CAS No.98-08-8,Benzotrifluoride Suppliers,MSDS download

JINHUA HUAYI CHEMICAL CO., LTD.

Jinhua huayi chemical co., ltd. is dedicated to the development, production and marketing of chemicals. On the basis of equality and mutual benefit, and under the principle of customer first, credit first, quality first, we are ready to join hands

Benzotrifluoride

Cas:98-08-8

Min.Order:100 Gram

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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Benzotrifluoride supplier in China

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply α,α,α-trifluorotoluene

Cas:98-08-8

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Benzotrifluoride

Cas:98-08-8

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Hebei yanxi chemical co.,LTD.

Hebei Yanxi Chemical Co., Ltd. is a professional research, development and production of lead acetate benzene acetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low car

Benzotrifluoride

Cas:98-08-8

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LIDE PHARMACEUTICALS LIMITED

Advantage : LIDE PHARMACEUTICALS LTD. is a mid-small manufacturing-type enterprise, engaged in pharmaceutical intermediates of R&D, custom-made and production, and also involving trading chemicals for export. We have established the R&amp

Benzotrifluoride / LIDE PHARMA- Factory supply / Best price

Cas:98-08-8

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Henan Sinotech Import&Export Corporation

Chemical Name: Benzotrifluoride Synonym: Benzylidyne fluoride; Trifluoromethylbenzen CAS No.: 98-08-8 Molecular Formula: C7H5F3 Property: colorless transparent liquid with aromatic odor Specification: Purity(Benzotrifluoride): 99.

Factory price,Benzotrifluoride,CAS 98-08-8

Cas:98-08-8

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Trifluorotoluene

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Benzotrifluoride

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Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

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Cas:98-08-8

Min.Order:1 Gram

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality Benzotrifluoride

Cas:98-08-8

Min.Order:10 Gram

FOB Price: $100.0

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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 6 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so

Trifluorotoluene 98-08-8

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Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

alpha,alpha,alpha-Trifluorotoluene

Cas:98-08-8

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SAGECHEM LIMITED

SAGECHEM is a chemical R&D, manufacturing and distribution company in China since 2009, including pharmaceutical intermediates, agrochemical, dyestuff intermediates, organosilicone, API and etc. We also offer a full range of services in custom synthe

SAGECHEM/Trifluoromethylbenzene

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Beijing Greenchem Technology Co.,Ltd. ( Panjin Greenchem Technology Co.Ltd .)

Capability on chemical synthesis1. Beijing High-Tech Enterprises2. Strong R&D Team3. 8 years of experiences in R & D of high-tech Catalyst;4. 5000 production techniques, 69 items of national patents, and 360 kinds of products on sales;5. The producti

Trifluoromethylbenzene

Cas:98-08-8

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Wuhan Fortuna Chemical Co.,Ltd

Best service,high quality and cheap price. Storage:Keep away from heat,sparks and flames. Package:25kg/50kg/200kg drum or Customer demand Application:Used as pharmaceutical intermediates Transportation:BY sea/air or by courier

benzotrifluoride

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Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

benzotrifluoride

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Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stock Package:1kg Application:pharmaceutical intermediates

Benzene,(trifluoromethyl)-

Cas:98-08-8

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HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:white crystalline powder Storage:Sealed in a cool ,dry and microtherm place , avoid light . Package:25kg/drum;200kg/drum as per your request Application:It is an important raw mater

(trifluoromethyl)benzene supplier in China

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Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

Benzotrifluoride

Cas:98-08-8

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Jiangsu Huaen Energy Co., Ltd.

