CAS No.7647-18-9,ANTIMONY(V) CHLORIDE Suppliers,MSDS download

: 25362-97-4
SbCl5*SO3

A: 7791-27-7
pyrosulfuryl chloride

B: 2SbCl4(1+)*SO4(2-)=(SbCl4)2SO4

C: 7647-18-9
antimonypentachloride

D: 7446-11-9
sulfur trioxide

Conditions

Conditions	Yield
70°C in vac.;	A n/a B n/a C n/a D 95%

...Expand

: 10025-91-9
antimony(III) chloride

: 2696-92-6
nitrosylchloride

: 7647-18-9
antimonypentachloride

Conditions

Conditions	Yield
In melt Reaction of SbCl3 melt with NOCl to give SbCl5;	80%
With chlorine In melt Reaction of SbCl3 melt with a mixt. of NOCl and Cl2 to give SbCl5;

: silver(I) fluoride

A: 13709-35-8
disulfur difluoride

B: 7647-18-9
antimonypentachloride

Conditions

Conditions	Yield
With sulfur with melted Ag2F2 at 500°C; gaseous S2F2 formed;	A 48.9% B n/a
With sulfur with melted Ag2F2 at 600°C; gaseous S2F2 formed;	A 40.6% B n/a
With sulfur with melted Ag2F2 at 140-400°C; gaseous S2F2 formed;	A 65-67 B n/a
With sulfur with melted Ag2F2; geseous S2F2 formed;
With S with melted Ag2F2; geseous S2F2 formed;

: 7440-36-0
antimony

A: 7647-18-9
antimonypentachloride

B: 10025-91-9
antimony(III) chloride

Conditions

Conditions	Yield
With chlorine with dry Cl2; refluxing over Sb; distn.;
With hydrogenchloride; dihydrogen peroxide In not given powdered Sb reacts with HCl soln. containing H2O2;
With Cl2 with dry Cl2; refluxing over Sb; distn.;
In not given

: 7440-36-0
antimony

: 7647-18-9
antimonypentachloride

Conditions

Conditions	Yield
With chlorine heating; distillation;
With chlorine moderatly heating with dry Cl2; fire phonomenon;
With Cl2 heating; distillation;

: 7440-36-0
antimony

A: antimony(III) sulfide

B: 7647-18-9
antimonypentachloride

Conditions

Conditions	Yield
With thionyl chloride byproducts: SO2, S2Cl2; SbCl3 and Sb2O3 formed in cold with excess of pwdered Sb; Sbl5 formed wth excess of SOCl2 in a sealed tube;

: 7440-36-0
antimony

: 7791-23-3
selenium oxychloride

A: 7647-18-9
antimonypentachloride

B: 10025-91-9
antimony(III) chloride

C: 10025-68-0
diselenium dichloride

Conditions

Conditions	Yield
with excess of SeOCl2;	A 0% B n/a C n/a

...Expand

: 7440-36-0
antimony

: 7722-84-1
dihydrogen peroxide

A: 7647-18-9
antimonypentachloride

B: 10025-91-9
antimony(III) chloride

Conditions

Conditions	Yield
With hydrogenchloride In water
With HCl In water

...Expand

: 7783-70-2
antimony pentafluoride

: 10241-05-1
molybdenum(V) chloride

: 7647-18-9
antimonypentachloride

Conditions

Conditions	Yield
over 100 °C; molibdenum fluoride forming as by-product;
over 100 °C; molibdenum fluoride forming as by-product;

: 10025-91-9
antimony(III) chloride

A: 7440-36-0
antimony

B: antimonic acid

C: 7647-18-9
antimonypentachloride

Conditions

Conditions	Yield
With nitric acid In hydrogenchloride	A 0% B n/a C n/a
In hydrogenchloride

