Diethylenetriamine supplier

Name
Diethylenetriamine
EINECS 203-865-4
CAS No. 111-40-0
Article Data86
CAS DataBase
Density 0.951 g/cm³
Solubility miscible with water
Melting Point -40 °C
Formula C₄H₁₃N₃
Boiling Point 206.899 °C at 760 mmHg
Molecular Weight 103.167
Flash Point 94.444 °C
Transport Information UN 2079 8/PG 2
Appearance colourless liquid
Safety 26-36/37/39-45
Risk Codes 21/22-34-43
Molecular Structure
Hazard Symbols C
Synonyms 1,2-Ethanediamine,N-(2-aminoethyl)- (9CI);Diethylenetriamine (8CI);1,4,7-Triazaheptane;1,5-Diamino-3-azapentane;2,2'-Diaminodiethylamine;2,2'-Iminobis(ethanamine);2-(2-Aminoethylamino)ethylamine;3-Azapentane-1,5-diamine;Ancamine DETA;Bis(2-aminoethyl)amine;Bis(b-aminoethyl)amine;ChS-P 1;DEH 20;Epicure 3223;Epicure 3290;Epicure T;Epon 3223;H 9506;JER Cure T;JER-T;N,N-Bis(2-aminoethyl)amine;N-(2-Aminoethyl)-1,2-ethanediamine;N-(2-Aminoethyl)ethylenediamine;NCI138881;NSC 446;Diethylenetriamine;
PSA 64.07000
LogP 0.28490

Synthetic route

: 628-87-5
iminodiacetonitrile

A: 110-85-0
piperazine

B: 111-40-0
1,5-diamino-3-azapentane

Conditions

Conditions	Yield
With ammonia; hydrogen; potassium hydroxide In ethanol at 80℃; under 90009 Torr; Pressure; Reagent/catalyst; Solvent; Temperature; Time;	A 1.03% B 97.53%

: 151-56-4
ethyleneimine

: 107-15-3
ethylenediamine

: 111-40-0
1,5-diamino-3-azapentane

Conditions

Conditions	Yield
With iron(II) sulfate at 150℃; for 2h; Autoclave;	93%
palladium at 120℃; for 12h;	81%
With hydrogenchloride In water at 35℃; Kinetics; Thermodynamic data; ring opening reactions, at various temperature, Ea is given;

: 99708-65-3
[C5H4NCH2Cr(NH((CH2)2NH2)2)]Cl2

A: 4916-58-9
1,2-di-(3-pyridyl)-ethane

B: 108-99-6
3-Methylpyridine

C: 14873-01-9
chromium(III) hexahydrate cation

D: 111-40-0
1,5-diamino-3-azapentane

Conditions

Conditions	Yield
In perchloric acid Kinetics; (N2); decompn. of Cr complex in 1 M HClO4 depending on temp. under anaerobic conditions; not isolated, monitored by UV;	A 30% B 55% C n/a D n/a
In perchloric acid Kinetics; decompn. of Cr complex in 1 M HClO4 depending on temp. under aerobic conditions; not isolated, monitored by UV;	A 38% B 48% C n/a D n/a

...Expand

: 107-21-1
ethylene glycol

A: 110-85-0
piperazine

B: 141-43-5
ethanolamine

C: 111-41-1
2-(2-Aminoethylamino)ethanol

D: 107-15-3
ethylenediamine

E: 111-40-0
1,5-diamino-3-azapentane

F: 111-42-2
2,2'-iminobis[ethanol]

Conditions

Conditions	Yield
Stage #1: ethylene glycol With ammonia; hydrogen at 150℃; under 150015 Torr; Stage #2: copper oxide; graphite; molybdenum oxide; nickel oxide; zirconium dioxide; mixture of at 170℃; under 150015 Torr;	A 6.8% B 29% C 5.7% D 49.5% E 3.9% F 1.7%
With ammonia; hydrogen at 170 - 180℃; under 150015 Torr; Conversion of starting material;
With ammonia; water; hydrogen at 180℃; under 150015 Torr; Conversion of starting material;
With ammonia; hydrogen at 150 - 170℃; under 150015 Torr; Conversion of starting material;
With ammonia; hydrogen at 200℃; under 150015 Torr; Conversion of starting material;

