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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

Vanadium(V) trichloride oxide

Cas:7727-18-6

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Vanadium trichloride oxide

Cas:7727-18-6

Min.Order:1

Negotiable

Type:Other

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Vanadyl trichloride

Cas:7727-18-6

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Pyridine,4-(4-chlorophenyl)-

Cas:7727-18-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High Purity vanadium oxytrichloride;vanadylic chloride

Cas:7727-18-6

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Hangzhou Ocean Chemical Co., Ltd.

Ocean inorganic department is a professional supplier and exporter engaging in inorganic chemical materials and metal organic compounds. Over the past years, our company is committed to improving the product quality and developing new products, in

Vanadium Trichloride Oxide

Cas:7727-18-6

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

Vanadium (V) trichloride oxide

Cas:7727-18-6

Min.Order:0

Negotiable

Type:Other

inquiry

Henan Tianfu Chemical Co., Ltd.

1.Our services:A.Supply sampleB.The packing also can be according the customers` requirmentC.Any inquiries will be replied within 24 hoursD.we provide Commerical Invoice, Packing List, Bill of loading, COA , Health certificate and Origin certificate.

Vanadium,trichlorooxo-, (T-4)-

Cas:7727-18-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard

factory directly supply CAS 7727-18-6 with competitive price

Cas:7727-18-6

Min.Order:1 Kilogram

FOB Price: $112.0

Type:Trading Company

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Vanadium,trichlorooxo-, (T-4)-

Cas:7727-18-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hubei Langyou International Trading Co., Ltd

Oxovanadium,trihydrochloride Application:Oxovanadium,trihydrochloride

Oxovanadium,trihydrochloride

Cas:7727-18-6

Min.Order:0

Negotiable

Type:Other

inquiry

Hunan Longxianng Runhui Trading Co.,Ltd

Oxovanadium,trihydrochlorideAppearance:ask Storage:Keep in dry and cool condition Package:foil aluminium bag/vacuum packing Application:intermediates Transportation:By express (Door to door) such as FEDEX, DHL, EMS for small amount. By air(airport to

Oxovanadium,trihydrochloride

Cas:7727-18-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Beantown Chemical

in stock Application:7727-18-6

Vanadium(V) trichloride oxide

Cas:7727-18-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

HuBei Ipure Biotech CO.,ltd

HuBei ipure is a diversified product production and operation enterprise, with API, pharma intermediates, and other fine chemicals as well as R&D and pigments development and sales as one of the large enterprises, with more than 130 acres of

Vanadium,trichlorooxo-, (T-4)-

Cas:7727-18-6

Min.Order:1 Gram

FOB Price: $1.0

Type:Trading Company

inquiry

Cerametek Materials(ShenZhen)Co., Ltd.

sub/micron to mesh powders (near/spheres, whiskers, flake, fiber, porous) and grain/ball, thin/ thick metal / alloys pieces / parts, thin and thick (particle) film materials /target, and custom-made crystals, substrates/parts. In the industries and a

Vanadium trichloride oxide

Cas:7727-18-6

Min.Order:0

Negotiable

Type:Other

inquiry

Hangzhou Share Chemical Co., Ltd

At Share Chemical Company, we scrupulously abide by our policy of “Excellent Quality at a Reasonable Price”. We strive to satisfy all of our customers by providing the finest quality products supported by the finest in customer servi

VanadiuM(V) trichloride oxide, V+5 28.5

Cas:7727-18-6

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Henan Fine Chemicals Co., Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & CommercialHenan Fine Chemicals Co., LTD. is a diversified technology - oriented integrated company, which mainly concentrates on fine chemicals. Our company is committed to becom

Vanadium(V) trichloride oxide

Cas:7727-18-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Shanghai united Scientific Co.,Ltd.

United Scientific Company Located in Shanghai of China , is a competitive player in the global specialty and fine chemical market. Fenghua has both the expertise and flexibility to produce a wide range of chemicals. Focusing on developing the innovat

Vanadium,trichlorooxo-, (T-4)-

Cas:7727-18-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Chungking Joyinchem Co., Ltd.

Joyinchem have been committed to chemical supply for several years and have built good cooperation records with multinational chemical corporations and importers from all over the world. Our services include:-Spot goods-Contract manufacturing-Custom

Vanadium,trichlorooxo-, (T-4)-

Cas:7727-18-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Strem Chemicals, Inc.

