Product Name

  • Name

    vanadium dichloride oxide

  • EINECS
  • CAS No. 10213-09-9
  • Article Data7
  • CAS DataBase
  • Density g/cm3
  • Solubility slowly decomposed in water; soluble absolute alcohol, glacial acetic acid [MER06]
  • Melting Point
  • Formula Cl2O V
  • Boiling Point °Cat760mmHg
  • Molecular Weight 137.847
  • Flash Point °C
  • Transport Information
  • Appearance
  • Safety Mutation data reported. See also VANADIUM COMPOUNDS and CHLORIDES. Reacts violently with K. When heated to decomposition it emits toxic fumes of Cl− and VOx.
  • Risk Codes
  • Molecular Structure Molecular Structure of 10213-09-9 (vanadium dichloride oxide)
  • Hazard Symbols Strong irritant to tissue.
  • Synonyms Vanadium chloride(VOCl2) (6CI); Dichlorooxovanadium; NSC 79526; Oxovanadium(IV) chloride;Vanadium chloride oxide (VCl2O); Vanadium chloride oxide (VOCl2); Vanadiumdichloride oxide; Vanadium oxychloride (VOCl2); Vanadium oxydichloride; Vanadylchloride; Vanadyl chloride (VOCl2); Vanadyl dichloride
  • PSA 17.07000
  • LogP 1.26020

Synthetic route

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

A

vanadium(II) oxide
12035-98-2

vanadium(II) oxide

B

vanadium oxychloride
13520-87-1

vanadium oxychloride

C

vanadyl chloride
10213-09-9

vanadyl chloride

Conditions
ConditionsYield
In gas byproducts: Cl2; Irradiation (UV/VIS); irradiation of VOCl3 by pulsed CO2 laser radiation; detected by luminescence spectroscopy;
...Expand
(C5H5)2V(2+) Chlorid

(C5H5)2V(2+) Chlorid

vanadyl chloride
10213-09-9

vanadyl chloride

Conditions
ConditionsYield
With oxygen In not given
With O2 In not given
vanadyl-p-toluene sulfinate
184477-10-9

vanadyl-p-toluene sulfinate

vanadyl chloride
10213-09-9

vanadyl chloride

Conditions
ConditionsYield
With hydrogenchloride In 1,4-dioxane
vanadia

vanadia

chlorine
7782-50-5

chlorine

A

vanadyl chloride
10213-09-9

vanadyl chloride

B

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

Conditions
ConditionsYield
In neat (no solvent) byproducts: VCl3, O2; 600-1000°C;
...Expand
VO(biur)2Cl2

VO(biur)2Cl2

A

BIURET
108-19-0

BIURET

B

vanadyl chloride
10213-09-9

vanadyl chloride

Conditions
ConditionsYield
In solid heating in range 220-500°C; not isolated;
oxovanadium(IV) sulfate

oxovanadium(IV) sulfate

barium(II) chloride dihydrate
10361-37-2

barium(II) chloride dihydrate

vanadyl chloride
10213-09-9

vanadyl chloride

Conditions
ConditionsYield
In ethanol at 25℃; for 1h;
sodium isopropylate
683-60-3

sodium isopropylate

vanadyl chloride
10213-09-9

vanadyl chloride

vanadyl diisopropoxide
119254-23-8

vanadyl diisopropoxide

Conditions
ConditionsYield
In ethanol byproducts: NaCl; vacuum., mixing of alcoholic VOCl2 and soln. of NaO(i-Pr) in EtOH, room temp.; removal of pptd. NaCl (freezing, liquid N2), evapn. (ca. 40°C); elem. anal.;95%
sodium ethanolate
141-52-6

sodium ethanolate

vanadyl chloride
10213-09-9

vanadyl chloride

vanadyl diethoxide
67332-62-1

vanadyl diethoxide

Conditions
ConditionsYield
In ethanol byproducts: NaCl; vacuum., mixing of alcoholic VOCl2 and soln. of NaOEt in EtOH, room temp.; removal of pptd. NaCl (freezing, liquid N2), evapn. (ca. 40°C); elem. anal.;95%
4’-ferrocenyl-2,2’:6’,2’’-terpyridine
154270-06-1

4’-ferrocenyl-2,2’:6’,2’’-terpyridine

1,7-bis(3-methoxyphenyl)-1,6-heptadiene-3,5-dione
1393710-37-6

1,7-bis(3-methoxyphenyl)-1,6-heptadiene-3,5-dione

sodium perchlorate

sodium perchlorate

vanadyl chloride
10213-09-9

vanadyl chloride

[VO(4'-ferrocenyl-2,2':6',2''-terpyridine)(bDHC)](ClO4)