...Expand

: 63563-83-7
bis(phthalimidylethyl)amine

: 111-40-0
1,5-diamino-3-azapentane

Conditions

Conditions	Yield
With hydrogenchloride; water

: 926-39-6
sulfuric acid mono-(2-amino-ethyl ester)

: 107-15-3
ethylenediamine

: 111-40-0
1,5-diamino-3-azapentane

Conditions

Conditions	Yield
With sodium hydroxide; water at 104℃;
With sodium hydroxide; water at 104℃;

: 107-06-2
1,2-dichloro-ethane

: 111-40-0
1,5-diamino-3-azapentane

Conditions

Conditions	Yield
With ammonia
With ammonia; water at 115 - 120℃;

: 4025-37-0
1-(2-amino-ethyl)-aziridine

: 111-40-0
1,5-diamino-3-azapentane

Conditions

Conditions	Yield
With hydrogenchloride; ammonia; ammonium chloride In water at 50℃; Rate constant; Thermodynamic data; effect of the ammonia an d hydrochloric acid concn. and the temperature;
With hydrogenchloride; ammonia In water at 60℃; Thermodynamic data; ΔH(scission), activation energy;

: 151-56-4
ethyleneimine

: ammonium chloride

: 7664-41-7
ammonia

A: 110-85-0
piperazine

B: 107-15-3
ethylenediamine

C: 111-40-0
1,5-diamino-3-azapentane

Conditions

Conditions	Yield
at 100℃; under 36775.4 Torr;
at 25℃; under 7355.08 Torr;

...Expand

1,7-di-p-toluenesulfonyl-triethylenediamine: 1,7-di-p-toluenesulfonyl-triethylenediamine

: 111-40-0
1,5-diamino-3-azapentane

Conditions

Conditions	Yield
With hydrogenchloride at 160℃;

: 7664-41-7
ammonia

: 107-06-2
1,2-dichloro-ethane

A: 107-15-3
ethylenediamine

B: 111-40-0
1,5-diamino-3-azapentane

Conditions

Conditions	Yield
unter Druck;

...Expand

: 7664-41-7
ammonia

: 106-93-4
ethylene dibromide

A: 107-15-3
ethylenediamine

B: 111-40-0
1,5-diamino-3-azapentane

C: 112-24-3
triethylentetramine

D diethylene-diamine: diethylene-diamine

...Expand

: 7664-41-7
ammonia

: 107-06-2
1,2-dichloro-ethane

A: 107-15-3
ethylenediamine

B: 111-40-0
1,5-diamino-3-azapentane

C triethylanetetraamine: triethylanetetraamine

Conditions

Conditions	Yield
unter Druck;

...Expand

: 106-93-4
ethylene dibromide

A: 111-40-0
1,5-diamino-3-azapentane

B triethylenetriamine: triethylenetriamine

Conditions

Conditions	Yield
With ammonia

: 926-39-6
sulfuric acid mono-(2-amino-ethyl ester)

: 7664-41-7
ammonia

aqueous NaOH: aqueous NaOH

A: 111-41-1
2-(2-Aminoethylamino)ethanol

B: 107-15-3
ethylenediamine

C: 111-40-0
1,5-diamino-3-azapentane

Conditions

Conditions	Yield
at 130℃; mit Dimethylamin und anderen Alkylaminen an Stelle von NH3 verlaeuft die Reaktion analog;

