(2,4,6-trimethylbenzoyl)diphenylphosphine oxide
Conditions | Yield |
---|---|
With manganese(IV) oxide In dichloromethane at 20℃; | 98% |
With vanadium(V) oxide; dihydrogen peroxide at 8 - 25℃; for 3.5h; Reagent/catalyst; Green chemistry; | 96% |
With tert.-butylhydroperoxide In dichloromethane at 5 - 20℃; for 6.5h; Reagent/catalyst; | 92.5% |
mesytaldehyde
Diphenylphosphine oxide
(2,4,6-trimethylbenzoyl)diphenylphosphine oxide
Conditions | Yield |
---|---|
Stage #1: mesytaldehyde; Diphenylphosphine oxide In dichloromethane for 6h; Green chemistry; Stage #2: With ammonium metavanadate; dihydrogen peroxide at 8 - 20℃; for 5.5h; Reagent/catalyst; Green chemistry; | 98% |
diphenyl n-pentyloxyphosphine
mesitylene-2-carboxylic acid chloride
(2,4,6-trimethylbenzoyl)diphenylphosphine oxide
Conditions | Yield |
---|---|
at 50 - 90℃; for 9.33333h; | 95.8% |
(sec-butyloxy)di(phenyl)phosphine
mesitylene-2-carboxylic acid chloride
(2,4,6-trimethylbenzoyl)diphenylphosphine oxide
Conditions | Yield |
---|---|
at 50 - 90℃; for 7.33333h; | 95.6% |
Ethyl diphenylphosphinite
mesitylene-2-carboxylic acid chloride
(2,4,6-trimethylbenzoyl)diphenylphosphine oxide
Conditions | Yield |
---|---|
at 40 - 90℃; for 8h; Time; Green chemistry; | 95.1% |
With N,N-dimethyl-cyclohexanamine at 80 - 85℃; Product distribution / selectivity; |
diphenyl n-propoxyphosphine
mesitylene-2-carboxylic acid chloride
(2,4,6-trimethylbenzoyl)diphenylphosphine oxide
Conditions | Yield |
---|---|
at 50 - 90℃; for 7.33333h; | 95.1% |
diphenyl sec-pentyloxyphosphine
mesitylene-2-carboxylic acid chloride
(2,4,6-trimethylbenzoyl)diphenylphosphine oxide
Conditions | Yield |
---|---|
at 50 - 90℃; for 7.33333h; | 94.9% |
(n-butyloxy)di(phenyl)phosphine
mesitylene-2-carboxylic acid chloride
(2,4,6-trimethylbenzoyl)diphenylphosphine oxide
Conditions | Yield |
---|---|
at 50 - 90℃; for 9.33333h; | 94.8% |
(2,4,6-trimethylbenzyl)diphenylphosphine oxide
(2,4,6-trimethylbenzoyl)diphenylphosphine oxide
Conditions | Yield |
---|---|
With tert.-butylhydroperoxide; bis(acetylacetonate)oxovanadium In dichloromethane at 20℃; | 94% |
ethanol
chloro-diphenylphosphine
mesitylene-2-carboxylic acid chloride
(2,4,6-trimethylbenzoyl)diphenylphosphine oxide
Conditions | Yield |
---|---|
Stage #1: ethanol With sodium In toluene at 65 - 70℃; for 2h; Stage #2: chloro-diphenylphosphine In toluene at 5 - 10℃; for 1h; Stage #3: mesitylene-2-carboxylic acid chloride In toluene at 70 - 75℃; for 5h; Temperature; Solvent; | 92.2% |
(trichloromethyl)mesitylene
chloro-diphenylphosphine
(2,4,6-trimethylbenzoyl)diphenylphosphine oxide
Conditions | Yield |
---|---|
Stage #1: chloro-diphenylphosphine With potassium hydroxide In toluene at 20℃; for 2.5h; Inert atmosphere; Stage #2: (trichloromethyl)mesitylene With iron(III) chloride at 90℃; Inert atmosphere; | 91% |
Stage #1: (trichloromethyl)mesitylene; chloro-diphenylphosphine With magnesium In tetrahydrofuran Reflux; Stage #2: With hydrogenchloride; dihydrogen peroxide In water | 87 g |
isopropyl diphenylphosphinite
mesitylene-2-carboxylic acid chloride
(2,4,6-trimethylbenzoyl)diphenylphosphine oxide
Conditions | Yield |