1.High Quality Specialty Chemicals2.Expertise and Experience in Manufacturing High Purity, High Quality Chemicals3.Long Term Focus in Inorganics, Organometallics and Metals4.ISO 9001 CertifiedAppearance:orange liq.

Vanadium(V) trichloride oxide, min. 99%

Cas:7727-18-6

Min.Order:0

Negotiable

Type:Other

inquiry

Nanjing Raymon Biotech Co., Ltd.

Pyridine,4-(4-chlorophenyl)- Storage:keep in dry and cool condition Package:25kg or according to cutomer's demand Application:Chemical research/pharma intermediate Transportation:By Sea,by Air,By courier like DHL or Fedx. Port:Shanghai/Shenzhen

Pyridine,4-(4-chlorophenyl)-

Cas:7727-18-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hebei Minshang Biotechnology Co., Ltd

Oxovanadium,trihydrochloride Application:intermediates

7727-18-6

Cas:7727-18-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Skyrun Industrial Co.,Ltd

Adequate stocks available,prompt shipment,Strictly control on quality,Timely after-sales Application:API

VanadiuM(V) trichloride oxide, V+5 28.5% Min

Cas:7727-18-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Fenjun Chemical Co Ltd.

Oxovanadium,trihydrochloride Application:Oxovanadium,trihydrochloride

Oxovanadium,trihydrochloride

Cas:7727-18-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hebei Ruishun Trade Co.,Ltd

Supply top quality products with a reasonable price Application:api

7727-18-6

Cas:7727-18-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Sparrow Chemical Co.,Ltd

Our company provides the best service for our customers. Under the premise of ensuring quality and delivery date, give customers the best price. The company is more willing to meet our customers. If you want to visit our factories and warehouses, we

VANADIUM(V)TRICHLORIDEOXIDE

Cas:7727-18-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Changzhou Foreign Trade Corp

CFTC?PharmaChem?is?a?service?based?company?in?China,?a?pharmachem?division?of?Changzhou?Foreign?Trade?Corp.,supplying?raw?materials,?intermediates,?APIs?and?fine?chemicals?for?the?pharmaceutical?and?specialty?chemical?industries?worldwide. Applicatio

vanadium trichloride oxide

Cas:7727-18-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

vanadia

vanadia

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

Conditions
ConditionsYield
With chlorine In neat (no solvent) Kinetics; heating in a flow of Cl2 at various temps. and reaction times; 99% yield after 50 min. at 680 °C;;99%
With hydrogenchloride In ethanol; water reaction V2O5 with concentrated HCl in presense a few drops of ethanol on water bath untill pentoxide dissolved giving clear blue soln.; not isolated;
In hydrogenchloride at ambient temp.;;
With SOCl2 In not given reflux. equimol. quants. V2O5 and SOCl2 for 6-8 h; product distd.; elem. anal.;
In hydrogenchloride at ambient temp.;;
thionyl chloride
7719-09-7

thionyl chloride

vanadia

vanadia

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

Conditions
ConditionsYield
In neat (no solvent) heating (excess SOCl2);;74%
In neat (no solvent) heating equimolar amounts 6 - 8 h at reflux;;
In not given at 70 - 75°C;;
vanadia

vanadia

chlorine
7782-50-5

chlorine

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

Conditions
ConditionsYield
With coal powder In neat (no solvent) distn.;;70%
With pyrographite In neat (no solvent) in 2 h at 180 - 200°C;;>99
With coal powder In neat (no solvent) heating;;
vanadia

vanadia

titanium tetrachloride
7550-45-0

titanium tetrachloride

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

Conditions
ConditionsYield
In neat (no solvent) heating 6 h under N2 at reflux (105 - 130°C);; distn.;;65%
vanadia

vanadia

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

Conditions
ConditionsYield
With chlorine In neat (no solvent) Kinetics; heating in a flow of Cl2 at various temps. and reaction times; 64% yield after 50 min. at 300 °C;;64%
aluminium trichloride
7446-70-0

