Product Name

Stability

    Stable. Incompatible with strong oxidizing agents.

Toxicology

    Harmful if swallowed, inhaled or absorbed through the skin.Lachrymator. Skin, eye and respiratory irritant. Repeated skin contactmay
  • Melting Point -73°C
  • Formula C3Cl6
  • Boiling Point 209-210 °C(lit.)
  • Molecular Weight 248.751
  • Flash Point 209-210°C
  • Transport Information
  • Appearance colourless liquid
  • Safety A poison by inhalation and intraperitoneal routes. A powerful irritant. Mutation data reported. When heated to decomposition it emits toxic fumes of Cl−. See also CHLORINATED HYDROCARBONS, ALIPHATIC.
  • Risk Codes R23; R36/37/38
  • Molecular Structure Molecular Structure of 1888-71-7 (1,1,2,3,3,3-hexachloro-1-propene)
  • Hazard Symbols T
  • Synonyms Propene,hexachloro- (6CI,7CI,8CI); 1,1,1,2,3,3-Hexachloropropene; Hexachloro-1-propene;Hexachloropropene; Hexachloropropylene; NSC 7297; Perchloropropene;Perchloropropylene
  • PSA 0.00000
  • LogP 4.24210

Synthetic route

1,1,1,2,2,3,3-heptachloropropane
594-89-8

1,1,1,2,2,3,3-heptachloropropane

perchloropropene
1888-71-7

perchloropropene

Conditions
ConditionsYield
With methyl diethylphosphinate at 180℃; for 14.5h;56%
With potassium hydroxide
at 250 - 420℃;
trichloro(heptachloropropyl)silane
131367-96-9

trichloro(heptachloropropyl)silane

perchloropropene
1888-71-7

perchloropropene

Conditions
ConditionsYield
With aluminium trichloride at 160 - 180℃;52%
pentachloro-2-(trimethylsiloxy)propene
87651-34-1

pentachloro-2-(trimethylsiloxy)propene

A

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

B

pentachloroacetone
1768-31-6

pentachloroacetone

C

perchloropropene
1888-71-7

perchloropropene

Conditions
ConditionsYield
With phosphorus pentachloride at 150℃; for 15h; Yields of byproduct given;A 52%
B n/a
C n/a
With phosphorus pentachloride at 150℃; for 15h; Yield given. Title compound not separated from byproducts;A 52%
B n/a
C n/a
...Expand
chloroform
67-66-3

chloroform

perchloropropene
1888-71-7

perchloropropene

Conditions
ConditionsYield
With hydrogen
1,1,1,2,3,3,3-heptachloropropane
3849-33-0

1,1,1,2,3,3,3-heptachloropropane

perchloropropene
1888-71-7

perchloropropene

Conditions
ConditionsYield
at 350℃;
2-fluoropentachloropropylene
815-15-6

2-fluoropentachloropropylene

perchloropropene
1888-71-7

perchloropropene

Conditions
ConditionsYield
With aluminium trichloride
heptachloro-butyraldehyde
25290-40-8

heptachloro-butyraldehyde

perchloropropene
1888-71-7

perchloropropene

Conditions
ConditionsYield
With sodium ethanolate
pentaerythrityl tetrachloride
3228-99-7

pentaerythrityl tetrachloride

perchloropropene
1888-71-7

perchloropropene

Conditions
ConditionsYield
With chlorine at 200℃; Irradiation;
octachloropropane
594-90-1

octachloropropane

perchloropropene
1888-71-7

perchloropropene

Conditions
ConditionsYield
With sodium hydroxide; N-benzyl-N,N,N-triethylammonium chloride In chloroform
perchloroallene
18608-30-5

perchloroallene

perchloropropene
1888-71-7

perchloropropene

Conditions
ConditionsYield
With chlorine In dichloromethane
heptachlorobutyryl chloride
22414-28-4

heptachlorobutyryl chloride

perchloropropene
1888-71-7

perchloropropene

Conditions
ConditionsYield
In N,N-dimethyl-formamide
propene
187737-37-7

propene

A

1,1,1,3,3-pentachloropropene
6262-54-0

1,1,1,3,3-pentachloropropene

B

1,1-dichloropropene
563-58-6

1,1-dichloropropene

C

3,3-dichloroallyl chloride
2567-14-8

3,3-dichloroallyl chloride

D

perchloropropene
1888-71-7

perchloropropene

E

1,1,3,3-tetrachloro-1-propene
18611-43-3

1,1,3,3-tetrachloro-1-propene

F

propenyl chloride
590-21-6

propenyl chloride

Conditions
ConditionsYield
With hydrogenchloride; oxygen; CuCl2 on calcined alumina at 490℃; Product distribution; several conditions investigated;
...Expand
1,1,1,2,2,3,3-heptachloropropane
594-89-8