...Expand

: (Z)-1-[N-(2-aminoethyl)-N-(2-ammonioethyl)-amino]-diazen-1-ium-1,2-diolate

: 111-40-0
1,5-diamino-3-azapentane

Conditions

Conditions	Yield
With sodium hydroxide; phosphate buffer at 37℃; pH=5.88 - 7.46; Kinetics; Further Variations:; pH-values; Reagents;

: 23538-91-2
N,N-bis(2-(1,3-dioxoisoindolin-2-yl)ethyl)-4-methylbenzenesulfonamide

: 111-40-0
1,5-diamino-3-azapentane

Conditions

Conditions	Yield
With hydrogen bromide; acetic acid for 72h; Heating;

: 141-43-5
ethanolamine

: 111-40-0
1,5-diamino-3-azapentane

Conditions

Conditions	Yield
With ammonia; ethylenediamine; monoaluminum phosphate In tungstosilicic acid

: 107-15-3
ethylenediamine

A: 110-85-0
piperazine

B: 103-76-4
1-(2-hydroxyethyl)piperazine

C: 140-31-8
aminoethylpiperazine

D: 111-41-1
2-(2-Aminoethylamino)ethanol

E: 111-40-0
1,5-diamino-3-azapentane

F: 112-24-3
triethylentetramine

Conditions

Conditions	Yield
With hydrogen at 150 - 160℃; under 22502.3 Torr;

...Expand

: 107-15-3
ethylenediamine

A: 110-85-0
piperazine

B: 111-40-0
1,5-diamino-3-azapentane

Conditions

Conditions	Yield
hetrogeneous catalyst at 162 - 186℃; Conversion of starting material;
With hydrogen; heterogeneous Ni-Re on a 1/16" alumina silica (80:20) support at 152.1℃; under 42148.7 Torr; Product distribution / selectivity;
6.8 weight% Ni and 1.8 weight% Re on mixture of θ -alumina and silica (80:20), activated on heating in H2 at 140℃; Product distribution / selectivity; Gas phase;

: 141-43-5
ethanolamine

A: 110-85-0
piperazine

B: 103-76-4
1-(2-hydroxyethyl)piperazine

C: 140-31-8
aminoethylpiperazine

D: 111-41-1
2-(2-Aminoethylamino)ethanol

E: 107-15-3
ethylenediamine

F: 111-40-0
1,5-diamino-3-azapentane

G: 112-24-3
triethylentetramine

Conditions

Conditions	Yield
With ammonia; hydrogen at 170℃; under 150015 Torr;

...Expand

: 107-15-3
ethylenediamine

: 111-40-0
1,5-diamino-3-azapentane

Conditions

Conditions	Yield
With hydrogen; DE-A19 53 263 catalyst at 150 - 170℃; under 12751.3 - 150015 Torr; Conversion of starting material;
With hydrogen; nickel on silica/alumina (Sud-Chemie C46-7-03) at 156℃; under 42133 - 59457.9 Torr; for 1h; Product distribution / selectivity; Autoclave;
With hydrogen; heterogeneous Ni-Re on a 1/16" alumina silica (80:20) support at 150.3℃; under 42148.7 Torr; Product distribution / selectivity;

: 75-21-8
oxirane

A: 110-85-0
piperazine

B: 141-43-5
ethanolamine

C: 111-41-1
2-(2-Aminoethylamino)ethanol

D: 107-15-3
ethylenediamine

E: 111-40-0
1,5-diamino-3-azapentane

F: 111-42-2
2,2'-iminobis[ethanol]

Conditions

Conditions	Yield
Stage #1: oxirane With ammonia at 95℃; under 105011 Torr; Stage #2: With hydrogen; DE-A19 53 263 catalyst In water at 170 - 210℃; under 150015 Torr;

