Cyanuric fluoride supplier

Name
Cyanuric fluoride
EINECS 211-620-8
CAS No. 675-14-9
Article Data77
CAS DataBase
Density 1.652 g/cm³
Solubility
Melting Point -38ºC
Formula C3F3 N3
Boiling Point 316.1 °C at 760 mmHg
Molecular Weight 135.048
Flash Point 145 °C
Transport Information UN 3389
Appearance amber liquid
Safety Poison by skin contact and inhalation. Questionable carcinogen with experimental carcinogenic data. When heated to decomposition it emits very toxic fumes of F⁻ and NO_x. See also FLUORIDES.
Risk Codes R24;R26;R35
Molecular Structure
Hazard Symbols
Synonyms Cyanuricfluoride (6CI); s-Triazine, 2,4,6-trifluoro- (7CI,8CI);1,3,5-Trifluoro-2,4,6-triazine; 2,4,6-Trifluoro-1,3,5-triazine; 2,4,6-Trifluoro-s-triazine;2,4,6-Trifluoro-sym-triazine; 2,4,6-Trifluorotriazine; Cyanuric trifluoride;NSC 168386; Trifluoro-1,3,5-triazine; Trifluoro-s-triazine
PSA 38.67000
LogP 0.28890

Synthetic route

: 108-77-0
1,3,5-trichloro-2,4,6-triazine

: 675-14-9
trifluoro-[1,3,5]triazine

Conditions

Conditions	Yield
With sulfolane; sodium fluoride at 150℃; Reagent/catalyst; Large scale;	97%
With tetrabutyl ammonium fluoride In dimethyl sulfoxide at 60℃; for 6h; Temperature; Solvent;	95%
With 1-methyl-pyrrolidin-2-one; hydrogen fluoride; triethylamine at 20 - 25℃; for 0.5h;	90%

: 108-77-0
1,3,5-trichloro-2,4,6-triazine

: 7783-56-4
antimony(III) fluoride

: 675-14-9
trifluoro-[1,3,5]triazine

Conditions

Conditions	Yield
With antimony(III) chloride; chlorine 160-180°C, 10 mol SbF3, 1 mol SbCl3, 3 mol Cl2;	91%
With antimony(III) chloride; chlorine 160-180°C, 10 mol SbF3, 1 mol SbCl3, 3 mol Cl2;	91%
With chlorine at 100°C, exclusion of H2O; destillation;	71.4%

: 57310-43-7
4-N,N-dichloroamino-2,3,5,6-tetrafluoropyridine

A: 675-14-9
trifluoro-[1,3,5]triazine

B: 52026-98-9
4-chloro-2,3,5,6-tetrafluoropyridine

C: 700-16-3
Pentafluoropyridine

D: 75-69-4
trichlorofluoromethane

E: 667-42-5
2-chloro-3,3-difluoro-acrylonitrile

F: 13177-77-0
tetrafluoropyrazine

Conditions

Conditions	Yield
at 550℃; under 2 Torr; Mechanism; vacuum pyrolysis, other fluoropyridine compounds;	A n/a B 75% C n/a D n/a E n/a F n/a

...Expand

: 112291-51-7
1,2,3-trifluoro-4,5,6-triazine

: 112291-50-6
perfluoro-4,6-di-isopropyl-1,2,3-triazine

A: 675-14-9
trifluoro-[1,3,5]triazine

B: 20017-47-4
perfluoro-2,4-di-isopropylpyridine

C: 129574-48-7
perfluoro-2,4,6,8-tetraisopropyl-1,5-diazatricyclo<4.2.0.02,5>octa-3,7-diene

Conditions

Conditions	Yield
In 1,1,2-Trichloro-1,2,2-trifluoroethane for 24h; Irradiation;	A 0.01 g B 53% C 11%
In 1,1,2-Trichloro-1,2,2-trifluoroethane for 24h; Irradiation;	A 0.01 g B 4% C 11 g
In 1,1,2-Trichloro-1,2,2-trifluoroethane for 24h; Mechanism; Irradiation;	A 0.01 g B 0.17 g C 0.03 g