Talent Advantages: The Company features strong technical strength, possesses an efficient and cohesive management team, and enthusiastic and creative talents. The whole team has excellent execution ability, faces the market competition with firm be

Benzotrifluoride

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Enke Pharma-tech Co.,Ltd. （Cangzhou, China ）

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city?in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new api,?intermediat

Benzotrifluoride

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Zhuozhou Wenxi import and Export Co., Ltd

Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard

factory supply CAS 98-08-8 with competitive price

Cas:98-08-8

Min.Order:1 Kilogram

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Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Benzene,(trifluoromethyl)-

Cas:98-08-8

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Xiamen AmoyChem Co.,Ltd

Amoychem is committed to providing the top-quality chemical products and services Internationally. We offer our customers with friendly, professional service and reliable, high performance products that have been manufactured according to the accredi

Benzotrifluoride

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Hangzhou Ocean Chemical Co., Ltd.

1.High purity, like 99%, 99.9%, 99.95%, 99.99%, 99.999%2.Quality control, test sample before shipping and keep sample for 3 years after shipping;3. Prompt shipment with professional documents;4. Packing as your request, with photo before shipment;5.

(Trifluoromethyl)benzene

Cas:98-08-8

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Hangzhou ZeErRui Chemical Co., Ltd.

Hangzhou ZeErRui Chemical Co., Ltd. located in Lingang industrial areas, our plant covers an area of 6000 square meters.ZeErRui dedicated to the development, production and marketing of chemicals. We have earned ourselves a good reputation at home an

Trifluorotoluene manufacture

Cas:98-08-8

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Hunan Russell Chemicals Technology Co.,Ltd

low price and high purityAppearance:solid or liquid Storage:in sealed air resistant place Package:As customer require Application:Pharma;Industry;Agricultural Transportation:by sea or by airplane Port:any port in China

Benzotrifluoride, 99% 98-08-8

Cas:98-08-8

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Chemsigma International Co.,Ltd.

bulk?production Application:Pharmaceutical intermediates

Benzotrifluoride

Cas:98-08-8

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Synthetic route

: 98-07-7
Benzotrichlorid

: 98-08-8
α,α,α-trifluorotoluene

Conditions

Conditions	Yield
In polyethylene	100%
In polyethylene	100%
In polyethylene	98.5%

: 913653-92-6, 913744-90-8
cis-(4,5-bis(diphenylphosphino)-9,9-dimethylxanthene)phenyl(trifluoromethyl)palladium(II)

: 98-08-8
α,α,α-trifluorotoluene

Conditions

Conditions	Yield
With 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In benzene at 50 - 80℃; Kinetics;	100%

: [Ru(η6-α,α,α-trifluorotoluene)(η5-cyclopentadienyl)]PF6

: 98-08-8
α,α,α-trifluorotoluene

Conditions

Conditions	Yield
In [D3]acetonitrile at 20℃; for 27h; Irradiation;	100%

: 98-56-6
4-chlorobenzotrifluoride

: 98-08-8
α,α,α-trifluorotoluene

Conditions

Conditions	Yield
With C60H48BP3Pd; potassium formate; [2.2.2]cryptande In tetrahydrofuran at 60℃; for 72h; Schlenk technique; Inert atmosphere;	99%
With Ni-Al clusters In tetrahydrofuran for 1h; Dehalogenation; reduction; hydrogenolysis; dechlorination; Heating;	98%
With isopropyl alcohol In N,N-dimethyl-formamide at 20℃; for 36h; UV-irradiation; chemoselective reaction;	80%

: C29H41F3FeP2Pd

: 98-08-8
α,α,α-trifluorotoluene

Conditions

Conditions	Yield
With 1,1'-bis(diisopropylphosphino)ferrocene; 1-trifluoromethoxybenzene In para-xylene at 130℃; for 24h; Inert atmosphere;	99%

: 65-85-0
benzoic acid

: 98-08-8
α,α,α-trifluorotoluene

Conditions

Conditions	Yield
With pyridine; phenylsulphur trifluoride; hydrogen fluoride at 50℃; for 24h; Product distribution / selectivity; Neat (no solvent);	95%
With 4-tert-butyl-2,6-dimethylphenylsulfur trifluoride at 20 - 100℃; for 2h; sealed tube;	89%
With 4-tert-butyl-2,6-dimethylphenylsulfur trifluoride at 20 - 100℃; for 2h; Reactivity;	88%

