Antimony(V) chloride supplier

Name
ANTIMONY(V) CHLORIDE
EINECS 231-601-8
CAS No. 7647-18-9
Article Data92
CAS DataBase
Density 2.36 g/mL at 25oC(lit.)
Solubility decomposes

Stability

Stable, but reacts with moisture and water. Releases highlytoxic fumes if involved in a fire.

Toxicology

Harmful if swallowed or inhaled and in contact with skin.Corrosive - causes seve

Melting Point 2.8 °C(lit.)
Formula Cl5Sb
Boiling Point 92 °C30 mm Hg(lit.)
Molecular Weight 299.015
Flash Point 79°C/22mm
Transport Information
Appearance colourless to light yellow oily liquid
Safety Poison by ingestion. Corrosive. Mutation data reported. See ANTIMONY COMPOUNDS and ANTIMONY(III) CHLORIDE. When heated to decomposition it emits very toxic fumes of Cl⁻ and Sb.
Risk Codes 34-51/53-40-23/24/25-14-62-48/20-63
Molecular Structure
Hazard Symbols Corrosive, fumes in moist air, reacts strongly with organics. TLV: 0.5 mg(Sb)/m³.
Synonyms Antimonypentachloride; Antimony pentachloride (SbCl5); Antimony perchloride;Antimony(V) chloride; Pentachloroantimony
PSA 0.00000
LogP 3.44750

Synthetic route

: 25362-97-4
SbCl5*SO3

A: 7791-27-7
pyrosulfuryl chloride

B: 2SbCl4(1+)*SO4(2-)=(SbCl4)2SO4

C: 7647-18-9
antimonypentachloride

D: 7446-11-9
sulfur trioxide

Conditions

Conditions	Yield
70°C in vac.;	A n/a B n/a C n/a D 95%

...Expand

: 10025-91-9
antimony(III) chloride

: 2696-92-6
nitrosylchloride

: 7647-18-9
antimonypentachloride

Conditions

Conditions	Yield
In melt Reaction of SbCl3 melt with NOCl to give SbCl5;	80%
With chlorine In melt Reaction of SbCl3 melt with a mixt. of NOCl and Cl2 to give SbCl5;

: silver(I) fluoride

A: 13709-35-8
disulfur difluoride

B: 7647-18-9
antimonypentachloride

Conditions

Conditions	Yield
With sulfur with melted Ag2F2 at 500°C; gaseous S2F2 formed;	A 48.9% B n/a
With sulfur with melted Ag2F2 at 600°C; gaseous S2F2 formed;	A 40.6% B n/a
With sulfur with melted Ag2F2 at 140-400°C; gaseous S2F2 formed;	A 65-67 B n/a
With sulfur with melted Ag2F2; geseous S2F2 formed;
With S with melted Ag2F2; geseous S2F2 formed;

: 7440-36-0
antimony

A: 7647-18-9
antimonypentachloride

B: 10025-91-9
antimony(III) chloride

Conditions

Conditions	Yield
With chlorine with dry Cl2; refluxing over Sb; distn.;
With hydrogenchloride; dihydrogen peroxide In not given powdered Sb reacts with HCl soln. containing H2O2;
With Cl2 with dry Cl2; refluxing over Sb; distn.;
In not given

: 7440-36-0
antimony

: 7647-18-9
antimonypentachloride

Conditions

Conditions	Yield
With chlorine heating; distillation;
With chlorine moderatly heating with dry Cl2; fire phonomenon;
With Cl2 heating; distillation;

: 7440-36-0
antimony

A: antimony(III) sulfide

B: 7647-18-9
antimonypentachloride

Conditions

Conditions	Yield
With thionyl chloride byproducts: SO2, S2Cl2; SbCl3 and Sb2O3 formed in cold with excess of pwdered Sb; Sbl5 formed wth excess of SOCl2 in a sealed tube;