...Expand

: 108-77-0
1,3,5-trichloro-2,4,6-triazine

A: 675-14-9
trifluoro-[1,3,5]triazine

B: 696-85-5
2-chloro-4,6-difluoro-[1,3,5]triazine

C: 696-84-4
2,4-dichloro-6-fluoro-[1,3,5]triazine

Conditions

Conditions	Yield
With potassium fluoride at 300℃; for 2h; Product distribution; C3Cl3N3/KF = 16 x 10 E-2, other temperatures, other times, other molar ratios;	A n/a B n/a C 48%
With cesium fluoride; 3-butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate at 80℃;

...Expand

: 108-77-0
1,3,5-trichloro-2,4,6-triazine

: 7783-60-0
sulfur tetrafluoride

: 675-14-9
trifluoro-[1,3,5]triazine

Conditions

Conditions	Yield
in 1:6 molar ratio, at 250°C, in autoclave;	40%

: 7783-54-2
nitrogen trifluoride

: 506-77-4
cyanogen chloride

A: 675-14-9
trifluoro-[1,3,5]triazine

B: 73513-59-4
cis-hexafluoroazomethane

C: 371-71-1
Perfluoro-2-azapropen

Conditions

Conditions	Yield
In not given at 500°C, in Ni-tube, in excess of NF3;	A 40% B 30% C 30%

...Expand

: 75995-67-4
trifluoro-1,2,4-triazine

A: 675-14-9
trifluoro-[1,3,5]triazine

B: 371-71-1
Perfluoro-2-azapropen

C silicon tetrafluoride: silicon tetrafluoride

Conditions

Conditions	Yield
at 500℃; for 42h;	A 32% B 12% C n/a

...Expand

: 108-77-0
1,3,5-trichloro-2,4,6-triazine

A: 675-14-9
trifluoro-[1,3,5]triazine

B: 696-85-5
2-chloro-4,6-difluoro-[1,3,5]triazine

Conditions

Conditions	Yield
With antimonypentachloride; antimony(III) fluoride
With antimonypentachloride; antimony(III) fluoride melting, heating, 1 h distn.; fractionated distn.;
With SbF3; SbCl5 melting, heating, 1 h distn.; fractionated distn.;

: 108-77-0
1,3,5-trichloro-2,4,6-triazine

: 7783-56-4
antimony(III) fluoride

: 10025-91-9
antimony(III) chloride

: 7782-50-5
chlorine

: 675-14-9
trifluoro-[1,3,5]triazine

...Expand

: 108-77-0
1,3,5-trichloro-2,4,6-triazine

SbCl2F3: SbCl2F3

: 675-14-9
trifluoro-[1,3,5]triazine

: 108-77-0
1,3,5-trichloro-2,4,6-triazine

: 7664-39-3
hydrogen fluoride

A: 675-14-9
trifluoro-[1,3,5]triazine

B: 696-85-5
2-chloro-4,6-difluoro-[1,3,5]triazine

C: 696-84-4
2,4-dichloro-6-fluoro-[1,3,5]triazine

Conditions

Conditions	Yield
auch unter Zusatz von Sb2O3 oder SbCl5;
With SbCl5

...Expand

: 108-77-0
1,3,5-trichloro-2,4,6-triazine

KF*HF: KF*HF

A: 675-14-9
trifluoro-[1,3,5]triazine

B: 696-85-5
2-chloro-4,6-difluoro-[1,3,5]triazine

C: 696-84-4
2,4-dichloro-6-fluoro-[1,3,5]triazine

Conditions

Conditions	Yield
auch unter Zusatz von Sb2O3 oder SbCl5;
auch unter Zusatz von Sb2O3 oder SbCl5;

...Expand

: 108-77-0
1,3,5-trichloro-2,4,6-triazine

KF: KF

A: 675-14-9
trifluoro-[1,3,5]triazine

B: 696-85-5
2-chloro-4,6-difluoro-[1,3,5]triazine

C: 696-84-4
2,4-dichloro-6-fluoro-[1,3,5]triazine

Conditions

Conditions	Yield
auch unter Zusatz von Sb2O3 oder SbCl5;
auch unter Zusatz von Sb2O3 oder SbCl5;