: 110-66-7
n-pentanethiol

: 402-43-7
p-trifluoromethylphenyl bromide

A: 98-08-8
α,α,α-trifluorotoluene

B: C12H15F3S

Conditions

Conditions	Yield
With [(C6H3(OP(i-Pr)2)2)RhHCl]; sodium t-butanolate In toluene at 110℃; for 3h; Sealed tube; Inert atmosphere;	A 10 %Spectr. B 94%

...Expand

: 591-50-4
iodobenzene

: 680-15-9
2,2-difluoro-2-(fluorosulfonyl)acetate

: 98-08-8
α,α,α-trifluorotoluene

Conditions

Conditions	Yield
With potassium iodide In N,N-dimethyl-formamide at 70℃; for 2.5h;	93%
With copper In N,N-dimethyl-formamide at 65℃; for 4h; Mechanism; other substrates, other times, other temperatures, also in the presence of O2 or p-dinitrobenzene, also inthe darkness, also in absence of alkylhalides;	84%
With copper(l) iodide In N,N-dimethyl-formamide at 70℃; for 2.5h; Mechanism; var. solvent, temp., time;	84%
With copper In N,N-dimethyl-formamide at 65℃; for 4h;	84%
With copper(l) iodide In various solvent(s) at 55℃; for 8h;	70%

: 98-88-4
benzoyl chloride

: 98-08-8
α,α,α-trifluorotoluene

Conditions

Conditions	Yield
With pyridine; phenylsulphur trifluoride; hydrogen fluoride at 50℃; for 24h; Product distribution / selectivity; Neat (no solvent);	93%

: 56-23-5
tetrachloromethane

: 71-43-2
benzene

: 98-08-8
α,α,α-trifluorotoluene

Conditions

Conditions	Yield
With hydrogen fluoride at 100℃; for 5h;	92%
With hydrogen fluoride

: 998-30-1
Triethoxysilane

: 401-81-0
m-trifluoromethylphenyl iodide

A: 98-08-8
α,α,α-trifluorotoluene

B: 310-17-8
triethoxy(3-(trifluoromethyl)phenyl)silane

Conditions

Conditions	Yield
With triethylamine; acetylacetonato(1,5-cyclooctadiene)rhodium(I) In N,N-dimethyl-formamide at 80℃; for 2h;	A n/a B 92%

...Expand

: 591-50-4
iodobenzene

: potassium trimethoxy(trifluoromethyl)boranuide

: 98-08-8
α,α,α-trifluorotoluene

Conditions

Conditions	Yield
With copper(l) iodide; 1,10-Phenanthroline In dimethyl sulfoxide at 60℃; for 16h; Inert atmosphere;	91%

: 110907-55-6
tri(n-butyl)(2-methyl-naphth-1-yl)stannane

: 455-13-0
4-Iodobenzotrifluoride

A: 98-08-8
α,α,α-trifluorotoluene

B: 1254105-11-7
C18H13F3

Conditions

Conditions	Yield
With PdCl2(AsPh3)2; (triphenylarsine)gold(I) chloride; triphenyl-arsane; lithium chloride In acetonitrile at 80℃; for 24h; Stille Cross Coupling; Inert atmosphere;	A 6% B 90%

...Expand

: 401-78-5
3-bromo-1-trifluoromethylbenzene

: 998-30-1
Triethoxysilane

A: 98-08-8
α,α,α-trifluorotoluene

B: 310-17-8
triethoxy(3-(trifluoromethyl)phenyl)silane

Conditions

Conditions	Yield
With tetra-(n-butyl)ammonium iodide; triethylamine; acetylacetonato(1,5-cyclooctadiene)rhodium(I) In N,N-dimethyl-formamide at 80℃; for 2h;	A n/a B 89%

...Expand

: C41H33F3FeP2Pd

: 98-08-8
α,α,α-trifluorotoluene

Conditions

Conditions	Yield
With 1,1'-bis-(diphenylphosphino)ferrocene; 1-trifluoromethoxybenzene at 130℃; for 36h; Inert atmosphere;	89%