...Expand

: 10025-91-9
antimony(III) chloride

: 7647-18-9
antimonypentachloride

Conditions

Conditions	Yield
With chlorine In melt Reaction of SbCl3 melt with Cl2 to give SbCl5;	93-94
With chlorine distillation;
With chlorine with molten SbCl3; distillation;

: 10025-91-9
antimony(III) chloride

: 10102-44-0
Nitrogen dioxide

: 7647-18-9
antimonypentachloride

Conditions

Conditions	Yield
In melt Reaction of SbCl3 melt with NO2 to give SbCl5;

: 7647-01-0
hydrogenchloride

: potassium antimony(III) tartrate

A: 7647-18-9
antimonypentachloride

B: 147-78-4, 868-14-4, 921-53-9, 2690-13-3, 4504-81-8, 4601-94-9, 34004-13-2, 40968-90-9, 57341-16-9, 91269-83-9
potassium bitartrate

Conditions

Conditions	Yield
In neat (no solvent) stream of HCl; strong evolution of heat;;
In neat (no solvent) stream of HCl; strong evolution of heat;;

...Expand

: diantimony tetraoxide

: 7782-50-5
chlorine

A: antimony pentoxide

B: 7647-18-9
antimonypentachloride

C: 10025-91-9
antimony(III) chloride

Conditions

Conditions	Yield
In neat (no solvent) Kinetics; react. at 200°C;

...Expand

: native antimony

A: 7647-18-9
antimonypentachloride

B: 10025-91-9
antimony(III) chloride

Conditions

Conditions	Yield
With aqua regia
With aqua regia

: antimony(III) trioxide

A: 75-44-5
phosgene

B: 7647-18-9
antimonypentachloride

Conditions

Conditions	Yield
With chlorine In tetrachloromethane heating Sb2O3 with a soln. of Cl2 in CCl4 in a sealed tube at 100°C;;
With tetrachloromethane; chlorine at 100°C in sealed tube;
With Cl2 In tetrachloromethane heating Sb2O3 with a soln. of Cl2 in CCl4 in a sealed tube at 100°C;;
With Cl2; CCl4 at 100°C in sealed tube;

: antimony(III) trioxide

A: 10025-67-9
disulfur dichloride

B: 7647-18-9
antimonypentachloride

Conditions

Conditions	Yield
With thionyl chloride byproducts: SO2; with large excess of SOCl2;
With SOCl2 byproducts: SO2; with large excess of SOCl2;

: antimony(III) trioxide

A: cervantite

B: 7647-18-9
antimonypentachloride

C: 10025-91-9
antimony(III) chloride

Conditions

Conditions	Yield
With chlorine by heating;
With Cl2 by heating;

...Expand

: antimony(III) sulfide

: 7647-18-9
antimonypentachloride

Conditions

Conditions	Yield
With chlorine	0%
With Cl2	0%

: 7440-36-0
antimony

: 7782-49-2
selenium

A: SbCl5*SeCl4

B: 7647-18-9
antimonypentachloride

Conditions

Conditions	Yield
With chlorine dry Cl2; remowing SbCl5 over H2SO4;
With Cl2 dry Cl2; remowing SbCl5 over H2SO4;

...Expand

: 56-23-5
tetrachloromethane

: antimony pentoxide

: 7647-18-9
antimonypentachloride

Conditions

Conditions	Yield
at 420°C;

: 7791-25-5
sulfuryl dichloride

: antimony(V) sulfide

A: 7647-18-9
antimonypentachloride

B: 7704-34-9
sulfur

Conditions

Conditions	Yield
In neat (no solvent)

...Expand

: 13596-35-5
rhenium(V) chloride

: 10025-91-9
antimony(III) chloride

A: 13569-71-6
rhenium tetrachloride

B: 7647-18-9
antimonypentachloride

Conditions

Conditions	Yield
In neat (no solvent) byproducts: Re3Cl9; distiln. (vac.), sublimation;

