Diallylamine supplier | CasNO.124-02-7

Name
N,N-Diallylamine
EINECS 204-671-2
CAS No. 124-02-7
Article Data31
CAS DataBase
Density 0.767 g/cm³
Solubility 8.6 g/100mL
Melting Point -88 °C
Formula C₆H₁₁N
Boiling Point 115.3 °C at 760 mmHg
Molecular Weight 97.16
Flash Point 15.6 °C
Transport Information UN 2359 3/PG 2
Appearance clear colourless to yellow liquid
Safety 16-26-36/37/39-45-28
Risk Codes 11-20/22-24-34
Molecular Structure
Hazard Symbols T,F
Synonyms 2-propen-1-amine, N-2-propen-1-yl-;N-(prop-2-en-1-yl)prop-2-en-1-amine;N-Allyl-2-propen-1-amine;N-Allylprop-2-en-1-amine;Diallylamine;
PSA 12.03000
LogP 1.33890

Synthetic route

: Diallyl-carbamic acid 1-(3,5-dimethoxy-phenyl)-2-oxo-2-phenyl-ethyl ester

A: 34911-33-6
5,7-Dimethoxy-2-phenylbenzofuran

B: 124-02-7
diallylamine

Conditions

Conditions	Yield
In benzene Irradiation;	A 96% B 56%

: N,N-Diallylpyridine-2-sulfonamide

: 124-02-7
diallylamine

Conditions

Conditions	Yield
With samarium diiodide In tetrahydrofuran for 4h; Ambient temperature;	90%

: 109-73-9
N-butylamine

: 107-18-6
allyl alcohol

A: 4538-09-4
N-allyl-N-butylamine

B: 124-02-7
diallylamine

Conditions

Conditions	Yield
With ammonium hexafluorophosphate; [Pt(η3-C3H5)(DPP-Xantphos)]PF6 In toluene; acetonitrile at 30℃; for 44h; Inert atmosphere;	A 85% B 4%

...Expand

: 111-26-2
hexan-1-amine

: 107-18-6
allyl alcohol

A: 22774-71-6
N-allylhexan-1-amine

B: 124-02-7
diallylamine

Conditions

Conditions	Yield
With ammonium hexafluorophosphate; [Pt(η3-C3H5)(DPP-Xantphos)]PF6 In toluene; acetonitrile at 50℃; for 8h; Inert atmosphere;	A 81% B 7%

...Expand

: 107-18-6
allyl alcohol

: 100-46-9
benzylamine

A: 4383-22-6
Allylbenzylamine

B: 124-02-7
diallylamine

Conditions

Conditions	Yield
With ammonium hexafluorophosphate; [Pt(η3-C3H5)(DPP-Xantphos)]PF6 In toluene; acetonitrile at 30℃; for 20h; Inert atmosphere;	A 80% B 7%

...Expand

: N,N-diallyl-2-phenyl-2-propen-1-amine

: 594-19-4
tert.-butyl lithium

A: 7283-47-8
(4,4-dimethylpent-1-en-2-yl)benzene

B: 124-02-7
diallylamine

Conditions

Conditions	Yield
Stage #1: N,N-diallyl-2-phenyl-2-propen-1-amine; tert.-butyl lithium In tetrahydrofuran at -78 - 0℃; Stage #2: With water In tetrahydrofuran	A n/a B 79%

...Expand

: N,N-diallyltritylamine

: 124-02-7
diallylamine

Conditions

Conditions	Yield
Stage #1: N,N-diallyltritylamine With naphthalene; lithium In tetrahydrofuran at 0℃; for 6h; Stage #2: With water In tetrahydrofuran at 0 - 20℃;	62%

: 538-08-9
Diallylcyanamid

: 124-02-7
diallylamine

Conditions

Conditions	Yield
With sulfuric acid
With sulfuric acid In water at 30℃;

