Bromotrifluoromethane supplier

Name
BROMOTRIFLUOROMETHANE
EINECS 200-887-6
CAS No. 75-63-8
Article Data104
CAS DataBase
Density 1.58
Solubility 0.03 wt % at 20 °C (NIOSH, 1997)
Melting Point -168°C
Formula CBr F3
Boiling Point -58°C
Molecular Weight 148.91
Flash Point
Transport Information
Appearance
Safety Mildly toxic by inhalation. Incompatible with aluminum. When heated to decomposition it emits toxic fumes of F⁻ and Br⁻. See also BROMIDES and FLUORIDES.
Analytical Methods:

For occupational chemical analysis use NIOSH: see Bromotrifluoromethane, 1017.
Risk Codes 20
Molecular Structure
Hazard Symbols TLV: 1000 ppm.
Synonyms Bromofluoroform;Bromotrifluoromethane;CFC 13B1;Carbon bromide fluoride (CBrF3);Carbonmonobromide trifluoride;Daiflon 13B1;F 13B1;FC 13B1;FKWR 13B1;Flugex 13B1;Fluorocarbon 1301;Freon 13B1;Halon 1301;Halon 13B1;Khladon 13B1;Monobromotrifluoromethane;Perfluoromethyl bromide;R 13B1;Refrigerant 13B1;Trifluorobromomethane;Trifluoromethyl bromide;Trifluoromonobromomethane;
PSA 0.00000
LogP 1.90110

Synthetic route

: 2714-60-5
tetrakis(trifluoromethyl)diphosphine

: 75-63-8
Bromotrifluoromethane

Conditions

Conditions	Yield
With bromine byproducts: phophorus bromide; 280°C (48 h);	94%

: 76-05-1
trifluoroacetic acid

: 75-63-8
Bromotrifluoromethane

Conditions

Conditions	Yield
With bromine(I) fluorosulfate for 2h; Ambient temperature;	88%
With bromine; pyrographite at 540℃;

: 116-14-3
polytetrafluoroethylene

: 70142-16-4
Bromine(I) trifluoromethanesulfonate

A: 75-63-8
Bromotrifluoromethane

B: 3582-05-6
trifluoromethyl trifluoromethanesulfonate

C: 73323-42-9
Trifluoro-methanesulfonic acid 2-bromo-1,1,2,2-tetrafluoro-ethyl ester

Conditions

Conditions	Yield
at -111 - -55℃; for 10h;	A n/a B n/a C 83%

...Expand

: 75-46-7
trifluoromethan

A: 75-63-8
Bromotrifluoromethane

B HBr: HBr

Conditions

Conditions	Yield
With bromine; aluminum(III) fluoride; CoCl2 + PdCl2; nickel dichloride at 456.9℃; for 0.00277778h;	A 76.4% B n/a
With bromine Product distribution; Heating; optimization in dependence on temperature and catalysts: KF, CaCl2, NaF, CuCl2, KBr, FeCl3, TiCl2, CoCl2, CrCl3, NiCl2 on activated charcoal or AlF3;

: 354-34-7
trifluoroacetyl fluoride

A: 75-63-8
Bromotrifluoromethane

B: 354-31-4
trifluoroacetyl bromide

Conditions

Conditions	Yield
With lithium bromide at 330℃; for 5h;	A 31% B 65%

: 79-35-6
1,1'-dichloro-2,2'-difluoroethene

: 178984-96-8
C4BrF9O

A: 75-63-8
Bromotrifluoromethane

B: 684-16-2
Hexafluoroacetone

C: 2-(2-Bromo-2,2-dichloro-1,1-difluoro-ethoxy)-1,1,1,3,3,3-hexafluoro-2-trifluoromethyl-propane

D: 2-(2-Bromo-1,1-dichloro-2,2-difluoro-ethoxy)-1,1,1,3,3,3-hexafluoro-2-trifluoromethyl-propane

Conditions

Conditions	Yield
at -88 - 25℃; for 12h; Yields of byproduct given. Title compound not separated from byproducts;	A n/a B n/a C 37% D n/a
at -83 - 24℃; for 12h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

...Expand

: sodium hypobromide

: 354-38-1
2,2,2-trifluoroacetamide

A: 75-63-8
Bromotrifluoromethane

B: 2923-18-4
sodium 2,2,2-trifluoroacetate

Conditions

Conditions	Yield
In alcaline soln. at 0°C.;	A 34% B n/a
In alcaline soln. at 0°C.;	A 34% B n/a