...Expand

: antimony(III) sulfate

A: antimony(III) sulfate * 5 HCl

B: 7647-18-9
antimonypentachloride

Conditions

Conditions	Yield
In neat (no solvent) byproducts: SbCl5; passing dry HCl-stream over Sb2(SO4)3 with spontaneous heat evolution (up to melting temp.); cooling;; SbCl5 sublimes;;
In neat (no solvent) byproducts: SbCl5; passing dry HCl-stream over Sb2(SO4)3 with spontaneous heat evolution (up to melting temp.); cooling;; SbCl5 sublimes;;

: SbCl5*2SbF5

: 2696-92-6
nitrosylchloride

A: antimony pentoxide

B: SbF5*NOF

C: 7647-18-9
antimonypentachloride

Conditions

Conditions	Yield
without moisture of air; heating to 100 °C then in vac. (1-3 mmHg) at 180-200 °C (6h); max. purity 90%;
without moisture of air; heating to 100 °C then in vac. (1-3 mmHg) at 180-200 °C (6h); max. purity 90%;

...Expand

: antimony(III) trioxide

: cesium hexachloro-stannate(IV)

A: caesium oxochlorostannate(IV)

B: 7647-18-9
antimonypentachloride

Conditions

Conditions	Yield
Cl2 atm;
Cl2 atm;

...Expand

: 52940-42-8, 44479-97-2, 16918-97-1
SbCl5*H2O

A: 7647-18-9
antimonypentachloride

B: 10025-91-9
antimony(III) chloride

Conditions

Conditions	Yield
heating at 20 Torr;

: Sb3OCl13

A: antimony pentoxide

B: 7647-18-9
antimonypentachloride

C: 10025-91-9
antimony(III) chloride

Conditions

Conditions	Yield
byproducts: Cl2; with heating; SbCl3 and SbCl5 evaporate;

...Expand

: 17455-13-9
18-crown-6 ether

: 7647-18-9
antimonypentachloride

: lead(II) chloride

: {Pb(O6(CH2)12)(CH3CN)3}(2+)*2(SbCl6)(1-)={Pb(O6(CH2)12)(CH3CN)3}{SbCl6}2

Conditions

Conditions	Yield
In acetonitrile PbCl2 is dissolved by injection of SbCl5 in MeCN, addn. of 18-crown-6; concn. the volume under vac., standing for some time at 20°C, filtn., elem. anal.;	100%

...Expand

: 7791-25-5
sulfuryl dichloride

: 7647-18-9
antimonypentachloride

: tris[2-(2-pyridyl)phenyl]stibine

: C33H24N3Sb(2+)*2Cl6Sb(1-)

Conditions

Conditions	Yield
Stage #1: sulfuryl dichloride; tris[2-(2-pyridyl)phenyl]stibine In acetonitrile at -40℃; for 2h; Inert atmosphere; Stage #2: antimonypentachloride In dichloromethane at -40℃; for 2h; Inert atmosphere;	100%

...Expand

: 7647-01-0
hydrogenchloride

: 7647-18-9
antimonypentachloride

: 7732-18-5
water

: 53890-32-7
H2O*H(1+)*SbCl6(1-)=H2O*HSbCl6

Conditions

Conditions	Yield
In dichloromethane (He atm.) the calculated volumes of CH2Cl2-solns. of SbCl5, H2O and HCl were mixed;	99%

...Expand

: 7647-01-0
hydrogenchloride

: 7647-18-9
antimonypentachloride

: 7732-18-5
water

: H(1+)*SbCl6(1-)*2H2O=HSbCl6*2H2O

Conditions

Conditions	Yield
In dichloromethane (He atm.) the calculated volumes of CH2Cl2-solns. of SbCl5, H2O and HCl were mixed;	99%

...Expand

: 506-68-3
bromocyane

: 7647-18-9
antimonypentachloride

: 22538-96-1, 24273-95-8
SbCl5(BrCN)

Conditions

Conditions	Yield
In dichloromethane under N2, SbCl5 was added to equiv. amt. of BrCN in CH2Cl2 at room temp.; solvent was removed in dynamic vac., elem. anal.;	99%