: 106-95-6
allyl bromide

: 107-11-9
1-amino-2-propene

: 124-02-7
diallylamine

: 107-11-9
1-amino-2-propene

: 107-05-1
3-chloroprop-1-ene

: 124-02-7
diallylamine

: 463-49-0
1,2-propanediene

: 107-11-9
1-amino-2-propene

A: 102-70-5
Triallylamine

B: 86660-16-4
N-allyl(2,3-dimethylene)butylamine

C: 86660-17-5
Diallyl-(3-methyl-2-methylene-but-3-enyl)-amine

D: Allyl-bis-(3-methyl-2-methylene-but-3-enyl)-amine

E: 124-02-7
diallylamine

Conditions

Conditions	Yield
sodium tetrahydroborate; triphenylphosphine; palladium dichloride at 150℃; for 1h; Product distribution; other temperatures, times; reaction with diallyl amine and N-allyl(2,3-dimethylene)butylamine; telomerization of propadiene with allyl amines;

...Expand

: 463-49-0
1,2-propanediene

: 107-11-9
1-amino-2-propene

A: 86660-16-4
N-allyl(2,3-dimethylene)butylamine

B: 86660-17-5
Diallyl-(3-methyl-2-methylene-but-3-enyl)-amine

C: Allyl-bis-(3-methyl-2-methylene-but-3-enyl)-amine

D: 124-02-7
diallylamine

Conditions

Conditions	Yield
sodium tetrahydroborate; triphenylphosphine; palladium dichloride at 130℃; for 3h;

...Expand

: 463-49-0
1,2-propanediene

A: 86660-17-5
Diallyl-(3-methyl-2-methylene-but-3-enyl)-amine

B: 124-02-7
diallylamine

Conditions

Conditions	Yield
sodium tetrahydroborate; triphenylphosphine; palladium dichloride at 130℃; for 6h;

: (R)-5-Allylaminomethyl-2,7,8-trimethyl-2-((4R,8R)-4,8,12-trimethyl-tridecyl)-chroman-6-ol; hydrobromide

allylHal: allylHal

: 124-02-7
diallylamine

Conditions

Conditions	Yield
With sodium hydroxide 1.) CH2Cl2, -20 deg C, 10 min, 2.) room temperature, 30 min, 3.) 70 deg C, 1 h; Yield given. Multistep reaction;

: 7664-41-7
ammonia

: 107-05-1
3-chloroprop-1-ene

A: 102-70-5
Triallylamine

B: 107-11-9
1-amino-2-propene

C: 124-02-7
diallylamine

Conditions

Conditions	Yield
at 97 - 105℃; unter Druck;

...Expand

: 107-05-1
3-chloroprop-1-ene

A: 124-02-7
diallylamine

B allylamine and triallylamine: allylamine and triallylamine

Conditions

Conditions	Yield
With ammonia at 97 - 105℃; under 5884.06 - 11032.6 Torr;
With ammonia at 97 - 105℃; under 5884.06 - 11032.6 Torr;

: 64-17-5
ethanol

: 107-05-1
3-chloroprop-1-ene

A: 124-02-7
diallylamine

B allylamine and triallylamine: allylamine and triallylamine

Conditions

Conditions	Yield
With ammonia at 10℃;

...Expand

: 538-08-9
Diallylcyanamid

diluted alkaline solution: diluted alkaline solution

: 124-02-7
diallylamine

Conditions

Conditions	Yield
Hydrolysis;

: 538-08-9
Diallylcyanamid

diluted mineral acid: diluted mineral acid

: 124-02-7
diallylamine

Conditions

Conditions	Yield
Hydrolysis;

: 102-70-5
Triallylamine

A: 124-02-7
diallylamine

B polymer of acrylaldehyde: polymer of acrylaldehyde

Conditions

Conditions	Yield
With alkaline potassium hexacyanoferrate(III) In ethanol at 25℃; Mechanism; Rate constant; Kinetics; variations in the ionic strength of the reaction medium (cations and anions), varying amount of solvent; ΔG(excit.), ΔH(excit.), ΔS(excit.);

: 25070-76-2
benzyl diallylcarbamate

: 124-02-7
diallylamine

Conditions

Conditions	Yield
With naphthalen-1-yl-lithium In tetrahydrofuran at 0℃; for 1h;	62 % Chromat.