...Expand

: 116-14-3
polytetrafluoroethylene

: 178984-96-8
C4BrF9O

A: 75-63-8
Bromotrifluoromethane

B: 684-16-2
Hexafluoroacetone

C: 2-(2-Bromo-1,1,2,2-tetrafluoro-ethoxy)-1,1,1,3,3,3-hexafluoro-2-trifluoromethyl-propane

Conditions

Conditions	Yield
at -85 - 25℃; for 12h; Yields of byproduct given. Title compound not separated from byproducts;	A n/a B n/a C 33%

...Expand

: sodium hypobromide

: 354-38-1
2,2,2-trifluoroacetamide

: 75-63-8
Bromotrifluoromethane

Conditions

Conditions	Yield
In alcaline soln. at 60-70°C.;	11%
In alcaline soln. at 60-70°C.;	11%
In water formation on heating;;
In water formation on heating;;

: 76-19-7
freon-218

: 75-63-8
Bromotrifluoromethane

Conditions

Conditions	Yield
With bromine at 850℃;

: 75-46-7
trifluoromethan

: 75-63-8
Bromotrifluoromethane

Conditions

Conditions	Yield
With bromine; KBr/C; iron(III) chloride at 450℃; for 5h; Product distribution; var. catalysts and temp.;	71 % Chromat.
With bromine at 699.9℃; Kinetics; Mechanism; various conc. and ratio of reactants; temperature;
With bromine at 500 - 600℃;
With bromine; chlorine at 450℃;
With bromine at 600℃; in einem mit Pyrexglasringen gefuellten Rohr;

: 75-61-6
dibromodifluoromethane

: 75-63-8
Bromotrifluoromethane

Conditions

Conditions	Yield
With aluminium fluoride oxide-nickel halide; hydrogen fluoride at 350 - 500℃;

: 558-13-4
carbon tetrabromide

: 75-63-8
Bromotrifluoromethane

Conditions

Conditions	Yield
With aluminium fluoride oxide-nickel halide; hydrogen fluoride at 300 - 500℃;
With chromium(III) oxyfluoride; hydrogen fluoride at 300℃;
With bromine; antimony(III) fluoride at 200℃;
With bromine; titanium(IV) fluoride at 120℃;
With bromine trifluoride at 0℃;

: 76-16-4
Hexafluoroethane

: 75-63-8
Bromotrifluoromethane

Conditions

Conditions	Yield
With bromine at 900 - 925℃;
With bromine Irradiation;

: 354-38-1
2,2,2-trifluoroacetamide

: 75-63-8
Bromotrifluoromethane

Conditions

Conditions	Yield
With sodium hypobromide; water

: 464-10-8
bromopicrin

: 75-63-8
Bromotrifluoromethane

Conditions

Conditions	Yield
With hydrogen fluoride; mercury(II) oxide

: 359-45-5
N-bromo-trifluoroacetamide

: 75-63-8
Bromotrifluoromethane

Conditions

Conditions	Yield
With sodium hydroxide
With sodium hydroxide Boiling for 5h.;
With NaOH Boiling for 5h.;

: 2966-50-9
silver trifluoroacetate

: 75-63-8
Bromotrifluoromethane

Conditions

Conditions	Yield
With bromine at 65 - 130℃;

: 407-25-0
trifluoroacetic anhydride

: 75-63-8
Bromotrifluoromethane

Conditions

Conditions	Yield
With bromine; pyrographite at 300℃;

: 354-33-6
1,1,1,2,2-pentafluoroethane

A: 1511-62-2
bromodifluoromethane

B: 75-63-8
Bromotrifluoromethane

C: 75-61-6
dibromodifluoromethane

D: 124-73-2
1,2-dibromo-1,1,2,2-tetrafluoroethane

Conditions

Conditions	Yield
With bromine under 20 Torr; Product distribution; Mechanism; Irradiation; variation of laser pulse energy;

...Expand

: 2252-84-8
HFC-227ca

A: 1511-62-2
bromodifluoromethane

B: 661-95-0
1,2-dibromohexafluoropropane

C: 75-63-8
Bromotrifluoromethane

D: 75-61-6
dibromodifluoromethane

E: 354-07-4
1-bromo-1,1,2,2-tetrafluoro-ethane

F: 354-55-2
bromopentafluoroethane

Conditions

Conditions	Yield
With bromine under 0.05 Torr; Rate constant; Product distribution; Irradiation; Infrared multiphoton dissociation with Br2 as a scavenger.;

