Product Name

  • Name

    L-Xylose

  • EINECS 210-174-1
  • CAS No. 609-06-3
  • Article Data48
  • CAS DataBase
  • Density 1.508 g/cm3
  • Solubility within almost transparency
  • Melting Point 150-152 °C(lit.)
  • Formula C5H10O5
  • Boiling Point 415.5 °C at 760 mmHg
  • Molecular Weight 150.131
  • Flash Point 219.2 °C
  • Transport Information
  • Appearance fine crystalline powder
  • Safety 24/25-36-26
  • Risk Codes 36/37/38
  • Molecular Structure Molecular Structure of 609-06-3 (L-Xylose)
  • Hazard Symbols IrritantXi
  • Synonyms Xylose, L-(8CI);NSC 26213;L(+)-Xylose;
  • PSA 97.99000
  • LogP -2.73970

Synthetic route

(2S,3R,4S)-5,5-Diethoxy-pentane-1,2,3,4-tetraol
124244-64-0

(2S,3R,4S)-5,5-Diethoxy-pentane-1,2,3,4-tetraol

L-xylose
609-06-3

L-xylose

Conditions
ConditionsYield
With hydrogenchloride In tetrahydrofuran95%
Tetra-O-acetyl-aldehydo-L-xylose
1195193-89-5

Tetra-O-acetyl-aldehydo-L-xylose

L-xylose
609-06-3

L-xylose

Conditions
ConditionsYield
With sodium ethanolate at 20 - 30℃;92%
L-arabinose
5328-37-0

L-arabinose

A

L-xylose
609-06-3

L-xylose

B

L-lyxose
1949-78-6

L-lyxose

C

L-ribose
24259-59-4

L-ribose

Conditions
ConditionsYield
With molybdenum(VI) oxide In water at 90℃; for 9h; Bilik reaction;A n/a
B n/a
C 19%
(2S,3S,4R)-5-hexene-1,2,3,4-tetrol
139404-79-8

(2S,3S,4R)-5-hexene-1,2,3,4-tetrol

L-xylose
609-06-3

L-xylose

Conditions
ConditionsYield
With ozone; sodium sulfite 1.) MeOH, -78 deg C, 2. a) -78 deg C, 1 h, b) r.t., 15 h; Yield given. Multistep reaction;
3,4,5,6-tetra-O-acetyl-1,2-dideoxy-L-xylo-hex-1-enitol
137491-74-8

3,4,5,6-tetra-O-acetyl-1,2-dideoxy-L-xylo-hex-1-enitol

L-xylose
609-06-3

L-xylose

Conditions
ConditionsYield
Yield given. Multistep reaction;
water
7732-18-5

water

ascorbic acid
50-81-7

ascorbic acid

A

furfural
98-01-1

furfural

B

L-xylose
609-06-3

L-xylose

C

carbon dioxide
124-38-9

carbon dioxide

O1,O3;O2,O4-diethylidene-D-glucitol

O1,O3;O2,O4-diethylidene-D-glucitol

L-xylose
609-06-3

L-xylose

Conditions
ConditionsYield
With lead(IV) acetate; acetic acid anschliessendes Erwaermen mit wss.Schwefelsaeure;
With lead(II,IV) oxide; acetic acid anschliessendes Behandeln mit wss.Schwefelsaeure,zuletz bei 100grad;
With sodium periodate anschliessendes Behandeln mit wss.Saeure;
O2,O4-benzylidene-D-glucitol

O2,O4-benzylidene-D-glucitol

L-xylose
609-06-3

L-xylose

Conditions
ConditionsYield
With lead(IV) acetate; acetic acid Erwaermen des Reaktionsprodukts mit wss.Essigsaeure;
With water; periodic acid Erwaermen des Reaktionsprodukts mit Essigsaeure;
O2,O4-furfurylidene-D-glucitol

O2,O4-furfurylidene-D-glucitol

L-xylose
609-06-3

L-xylose

Conditions
ConditionsYield
With lead(IV) acetate; ammonium hydroxide; acetic acid anschliessendes Erhitzen;
(S)-cyclohexylidene glyceraldehyde
78008-36-3, 92822-62-3, 99744-77-1