: 7440-36-0
antimony

: 7791-23-3
selenium oxychloride

A: 7647-18-9
antimonypentachloride

B: 10025-91-9
antimony(III) chloride

C: 10025-68-0
diselenium dichloride

Conditions

Conditions	Yield
with excess of SeOCl2;	A 0% B n/a C n/a

...Expand

: 7440-36-0
antimony

: 7722-84-1
dihydrogen peroxide

A: 7647-18-9
antimonypentachloride

B: 10025-91-9
antimony(III) chloride

Conditions

Conditions	Yield
With hydrogenchloride In water
With HCl In water

...Expand

: 7783-70-2
antimony pentafluoride

: 10241-05-1
molybdenum(V) chloride

: 7647-18-9
antimonypentachloride

Conditions

Conditions	Yield
over 100 °C; molibdenum fluoride forming as by-product;
over 100 °C; molibdenum fluoride forming as by-product;

: 10025-91-9
antimony(III) chloride

A: 7440-36-0
antimony

B: antimonic acid

C: 7647-18-9
antimonypentachloride

Conditions

Conditions	Yield
With nitric acid In hydrogenchloride	A 0% B n/a C n/a
In hydrogenchloride

...Expand

: 10025-91-9
antimony(III) chloride

: 7647-18-9
antimonypentachloride

Conditions

Conditions	Yield
With chlorine In melt Reaction of SbCl3 melt with Cl2 to give SbCl5;	93-94
With chlorine distillation;
With chlorine with molten SbCl3; distillation;

: 10025-91-9
antimony(III) chloride

: 10102-44-0
Nitrogen dioxide

: 7647-18-9
antimonypentachloride

Conditions

Conditions	Yield
In melt Reaction of SbCl3 melt with NO2 to give SbCl5;

: 7647-01-0
hydrogenchloride

: potassium antimony(III) tartrate

A: 7647-18-9
antimonypentachloride

B: 147-78-4, 868-14-4, 921-53-9, 2690-13-3, 4504-81-8, 4601-94-9, 34004-13-2, 40968-90-9, 57341-16-9, 91269-83-9
potassium bitartrate

Conditions

Conditions	Yield
In neat (no solvent) stream of HCl; strong evolution of heat;;
In neat (no solvent) stream of HCl; strong evolution of heat;;

...Expand

: diantimony tetraoxide

: 7782-50-5
chlorine

A: antimony pentoxide

B: 7647-18-9
antimonypentachloride

C: 10025-91-9
antimony(III) chloride

Conditions

Conditions	Yield
In neat (no solvent) Kinetics; react. at 200°C;

...Expand

: native antimony

A: 7647-18-9
antimonypentachloride

B: 10025-91-9
antimony(III) chloride

Conditions

Conditions	Yield
With aqua regia
With aqua regia

: antimony(III) trioxide

A: 75-44-5
phosgene

B: 7647-18-9
antimonypentachloride

Conditions

Conditions	Yield
With chlorine In tetrachloromethane heating Sb2O3 with a soln. of Cl2 in CCl4 in a sealed tube at 100°C;;
With tetrachloromethane; chlorine at 100°C in sealed tube;
With Cl2 In tetrachloromethane heating Sb2O3 with a soln. of Cl2 in CCl4 in a sealed tube at 100°C;;
With Cl2; CCl4 at 100°C in sealed tube;

: antimony(III) trioxide

A: 10025-67-9
disulfur dichloride

B: 7647-18-9
antimonypentachloride

Conditions

Conditions	Yield
With thionyl chloride byproducts: SO2; with large excess of SOCl2;
With SOCl2 byproducts: SO2; with large excess of SOCl2;

: antimony(III) trioxide

A: cervantite

B: 7647-18-9
antimonypentachloride

C: 10025-91-9
antimony(III) chloride

Conditions

Conditions	Yield
With chlorine by heating;
With Cl2 by heating;

...Expand

: antimony(III) sulfide

: 7647-18-9
antimonypentachloride

Conditions

Conditions	Yield
With chlorine	0%
With Cl2	0%

: 7440-36-0
antimony

: 7782-49-2
selenium

A: SbCl5*SeCl4

B: 7647-18-9
antimonypentachloride

Conditions

Conditions	Yield
With chlorine dry Cl2; remowing SbCl5 over H2SO4;
With Cl2 dry Cl2; remowing SbCl5 over H2SO4;

...Expand

: 56-23-5
tetrachloromethane

: antimony pentoxide

: 7647-18-9
antimonypentachloride

Conditions

Conditions	Yield
at 420°C;