aluminium trichloride

vanadia

vanadia

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

Conditions
ConditionsYield
In neat (no solvent) distn.;; VOCl3 with 0.1 % Al;;60%
In neat (no solvent) slowly heating at 400°C;;
In neat (no solvent) slowly heating at 400°C;;
hydrogenchloride
7647-01-0

hydrogenchloride

vanadia

vanadia

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

Conditions
ConditionsYield
With phosphorus pentoxide In neat (no solvent) in 3.5 h at 80 - 90°C;;17%
With P2O5 In neat (no solvent) in 3.5 h at 80 - 90°C;;17%
In diethyl ether passing HCl gas over solvent, V2O5 added;; not isolated;;
magnesium orthovanadate

magnesium orthovanadate

Dichlorodifluoromethane
75-71-8

Dichlorodifluoromethane

A

magnesium fluoride

magnesium fluoride

B

magnesium divanadate (V)
13568-63-3

magnesium divanadate (V)

C

carbon dioxide
124-38-9

carbon dioxide

D

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

Conditions
ConditionsYield
In neat (no solvent) using a fixed-bed flow reactor system at atmospheric pressure; placing of of Mg3(VO4)2 in quartz reactor; heating at 723 K under 1% CCl2F2/He atmosphere with total flow rate of 30 ml/min for 5 h; monitoring by XRD and GC-TCD;A n/a
B 1%
C n/a
D n/a
trioxovanadate(1-)

trioxovanadate(1-)

benzoyl chloride
98-88-4

benzoyl chloride

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

Conditions
ConditionsYield
In neat (no solvent) VOCl3 distd.;;
In neat (no solvent) VOCl3 distd.;;
vanadium(II) oxide
12035-98-2

vanadium(II) oxide

chlorine
7782-50-5

chlorine

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

Conditions
ConditionsYield
In neat (no solvent) annealing;;
In neat (no solvent) annealing;;
aluminium trichloride
7446-70-0

aluminium trichloride

vanadia

vanadia

1-butyl-3-methylimidazolium chloride
79917-90-1

1-butyl-3-methylimidazolium chloride

A

[VO2Cl2](1-)
44142-34-9

[VO2Cl2](1-)

B

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

Conditions
ConditionsYield
In melt in acidic imidazolium/AlCl3 ionic melt at 25°C; not isolated, detd. by (51)V-NMR and IR spectroscopy;
vanadia

vanadia

acetyl chloride
75-36-5

acetyl chloride

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

Conditions
ConditionsYield
In not given at ambiente temp.;;
In not given at ambiente temp.;;
vanadia

vanadia

acetyl chloride
75-36-5

acetyl chloride

A

acetic anhydride
108-24-7

acetic anhydride

B

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

Conditions
ConditionsYield
In neat (no solvent)
vanadia

vanadia

chlorine
7782-50-5

chlorine

sulfur
7704-34-9

sulfur

A

disulfur dichloride
10025-67-9

disulfur dichloride

B

sulfur dichloride
10545-99-0

sulfur dichloride

C

vanadiumtetrachloride
7632-51-1

vanadiumtetrachloride

D

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

Conditions
ConditionsYield
In neat (no solvent) heating;;
vanadium
7440-62-2

vanadium

chlorine
7782-50-5

chlorine

A

vanadiumtetrachloride
7632-51-1

vanadiumtetrachloride

B

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

Conditions
ConditionsYield
With oxygen In neat (no solvent) react. of V powder with gaseous Cl2 in presence of O2 at ambient temp., faster on heating;; VCl4 contaminated with VOCl3 obtained;;
With O2 In neat (no solvent) react. of V powder with gaseous Cl2 in presence of O2 at ambient temp., faster on heating;; VCl4 contaminated with VOCl3 obtained;;
thionyl chloride
7719-09-7

thionyl chloride

vanadia

vanadia

A

sulfur dioxide
7446-09-5

sulfur dioxide

B

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

Conditions
ConditionsYield
In neat (no solvent) reflux (75°C);;
In neat (no solvent) reflux (75°C);;
phosgene
75-44-5

phosgene

vanadia

vanadia

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

Conditions
ConditionsYield
With sodium In neat (no solvent) heating (300°C=reflux);;>99
In not given at 250 - 300°C;;
phosgene
75-44-5

