• Name

  GERMANIUM DICHLORIDE-DIOXANE COMPLEX

• EINECS
• CAS No. 10060-11-4
• Article Data4
• CAS DataBase
• Density g/cm³
• Solubility decomposes in H2O; soluble ether, benzene; insolublealcohol and chloroform [HAW93] [MER06]
• Melting Point 110-165°C (dec.)
• Formula Cl2Ge
• Boiling Point °Cat760mmHg
• Molecular Weight 143.496
• Flash Point °C
• Transport Information
• Appearance
• Safety

  Risk Statements	34
  Safety Statements	26-36/37/39
  RIDADR	1759
  TSCA	No
  HazardClass	8
  PackingGroup	III

• Risk Codes 34
• Molecular Structure
• Hazard Symbols
• Synonyms Dichlorogermylene;Germanium dichloride; Germanium(2+) chloride
• PSA 18.46000
• LogP 1.25640

Synthetic route

623-73-4

diazoacetic acid ethyl ester

1188-14-3

Triethylgerman

10038-98-9

germaniumtetrachloride

100-58-3

phenylmagnesium bromide

A

10060-11-4

germanium dichloride

B

2817-41-6

triethyl(phenyl)germane

C

1048-05-1

tetraphenylgermane

Conditions

Conditions	Yield
In pentane byproducts: N2; 1 equiv of diazoester adding to a soln. of equimolar mixt. of Ge derivs., allowing to stand for 48 h at 20°C, orange-red oil decanting, PhMgBr adding to a supernatant; identified as adduct with ClCH2OMe;	A 57% B n/a C n/a

...Expand

7440-56-4

germanium

7790-99-0

Iodine monochloride

A

21110-21-4

germanium monochloride

B

10060-11-4

germanium dichloride

Conditions

Conditions	Yield
In gas Kinetics; metals were vaporized in a high temperature beam and the vapor were collimated upon entering a separatly pumped chamber filled with halogen; chemiluminescence spectroscopy;

...Expand

germanium(II) sulfide

lead(II) chloride

10060-11-4

germanium dichloride

Conditions

Conditions	Yield
excess of GeS;

7440-56-4

germanium

10038-98-9

germaniumtetrachloride

10060-11-4

germanium dichloride

Conditions

Conditions	Yield
350-400°C;

13465-77-5

hexachlorodisilane

10038-98-9

germaniumtetrachloride

10060-11-4

germanium dichloride

Conditions

Conditions	Yield
In neat (no solvent, gas phase) at 550°C; detn. by chemical trapping;

1184-65-2

germanium hydride trichloride

10060-11-4

germanium dichloride

Conditions

Conditions	Yield
byproducts: HCl; thermal decompn.;