---|---|
at 50 - 90℃; for 7.33333h; | 90.7% |
(trichloromethyl)mesitylene
Diphenylphosphine oxide
(2,4,6-trimethylbenzoyl)diphenylphosphine oxide
Conditions | Yield |
---|---|
Stage #1: (trichloromethyl)mesitylene; Diphenylphosphine oxide With iron(III) chloride In toluene at 90℃; for 3h; Inert atmosphere; Stage #2: With water; sodium hydrogencarbonate In toluene at 20℃; Inert atmosphere; | 89% |
Stage #1: Diphenylphosphine oxide With n-butyllithium In tetrahydrofuran for 0.5h; Cooling with ice; Stage #2: (trichloromethyl)mesitylene In tetrahydrofuran for 0.5h; | 87% |
Diphenylphosphine oxide
mesitylene-2-carboxylic acid chloride
B
(2,4,6-trimethylbenzoyl)diphenylphosphine oxide
Conditions | Yield |
---|---|
With potassium hydroxide In 1,2-dichloro-ethane at -10℃; Solvent; Reagent/catalyst; Temperature; Inert atmosphere; | A 8% B 89% |
Diphenylphosphine oxide
mesitylene-2-carboxylic acid chloride
(2,4,6-trimethylbenzoyl)diphenylphosphine oxide
Conditions | Yield |
---|---|
With dmap at 80℃; | 88.2% |
With Methyltrichlorosilane; triethylamine In 1,4-dioxane at 60℃; Catalytic behavior; Reagent/catalyst; Solvent; Temperature; Schlenk technique; Inert atmosphere; Green chemistry; | 71% |
Stage #1: mesitylene-2-carboxylic acid chloride With aluminum (III) chloride In 1,2-dichloro-ethane at 20℃; for 1h; Inert atmosphere; Stage #2: Diphenylphosphine oxide In 1,2-dichloro-ethane for 5h; Reflux; | 1.6 g |
(2,4,6-trimethylbenzoyl)diphenylphosphine oxide
Conditions | Yield |
---|---|
With dihydrogen peroxide In toluene | 84% |
tetrachloromethane
Diphenylphosphine oxide
1,3,5-trimethyl-benzene
(2,4,6-trimethylbenzoyl)diphenylphosphine oxide
Conditions | Yield |
---|---|
Stage #1: tetrachloromethane; 1,3,5-trimethyl-benzene With aluminum (III) chloride at 40℃; for 3.25h; Inert atmosphere; Stage #2: With hydrogenchloride; water at 20℃; for 0.5h; Inert atmosphere; Stage #3: Diphenylphosphine oxide In toluene Reagent/catalyst; Inert atmosphere; | 84% |
diphenylphosphinous acid methyl ester
2,2,2-trichloro-1-(2,4,6-trimethylphenyl)ethan-1-one
(2,4,6-trimethylbenzoyl)diphenylphosphine oxide
Conditions | Yield |
---|---|
In toluene at 40 - 60℃; | 82% |
Ethyl diphenylphosphinite
2,2,2-trichloro-1-(2,4,6-trimethylphenyl)ethan-1-one
(2,4,6-trimethylbenzoyl)diphenylphosphine oxide
Conditions | Yield |
---|---|
In toluene at 40 - 60℃; | 81% |
tetrachloromethane
chloro-diphenylphosphine
1,3,5-trimethyl-benzene
(2,4,6-trimethylbenzoyl)diphenylphosphine oxide
Conditions | Yield |
---|---|
Stage #1: tetrachloromethane; 1,3,5-trimethyl-benzene With aluminum (III) chloride at 40℃; for 3.25h; Inert atmosphere; Stage #2: With hydrogenchloride; water at 20℃; for 0.5h; Inert atmosphere; Stage #3: chloro-diphenylphosphine Further stages; | 81% |
Conditions | Yield |
---|---|
Stage #1: benzene With aluminum (III) chloride; phosphorus trichloride at 70 - 120℃; Stage #2: mesytaldehyde at 5 - 10℃; Stage #3: With tungsten trioxide; tetrabutylammomium bromide; dihydrogen peroxide; sodium hydroxide at 5 - 10℃; pH=2; | 80% |
1,3,5-trimethyl-benzene
(2,4,6-trimethylbenzoyl)diphenylphosphine oxide