phosgene

vanadia

vanadia

A

carbon dioxide
124-38-9

carbon dioxide

B

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

Conditions
ConditionsYield
Kinetics;
aluminium trichloride
7446-70-0

aluminium trichloride

vanadia

vanadia

A

aluminum oxochloride

aluminum oxochloride

B

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

Conditions
ConditionsYield
In neat (no solvent) at 300°C;;
In neat (no solvent) at 330°C in tube;;
In neat (no solvent) react. V2O5 with excess of AlCl3; distn. of VOCl3 and excess of AlCl3 at 300°C;
In neat (no solvent) at 330°C in tube;;
aluminium trichloride
7446-70-0

aluminium trichloride

vanadia

vanadia

1-ethyl-3-methyl-1H-imidazol-3-ium chloride
65039-09-0

1-ethyl-3-methyl-1H-imidazol-3-ium chloride

A

[VO2Cl2](1-)
44142-34-9

[VO2Cl2](1-)

B

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

Conditions
ConditionsYield
In melt in acidic imidazolium/AlCl3 ionic melt at 25°C; not isolated, detd. by (51)V-NMR and IR spectroscopy;
disulfur dichloride
10025-67-9

disulfur dichloride

vanadia

vanadia

A

vanadium(III) chloride
7718-98-1

vanadium(III) chloride

B

vanadiumtetrachloride
7632-51-1

vanadiumtetrachloride

C

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

Conditions
ConditionsYield
In not given heating;;
disulfur dichloride
10025-67-9

disulfur dichloride

vanadia

vanadia

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

Conditions
ConditionsYield
In neat (no solvent) room temp.;;
In neat (no solvent) room temp.;;
disulfur dichloride
10025-67-9

disulfur dichloride

vanadia

vanadia

chlorine
7782-50-5

chlorine

A

vanadiumtetrachloride
7632-51-1

vanadiumtetrachloride

B

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

Conditions
ConditionsYield
In neat (no solvent) passing Cl2 stream with S2Cl2 over V2O5 at ambient temp., slow heating;;
tetrachloromethane
56-23-5

tetrachloromethane

vanadia

vanadia

A

carbon dioxide
124-38-9

carbon dioxide

B

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

Conditions
ConditionsYield
In neat (no solvent) byproducts: COCl2; using a fixed-bed reaction system directly connected to GC-TCD; placing of V2O5 in quartz reactor; injecting of CCl4; heating at 723 K; monitoring by XRD and GC-TCD;
vanadia

vanadia

titanium tetrachloride
7550-45-0

titanium tetrachloride

A

titanium oxychloride

titanium oxychloride

B

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

Conditions
ConditionsYield
In neat (no solvent) heating mixture 2 h; cooling down soln.;; TiOCl as pptn.;;
In neat (no solvent)
In neat (no solvent)
vanadia

vanadia

benzoyl chloride
98-88-4

benzoyl chloride

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

Conditions
ConditionsYield
In neat (no solvent) VOCl3 distd.;;
In neat (no solvent) VOCl3 distd.;;
In not given at ambiente temp.;;
ferrous chloride

ferrous chloride

vanadia

vanadia

A

iron(III) oxide

iron(III) oxide

B

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

Conditions
ConditionsYield
In neat (no solvent) reaction at red heat;;
trichlorofluoromethane
75-69-4

trichlorofluoromethane

vanadia

vanadia

A

carbon dioxide
124-38-9

carbon dioxide

B

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

Conditions
ConditionsYield
In neat (no solvent) 280 °C, 1.5 Torr of CCl3F; monitored by gas-phase FT-IR;
vanadia

vanadia

Benzotrichlorid
98-07-7

Benzotrichlorid

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

Conditions
ConditionsYield
In neat (no solvent) between 200 - 300°C;;
di-trichloromethyl benzene

di-trichloromethyl benzene

vanadia

vanadia

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

Conditions
ConditionsYield
In neat (no solvent) at 200 - 300°C;;
In neat (no solvent) at 200 - 300°C;;
vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

trans-1,2-bis[(trimethylsilyl)oxy]cyclohexane
13871-93-7, 39789-20-3, 39789-21-4, 125329-92-2