: 107-05-1
3-chloroprop-1-ene

A: 102-70-5
Triallylamine

B: 107-11-9
1-amino-2-propene

C: 124-02-7
diallylamine

Conditions

Conditions	Yield
Stage #1: 3-chloroprop-1-ene With formaldehyd; ammonia In methanol; water at 40 - 70℃; for 6h; Stage #2: With hydroxyammonium sulfate; sulfuric acid In methanol; water at 40℃; for 0.5h; pH=0.8; Stage #3: With sodium hydroxide In methanol; water pH=12; Product distribution / selectivity;
Stage #1: 3-chloroprop-1-ene With ammonia In methanol; water at 40 - 70℃; for 6h; Stage #2: With hydroxyammonium sulfate; sulfuric acid In methanol; water at 40℃; for 0.5h; pH=0.8; Stage #3: With sodium hydroxide In methanol; water pH=12; Product distribution / selectivity;
With ammonium hydroxide at 35℃; for 0.666667h; Temperature;

...Expand

: 110-89-4
piperidine

: 26256-86-0
C13H23NO

A: 18494-53-6
1-(piperidin-1-yl)heptan-1-one

B: 124-02-7
diallylamine

Conditions

Conditions	Yield
With Al2(NMe2)6 In toluene at 90℃; for 16h; Equilibrium constant;

...Expand

: 26256-86-0
C13H23NO

: 103-67-3
benzyl-methyl-amine

A: 1002752-21-7
C15H23NO

B: 124-02-7
diallylamine

Conditions

Conditions	Yield
With Al2(NMe2)6 In toluene at 90℃; for 16h; Equilibrium constant;

...Expand

: 463-49-0
1,2-propanediene

A: 102-70-5
Triallylamine

B: 107-11-9
1-amino-2-propene

C: 124-02-7
diallylamine

Conditions

Conditions	Yield
With AuC27H42N2(1+)*B(C6F5)4(1-)=(AuC27H42N2)(B(C6F5)4); ammonia In benzene-d6 at -60 - 165℃; Inert atmosphere;
With ammonia; AuC27H42N2(1+)*B(C6F5)4(1-)=(AuC27H42N2)(B(C6F5)4) In benzyl methyl ether; benzene-d6 at -60 - 175℃; Conversion of starting material;

...Expand

: 463-49-0
1,2-propanediene

A: 107-11-9
1-amino-2-propene

B: 124-02-7
diallylamine

Conditions

Conditions	Yield
With AuC27H42N2(1+)*B(C6F5)4(1-)=(AuC27H42N2)(B(C6F5)4); ammonia In benzene-d6 at -60 - 175℃; Inert atmosphere;

: 102-70-5
Triallylamine

A: 107-02-8
acrolein

B: 124-02-7
diallylamine

Conditions

Conditions	Yield
With rhodium(III) 5,10,15,20-tetra(p-sulfonatophenyl)porphyrin; oxygen; trifluoroacetic acid In water at 100℃; under 760.051 Torr; for 2h;

: diphenyl diallylphosphoramidate

: 124-02-7
diallylamine

Conditions

Conditions	Yield
Stage #1: diphenyl diallylphosphoramidate With water; monoammonium para-toluenesulfonate; o-phthalic dicarboxaldehyde In acetonitrile at 90℃; for 24h; Sealed tube; Stage #2: With sodium hydroxide In water pH=8 - 9; chemoselective reaction;