...Expand

: 112-24-3
triethylentetramine

: 111-40-0
1,5-diamino-3-azapentane

: 99708-64-2
[C5H4NCH2Cr(NH((CH2)2NH2)2)]Cl2

A: 109-06-8
α-picoline

B: 14873-01-9
chromium(III) hexahydrate cation

C: 111-40-0
1,5-diamino-3-azapentane

Conditions

Conditions	Yield
In perchloric acid Kinetics; (N2); decompn. of Cr complex in 1 M HClO4 depending on temp. under anaerobic conditions; not isolated, monitored by UV;
In perchloric acid Kinetics; decompn. of Cr complex in 1 M HClO4 depending on temp. under aerobic conditions; not isolated, monitored by UV;

...Expand

: 141-43-5
ethanolamine

A: 107-15-3
ethylenediamine

B: 111-40-0
1,5-diamino-3-azapentane

Conditions

Conditions	Yield
With ammonia; 10wt% CoO/10wt%NiO/4wt%CuO on γ-Al2O3 activated with hydrogen at 174.8 - 175℃; under 150015 - 165017 Torr; Product distribution / selectivity;
With ammonia; Ni-Re Product distribution / selectivity;

: 107-15-3
ethylenediamine

A: 110-85-0
piperazine

B: 111-40-0
1,5-diamino-3-azapentane

C: 112-24-3
triethylentetramine

Conditions

Conditions	Yield
With hydrogen; 10% by weight of CoO, 10% by weight of NiO and 4% by weight of CuO on γ-Al2O3 at 150 - 175℃; under 21752.2 - 67506.8 Torr; Product distribution / selectivity;
With hydrogen; 57percent nickel on silica (Engelhard Ni5256E) at 173℃; under 50407.6 - 111433 Torr; for 3h; Product distribution / selectivity; Autoclave;
With hydrogen; heterogeneous Ni-Re on a 1/16" alumina silica (80:20) support at 155.5℃; under 52491.9 Torr; Product distribution / selectivity;
With hydrogen; 6.8 wtpercent Co on theta alumina/silica (80:20) at 124 - 146℃; under 31789.8 Torr; for 487h; Product distribution / selectivity; Neat (no solvent);

...Expand

: ethylenediaminemonoacetonitrile

: 18907-76-1
2,2’-(ethane-1,2-diylbis(azanediyl))diacetonitrile

A: 110-85-0
piperazine

B: 140-31-8
aminoethylpiperazine

C: 111-40-0
1,5-diamino-3-azapentane

D: 112-24-3
triethylentetramine

Conditions

Conditions	Yield
With hydrogen; Cr-doped Raney cobalt In tetrahydrofuran; water; ethylenediamine at 120℃; under 75007.5 Torr; for 3h; Product distribution / selectivity; Autoclave;

...Expand

: 540-61-4
2-aminoacetonitrile

: 628-87-5
iminodiacetonitrile

A: 107-15-3
ethylenediamine

B: 111-40-0
1,5-diamino-3-azapentane

Conditions

Conditions	Yield
With hydrogen; Cr-doped Raney cobalt In tetrahydrofuran Product distribution / selectivity; In autoclave;
With hydrogen; Cr-doped Raney cobalt In tetrahydrofuran; water Product distribution / selectivity; In autoclave;
With hydrogen In tetrahydrofuran; water for 7h; Product distribution / selectivity; Autoclave;

...Expand

: 76-83-5
trityl chloride

: 111-40-0
1,5-diamino-3-azapentane

: N-(2-(triphenylmethyl)amino)ethyl-1,2-ethanediamine

Conditions

Conditions	Yield
In dichloromethane at 0 - 20℃; for 5h;	100%
In dichloromethane at 0℃;	94%

: 1262336-92-4
5,11,17,23-tetra-tert-butyl-25,27-di(ethoxycarbonylmethoxy)-26,28-dihydroxycalix[4]arene

: 111-40-0
1,5-diamino-3-azapentane

: 136158-03-7
(C6H2(C(CH3)3)OCH2)4H2(CH2C(O)NHCH2CH2)2NH

Conditions

Conditions	Yield
In methanol; toluene at 80℃;	100%
In methanol; toluene for 24h; Heating;	72%
In methanol; toluene Ambient temperature;	63%
In ethanol Heating;	60%
In methanol; toluene for 48h;