...Expand

: 75-72-9
chlorotrifluoromethane

: 75-63-8
Bromotrifluoromethane

Conditions

Conditions	Yield
With bromine; sulphur hexafluoride Irradiation;

: 89554-90-5
C2BrF4N

A: 1495-50-7
cyanogen fluoride

B: 75-63-8
Bromotrifluoromethane

Conditions

Conditions	Yield
at 450 - 500℃; other substrates;

: 75-46-7
trifluoromethan

A: 75-72-9
chlorotrifluoromethane

B: 75-63-8
Bromotrifluoromethane

Conditions

Conditions	Yield
With bromine; chlorine at 391.9℃; Kinetics; var. reaction time, var. concentrations of the initial reactants;

: 1511-62-2
bromodifluoromethane

A: 75-73-0
carbon tetrafluoride

B: 353-50-4
Carbonyl fluoride

C: 75-63-8
Bromotrifluoromethane

D: 1718-18-9
Bis-trifluormethyl-trioxid

Conditions

Conditions	Yield
With fluorine at 22.9℃; Product distribution; Equilibrium constant; Kinetics; Irradiation; also in the presence CH4;

...Expand

: sodium 1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-olate

A: 75-63-8
Bromotrifluoromethane

B: 684-16-2
Hexafluoroacetone

C: 178984-96-8
C4BrF9O

Conditions

Conditions	Yield
With bromine(I) fluorosulfate 1.) -25 deg C, 1.25 h, 2.) -25 deg C to 24 deg C, 1.25 h;

...Expand

: 7726-95-6
bromine

: 76-05-1
trifluoroacetic acid

aluminium bromide/ coal: aluminium bromide/ coal

: 75-63-8
Bromotrifluoromethane

Conditions

Conditions	Yield
at 300℃;

...Expand

: 7726-95-6
bromine

: 76-05-1
trifluoroacetic acid

A: 1511-62-2
bromodifluoromethane

B: 75-46-7
trifluoromethan

C: 75-63-8
Bromotrifluoromethane

D: 75-61-6
dibromodifluoromethane

Conditions

Conditions	Yield
at 400℃; in der Dampfphase; Produkt5: Hexafluoraethan;

...Expand

: 108-86-1
bromobenzene

: 55642-42-7
bis(trifluoromethyl)tellurium

A: 401-78-5
3-bromo-1-trifluoromethylbenzene

B: 75-63-8
Bromotrifluoromethane

C: 1718-20-3
bis(trifluoromethyl) ditelluride

D: 98-08-8
α,α,α-trifluorotoluene

E: 392-83-6
o-trifluoromethylphenyl bromide

F: 402-43-7
p-trifluoromethylphenyl bromide

G tellur: tellur

Conditions

Conditions	Yield
at 168℃; for 120h; Product distribution;

...Expand

: 75-63-8
Bromotrifluoromethane

: 100-52-7
benzaldehyde

: 340-04-5, 340-05-6
1-phenyl-2,2,2-trifluoromethylethanol

Conditions

Conditions	Yield
In N,N-dimethyl-formamide at 0 - 30℃; cathodic reduction;	98%
With tetrabutylammomium bromide In N,N-dimethyl-formamide at -10℃; for 5h; zinc rod anode, nickel cathode, 0.3 A;	95%
With chloro-trimethyl-silane In N,N-dimethyl-formamide at -50℃; 20 mF, Pb cathode;	60%

: 623-26-7
terephthalonitrile

: 111-34-2
-butyl vinyl ether

: 75-63-8
Bromotrifluoromethane

: 126958-92-7
4-(1-trifluoromethyl-2-n-butyloxyethyl)benzonitrile

Conditions

Conditions	Yield
With tetrabutylammonium tetrafluoroborate In N,N-dimethyl-formamide at 20℃; electrolysis;	95%
With tetrabutylammonium tetrafluoroborate In N,N-dimethyl-formamide at 20℃; Mechanism; electrolysis;