...Expand

: 108-77-0
1,3,5-trichloro-2,4,6-triazine

KSO2F: KSO2F

A: 675-14-9
trifluoro-[1,3,5]triazine

B: 696-85-5
2-chloro-4,6-difluoro-[1,3,5]triazine

C: 696-84-4
2,4-dichloro-6-fluoro-[1,3,5]triazine

Conditions

Conditions	Yield
auch unter Zusatz von Sb2O3 oder SbCl5;
auch unter Zusatz von Sb2O3 oder SbCl5;

...Expand

: 421-17-0
Trifluoromethylsulfenyl chloride

: 832-34-8
1,3,5-Trichlor-2,2,4,4,6,6-hexafluor-1,3,5-triazinan

A: 675-14-9
trifluoro-[1,3,5]triazine

B: 372-64-5
Bis(trifluoromethyl)disulfid

C: 812-12-4
trifluoromethanesulfinyl fluoride

Conditions

Conditions	Yield
byproducts: Cl2; at 20°C (1 h);
byproducts: Cl2; at 20°C (1 h);

...Expand

: 73513-59-4
cis-hexafluoroazomethane

A: 675-14-9
trifluoro-[1,3,5]triazine

B: 75-73-0
carbon tetrafluoride

C: 371-77-7
N,N-Bis(trifluoromethyl)amine

D: 371-71-1
Perfluoro-2-azapropen

E: 383-96-0
tetrakis(trifluoromethyl)hydrazine

Conditions

Conditions	Yield
heating in autoclave at 483°C; further product;
heating in autoclave at 483°C; further product;

...Expand

: 1495-50-7
cyanogen fluoride

: 675-14-9
trifluoro-[1,3,5]triazine

Conditions

Conditions	Yield
at ambient temp. quick polimn.;
room temp., polymerisation;
at ambient temp. quick polimn.;

: 21690-85-7
2,2,2-trifluoro-1-oxoethanesulphenylchloride

: 832-34-8
1,3,5-Trichlor-2,2,4,4,6,6-hexafluor-1,3,5-triazinan

A: 675-14-9
trifluoro-[1,3,5]triazine

B: 57160-00-6
2,2,2-trifluoro-1-oxoethanesulfenyl fluoride

Conditions

Conditions	Yield
byproducts: Cl2;
byproducts: Cl2;

...Expand

: 108-77-0
1,3,5-trichloro-2,4,6-triazine

A: 675-14-9
trifluoro-[1,3,5]triazine

B: 696-85-5
2-chloro-4,6-difluoro-[1,3,5]triazine

C: 696-84-4
2,4-dichloro-6-fluoro-[1,3,5]triazine

D: 4394-93-8
Hexafluormethandiamin

E: 4394-92-7
cycloperfluoro dimethylenediamine

Conditions

Conditions	Yield
With fluorine 125°C, under N2;

...Expand

: 108-77-0
1,3,5-trichloro-2,4,6-triazine

: 7664-39-3
hydrogen fluoride

: 675-14-9
trifluoro-[1,3,5]triazine

: 108-77-0
1,3,5-trichloro-2,4,6-triazine

: 7782-41-4
fluorine

: 675-14-9
trifluoro-[1,3,5]triazine

Conditions

Conditions	Yield
other products, in N2, at 125°C;

: 696-85-5
2-chloro-4,6-difluoro-[1,3,5]triazine

: 696-84-4
2,4-dichloro-6-fluoro-[1,3,5]triazine

: 108-77-0
1,3,5-trichloro-2,4,6-triazine

: 675-14-9
trifluoro-[1,3,5]triazine

Conditions

Conditions	Yield
With Sb2O3; KHF2 In benzene
With KF
With KHF2

...Expand

: 14921-00-7
cyanuric bromide

: 675-14-9
trifluoro-[1,3,5]triazine

Conditions

Conditions	Yield
With ZnF2
With KF; Sb2O3

: 33278-60-3
dichloromethylene-trifluoromethylmercaptoamine

: silver fluoride

A: 675-14-9
trifluoro-[1,3,5]triazine

B: CF3SNCF2

C: 34764-16-4
bis(trifluoromethylmercapto)-trifluoromethylamine

Conditions

Conditions	Yield
byproducts: AgCl; 130°C; 21 h;; detected by IR and Mass spectr.;
byproducts: AgCl; 130°C; 21 h;; detected by IR and Mass spectr.;