: 1121-60-4
pyridine-2-carbaldehyde

: 111-40-0
1,5-diamino-3-azapentane

: 58214-73-6
N-pyridin-2-ylmethyl-N'-{2-[(pyridin-2-ylmethyl)amino]ethyl}ethane-1,2-diamine

Conditions

Conditions	Yield
With hydrogen; palladium on activated charcoal In methanol under 2585.74 Torr; for 24h;	100%
Stage #1: pyridine-2-carbaldehyde; 3-azapentane-1,5-diamine In ethanol at 50℃; for 2h; Inert atmosphere; Stage #2: With sodium tetrahydroborate In ethanol at 50℃; for 2h; Inert atmosphere; chemoselective reaction;	92%
Stage #1: pyridine-2-carbaldehyde; 3-azapentane-1,5-diamine With acetic acid; zinc In methanol at 70 - 80℃; for 4.5h; Stage #2: With hydrogenchloride In methanol at 20℃; Stage #3: With sodium hydroxide In water	85%

: 498-60-2
furan-3-carboxaldehyde

: 111-40-0
1,5-diamino-3-azapentane

: N-furan-3-ylmethyl-N'-{2-[(furan-3-ylmethyl)-amino]-ethyl}-ethane-1,2-diamine

Conditions

Conditions	Yield
With hydrogen; palladium on activated charcoal In methanol under 2585.74 Torr; for 24h;	100%

: 576-83-0
2,4,6-trimethylphenyl bromide

: 111-40-0
1,5-diamino-3-azapentane

: 236111-35-6
(2,4,6-Me3C6H2NHCH2CH2)2NH

Conditions

Conditions	Yield
With tris(dibenzylideneacetone)dipalladium (0); 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate In toluene Heating;	100%

: 383-63-1
ethyl trifluoroacetate,

: 111-40-0
1,5-diamino-3-azapentane

: 88793-42-4
2,2,2-trifluoro-N-[2-({2-[(trifluoroacetyl)amino]ethyl}amino)ethyl]acetamide

Conditions

Conditions	Yield
In acetonitrile at 20℃;	100%
In water; acetonitrile for 18h; Reflux;	99%
In tetrahydrofuran Acylation; Heating;	95%

: 111-40-0
1,5-diamino-3-azapentane

: 359028-02-7
1-chloro-6-methylxanthone

: 1-[(2-aminoethyl)aminoethylamino]-6-methylxanthone

Conditions

Conditions	Yield
With potassium carbonate In N,N-dimethyl-formamide for 2h; Heating;	100%

: 5453-67-8
2,6-bis(methoxycarbonyl)pyridine

: 111-40-0
1,5-diamino-3-azapentane

: 955084-14-7
C5H3N(CONHCH2CH2NHCH2CH2NH2)2

Conditions

Conditions	Yield
In methanol for 1h; Heating;	100%

: 111-40-0
1,5-diamino-3-azapentane

: 55550-98-6
2,2-dimethyltetrahydro-[1,3]dithiol[4,5-c]furan

: 869193-24-8
C18H29N3O6S4

Conditions

Conditions	Yield
In dichloromethane at 0 - 20℃; for 1h;	100%

: 50-00-0
formaldehyd

: 111-40-0
1,5-diamino-3-azapentane

: 49859-90-7
1-(2-aminoethyl)imidazolidine

Conditions

Conditions	Yield
In water at 60℃; for 0.5h; Temperature; Solvent; Inert atmosphere;	100%
In water at 0℃; for 1.16667h;	95%