1,1,1,2,2,3,3-heptachloropropane

alcoholic KOH-solution

alcoholic KOH-solution

perchloropropene
1888-71-7

perchloropropene

1,1,1,2,3,3,3-heptachloropropane
3849-33-0

1,1,1,2,3,3,3-heptachloropropane

alcoholic potash

alcoholic potash

perchloropropene
1888-71-7

perchloropropene

asymm. heptachloropropane

asymm. heptachloropropane

perchloropropene
1888-71-7

perchloropropene

Conditions
ConditionsYield
With potassium hydroxide
With pyridine
With -base of crystal violet
pyridine
110-86-1

pyridine

1,1,1,2,2,3,3-heptachloropropane
594-89-8

1,1,1,2,2,3,3-heptachloropropane

A

hydrogenchloride
7647-01-0

hydrogenchloride

B

perchloropropene
1888-71-7

perchloropropene

...Expand
1,1,1,2,2,3,3-heptachloropropane
594-89-8

1,1,1,2,2,3,3-heptachloropropane

alkali

alkali

A

hydrogenchloride
7647-01-0

hydrogenchloride

B

perchloropropene
1888-71-7

perchloropropene

...Expand
1,1,2,3-tetrachloro-3,3-difluoropropene
431-50-5

1,1,2,3-tetrachloro-3,3-difluoropropene

antimonypentachloride
7647-18-9

antimonypentachloride

A

1,1,2-trichloro-3,3,3-trifluoropropene
431-52-7

1,1,2-trichloro-3,3,3-trifluoropropene

B

1,1,2,3,3-pentachloro-3-fluoropropene
815-14-5

1,1,2,3,3-pentachloro-3-fluoropropene

C

perchloropropene
1888-71-7

perchloropropene

...Expand
1,1,1,2,2,3,3-heptachloropropane
594-89-8

1,1,1,2,2,3,3-heptachloropropane

-base of crystal violet

-base of crystal violet

A

perchloropropene
1888-71-7

perchloropropene

B

crystal violet
548-62-9

crystal violet

...Expand
1,1,2,3,3,4,4,5,6,6-decachloro-hexa-1,5-diene
29030-84-0

1,1,2,3,3,4,4,5,6,6-decachloro-hexa-1,5-diene

A

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

B

perchloropropene
1888-71-7

perchloropropene

C

octachloro-1-methylene-cyclopentene-(3)

octachloro-1-methylene-cyclopentene-(3)

Conditions
ConditionsYield
at 200 - 210℃;
...Expand
heptachloro-butyraldehyde
25290-40-8

heptachloro-butyraldehyde

sodium ethanolate
141-52-6

sodium ethanolate

A

perchloropropene
1888-71-7

perchloropropene

B

sodium formate
141-53-7

sodium formate

C

sodium chloride

sodium chloride

...Expand
diethyl ether
60-29-7

diethyl ether

octachloropropane
594-90-1

octachloropropane

aluminium

aluminium

A

perchloropropene
1888-71-7

perchloropropene

B

solid octachlorohexatriene

solid octachlorohexatriene

C

liquid octachlorohexatriene

liquid octachlorohexatriene

D

octachloro-1-methylene-cyclopentene of mp: 183 degree

octachloro-1-methylene-cyclopentene of mp: 183 degree

Conditions
ConditionsYield
Produkt 5:Perchlorfulven;
...Expand
1,1,1,3,3,3-hexachloropropane
3607-78-1