trans-1,2-bis[(trimethylsilyl)oxy]cyclohexane

C6H10(OVOCl2)2

C6H10(OVOCl2)2

Conditions
ConditionsYield
In dichloromethane under Ar, 2 equiv. VOCl3, dropwise addn. of VOCl3 to a stirred soln. of ether in CH2Cl2 in the dark at -78°C, 25°C for 24 h; removal of volatiles by evapn. in vac.; elem. anal.;99%
tris-(trifluoromethyl)methyl hypochlorite
27579-40-4

tris-(trifluoromethyl)methyl hypochlorite

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

VO{(CF3)3CO}3
88391-96-2

VO{(CF3)3CO}3

Conditions
ConditionsYield
byproducts: (CF3)2CO, CF3Cl, Cl2; stirring at 0°C for 22 h, volatiles removed under vac.; sublimed in vac., elem. anal.;99%
2,6-diisopropylphenyl isocyanate
28178-42-9

2,6-diisopropylphenyl isocyanate

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

VCl3[N-2,6-C6H3-((i)Pr)2]

VCl3[N-2,6-C6H3-((i)Pr)2]

Conditions
ConditionsYield
In octane N2-atmosphere; refluxing equimolar amts. for 16 h; cooling to 25°C, solvent removal (vac.), solidification on standing at -50°C for 16 h; elem. anal.;99%
In octane byproducts: CO; react. of VOCl3 with ArNCO in refluxing n-octane; elem. anal.;>99
ethyl trimethylsilyl ether
1825-62-3

ethyl trimethylsilyl ether

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

chloroorthovanadic acid diethyl ester
1635-99-0

chloroorthovanadic acid diethyl ester

Conditions
ConditionsYield
In dichloromethane byproducts: (CH3)3SiCl; (N2); addn. of 3 equiv. of silane deriv. to CH2Cl2 soln. of vanadium compd. at room temp., stirring for 2 h at room temp.; evapn., elem. anal.;99%
N‑sulfinyl‑2‑methoxyaniline
17419-98-6

N‑sulfinyl‑2‑methoxyaniline

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

(o-methoxyphenylimido)vanadium(V) trichloride

(o-methoxyphenylimido)vanadium(V) trichloride

Conditions
ConditionsYield
In n-heptane for 72h; Schlenk technique; Reflux;99%
spiro[adamantane-2,2'-[2a]homoadamantan]-2'a-one
29798-94-5

spiro[adamantane-2,2'-[2a]homoadamantan]-2'a-one

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

[C10H14(C10H14)O]VOCl3

[C10H14(C10H14)O]VOCl3

Conditions
ConditionsYield
In dichloromethane in Ar atmosphere spiro(adamantan-2,2'-homoadamantan-3-one in CH2Cl2 placed in glass tube, frozen to -196 °C, gasphase removed, VOCl3 added, mixt. allowed to anneal to room temp., soln. stirred 1 h; volatiles removed in vac., wshing with n-hexane, residue dissoved in CH2Cl2, cooling to -30 °C, crystn., elem. anal.;98.8%
OC6H4CHNNC(S)NH2(2-)*2Na(1+)=Na2(OC6H4CHNNC(S)NH2)

OC6H4CHNNC(S)NH2(2-)*2Na(1+)=Na2(OC6H4CHNNC(S)NH2)

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

(VOCl)(OC6H4CHNNC(S)NH2)

(VOCl)(OC6H4CHNNC(S)NH2)

Conditions
ConditionsYield
In benzene byproducts: NaCl; anhydrous conditions, addn. of Na-salt to VOCl3 in benzene, refluxed for 12-14 h at 120°C; filtered, evapd., washed with n-hexane, dried in vac. at 40-60°Cfor 3 h, purity checked by TLC; elem. anal.;98%
2Na(1+)*OC6H4CHNNC(O)NH2(2-) = Na2(OC6H4CHNNC(O)NH2)

2Na(1+)*OC6H4CHNNC(O)NH2(2-) = Na2(OC6H4CHNNC(O)NH2)

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

(VOCl)(OC6H4CHNNC(O)NH2)

(VOCl)(OC6H4CHNNC(O)NH2)