: 591-50-4
iodobenzene

: 1514-87-0
metyhyl chlorodifluoroacetate

: 98-08-8
α,α,α-trifluorotoluene

Conditions

Conditions	Yield
With potassium fluoride; copper(l) iodide In N,N-dimethyl-formamide at 120℃; for 8h; Product distribution; other methyl halodifluoroacetates, var. organic halides, var. temp., var. time;	88%
With potassium fluoride; copper(l) iodide In N,N-dimethyl-formamide at 100 - 120℃; for 8h;	88%
With 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone; potassium fluoride; copper(l) iodide at 120℃; for 4h;	62%

: 591-50-4
iodobenzene

: 1514-87-0
metyhyl chlorodifluoroacetate

A: 98-08-8
α,α,α-trifluorotoluene

B: 74-88-4
methyl iodide

Conditions

Conditions	Yield
With potassium fluoride; copper(l) iodide In N,N-dimethyl-formamide at 100 - 120℃; for 8h; Product distribution; Mechanism; other solvent; other organic halides;	A 88% B n/a

...Expand

: 392-83-6
o-trifluoromethylphenyl bromide

: 98-08-8
α,α,α-trifluorotoluene

Conditions

Conditions	Yield
With Triethoxysilane; C20H24N4Ni; sodium t-butanolate In toluene at 80℃; for 8h; Kumada Cross-Coupling; Inert atmosphere; Schlenk technique;	87%
Stage #1: o-trifluoromethylphenyl bromide With chloro-trimethyl-silane; ethylene dibromide; lithium chloride; zinc In tetrahydrofuran at 20℃; Inert atmosphere; Stage #2: With water; ammonium chloride In tetrahydrofuran Inert atmosphere; regioselective reaction;	93 %Chromat.
With 1,2,3,4-tetrakis(carbazol-9-yl)-5,6-dicyanobenzene; triethylamine In 1-methyl-pyrrolidin-2-one at 20℃; for 1h; Inert atmosphere; Irradiation;	45 %Chromat.
With methyl phenylphosphinate; tetrabutylammomium bromide; tetra-(n-butyl)ammonium iodide; ethylene dibromide; triethylamine In N,N-dimethyl-formamide; acetonitrile at 20℃; Electrochemical reaction;

: 312-75-4
trimethyl(4-trifluoromethylphenyl)silane

: 98-08-8
α,α,α-trifluorotoluene

Conditions

Conditions	Yield
With potassium trimethylsilonate In dimethyl sulfoxide at 60℃; under 760.051 Torr; for 12h; Catalytic behavior; Reagent/catalyst; Solvent; Sealed tube;	87%

: 402-43-7
p-trifluoromethylphenyl bromide

: 7440-66-6
zinc

A: 198345-82-3
(4-(trifluoromethyl)phenyl)zinc(II) bromide

B: 581-80-6
4,4'-bis(trifluoromethyl)biphenyl

C: 98-08-8
α,α,α-trifluorotoluene

Conditions

Conditions	Yield
With trifluoroacetic acid; cobalt(II) bromide; zinc dibromide In acetonitrile the mixt. in CH3CN was stirred at room temp., then arylbromide was added, stirred at room temp.; GC analysis;	A 86% B 10% C 4%

...Expand

: 2168-78-7
methyl dithiobenzoate

: 98-08-8
α,α,α-trifluorotoluene

Conditions

Conditions	Yield
With phenylsulphur trifluoride at 70℃; for 22h; Product distribution / selectivity; Neat (no solvent);	85%
With trans-phenylsulfur chlorotetrafluoride In dichloromethane at 20℃; for 40h; Product distribution / selectivity;
With phenyltetrafluoro-λ6-sulfanyl chloride In dichloromethane at 20℃; for 20h; Inert atmosphere;	99 %Spectr.

