Benzene,(2-chloropropyl)- supplier

Name
2-chloropropylbenzene
EINECS
CAS No. 10304-81-1
Article Data61
CAS DataBase
Density 1.027 g/cm³
Solubility
Melting Point
Formula C₉H₁₁Cl
Boiling Point 211.1 °C at 760 mmHg
Molecular Weight 154.639
Flash Point 79.7 °C
Transport Information
Appearance
Safety
Risk Codes
Molecular Structure
Hazard Symbols
Synonyms (2-Chloropropyl)benzene;1-Phenyl-2-chloropropane;2-Chloro-1-phenylpropane;NSC 27450;
PSA 0.00000
LogP 2.85640

Synthetic route

: 698-87-3
3-phenyl-2-propanol

: 10304-81-1
1-phenyl-2-chloropropane

Conditions

Conditions	Yield
With oxalyl dichloride; 1-methyl-3-(2-(3-methyl-2-oxoimidazolidin-1-yl)ethyl)-1H-imidazol-3-ium hexafluorophosphate at 20 - 60℃;	95%
With tetrachlorosilane In tetrachloromethane at 25℃; for 0.5h;	80%
With gallium(III) trichloride; dimethylmonochlorosilane; diethyl (2R,3R)-tartrate In dichloromethane; pentane at 20℃; for 1h; Inert atmosphere;	69%

: 698-87-3
3-phenyl-2-propanol

: 2570-00-5
3,3-dichloro-1,2-diphenylcyclopropene

A: 10304-81-1
1-phenyl-2-chloropropane

B: 886-38-4
diphenylcyclopropenone

Conditions

Conditions	Yield
In acetonitrile at 80℃; for 0.333333h; Inert atmosphere;	A 95% B n/a

...Expand

: 866942-23-6
1-phenyl-2-propyl 2-(methoxyethoxyethylcarboxy)-1-benzosulfonate

: 10304-81-1
1-phenyl-2-chloropropane

Conditions

Conditions	Yield
With lithium chloride In acetone for 8h;	94%
With lithium chloride In acetone for 8h; Product distribution / selectivity; Heating / reflux;	94%

: 61380-47-0
(±)-1-phenylpropanyl-2-yl methansulfonate

: 10304-81-1
1-phenyl-2-chloropropane

Conditions

Conditions	Yield
With 1-butyl-3-methylimidazolium chloride at 60℃; for 8h; Inert atmosphere; Green chemistry;	94%

: 1-phenyl-2-(chlorodimethylsiloxy)propane

: 10304-81-1
1-phenyl-2-chloropropane

Conditions

Conditions	Yield
With indium(III) chloride; benzil In dichloromethane at 20℃; for 7h;	82%

: 134906-52-8
1-phenyl-2-propyl benzenesulphonate

: 10304-81-1
1-phenyl-2-chloropropane

Conditions

Conditions	Yield
With benzyltri(n-butyl)ammonium chloride In acetone for 0.5h; Reflux;	82%
With lithium chloride; manganese(ll) chloride In tetrahydrofuran Inert atmosphere; Reflux;	60%

: 187737-37-7
propene

: 100-56-1
phenylmercury(II) chloride

: 10304-81-1
1-phenyl-2-chloropropane

Conditions

Conditions	Yield
With lithium chloride; copper dichloride; lithium tetrachloropalladate(II)

: 7705-08-0
iron(III) chloride

: 107-18-6
allyl alcohol

: 71-43-2
benzene

: 10304-81-1
1-phenyl-2-chloropropane

Conditions

Conditions	Yield
at 80℃;

...Expand

: 7705-08-0
iron(III) chloride

: 107-18-6
allyl alcohol

: 71-43-2
benzene

A: 300-57-2
allylbenzene

B: 10304-81-1
1-phenyl-2-chloropropane

Conditions

Conditions	Yield
at 25℃;

...Expand

: 7705-08-0
iron(III) chloride

: 107-05-1
3-chloroprop-1-ene

: 71-43-2
benzene

A: 10304-81-1
1-phenyl-2-chloropropane

B: 5814-85-7
1,2-diphenylpropane

Conditions

Conditions	Yield
at -10℃;
at -20 - -10℃;

...Expand

: 107-05-1
3-chloroprop-1-ene

: 71-43-2
benzene

ZnCl2: ZnCl2

A: 637-50-3
1-phenylpropene

B: 10304-81-1
1-phenyl-2-chloropropane

...Expand

: 7446-70-0
aluminium trichloride

: 75-52-5
nitromethane

: 107-05-1
3-chloroprop-1-ene

: 71-43-2
benzene

A: 10304-81-1
1-phenyl-2-chloropropane

B: 5814-85-7
1,2-diphenylpropane

Conditions

Conditions	Yield
at 5℃;

...Expand

(+-)-<2-hydroxy-propyl>-benzene: (+-)-<2-hydroxy-propyl>-benzene

: 10304-81-1
1-phenyl-2-chloropropane

Conditions

Conditions	Yield
With diethyl ether Einleiten von HCl;