...Expand

: 75-77-4
chloro-trimethyl-silane

: 75-63-8
Bromotrifluoromethane

: 2283-11-6
hexaethylphosphoric triamide

A: 81290-20-2
(trifluoromethyl)trimethylsilane

B: 89217-83-4
(N(C2H5)2)3PClBr

Conditions

Conditions	Yield
In dichloromethane	A 95% B n/a

...Expand

: 75-63-8
Bromotrifluoromethane

: 1608-26-0
Hexamethylphosphorous triamide

: trifluoromethyltris(dimethylamino)phosphonium bromide

Conditions

Conditions	Yield
at 20℃; under 760 Torr;	95%

: 373-91-1
hypofluorous acid trifluoromethyl ester

: 75-63-8
Bromotrifluoromethane

A: 353-50-4
Carbonyl fluoride

B: 753-56-0
carbonyl bromide fluoride

C: 38126-07-7
difluorobromoacetyl fluoride

Conditions

Conditions	Yield
With oxygen at -0.15℃; for 0.166667h; gas-phase;	A n/a B n/a C 95%

...Expand

: 637-69-4
4-Methoxystyrene

: 75-63-8
Bromotrifluoromethane

: 1216911-72-6
3,3,3-trifluoro-1-(4-methoxyphenyl)-1-propanol

Conditions

Conditions	Yield
With cobalt(II) tetrafluoroborate hexahydrate; N-isopropyl-N,2-dimethylpropan-2-amine In water; acetonitrile at 20℃; for 24h;	94%

: 75-63-8
Bromotrifluoromethane

: 2350-89-2
p-vinylbiphenyl

: 1282444-70-5
1-([1,1'-biphenyl]-4-yl)-3,3,3-trifluoropropan-1-ol

Conditions

Conditions	Yield
With cobalt(II) tetrafluoroborate hexahydrate; N-isopropyl-N,2-dimethylpropan-2-amine In water; acetonitrile at 20℃; for 24h;	94%

: 75-63-8
Bromotrifluoromethane

: 882-33-7
diphenyldisulfane

: 456-56-4
phenyl trifluoromethylsulfide

Conditions

Conditions	Yield
With disodium hydrogenphosphate; rongalite In water; N,N-dimethyl-formamide under 3000.2 Torr; Product distribution; Ambient temperature; Na2S2O4, other disulphides;	93%
With disodium hydrogenphosphate; rongalite In water; N,N-dimethyl-formamide under 3000.2 Torr; Ambient temperature;	93%
With rongalite In water; N,N-dimethyl-formamide	93%
With disodium hydrogenphosphate; rongalite In water; N,N-dimethyl-formamide at 20℃; under 9000.9 Torr; for 2.5h;	91%

: 75-63-8
Bromotrifluoromethane

: 2283-11-6
hexaethylphosphoric triamide

: 89217-87-8
trifluoromethyltris(diethylamino)phosphonium bromide

Conditions

Conditions	Yield
at 20℃; under 760 Torr;	93%

: 2039-82-9
1-bromo-4-ethenyl-benzene

: 75-63-8
Bromotrifluoromethane

: 13541-19-0
1-(4-bromophenyl)-3,3,3-trifluoropropan-1-ol

Conditions

Conditions	Yield
With cobalt(II) tetrafluoroborate hexahydrate; N-isopropyl-N,2-dimethylpropan-2-amine In water; acetonitrile at 20℃; for 24h;	92%

: 75-63-8
Bromotrifluoromethane

: 159635-49-1
tert-butyl 4-methylidenepiperidine-1-carboxylate

: C12H20F3NO3

Conditions

Conditions	Yield
With cobalt(II) tetrafluoroborate hexahydrate; N-isopropyl-N,2-dimethylpropan-2-amine In water; acetonitrile at 20℃; for 24h;	92%

: 120069-10-5
5-amino-1-(2,6-dichloro-4-trifluoromethyl-phenyl)-4-thiocyanato-1H-pyrazole-3-carbonitrile

: 75-63-8
Bromotrifluoromethane

: 120067-83-6
5-amino-1-(2,6-dichloro-4-(trifluoromethyl)phenyl)-4-(trifluoromethylthio)-1H-pyrazole-3-carbonitrile