(S)-cyclohexylidene glyceraldehyde

polymer bonded 2-phenyl-1,3,2-dioxaborole

polymer bonded 2-phenyl-1,3,2-dioxaborole

A

L-xylose
609-06-3

L-xylose

B

L-lyxose
1949-78-6

L-lyxose

C

L-ribose
24259-59-4

L-ribose

D

L-arabinose
5328-37-0

L-arabinose

Conditions
ConditionsYield
In dichloromethane Ambient temperature; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
In dichloromethane Ambient temperature; Yield given. Yields of byproduct given;
(S)-cyclohexylidene glyceraldehyde
78008-36-3, 92822-62-3, 99744-77-1

(S)-cyclohexylidene glyceraldehyde

polymer bound 1,3,2-dioxaborole

polymer bound 1,3,2-dioxaborole

A

L-xylose
609-06-3

L-xylose

B

L-lyxose
1949-78-6

L-lyxose

C

L-ribose
24259-59-4

L-ribose

D

L-arabinose
5328-37-0

L-arabinose

Conditions
ConditionsYield
Yield given. Multistep reaction. Yields of byproduct given;
D-sorbitol
50-70-4

D-sorbitol

water
7732-18-5

water

manganese (IV)-oxide

manganese (IV)-oxide

A

D-Arabinose
10323-20-3

D-Arabinose

B

L-xylose
609-06-3

L-xylose

C

L-gulose
6027-89-0

L-gulose

D

D-glucose
50-99-7

D-glucose

Conditions
ConditionsYield
at 100℃;
dihydrogen peroxide
7722-84-1

dihydrogen peroxide

L-gulonic acid ; calcium compound
5743-42-0, 66905-23-5, 126259-97-0

L-gulonic acid ; calcium compound

ferriacetate

ferriacetate

L-xylose
609-06-3

L-xylose

2,3,4,5-tetra-O-tert-butyldimethylsilyl-L-xylose
405218-68-0

2,3,4,5-tetra-O-tert-butyldimethylsilyl-L-xylose

L-xylose
609-06-3

L-xylose

Conditions
ConditionsYield
With tetrabutyl ammonium fluoride In tetrahydrofuran at 0℃; for 2h;
1'-O-((E)-3-O-β-D-glucopyranosyl-caffeoyl) α-L-xylopyranosyl-(4''-2')-β-D-glucopyranoside

1'-O-((E)-3-O-β-D-glucopyranosyl-caffeoyl) α-L-xylopyranosyl-(4''-2')-β-D-glucopyranoside

A

L-xylose
609-06-3

L-xylose

B

D-glucose
50-99-7

D-glucose

C

caffeic acid
331-39-5

caffeic acid

Conditions
ConditionsYield
With hydrogenchloride at 90℃; for 0.5h;A n/a
B n/a
C 3.5 mg
5,6-di-O-isopropylidene-D-glucono-1,4-lactone
100227-29-0

5,6-di-O-isopropylidene-D-glucono-1,4-lactone

L-xylose
609-06-3

L-xylose

Conditions
ConditionsYield
Multi-step reaction with 6 steps
1: 92 percent / pyridine / dimethylformamide / 20 h / 20 °C
2: 100 percent / NaBH4 / tetrahydrofuran; H2O / 2 h / 20 °C
3: 90 percent / pyridine / dimethylformamide / 15 h / 24 °C
4: 92 percent / SnCl2 / CH2Cl2 / 0.5 h / 20 °C
5: 73 percent / Dess-Martin periodinane / CH2Cl2 / 10 h / 20 °C
6: TBAF / tetrahydrofuran / 2 h / 0 °C
View Scheme
Multi-step reaction with 6 steps
1: 92 percent / pyridine / dimethylformamide / 20 h / 20 °C
2: 100 percent / NaBH4 / tetrahydrofuran; H2O / 2 h / 20 °C
3: 90 percent / pyridine / dimethylformamide / 15 h / 24 °C
4: 70 percent / BCl3 / CH2Cl2 / 0.08 h / -78 °C
5: 73 percent / Dess-Martin periodinane / CH2Cl2 / 10 h / 20 °C
6: TBAF / tetrahydrofuran / 2 h / 0 °C
View Scheme
2,3-bis-O-(tert-butyldimethylsilyl)-5,6-O-isopropylidene-D-glucono-1,4-lactone
196494-81-2