...Expand

: 7783-53-1
manganese(III) fluoride

: 506-77-4
cyanogen chloride

A: 675-14-9
trifluoro-[1,3,5]triazine

B: 75-73-0
carbon tetrafluoride

C: 75-72-9
chlorotrifluoromethane

D: 660-80-0
pentafluoro chloro azomethane

Conditions

Conditions	Yield
byproducts: Cl2; at 160-190°C;

...Expand

: 7783-54-2
nitrogen trifluoride

: 506-77-4
cyanogen chloride

A: 675-14-9
trifluoro-[1,3,5]triazine

B: 75-73-0
carbon tetrafluoride

C: 73513-59-4
cis-hexafluoroazomethane

D: 75-69-4
trichlorofluoromethane

E: 371-71-1
Perfluoro-2-azapropen

Conditions

Conditions	Yield
With chlorine In not given at 450-500°C, in Ni-tube, in excess of NF3;

...Expand

: 7783-54-2
nitrogen trifluoride

: 506-77-4
cyanogen chloride

: 675-14-9
trifluoro-[1,3,5]triazine

Conditions

Conditions	Yield
In not given ClCN/NF3 = 1:1;

: 675-14-9
trifluoro-[1,3,5]triazine

: 150746-76-2
tris(dimethylamino)sulfonium trimethylsilyldifluoride

: C6H18N3S(1+)*C3F4N3(1-)

Conditions

Conditions	Yield
In acetonitrile at -196 - -40℃; for 0.75h;	100%

: 675-14-9
trifluoro-[1,3,5]triazine

: 301685-23-4
(2R)-2-({formyl[(phenylmethyl)oxy]amino}methyl)hexanoic acid

: 1398752-25-4
(2R)-2-({formyl[(phenylmethyl)oxy]amino}methyl)hexanoyl fluoride

Conditions

Conditions	Yield
With pyridine	100%

: 675-14-9
trifluoro-[1,3,5]triazine

: 1092523-21-1
6-chloro-2-(ethylamino)pyridine-3-carboxylic acid

: 1092523-22-2
6-chloro-2-(ethylamino)pyridine-3-carbonyl fluoride

Conditions

Conditions	Yield
In dichloromethane at 20℃; for 3h;	99%

: 675-14-9
trifluoro-[1,3,5]triazine

: 2450-71-7
Propargylamine

: 4,6-difluoro-2-(prop-2-yn-1-yl-amino)-1,3,5-triazine

Conditions

Conditions	Yield
In N,N-dimethyl-formamide Inert atmosphere;	98%

: 675-14-9
trifluoro-[1,3,5]triazine

: 753-90-2
trifluoroethylamine

: 144535-16-0
2-fluoro-4,6-bis<(2,2,2-trifluoroethyl)amino>-1,3,5-triazine

Conditions

Conditions	Yield
	97%

: 675-14-9
trifluoro-[1,3,5]triazine

: 2,2,2-trifluoroethylamine

: 144535-16-0
2-fluoro-4,6-bis<(2,2,2-trifluoroethyl)amino>-1,3,5-triazine

Conditions

Conditions	Yield
	97%

: 675-14-9
trifluoro-[1,3,5]triazine

: 5-(t-butoxycarbonyl)-2-[N-(butoxycarbonyl)-N-(2-phenylethyl)aminomethyl]phenylpropionic acid

: 5-(t-butoxycarbonyl)-2-[N-(butoxycarbonyl)-N-(2-phenylethyl)aminomethyl]phenylpropionyl fluoride