[VO(4'-ferrocenyl-2,2':6',2''-terpyridine)(bDHC)](ClO4)

Conditions
ConditionsYield
Stage #1: 1,7-bis(3-methoxyphenyl)-1,6-heptadiene-3,5-dione; vanadyl chloride With sodium hydroxide In water for 0.5h;
Stage #2: 4’-ferrocenyl-2,2’:6’,2’’-terpyridine In methanol; chloroform; water for 0.5h;
Stage #3: sodium perchlorate In methanol; chloroform; water		80%
...Expand
curcumin
458-37-7

curcumin

4'-phenyl-2,2':6',2-terpyridine
58345-97-4

4'-phenyl-2,2':6',2-terpyridine

sodium perchlorate

sodium perchlorate

vanadyl chloride
10213-09-9

vanadyl chloride

[VO(4'-phenyl-2,2':6',2''-terpyridine)(Curc)](ClO4)

[VO(4'-phenyl-2,2':6',2''-terpyridine)(Curc)](ClO4)

Conditions
ConditionsYield
Stage #1: curcumin; vanadyl chloride With sodium hydroxide In water for 0.5h;
Stage #2: 4'-phenyl-2,2':6',2-terpyridine In methanol; chloroform; water for 0.5h;
Stage #3: sodium perchlorate In methanol; chloroform; water		72%
...Expand
4’-ferrocenyl-2,2’:6’,2’’-terpyridine
154270-06-1

4’-ferrocenyl-2,2’:6’,2’’-terpyridine

curcumin
458-37-7

curcumin

sodium perchlorate

sodium perchlorate

vanadyl chloride
10213-09-9

vanadyl chloride

[VO(4'-ferrocenyl-2,2':6',2''-terpyridine)(Curc)](ClO4)

[VO(4'-ferrocenyl-2,2':6',2''-terpyridine)(Curc)](ClO4)

Conditions
ConditionsYield
Stage #1: curcumin; vanadyl chloride With sodium hydroxide In water for 0.5h;
Stage #2: 4’-ferrocenyl-2,2’:6’,2’’-terpyridine In methanol; chloroform; water for 0.5h;
Stage #3: sodium perchlorate In methanol; chloroform; water		70%
...Expand
4’-ferrocenyl-2,2’:6’,2’’-terpyridine
154270-06-1

4’-ferrocenyl-2,2’:6’,2’’-terpyridine

bisdemethoxycurcumin
22608-12-4, 24939-16-0, 33171-05-0

bisdemethoxycurcumin

sodium perchlorate

sodium perchlorate

vanadyl chloride
10213-09-9

vanadyl chloride

[VO(4'-ferrocenyl-2,2':6',2''-terpyridine)(bDMC)](ClO4)

[VO(4'-ferrocenyl-2,2':6',2''-terpyridine)(bDMC)](ClO4)

Conditions
ConditionsYield
Stage #1: bisdemethoxycurcumin; vanadyl chloride With sodium hydroxide In water for 0.5h;
Stage #2: 4’-ferrocenyl-2,2’:6’,2’’-terpyridine In methanol; chloroform; water for 0.5h;
Stage #3: sodium perchlorate In methanol; chloroform; water		68%
...Expand
vanadyl chloride
10213-09-9

vanadyl chloride

salicylaldehyde
90-02-8

salicylaldehyde

2-Amino-2-methyl-1-propanol
124-68-5

2-Amino-2-methyl-1-propanol

VO(SALAHE)
103300-99-8

VO(SALAHE)

Conditions
ConditionsYield
In ethanol to an ethanolic soln. of VOCl2 was added aldehyde and amine, the soln. was stirred for about 3 h at room temp., then allowed to stand overnight; filtered, recrystd. from 1,2-dichloroethane/hexane; elem. anal.;65%
...Expand
water
7732-18-5

water

vanadyl chloride
10213-09-9

vanadyl chloride

imidazole-4-carboxylic acid
1072-84-0

imidazole-4-carboxylic acid

C8H8N4O6V

C8H8N4O6V

Conditions
ConditionsYield
With tetramethyl ammoniumhydroxide64.6%
...Expand
(R)-5-((bis(pyridin-2-ylmethyl)amino)methyl)-2,8-dimethyl-2-((4R,8R)-4,8,12-trimethyltridecyl)chroman-6-ol