: 7791-25-5
sulfuryl dichloride

: antimony(V) sulfide

A: 7647-18-9
antimonypentachloride

B: 7704-34-9
sulfur

Conditions

Conditions	Yield
In neat (no solvent)

...Expand

: 13596-35-5
rhenium(V) chloride

: 10025-91-9
antimony(III) chloride

A: 13569-71-6
rhenium tetrachloride

B: 7647-18-9
antimonypentachloride

Conditions

Conditions	Yield
In neat (no solvent) byproducts: Re3Cl9; distiln. (vac.), sublimation;

...Expand

: antimony(III) sulfate

A: antimony(III) sulfate * 5 HCl

B: 7647-18-9
antimonypentachloride

Conditions

Conditions	Yield
In neat (no solvent) byproducts: SbCl5; passing dry HCl-stream over Sb2(SO4)3 with spontaneous heat evolution (up to melting temp.); cooling;; SbCl5 sublimes;;
In neat (no solvent) byproducts: SbCl5; passing dry HCl-stream over Sb2(SO4)3 with spontaneous heat evolution (up to melting temp.); cooling;; SbCl5 sublimes;;

: SbCl5*2SbF5

: 2696-92-6
nitrosylchloride

A: antimony pentoxide

B: SbF5*NOF

C: 7647-18-9
antimonypentachloride

Conditions

Conditions	Yield
without moisture of air; heating to 100 °C then in vac. (1-3 mmHg) at 180-200 °C (6h); max. purity 90%;
without moisture of air; heating to 100 °C then in vac. (1-3 mmHg) at 180-200 °C (6h); max. purity 90%;

...Expand

: antimony(III) trioxide

: cesium hexachloro-stannate(IV)

A: caesium oxochlorostannate(IV)

B: 7647-18-9
antimonypentachloride

Conditions

Conditions	Yield
Cl2 atm;
Cl2 atm;

...Expand

: 52940-42-8, 44479-97-2, 16918-97-1
SbCl5*H2O

A: 7647-18-9
antimonypentachloride

B: 10025-91-9
antimony(III) chloride

Conditions

Conditions	Yield
heating at 20 Torr;

: Sb3OCl13

A: antimony pentoxide

B: 7647-18-9
antimonypentachloride

C: 10025-91-9
antimony(III) chloride

Conditions

Conditions	Yield
byproducts: Cl2; with heating; SbCl3 and SbCl5 evaporate;

...Expand

: 17455-13-9
18-crown-6 ether

: 7647-18-9
antimonypentachloride

: lead(II) chloride

: {Pb(O6(CH2)12)(CH3CN)3}(2+)*2(SbCl6)(1-)={Pb(O6(CH2)12)(CH3CN)3}{SbCl6}2

Conditions

Conditions	Yield
In acetonitrile PbCl2 is dissolved by injection of SbCl5 in MeCN, addn. of 18-crown-6; concn. the volume under vac., standing for some time at 20°C, filtn., elem. anal.;	100%

...Expand

: 7791-25-5
sulfuryl dichloride

: 7647-18-9
antimonypentachloride

: tris[2-(2-pyridyl)phenyl]stibine

: C33H24N3Sb(2+)*2Cl6Sb(1-)

Conditions

Conditions	Yield
Stage #1: sulfuryl dichloride; tris[2-(2-pyridyl)phenyl]stibine In acetonitrile at -40℃; for 2h; Inert atmosphere; Stage #2: antimonypentachloride In dichloromethane at -40℃; for 2h; Inert atmosphere;	100%

...Expand

: 7647-01-0
hydrogenchloride

: 7647-18-9
antimonypentachloride

: 7732-18-5
water

: 53890-32-7
H2O*H(1+)*SbCl6(1-)=H2O*HSbCl6

Conditions

Conditions	Yield
In dichloromethane (He atm.) the calculated volumes of CH2Cl2-solns. of SbCl5, H2O and HCl were mixed;	99%

...Expand

: 7647-01-0
hydrogenchloride

: 7647-18-9
antimonypentachloride

: 7732-18-5
water

: H(1+)*SbCl6(1-)*2H2O=HSbCl6*2H2O

Conditions

Conditions	Yield
In dichloromethane (He atm.) the calculated volumes of CH2Cl2-solns. of SbCl5, H2O and HCl were mixed;	99%