2,3-bis-O-(tert-butyldimethylsilyl)-5,6-O-isopropylidene-D-glucono-1,4-lactone

L-xylose
609-06-3

L-xylose

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1: 100 percent / NaBH4 / tetrahydrofuran; H2O / 2 h / 20 °C
2: 90 percent / pyridine / dimethylformamide / 15 h / 24 °C
3: 92 percent / SnCl2 / CH2Cl2 / 0.5 h / 20 °C
4: 73 percent / Dess-Martin periodinane / CH2Cl2 / 10 h / 20 °C
5: TBAF / tetrahydrofuran / 2 h / 0 °C
View Scheme
Multi-step reaction with 5 steps
1: 100 percent / NaBH4 / tetrahydrofuran; H2O / 2 h / 20 °C
2: 90 percent / pyridine / dimethylformamide / 15 h / 24 °C
3: 70 percent / BCl3 / CH2Cl2 / 0.08 h / -78 °C
4: 73 percent / Dess-Martin periodinane / CH2Cl2 / 10 h / 20 °C
5: TBAF / tetrahydrofuran / 2 h / 0 °C
View Scheme
(1R,2S,3S)-2,3-Bis-(tert-butyl-dimethyl-silanyloxy)-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-butane-1,4-diol
280561-89-9

(1R,2S,3S)-2,3-Bis-(tert-butyl-dimethyl-silanyloxy)-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-butane-1,4-diol

L-xylose
609-06-3

L-xylose

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: 90 percent / pyridine / dimethylformamide / 15 h / 24 °C
2: 92 percent / SnCl2 / CH2Cl2 / 0.5 h / 20 °C
3: 73 percent / Dess-Martin periodinane / CH2Cl2 / 10 h / 20 °C
4: TBAF / tetrahydrofuran / 2 h / 0 °C
View Scheme
Multi-step reaction with 4 steps
1: 90 percent / pyridine / dimethylformamide / 15 h / 24 °C
2: 70 percent / BCl3 / CH2Cl2 / 0.08 h / -78 °C
3: 73 percent / Dess-Martin periodinane / CH2Cl2 / 10 h / 20 °C
4: TBAF / tetrahydrofuran / 2 h / 0 °C
View Scheme
(3S,4S)-5,5-Diethoxy-1,3,4-trihydroxy-pentan-2-one
124244-63-9

(3S,4S)-5,5-Diethoxy-1,3,4-trihydroxy-pentan-2-one

L-xylose
609-06-3

L-xylose

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 69 percent / L-iditol dehydrogenase, triosephosphate isomerase, formate dehydrogenase, sodium formate
2: 95 percent / 0.5 M aq. HCl / tetrahydrofuran
View Scheme
5,6-dideoxy-D-threo-hex-5-en-2-ulose
143106-69-8

5,6-dideoxy-D-threo-hex-5-en-2-ulose

L-xylose
609-06-3

L-xylose

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 61 percent / phosphate buffer (pH 7.0), sodium formate, NADH sodium salt / H2O / 72 h / Ambient temperature; sorbitol dehydrogenase (EC 1.1.1.14) from sheep liver, formate dehydrogenase (EC 1.2.1.2) from yeast
2: 1.) O3, 2.) Na2SO3 / 1.) MeOH, -78 deg C, 2. a) -78 deg C, 1 h, b) r.t., 15 h
View Scheme
sodium gluconate
6027-87-8

sodium gluconate

L-xylose
609-06-3

L-xylose

Conditions
ConditionsYield
With methanol; water Product distribution / selectivity; Electrochemical reaction;
L-gulono-1,4-lactone
1128-23-0