: 285-67-6
Cyclopentene oxide

: 124-02-7
diallylamine

: 77924-51-7
trans-2-(diallylamino)cyclopentanol

Conditions

Conditions	Yield
In ethanol for 24h; Heating;	100%
In ethanol at 95℃; Sealed tube;	100%
With triethylaluminum 1.) toluene, CH2Cl2, 25-30 deg C, 30 min, 2.) room temperature; Yield given. Multistep reaction;

: 3376-23-6, 7372-59-0, 59862-60-1
C-phenyl-N-methylnitrone

: 124-02-7
diallylamine

: trans-2,3-dimethyl-6-phenyl-5-(prop-2-enyl)-1,2,5-oxadiazinane

Conditions

Conditions	Yield
In chloroform at 60℃; for 72h;	100%
In chloroform at 60℃; for 72h; Cyclization;	100%

: 124-02-7
diallylamine

: 2272-55-1
ethyl trans-3-phenyl-1-oxirane-2-carboxylate

: ethyl (2R*,3R*)-3-chloro-2-(diallylamino)-3-phenylpropanoate

Conditions

Conditions	Yield
Stage #1: diallylamine; ethyl trans-3-phenyl-1-oxirane-2-carboxylate In ethanol for 12h; Ring cleavage; addition; Heating; Stage #2: With methanesulfonyl chloride; triethylamine In dichloromethane at 0 - 20℃; for 3h; Rearrangement; chlorination;	100%

: 21040-45-9
Cinnamyl acetate

: 124-02-7
diallylamine

: 155687-70-0
(E)-N,N-diallyl-3-phenylprop-2-en-1-amine

Conditions

Conditions	Yield
bis(η3-allyl-μ-chloropalladium(II)); (1RS,2RS,3SR,4SR)-1,2,3,4-tetrakis((diphenylphosphanyl)methyl)cyclopentane In water at 25℃; for 40h;	100%
bis(η3-allyl-μ-chloropalladium(II)); Tedicyp In water at 25℃; for 40h;	99%

: 925211-06-9, 925211-07-0
bicyclo(3.2.0)hept-2-en-6-one

: 126421-91-8
5-phenyl-[1,2,4]triazine-3-carboxylic acid ethyl ester

: 124-02-7
diallylamine

: [1RS,2RS,3SR,7SR,8SR,11SR,12SR]-9-allyl-12-(ethoxycarbonyl)-14-phenyl-9,13-diazapentacyclo[9.3.1.02,8.03,7.08,12]pentadecadi-4,13-ene

Conditions

Conditions	Yield
With 4 A molecular sieve In chloroform for 21h; Heating;	100%
With 4 A molecular sieve In chloroform for 21h; Heating;	100%

...Expand

: 1191-95-3
cyclobutanone

: 126421-91-8
5-phenyl-[1,2,4]triazine-3-carboxylic acid ethyl ester

: 124-02-7
diallylamine

: [1RS,2RS,5SR,8SR,9SR]-6-allyl-9-(ethoxycarbonyl)-11-phenyl-6,10-diazatetracyclo[6.2.1.02,5.05,9]dodec-10-ene

Conditions

Conditions	Yield
With 4 A molecular sieve In chloroform for 22h; Heating;	100%
With 4 A molecular sieve In chloroform for 22h; Heating;	99%

...Expand

: 19545-26-7
wortmannin

: 124-02-7
diallylamine

: acetic acid 4-diallylaminomethylene-6-hydroxy-1α-methoxymethyl-10β,13β-dimethyl-3,7,17-trioxo-1,3,4,7,10,11β,12,13,14α,15,16,17-dodecahydro-2-oxa-cyclopenta[a]phenanthren-11-yl ester

Conditions

Conditions	Yield
In dichloromethane at 20℃; for 1h;	100%
In dichloromethane at 20℃; for 1h;	68%