...Expand

: 506-68-3
bromocyane

: 7647-18-9
antimonypentachloride

: 22538-96-1, 24273-95-8
SbCl5(BrCN)

Conditions

Conditions	Yield
In dichloromethane under N2, SbCl5 was added to equiv. amt. of BrCN in CH2Cl2 at room temp.; solvent was removed in dynamic vac., elem. anal.;	99%

: 506-78-5
cyanogen iodide

: 7647-18-9
antimonypentachloride

: 359860-18-7
SbCl5(ICN)

Conditions

Conditions	Yield
In dichloromethane under N2, SbCl5 was added to equiv. amt. of ICN in CH2Cl2 at room temp.; solvent was removed in dynamic vac., elem. anal.;	99%

: 420-04-2
CYANAMID

: 7647-18-9
antimonypentachloride

: 359860-20-1
SbCl5NCNH2

Conditions

Conditions	Yield
In dichloromethane under N2, SbCl5 was added to equiv. amt. of H2NCN in CH2Cl2 at room temp.; solvent was removed in dynamic vac., elem. anal.;	99%

: 676-85-7
methylsulphinyl chloride

: 7647-18-9
antimonypentachloride

: 65554-06-5
methyl(chloro)sulfinylantimony pentachloride

Conditions

Conditions	Yield
In dichloromethane addn. of SbCl5 in CH2Cl2 at 243 K with stirring to CH3SOCl in CH2Cl2 within 1.5 h, further stirring (1 h); concn. (dynamic vac.), filtration at 233 K, drying (dynamic vac., 273 K);	99%

: 110-86-1
pyridine

: 7647-18-9
antimonypentachloride

: 24551-32-4
SbCl5(C5H5N)

Conditions

Conditions	Yield
In dichloromethane under N2, SbCl5 was added to equiv. amt. of pyridine in CH2Cl2 at room temp.; solvent was removed in dynamic vac., elem. anal.;	99%

: 7647-18-9
antimonypentachloride

: 75307-82-3
6-Methyl-7-oxo-8-phenyl-1λ3-thionia-3λ4,5λ4-dithia-2,4,6,8,9-pentaazabicyclo<3.3.1>nona-2,3,5(9)-trien-chlorid

: 75307-85-6
6-Methyl-7-oxo-8-phenyl-1λ3-thionia-3λ4,5λ4-dithia-2,4,6,8,9-pentaazabicyclo[3.3.1]nona-2,3,5(9)-trien-chlorid

Conditions

Conditions	Yield
In tetrachloromethane ppt. was recrystd. from CH3CN/CCl4 (1:15); elem. anal.;	99%

: 5400-82-8
N,N-dimethylbenzylamine N-oxide

: 7647-18-9
antimonypentachloride

: 83616-70-0
N,N-dimethylbenzylamine oxide-SbCl5

Conditions

Conditions	Yield
In tetrachloromethane soln. of PhCH2Me2NO in CCl4 added to soln. of SbCl5 in CCl4; filtered, washed with CCl4 and petroleum ether; elem. anal.;	99%

: 7647-18-9
antimonypentachloride

: 67-68-5
dimethyl sulfoxide

: 23058-09-5
((CH3)2SO)SbCl5

Conditions

Conditions	Yield
In tetrachloromethane DMSO and SbCl5 (mole ratio 1:1) were mixed in CCl4 with cooling; the mixt was allowed to stand overnight;; the ppt. was collected by filtration, washed with CCl4, then with petroleum ether; elem. anal.;;	98.7%

: 130256-90-5
4-methylaminopent-3-en-2-one

: 7647-18-9
antimonypentachloride

: SbCl5*CH3COCHC(NHCH3)CH3

Conditions

Conditions	Yield
In chloroform dropwise addn. of SbCl3 soln. to ketoamine soln. with stirring and exclusion of moisture; stirring, 8h; decanting; washing (chloroform); drying (30°C/0.1 mm, 5h); elem. anal.;	98%

: 7647-18-9
antimonypentachloride

: 59487-11-5
N-isopropyl-4-amino-3-penten-2-one

: SbCl5*CH3COCHC(NHCH(CH3)2)CH3

Conditions

Conditions	Yield
In chloroform dropwise addn. of SbCl3 soln. to ketoamine soln. with stirring and exclusion of moisture; stirring, 8h; decanting; washing (chloroform); drying (30°C/0.1 mm, 5h); elem. anal.;	98%