: 124-38-9
carbon dioxide

: 402-43-7
p-trifluoromethylphenyl bromide

A: 98-08-8
α,α,α-trifluorotoluene

B: 455-24-3
4-trifluoromethylbenzoic acid

Conditions

Conditions	Yield
With 1,2-bis(diphenylphosphino)ethane nickel(II) chloride In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide for 10h; Ambient temperature; electrochemically;	A 2.4 mmol B 84%

...Expand

: 201230-82-2
carbon monoxide

A: 455-19-6
4-Trifluoromethylbenzaldehyde

B: 98-08-8
α,α,α-trifluorotoluene

Conditions

Conditions	Yield
Stage #1: p-trifluoromethylphenyl bromide With triethylamine; catacxium A; palladium diacetate In tolulene Stage #2: carbon monoxide With hydrogen In toluene at 100℃; under 7500.75 Torr; for 4h; Product distribution / selectivity;	A 84% B 3%
Stage #1: p-trifluoromethylphenyl bromide With caesium carbonate; catacxium A; palladium diacetate In tolulene Stage #2: carbon monoxide With hydrogen In toluene at 100℃; under 7500.75 Torr; for 4h; Product distribution / selectivity;	A 83% B 8%
Stage #1: p-trifluoromethylphenyl bromide With 1,4-diaza-bicyclo[2.2.2]octane; catacxium A; palladium diacetate In 1-methyl-pyrrolidin-2-one Stage #2: carbon monoxide With hydrogen In 1-methyl-pyrrolidin-2-one at 100℃; under 7500.75 Torr; for 4h; Product distribution / selectivity;	A 82% B 7%

: 591-50-4
iodobenzene

: 81290-20-2
(trifluoromethyl)trimethylsilane

: 98-08-8
α,α,α-trifluorotoluene

Conditions

Conditions	Yield
Stage #1: (trifluoromethyl)trimethylsilane With silver fluoride In N,N-dimethyl-formamide at 20℃; for 0.333333h; Stage #2: With copper In N,N-dimethyl-formamide for 4h; Stage #3: iodobenzene In N,N-dimethyl-formamide at 90℃; for 5h;	84%
With C13H27CuN2O(1+) In N,N-dimethyl-formamide at 25℃; for 112h;	94 %Spectr.
Stage #1: (trifluoromethyl)trimethylsilane With copper(l) iodide; cesium fluoride In N,N-dimethyl-formamide at 20℃; for 0.333333h; Stage #2: iodobenzene In N,N-dimethyl-formamide at 20℃; for 30h;

: 98-56-6
4-chlorobenzotrifluoride

: 25015-63-8
4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

A: 98-08-8
α,α,α-trifluorotoluene

B: 214360-65-3
4-trifluoromethylphenylboronic acid pinacol ester

Conditions

Conditions	Yield
With tetra-(n-butyl)ammonium iodide; triethylamine; bis(dibenzylideneacetone)-palladium(0); 2,2'-bis(di-tert-butylphosphino)diphenyl ether In 1,4-dioxane at 100℃; for 24h;	A n/a B 84%

...Expand

: 455-13-0
4-Iodobenzotrifluoride

: 68971-91-5
tri-n-butyl(mesityl)stannane

A: 581-80-6
4,4'-bis(trifluoromethyl)biphenyl

B: 98-08-8
α,α,α-trifluorotoluene

C: 66818-57-3
2,4,6-trimethyl-4'-(trifluoromethyl)-1,1'-biphenyl

Conditions

Conditions	Yield
With PdCl2(AsPh3)2; (triphenylarsine)gold(I) chloride; triphenyl-arsane; lithium chloride In acetonitrile at 80℃; for 24h; Reagent/catalyst; Stille Cross Coupling; Inert atmosphere;	A 8% B 6% C 84%
With bis-triphenylphosphine-palladium(II) chloride; (triphenylarsine)gold(I) chloride; triphenyl-arsane; lithium chloride In acetonitrile at 80℃; for 84h;