: 124-02-7
diallylamine

: 252577-46-1
(1R,2S,4S)-(+)-(N-bromoacetyl)bornane-10,2-sultam

: 844498-35-7
(1R,2S)-N-[2'-(diallylamino)acetyl]bornane-10,2-sultam

Conditions

Conditions	Yield
With potassium carbonate In acetone at 20℃;	100%

: 15761-38-3
L-N-Boc-Ala

: 124-02-7
diallylamine

: 950608-92-1
(S)-tert-butyl 1-(diallylamino)-1-oxopropan-2-ylcarbamate

Conditions

Conditions	Yield
Stage #1: L-N-Boc-Ala With dicyclohexyl-carbodiimide In dichloromethane at 20℃; for 0.5h; Inert atmosphere; Stage #2: diallylamine In dichloromethane at 20℃; for 12h; Inert atmosphere;	100%
With dicyclohexyl-carbodiimide In dichloromethane at 20℃; for 12h;

: 884540-65-2
17-formylwortmannin

: 124-02-7
diallylamine

: (1E,4S,4aR,5R,6aS,7S)-1-[(diallylamino)methylene]-7-(formyloxy)-11-hydroxy-4-(methoxymethyl)-4a,6a-dimethyl-2,10-dioxo-1,2,4,4a,5,6,6a,7,8,9,9a,10-dodecahydroindeno[4,5-h]isochromen-5-yl acetate

Conditions

Conditions	Yield
In dichloromethane for 0.5h;	100%

: 926648-02-4
C12H12FNO6

: 124-02-7
diallylamine

: 926648-05-7
C18H22N2O6

Conditions

Conditions	Yield
With triethylamine In acetonitrile at 20℃; for 1.5h;	100%

: 124-02-7
diallylamine

: 76-02-8
Trichloroacetyl chloride

: 39089-57-1
N,N-diallyl-α,α,α-trichloroacetamide

Conditions

Conditions	Yield
With pyridine In dichloromethane at 0 - 20℃; for 2h;	100%
With pyridine In dichloromethane at 20℃; for 2h;	94%

: 1191-99-7
2,3-dihydro-2H-furan

: 75-15-0
carbon disulfide

: 124-02-7
diallylamine

: 1239488-67-5
tetrahydrofuran-2-yl diallylcarbamodithioate

Conditions

Conditions	Yield
In water at 20℃; for 16h; regiospecific reaction;	100%

...Expand

: 79-37-8
oxalyl dichloride

: 611-73-4
Benzoylformic acid

: 124-02-7
diallylamine

: 1-phenyl-2-(diallylamino)ethane-1,2-dione

Conditions

Conditions	Yield
Stage #1: oxalyl dichloride; Benzoylformic acid With copper diacetate; N,N-dimethyl-formamide In dichloromethane at 20℃; for 2h; Stage #2: diallylamine With triethylamine In dichloromethane	100%

...Expand

: 4285-42-1
N-phenyl-N-methylcarbamoyl chloride

: 124-02-7
diallylamine

: 1,1-diallyl-3-methyl-3-phenyl-urea

Conditions

Conditions	Yield
With dmap; triethylamine In 1,2-dichloro-ethane Reflux; Inert atmosphere;	100%

: 100-69-6
2-vinylpyridine

: 75-15-0
carbon disulfide

: 124-02-7
diallylamine

: 2-(pyridin-2-yl)ethyl diallylcarbamodithioate

Conditions

Conditions	Yield
In neat (no solvent) at 20℃; for 6h; Green chemistry; regioselective reaction;	100%

...Expand

: 764-85-2
Nonanoyl chloride

: 124-02-7
diallylamine

: N,N-diallylnonanamide

Conditions

Conditions	Yield
With triethylamine In dichloromethane at 20℃; for 14h; Inert atmosphere;	100%