: 7647-18-9
antimonypentachloride

: 72160-17-9
6,8-Dimethyl-7-oxo-1λ3-thionia-3λ4,5λ4-dithia-2,4,6,8,9-pentaazabicyclo<3.3.1>nona-2,3,5(9)-trien-chlorid

: 75307-83-4
6,8-Dimethyl-7-oxo-1λ3-thionia-3λ4,5λ4-dithia-2,4,6,8,9-pentaazabicyclo[3.3.1]nona-2,3,5(9)-trien-hexachloroantimonat

Conditions

Conditions	Yield
In tetrachloromethane ppt. was recrystd. from CH3CN/CCl4 (1:15); elem. anal.;	98%

: 17455-13-9
18-crown-6 ether

: 7647-18-9
antimonypentachloride

: lead(II) chloride

: {Pb(O5(CH2)10)2}(2+)*2(SbCl6)(1-)={Pb(O5(CH2)10)2}{SbCl6}2

Conditions

Conditions	Yield
In acetonitrile PbCl2 is dissolved by injection of SbCl5 in MeCN, addn. of 15-crown-5; concn. the volume under vac., filtn., cooling the filtrate, filtn., washing with MeCN, vac. drying, elem. anal.;	97%

...Expand

: 50967-59-4
4-(ethylamino)penten-2-one

: 7647-18-9
antimonypentachloride

: SbCl5*CH3COCHC(NHC2H5)CH3

Conditions

Conditions	Yield
In chloroform dropwise addn. of SbCl3 soln. to ketoamine soln. with stirring and exclusion of moisture; stirring, 8h; decanting; washing (chloroform); drying (30°C/0.1 mm, 5h); elem. anal.;	97%

: 54434-25-2
Isopropylmethylcyanamide

: 7647-18-9
antimonypentachloride

: 89953-15-1
antimony pentachloride-isopropylmethylcyanamide

Conditions

Conditions	Yield
In dichloromethane addn. dropwise, stirring -78°C for 1 h, then 22°C for 2h,; evapn. in vac., pptn.with pentane, washed with pentane, recrystn. from CH2Cl2, elem.anal.;	97%

: 49677-01-2
N-methyl-N-cyclohexyl cyanamide

: 7647-18-9
antimonypentachloride

: 89953-16-2
antimony pentachloride-cyclohexylmethylcyanamide

Conditions

Conditions	Yield
In dichloromethane addn. dropwise, stirring -78°C for 1 h, then 22°C for 2h,; evapn., in vac., pptn. with pentane, washed with pentane, recrystn. from CH2Cl2, elem.anal.;	97%

: 292638-84-7
styrene

: 59957-75-4
2,2'-dipyridyldiselenide

: 7647-18-9
antimonypentachloride

: bis(3-phenyl-2,3-dihydro[1,3]selenazolo[3,2-a]pyridinium-4) pentachloroantimonate(III)

Conditions

Conditions	Yield
In dichloromethane soln. of SbCl5 in CH2Cl2 added to soln. of Se-compound in CH2Cl2 at -40°C with stirring under Ar, stirred for 15 min at -40°C, CH2Cl2 soln. of styrene added dropwise, stirred for 30 min, warmed to room temp.; solvent evapd. in vacuo, recrystd. from CH2Cl2; elem. anal.;	97%

...Expand

: 75-09-2
dichloromethane

: 7647-18-9
antimonypentachloride

: 7782-50-5
chlorine

: 107-06-2
1,2-dichloro-ethane

: 1663-45-2
1,2-bis-(diphenylphosphino)ethane

: C26H24Cl2P2(2+)*CH2Cl2*2C2H4Cl2*Cl5Sb(2-)

Conditions

Conditions	Yield
Stage #1: chlorine; 1,2-dichloro-ethane; 1,2-bis-(diphenylphosphino)ethane In 1,2-dichloro-ethane at -30℃; for 0.0833333h; Stage #2: dichloromethane; antimonypentachloride In dichloromethane; 1,2-dichloro-ethane at -30 - 23℃; for 1h;	97%