1,1,1,3,3,3-hexachloropropane

A

1-chloro-1,1,3,3,3-pentafluoropropane
460-92-4

1-chloro-1,1,3,3,3-pentafluoropropane

B

2H-pentafluoropropene
690-27-7

2H-pentafluoropropene

C

1,1,1,3,3,3-hexafluoropropane
690-39-1

1,1,1,3,3,3-hexafluoropropane

D

perchloropropene
1888-71-7

perchloropropene

Conditions
ConditionsYield
With hydrogen fluoride; chlorine; antimonypentachloride at 80 - 95℃; under 8517.48 - 10069 Torr;
With hydrogen fluoride; chromium(III) oxide at 300℃;
...Expand
1,1,1,2,2,3,3-heptachloropropane
594-89-8

1,1,1,2,2,3,3-heptachloropropane

tetrabutyl-ammonium chloride
1112-67-0

tetrabutyl-ammonium chloride

perchloropropene
1888-71-7

perchloropropene

Conditions
ConditionsYield
With potassium hydroxide237 g (95%)
1,1,1,2,2,3,3-heptachloropropane
594-89-8

1,1,1,2,2,3,3-heptachloropropane

tetra-n-butylphosphonium chloride
2304-30-5

tetra-n-butylphosphonium chloride

perchloropropene
1888-71-7

perchloropropene

Conditions
ConditionsYield
With potassium hydroxide239 g (96%)
tricaprylylmethyl ammoniumchloride

tricaprylylmethyl ammoniumchloride

1,1,1,2,2,3,3-heptachloropropane
594-89-8

1,1,1,2,2,3,3-heptachloropropane

perchloropropene
1888-71-7

perchloropropene

Conditions
ConditionsYield
With potassium hydroxide237 g (95%)
tetrachloromethane
56-23-5

tetrachloromethane

A

Hexachlorobutadiene
87-68-3

Hexachlorobutadiene

B

perchloropropene
1888-71-7

perchloropropene

C

hexachlorobenzene
118-74-1

hexachlorobenzene

Conditions
ConditionsYield
With silica gel In neat (no solvent) byproducts: SiCl4, COCl2; decomposition of streaming CCl4 with high-frequency discharge in a quartz tube; condensation of the reaction mixture at -190°C; mechanism discussed; further products;; determination by IR and MS;;
...Expand
uranyl nirate hexahydrate

uranyl nirate hexahydrate

perchloropropene
1888-71-7

perchloropropene

uranium(IV) chloride
10026-10-5

uranium(IV) chloride

Conditions
ConditionsYield
Inert atmosphere; Reflux;100%
perchloropropene
1888-71-7

perchloropropene

uranium(VI) trioxide

uranium(VI) trioxide

uranium(IV) chloride
10026-10-5

uranium(IV) chloride

Conditions
ConditionsYield
at 190℃; for 18h; Schlenk technique; Inert atmosphere;98%
In neat (no solvent) refluxing; sublimation (vac.);
In neat (no solvent) absence of air and moisture; refluxing;
uranium(IV) oxide dihydrate

uranium(IV) oxide dihydrate

uranium(VI) oxide dihydrate

uranium(VI) oxide dihydrate

perchloropropene
1888-71-7

perchloropropene

uranium(IV) chloride
10026-10-5

uranium(IV) chloride

Conditions
ConditionsYield
In further solvent(s) (N2); standard Schlenk technique; UO2*2H2O was added to hexachloropropene at 190°C; heated at 190°C; UO3*2H2O was carefully added;mixt. was heated at 190°C overnight; cooled to room temp.; filtered; washed (CH2Cl2); dried (vac.);98%
...Expand
perchloropropene
1888-71-7

perchloropropene

A

2,3,3-trichloroacryloyl chloride
815-58-7

2,3,3-trichloroacryloyl chloride

B

thionyl chloride (84percent)

thionyl chloride (84percent)

Conditions
ConditionsYield
With aluminium trichloride; sulfur dioxide at 90℃; for 48h;A 85%
B n/a
3-(3-pyridyl)propan-1-ol
2859-67-8