: 103-65-1
Propylbenzene

A: 10304-81-1
1-phenyl-2-chloropropane

B: 104-52-9
phenylpropyl chloride

C: 934-11-2
(1-Chloro-propyl)-benzene

Conditions

Conditions	Yield
With chlorine In tetrachloromethane for 0.0833333h; Photolysis;

...Expand

: 1-phenyl-2-phenyltelluropropane

: 10304-81-1
1-phenyl-2-chloropropane

Conditions

Conditions	Yield
With sulfuryl dichloride; sodium chloride at 60℃; Kinetics; Activation energy; Further Variations:; Temperatures;

: 107-05-1
3-chloroprop-1-ene

: 71-43-2
benzene

A: 300-57-2
allylbenzene

B: 10304-81-1
1-phenyl-2-chloropropane

Conditions

Conditions	Yield
With oxygen at 110℃;

...Expand

: 10304-81-1
1-phenyl-2-chloropropane

: 96-22-0
pentan-3-one

: 3-ethyl-2-methyl-1-phenylpentan-3-ol

Conditions

Conditions	Yield
Stage #1: 1-phenyl-2-chloropropane; pentan-3-one With 4,4'-di-tert-butylbiphenyl; lithium In tetrahydrofuran at 25℃; for 1h; Schlenk technique; Inert atmosphere; Stage #2: With water In tetrahydrofuran at 0 - 25℃; Schlenk technique; Cooling with ice;	74%

: 76-09-5
2,3-dimethyl-2,3-butane diol

: 10304-81-1
1-phenyl-2-chloropropane

: 1,3-dimethyl-2-(tributylstannyl)-2,3-dihydro-1H-benzo[d][1,3,2]diazaborole

: 916658-74-7
2-(1-phenylpropan-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Conditions

Conditions	Yield
Stage #1: 1-phenyl-2-chloropropane; 1,3-dimethyl-2-(tributylstannyl)-2,3-dihydro-1H-benzo[d][1,3,2]diazaborole With 1,1'-azobis(1-cyanocyclohexanenitrile) In n-heptane at 100℃; for 6h; Inert atmosphere; Glovebox; Sealed tube; Stage #2: 2,3-dimethyl-2,3-butane diol With hydrogenchloride In 1,4-dioxane; n-heptane; water at 20℃; for 2h; Inert atmosphere; Glovebox; Sealed tube;	60%

...Expand

: 1066-35-9
dimethylmonochlorosilane

: 10304-81-1
1-phenyl-2-chloropropane

: dimethyl(1-phenylpropan-2-yl)silane

Conditions

Conditions	Yield
With iodine; magnesium In tetrahydrofuran for 17h; Inert atmosphere; Reflux;	47%

: 10304-81-1
1-phenyl-2-chloropropane

: 25015-63-8
4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

: 916658-74-7
2-(1-phenylpropan-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Conditions

Conditions	Yield
Stage #1: 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane With bis(cyclopentadienyl)titanium dichloride; lithium methanolate In tert-butyl methyl ether for 0.5h; Stage #2: 1-phenyl-2-chloropropane In tert-butyl methyl ether at 100℃; under 760.051 Torr; for 24h; Inert atmosphere;	41%
Stage #1: 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane With bis(cyclopentadienyl)titanium dichloride; lithium methanolate In tert-butyl methyl ether for 0.5h; Inert atmosphere; Glovebox; Stage #2: 1-phenyl-2-chloropropane In tert-butyl methyl ether at 100℃; for 24h; Sealed tube;	41%

: 1859-37-6
C-(1-methyl-4-phenyl-piperidin-4-yl)-methylamine

: 10304-81-1
1-phenyl-2-chloropropane

: 96061-20-0
(1-methyl-2-phenyl-ethyl)-(1-methyl-4-phenyl-[4]piperidylmethyl)-amine

Conditions

Conditions	Yield
at 110℃;

: 10304-81-1
1-phenyl-2-chloropropane

: 60-15-1, 156-34-3, 51-64-9, 300-62-9
2-amino-1-phenylpropane

Conditions

Conditions	Yield
With ethanol; ammonia at 160℃;

: 10304-81-1
1-phenyl-2-chloropropane

: 74-89-5
methylamine

: 7632-10-2
methamphetamin

Conditions

Conditions	Yield
With ethanol at 160℃;

: 124-38-9
carbon dioxide

: 10304-81-1
1-phenyl-2-chloropropane

: 1009-67-2
2-methyl-3-phenylpropanoic acid

Conditions

Conditions	Yield
With magnesium In diethyl ether

: 10304-81-1
1-phenyl-2-chloropropane

: 122-51-0
orthoformic acid triethyl ester

: 5445-77-2
2-benzylpropionaldehyde

Conditions

Conditions	Yield
(i) Mg, Et2O, (ii) aq. HCl; Multistep reaction;