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: aluminum (III) chloride; hydrogenchloride / 2 h / 20 °C 2: magnesium / tetrahydrofuran / Reflux View Scheme | |
Multi-step reaction with 2 steps 1.1: aluminum (III) chloride / 3 h / 20 - 45 °C 2.1: n-butyllithium / tetrahydrofuran / 0.5 h / Cooling with ice 2.2: 0.5 h View Scheme | |
Multi-step reaction with 3 steps 1.1: aluminum (III) chloride / 3 h / 20 - 45 °C 2.1: lithium / tetrahydrofuran / 35 °C / Inert atmosphere 2.2: 20 °C 3.1: dihydrogen peroxide / toluene View Scheme | |
Multi-step reaction with 2 steps 1.1: C8H15N2(1+)*Br(1-)*2AlCl3; titanium tetrachloride; 1-methylimidazole hydrogen sulfate / 20 °C / 22502.3 - 30003 Torr / Autoclave 2.1: water; chlorobenzene / 2 h / 5 - 20 °C 2.2: 20 h / 5 °C / pH 3 View Scheme |
(trichloromethyl)mesitylene
(2,4,6-trimethylbenzoyl)diphenylphosphine oxide
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1.1: lithium / tetrahydrofuran / 35 °C / Inert atmosphere 1.2: 20 °C 2.1: dihydrogen peroxide / toluene View Scheme |
2,4,6-trimethylbenzyl alcohol
Diphenylphosphine oxide
(2,4,6-trimethylbenzoyl)diphenylphosphine oxide
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: dipotassium peroxodisulfate / acetone / 20 °C 2: manganese(IV) oxide / dichloromethane / 20 °C View Scheme |
mesitylene-2-carboxylic acid chloride
diphenyl(methyl)phosphine oxide
(2,4,6-trimethylbenzoyl)diphenylphosphine oxide
Conditions | Yield |
---|---|
In toluene at 0 - 80℃; for 3h; Inert atmosphere; | |
In toluene at 0 - 80℃; for 3h; Inert atmosphere; |
benzene
(2,4,6-trimethylbenzoyl)diphenylphosphine oxide
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: aluminum (III) chloride; trichlorophosphate / 4 h / 70 °C / Inert atmosphere 2: dmap / 80 °C View Scheme | |
Multi-step reaction with 2 steps 1.1: aluminum (III) chloride; trichlorophosphate / 70 - 120 °C 1.2: 0.5 h / 30 °C 2.1: toluene / 40 - 60 °C View Scheme | |
Multi-step reaction with 2 steps 1.1: aluminum (III) chloride; trichlorophosphate / 70 - 130 °C 1.2: 0.5 h / 30 °C 2.1: toluene / 40 - 60 °C View Scheme |
(2,4,6-trimethylbenzoyl)diphenylphosphine oxide
Conditions | Yield |
---|---|
With dihydrogen peroxide In diethyl ether at 30 - 45℃; for 2h; Inert atmosphere; | 59.3g |
With tert.-butylhydroperoxide; vanadia In chlorobenzene at 30℃; under 1500.15 Torr; for 0.00138889h; Temperature; Reagent/catalyst; | |
With 3-chloro-benzenecarboperoxoic acid In tetrahydrofuran at 25℃; for 3h; Inert atmosphere; |
chloro-diphenylphosphine
(2,4,6-trimethylbenzoyl)diphenylphosphine oxide
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 1-methyl-1H-imidazole / 2 h / 35 - 60 °C 2: 7.33 h / 50 - 90 °C View Scheme | |
Multi-step reaction with 2 steps 1: 1-methyl-1H-imidazole / 2 h / 45 - 65 °C 2: 9.33 h / 50 - 90 °C View Scheme | |
Multi-step reaction with 2 steps 1: 1-methyl-1H-imidazole / 2 h / 50 - 100 °C 2: 7.33 h / 50 - 90 °C View Scheme | |
Multi-step reaction with 2 steps 1: 1-methyl-1H-imidazole / 2 h / 50 - 65 °C 2: 7.33 h / 50 - 90 °C View Scheme | |
Multi-step reaction with 2 steps 1: 1-methyl-1H-imidazole / 3 h / 50 - 80 °C 2: 9.33 h / 50 - 90 °C View Scheme |