3-(3-pyridyl)propan-1-ol

2,3,3-trichloroacryloyl chloride
815-58-7

2,3,3-trichloroacryloyl chloride

perchloropropene
1888-71-7

perchloropropene

3-(3-Pyridyl)-1-propyl-2',3',3'-trichloroacrylate
103146-15-2

3-(3-Pyridyl)-1-propyl-2',3',3'-trichloroacrylate

Conditions
ConditionsYield
With pyridine; iron(III) chloride82%
...Expand
perchloropropene
1888-71-7

perchloropropene

A

1,1,2-trichloro-3,3,3-trifluoropropene
431-52-7

1,1,2-trichloro-3,3,3-trifluoropropene

B

1,1,2,3-tetrachloro-3,3-difluoropropene
431-50-5

1,1,2,3-tetrachloro-3,3-difluoropropene

C

1,1,2,3,3-pentachloro-3-fluoropropene
815-14-5

1,1,2,3,3-pentachloro-3-fluoropropene

Conditions
ConditionsYield
With antimony(III) fluoride at 170℃;A 74.2%
B n/a
C n/a
With antimony(III) fluoride at 170℃;
...Expand
perchloropropene
1888-71-7

perchloropropene

2,3,4,5,6-pentafluoroaniline
771-60-8

2,3,4,5,6-pentafluoroaniline

1,1,2,3-tetrachloro-4-(pentafluorophenyl)-4-aza-1,3-butadiene
119771-89-0

1,1,2,3-tetrachloro-4-(pentafluorophenyl)-4-aza-1,3-butadiene

Conditions
ConditionsYield
With aluminium trichloride In fluorobenzene at 70 - 80℃; for 6h;73%
perchloropropene
1888-71-7

perchloropropene

3,4,5-trichlor-1,2-dithiolylium chloride

3,4,5-trichlor-1,2-dithiolylium chloride

Conditions
ConditionsYield
With sulfur at 170℃; for 24h;70%
methyl thiocyanate
556-64-9

methyl thiocyanate

perchloropropene
1888-71-7

perchloropropene

1,3,4,5,5-pentachloro-1-methylthio-2-azonia-1,2,4-pentatriene hexachloroantimonate

1,3,4,5,5-pentachloro-1-methylthio-2-azonia-1,2,4-pentatriene hexachloroantimonate

Conditions
ConditionsYield
With antimonypentachloride In 1,2-dichloro-ethane for 0.166667h; Heating;66%
perchloropropene
1888-71-7

perchloropropene

methyl isocyanate
624-83-9

methyl isocyanate

2,2-dichloro-5,6-dihydro-3,5-dimethyl-4-(trichlorovinyl)-6-oxo-2H-1,3,5-oxadiazinium hexachloroantimonate

2,2-dichloro-5,6-dihydro-3,5-dimethyl-4-(trichlorovinyl)-6-oxo-2H-1,3,5-oxadiazinium hexachloroantimonate

Conditions
ConditionsYield
With antimonypentachloride In dichloromethane 1.) -30 deg C, 30 min, 2.) 23 deg C, 4 h;63%
perchloropropene
1888-71-7

perchloropropene

p-Tolylisocyanate
622-58-2

p-Tolylisocyanate

1-(chlorocarbonyl)-2,3,4-trichloro-6-methylquinolinium hexachloroantimonate

1-(chlorocarbonyl)-2,3,4-trichloro-6-methylquinolinium hexachloroantimonate

Conditions
ConditionsYield
In dichloromethane 1.) -40 deg C, 30 min, 2.) 23 deg C, 4 h;61%
2-propyl thiocyanate
625-59-2

2-propyl thiocyanate

perchloropropene
1888-71-7

perchloropropene

2,4,5,6-tetrachloro-1,3-thiazinium hexachloroantimonate

2,4,5,6-tetrachloro-1,3-thiazinium hexachloroantimonate

Conditions
ConditionsYield
With antimonypentachloride In 1,2-dichloro-ethane for 0.0833333h; Heating;57%
uranium oxide

uranium oxide

perchloropropene
1888-71-7

perchloropropene

uranium(IV) chloride
10026-10-5

uranium(IV) chloride

Conditions
ConditionsYield
Inert atmosphere;55%
hexyl-sulfinyl-amine
66838-82-2

hexyl-sulfinyl-amine

perchloropropene
1888-71-7

perchloropropene

N-hexyl-2,3,3-trichloro-2-propenamide

N-hexyl-2,3,3-trichloro-2-propenamide

Conditions
ConditionsYield
With antimonypentachloride In dichloromethane 1.) -40 deg C, 10 min; 2.) 23 deg C, 1 h;49%
perchloropropene
1888-71-7

perchloropropene

1,2-dichloro-benzene
95-50-1

1,2-dichloro-benzene

hexachloroindene

hexachloroindene

Conditions
ConditionsYield
With iron(III) chloride In 1,1,2,2-tetrachloroethylene48.7%
perchloropropene
1888-71-7

perchloropropene

ethyl isocyanate
109-90-0

ethyl isocyanate

2,2-dichloro-3,5-diethyl-5,6-dihydro-4-(trichlorovinyl)-6-oxo-2H-1,3,5-oxadiazinium hexachloroantimonate