Conditions

Conditions	Yield
With pyridine In dichloromethane	96%

: 675-14-9
trifluoro-[1,3,5]triazine

: 1236188-80-9
3-phenyl-4-(trifluoromethyl)isoxazole-5-carboxylic acid

: 1236188-83-2
3-phenyl-4-(trifluoromethyl)isoxazole-5-carbonyl fluoride

Conditions

Conditions	Yield
With pyridine In dichloromethane at 20℃;	96%

: 675-14-9
trifluoro-[1,3,5]triazine

: 7732-18-5
water

: 108-80-5
cyanuric acid

Conditions

Conditions	Yield
In tetrahydrofuran hydrolysis at 0°C;	94%
In water hydrolysis at 0°C;	>99

: 675-14-9
trifluoro-[1,3,5]triazine

: 2450-71-7
Propargylamine

: 144535-20-6
N2,N4,N6-tri(prop-2-yn-1-yl)-1,3,5-triazine-2,4,6-triamine

Conditions

Conditions	Yield
In toluene for 20h; Heating;	93%
In toluene Reflux;	83%

: 675-14-9
trifluoro-[1,3,5]triazine

: 753-90-2
trifluoroethylamine

: 144535-17-1
2,4,6-tris<(2,2,2-trifluoroethyl)amino>-1,3,5-triazine

Conditions

Conditions	Yield
With cesium fluoride In N,N-dimethyl-formamide at 40℃; for 72h;	91%
With cesium fluoride In N,N-dimethyl-formamide

: 675-14-9
trifluoro-[1,3,5]triazine

: 56583-58-5, 76985-10-9, 58438-04-3
N-tert-butoxycarbonyl-3-(2-naphthyl)-L-alanine

: ((S)-1-Fluorocarbonyl-2-naphthalen-2-yl-ethyl)-carbamic acid tert-butyl ester

Conditions

Conditions	Yield
With pyridine In dichloromethane at -15℃; for 1h;	91%

: 675-14-9
trifluoro-[1,3,5]triazine

: 205677-08-3
2-[N-(tert-butoxycarbonyl)-N-(2,2,2-trifluoroethyl)aminomethyl]-4-methoxydihydrocinnamic acid

: 40217-17-2, 90719-32-7, 120574-96-1, 102029-44-7
(R)-4-(phenylmethyl)-2-oxazolidinone

: (R)-4-benzyl-2-oxazolidinonyl 2-[N-(tert-butoxycarbonyl)-N-(2,2,2-trifluoroethyl)aminomethyl]-4-methoxydihydrocinnamide

Conditions

Conditions	Yield
With pyridine; n-butyllithium; ammonium chloride In tetrahydrofuran; dichloromethane	91%

...Expand

: 675-14-9
trifluoro-[1,3,5]triazine

: 1111735-43-3
ferrocenylamidoundecanoic acid

: 1111735-46-6
ferrocenylamidoundecanoic acid fluoride

Conditions

Conditions	Yield
With pyridine In dichloromethane (Ar, Schlenk technique); addn. of cyanuric fluoride to suspn. of ferrocene deriv. and pyridine in dry CH2Cl2, stirring for 2 h; addn. of ice cold water, filtration, separating organic layer, washing with cold water, drying over MgSO4, filtration, evapn., elem. anal.;	91%

: 116-14-3
polytetrafluoroethylene

: 675-14-9
trifluoro-[1,3,5]triazine

: 858-46-8
tris(perfluoroethyl)-s-triazine

Conditions

Conditions	Yield
at 140℃; Large scale;	91%

: 675-14-9
trifluoro-[1,3,5]triazine

: 205676-97-7
2-[N-(tert-butoxycarbonyl)-N-(4-trifluoromethylbenzyl)aminomethyl]-4-methoxydihydrocinnamic acid

: 40217-17-2, 90719-32-7, 120574-96-1, 102029-44-7
(R)-4-(phenylmethyl)-2-oxazolidinone

: (R)-4-Benzyl-2-oxazolidinonyl 2-[N-(tert-butoxycarbonyl)-N-(4-trifluoromethylbenzyl) aminomethyl]-4-methoxydihydrocinnamide

Conditions

Conditions	Yield
With pyridine; n-butyllithium; ammonium chloride In tetrahydrofuran; dichloromethane	90%
With pyridine; n-butyllithium; ammonium chloride In tetrahydrofuran; dichloromethane	90%

