Antimony(V) pentafluoride supplier

Name
ANTIMONY PENTAFLUORIDE
EINECS 232-021-8
CAS No. 7783-70-2
Article Data63
CAS DataBase
Density 2.993 g/mL at 25 °C(lit.)
Solubility reacts vigorously with H2O, becoming hydrolyzed [HAW93] [KIR78]
Melting Point 7 °C(lit.)
Formula F₅Sb
Boiling Point 149.4 °C
Molecular Weight 216.742
Flash Point 149.5°C
Transport Information UN 2923 8/PG 2
Appearance colourless oily liquid
Safety 61-45-36/37/39-28-27-26-22
Risk Codes 23/24/25-34-51/53-20/22
Molecular Structure
Hazard Symbols T,O,C,N,Xn
Synonyms Antimonypentafluoride;Antimony(V) fluoride;Pentafluoroantimony;
PSA 0.00000
LogP 2.10100

Synthetic route

: 7440-36-0
antimony

: 13847-65-9, 57526-95-1, 478286-98-5
trifluoroamine oxide

: 7783-70-2
antimony pentafluoride

Conditions

Conditions	Yield
In neat (no solvent) cylinder fiited with dry powdered element, NF3O condensed into cylinder at -196°C, mixt. heated at 210°C for 24h; not isolated, monitored by NMR, IR;	90%

: 13774-70-4
((pentafluorosulfanyl)imino)difluorosulfane

: 7647-18-9
antimonypentachloride

A: 25502-15-2
SF5N=SCl2

B: 80997-19-9
((pentafluorosulfanyl)imino)chlorofluorosulfane

C: 7783-70-2
antimony pentafluoride

Conditions

Conditions	Yield
sulfane was condesed on SbCl5 at -196°C, heated at 100°C to initiate the reaction; fractionation through a series of traps at -6, -45, -78, -112 and -196°C in vac., a -45°C trap contained the product;	A 35% B n/a C n/a

...Expand

: 128362-15-2
H2F(1+)*SbClF5(1-)=H2FSbClF5

: 7783-70-2
antimony pentafluoride

Conditions

Conditions	Yield
In neat (no solvent) byproducts: HCl, HF; decomposition above -50°C;;

: 7440-36-0
antimony

: 13709-36-9
xenon difluoride

: 7783-70-2
antimony pentafluoride

Conditions

Conditions	Yield
In neat (no solvent) powdered metal treated with XeF2 (air-tight autoclave, 200-300°C);

: 7440-36-0
antimony

: 7782-41-4
fluorine

: 7783-70-2
antimony pentafluoride

Conditions

Conditions	Yield
burning antimony filings in F2 atmosphere; without isolation of intermediates the end product liq. SbF5;
in a stream of HF-free F2; distn. in vac.;
In not given

: 7664-39-3
hydrogen fluoride

: 7647-18-9
antimonypentachloride

: 7783-70-2
antimony pentafluoride

Conditions

Conditions	Yield
HF free of water;;
HF free of water;;
at 100℃; for 3h; Autoclave; Inert atmosphere;

: 7647-18-9
antimony(V) chloride

: 7664-39-3
hydrogen fluoride

: 7783-70-2
antimony pentafluoride

Conditions

Conditions	Yield
In hydrogen fluoride
In hydrogen fluoride HF (liquid);

: antimonic acid

: 7783-70-2
antimony pentafluoride

Conditions

Conditions	Yield
With hydrogen fluoride by addn. antimonic acid into HF soln.; evapn. in vac.; cannot be crystallized;
With calcium fluoride; sulfuric acid by distn.;	0%
With hydrogen fluoride anhydrous antimonic acid with concd. HF soln.;	0%

: mercury(II) fluoride

: antimonic acid

: 7783-70-2
antimony pentafluoride

Conditions

Conditions	Yield
by glowing antimonic acid with dry HgF2;	0%
by glowing antimonic acid with dry HgF2;	0%

: triethyloxonium hexafluoroantimonate

: 7783-70-2
antimony pentafluoride

Conditions

Conditions	Yield
With diethyl ether In dichloromethane Kinetics; byproducts: Et2O, CH3CH2F; vac. line; 298 - 343 K;
With 1,3-dioxolan In dichloromethane Kinetics; byproducts: Et2O, CH3CH2F; vac. line; 298 - 343 K;