: 23095-16-1
2-bromo-4-methoxybenzenesulfonyl chloride

: 124-02-7
diallylamine

: N,N-diallyl-2-bromo-4-methoxybenzenesulfonamide

Conditions

Conditions	Yield
With triethylamine In dichloromethane at 0 - 20℃; for 15h;	100%

: 179251-57-1
2-bromo-5-methoxybenzenesulfonyl chloride

: 124-02-7
diallylamine

: N,N-diallyl-2-bromo-5-methoxybenzenesulfonamide

Conditions

Conditions	Yield
With triethylamine In dichloromethane at 0 - 20℃; for 15h;	100%

: 103-71-9
phenyl isocyanate

: 124-02-7
diallylamine

: 100615-32-5
1,1-diallyl-3-phenylurea

Conditions

Conditions	Yield
In diethyl ether at 20℃; for 0.166667h;	99%
With 1,6-anhydro-3,4-dideoxy-β-D-glycero-hexopyranos-2-ulose at 0 - 20℃; for 1h;	99%
With triethylamine In dichloromethane at 0 - 20℃; for 1h; Inert atmosphere;	95%

: 814-68-6
acryloyl chloride

: 124-02-7
diallylamine

: 3085-68-5
N,N-diallylacrylamide

Conditions

Conditions	Yield
With triethylamine In benzene at 0℃; for 0.5h;	99%
With trimethylamine In ethyl acetate at 23℃; for 18h; Cooling with ice;	75%
With triethylamine In dichloromethane for 24h; Ambient temperature;	71%

: 107-02-8
acrolein

: 124-02-7
diallylamine

: 142138-16-7
3-(N,N-diallylamino)-propanal

Conditions

Conditions	Yield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In tetrahydrofuran at 0℃; Michael addition;	99%
With 1,8-diazabicyclo[5.4.0]undec-7-ene In tetrahydrofuran at -15℃; for 0.166667h;	95%
With 1,8-diazabicyclo[5.4.0]undec-7-ene In tetrahydrofuran at -15℃; for 0.666667h;

: 24424-99-5
di-tert-butyl dicarbonate

: 124-02-7
diallylamine

: 151259-38-0
tert-butyl diallylcarbamate

Conditions

Conditions	Yield
In methanol at 0 - 20℃; for 1h;	99%
With iodine at 20℃; for 0.5h;	95%
In cyclohexane at 20℃; for 20h;	93%

: 586-75-4
4-chlorobenzoyl chloride

: 124-02-7
diallylamine

: 5866-96-6
N,N-diallyl-4-bromobenzamide

Conditions

Conditions	Yield
Stage #1: 4-chlorobenzoyl chloride With pyridine; Merrifield's resin-bound 6-methyl-2-thiouracil In dichloromethane at 80℃; for 0.0833333h; microwave irradiation; Stage #2: diallylamine In dichloromethane at 80℃; for 0.0833333h; microwave irradiation;	99%
With triethylamine In dichloromethane at 0 - 20℃; for 1h; Inert atmosphere;	97%
With triethylamine In dichloromethane at 0 - 20℃;	89%

: 22921-68-2
2-bromo-5-methoxy-benzoic acid

: 124-02-7
diallylamine

: 851297-49-9
N,N-diallyl-2-bromo-5-methoxy-benzamide

Conditions

Conditions	Yield
With dmap; dicyclohexyl-carbodiimide In dichloromethane at 0 - 20℃;	99%

: 98-01-1
furfural

: 124-02-7
diallylamine

: trans-4,5-bis(diallylamine)cyclopent-2-enone

Conditions

Conditions	Yield
With 4C14H11NO3(2-)2Ni(2+)2Dy(3+)2Cl(1-)2C2H3N In acetonitrile at 20℃; for 24h; Reagent/catalyst; Molecular sieve;	99%
In water at 60℃; for 0.0833333h; Microwave irradiation;	93%
With 4 A molecular sieve; dysprosium(III) trifluoromethanesulfonate In acetonitrile at 20℃; for 16h;	82%