: 201230-82-2
carbon monoxide

: 10304-81-1
1-phenyl-2-chloropropane

: 71-43-2
benzene

: 1005420-27-8, 10474-32-5, 887255-49-4
(±)-2-methyl-2-phenyl-2,3-dihydro-1H-inden-1-one

Conditions

Conditions	Yield
With aluminium trichloride at 23 - 25℃;

...Expand

: 67-56-1
methanol

: 10304-81-1
1-phenyl-2-chloropropane

A: 300-57-2
allylbenzene

B: 873-66-5
1-propenylbenzene

C: 59588-12-4
(1-methoxypropyl)benzene

D: 10066-31-6
methyl 1-phenyl-2-propyl ether

E: 100-52-7
benzaldehyde

Conditions

Conditions	Yield
With Methyl fluoride; oxygen at 37.5℃; Product distribution; Irradiation; 0.6 Torr substrate, 700 Torr bulk gas, 4 Torr O2 and 1.9 Torr methanol partial pressures;

...Expand

: 67-56-1
methanol

: 10304-81-1
1-phenyl-2-chloropropane

A: 300-57-2
allylbenzene

B: 766-90-5
cis-1-phenyl-1-propylene

C: 59588-12-4
(1-methoxypropyl)benzene

D: 10066-31-6
methyl 1-phenyl-2-propyl ether

E: 100-52-7
benzaldehyde

Conditions

Conditions	Yield
With C3H8 bulk gas; oxygen at 37.5℃; Product distribution; Irradiation; 0.5 Torr substrate, 700 Torr bulk gas, 4 Torr O2 and 2.0 Torr methanol partial pressures;

...Expand

: 67-56-1
methanol

: 10304-81-1
1-phenyl-2-chloropropane

A: 873-66-5
1-propenylbenzene

B: 766-90-5
cis-1-phenyl-1-propylene

C: 59588-12-4
(1-methoxypropyl)benzene

D: 10066-31-6
methyl 1-phenyl-2-propyl ether

E: 100-52-7
benzaldehyde

Conditions

Conditions	Yield
With oxygen; deuterium at 37.5℃; Product distribution; Irradiation; 0.5 Torr substrate, 750 Torr bulk gas, 4 Torr O2 and 2.5 Torr methanol partial pressures;
With methane; oxygen at 37.5℃; Product distribution; Irradiation; different partial pressures of components and in the given case: in the presence of 4 Torr NMe3 partial pressure;

...Expand

: 106-42-3
para-xylene

: 10304-81-1
1-phenyl-2-chloropropane

A: 37446-36-9
1-phenyl-11-(2,5-dimethylphenyl)propane

B: 1-phenyl-2-(2,5-dimethylphenyl)propane

Conditions

Conditions	Yield
With iron(III) chloride In carbon disulfide at 40℃; for 0.2h; Yield given. Yields of byproduct given;
With iron(III) chloride In carbon disulfide at 0℃; for 3h; Yield given. Yields of byproduct given;

...Expand

: 10304-81-1
1-phenyl-2-chloropropane

: 98796-29-3
Spiro(piperidine-4,6'-dibenz-1,4-oxathiepin)

: 98796-30-6
C26H27NOS*ClH

Conditions

Conditions	Yield
With sodium hydroxide In dimethyl sulfoxide at 120℃; for 3.5h;	0.2 g

Benzene,(2-chloropropyl)- Specification

The Benzene,(2-chloropropyl)- is an organic compound with the formula C₉H₁₁Cl. The IUPAC name of this chemical is 2-chloropropylbenzene. With the CAS registry number 10304-81-1, it is also named as 1-Phenyl-2-chloropropane.

Physical properties about Benzene,(2-chloropropyl)- are: (1)ACD/LogP: 3.22; (2)#Freely Rotating Bonds: 2; (3)Index of Refraction: 1.513; (4)Molar Refractivity: 45.24 cm³; (5)Molar Volume: 150.5 cm³; (6)Polarizability: 17.93×10^-24cm³; (7)Surface Tension: 32.5 dyne/cm; (8)Density: 1.027 g/cm³; (9)Flash Point: 79.7 °C; (10)Enthalpy of Vaporization: 42.91 kJ/mol; (11)Boiling Point: 211.1 °C at 760 mmHg; (12)Vapour Pressure: 0.27 mmHg at 25°C.

You can still convert the following datas into molecular structure:
(1)SMILES: ClC(Cc1ccccc1)C
(2)InChI: InChI=1/C9H11Cl/c1-8(10)7-9-5-3-2-4-6-9/h2-6,8H,7H2,1H3
(3)InChIKey: CKWAHIDVXZGPES-UHFFFAOYAH
(4)Std. InChI: InChI=1S/C9H11Cl/c1-8(10)7-9-5-3-2-4-6-9/h2-6,8H,7H2,1H3
(5)Std. InChIKey: CKWAHIDVXZGPES-UHFFFAOYSA-N

Product Name

2-chloropropylbenzene

Synthetic route

Benzene,(2-chloropropyl)- Specification

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