...Expand

: 455-13-0
4-Iodobenzotrifluoride

: 960-16-7
tributylphenylstannane

A: 581-80-6
4,4'-bis(trifluoromethyl)biphenyl

B: 98-08-8
α,α,α-trifluorotoluene

C: 398-36-7
1-phenyl-4-(trifluoromethyl)benzene

Conditions

Conditions	Yield
With PdCl2(AsPh3)2; (triphenylarsine)gold(I) chloride; triphenyl-arsane; lithium chloride In acetonitrile at 80℃; for 5h; Stille Cross Coupling; Inert atmosphere;	A 7% B 10% C 83%

...Expand

: 2926-29-6
Langlois reagent

: 62-53-3
aniline

: 98-08-8
α,α,α-trifluorotoluene

Conditions

Conditions	Yield
Stage #1: aniline With hydrogenchloride; sodium nitrite In water at 0 - 20℃; for 0.333333h; Stage #2: Langlois reagent With tert.-butylhydroperoxide; sodium hydrogencarbonate; copper(l) chloride In water; acetonitrile at 20℃; for 20h;	83%

: 1423-27-4
2-(trifluoromethyl)phenylboronic acid

: 98-08-8
α,α,α-trifluorotoluene

Conditions

Conditions	Yield
With sodium hypochlorite; tetrabutylammomium bromide; water at 100℃;	83%

: 591-50-4
iodobenzene

: 2314-97-8
iodotrifluoromethane

: 98-08-8
α,α,α-trifluorotoluene

Conditions

Conditions	Yield
With zinc; bis-triphenylphosphine-palladium(II) chloride In tetrahydrofuran for 0.5h; ultrasound;	82%
With pyridine; copper at 140℃; for 20h; Yield given;

: 98-08-8
α,α,α-trifluorotoluene

: α,α,α-triiodotoluene

Conditions

Conditions	Yield
With hafnium(IV) iodide for 5h; Reagent/catalyst; Glovebox; Inert atmosphere;	100%
With aluminium(III) iodide In chlorobenzene at 80℃; for 21h;

: 98-08-8
α,α,α-trifluorotoluene

: C84H104B2Fe2N14

: C49H57BF3FeN6

Conditions

Conditions	Yield
Inert atmosphere;	99%

: 98-08-8
α,α,α-trifluorotoluene

: 392-83-6
o-trifluoromethylphenyl bromide

Conditions

Conditions	Yield
With bis-triphenylphosphine-palladium(II) chloride; sulfuric acid; potassium bromide; copper(I) bromide at 20℃; for 8h; Reagent/catalyst;	98.7%
With n-butyllithium; diethyl ether anschliessendes Einleiten von mit Stickstoff verduenntem Brom-Dampf;

: 303009-58-7
cis-[Rh(cyclooctene)(PiPr3)(acetone)2]PF6

: 98-08-8
α,α,α-trifluorotoluene

: 311817-62-6
[(η6-C6H5CF3)Rh(cyclooctene)(PiPr3)]PF6

Conditions

Conditions	Yield
In neat (no solvent) a few s under Ar at room temp.; ppt. washed wiyh pentane and dried; elem. anal.;	98%

: 98-08-8
α,α,α-trifluorotoluene

: 98-07-7
Benzotrichlorid

Conditions

Conditions	Yield
With aluminum (III) chloride In hexane; 1,2-dichloro-ethane at -78℃; for 24h; Inert atmosphere;	98%
With aluminum (III) chloride; tetrachlorosilane at 80℃; for 20h; Reagent/catalyst;	94%

: 98-08-8
α,α,α-trifluorotoluene

: tert-butyl (R)-(2-((3,5-Difluoro-4-(trimethylsilyl)phenyl)amino)-1-(4-methoxyphenyl)-2-oxoethyl)(methyl)carbamate

: N-(3,5-difluoro-4-(trimethylsilyl)phenyl)-2-(4-methoxyphenyl)-2-(methylamino)acetamide