...Expand

: 6628-18-8
1,2-bis(methylthio)ethane

: 7647-18-9
antimonypentachloride

: C4H10ClS2(1+)*Cl6Sb(1-)

Conditions

Conditions	Yield
Stage #1: 1,2-bis(methylthio)ethane With chlorine In 1,2-dichloro-ethane at -30℃; for 0.0833333h; Inert atmosphere; Stage #2: antimonypentachloride In dichloromethane at 23℃; for 1h; Inert atmosphere;	97%

: 7647-18-9
antimonypentachloride

: 6831-82-9
potassium isopropoxide

: KSb(OCHCH3CH3)6

Conditions

Conditions	Yield
In chloroform byproducts: KCl; A soln. of potassium metal in isopropanol is added to an ice cold soln. of SbCl5, refluxed for 4 h under dry N2, cooling.; KCl is filtered off, elem. anal.;	96%

: 7647-18-9
antimonypentachloride

: 2696-92-6
nitrosylchloride

: 16871-80-0
nitrosonium hexachloroantimonate

Conditions

Conditions	Yield
In dichloromethane 0 - 10 °C, under N2; the product was filtered under N2, washed with CH2Cl2, dried in vac. at25 °C, elem. anal.;	96%

: 19227-13-5
p-toluamidoxime

: 7647-18-9
antimonypentachloride

: 132293-63-1
SbCl5N(OH)C(NH2)C6H4CH3

Conditions

Conditions	Yield
In dichloromethane addn. of ligand soln. to soln. of SbCl5, pptn., stirred for 1h; ppt. filtered, washed with CH2Cl2, recrystd. from CHCl3/hexane, dried in vac. at 50°C; elem. anal.;	96%

: 586-77-6
4-bromo-N,N-dimethylaniline

: 7647-18-9
antimonypentachloride

: 4-bromo-N,N-dimethylaniline antimony pentachloride complex

Conditions

Conditions	Yield
In chloroform stirring for 30 min; filtration of ppt., washing with CHCl3, drying, elem. anal.;	96%

: 5395-75-5
1,2-bis(ethylthio)ethane

: 7647-18-9
antimonypentachloride

: C6H14ClS2(1+)*Cl6Sb(1-)

Conditions

Conditions	Yield
Stage #1: 1,2-bis(ethylthio)ethane With chlorine In 1,2-dichloro-ethane at -30℃; for 0.0833333h; Inert atmosphere; Stage #2: antimonypentachloride In dichloromethane at 23℃; for 1h; Inert atmosphere;	96%

: 7647-18-9
antimonypentachloride

: 62-55-5
thioacetamide

: antimony(III) sulfide

Conditions

Conditions	Yield
With HCl In water High Pressure; SbCl5 dissolved in HCl at ambient temp.; H2O added; temp. increased to 50°C; mixed with stoich. amt. of thioacetamide; soln. transferred into stainless-steel autoclave; sealed autoclave maintained at 180°C for 3 h; cooled to room temp.; filtered; washed (soln. of tartaric acid, H2O); dried (vac.) at 60°C for 5 h;	95%

: Se2NCl3

: 7647-18-9
antimonypentachloride

: 151654-58-9, 603109-87-1
{ClSeNSeCl}(1+)*SbCl6(1-)={ClSeNSeCl}SbCl6

Conditions

Conditions	Yield
In sulfur dioxide N2-atmosphere; addn. of 1 equiv. SbCl5 to Se2NCl3 soln., stirring (room temp., 2 h); solvent removal (reduced pressure);	95%