: 7647-18-9
antimonypentachloride

: 7783-70-2
antimony pentafluoride

Conditions

Conditions	Yield
With hydrogen fluoride
With hydrogen fluoride byproducts: HCl; with anhydrous HF excess; temp. programming is given; SbF5 in liq. form;
With HF byproducts: HCl; with anhydrous HF, at room temp., in dry conditions; HF excess; SbF5 in liq. form;
With HF byproducts: HCl; with anhydrous HF excess; temp. programming is given; SbF5 in liq. form;
With HF

: SbF5*5HF

: 7783-70-2
antimony pentafluoride

Conditions

Conditions	Yield
byproducts: HF; at 80 °C;

: 2SbF5*I

: 7783-70-2
antimony pentafluoride

Conditions

Conditions	Yield
at >240 °C;
at >240 °C;

: antimony pentoxide

: 75-71-8
Dichlorodifluoromethane

A: 14913-58-7
antimony tetrachloride fluoride

B: 7791-16-4
antimony dichloride trifluoride

C: 15588-48-4
SbF4Cl

D: 24626-20-8
SbCl3F2

E: 7783-70-2
antimony pentafluoride

Conditions

Conditions	Yield
In neat (no solvent) reaction at 600°C;;

...Expand

: 7440-36-0
antimony

: 7783-41-7
difluoroether

: 7783-70-2
antimony pentafluoride

Conditions

Conditions	Yield
In neat (no solvent) heating of antimony powder and OF2; inflammation;;
In neat (no solvent) heating of antimony powder and OF2; inflammation;;

: 6141-72-6
perfluoro(2,4-dimethyl-3-oxa-2,4-diazapentane)

: 432-05-3
tris(trifluoromethyl)stibane

A: 371-71-1
Perfluoro-2-azapropen

B: 671-63-6
tris(trifluoromethyl)hydroxylamine

C: 7783-70-2
antimony pentafluoride

Conditions

Conditions	Yield
warming from -60°C to room temp. within 10 h;	A >99 B >99 C >99
warming from -60°C to room temp. within 10 h;	A >99 B >99 C >99

...Expand

: Ca(antimony hexafluoride)2

A: calcium fluoride

B: 7783-70-2
antimony pentafluoride

Conditions

Conditions	Yield
In neat (no solvent) dry air atmosphere; melting and thermal decompn. above 600-650°C; TGA;

: Ba(antimony hexafluoride)2

A: barium fluoride

B: 7783-70-2
antimony pentafluoride

Conditions

Conditions	Yield
In neat (no solvent) dry air atmosphere; melting and thermal decompn. above 600-650°C; TGA;

: Sr(antimony hexafluoride)2

A: strontium fluoride

B: 7783-70-2
antimony pentafluoride

Conditions

Conditions	Yield
In neat (no solvent) dry air atmosphere; melting and thermal decompn. above 600-650°C; TGA;

: Mg(antimony hexafluoride)2

A: magnesium fluoride

B: 7783-70-2
antimony pentafluoride

Conditions

Conditions	Yield
In neat (no solvent) dry air atmosphere; melting and thermal decompn. above 600-650°C; TGA;

: 7647-18-9
antimony(V) chloride

: 7664-39-3
hydrogen fluoride

A: 7647-01-0
hydrogenchloride

B: 7783-70-2
antimony pentafluoride

Conditions

Conditions	Yield
In hydrogen fluoride solving of SbCl5 in liq. HF;;
In hydrogen fluoride solving of SbCl5 in liq. HF;;

...Expand

: 13693-06-6
plutonium hexafluoride

: 7783-56-4
antimony(III) fluoride

A: 13709-56-3
PuF4

B: 7783-70-2
antimony pentafluoride

Conditions

Conditions	Yield
below room temp.; powder XRD;

...Expand

: 7783-75-7
iridium hexafluoride

: 7783-56-4
antimony(III) fluoride

A: 14568-19-5
iridium pentafluoride

B: 7783-70-2
antimony pentafluoride

Conditions

Conditions	Yield
In neat (no solvent) IrF6 condensed onto excess of SbF3 at -196°C, allowed to warm slowly to room temp.; volatiles species removed, fractionated; IR;

...Expand

: 14884-42-5
chromium pentafluoride

: 52708-44-8
KrF(1+)*SbF6(1-) = [KrF][SbF6]

A: 13843-28-2
hexafluoro-chromium(VI)

