Conditions | Yield |
---|---|
With H nitrate, in dild. soln., is completely reacting with Pd, satd. with H, at 16 °C in 24 hours to Ag and HNO3;; | A 100% B 100% |
With H |
2-(salicylideneamino)thiophenol
B
(OC6H4CHNC6H4S)Ce(NO3)2(H2O)
C
nitric acid
Conditions | Yield |
---|---|
With ammonium hydroxide In ethanol; water addn. of hot soln. of Schiff base in EtOH to soln. of Ce salt in EtOH (ratio 1 : 1), addn. of H2O and EtOH (to 85% EtOH), pH adjusting to 5.0 - 6.0 (NH4OH), refluxing (2 h), concn. (vac.), crystn. on cooling (over night); filtration, washing (EtOH), recrystn. (hot DMF/EtOH), washing (EtOH, Et2O), drying (vac.); elem. anal.; | A n/a B 90% C n/a |
aluminum oxide
sodium nitrate
A
sodium aluminate
B
nitric acid
Conditions | Yield |
---|---|
heating; it attacks vessel of iron or platinum and glass or china; | A n/a B 89% |
isoquinoline
malonic acid
dihydrogen peroxide
A
UO(O2)(CH2(COO)2)(C9H7N)2
B
nitric acid
Conditions | Yield |
---|---|
In ethanol; water addn. of org. acid in EtOH to aq. soln. of metal salt, cooling, addn. ofsoln. of isoquinoline in EtOH, addn. of aq. H2O2 (30 %), stirring (30 m in; pptn.); filtration, washing (water, EtOH), purification by TLC, drying (vac., over silica gel); elem. anal.; | A 79% B n/a |
Conditions | Yield |
---|---|
In ethanol; water addn. of org. acid in EtOH to aq. soln. of metal salt, cooling, addn. ofsoln. of quinoline in EtOH, addn. of aq. H2O2 (30 %), stirring (30 min; pptn.); filtration, washing (water, EtOH), purification by TLC, drying (vac., over silica gel); elem. anal.; | A 76% B n/a |
Conditions | Yield |
---|---|
In ethanol; water addn. of org. acid in EtOH to aq. soln. of metal salt, cooling, addn. ofsoln. of isoquinoline in EtOH, addn. of aq. H2O2 (30 %), stirring (30 m in; pptn.); filtration, washing (water, EtOH), purification by TLC, drying (vac., over silica gel); elem. anal.; | A 72% B n/a |
quinoline
malonic acid
dihydrogen peroxide
A
Zr(O2)(CH2(COO)2)(C9H7N)2
B
nitric acid
Conditions | Yield |
---|---|
In ethanol; water addn. of org. acid in EtOH to aq. soln. of metal salt, cooling, addn. ofsoln. of quinoline in EtOH, addn. of aq. H2O2 (30 %), stirring (30 min; pptn.); filtration, washing (water, EtOH), purification by TLC, drying (vac., over silica gel); elem. anal.; | A 72% B n/a |
quinoline
malonic acid
dihydrogen peroxide
A
UO(O2)(CH2(COO)2)(C9H7N)2
B
nitric acid
Conditions | Yield |
---|---|
In ethanol; water addn. of org. acid in EtOH to aq. soln. of metal salt, cooling, addn. ofsoln. of quinoline in EtOH, addn. of aq. H2O2 (30 %), stirring (30 min; pptn.); filtration, washing (water, EtOH), purification by TLC, drying (vac., over silica gel); elem. anal.; | A 70% B n/a |
isoquinoline
malonic acid
dihydrogen peroxide
A
Zr(O2)(CH2(COO)2)(C9H7N)2
B
nitric acid
Conditions | Yield |
---|---|
In ethanol; water addn. of org. acid in EtOH to aq. soln. of metal salt, cooling, addn. ofsoln. of isoquinoline in EtOH, addn. of aq. H2O2 (30 %), stirring (30 m in; pptn.); filtration, washing (water, EtOH), purification by TLC, drying (vac., over silica gel); elem. anal.; | A 70% B n/a |
Conditions | Yield |
---|---|
In ethanol; water addn. of org. acid in EtOH to aq. soln. of metal salt, cooling, addn. ofsoln. of isoquinoline in EtOH, addn. of aq. H2O2 (30 %), stirring (30 m in; pptn.); filtration, washing (water, EtOH), purification by TLC, drying (vac., over silica gel); elem. anal.; | A 68% B n/a |
Conditions | Yield |
---|---|
In ethanol; water addn. of org. acid in EtOH to aq. soln. of metal salt, cooling, addn. ofsoln. of quinoline in EtOH, addn. of aq. H2O2 (30 %), stirring (30 min; pptn.); filtration, washing (water, EtOH), purification by TLC, drying (vac., over silica gel); elem. anal.; | A 67% B n/a |