Antimony(V) chloride Chemical Properties

IUPAC Name: Pentachloro-λ⁵-stibane
Synonyms: Antimony pentachloride ; Antimony, pentachloro- ; Pentachlorostiborane ; Antimony (V) chloride
Product Categories: Intermediates of Dyes and Pigments;Inorganics;Antimony Salts;Metal and Ceramic Science;Salts
CAS NO: 7647-18-9
Molecular Formula of Antimony(V) chloride (CAS NO.7647-18-9) : Cl₅Sb
Molecular Weight of Antimony(V) chloride (CAS NO.7647-18-9) : 299.02
Molecular Structure of Antimony(V) chloride (CAS NO.7647-18-9) :
EINECS: 231-601-8
Mol File: 7647-18-9.mol
Merck : 14,695
Melting point: 2.8 °C(lit.)
Boiling Point: 92 °C30 mm Hg(lit.)
Flash Point: 79°C/22mm
Density 2.36 g/mL at 25 °C(lit.)
Vapor density >10.2 (vs air)
Vapor pressure 0.13 psi ( 55 °C)
Refractive index 1.601
Sensitive Moisture Sensitive
Stability: Stable, but reacts with moisture and water. Releases highly toxic fumes if involved in a fire.
Appearance:colourless to light yellow oily liquid

Antimony(V) chloride Uses

Antimony(V) chloride (CAS NO.7647-18-9) is used for high-purity analytical reagents, catalysts, and also for preparation of high purity antimony.

Antimony(V) chloride Production

Antimony(V) chloride (CAS NO.7647-18-9) is prepared by passing chlorine gas into molten antimony trichloride:
SbCl₃ + Cl₂ → SbCl₅

Antimony(V) chloride Toxicity Data With Reference

1.	mrc-bcs 30 µL/disc	MUREAV Mutation Research. 77 (1980),109.
2.	orl-rat LD50:1115 mg/kg	HYSAAV Hygiene and Sanitation: English Translation of Gigiena Sanitariya. 29 (12)(1964),16.
3.	orl-gpg LD50:900 mg/kg	HYSAAV Hygiene and Sanitation: English Translation of Gigiena Sanitariya. 29 (12)(1964),16.

Antimony(V) chloride Consensus Reports

Reported in EPA TSCA Inventory. Antimony and its compounds are on the Community Right-To-Know List.

Antimony(V) chloride Safety Profile

Poison by ingestion. Corrosive. Mutation data reported. See ANTIMONY COMPOUNDS and ANTIMONY(III) CHLORIDE. When heated to decomposition it emits very toxic fumes of Cl⁻ and Sb.
Hazard Codes Toxic T, Dangerous N,C
Risk Statements 34-51/53-40-23/24/25-14
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed.
R14 :Reacts violently with water.
R34:Causes burns.
R40:Limited evidence of a carcinogenic effect.
R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Statements 26-45-61-36/37/39-23
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
S23:Do not breathe vapour.
RIDADR UN 1731 8/PG 3
WGK Germany 2
RTECS CC5075000
F 10
HazardClass 8
PackingGroup II

Antimony(V) chloride Standards and Recommendations

OSHA PEL: TWA 500 µg(Sb)/m³
ACGIH TLV: TWA 0.5 mg(Sb)/m³
NIOSH REL: (Antimony) TWA 0.5 mg(Sb)/m³
DOT Classification: 8; Label: Corrosive

Antimony(V) chloride Specification

1.General Description :A reddish-yellow fuming liquid with a pungent odor. Fumes are irritating to the eyes and mucous membranes. Solidifies at 37°F. Corrosive to metals and tissue. Used to make other chemicals, and in chemical analysis.
2.Air & Water Reactions: Fumes in air to form hydrochloric acid. Reacts with water to yield heat and antimony pentaoxide (Sb₂O₅) and hydrochloric acid 3.Reactivity Profile: Acidic salts, such as Antimony pentachloride , are generally soluble in water. The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Many of these compounds catalyze organic reactions.
4.Health Hazard :Inhalation causes irritation of nose and throat. Contact of liquid with eyes or skin causes severe burns. Ingestion causes vomiting and severe burns of mouth and stomach. Overexposure by any route can cause bloody stools, slow pulse, low blood pressure, coma, convulsions, cardiac arrest.
5.Fire Hazard :Behavior in Fire: Irritating fumes of hydrogen chloride given off when water or foam is used to extinguish adjacent fire.

Product Name

ANTIMONY(V) CHLORIDE

Stability

Toxicology

Synthetic route

Antimony(V) chloride Chemical Properties

Antimony(V) chloride Uses

Antimony(V) chloride Production

Antimony(V) chloride Toxicity Data With Reference

Antimony(V) chloride Consensus Reports

Antimony(V) chloride Safety Profile

Antimony(V) chloride Standards and Recommendations

Antimony(V) chloride Specification

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