B: krypton

C: 7783-70-2
antimony pentafluoride

D: 7782-41-4
fluorine

Conditions

Conditions	Yield
34°C;	A 0% B n/a C n/a D n/a

...Expand

: SbF5*S

A: 7783-56-4
antimony(III) fluoride

B: 7783-70-2
antimony pentafluoride

C: 7704-34-9
sulfur

Conditions

Conditions	Yield
partial decompn. in wet air;
partial decompn. in wet air;

...Expand

: 124489-84-5
fluoro(trifluoromethylsulfenyl)phosphonium SbF6

: 7783-70-2
antimony pentafluoride

Conditions

Conditions	Yield
In liquid sulphur dioxide byproducts: HF, (CF3SP)99;

: 13693-08-8
ruthenium(VI) fluoride

: 7783-56-4
antimony(III) fluoride

A: 14521-18-7
ruthenium(V) fluoride

B: 7783-70-2
antimony pentafluoride

Conditions

Conditions	Yield
RuF6 was condensed onto SbF3 at -196°C; was allowed to warm slowly to room temperature; volatiles were removed; IR;

...Expand

: 7647-18-9
antimonypentachloride

A: 2SbF3*SbF5

B: 10025-91-9
antimony(III) chloride

C: 7783-70-2
antimony pentafluoride

Conditions

Conditions	Yield
With HF byproducts: HCl, Cl2; with anhydrous HF; distn. (8h) at 90 °C (distn. of HCl and HF), and up to 125 °C (distn. of SbCl5, SbCl3 and SbF5); distn. at 390 °C;

...Expand

: PF4(1+)*Sb3F16(1-) = PF4Sb3F16

A: 7783-70-2
antimony pentafluoride

B: 7647-19-0, 874483-74-6
phosphorus pentafluoride

Conditions

Conditions	Yield
in soln.; 194 K; 30 min;	A >99 B >99

: 25562-23-6
NF2O(1+)*SbF6(1-) = (NF2O)(SbF6)

A: 13847-65-9, 57526-95-1, 478286-98-5
trifluoroamine oxide

B: 7783-70-2
antimony pentafluoride

: (η5-C5H5)2niobium(V)(Cl2) hexafluoroantimonate

: 7783-70-2
antimony pentafluoride

: (η5-C5H5)2niobium(V)(Cl2) {Sb2F11}

Conditions

Conditions	Yield
In liquid sulphur dioxide under Ar; recrystn. (SO2), elem. anal.;	100%

: 64023-44-5, 16560-95-5, 30406-47-4
Ph3GeCo(CO)4

: 7783-70-2
antimony pentafluoride

: 379-47-5
triphenylgermanium fluoride

Conditions

Conditions	Yield
With pyrographite In diethyl ether under N2 a soln. of Co-complex in ether was added dropwise with stirring to a suspension of SbF5/C in ether at room temp., stood for 6 d; monitored by IR, filtered, pumped off, dissolved in pentane, filtered, cocnd., cooled to -20°C;	100%

: 62792-13-6
indium(I) tetrafluoroborate

: 7664-39-3
hydrogen fluoride

: 7783-70-2
antimony pentafluoride

: 877238-63-6
indium(I) hexafluoroantimonate

Conditions

Conditions	Yield
In hydrogen fluoride HF (liquid); equimol., HF condenced onto reagent at 77 K, alowed to warm to room temp., left for 1 d; volatiles removed (vac.); elem. anal.;	100%

...Expand

: 17632-18-7
(2,3,7,8,12,13,17,18-octaethylporphyrinato)zinc(II)

: 7783-70-2
antimony pentafluoride

: C36H44N4Zn(2+)*2F6Sb(1-)

Conditions

Conditions	Yield
In dichloromethane at -78 - 20℃; Inert atmosphere;	100%

: 7664-39-3
hydrogen fluoride

: 7783-70-2
antimony pentafluoride

: 75-05-8
acetonitrile

: C2H3N*F6Sb(1-)*H(1+)

Conditions

Conditions	Yield
Stage #1: hydrogen fluoride; antimony pentafluoride at -196 - 20℃; Sealed tube; Stage #2: acetonitrile at -196 - 20℃; for 0.5h; Sealed tube; Inert atmosphere;	100%

...Expand

: 7664-39-3
hydrogen fluoride

: 7783-70-2
antimony pentafluoride

: 75-05-8
acetonitrile

: MeCNHSb2F11

Conditions

Conditions	Yield
Stage #1: hydrogen fluoride; antimony pentafluoride at -196 - 20℃; Sealed tube; Stage #2: acetonitrile at -196 - 20℃; for 0.5h; Sealed tube; Inert atmosphere;	100%