: 37517-81-0
3-chloro-3-oxopropanoic acid methyl ester

: 124-02-7
diallylamine

: 1193366-04-9
methyl 3-(N,N-diallylamino)-3-oxopropanoate

Conditions

Conditions	Yield
In dichloromethane at 10 - 20℃;	99%

: 24424-99-5
di-tert-butyl dicarbonate

: 124-02-7
diallylamine

: 1211531-07-5
tert-butyl di(but-3-en-1-yl)carbamate

Conditions

Conditions	Yield
In methanol at 0 - 20℃;	99%

: 87751-69-7
rac-(E)-1,3-diphenyl-3-acetoxy-prop-1-ene

: 124-02-7
diallylamine

: 1202053-74-4
(S,E)-N,N-diallyl-(1,3-diphenyl-2-propenyl)amine

Conditions

Conditions	Yield
With C32H31NO2PPd(1+)*F6P(1-); potassium acetate; N,O-bis-(trimethylsilyl)-acetamide at 20℃; for 4h; Inert atmosphere; Neat (no solvent); enantioselective reaction;	99%
With N,O-bis-(trimethylsilyl)-acetamide; bis(η3-allyl-μ-chloropalladium(II)); 1-benzyl-5-(((4R,5R)-2-(2-(diphenyl-phosphino)phenyl)-4,5-diphenyl-4,5-dihydro-1H-imidazol-1-yl)methyl)-1H-1,2,3-triazole; potassium acetate In dichloromethane for 24h; Inert atmosphere; Reflux; optical yield given as %ee; enantioselective reaction;

: 131276-87-4
1-ethynyl cobaltocenium hexafluorophosphate

: 124-02-7
diallylamine

: C18H21CoN(1+)*F6P(1-)

Conditions

Conditions	Yield
In neat (no solvent) at 35℃; for 1h; Solvent; Time;	99%

Diallylamine Consensus Reports

Reported in EPA TSCA Inventory.

Diallylamine Standards and Recommendations

DOT Classification: 3; Label: Flammable Liquid

Diallylamine Specification

1. Introduction of Diallylamine

Diallylamine has the IUPAC name of N-prop-2-enylprop-2-en-1-amine. It is a kind of clear colourless to yellow liquid and belongs to the classes of Pharmaceutical Intermediates; Acyclic; Alkenes; Organic Building Blocks. And it should be stored in a cool, ventilated and dry place.

2. Properties of Diallylamine

Physical properties of Diallylamine are: (1)ACD/LogP: 1.11 ; (2)#H bond acceptors: 1; (3)#H bond donors: 1; (4)#Freely Rotating Bonds: 4; (5)Polar Surface Area: 12.03 Å²; (6)Index of Refraction: 1.432; (7)Molar Refractivity: 32.89 cm³; (8)Molar Volume: 126.5 cm³; (9)Polarizability: 13.03 ×10^-24cm³; (10)Surface Tension: 22.8 dyne/cm; (11)Density: 0.767 g/cm³; (12)Flash Point: 15.6 °C; (13)Enthalpy of Vaporization: 35.37 kJ/mol; (14)Boiling Point: 115.3 °C at 760 mmHg; (15)Vapour Pressure: 19.2 mmHg at 25°C.

3. Structure Descriptors of Diallylamine

You could convert the following datas into the molecular structure:
(1)SMILES: C=CCNCC=C
(2)InChI: InChI=1/C6H11N/c1-3-5-7-6-4-2/h3-4,7H,1-2,5-6H2
(3)InChIKey: DYUWTXWIYMHBQS-UHFFFAOYAO