1,1,1-trifluoro-4-(2-thienyl)butane-2,4-dione
1,4,10,13-tetraoxa-7,16-diazacyclooctadecane
B
nitric acid
Conditions | Yield |
---|---|
In water; toluene dropwise addn. of soln. of Eu-salt in H2O to soln. of macrocycle and diketone (stirring), sepd. of org. phase after 30 min, pptn. on addn. of cyclohexane to org. phase; collection, recrystn. (toluene/cyclohexane 1/1), drying (over P2O5, vac., 5 h); elem. anal.; | A 62% B n/a |
Conditions | Yield |
---|---|
With oxygen NH3-air mixture,at gently red heat; | 60% |
With oxygen; Sr(2+)*PbO3(2-)*Sr(2+)*MnO4(2-)=SrPbO3*SrMnO4 byproducts: nitrogen oxides; above 500 °C,NH3-air mixture,overall yield:from 90%; | |
With oxygen; Ba(2+)*PbO3(2-)*Ba(2+)*MnO4(2-)=BaPbO3*BaMnO4 byproducts: nitrogen oxides; above 500 °C,NH3-air mixture,overall yield:from 90%; |
Conditions | Yield |
---|---|
at 4 - 20℃; pH=2.5; | A 56% B n/a C n/a |
hydrogenchloride
dinitrogen pentoxide
A
nitric acid
B
chlorine
Conditions | Yield |
---|---|
In neat (no solvent) at 213 K; purified from N2O5 and nitric acid by distillation at 213 K; | A n/a B 2% C n/a |
Conditions | Yield |
---|---|
at 0℃; Rate constant; in festen und fluessigen H2SO4-H2O-Gemischen <84.5-86.4%ig>.Hydrolysis; |
nitro-tetrahydropyrimidin-2-ylidene-amine
sulfuric acid
acetic acid
nitric acid
Conditions | Yield |
---|---|
at 25℃; Rate constant; |
Conditions | Yield |
---|---|
at 25℃; Rate constant; |
water
(4-methyl-4,5-dihydro-1(3)H-imidazol-2-yl)-nitro-amine
nitric acid
Conditions | Yield |
---|---|
at 25℃; Rate constant; Hydrolysis; |
Conditions | Yield |
---|---|
at 25℃; Rate constant; Hydrolysis; |
water
(4-methyl-4,5-dihydro-1(3)H-imidazol-2-yl)-nitro-amine
nitric acid
Conditions | Yield |
---|---|
at 0℃; Rate constant; in festen und fluessigen Gemischen <84.5%ig>.Hydrolysis; |
Conditions | Yield |
---|---|
at 25℃; Rate constant; |
Conditions | Yield |
---|---|
With sodium nitrite |
A
methyl-imidazolidinetrione-5-oxime
B
nitric acid
Conditions | Yield |
---|---|
With sodium nitrite |
water
2,4,6-Trinitrophenol
A
hydrogen cyanide
B
carbon dioxide
C
nitric acid
Conditions | Yield |
---|---|
at 70 - 80℃; es erfolgt Oxidation; |
5-chloro-4-[cyclohexyl-(2,2,2-trifluoroacetyl)amino]-2-methoxybenzoic acid methyl ester
nitric acid
5-chloro-4-[cyclohexyl-(2,2,2-trifluoroacetyl)amino]-2-methoxy-3-nitrobenzoic acid methyl ester
Conditions | Yield |
---|---|
Stage #1: 5-chloro-4-[cyclohexyl-(2,2,2-trifluoroacetyl)amino]-2-methoxybenzoic acid methyl ester; nitric acid at -40 - -20℃; for 2h; Stage #2: With sodium hydroxide In water | 100% |
Conditions | Yield |
---|---|
at 80℃; | 100% |
In nitric acid aq. HNO3; dissolving metal oxide in concd. HNO3, heating; evapn. on water bath, dissolving in water; | |
In nitric acid aq. HNO3; by treating the metal oxide with dil. HNO3; the soln. was evapd. on a steam bath; the residue was dissolved in water, conced. to a viscous mass, cooled and kept in a desiccator after breaking up any lumps; |
Conditions | Yield |
---|---|
at 80℃; | 100% |
In nitric acid aq. HNO3; Eu2O3 treated with concd. HNO3; excess HNO3 evapd.; | |
In nitric acid aq. HNO3; dissolving metal oxide in concd. HNO3, heating; evapn. on water bath, dissolving in water; |
Conditions | Yield |
---|---|
at 80℃; | 100% |
In water react. metal oxide with 6N HNO3; evapn. at 100°C; | |
In nitric acid aq. HNO3; by treating the metal oxide with dil. HNO3; the soln. was evapd. on a steam bath; the residue was dissolved in water, conced. to a viscous mass, cooled and kept in a desiccator after breaking up any lumps; | |