Conditions

Conditions	Yield
Stage #1: 5-amino-1-(2,6-dichloro-4-trifluoromethyl-phenyl)-4-thiocyanato-1H-pyrazole-3-carbonitrile With sulfur dioxide; sodium formate In DMF (N,N-dimethyl-formamide) at 20℃; for 0.0833333h; Stage #2: Bromotrifluoromethane In DMF (N,N-dimethyl-formamide) at 20 - 45℃; under 8625.86 Torr; for 1.5h; Product distribution / selectivity;	90.8%
Stage #1: 5-amino-1-(2,6-dichloro-4-trifluoromethyl-phenyl)-4-thiocyanato-1H-pyrazole-3-carbonitrile With sulfur dioxide In DMF (N,N-dimethyl-formamide) at 20℃; for 0.0333333h; Stage #2: Bromotrifluoromethane With sodium formate In DMF (N,N-dimethyl-formamide) at 20 - 54℃; for 2.33333h; Product distribution / selectivity;	84.7%
With sulfur dioxide; potassium formate In DMF (N,N-dimethyl-formamide); water at -60 - 55℃; for 3h; Product distribution / selectivity;	81%

: 75-63-8
Bromotrifluoromethane

: 124-13-0
Octanal

: 26902-80-7
1,1,1-trifluoro-2-nonanol

Conditions

Conditions	Yield
In N,N-dimethyl-formamide at 0 - 30℃; cathodic reduction;	90%
With chloro-trimethyl-silane In N,N-dimethyl-formamide at -50℃; 20 mF, Pb cathode;	62%

: 75-63-8
Bromotrifluoromethane

: 104-88-1
4-chlorobenzaldehyde

: 72487-06-0, 80418-11-7, 446-66-2
1-(4-chlorophenyl)-2,2,2-trifluoroethanol

Conditions

Conditions	Yield
With tetrabutylammomium bromide In N,N-dimethyl-formamide at -10℃; for 5h; zinc rod anode, nickel cathode, 0.3 A;	90%
With zinc In pyridine at 40℃; under 1500.1 - 3000.2 Torr; for 4h;	46%
With zinc; bis(triphenylphosphine)nickel(II) chloride; triphenylphosphine In N,N-dimethyl-formamide In a sealed tube;	34%

: 75-63-8
Bromotrifluoromethane

: 39515-51-0
3-Phenoxybenzaldehyde

: 67851-11-0
1-(m-phenoxy-phenyl)-2,2,2-trifluoro-ethanol

Conditions

Conditions	Yield
With tetrabutylammomium bromide In N,N-dimethyl-formamide at -10℃; for 5h; zinc rod anode, nickel cathode, 0.3 A;	90%

: 75-63-8
Bromotrifluoromethane

: 1529-47-1
chlorotrimethylgermane

: 21907-59-5
Trifluormethyl-trimethylgermanium

Conditions

Conditions	Yield
In 1,2-dimethoxyethane Electrochem. Process; electrochem. react. in DME/Bu4NBr with Al-anode and V4A steel cathode (wall of autoclave); identified by (19)F NMR studies;	90%

: 75-63-8
Bromotrifluoromethane

: 98-83-9
isopropenylbenzene

: 1417820-89-3
3,3,3-trifluoro-1-methyl-1-phenyl-1-propanol

Conditions

Conditions	Yield
With cobalt(II) tetrafluoroborate hexahydrate; N-isopropyl-N,2-dimethylpropan-2-amine In water; acetonitrile at 20℃; for 24h;	89%

: 75-63-8
Bromotrifluoromethane

: 129922-47-0
2-mercaptobiphenyl sodium salt

: 129922-51-6
2-<(trifluoromethyl)thio>biphenyl

Conditions

Conditions	Yield
In N,N-dimethyl-formamide at 0℃; Irradiation;	88%

: 75-63-8
Bromotrifluoromethane

: 106-45-6
para-thiocresol

: 352-68-1
4-trifluoromethylthiotoluene

Conditions

Conditions	Yield
In ammonia at -70 - -30℃; for 1h; Irradiation;	88%

: 622-97-9
1-ethenyl-4-methylbenzene

: 75-63-8
Bromotrifluoromethane

: 1250571-35-7
3,3,3-trifluoro-1-(p-tolyl)propan-1-ol

Conditions

Conditions	Yield
With cobalt(II) tetrafluoroborate hexahydrate; N-isopropyl-N,2-dimethylpropan-2-amine In water; acetonitrile at 20℃; for 24h;	87%