mesytaldehyde
chloro-diphenylphosphine
(2,4,6-trimethylbenzoyl)diphenylphosphine oxide
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: chlorobenzene / 0 h / 30 °C / 1500.15 Torr 2: vanadia; tert.-butylhydroperoxide / chlorobenzene / 0 h / 30 °C / 1500.15 Torr View Scheme | |
Stage #1: mesytaldehyde; chloro-diphenylphosphine In water; chlorobenzene at 5 - 20℃; for 2h; Stage #2: With ammonium molibdate; tetrabutylammomium bromide; dihydrogen peroxide; sodium hydroxide In water; chlorobenzene at 5℃; for 20h; pH=3; |
(2,4,6-trimethylbenzoyl)diphenylphosphine oxide
2-chloropropionyl chloride
Conditions | Yield |
---|---|
With aluminum (III) chloride In dichloromethane at 10 - 35℃; for 7h; | 99% |
1-iodoperfluorododecane
(2,4,6-trimethylbenzoyl)diphenylphosphine oxide
pentacosafluorododecyldiphenylphosphine
Conditions | Yield |
---|---|
With Diphenylphosphine oxide at 20℃; for 6h; Inert atmosphere; Irradiation; | 98% |
(2,4,6-trimethylbenzoyl)diphenylphosphine oxide
diphenyl(2,4,6-trimethylphenyl)phosphine oxide
Conditions | Yield |
---|---|
With tris-(dibenzylideneacetone)dipalladium(0); tricyclohexylphosphine In 5,5-dimethyl-1,3-cyclohexadiene at 130℃; for 16h; Schlenk technique; Inert atmosphere; | 97% |
1-Iodo-perfluorodecane
(2,4,6-trimethylbenzoyl)diphenylphosphine oxide
Conditions | Yield |
---|---|
With Diphenylphosphine oxide at 20℃; for 1.5h; Wavelength; Reagent/catalyst; Time; Inert atmosphere; Irradiation; | 96% |
With diphenylphosphane at 20℃; for 3.5h; Wavelength; Irradiation; Inert atmosphere; Sealed tube; | 81 %Spectr. |
In chloroform-d1 at 15 - 25℃; for 3.5h; Solvent; Irradiation; Sealed tube; | 41 %Spectr. |
dodecafluoro-1,6-diiodohexane
(2,4,6-trimethylbenzoyl)diphenylphosphine oxide
1,6-bis(diphenylthiophosphinyl)perfluorohexane
Conditions | Yield |
---|---|
Stage #1: dodecafluoro-1,6-diiodohexane; (2,4,6-trimethylbenzoyl)diphenylphosphine oxide With Diphenylphosphine oxide at 20℃; for 6h; Inert atmosphere; Irradiation; Stage #2: With sulfur at 80℃; for 5h; Inert atmosphere; | 96% |
4,4'-dimethoxyphenyl disulfide
(2,4,6-trimethylbenzoyl)diphenylphosphine oxide
B
S-(4-methoxyphenyl)thiodiphenylphosphorus oxide
Conditions | Yield |
---|---|
In dichloromethane at 20℃; for 6h; Inert atmosphere; Sealed tube; Irradiation; | A 87% B 96% |
(2,4,6-trimethylbenzoyl)diphenylphosphine oxide
diphenyldisulfane
A
S-phenyl 2,4,6-trimethylthiobenzoate
B
diphenylthiophosphinic acid-S-phenyl ester
Conditions | Yield |
---|---|
In dichloromethane at 20℃; for 6h; Inert atmosphere; Sealed tube; Irradiation; | A 78% B 95% |
1-Iodo-perfluorodecane
(2,4,6-trimethylbenzoyl)diphenylphosphine oxide
diphenylphosphane
Conditions | Yield |
---|---|
at 20℃; for 1.5h; Irradiation; | 95% |
In chloroform-d1 at 15 - 25℃; for 1.5h; Irradiation; Sealed tube; | 88% |
di(p-tolyl) disulfide
(2,4,6-trimethylbenzoyl)diphenylphosphine oxide
A
S-(4-methylphenyl)thiodiphenylphosphorus oxide
Conditions | Yield |
---|---|
In dichloromethane at 20℃; for 6h; Inert atmosphere; Sealed tube; Irradiation; | A 94% B 94% |
bis(p-chlorophenyl) diselenide
(2,4,6-trimethylbenzoyl)diphenylphosphine oxide