: 37942-07-7
3,5-di-tert-butyl-2-hydroxybenzaldehyde

: 111-40-0
1,5-diamino-3-azapentane

: N,N'-bis-(3,5-di-tert-butylsalicylidene)diethylenetriamine

Conditions

Conditions	Yield
In toluene at 20℃; for 4h;	100%

: 111-40-0
1,5-diamino-3-azapentane

: 616-38-6
carbonic acid dimethyl ester

: 1312807-92-3
C8H17N3O4

Conditions

Conditions	Yield
at 20℃; under 6000600 Torr; for 16h; neat (no solvent);	100%

: 111-40-0
1,5-diamino-3-azapentane

: 104-55-2
3-phenyl-propenal

: C22H25N3

Conditions

Conditions	Yield
In ethanol for 1h;	100%

: copper(II) carbonate hydroxide

: 7732-18-5
water

: 111-40-0
1,5-diamino-3-azapentane

: di(μ-carbonato)bis[aqua(diethylenetriamine)copper(II)] hexahydrate

Conditions

Conditions	Yield
at 20℃;	100%

...Expand

: 111-40-0
1,5-diamino-3-azapentane

: 172611-72-2
2-(1-hydroxy-3-methylbutylidene)-5,5-dimethylcyclohexane-1,3-dione

: 2,2'-(((azanediylbis(ethane-2,1-diyl))bis(azanediyl))bis(3-methylbutan-1-yl-1-ylidene))bis(5,5-dimethylcyclohexane-1,3-dione)

Conditions

Conditions	Yield
In dichloromethane Solvent;	100%

: 100-21-0
terephthalic acid

: 111-40-0
1,5-diamino-3-azapentane

: C16H24N6

Conditions

Conditions	Yield
at 170 - 270℃;	100%

: 4'-(2-chloroacetamido)-4'-deoxy-2'',3',3''',4''',5'',6-hexa-O-benzyl-1,2',2''',3,6',6'''-hexaazidoneomycin

: 111-40-0
1,5-diamino-3-azapentane

: 4'-[2-(2-(2-aminoethylamino)ethylamino)acetamido]-4'-deoxy-2'',3',3''',4''',5'',6-hexa-O-benzyl-1,2',2''',3,6',6'''-hexaazidoneomycin

Conditions

Conditions	Yield
In N,N-dimethyl-formamide at 20℃;	100%

: 1458-99-7
4-chloropent-2-ene

: 111-40-0
1,5-diamino-3-azapentane

: C14H29N3*2ClH

Conditions

Conditions	Yield
In water at 80℃; under 760.051 Torr; for 0.75h; Inert atmosphere;	99.96%

: 1458-99-7
4-chloropent-2-ene

: 111-40-0
1,5-diamino-3-azapentane

: 1191290-73-9
C9H21N3*ClH

Conditions

Conditions	Yield
In water at 80℃; under 760.051 Torr; for 0.75h; Inert atmosphere;	99.94%

: 1458-99-7
4-chloropent-2-ene

: 111-40-0
1,5-diamino-3-azapentane

: C19H37N3*3ClH

Conditions

Conditions	Yield
In water at 80℃; under 760.051 Torr; for 0.75h; Inert atmosphere;	99.8%

: 111-40-0
1,5-diamino-3-azapentane

: 79-11-8
chloroacetic acid

: diethylene triaminepentaacetic acid

Conditions

Conditions	Yield
Stage #1: 3-azapentane-1,5-diamine; chloroacetic acid With sodium hydroxide In water at 35 - 60℃; for 8h; pH=11.2 - 11.5; Stage #2: With sodium carbonate In water at 40 - 80℃; for 2h; Reagent/catalyst;	99.7%

: 5153-40-2
2,3,4,5,6-pentamethylbromobenzene

: 111-40-0
1,5-diamino-3-azapentane

: 862464-60-6
N1-(2,3,4,5,6-pentamethylphenyl)-N2-(2-(2,3,4,5,6-pentamethylphenylamino)ethyl)ethane-1,2-diamine

Conditions

Conditions	Yield
With sodium t-butanolate; (R)-(-)-1-[(SP)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine; palladium diacetate In 1,2-dimethoxyethane at 100℃; for 14h; Product distribution / selectivity;	99.4%