: 75-63-8
Bromotrifluoromethane

: 29264-40-2
5-pentenylbenzoate

: 4-bromo-6,6,6-trifluorohexyl benzoate

Conditions

Conditions	Yield
With fac-tris(2-phenylpyridinato-N,C2')iridium(III); 1,3-bis(2,4,6-trimethylphenyl)imidazoliumcarbene copper(I) bromide; triphenylphosphine In acetonitrile at -92 - -20℃; for 16h; Inert atmosphere; Sealed tube; Irradiation;	87%

: 75-63-8
Bromotrifluoromethane

: 20213-75-6
bis(dimethylamino)chlorosilane

: 109111-30-0
(trifluoromethyl)bis(dimethylamino)silane

Conditions

Conditions	Yield
With hexaethylphosphoric triamide In benzonitrile under 26.3 Torr; 1.) 0 deg. C., 1 h,;	86%
With hexaethylphosphoric triamide

: 75-63-8
Bromotrifluoromethane

: 811-62-1
chlorodimethylphosphine

: 421-57-8
dimethyl(trifluoromethyl)phosphine

Conditions

Conditions	Yield
With hexaethylphosphorous triamide In N,N,N,N,N,N-hexamethylphosphoric triamide at -50℃; for 2h;	86%
With hexaethylphosphoric triamide

: 75-63-8
Bromotrifluoromethane

: 15015-57-3
bis(4-hydroxyphenyl)disulfide

: 461-84-7
(4-trifluoromethylthio)phenol

Conditions

Conditions	Yield
With disodium hydrogenphosphate; rongalite In water; N,N-dimethyl-formamide at 20℃; under 9000.9 Torr; for 2.5h;	86%

: 75-63-8
Bromotrifluoromethane

: 130755-46-3
4,4'-dithiobis [5-amino-3-cyano-1-{2,6-dichloro-4-(trifluoromethyl)phenyl}-1H-pyrazole]

: 120067-83-6
5-amino-1-(2,6-dichloro-4-(trifluoromethyl)phenyl)-4-(trifluoromethylthio)-1H-pyrazole-3-carbonitrile

Conditions

Conditions	Yield
With sulfur dioxide; sodium formate In N,N-dimethyl-formamide at 60℃; under 9000.7 - 9750.8 Torr; for 4h; Mechanism; Product distribution; other reagent, other perhalogenoalkanes, other disulfide;	85%
With sulfur dioxide; sodium formate In N,N-dimethyl-formamide at 60℃; under 9000.7 - 9750.8 Torr; for 4h;	85%
With disodium hydrogenphosphate; sodium dithionite In water; N,N-dimethyl-formamide at 20℃; for 4h;	51%

: 75-63-8
Bromotrifluoromethane

A: 75-46-7
trifluoromethan

B: 432-04-2
tris(trifluoromethyl)phosphine

Conditions

Conditions	Yield
With triphenyl phosphite; hexaethylphosphoric triamide In N,N,N,N,N,N-hexamethylphosphoric triamide at 36℃; for 1h;	A n/a B 85%

: 75-63-8
Bromotrifluoromethane

: 434-45-7
1,1,1-trifluoroacetophenone

: 2283-11-6
hexaethylphosphoric triamide

: [1-phenyl-2,2,2-trifluoro-1-(trifluoromethyl)ethoxy]tris(diethylamino)phosphonium bromide

Conditions

Conditions	Yield
In tetrahydrofuran; dichloromethane; acetone	85%

...Expand

: 75-63-8
Bromotrifluoromethane

: 53498-47-8
N-(4-vinyl-phenyl)-acetamide

: C11H12F3NO2

Conditions

Conditions	Yield
With cobalt(II) tetrafluoroborate hexahydrate; N-isopropyl-N,2-dimethylpropan-2-amine In water; acetonitrile at 20℃; for 24h;	85%

Bromotrifluoromethane Chemical Properties

IUPAC Name: Bromo(trifluoro)methane (75-63-8)
Synonyms: Bromotrifluoro-methan ; Bromotrifluorormethane ; Bromtrifluormethan ; Carbon monobromide trifluoride ; Carbonbromidefluoride(CBrF₃) ; Carbonmonobromidetrifluoride ; CBrF₃
CAS: 75-63-8
Molecular Formula: CBrF₃
Molecular Weight: 148.91
Molecular Structure:
EINECS: 200-887-6
Product Categories: Industrial/Fine Chemicals;CFC;refrigerants;Organics
Mol File: 75-63-8.mol
Surface Tension: 15.3 dyne/cm
Density: 1.995 g/cm³
Enthalpy of Vaporization: 19.68 kJ/mol
Boiling Point: -58°C
Melting point:-168°C
Vapour Pressure: 9740 mmHg at 25°C

Bromotrifluoromethane Uses

Bromo(trifluoro)methane (75-63-8) is used fire-fighting for a variety of organic ,such as oil, electrical equipment, organic solvents, natural gas.