L-gulono-1,4-lactone

L-xylose
609-06-3

L-xylose

Conditions
ConditionsYield
With dihydrogen peroxide; Fe2(SO4)3
XYLITOL
87-99-0

XYLITOL

L-xylose
609-06-3

L-xylose

Conditions
ConditionsYield
With recombinant alditol oxidase from Streptomyces coelicolor A3(2); catalase from bovine liver at 20℃; for 4h; pH=7.5; Kinetics; Reagent/catalyst; Temperature; pH-value; aq. phosphate buffer; Enzymatic reaction; regioselective reaction;
With sulfuric acid; quinolinium dichromate(VI) In water at 19.84℃; Kinetics; Mechanism; Temperature; Reagent/catalyst;
2α,3β-dihydroxy-5α-pregn-16-en-20-one-3-O-{β-D-glucopyranosyl-(1→2)-[β-D-xylopyranosyl-(1→3)]-β-D-glucopyranosyl-(1→4)-β-D-galactopyranoside}

2α,3β-dihydroxy-5α-pregn-16-en-20-one-3-O-{β-D-glucopyranosyl-(1→2)-[β-D-xylopyranosyl-(1→3)]-β-D-glucopyranosyl-(1→4)-β-D-galactopyranoside}

A

L-xylose
609-06-3

L-xylose

B

D-glucose
50-99-7

D-glucose

C

D-Galactose
59-23-4

D-Galactose

D

2α,3β-dihydroxy-5α-pregna-16-en-20-one

2α,3β-dihydroxy-5α-pregna-16-en-20-one

Conditions
ConditionsYield
With hydrogenchloride; water In 1,4-dioxane at 100℃; for 2h;A n/a
B n/a
C n/a
D 2.4 mg
3-O-[β-D-glucopyranosyl-(1→2)-β-D-glucopyranosyl-(1→4)-β-D-xylopyranosyl]-2β,3β,16α-trihydroxyolean-12-en-23,28-dioic acid-28-O-α-L-rhamnopyranosyl-(1→4)-α-L-rhamnopyranosyl-(1→2)-β-D-glucopyranosyl-(1→2)-α-L-arabinopyranoside

3-O-[β-D-glucopyranosyl-(1→2)-β-D-glucopyranosyl-(1→4)-β-D-xylopyranosyl]-2β,3β,16α-trihydroxyolean-12-en-23,28-dioic acid-28-O-α-L-rhamnopyranosyl-(1→4)-α-L-rhamnopyranosyl-(1→2)-β-D-glucopyranosyl-(1→2)-α-L-arabinopyranoside

A

L-xylose
609-06-3

L-xylose

B

L-arabinose
5328-37-0

L-arabinose

C

D-quionovose
7658-08-4

D-quionovose

D

D-glucose
50-99-7

D-glucose

Conditions
ConditionsYield
With hydrogenchloride; water for 4h; Reflux;
acid polysaccharide from Boletus edulis

acid polysaccharide from Boletus edulis

A

D-Mannose
3458-28-4

D-Mannose

B

L-xylose
609-06-3

L-xylose

C

D-glucose
50-99-7

D-glucose

D

D-Galactose
59-23-4

D-Galactose

E

D-Glucuronic acid
6556-12-3

D-Glucuronic acid

F

D-galacturonic acid
685-73-4

D-galacturonic acid

Conditions
ConditionsYield
With water; trifluoroacetic acid at 110℃; for 3h;
L-xylose
609-06-3

L-xylose

XYLITOL
87-99-0

XYLITOL

Conditions
ConditionsYield
With hydrogen In water at 150℃; under 37503.8 Torr; for 2h; Catalytic behavior; Solvent; Concentration; Reagent/catalyst; Temperature; Pressure; Sealed tube;98%
With sodium amalgam
With hydrogen; nickel In methanol; ethanol; water at 50℃; under 760.051 Torr; Product distribution / selectivity;
With Ru/TiO2; hydrogen In water at 120℃; under 15001.5 Torr; Temperature; Time; Autoclave;
methanol
67-56-1

methanol

L-xylose
609-06-3

L-xylose

(2S,3S,4S)-2-(hydroxymethyl)-5-methoxyoxolane-3,4-diol
13039-67-3

(2S,3S,4S)-2-(hydroxymethyl)-5-methoxyoxolane-3,4-diol

Conditions
ConditionsYield
With hydrogenchloride95%
With hydrogenchloride at 5 - 10℃;
With hydrogenchloride Reflux;
With sulfuric acid at 20℃; for 5h;
Stage #1: methanol; L-xylose With hydrogenchloride at 55℃; for 21h;
Stage #2: With silver carbonate In methanol at 25℃; for 0.5h;
L-xylose
609-06-3