...Expand

: 675-14-9
trifluoro-[1,3,5]triazine

: 15693-51-3
K{Mn(CO)5}

: 2-(pentacarbonylmanganese)-4,6-difluoro-1,3,5-triazene

Conditions

Conditions	Yield
In not given -18°C; sublimed in vacuo (50°C/0.01 Torr), recrystd. from dry hexane;	90%

: 675-14-9
trifluoro-[1,3,5]triazine

: 116-15-4
perfluoropropylene

: 10271-37-1
perfluoro-2,4,6-triisopropyl-s-triazine

Conditions

Conditions	Yield
at 140℃; Reagent/catalyst; Temperature; Large scale;	89%

: 675-14-9
trifluoro-[1,3,5]triazine

: 4-[1-(tert-butoxycarbonyl)-4-piperidyl]-2-{2-[1-(tert-butoxycarbonyl)-4-piperidyl]ethyl}butanoic acid

: 5680-79-5
glycine ethyl ester hydrochloride

: 255880-67-2
2-[(4-[1-(tert-butoxycarbonyl)-4-piperidyl]-2-{2-[1-(tert-butoxycarbonyl)-4-piperidyl]ethyl}butanoyl)amino]acetic acid

Conditions

Conditions	Yield
With pyridine; hydrogenchloride; lithium hydroxide monohydrate; N-ethyl-N,N-diisopropylamine In tetrahydrofuran; dichloromethane; water	88%

...Expand

: 675-14-9
trifluoro-[1,3,5]triazine

: 2450-71-7
Propargylamine

: 2-fluoro-4,6-bis(propargylamino)-1,3,5-triazine

Conditions

Conditions	Yield
In N,N-dimethyl-formamide	87%
In N,N-dimethyl-formamide

: 675-14-9
trifluoro-[1,3,5]triazine

: 626-18-6
1,3-dimethanol benzene

: 1228184-79-9
C14H8F4N6O2

Conditions

Conditions	Yield
With triethylamine In diethyl ether at 20℃; for 2.5h;	87%

: 675-14-9
trifluoro-[1,3,5]triazine

: 109-63-7
boron trifluoride diethyl etherate

: 151515-23-0
2,3-Dihydro-1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene

: 1210257-36-5
2-(4,6-difluoro-1,3,5-triazin-2-yl)-1,3-diisopropyl-4,5-dimethylimidazolium tetrafluoroborate

Conditions

Conditions	Yield
In diethyl ether (Ar); imidazolylidene deriv. added to Et2O soln. of cyanuric trifluorideat -70°C; stirred for 12 h at room temp.; BF3*OEt2 added dropwis e; stirred for 4 h at room temp.; ppt. isolated; washed with Et2O; vac. dried; recrystd. from MeCN/Et2O; elem. anal.;	86%

...Expand

: 675-14-9
trifluoro-[1,3,5]triazine

4-[2-[N-(tert-butoxycarbonyl)-N-(2-phenylethyl)amino]methyl-4-methoxyphenyl]propionic acid: 4-[2-[N-(tert-butoxycarbonyl)-N-(2-phenylethyl)amino]methyl-4-methoxyphenyl]propionic acid

: 40217-17-2, 90719-32-7, 120574-96-1, 102029-44-7
(R)-4-(phenylmethyl)-2-oxazolidinone

: (R)-1,1-Dimethylethyl[[5-methoxy-2-[3-oxo-3-[2-oxo-4-(phenylmethyl)-3-oxazolidinyl]propyl]phenyl]methyl](2-phenylethyl)carbamate

Conditions

Conditions	Yield
With pyridine; n-butyllithium In tetrahydrofuran; dichloromethane	85%

...Expand

: 675-14-9
trifluoro-[1,3,5]triazine

: 112-80-1
cis-Octadecenoic acid

: 1480-60-0
oleoyl fluoride

Conditions

Conditions	Yield
With pyridine In acetonitrile	85%

: 675-14-9
trifluoro-[1,3,5]triazine

: 151515-23-0
2,3-Dihydro-1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene

: 1210257-36-5
2-(4,6-difluoro-1,3,5-triazin-2-yl)-1,3-diisopropyl-4,5-dimethylimidazolium tetrafluoroborate

Conditions

Conditions	Yield
Stage #1: trifluoro-[1,3,5]triazine; 2,3-Dihydro-1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene In diethyl ether at -70 - 20℃; Inert atmosphere; Stage #2: With boron trifluoride diethyl etherate at 20℃; Inert atmosphere;	85%

: 675-14-9
trifluoro-[1,3,5]triazine

: 433301-35-0
(Sp)-2-formylferrocene-1-carboxylic acid

: 1296752-87-8
(Sp)-2-formylferrocenoyl fluoride

Conditions

Yield

With pyridine In dichloromethane pyridine (1.650 ml) and cyanuric fluoride (3.605 ml) added to CH2Cl2 soln. of Fc(CHO)CO2H (10 mmol) at 0°C under Ar, after few min cooling bath removed, mixt. stirred at room temp. for 90 min; crushed ice added, suspn. filtered, organic phase sepd., washed with cold H2O, dried over Na2SO4, filtered, solidified for few min, crystals collected, dried in vac. exicator over P2O5 overnight at room temp.; elem. anal.;

85%

: 675-14-9
trifluoro-[1,3,5]triazine

: ruthenocene carboxylic acid

A: 1279129-18-8
fluorocarbonyl ruthenocene

B: 1279129-20-2
[Ru(η5-C5H5)(η5-C5H4CO)]2O

Conditions

Conditions	Yield
With pyridine In dichloromethane under N2 or Ar; suspn. of Ru complex and pyridine in CH2Cl2 cooled to 0°C; N3C3F3 added; stirred at 0°C for 2 h; poured into ice-cold H2O; filtered; org. layer collected; concd. in vac.; purified by column chromy. (silica gel, ethyl acetate-hexane 1:5); elem. anal.;	A 82% B 2%

...Expand

: 675-14-9
trifluoro-[1,3,5]triazine

: 63-74-1
sulfanilamide

: 4-(4',6'-difluoro-1',3',5'-triazin-2'-ylamino)benzenesulfonamide

Conditions

Conditions	Yield
Stage #1: trifluoro-[1,3,5]triazine; sulfanilamide In acetone at 0℃; for 0.5h; Stage #2: With sodium hydroxide In water; acetone at 20℃; for 1.33333h;	82%

Cyanuric fluoride Chemical Properties

Chemical Name: Cyanuric fluoride
IUPAC NAME: 2,4,6-trifluoro-1,3,5-triazine
CAS No.: 675-14-9
EINECS: 211-620-8
RTECS: XZ1750000
Molecular Formula: C₃F₃N₃
Molecular Weight: 135.05 g/mol
Hazard Note: Corrosive/Toxic
Density: 1.652 g/cm³
Melting Point: -38°C
Flash Point: 145 °C
Boiling Point: 316.1 °C at 760 mmHg
2,4,6-TRIFLUORO-s-TRIAZINE(675-14-9) is a colourless, pungent liquid. it is moisture sensitive and incompatible with xoidizing agents.Following is the structure:

The chemical synonymous of 2,4,6-TRIFLUORO-s-TRIAZINE(675-14-9) are 2,4,6-TRIFLUORO-1,3,5-TRIAZINE;CYANURIC FLUORIDE;1,3,5-triazine,2,4,6-trifluoro-;2,4,6-trifluoro-s-triazin;2,4,6-Trifluoro-s-triazine;2,4,6-Trifluorotriazine;2,4,6-trifluro-s-triazin;5-triazine,2,4,6-trifluoro-3.

Cyanuric fluoride Uses

2,4,6-TRIFLUORO-s-TRIAZINE(675-14-9) is mainly used for preparation of reactive dyes and used in organic synthesis.It has been used as a precursor for fibre-reactive dyes, as a specific reagent for tyrosine residues in enzymes, and as a fluorinating agent.

Cyanuric fluoride Production

Product Categories about 2,4,6-TRIFLUORO-s-TRIAZINE(675-14-9) is mainly refer to Heterocycles.