: 506-78-5
cyanogen iodide

: 7647-18-9
antimonypentachloride

: 359860-18-7
SbCl5(ICN)

Conditions

Conditions	Yield
In dichloromethane under N2, SbCl5 was added to equiv. amt. of ICN in CH2Cl2 at room temp.; solvent was removed in dynamic vac., elem. anal.;	99%

: 420-04-2
CYANAMID

: 7647-18-9
antimonypentachloride

: 359860-20-1
SbCl5NCNH2

Conditions

Conditions	Yield
In dichloromethane under N2, SbCl5 was added to equiv. amt. of H2NCN in CH2Cl2 at room temp.; solvent was removed in dynamic vac., elem. anal.;	99%

: 676-85-7
methylsulphinyl chloride

: 7647-18-9
antimonypentachloride

: 65554-06-5
methyl(chloro)sulfinylantimony pentachloride

Conditions

Conditions	Yield
In dichloromethane addn. of SbCl5 in CH2Cl2 at 243 K with stirring to CH3SOCl in CH2Cl2 within 1.5 h, further stirring (1 h); concn. (dynamic vac.), filtration at 233 K, drying (dynamic vac., 273 K);	99%

: 110-86-1
pyridine

: 7647-18-9
antimonypentachloride

: 24551-32-4
SbCl5(C5H5N)

Conditions

Conditions	Yield
In dichloromethane under N2, SbCl5 was added to equiv. amt. of pyridine in CH2Cl2 at room temp.; solvent was removed in dynamic vac., elem. anal.;	99%

: 7647-18-9
antimonypentachloride

: 75307-82-3
6-Methyl-7-oxo-8-phenyl-1λ3-thionia-3λ4,5λ4-dithia-2,4,6,8,9-pentaazabicyclo<3.3.1>nona-2,3,5(9)-trien-chlorid

: 75307-85-6
6-Methyl-7-oxo-8-phenyl-1λ3-thionia-3λ4,5λ4-dithia-2,4,6,8,9-pentaazabicyclo[3.3.1]nona-2,3,5(9)-trien-chlorid

Conditions

Conditions	Yield
In tetrachloromethane ppt. was recrystd. from CH3CN/CCl4 (1:15); elem. anal.;	99%

: 5400-82-8
N,N-dimethylbenzylamine N-oxide

: 7647-18-9
antimonypentachloride

: 83616-70-0
N,N-dimethylbenzylamine oxide-SbCl5

Conditions

Conditions	Yield
In tetrachloromethane soln. of PhCH2Me2NO in CCl4 added to soln. of SbCl5 in CCl4; filtered, washed with CCl4 and petroleum ether; elem. anal.;	99%

: 7647-18-9
antimonypentachloride

: 67-68-5
dimethyl sulfoxide

: 23058-09-5
((CH3)2SO)SbCl5

Conditions

Conditions	Yield
In tetrachloromethane DMSO and SbCl5 (mole ratio 1:1) were mixed in CCl4 with cooling; the mixt was allowed to stand overnight;; the ppt. was collected by filtration, washed with CCl4, then with petroleum ether; elem. anal.;;	98.7%

: 130256-90-5
4-methylaminopent-3-en-2-one

: 7647-18-9
antimonypentachloride

: SbCl5*CH3COCHC(NHCH3)CH3

Conditions

Conditions	Yield
In chloroform dropwise addn. of SbCl3 soln. to ketoamine soln. with stirring and exclusion of moisture; stirring, 8h; decanting; washing (chloroform); drying (30°C/0.1 mm, 5h); elem. anal.;	98%

: 7647-18-9
antimonypentachloride

: 59487-11-5
N-isopropyl-4-amino-3-penten-2-one

: SbCl5*CH3COCHC(NHCH(CH3)2)CH3

Conditions

Conditions	Yield
In chloroform dropwise addn. of SbCl3 soln. to ketoamine soln. with stirring and exclusion of moisture; stirring, 8h; decanting; washing (chloroform); drying (30°C/0.1 mm, 5h); elem. anal.;	98%