L-xylose

acetone
67-64-1

acetone

(3aS,3bR,7aS,8aS)-2,2,5,5-tetramethyltetrahydro-3aH-[1,3]dioxolo[4',5':4,5]furo[3,2-d][1,3]dioxane
131156-47-3

(3aS,3bR,7aS,8aS)-2,2,5,5-tetramethyltetrahydro-3aH-[1,3]dioxolo[4',5':4,5]furo[3,2-d][1,3]dioxane

Conditions
ConditionsYield
With malonic acid; choline chloride for 0.666667h; Inert atmosphere; Reflux;95%
With sulfuric acid; copper(II) sulfate at 25℃; for 24h;86%
With sulfuric acid; magnesium sulfate at 20 - 30℃; for 12h;84.3%
L-xylose
609-06-3

L-xylose

ethylamine
75-04-7

ethylamine

N-ethyl-β-L-arabinopyranosylamine
93253-22-6

N-ethyl-β-L-arabinopyranosylamine

Conditions
ConditionsYield
In ethanol93%
L-xylose
609-06-3

L-xylose

trans-2-phenylvinylboronic acid
6783-05-7

trans-2-phenylvinylboronic acid

1-amino-2-propene
107-11-9

1-amino-2-propene

(6E)-5-(allylamino)-5,6,7-trideoxy-7-phenyl-D-gluco-hept-6-enitol
691905-77-8

(6E)-5-(allylamino)-5,6,7-trideoxy-7-phenyl-D-gluco-hept-6-enitol

Conditions
ConditionsYield
In ethanol at 20℃; for 72h;92%
In ethanol at 20℃; for 16h; Petasis reaction;73%
L-xylose
609-06-3

L-xylose

phenylhydrazine
100-63-0

phenylhydrazine

D-xylose phenylhydrazone

D-xylose phenylhydrazone

Conditions
ConditionsYield
89%
propylamine
107-10-8

propylamine

L-xylose
609-06-3

L-xylose

N-propyl-β-L-arabinopyranosylamine
93303-81-2

N-propyl-β-L-arabinopyranosylamine

Conditions
ConditionsYield
In methanol88%
L-xylose
609-06-3

L-xylose

acetone
67-64-1

acetone

1,2-O-isopropylidene-α-L-xylofuranose
114861-22-2

1,2-O-isopropylidene-α-L-xylofuranose

Conditions
ConditionsYield
Stage #1: L-xylose; acetone With sulfuric acid; magnesium sulfate at 20 - 24℃; for 17.25h; Industry scale;
Stage #2: With hydrogenchloride In water at 20℃; for 6h; pH=2;
86%
Stage #1: L-xylose; acetone With magnesium sulphate; sulfuric acid at 20 - 24℃; for 17.25h;
Stage #2: With hydrogenchloride In water at 20℃; for 6h; pH=2;
86%
With hydrogenchloride; sulfuric acid; copper(II) sulfate Yield given. Multistep reaction;
Stage #1: L-xylose; acetone With sulfuric acid; copper(II) sulfate at 20℃; for 24h;
Stage #2: With hydrogenchloride at 20℃; for 1h; Further stages.;
Stage #1: L-xylose; acetone With sulfuric acid; copper(II) sulfate
Stage #2: With hydrogenchloride; water
L-xylose
609-06-3

L-xylose

Isopropyl acetate
108-21-4

Isopropyl acetate

(3aS,5R,6S,6aS)-5-hydroxymethyl-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxolane-6-ol
1352955-16-8