: 90-02-8
salicylaldehyde

: 111-40-0
1,5-diamino-3-azapentane

: 2851-60-7
N,N'-bis(salicylidene)diethylenetriamine

Conditions

Conditions	Yield
In neat (no solvent) at 20℃; Green chemistry;	99%
In ethanol at 20℃; for 24h;	92.5%
In water at 20℃; for 1h;	92%

: 66433-95-2
2,6-Bis(2-formylphenoxymethyl)pyridine

: 111-40-0
1,5-diamino-3-azapentane

: C25H26N4O2

Conditions

Conditions	Yield
In toluene	99%

: 111-40-0
1,5-diamino-3-azapentane

: 98-59-9
p-toluenesulfonyl chloride

: 56187-04-3
1,4,7-tritosyl-1,4,7-triazaheptane

Conditions

Conditions	Yield
With sodium hydroxide In diethyl ether; water at 0℃; for 1h;	99%
With triethylamine In dichloromethane at 0℃; for 24h;	95%
With potassium carbonate In water; acetone at 0 - 20℃; for 5h;	92%

: 111-40-0
1,5-diamino-3-azapentane

: 90-80-2
D-Glucono-1,5-lactone

: (2S,3R,4S,5R)-2,3,4,5,6-Pentahydroxy-hexanoic acid {2-[2-((2S,3R,4S,5R)-2,3,4,5,6-pentahydroxy-hexanoylamino)-ethylamino]-ethyl}-amide

Conditions

Conditions	Yield
In N,N-dimethyl-formamide at 20℃; amidation;	99%

: 111-40-0
1,5-diamino-3-azapentane

: 1H-benzotriazole-1-carboxamidine hydrochloride

: 90010-56-3
N,N-di(2-guanidinylethyl)amine

Conditions

Conditions	Yield
With triethylamine In acetonitrile at 60℃; for 6h;	99%

: 111-40-0
1,5-diamino-3-azapentane

: N,N-dimethyl-1H-benzotriazole-carboximidamide hydrochloride

: N'-{2-[2-(N',N'-dimethyl-guanidino)-ethylamino]-ethyl}-N,N-dimethyl-guanidine

Conditions

Conditions	Yield
With triethylamine In acetonitrile at 60℃; for 6h;	99%

: bis(1,1,1-trifluoroacetylacetonato)copper(II)

: 111-40-0
1,5-diamino-3-azapentane

: copper bis(1,1,1-trifluoro-2,4-pentanedionate) diethylenetriamine

Conditions

Conditions	Yield
In chloroform anhydrous dien added to soln. of complex;; pptd. from hexane; vacuum-dried; elem. anal.;;	99%

: nickel(II) chloride hexahydrate

: 677-71-4
hexafluoroacetone hydrate

: 111-40-0
1,5-diamino-3-azapentane

: [Ni(di(2-aminoethyl)amine)2][HOC(CF3)2O]2

Conditions

Conditions	Yield
With KOH In ethanol byproducts: KCl; HOC(CF3)2OH and KOH ethanol soln. addn. to NiCl2 ethanol soln., stirring(30 min); solvent and KCl removing, recrystn. (methanol/ethanol/2-propanol); elem.anal.;	99%

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Diethylenetriamine Consensus Reports

Reported in EPA TSCA Inventory.

Diethylenetriamine Standards and Recommendations

OSHA PEL: TWA 1 ppm
ACGIH TLV: TWA 1 ppm (skin)
DOT Classification: 8; Label: Corrosive

Diethylenetriamine Analytical Methods

For occupational chemical analysis use OSHA: #ID-60 or NIOSH: Diethylenetriamine, 2540.