: 7647-18-9
antimonypentachloride

: 72160-17-9
6,8-Dimethyl-7-oxo-1λ3-thionia-3λ4,5λ4-dithia-2,4,6,8,9-pentaazabicyclo<3.3.1>nona-2,3,5(9)-trien-chlorid

: 75307-83-4
6,8-Dimethyl-7-oxo-1λ3-thionia-3λ4,5λ4-dithia-2,4,6,8,9-pentaazabicyclo[3.3.1]nona-2,3,5(9)-trien-hexachloroantimonat

Conditions

Conditions	Yield
In tetrachloromethane ppt. was recrystd. from CH3CN/CCl4 (1:15); elem. anal.;	98%

: 17455-13-9
18-crown-6 ether

: 7647-18-9
antimonypentachloride

: lead(II) chloride

: {Pb(O5(CH2)10)2}(2+)*2(SbCl6)(1-)={Pb(O5(CH2)10)2}{SbCl6}2

Conditions

Conditions	Yield
In acetonitrile PbCl2 is dissolved by injection of SbCl5 in MeCN, addn. of 15-crown-5; concn. the volume under vac., filtn., cooling the filtrate, filtn., washing with MeCN, vac. drying, elem. anal.;	97%

...Expand

: 50967-59-4
4-(ethylamino)penten-2-one

: 7647-18-9
antimonypentachloride

: SbCl5*CH3COCHC(NHC2H5)CH3

Conditions

Conditions	Yield
In chloroform dropwise addn. of SbCl3 soln. to ketoamine soln. with stirring and exclusion of moisture; stirring, 8h; decanting; washing (chloroform); drying (30°C/0.1 mm, 5h); elem. anal.;	97%

: 54434-25-2
Isopropylmethylcyanamide

: 7647-18-9
antimonypentachloride

: 89953-15-1
antimony pentachloride-isopropylmethylcyanamide

Conditions

Conditions	Yield
In dichloromethane addn. dropwise, stirring -78°C for 1 h, then 22°C for 2h,; evapn. in vac., pptn.with pentane, washed with pentane, recrystn. from CH2Cl2, elem.anal.;	97%

: 49677-01-2
N-methyl-N-cyclohexyl cyanamide

: 7647-18-9
antimonypentachloride

: 89953-16-2
antimony pentachloride-cyclohexylmethylcyanamide

Conditions

Conditions	Yield
In dichloromethane addn. dropwise, stirring -78°C for 1 h, then 22°C for 2h,; evapn., in vac., pptn. with pentane, washed with pentane, recrystn. from CH2Cl2, elem.anal.;	97%

: 292638-84-7
styrene

: 59957-75-4
2,2'-dipyridyldiselenide

: 7647-18-9
antimonypentachloride

: bis(3-phenyl-2,3-dihydro[1,3]selenazolo[3,2-a]pyridinium-4) pentachloroantimonate(III)

Conditions

Conditions	Yield
In dichloromethane soln. of SbCl5 in CH2Cl2 added to soln. of Se-compound in CH2Cl2 at -40°C with stirring under Ar, stirred for 15 min at -40°C, CH2Cl2 soln. of styrene added dropwise, stirred for 30 min, warmed to room temp.; solvent evapd. in vacuo, recrystd. from CH2Cl2; elem. anal.;	97%

...Expand

: 75-09-2
dichloromethane

: 7647-18-9
antimonypentachloride

: 7782-50-5
chlorine

: 107-06-2
1,2-dichloro-ethane

: 1663-45-2
1,2-bis-(diphenylphosphino)ethane

: C26H24Cl2P2(2+)*CH2Cl2*2C2H4Cl2*Cl5Sb(2-)