Conditions
ConditionsYield
In benzene byproducts: NaCl; anhydrous conditions, addn. of Na-salt to VOCl3 in benzene, refluxed for 12-14 h at 120°C; filtered, evapd., washed with n-hexane, dried in vac. at 40-60°Cfor 3 h, purity checked by TLC; elem. anal.;98%
rac-(2,3-trans-butanediyl-1,4-dithiabutanediyl)-2,2'-bis(6-tert-butyl-4-methylphenol)

rac-(2,3-trans-butanediyl-1,4-dithiabutanediyl)-2,2'-bis(6-tert-butyl-4-methylphenol)

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

[(trans-1,2-dithiacyclohexanediyl-2,2'-bis(6-tert-butyl-4-methylphenolate))VOCl]

[(trans-1,2-dithiacyclohexanediyl-2,2'-bis(6-tert-butyl-4-methylphenolate))VOCl]

Conditions
ConditionsYield
In pentane (Ar); std. Schlenk technique; soln. of V compd. in pentane was added dropwise to stirred soln. of ligand in pentane at -60°C; stirred for2 h while warmed to room temp.; evacuated; washed (pentane); dried (vac.); elem. anal.;98%
Methoxytrimethylsilane
1825-61-2

Methoxytrimethylsilane

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

VOCl(methoxide)2
62449-99-4

VOCl(methoxide)2

Conditions
ConditionsYield
In dichloromethane byproducts: (CH3)3SiCl; (N2); addn. of 5 equiv. of silane deriv. to CH2Cl2 soln. of vanadium compd. at room temp., stirring for 16 h at room temp.; evapn., elem. anal.;98%
1,2-dimethoxyethane
110-71-4

1,2-dimethoxyethane

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

VOCl3*CH3OC2H4OCH3

VOCl3*CH3OC2H4OCH3

Conditions
ConditionsYield
In hexane a soln. of DME in hexane was added dropwise at room temp. over 30 min toa stirred soln. of VOCl3 in hexane, the mixt. was stirred for 1 h (iner t atm.); ppt. was filtered off, washed with hexane, dried under vac. at room temp.; elem. anal.;97%
OC10H6CHNNC(S)NH2(2-)*2Na(1+)=Na2(OC10H6CHNNC(S)NH2)

OC10H6CHNNC(S)NH2(2-)*2Na(1+)=Na2(OC10H6CHNNC(S)NH2)

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

(VOCl)(OC10H6CHNNC(S)NH2)

(VOCl)(OC10H6CHNNC(S)NH2)

Conditions
ConditionsYield
In benzene byproducts: NaCl; anhydrous conditions, addn. of Na-salt to VOCl3 in benzene, refluxed for 12-14 h at 120°C; filtered, evapd., washed with n-hexane, dried in vac. at 40-60°Cfor 3 h, purity checked by TLC; elem. anal.;97%
ethyl trimethylsilyl ether
1825-62-3

ethyl trimethylsilyl ether

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

oxovanadium(V) ethoxydichloride
1801-77-0

oxovanadium(V) ethoxydichloride

Conditions
ConditionsYield
In dichloromethane byproducts: (CH3)3SiCl; (N2); addn. of 2 equiv. of silane deriv. to CH2Cl2 soln. of vanadium compd. at room temp., stirring for 2 h at room temp.; evapn., elem. anal.;97%
trimethyl(propoxy)silane
1825-63-4

trimethyl(propoxy)silane

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

VOCl2(OnPr)
19120-63-9

VOCl2(OnPr)

Conditions
ConditionsYield
In dichloromethane byproducts: (CH3)3SiCl; (N2); addn. of 3 equiv. of silane deriv. to CH2Cl2 soln. of vanadium compd. at room temp., stirring for 2 h at room temp.; evapn., elem. anal.;97%
trimethyl(propoxy)silane

trimethyl(propoxy)silane

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

VOCl(OnPr)2

VOCl(OnPr)2

Conditions
ConditionsYield
In dichloromethane byproducts: (CH3)3SiCl; (N2); addn. of 10 equiv. of silane deriv. to CH2Cl2 soln. of vanadium compd. at room temp., stirring for 16 h at room temp.; evapn., elem. anal.;97%
vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