2,2-dichloro-3,5-diethyl-5,6-dihydro-4-(trichlorovinyl)-6-oxo-2H-1,3,5-oxadiazinium hexachloroantimonate

Conditions
ConditionsYield
With antimonypentachloride In dichloromethane 1.) -30 deg C, 30 min, 2.) 23 deg C, 4 h;48%
perchloropropene
1888-71-7

perchloropropene

1,4-dichloropermethyltetrasilane
754-75-6

1,4-dichloropermethyltetrasilane

hexadecamethyl-2,3,4,5,6,7,8,9,10-octasilabicyclo<4.4.1>undeca-1(11),6(11)-diene
146574-31-4

hexadecamethyl-2,3,4,5,6,7,8,9,10-octasilabicyclo<4.4.1>undeca-1(11),6(11)-diene

Conditions
ConditionsYield
With magnesium In tetrahydrofuran at 50℃; for 4h;34%
1,3-dichloro-1,1,2,2,3,3-hexamethyltrisilane
812-36-2

1,3-dichloro-1,1,2,2,3,3-hexamethyltrisilane

perchloropropene
1888-71-7

perchloropropene

C18H36Cl2Si6

C18H36Cl2Si6

Conditions
ConditionsYield
With magnesium In tetrahydrofuran at 50℃; for 4h;16%
cis-1,2-Dichloroethylene
156-59-2

cis-1,2-Dichloroethylene

perchloropropene
1888-71-7

perchloropropene

3H-heptachloro-cyclopentene
858423-01-5

3H-heptachloro-cyclopentene

Conditions
ConditionsYield
With aluminium trichloride; dichloromethane at 13 - 15℃;
cis-1,2-Dichloroethylene
156-59-2

cis-1,2-Dichloroethylene

perchloropropene
1888-71-7

perchloropropene

hexachlorocyclopentadiene
77-47-4

hexachlorocyclopentadiene

Conditions
ConditionsYield
With aluminium trichloride; dichloromethane at 9℃; anschliessendes Erhitzen auf Siedetemperatur;
4-Chloro-3-methylphenol
59-50-7

4-Chloro-3-methylphenol

perchloropropene
1888-71-7

perchloropropene

3,4,6-trichloro-7-methyl-coumarin
71706-65-5

3,4,6-trichloro-7-methyl-coumarin

Conditions
ConditionsYield
With carbon disulfide; aluminium trichloride anschliessend Behandeln mit wss. Schwefelsaeure;
p-cresol
106-44-5

p-cresol

perchloropropene
1888-71-7

perchloropropene

3,4-dichloro-6-methyl-2H-chromen-2-one
15736-24-0

3,4-dichloro-6-methyl-2H-chromen-2-one

Conditions
ConditionsYield
With carbon disulfide; aluminium trichloride anschliessend Behandeln mit wss. Schwefelsaeure;
Stage #1: p-cresol; perchloropropene With aluminum (III) chloride In carbon disulfide
Stage #2: With sulfuric acid; water
3-monochlorophenol
108-43-0

3-monochlorophenol

perchloropropene
1888-71-7

perchloropropene

3,4,7-trichloro-coumarin
99846-75-0

3,4,7-trichloro-coumarin

4-bromo-phenol
106-41-2

4-bromo-phenol

perchloropropene
1888-71-7

perchloropropene

6-bromo-3,4-dichloro-2H-chromen-2-one
63795-99-3

6-bromo-3,4-dichloro-2H-chromen-2-one

Chlorodifluoromethane
75-45-6

Chlorodifluoromethane

perchloropropene
1888-71-7

perchloropropene

1,1,2-trichloro-3,3,3-trifluoropropene
431-52-7

1,1,2-trichloro-3,3,3-trifluoropropene

Conditions
ConditionsYield
With aluminium trichloride at 150℃; dann auf 200grad;
Chlorodifluoromethane
75-45-6