(3aS,5R,6S,6aS)-5-hydroxymethyl-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxolane-6-ol

Conditions
ConditionsYield
Stage #1: L-xylose With sulfuric acid; magnesium sulfate In acetone at 20 - 30℃;
Stage #2: With hydrogenchloride In water at 20 - 30℃; for 8h; pH=2-3;
Stage #3: Isopropyl acetate In water at 0 - 5℃; for 3h;
84.2%
L-xylose
609-06-3

L-xylose

ethanethiol
75-08-1

ethanethiol

L-xylose diethyl dithioacetal
23259-79-2

L-xylose diethyl dithioacetal

Conditions
ConditionsYield
With dimethylbromosulphonium bromide at 0 - 5℃; for 0.583333h; neat (no solvent);83%
With hydrogenchloride
With hydrogenchloride
With hydrogenchloride for 0.25h; Ambient temperature;
L-xylose
609-06-3

L-xylose

benzyl acetoacetate
5396-89-4

benzyl acetoacetate

benzyl 2-methyl-5-(L-threo-1,2,3-trihydroxyprop-1-yl)furan-3-carboxylate

benzyl 2-methyl-5-(L-threo-1,2,3-trihydroxyprop-1-yl)furan-3-carboxylate

Conditions
ConditionsYield
Stage #1: L-xylose With cerium(III) chloride heptahydrate; silica gel; sodium iodide In acetonitrile for 1h;
Stage #2: benzyl acetoacetate In acetonitrile at 50℃; for 24h;
77%
L-xylose
609-06-3

L-xylose

2-{5-[5-C-(1,4-anhydro-β-D-erythrotetrofuranosyl)-2-methylfuran-3-yl]-1,3,4-oxadiazol-2-ylthio}acetohydrazide
1338470-77-1

2-{5-[5-C-(1,4-anhydro-β-D-erythrotetrofuranosyl)-2-methylfuran-3-yl]-1,3,4-oxadiazol-2-ylthio}acetohydrazide

D-xylose 2-{5-[5-(1,4-anhydro-β-D-erythrotetrofuranosyl)-2-methylfuran-3-yl]-1,3,4-oxadiazol-2-ylthio}acetohydrazone

D-xylose 2-{5-[5-(1,4-anhydro-β-D-erythrotetrofuranosyl)-2-methylfuran-3-yl]-1,3,4-oxadiazol-2-ylthio}acetohydrazone

Conditions
ConditionsYield
With acetic acid In ethanol; water Reflux;74%
L-xylose
609-06-3

L-xylose

(R)-tert-butyl (3-(3,5-diamino-6-chloropyrazine-2-carboxamido)-2-(2-methylbenzyl)propyl)(4-((2-(hexylamino)ethyl)carbamoyl)benzyl)carbamate

(R)-tert-butyl (3-(3,5-diamino-6-chloropyrazine-2-carboxamido)-2-(2-methylbenzyl)propyl)(4-((2-(hexylamino)ethyl)carbamoyl)benzyl)carbamate

tert-butyl ((R)-3-(3,5-diamino-6-chloropyrazine-2-carboxamido)-2-(2-methylbenzyl)propyl)(4-((2-(hexyl((2R,3S,4S)-2,3,4,5-tetrahydroxypentyl)amino)ethyl)carbamoyl)benzyl)carbamate

tert-butyl ((R)-3-(3,5-diamino-6-chloropyrazine-2-carboxamido)-2-(2-methylbenzyl)propyl)(4-((2-(hexyl((2R,3S,4S)-2,3,4,5-tetrahydroxypentyl)amino)ethyl)carbamoyl)benzyl)carbamate

Conditions
ConditionsYield
Stage #1: L-xylose; (R)-tert-butyl (3-(3,5-diamino-6-chloropyrazine-2-carboxamido)-2-(2-methylbenzyl)propyl)(4-((2-(hexylamino)ethyl)carbamoyl)benzyl)carbamate With N-ethyl-N,N-diisopropylamine In methanol at 20℃; for 1h;
Stage #2: With sodium cyanoborohydride; acetic acid In methanol at 50℃; for 20h;
69.7%
L-xylose
609-06-3