N-sulphinyl-2-fluoro-aniline
74653-64-8

N-sulphinyl-2-fluoro-aniline

C6H4Cl3FNV

C6H4Cl3FNV

Conditions
ConditionsYield
In n-heptane for 72h; Reflux;97%
tri-(p-chlorophenyl)-silanol
18373-61-0

tri-(p-chlorophenyl)-silanol

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

tris(tri(p-chlorophenyl)silyl)vanadate
58101-91-0

tris(tri(p-chlorophenyl)silyl)vanadate

Conditions
ConditionsYield
With triethylamine In not given according to H. Pauling et al., Helv. Chim. Acta, 1976, 59, 1233;96%
disodium salt of 2-hydroxyacetophenone thiosemicarbazone

disodium salt of 2-hydroxyacetophenone thiosemicarbazone

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

(VOCl)(OC6H4CCH3NNC(S)NH2)

(VOCl)(OC6H4CCH3NNC(S)NH2)

Conditions
ConditionsYield
In benzene byproducts: NaCl; anhydrous conditions, addn. of Na-salt to VOCl3 in benzene, refluxed for 12-14 h at 120°C; filtered, evapd., washed with n-hexane, dried in vac. at 40-60°Cfor 3 h, purity checked by TLC; elem. anal.;96%
Methoxytrimethylsilane
1825-61-2

Methoxytrimethylsilane

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

VOCl2(methoxide)
62964-20-9

VOCl2(methoxide)

Conditions
ConditionsYield
In dichloromethane byproducts: ClSi(CH3)3; (N2); addn. of 3 equiv. of silane deriv. to CH2Cl2 soln. of vanadium compd. at room temp., stirring for 2 h at room temp.; evapn., elem. anal.;96%
vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

tert-butylamine
75-64-9

tert-butylamine

A

2{NH3C(CH3)3}(1+)*{(VOCl3)O(VOCl3)}(2-)={NH3C(CH3)3}2{(VOCl3)O(VOCl3)}

2{NH3C(CH3)3}(1+)*{(VOCl3)O(VOCl3)}(2-)={NH3C(CH3)3}2{(VOCl3)O(VOCl3)}

B

tert-butylimidovanadium(V) trichloride
80545-62-6

tert-butylimidovanadium(V) trichloride

Conditions
ConditionsYield
In pentane byproducts: H2O; under Ar; slow addn. of amine soln. to dissolved VOCl3 under stirring at -78°C; stirred for 30 min; removing of ice bath; further stirring until reaction mixture was warmed up to 25°C; filtration of (NH3-t-bu-(VOCl3)2O); washed (CH2Cl2 and n-pentane); dried under vac.; solvent removed from mother liquor under vacuo; sublimation of residue (80°C, high vac.); elem. anal.; NMR; IR;A 95%
B 85%
Triethylgerman
1188-14-3

Triethylgerman

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

A

vanadyl(IV) chloride

vanadyl(IV) chloride

B

vanadium(III) oxide chloride

vanadium(III) oxide chloride

C

hydrogen
1333-74-0

hydrogen

D

triethylchlorogermane
994-28-5

triethylchlorogermane

Conditions
ConditionsYield
In neat (no solvent) heating reagents;;A n/a
B n/a
C n/a
D 95%
In neat (no solvent) heating reagents;;A n/a
B n/a
C n/a
D 95%
bis(trichlorophosphine)iminium chloride

bis(trichlorophosphine)iminium chloride

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

{Cl3PNPCl3}(1+)*VOCl4(1-)={Cl3PNPCl3}VOCl4
134416-84-5

{Cl3PNPCl3}(1+)*VOCl4(1-)={Cl3PNPCl3}VOCl4

Conditions
ConditionsYield
In dichloromethane moisture excluded, dropwise addn. of CH2Cl2 soln. of VOCl3 to suspension of Cl3PNPCl3Cl in CH2Cl2 (room temp., stirred), clear soln.; concd. in vac., addn. of CCl4, crystn., filtered, washed (CCl4), dried in vac., elem. anal.;95%
vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

HN(P(C6H5)2NC6H5)2

HN(P(C6H5)2NC6H5)2

[N(P(C6H5)2NC6H5)2(VOCl2)]

[N(P(C6H5)2NC6H5)2(VOCl2)]