Conditions

Conditions	Yield
With trifluoroacetic acid at 20℃; for 0.05h;	98%

: 53416-46-9
2-(4-methoxyphenyl)-4,4-dimethyl-2-oxazoline

: 98-08-8
α,α,α-trifluorotoluene

1-halo-3-(trifluoromethyl)benzene: 1-halo-3-(trifluoromethyl)benzene

: C19H18F3NO2

Conditions

Conditions	Yield
Stage #1: 2-(4-methoxyphenyl)-4,4-dimethyl-2-oxazoline With di-sec-butylmagnesium In toluene at 40℃; for 0.166667h; Stage #2: α,α,α-trifluorotoluene; 1-halo-3-(trifluoromethyl)benzene With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; zinc(II) chloride regioselective reaction;	98%

...Expand

: 15617-18-2, 39958-10-6, 14220-64-5
bis(benzonitrile)palladium(II) dichloride

: CH2(C2H4P(C2H4(CF2)7CF3)2)2

: 98-08-8
α,α,α-trifluorotoluene

: trans,trans-Cl2Pd[(CF3(CF2)7CH2CH2)2P(CH2)5P(CH2CH2(CF2)7CF3)2]2PdCl2*2CF3C6H5

Conditions

Conditions	Yield
In further solvent(s) (N2); stirred for 4 h in CF3C6H5; evapd. (vac.), extd. (hot THF), evapd. (vac.); elem. anal.;	97%

...Expand

: 98-08-8
α,α,α-trifluorotoluene

: 2489-03-4
tribromomethylbenzene

Conditions

Conditions	Yield
With aluminum tri-bromide In chlorobenzene at 80℃; for 21h;	96%
With aluminum tri-bromide; trimethylsilyl bromide at 80℃; Inert atmosphere;	96%
With boron tribromide In tetrachloromethane at 20℃; for 36h; Inert atmosphere;	60%
With boron tribromide In tetrachloromethane at 20℃; for 36h; Inert atmosphere;	60%
With boron tribromide

: 98-08-8
α,α,α-trifluorotoluene

: (R)-3-bromo-N-(1-(naphthalen-1-yl)ethyl)propan-1-amine

: 226256-56-0
cinacalcet

Conditions

Conditions	Yield
With aluminum (III) chloride In dichloromethane at 0℃; for 2h;	95.6%

: 3195-78-6
N-vinyl-N-methylacetamide

: 98-08-8
α,α,α-trifluorotoluene

: N-(3,3-difluoro-3-phenylpropyl)-N-methylacetamide

Conditions

Conditions	Yield
With 3,7-di([1,1′-biphenyl]-4-yl)-10-(naphthalen-1-yl)-10H-phenoxazine; potassium formate; thiophenol In dimethyl sulfoxide at 100℃; for 24h; Inert atmosphere; Irradiation; Sealed tube;	95%

: 98-08-8
α,α,α-trifluorotoluene

: 98-46-4
3-trifluoromethylnitrobenzene

Conditions

Conditions	Yield
With sulfuric acid; nitric acid at 20℃; for 3h;	94%
With sulfuric acid; nitric acid In 1,2-dichloro-ethane at 30 - 40℃; for 8h; Large scale;	93.1%
With bromine; Nitrogen dioxide In sulfuric acid at 20℃; for 5h; Product distribution; other time, other solvent, under argon;	69%

: 98-08-8
α,α,α-trifluorotoluene

: 401-75-2
trifluoromethylcyclohexane

Conditions

Conditions	Yield
With hydrogen In neat (no solvent) at 50℃; under 760.051 Torr; for 64h; Temperature;	94%
With hydrogen In pentane at 40℃; under 30400 Torr;
With hydrogen In tetrahydrofuran at 120℃; under 7500.75 Torr; for 1h;