4. Toxicity of Diallylamine

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
mammal (species unspecified)	LC50	inhalation	2100mg/m³ (2100mg/m³)		Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. Vol. 14, Pg. 80, 1975.
mammal (species unspecified)	LD50	unreported	350mg/kg (350mg/kg)		Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. Vol. 14, Pg. 80, 1975.
man	TCLo	inhalation	5ppm/5M (5ppm)	SENSE ORGANS AND SPECIAL SENSES: LACRIMATION: EYE LUNGS, THORAX, OR RESPIRATION: STRUCTURAL OR FUNCTIONAL CHANGE IN TRACHEA OR BRONCHI	Archives of Environmental Health. Vol. 1, Pg. 343, 1960.
mouse	LD50	intraperitoneal	187mg/kg (187mg/kg)	BEHAVIORAL: TREMOR GASTROINTESTINAL: OTHER CHANGES LUNGS, THORAX, OR RESPIRATION: RESPIRATORY DEPRESSION	Archives of Environmental Health. Vol. 1, Pg. 343, 1960.
mouse	LD50	oral	355mg/kg (355mg/kg)		"Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 43, 1982.
rabbit	LD50	skin	280uL/kg (0.28mL/kg)		American Industrial Hygiene Association Journal. Vol. 23, Pg. 95, 1962.
rat	LC50	inhalation	795ppm/8H (795ppm)	SENSE ORGANS AND SPECIAL SENSES: OTHER CHANGES: OLFACTION SENSE ORGANS AND SPECIAL SENSES: LACRIMATION: EYE LUNGS, THORAX, OR RESPIRATION: DYSPNEA	Archives of Environmental Health. Vol. 1, Pg. 343, 1960.
rat	LD50	oral	578mg/kg (578mg/kg)	BEHAVIORAL: TREMOR LUNGS, THORAX, OR RESPIRATION: DYSPNEA GASTROINTESTINAL: OTHER CHANGES	Archives of Environmental Health. Vol. 1, Pg. 343, 1960.

5. Preparation of Diallylamine

Preparation of Diallylamine: it can be prepared by diallylcyanoamine through hydrolysis in the presence of sulfuric acid. This reaction should reflux for 6 hours, and the yield is about 80-88%. In addition, it also can be prepared by diallyl-carbamic acid 1-(3,5-dimethoxy-phenyl)-2-oxo-2-phenyl-ethyl ester. The other product is 5,7-dimethoxy-2-phenyl-benzofuran. This reaction will need reagent benzene with irradiation. The yield is about 56%. The equation as follows:

Diallylamine can be prepared by diallyl-carbamic acid 1-(3,5-dimethoxy-phenyl)-2-oxo-2-phenyl-ethyl ester. The other product is 5,7-dimethoxy-2-phenyl-benzofuran

Diallylamine can be prepared by diallyl-carbamic acid 1-(3,5-dimethoxy-phenyl)-2-oxo-2-phenyl-ethyl ester. The other product is 5,7-dimethoxy-2-phenyl-benzofuran

6. Uses of Diallylamine

Uses of Diallylamine: this chemical can be used as intermediates in organic synthesis. And it can react with acryloyl chloride to get diallylacrylamide. This reaction will need reagent Et₃N and solvent benzene. The reaction time is 30 minutes at reaction temperature of 0 °C. And the yield is about 99%.

Diallylamine can react with acryloyl chloride to get diallylacrylamide

7. Safety information of Diallylamine

Hazard Codes: F,T
Risk Statements: 11-20/22-24-34
Safety Statements: 16-26-36/37/39-45-28A
RIDADR UN: 2359 3/PG 2
WGK Germany: 3
RTECS: UC6650000
F: 2-10
HazardClass: 3
PackingGroup: II
Hazardous Substances Data: 124-02-7(Hazardous Substances Data)

When you are using this chemical, please be cautious about it as the following:
This chemical is highly flammable and can cause burns. In addition, it is toxic in contact with skin and harmful by inhalation and if swallowed. During using it, wear suitable protective clothing, gloves and eye/face protection. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. And in case of accident or if you feel unwell, seek medical advice immediately (show label where possible). What's more, you should keep away from sources of ignition.

Product Name

N,N-Diallylamine

Synthetic route

Diallylamine Consensus Reports

Diallylamine Standards and Recommendations

Diallylamine Specification

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