Conditions
ConditionsYield
With triethylamine In benzene byproducts: triethylamine hydrochloride; soln. of HN(P(C6H5)2NC6H5)2 with triethylamine added drope-wise with stirring to ice-cooled soln. of VOCl3 (under N2) (1:1 molar ratio), broughtto room temp., stirred for 1-2 h; filtered, excess of solvent removed (vac.), dried in vac. for 3 h, purified by dissolving in diethyl ether; elem. anal.;95%
2-(1-methylethoxy)-ethanol
109-59-1

2-(1-methylethoxy)-ethanol

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

bis[μ-chloro-chloro(η2-2-isopropoxyethanolato)oxovanadium(V)]

bis[μ-chloro-chloro(η2-2-isopropoxyethanolato)oxovanadium(V)]

Conditions
ConditionsYield
In pentane byproducts: HCl; Schlenk technique, protected from direct sun light; VOCl3 slowly added to soln. of alcohol in n-pentane at 0°C; HCl completely removed by heating at 30°C; crystd. at -30°C overnight; additional portion of crystals obtained by concg. the decanted soln. and storing at -30°C overnight; elem. anal.;95%
t-butyl-N-sulfinylamine
38662-39-4

t-butyl-N-sulfinylamine

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

tert-butylimidovanadium(V) trichloride
80545-62-6

tert-butylimidovanadium(V) trichloride

Conditions
ConditionsYield
In hexane byproducts: SO2; Sonication; (Ar) VOCl3 in hexane at room temp. was added to soiln. t-BuNSO in hexane, refluxed for 2 h; volatiles were removed in vacuo at 20°C, residue was suspnd. in pentane by sonication and kept at -80°C for 24 h, ppt. was decanted, washed with chilled pentane and dried in vacuo;95%
((2,6-diisopropylphenyl)imino)-λ4-sulfanone
51068-28-1

((2,6-diisopropylphenyl)imino)-λ4-sulfanone

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

VCl3[N-2,6-C6H3-((i)Pr)2]

VCl3[N-2,6-C6H3-((i)Pr)2]

Conditions
ConditionsYield
In octane byproducts: SO2; (Ar) VOCl3 and AtNSO in n-octane eas heated at reflux for 3 h; volatiles were removed in vacuo, residue was crystd. from hot hexane by cooling soln. slowly down to -80°C; elem. anal.;95%
(tetrabutylammonium)4H3PW11O39
83721-04-4

(tetrabutylammonium)4H3PW11O39

vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

4(C4H9)4N(1+)*PVW11O39(4-)=((C4H9)4N)4[PVW11O39]

4(C4H9)4N(1+)*PVW11O39(4-)=((C4H9)4N)4[PVW11O39]

Conditions
ConditionsYield
In pyridine (Ar); stirring (1 h, 80°C); cooling (room temp.), diethyl ether addn., washing (diethyl ether), drying (vac.); elem. anal.;94%
vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

HN(P(C6H5)2NC6H5)2

HN(P(C6H5)2NC6H5)2

[(N(P(C6H5)2NC6H5)2)2(VOCl)]

[(N(P(C6H5)2NC6H5)2)2(VOCl)]

Conditions
ConditionsYield
With triethylamine In benzene byproducts: triethylamine hydrochloride; soln. of (HN(P(C6H5)2NC6H5)2) along with triethylamine added drope-wise with stirring to ice-cooled soln. of VOCl3 (under N2) (2:1 molar ratio),brought to room temp., stirred for 1-2 h; filtered, excess of solvent removed (vac.), dried in vac. for 3 h, purified by dissolving in diethyl ether; elem. anal.;94%
vanadium(V) oxychloride
7727-18-6

vanadium(V) oxychloride

Bisamine
147637-37-4

Bisamine

[(N(P(C6H5)2NSi(CH3)3)2)2(VOCl)]

[(N(P(C6H5)2NSi(CH3)3)2)2(VOCl)]

Conditions
ConditionsYield
With triethylamine In benzene byproducts: triethylamine hydrochloride; soln. of (HN(P(C6H5)2NSi(CH3)3)2) with triethylamine added drope-wise with stirring to ice-cooled soln. of VOCl3 (under N2) (2:1 molar ratio), brought to room temp., stirred for 1-2 h; filtered, excess of solvent removed (vac.), dried in vac. for 3 h, purified by dissolving in diethyl ether; elem. anal.;94%

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