Conditions | Yield |
---|---|
In dichloromethane at 20℃; for 6h; Inert atmosphere; Sealed tube; Irradiation; | A 94% B 92% |
dibutyl diselenide
(2,4,6-trimethylbenzoyl)diphenylphosphine oxide
Conditions | Yield |
---|---|
In dichloromethane at 20℃; for 6h; Inert atmosphere; Sealed tube; Irradiation; | A 91% B 94% |
diphenyl diselenide
(2,4,6-trimethylbenzoyl)diphenylphosphine oxide
A
Se-phenyl diphenylselenophosphinate
Conditions | Yield |
---|---|
In dichloromethane at 20℃; for 6h; Inert atmosphere; Sealed tube; Irradiation; | A 92% B 88% |
(2,4,6-trimethylbenzoyl)diphenylphosphine oxide
chloroacetyl chloride
Conditions | Yield |
---|---|
With aluminum (III) chloride In dichloromethane at 10 - 35℃; for 7h; | 92% |
dibenzyl disulphide
(2,4,6-trimethylbenzoyl)diphenylphosphine oxide
A
diphenylphosphinothioic acid S-benzyl ester
Conditions | Yield |
---|---|
In dichloromethane at 20℃; for 6h; Inert atmosphere; Sealed tube; Irradiation; | A 91% B 40 %Spectr. |
1-Iodo-perfluorodecane
(2,4,6-trimethylbenzoyl)diphenylphosphine oxide
Diphenylphosphine oxide
Conditions | Yield |
---|---|
at 20℃; for 1.5h; Irradiation; | 90% |
In chloroform-d1 at 15 - 25℃; for 1.5h; Irradiation; | 90% |
IUPAC Name: Diphenylphosphoryl-(2,4,6-trimethylphenyl)methanone
Following is the structure of 2,4,6-Trimethylbenzoyldiphenylphosphine Oxide (CAS NO.75980-60-8):
Molecular formula: C22H21O2P
Molecular Weight: 348.37 g/mol
EINECS: 278-355-8
Index of Refraction: 1.6
Molar Refractivity: 101.52 cm3
Molar Volume: 296.6 cm3
Density: 1.17 g/cm3
Flash Point: 268.1 °C
Melting point: 88-92 °C(lit.)
Surface Tension: 48.4 dyne/cm
Enthalpy of Vaporization: 79.24 kJ/mol
Boiling Point: 519.6 °C at 760 mmHg
Vapour Pressure: 6.71E-11 mmHg at 25°C
Product Categories of 2,4,6-Trimethylbenzoyldiphenylphosphine Oxide (CAS NO.75980-60-8): Functional Materials; Photopolymerization Initiators; Miscellaneous; Organic Photoinitiators; Polymerization Initiators
Stability of 2,4,6-Trimethylbenzoyldiphenylphosphine Oxide (CAS NO.75980-60-8): Stable. Incompatible with strong oxidizing agents.
Appearance of 2,4,6-Trimethylbenzoyldiphenylphosphine Oxide (CAS NO.75980-60-8): white or cream powder
Canonical SMILES: CC1=CC(=C(C(=C1)C)C(=O)P(=O)(C2=CC=CC=C2)C3=CC=CC=C3)C
InChI: InChI=1S/C22H21O2P/c1-16-14-17(2)21(18(3)15-16)22(23)25(24,19-10-6-4-7-11-19)20-12-8-5-9-13-20/h4-15H,1-3H3
InChIKey: VFHVQBAGLAREND-UHFFFAOYSA-N
Hazard Codes: Xn
The Risk Statements information: 22
22: Harmful if swallowed
The Safety Statements information: 22-24/25
22: Harmful if swallowed
24/25: Avoid contact with skin and eyes
WGK Germany:2
2,4,6-Trimethylbenzoyldiphenylphosphine Oxide , its cas register number is 75980-60-8. It also can be called Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide . Its classification code is TSCA Flag P [A commenced PMN (Premanufacture Notice) substance].
About|Contact|Cas|Product Name|Molecular|Country|Encyclopedia
Message|New Cas|MSDS|Service|Advertisement|CAS DataBase|Article Data|Manufacturers | Chemical Catalog
©2008 LookChem.com,License: ICP
NO.:Zhejiang16009103
complaints:service@lookchem.com Desktop View