Conditions

Conditions	Yield
Stage #1: chlorine; 1,2-dichloro-ethane; 1,2-bis-(diphenylphosphino)ethane In 1,2-dichloro-ethane at -30℃; for 0.0833333h; Stage #2: dichloromethane; antimonypentachloride In dichloromethane; 1,2-dichloro-ethane at -30 - 23℃; for 1h;	97%

...Expand

: 6628-18-8
1,2-bis(methylthio)ethane

: 7647-18-9
antimonypentachloride

: C4H10ClS2(1+)*Cl6Sb(1-)

Conditions

Conditions	Yield
Stage #1: 1,2-bis(methylthio)ethane With chlorine In 1,2-dichloro-ethane at -30℃; for 0.0833333h; Inert atmosphere; Stage #2: antimonypentachloride In dichloromethane at 23℃; for 1h; Inert atmosphere;	97%

: 7647-18-9
antimonypentachloride

: 6831-82-9
potassium isopropoxide

: KSb(OCHCH3CH3)6

Conditions

Conditions	Yield
In chloroform byproducts: KCl; A soln. of potassium metal in isopropanol is added to an ice cold soln. of SbCl5, refluxed for 4 h under dry N2, cooling.; KCl is filtered off, elem. anal.;	96%

: 7647-18-9
antimonypentachloride

: 2696-92-6
nitrosylchloride

: 16871-80-0
nitrosonium hexachloroantimonate

Conditions

Conditions	Yield
In dichloromethane 0 - 10 °C, under N2; the product was filtered under N2, washed with CH2Cl2, dried in vac. at25 °C, elem. anal.;	96%

: 19227-13-5
p-toluamidoxime

: 7647-18-9
antimonypentachloride

: 132293-63-1
SbCl5N(OH)C(NH2)C6H4CH3

Conditions

Conditions	Yield
In dichloromethane addn. of ligand soln. to soln. of SbCl5, pptn., stirred for 1h; ppt. filtered, washed with CH2Cl2, recrystd. from CHCl3/hexane, dried in vac. at 50°C; elem. anal.;	96%

: 586-77-6
4-bromo-N,N-dimethylaniline

: 7647-18-9
antimonypentachloride

: 4-bromo-N,N-dimethylaniline antimony pentachloride complex

Conditions

Conditions	Yield
In chloroform stirring for 30 min; filtration of ppt., washing with CHCl3, drying, elem. anal.;	96%

: 5395-75-5
1,2-bis(ethylthio)ethane

: 7647-18-9
antimonypentachloride

: C6H14ClS2(1+)*Cl6Sb(1-)

Conditions

Conditions	Yield
Stage #1: 1,2-bis(ethylthio)ethane With chlorine In 1,2-dichloro-ethane at -30℃; for 0.0833333h; Inert atmosphere; Stage #2: antimonypentachloride In dichloromethane at 23℃; for 1h; Inert atmosphere;	96%

: 7647-18-9
antimonypentachloride

: 62-55-5
thioacetamide

: antimony(III) sulfide

Conditions

Conditions	Yield
With HCl In water High Pressure; SbCl5 dissolved in HCl at ambient temp.; H2O added; temp. increased to 50°C; mixed with stoich. amt. of thioacetamide; soln. transferred into stainless-steel autoclave; sealed autoclave maintained at 180°C for 3 h; cooled to room temp.; filtered; washed (soln. of tartaric acid, H2O); dried (vac.) at 60°C for 5 h;	95%

: Se2NCl3

: 7647-18-9
antimonypentachloride

: 151654-58-9, 603109-87-1
{ClSeNSeCl}(1+)*SbCl6(1-)={ClSeNSeCl}SbCl6

Conditions

Conditions	Yield
In sulfur dioxide N2-atmosphere; addn. of 1 equiv. SbCl5 to Se2NCl3 soln., stirring (room temp., 2 h); solvent removal (reduced pressure);	95%

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