(R)-5-((bis(pyridin-2-ylmethyl)amino)methyl)-2,8-dimethyl-2-((4R,8R)-4,8,12-trimethyltridecyl)chroman-6-ol

vanadyl chloride
10213-09-9

vanadyl chloride

C40H58ClN3O3V

C40H58ClN3O3V

Conditions
ConditionsYield
With oxygen In methanol for 12h;64%
water
7732-18-5

water

vanadyl chloride
10213-09-9

vanadyl chloride

imidazole-4-carboxylic acid
1072-84-0

imidazole-4-carboxylic acid

C10H12N4O6V

C10H12N4O6V

Conditions
ConditionsYield
With tetramethyl ammoniumhydroxide62.3%
...Expand
(E)-N’-(2,5-dimethoxylbenzylidene)nicotinohydrazide

(E)-N’-(2,5-dimethoxylbenzylidene)nicotinohydrazide

vanadyl chloride
10213-09-9

vanadyl chloride

2C15H15N3O3*OV(2+)

2C15H15N3O3*OV(2+)

Conditions
ConditionsYield
With triethylamine In ethanol at 80℃; for 6h;61.02%
thioacetic acid
507-09-5

thioacetic acid

vanadyl chloride
10213-09-9

vanadyl chloride

V(CH3CS3)2
76721-85-2

V(CH3CS3)2

Conditions
ConditionsYield
In neat (no solvent) byproducts: carbon dioxide, hydrochloride; solid VOCl2 and thioacetic acid warmed to 60.edgree.C for 2 days; crystal filtered, washed with water and benzene and dried under vac.; elem. anal.;60%
1-(bis(pyridin-2-ylmethyl)amino)octadecan-2-ol

1-(bis(pyridin-2-ylmethyl)amino)octadecan-2-ol

vanadyl chloride
10213-09-9

vanadyl chloride

C29H46ClN3O2V

C29H46ClN3O2V

Conditions
ConditionsYield
With triethylamine In methanol; acetonitrile Heating;55%
chlorogenic acid
327-97-9, 534-61-2, 906-33-2, 15016-60-1, 15076-00-3, 29587-84-6, 32719-11-2, 72690-58-5, 77209-78-0, 82659-69-6, 82659-70-9, 82659-71-0, 82690-55-9, 93451-45-7, 93451-46-8

chlorogenic acid

water
7732-18-5

water

vanadyl chloride
10213-09-9

vanadyl chloride

sodium hydroxide
1310-73-2

sodium hydroxide

C16H21O13V(1-)*Na(1+)*4H2O

C16H21O13V(1-)*Na(1+)*4H2O

Conditions
ConditionsYield
In methanol for 0.25h; pH=5; Inert atmosphere; Schlenk technique;50%
...Expand
water
7732-18-5

water

vanadyl chloride
10213-09-9

vanadyl chloride

sodium chloride
7647-14-5

sodium chloride

sodium hydroxide
1310-73-2

sodium hydroxide

sodium sulfite
7757-83-7

sodium sulfite

sodium trivanadium(III) bis(sulfate) hexahydroxide

sodium trivanadium(III) bis(sulfate) hexahydroxide

Conditions
ConditionsYield
In hydrogenchloride High Pressure; aq. soln. of Na comps. slowly added to a soln. of V comp., enclosed, heated at 202°C for 3 d; cooled to room temp. (0.1°C/min), cryts. filtered, washed, dried (air); elem. anal.;22%
...Expand
3,3'-(1,2-phenylenediimino)diacrolein

3,3'-(1,2-phenylenediimino)diacrolein

vanadyl chloride
10213-09-9

vanadyl chloride

oxo-(3,3`-(1,2-phenylenedinitrilo)dipropionaldehydato)vanadium(IV)

oxo-(3,3`-(1,2-phenylenedinitrilo)dipropionaldehydato)vanadium(IV)

Conditions
ConditionsYield
In methanol; N,N-dimethyl-formamide soln. of ligand in DMF was added to MeOH soln. of VOCl2; heated at 50°C for 30 min with stirring;; filtered, water added to the hot filtrate; recrystn. by cooling (refrigerator); recrystn. from DMF; elem. anal.;;18%
chlorine
7782-50-5

chlorine

vanadyl chloride
10213-09-9

vanadyl chloride

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

Conditions
ConditionsYield
Kinetics; 120-230°C; elem. anal.;
tetramethyl ammonium hydroxide

tetramethyl ammonium hydroxide

ammonium hydroxide

ammonium hydroxide

vanadyl chloride
10213-09-9

vanadyl chloride

(N-hydroxyimino)diacetic acid
87339-38-6

(N-hydroxyimino)diacetic acid

ammonium tetramethylammonium bis-(N-hydroxy-imino diacetate)vanadate(IV)

ammonium tetramethylammonium bis-(N-hydroxy-imino diacetate)vanadate(IV)