Cyanuric fluoride Toxicity Data With Reference

rabbit	LD50	skin	160mg/kg (160mg/kg)	SENSE ORGANS AND SPECIAL SENSES: LACRIMATION: EYE LUNGS, THORAX, OR RESPIRATION: BRONCHIOLAR CONSTRICTION	American Industrial Hygiene Association Journal. Vol. 33, Pg. 382, 1972.
rat	LC50	inhalation	3100ppb/4H (3.1ppm)	BEHAVIORAL: EXCITEMENT LUNGS, THORAX, OR RESPIRATION: CHRONIC PULMONARY EDEMA LUNGS, THORAX, OR RESPIRATION: DYSPNEA	American Industrial Hygiene Association Journal. Vol. 33, Pg. 382, 1972.

Cyanuric fluoride Consensus Reports

EPA Extremely Hazardous Substances List. Reported in EPA TSCA Inventory.

Cyanuric fluoride Safety Profile

Poison by skin contact and inhalation. Questionable carcinogen with experimental carcinogenic data. When heated to decomposition it emits very toxic fumes of F⁻ and NO_x. See also FLUORIDES.
Hazard Codes:
    T+: Very toxic
    T: Toxic
    C: Corrosive
Risk Statements about 2,4,6-TRIFLUORO-s-TRIAZINE(675-14-9):
    R24 Toxic in contact with skin.
    R26 Very toxic by inhalation.
    R35 Causes severe burns.
Safety Statements about 2,4,6-TRIFLUORO-s-TRIAZINE(675-14-9):
    S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
    S28 After contact with skin, wash immediately with plenty of soap-suds.
    S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
    S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.

Cyanuric fluoride Specification

1. Storage: Keep in a cool, dry, dark location in a tightly sealed container or cylinder. Keep away from incompatible materials, ignition sources and untrained individuals. Secure and label area. Protect containers/cylinders from physical damage.
2. Handling: All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.
3. Personal Protection: Chemical splash goggles in compliance with OSHA regulations are advised; however, OSHA regulations also permit other type safety glasses. Whre chemical resistant gloves. To prevent repeated or prolonged skin contact, wear impervious clothing and boots.
4. Fire Fighting: Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use agent most appropriate to extinguish fire.
5. Reactivity Profile Inorganic oxidizing agents can react with reducing agents to generate heat and products that may be gaseous (causing pressurization of closed containers). The products may themselves be capable of further reactions (such as combustion in the air). The chemical reduction of materials in this group can be rapid or even explosive, but often requires initiation (heat, spark, catalyst, addition of a solvent). Explosive mixtures of inorganic oxidizing agents with reducing agents often persist unchanged for long periods if initiation is prevented. Such systems are typically mixtures of solids, but may involve any combination of physical states. Some inorganic oxidizing agents are salts of metals that are soluble in water; dissolution dilutes but does not nullify the oxidizing power of such materials. Organic compounds, in general, have some reducing power and can in principle react with compounds in this class. Actual reactivity varies greatly with the identity of the organic compound. Inorganic oxidizing agents can react violently with active metals, cyanides, esters, and thiocyanates. Explosives often consist of an inorganic oxidizing agent mixed in intimate contact with a reducing agent. Gunpowder is such a mixture. Other examples are a mixture of sugar (an organic compound) plus sodium chlorate and magnesium (an inorganic reducing agent) plus barium peroxide. Compounds that inherently contain a group that is a reducing agent and an oxidizing agent are classed in both Group 44 (Inorganic Oxidizing Agents) and in Group 45 (Inorganic Reducing Agents; for example, ammonium nitrate). The strongly oxidizing elements oxygen and fluorine are classified here. Inorganic oxidizing agents that are also acids (such as nitric and perchloric acids) are not included in this group. They are in Group 2 (Acids, Inorganic Oxidizing).

Product Name

Cyanuric fluoride

Synthetic route

Cyanuric fluoride Chemical Properties

Cyanuric fluoride Uses

Cyanuric fluoride Production

Cyanuric fluoride Toxicity Data With Reference

Cyanuric fluoride Consensus Reports

Cyanuric fluoride Safety Profile

Cyanuric fluoride Specification

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