Chlorodifluoromethane

perchloropropene
1888-71-7

perchloropropene

1,1,2,3-tetrachloro-3,3-difluoropropene
431-50-5

1,1,2,3-tetrachloro-3,3-difluoropropene

Conditions
ConditionsYield
With aluminium trichloride at 100℃;

Hexachloropropene Chemical Properties

IUPAC Name: 1,1,2,3,3,3-Hexachloroprop-1-ene 
Molecular Formula: C3Cl6
Molecular Weight: 248.73g/mol
EINECS: 217-560-9
Transport information: UN 3382 6.1/PG 1
Properties colourless liquid
Density: 1.781 g/cm3 
Flash Point: 69.9 °C 
Boiling Point: 209.5 °C at 760 mmHg
Freely Rotating Bonds: 0
Polar Surface Area: 0 Å2
Index of Refraction: 1.554
Molar Refractivity: 44.75 cm3
Molar Volume: 139.6 cm3
Polarizability: 17.74 ×10-24 cm3
Surface Tension: 42.6 dyne/cm
Enthalpy of Vaporization: 42.76 kJ/mol
Vapour Pressure: 0.292 mmHg at 25°C 
Stability: stable,incompatible with strong oxidizing agents. 
Solubility: insoluble in water
The Cas Register Number of Hexachloropropene is 1888-71-7.The chemical synonyms of Hexachloropropene (CAS NO.1888-71-7) are 1,1,1,2,3,3-Hexachloropropene ; 1,1,2,3,3,3-Hexachloro-1-propen ; 1,1,2,3,3,3-Hexachloro-1-propene ; 1,1,2,3,3-Hexachloro-1-propene ; 1-Propene, hexachloro- ; 1-Propene,1,1,2,3,3,3-hexachloro ; 1-Propene,1,1,2,3,3,3-hexachloro- ; Hexachloro-1-propene .The molecular structure of Hexachloropropene (CAS NO.1888-71-7) is.

Hexachloropropene Uses

 Hexachloropropene (CAS NO.1888-71-7) is used as  plasticizer and hydraulic fluid .And it also is used in organic synthesis.

Hexachloropropene Production

Its raw materials are Potassium ethylate and 1,1,1,2,2,3,3-Heptachloropropane .

Hexachloropropene Toxicity Data With Reference

1.    

mmo-sat 15 µmol/L

     MUREAV    Mutation Research. 170 (1986),1.
2.    

ihl-rat LC50:425 ppm/30M

     XEURAQ    U.S. Atomic Energy Commission, University of Rochester, Research and Development Reports. (Rochester, NY) MDDC-1715 .
3.    

ipr-rat LD50:400 mg/kg

     XEURAQ    U.S. Atomic Energy Commission, University of Rochester, Research and Development Reports. (Rochester, NY) MDDC-1715 .
4.    

ihl-mus LCLo:300 ppm/30M

     XEURAQ    U.S. Atomic Energy Commission, University of Rochester, Research and Development Reports. (Rochester, NY) MDDC-1715 .
5.    

ipr-mus LDLo:64 mg/kg

     CBCCT*    “Summary Tables of Biological Tests“ National Research Council Chemical-Biological Coordination Center. 1 (1949),46.
6.    

ihl-rbt LCLo:85 ppm/30M

     XEURAQ    U.S. Atomic Energy Commission, University of Rochester, Research and Development Reports. (Rochester, NY) MDDC-1715 .

Hexachloropropene Consensus Reports

Reported in EPA TSCA Inventory.

Hexachloropropene Safety Profile

A poison by inhalation and intraperitoneal routes. A powerful irritant. Mutation data reported. When heated to decomposition it emits toxic fumes of Cl−. See also CHLORINATED HYDROCARBONS, ALIPHATIC.
Hazard Codes: ToxicT
Risk Statements: 23-36/37/38 
R23: Toxic by inhalation. 
R36/37/38: Irritating to eyes, respiratory system and skin.
Safety Statements: 26-36/37/39-45 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection. 
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)

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