L-xylose

cyclohexanone
108-94-1

cyclohexanone

C17H26O5

C17H26O5

Conditions
ConditionsYield
With sulfuric acid at 0 - 30℃; Inert atmosphere;64.6%
L-xylose
609-06-3

L-xylose

trityl chloride
76-83-5

trityl chloride

5-O-trityl-L-xylono-γ-lactone
868159-65-3

5-O-trityl-L-xylono-γ-lactone

Conditions
ConditionsYield
Stage #1: L-xylose With bromine; potassium carbonate In water at 0 - 20℃;
Stage #2: trityl chloride With pyridine; dmap Heating;
63%
L-xylose
609-06-3

L-xylose

ethylamine
75-04-7

ethylamine

hydrogen cyanide

hydrogen cyanide

2-deoxy-2-(ethylamino)-L-glucononitrile
93253-24-8

2-deoxy-2-(ethylamino)-L-glucononitrile

Conditions
ConditionsYield
In ethanol Ambient temperature;61%
L-xylose
609-06-3

L-xylose

A

Tetrahydrofurfuryl alcohol
97-99-4

Tetrahydrofurfuryl alcohol

B

XYLITOL
87-99-0

XYLITOL

Conditions
ConditionsYield
With 1% Pd on activated carbon; hydrogen In water at 140℃; under 37503.8 Torr; for 2h; Reagent/catalyst; Sealed tube;A n/a
B 58%
L-xylose
609-06-3

L-xylose

ethyl 4-benzyloxyacetoacetate
67354-34-1

ethyl 4-benzyloxyacetoacetate

ethyl 2-methyl-5-(L-threo-1,2,3-trihydroxyprop-1-yl)furan-3-carboxylate
1581292-10-5

ethyl 2-methyl-5-(L-threo-1,2,3-trihydroxyprop-1-yl)furan-3-carboxylate

Conditions
ConditionsYield
Stage #1: L-xylose With cerium(III) chloride heptahydrate; silica gel; sodium iodide In acetonitrile for 1h;
Stage #2: ethyl 4-benzyloxyacetoacetate In acetonitrile at 50℃; for 24h;
50%
L-xylose
609-06-3

L-xylose

benzaldehyde
100-52-7

benzaldehyde

(2R,4aS,7S,7aS)-7-hydroxy-2-phenyltetrahydro-6H-furo[3,2-d][1,3]dioxin-6-one

(2R,4aS,7S,7aS)-7-hydroxy-2-phenyltetrahydro-6H-furo[3,2-d][1,3]dioxin-6-one

Conditions
ConditionsYield
Stage #1: L-xylose With bromine; potassium carbonate In water at 0 - 20℃; for 2h;
Stage #2: benzaldehyde With sulfuric acid In tetrahydrofuran at 0 - 20℃;
49%
L-xylose
609-06-3

L-xylose

4-hydroxy-3-(3-(methoxyamino)-1-phenylbutyl)-2H-1-benzopyran-2-one
1101852-85-0

4-hydroxy-3-(3-(methoxyamino)-1-phenylbutyl)-2H-1-benzopyran-2-one

C25H29NO8
1207170-43-1

C25H29NO8

Conditions
ConditionsYield
With acetic acid In N,N-dimethyl-formamide at 50℃;45%
L-xylose
609-06-3

L-xylose

L-xylosone
3445-23-6

L-xylosone

Conditions
ConditionsYield
With copper diacetate In methanol; water Reflux;40%
With methanol; copper diacetate
With copper diacetate In methanol for 0.166667h; Heating;
propylamine
107-10-8

propylamine

L-xylose
609-06-3

L-xylose

hydrogen cyanide

hydrogen cyanide

2-deoxy-2-(propylamino)-L-glucononitrile
93253-26-0

2-deoxy-2-(propylamino)-L-glucononitrile

Conditions
ConditionsYield
In ethanol at 0℃;32%
L-xylose
609-06-3

L-xylose

(3S)-O-(N-methoxyglycyl)betulinic acid
1101863-07-3

(3S)-O-(N-methoxyglycyl)betulinic acid

(3S)-O-(N-methoxy-N-β-L-xylosylglycyl)betulinic acid
1101863-47-1

(3S)-O-(N-methoxy-N-β-L-xylosylglycyl)betulinic acid

Conditions
ConditionsYield
In methanol; dichloromethane at 40℃; for 48h;27%
L-xylose
609-06-3