...Expand

propyl cyanide: propyl cyanide

: 7783-70-2
antimony pentafluoride

: F5Sb*C4H7N

Conditions

Conditions	Yield
at -196 - -64℃; for 0.166667h; Sealed tube;	100%

: 7783-70-2
antimony pentafluoride

: 5500-21-0
cyclopropropanecarbonitrile

: C4H5N*F5Sb

Conditions

Conditions	Yield
at -196 - -64℃; for 0.166667h; Sealed tube;	100%

: 630-18-2
tert-butyl isocyanide

: 7783-70-2
antimony pentafluoride

: C5H9N*F5Sb

Conditions

Conditions	Yield
at -196 - -64℃; for 0.166667h; Sealed tube;	100%

: 309-89-7
titanocene difluoride

: 7783-70-2
antimony pentafluoride

: (cyclopentadienyl)2Ti(SbF6)2

Conditions

Conditions	Yield
In sulfur dioxide condensation of SbF5 in SO2 into a soln. of Ti-compd. in SO2 at -50°C, warming to room temp. with stirring, then stirring at room temp. for 30 min; cooling to 10-15°C and condensation of SO2, formation of a solid, elem. anal.;	99.8%

: 13812-43-6
cis-difluorodiazene

: 7783-70-2
antimony pentafluoride

: 16871-11-7
N2F(1+)*SbF6(1-)=[N2F][SbF6]

Conditions

Conditions	Yield
In hydrogen fluoride HF (liquid); (vac.); condensing HF onto SbF5 at -196°C, warming to room temp.,addn. of N2F2 at -196°C, warming to room temp., stirring for 10 min; pumping off at -64°C for 2 h;	99.7%

: 143672-39-3
cis-osmium tetrafluoride dioxide

: 7783-70-2
antimony pentafluoride

: F(cis-OsO2F3)2(+)Sb2F11(-)

B: 1203648-84-3
[OsO2F3](1+)*[SbF6](1-)=[OsO2F3][SbF6]

Conditions

Conditions	Yield
In hydrogen fluoride HF (liquid); SbF5 added to OsO2F4, HF condensed at -196°C, warmed to room temp.; pptd. at -78°C, pumped for 5 h at 0°C;	A 99.4% B 0%
In neat (no solvent) warmed to room temp.; pumped at 0°C for 6 d;	A 107 % B 0%

...Expand

: 59802-62-9
bis(pentafluoroethyl)selenium difluoride

: 7783-70-2
antimony pentafluoride

: bis(pentafluoroethyl)selenium difluoride SbF5 adduct

Conditions

Conditions	Yield
20°C, 1.5 h;	99%

: Au fluorosulfate

: 201230-82-2
carbon monoxide

: 7783-70-2
antimony pentafluoride

: bis(carbonyl)gold(I) undecafluorodiantimonate(V)

Conditions

Conditions	Yield
mild conditions, low CO pressure;	99%

...Expand

: 13773-81-4
krypton difluoride

: 7783-70-2
antimony pentafluoride

: 52708-44-8
KrF(1+)*SbF6(1-) = [KrF][SbF6]

Conditions

Conditions	Yield
In hydrogen fluoride dry HF was distd. in 1 equiv of SbF5, homogenized at ambient temp., 1.06 equiv of KrF2 was transferred under vac. at -196°C, warmed to room temp., cooled, warmup was repeated three cycles; volatiles pumped off at -22°C;	99%

: 201230-82-2
carbon monoxide

: 7783-70-2
antimony pentafluoride

: 13453-07-1
gold(III) chloride

: bis(carbonyl)gold(I) undecafluorodiantimonate(V)

Conditions

Conditions	Yield
In further solvent(s) byproducts: COF2; absence of air and moisture; stirring AuCl3 in SbF5 under 0.6 atm CO (60-70°C, 5 d); evapn. (vac., 55°C);	99%

...Expand

: Pd(II)Pd(IV) fluorosulfate

: 201230-82-2
carbon monoxide

: 7783-70-2
antimony pentafluoride

: tetrakis(carbonyl)palladium(II) undecafluoroantimonate(V)

Conditions

Conditions	Yield
mild conditions, low CO pressure;	99%

...Expand

: platinum tetrakis(fluorosulfate)