Bromotrifluoromethane Toxicity Data With Reference

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
dog	LC	inhalation	> 30pph/15M (300000ppm)	BEHAVIORAL: TREMOR GASTROINTESTINAL: CHANGES IN STRUCTURE OR FUNCTION OF SALIVARY GLANDS	National Technical Information Service. Vol. OTS0571524,
guinea pig	LC50	inhalation	88000ppm/15M (88000ppm)		"Documentation of the Threshold Limit Values and Biological Exposure Indices," 5th ed., Cincinnati, OH, American Conference of Governmental Industrial Hygienists, Inc., 1986Vol. 6, Pg. 1640, 1991.
man	LC	inhalation	> 15pph/1M (150000ppm)	BEHAVIORAL: "HALLUCINATIONS, DISTORTED PERCEPTIONS" CARDIAC: PULSE RATE INCREASE WITHOUT FALL IN BP	National Technical Information Service. Vol. OTS0571524,
mouse	LC50	inhalation	381gm/m3 (381000mg/m3)		Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 26(8), Pg. 53, 1982.
rat	LC50	inhalation	84000ppm/15M (84000ppm)		"Documentation of the Threshold Limit Values and Biological Exposure Indices," 5th ed., Cincinnati, OH, American Conference of Governmental Industrial Hygienists, Inc., 1986Vol. 6, Pg. 1640, 1991.

Bromotrifluoromethane Consensus Reports

Reported in EPA TSCA Inventory.

Bromotrifluoromethane Safety Profile

Risk Statements 20
20: Bromo(trifluoro)methane (75-63-8) is harmful by inhalation.
Safety Statements 23-36/37/39-38
23: Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer)
38: In case of insufficient ventilation, wear suitable respiratory equipment
36/37/39: Wear suitable protective clothing, gloves and eye/face protection
RIDADR 1009
HazardClass 2.2

Bromotrifluoromethane Standards and Recommendations

OSHA PEL: TWA 1000 ppm
ACGIH TLV: TWA 1000 ppm
DFG MAK: 1000 ppm (6200 mg/m³)
DOT Classification: 2.2; Label: Nonflammable Gas

Bromotrifluoromethane Analytical Methods

For occupational chemical analysis use NIOSH: see Bromotrifluoromethane, 1017.

Bromotrifluoromethane Specification

1.General Description A colorless, odorless gas at room conditions Shipped as a liquid confined under its own vapor pressure. Noncombustible. Nontoxic but can asphyxiate by the displacement of air. Contact with the unconfined liquid can cause frostbite by evaporative cooling. Exposure of the container to prolonged heat or fire can cause Bromotrifluoromethane to rupture violently and rocket.
3.Air & Water Reactions Slightly soluble in water.
4.Reactivity Profile: Bromotrifluoromethane may react with aluminum to produce substantial heat. Other halogenated hydrocarbons, such as fluorotrichloromethane, dichlorodifluoromethane, chlorodifluoromethane, tetrafluoromethane produce sufficient heat in this way to melt aluminum pieces. The vigor of the reaction appears to depend on the degree of fluorination and the vapor pressure
5..Health Hazard Vapors may cause dizziness or asphyxiation without warning. Vapors from liquefied gas are initially heavier than air and spread along ground. Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite. Fire may produce irritating, corrosive and/or toxic gases.
6.Fire Hazard Some may burn but none ignite readily. Containers may explode when heated. Ruptured cylinders may rocket.

Product Name

BROMOTRIFLUOROMETHANE

Synthetic route

Bromotrifluoromethane Chemical Properties

Bromotrifluoromethane Uses

Bromotrifluoromethane Toxicity Data With Reference

Bromotrifluoromethane Consensus Reports

Bromotrifluoromethane Safety Profile

Bromotrifluoromethane Standards and Recommendations

Bromotrifluoromethane Analytical Methods

Bromotrifluoromethane Specification

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