L-xylose

thiophenol
108-98-5

thiophenol

(2S,3R,4S)-5,5-bis(phenylthio)pentane-1,2,3,4-tetraol

(2S,3R,4S)-5,5-bis(phenylthio)pentane-1,2,3,4-tetraol

Conditions
ConditionsYield
With trifluoroacetic acid In water at 50 - 60℃; for 12h;20%
L-xylose
609-06-3

L-xylose

cyclopentanone
120-92-3

cyclopentanone

C15H22O5
189949-14-2

C15H22O5

Conditions
ConditionsYield
With sulfuric acid at 5 - 30℃; Inert atmosphere;16.7%
hydrogen cyanide
74-90-8

hydrogen cyanide

L-xylose
609-06-3

L-xylose

D-gulono-1,4-lactone
6322-07-2

D-gulono-1,4-lactone

L-(-)-Xylose Specification

The CAS registry number of L-(-)-Xylose is 609-06-3. The systematic name is L-xylose. Its EINECS registry number is 210-174-1. In addition, the molecular formula is C5H10O5 and the molecular weight is 150.13. It is a kind of white fine crystalline powder and belongs to the classes of Carbohydrate; Basic Sugars (Mono & Oligosaccharides); Biochemistry; Sugars; Xylose; Carbohydrate Sources (Sugars/Extracts); MonosaccharidesBase Ingredients; Sugars for Media; Carbohydrate Synthesis; Specialty Synthesis; Monosaccharides.

Physical properties about this chemical are: (1)ACD/LogP: -2.39; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): -2.39; (4)ACD/LogD (pH 7.4): -2.39; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)ACD/KOC (pH 5.5): 1.19; (8)ACD/KOC (pH 7.4): 1.19; (9)#H bond acceptors: 5; (10)#H bond donors: 4; (11)#Freely Rotating Bonds: 8; (12)Polar Surface Area: 53.99 Å2; (13)Index of Refraction: 1.543; (14)Molar Refractivity: 31.41 cm3; (15)Molar Volume: 99.5 cm3; (16)Polarizability: 12.45 ×10-24cm3; (17)Surface Tension: 81.4 dyne/cm; (18)Density: 1.508 g/cm3; (19)Flash Point: 219.2 °C; (20)Enthalpy of Vaporization: 77.23 kJ/mol; (21)Boiling Point: 415.5 °C at 760 mmHg; (22)Vapour Pressure: 1.22E-08 mmHg at 25°C.

Preparation of L-(-)-Xylose: it can be prepared by 5,5-diethoxy-pentane-1,2,3,4-tetraol. This reaction will need reagent 0.5 M aq. HCl and solvent tetrahydrofuran. The yield is about 95%.

L-(-)-Xylose can be prepared by 5,5-diethoxy-pentane-1,2,3,4-tetraol

Uses of L-(-)-Xylose: it can react with propylamine to get N-propyl-b-L-arabinopyranosylamine. This reaction will need solvent methanol. The yield is about 88%.

L-(-)-Xylose can react with propylamine to get N-propyl-b-L-arabinopyranosylamine

When you are using this chemical, please be cautious about it as the following:
This chemical is irritating to eyes, respiratory system and skin. During using it, wear suitable protective clothing and avoid contact with skin and eyes. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

You can still convert the following datas into molecular structure:
(1)SMILES: O=C[C@H](O)[C@@H](O)[C@H](O)CO
(2)InChI: InChI=1/C5H10O5/c6-1-3(8)5(10)4(9)2-7/h1,3-5,7-10H,2H2/t3-,4+,5+/m0/s1
(3)InChIKey: PYMYPHUHKUWMLA-VPENINKCBR

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