Conditions
ConditionsYield
In not given slow evapn.;
...Expand
vanadium(III) chloride
7718-98-1

vanadium(III) chloride

vanadyl chloride
10213-09-9

vanadyl chloride

A

vanadiumtetrachloride
7632-51-1

vanadiumtetrachloride

B

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

Conditions
ConditionsYield
200°C;
...Expand
phosphoric acid
86119-84-8, 7664-38-2

phosphoric acid

vanadyl chloride
10213-09-9

vanadyl chloride

oxovanadium(IV) dihydrogenphosphate

oxovanadium(IV) dihydrogenphosphate

Conditions
ConditionsYield
In not given mixing of VOCl2 soln. with 70% H3PO4, boiling with reflux for 3 h, evapn. on a water-bath, heating at 200°C; content of V(4+) and V(5+) det. by titration with potassium permanganate and Mohr's salt, XRD, EPR;
vanadyl chloride
10213-09-9

vanadyl chloride

vanadyl acetate

vanadyl acetate

Conditions
ConditionsYield
With CH3COOH; (CH3CO)2O In acetic acid in N2 atm. VOCl2 was refluxed with acetic acid containing acetic anhydride; elem. anal.;
vanadyl chloride
10213-09-9

vanadyl chloride

A

vanadium oxychloride
13520-87-1

vanadium oxychloride

B

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

Conditions
ConditionsYield
In solid
vanadyl chloride
10213-09-9

vanadyl chloride

UTP
63-39-8

UTP

vanadyl(IV) uridine-5'-triphosphate complex

vanadyl(IV) uridine-5'-triphosphate complex

Conditions
ConditionsYield
pH=7; low-temp. drying;
vanadyl chloride
10213-09-9

vanadyl chloride

5'-Uridylic Acid
58-97-9

5'-Uridylic Acid

vanadyl(IV) uridine-5'-monophosphate complex

vanadyl(IV) uridine-5'-monophosphate complex

Conditions
ConditionsYield
pH=7; low-temp. drying;
vanadyl chloride
10213-09-9

vanadyl chloride

UDP
58-98-0

UDP

vanadyl(IV) uridine-5'-diphosphate complex

vanadyl(IV) uridine-5'-diphosphate complex

Conditions
ConditionsYield
pH=7; low-temp. drying;
vanadyl chloride
10213-09-9

vanadyl chloride

ATP
56-65-5

ATP

vanadyl(IV)adenosine-5'-triphosphate complex

vanadyl(IV)adenosine-5'-triphosphate complex

Conditions
ConditionsYield
pH=7; low-temp. drying;

Dichlorooxovanadium Chemical Properties

Chemical Name: Vanadium dichloride oxide
IUPAC NAME: Oxovanadium dihydrochloride
CAS No.: 10213-09-9
EINECS: 233-517-7
Molecular Formula: Cl2H2OV
Molecular Weight: 139.86 g/mol
Following is the structure of Dichlorooxovanadium (10213-09-9):


The chemical synonymous of Dichlorooxovanadium (10213-09-9) are Vanadium dichloride oxide ; Vanadium oxydichloride ; Vanadyl dichloride ; Vanadyloxychloride ; Vanadyloxydichloride ; Dichlorooxovanadium ; Dichlorooxo-vanadium ; Dichlorooxovanadium(Iv)

Dichlorooxovanadium Toxicity Data With Reference

1.    

mrc-bcs 400 mmol/L

     MUREAV    Mutation Research. 77 (1980),109.

Dichlorooxovanadium Consensus Reports

EPA Genetic Toxicology Program.

Dichlorooxovanadium Safety Profile

Mutation data reported. See also VANADIUM COMPOUNDS and CHLORIDES. Reacts violently with K. When heated to decomposition it emits toxic fumes of Cl− and VOx.

Dichlorooxovanadium Standards and Recommendations

ACGIH TLV: TWA 0.05 mg(V2O5)/m3
NIOSH REL: (Vanadium Compounds) CL 0.05 mg(V)/m3/15M

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