: 98-08-8
α,α,α-trifluorotoluene

: 1280197-76-3
2,4,6-tris(1-phenyl-1H-tetrazolsulfanylmethyl)mesitylene

: 1280198-02-8
C7H5F3*C33H30N12S3

Conditions

Conditions	Yield
With air In dichloromethane for 48h;	94%

: 18516-37-5
2-methyl-undec-1-ene

: 98-08-8
α,α,α-trifluorotoluene

: (1,1-difluoro-3-methyldodecyl)benzene

Conditions

Conditions	Yield
With 3,7-di([1,1′-biphenyl]-4-yl)-10-(naphthalen-1-yl)-10H-phenoxazine; potassium formate; thiophenol In dimethyl sulfoxide at 100℃; for 24h; Inert atmosphere; Irradiation; Sealed tube;	94%

: 116-14-3
polytetrafluoroethylene

: 98-08-8
α,α,α-trifluorotoluene

: 455-13-0
4-Iodobenzotrifluoride

: 5123-13-7
5,5-dimethyl-2-phenyl-1,3,2-dioxaborinane

: 1,1,2,2,-tetrafluoro-1-(p-trifluoromethylphenyl)-2-phenylethane

Conditions

Conditions	Yield
Stage #1: polytetrafluoroethylene; α,α,α-trifluorotoluene; 5,5-dimethyl-2-phenyl-1,3,2-dioxaborinane With 1,10-Phenanthroline; copper (I) tert-butoxide In tetrahydrofuran under 2660.18 Torr; Inert atmosphere; Stage #2: 4-Iodobenzotrifluoride at 60℃; for 4h;	93%

...Expand

: 352670-77-0, 78622-84-1
trans-[PdIPh(AsPh3)2]

: 603-32-7
triphenyl-arsane

: 98-08-8
α,α,α-trifluorotoluene

: 81290-20-2
(trifluoromethyl)trimethylsilane

: trans-[Pd(CF3)Ph(AsPh3)2]

Conditions

Conditions	Yield
Stage #1: trans-[PdIPh(AsPh3)2]; triphenyl-arsane; α,α,α-trifluorotoluene With silver fluoride In benzene for 1h; Glovebox; Sonication; Darkness; Stage #2: (trifluoromethyl)trimethylsilane In benzene for 0.25h; Glovebox;	93%

...Expand

: 98-08-8
α,α,α-trifluorotoluene

: 20056-97-7
N-methoxypropargylamine

: (E)-5-phenyl-3-styryl-1,2,4-triazine

: 6-methoxy-7-methyl-2-(trifluoromethyl)-5,6,7,8-tetrahydro-1,6-naphthyridine

Conditions

Conditions	Yield
Stage #1: α,α,α-trifluorotoluene; N-methoxypropargylamine; (E)-5-phenyl-3-styryl-1,2,4-triazine With bis(trifluoromethanesulfonyl)amide at 20℃; for 48h; Microwave irradiation; Stage #2: With potassium carbonate at 180℃; for 2h; Sealed tube;	93%

...Expand

: 75-77-4
chloro-trimethyl-silane

: 98-08-8
α,α,α-trifluorotoluene

: 149021-01-2
(difluoro(trimethylsilyl)methyl)benzene

Conditions

Conditions	Yield
In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide electrochemical reaction;	92%
In tetrahydrofuran for 48h; electrolysis: aluminium anode, stainless steel cathode, NBu4Br as supporting electrolyte, i = 0.1 A, j = 0.4 A dm-2, 1.3 F mol-1; Yield given;

: 98-08-8
α,α,α-trifluorotoluene

: 184844-76-6
(S)-2-(3-furyl)-1-phenyl-1-ethanol

: 406945-07-1
(S)-2-(3-furyl)-1-phenylethyl[1-(trifluoromethyl)phenyl] ether

Conditions

Conditions	Yield
Stage #1: (S)-2-(3-furyl)-1-phenyl-1-ethanol With sodium hydride In N,N-dimethyl acetamide at 50 - 55℃; for 0.75h; Stage #2: α,α,α-trifluorotoluene In N,N-dimethyl acetamide at 95℃; for 2.5h;	92%

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