: 201230-82-2
carbon monoxide

: 7783-70-2
antimony pentafluoride

: tetrakis(carbonyl)platinum(II) undecafluoroantimonate(V)

Conditions

Conditions	Yield
mild conditions, low CO pressure;	99%

...Expand

: 353-49-1
fluoroformyl chloride

: 7783-70-2
antimony pentafluoride

: 229472-62-2, 229472-61-1, 229472-59-7
(COClF)SbF5

Conditions

Conditions	Yield
In neat (no solvent) Teflon ampoule inside stainless-steel vac. line; excess COClF, mixing at-196°C, stirring at -78°C for 1 h; pumping at -110°C;	99%

: 353-50-4
Carbonyl fluoride

: 7783-70-2
antimony pentafluoride

: 32222-72-3, 71841-00-4
(COF2)SbF5

Conditions

Conditions	Yield
In neat (no solvent) Teflon ampoule inside stainless-steel vac. line; excess COF2, mixing at -196°C, stirring at -78°C for 1 h; pumping at -126°C;	99%

: osmium tris(fluorosulfate)

: 201230-82-2
carbon monoxide

: 7783-70-2
antimony pentafluoride

: [Os(carbonyl)6](fluoroantimonate(V))2

Conditions

Conditions	Yield
In neat (no solvent) byproducts: CO2, S2O5F2, Sb2F9(SO3F); liquid SbF5, ca. 1 atm CO, 60-90°C, 2-4 d;	99%
With HF byproducts: CO2, S2O5F2, Sb2F9(SO3F); to the reactor charged with Os(SO3F)3 were added SbF5 and HF using a stainless steel vac. line, at -195°C CO was admitted to the reactor,heated to 50-60°C for 1-2 days without stirring; volatiles were removed in vac., crystals were washed with an SbF5/HF (2:1) mixt., volatiles were removed in vac.;	87%
heating at 60-90°C in 1 atm CO;

...Expand

Antimony(V) pentafluoride Consensus Reports

Reported in EPA TSCA Inventory. Antimony and its compounds are on the Community Right-To-Know List. EPA Extremely Hazardous Substances List.

Antimony(V) pentafluoride Standards and Recommendations

OSHA PEL: TWA 0.5 mg(Sb)/m³
ACGIH TLV: TWA 0.5 mg(Sb)/m³
NIOSH REL: (Antimony) TWA 0.5 mg(Sb)/m³
DOT Classification: 8; Label: Corrosive, Poison

Antimony(V) pentafluoride Specification

The Antimony(V) pentafluoride with the cas number7783-70-2, is also called (1) Antimony (V) fluoride ; (2) Antimony fluoride ; (3) Antimony fluoride (SbF5) ; (4) Antimony pentafluoride ; (5) Antimony(V) fluoride ; (6) Antimony(V) pentafluoride ; (7) Pentafluoroantimony . It belongs to the following Product Categories: (1)Inorganics; (2)Inorganic Fluorides; (3)Antimony Salts; (4)Metal and Ceramic Science; (5)Salts

The Antimony(V) pentafluoride is a colorless, oily liquid. It is quite toxic by inhalation, in contact with skin and if swallowed. Hence，when you are using this chmical, please wear suitable protective clothing, gloves and eye/face protection. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with plenty of soap-suds and take off immediately all contaminated clothing. If you feel unwell, seek medical advice immediately (show the label whenever possible.) Besides, It is toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment, so avoid release to the environment refering to special instructions / safety data sheets.

You can still convert the following datas into molecular structure :
1. [F-].[F-].[F-].[F-].[F-].[SbH3+3]
2. InChI=1/5FH.Sb.3H/h5*1H;;;;/q;;;;;+3;;;/p-5/r5FH.H3Sb/h5*1H;1H3/q;;;;;+3/p-5

The Antimony(V) pentafluoride toxic data can be showed in the following sheet.|

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
mouse	LC50	inhalation	270mg/m3 (270mg/m3)	LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES LIVER: OTHER CHANGES KIDNEY, URETER, AND BLADDER: OTHER CHANGES	Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 35(7), Pg. 25, 1970.

Product Name

ANTIMONY PENTAFLUORIDE

Synthetic route

Antimony(V) pentafluoride Consensus Reports

Antimony(V) pentafluoride Standards and Recommendations

Antimony(V) pentafluoride Specification

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