Diethylenetriamine Specification

The Diethylenetriamine, with the CAS registry number 111-40-0,is also known as 2,2'-Diaminodiethylamine; 2,2'-Iminodi(ethylamine); DETA. It belongs to the product categories of Organics;organic amine. This chemical's molecular formula is C₄H₁₃N₃ and molecular weight is 103.17.Its EINECS number is 203-865-4. What's more,Its systematic name is Diethylenetriamine. It is a colourless liquid which is stable, incompatible with strong oxidizing agents, copper and its alloys,but absorbs carbon dioxide from the air. And it is used as chemical intermediate for reactive polyamide resins, fatty aminoamides, fatty imidazolines.

Physical properties about Diethylenetriamine are:
(1)ACD/LogP: -1.87; (2)# of Rule of 5 Violations: 1; (3)ACD/LogD (pH 5.5): -5.98; (4)ACD/LogD (pH 7.4): -5.73; (5)ACD/BCF (pH 5.5): 1.00; (6)ACD/BCF (pH 7.4): 1.00; (7)ACD/KOC (pH 5.5): 1.00; (8)ACD/KOC (pH 7.4): 1.00; (9)#H bond acceptors: 3; (10)#H bond donors: 5; (11)#Freely Rotating Bonds: 6; (12)Index of Refraction: 1.476; (13)Molar Refractivity: 31.246 cm³; (14)Molar Volume: 110.733 cm³; (15)Surface Tension: 39.3380012512207 dyne/cm; (16)Density: 0.932 g/cm³; (17)Flash Point: 94.444 °C; (18)Enthalpy of Vaporization: 44.315 kJ/mol; (19)Boiling Point: 206.899 °C at 760 mmHg; (20)Vapour Pressure: 0.23199999332428 mmHg at 25°C.

You can still convert the following datas into molecular structure:
(1)SMILES:C(CNCCN)N;
(2)Std. InChI:InChI=1S/C4H13N3/c5-1-3-7-4-2-6/h7H,1-6H2;
(3)Std. InChIKey:RPNUMPOLZDHAAY-UHFFFAOYSA-N.

Safety Information of Diethylenetriamine:
The Diethylenetriamine is danger of cumulative effects and harmful in contact with skin and if swallowed .It may cause sensitization by skin contact .In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.When you use it ,wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .

The toxicity data of Diethylenetriamine are as follows:

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
guinea pig	LD50	skin	170uL/kg (.17mL/kg)		Journal of Industrial Hygiene and Toxicology. Vol. 26, Pg. 269, 1944.
guinea pig	LD50	unreported	600mg/kg (600mg/kg)		Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 37(7), Pg. 103, 1972.
mouse	LD50	intraperitoneal	71mg/kg (71mg/kg)	BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD GASTROINTESTINAL: PERITONITIS	AMA Archives of Industrial Health. Vol. 17, Pg. 129, 1958.
mouse	LD50	unreported	970mg/kg (970mg/kg)		Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 37(7), Pg. 103, 1972.
rabbit	LD50	skin	1090mg/kg (1090mg/kg)		Journal of Industrial Hygiene and Toxicology. Vol. 31, Pg. 60, 1949.
rabbit	LD50	unreported	970mg/kg (970mg/kg)		Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 37(7), Pg. 103, 1972.
rat	LCLo	inhalation	70mg/m3/4H (70mg/m3)		National Technical Information Service. Vol. OTS0556409,
rat	LD50	intraperitoneal	74mg/kg (74mg/kg)	GASTROINTESTINAL: PERITONITIS BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD	AMA Archives of Industrial Health. Vol. 17, Pg. 129, 1958.
rat	LD50	oral	1080mg/kg (1080mg/kg)	BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD	AMA Archives of Industrial Health. Vol. 17, Pg. 129, 1958.
rat	LD50	unreported	970mg/kg (970mg/kg)		Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 37(7), Pg. 103, 1972.

Product Name

Diethylenetriamine

Synthetic route

Diethylenetriamine Consensus Reports

Diethylenetriamine Standards and Recommendations

Diethylenetriamine Analytical Methods

Diethylenetriamine Specification

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