide

chloro(1,3-bis(2,6-di-i-propylphenyl)imidazol-2-ylidene)gold(I)

Au(I)(1,3-bis(2,6-diisopropylphenyl)imidazole-2-ylidene)

Conditions

Conditions	Yield
In dichloromethane at 25℃; for 1h; Glovebox;	99%

507-02-8

acetyl iodide

69952-89-2

N, N'-bis<3-(triethoxysilyl)propyl>thiourea

N-{3-[diethoxy-iodosilyl]propyl}-N'-[3-(triethoxysilyl)propyl]thiourea

Conditions

Conditions	Yield
at 50 - 55℃;	98%

507-02-8

acetyl iodide

88-99-3

benzene-1,2-dicarboxylic acid

85-44-9

phthalic anhydride

Conditions

Conditions	Yield
at 60 - 65℃; for 5h;	96%

2055-46-1

3,4,5,6-tetrahydropyrimidine-2-thione

507-02-8

acetyl iodide

1,3-diacetyl-3,4,5,6-tetrahydropyrimidine-2-thiol dihydroiodide

Conditions

Conditions	Yield
at 50 - 60℃; for 5h;	96%

120-93-4

imidazolidone

507-02-8

acetyl iodide

1-acetylimidazolidin-2-one hydroiodide

Conditions

Conditions	Yield
at 20 - 60℃; for 24h;	95%

507-02-8

acetyl iodide

106-37-6

1.4-dibromobenzene

A

506-96-7

Acetyl bromide

B

624-38-4

para-diiodobenzene

Conditions

Conditions	Yield
for 50h; UV-irradiation;	A 95% B 74%
UV-irradiation;	A n/a B 74%

...Expand

ACETYL IODIDE Chemical Properties

ACETYL IODIDE Toxicity Data With Reference

ACETYL IODIDE Consensus Reports

ACETYL IODIDE Safety Profile

ACETYL IODIDE Standards and Recommendations

ACETYL IODIDE Specification