In nitric acid aq. HNO3; dissolving of Y2O3 in excess amt. of aq. nitric acid; |
Conditions | Yield |
---|---|
In water Electrolysis; Cu-cathode, in presence of H2SO4;; | 100% |
With aluminium In water at elevated pressure;; | 0% |
With aluminium In water only small amounts of NH3 in dild. HNO3 (5%-20%) at atmospheric pressure;; |
Conditions | Yield |
---|---|
With sulfur trioxide pyridine complex at 25 - 100℃; for 180h; Sealed tube; | 100% |
In nitric acid in presence of air; | |
In nitric acid byproducts: N-oxide; by heating; in presence of air; |
Conditions | Yield |
---|---|
at 80℃; | 100% |
Conditions | Yield |
---|---|
In nitric acid aq. HNO3; PbWO4 dissolved in aq. HNO3 (10 wt %) at 75°C; isothermal holdingtime was 2 h; ppt. filtered off; washed (aq. HNO3); calcined at 700°C (WO3 was obtained); to filtrate contg. Pb(NO3)2 added aq. NH4OH with stirring; final pH was 8.9; ppt. diltered off; dried; calcined at 800°C; | A 99.9% B 93.6% |
Conditions | Yield |
---|---|
In water byproducts: NO2; Sb powder was covered with concd. nitric acid, heated under an open hood and over a bunsen burner flame, solid was filtered, washed with water,left to dry, heated in open beaker over a bunsen burner flame; | 99.729% |
Conditions | Yield |
---|---|
In water byproducts: oxalic acid; between 15 and 65°C;; pure NaNO3;; | 99% |
Conditions | Yield |
---|---|
In nitric acid byproducts: H2SO4, NO, CO; stirring for 0.5 h at 25°C; condensing silane in a trap cooled with solid CO2, treating aq. layer with NaOH, evapn. to dryness, IR; | A n/a B 99% |
Conditions | Yield |
---|---|
In further solvent(s) the mixt. of NaBiO3 and Am(3+) in 0.1 M nitric acid was agitated at roomtemp.; detected by UV spectra and γ-ray spectroscopy; | 99% |
Conditions | Yield |
---|---|
In further solvent(s) the mixt. of NaBiO3 and Am(3+) in 0.1 M nitric acid was heated at 80°C; detected by UV spectra and γ-ray spectroscopy; | 99% |
Conditions | Yield |
---|---|
In water High Pressure; Bi(NO3)3, HIO3, HNO3 were heated in autoclave to 200°C, held for 1 week, cooled slowly, 6°C/h, to room temp.; filtered, washed with distilled water; | 99% |
Conditions | Yield |
---|---|
With water; ammonium carbonate In nitric acid solution of Bi in HNO3 (36 Be); vigorous reaction, repeated addition of H2O;; filtration through an asbestos filter and evaporation of the filtrate; crystallisation and washing with H2O (containing a small amount of HNO3); drying at 25°C; addition of (NH4)2CO3 to the end liquors and formation of Bi nitrate with HNO3;; | 98% |
With H2O; (NH4)2CO3 In nitric acid solution of Bi in HNO3 (36 Be); vigorous reaction, repeated addition of H2O;; filtration through an asbestos filter and evaporation of the filtrate; crystallisation and washing with H2O (containing a small amount of HNO3); drying at 25°C; addition of (NH4)2CO3 to the end liquors and formation of Bi nitrate with HNO3;; | 98% |
With water; oxygen In nitric acid byproducts: N oxides; addition of warm Bi grains under reflux to HNO3 and O2; absorption of the formed N oxides after oxidation in H2O and returning back to the reaction mixture;; |
sulfolane
1,2,3,5-tetrafluoro-4-nitrobenzene
nitric acid
2,4,5,6-Tetrafluoro-1,3-dinitrobenzene
Conditions | Yield |
---|---|
With boron trifluoride at 65-70°C 7 d; | 98% |
With BF3 at 65-70°C 7 d; | 98% |
Conditions | Yield |
---|---|
Stage #1: barium(II) nitrate; 4C12H28N(1+)*4H2O*V4O12(4-); dimethyl sulfoxide at 70℃; for 4h; Stage #2: nitric acid at 20℃; for 2h; | 98% |
Conditions | Yield |
---|---|
In benzene-d6 at 20℃; for 0.0833333h; Glovebox; | 98% |
Conditions | Yield |
---|---|
In water HNO3 added to Nd/H(+)=2, Tl salt added dropwise at 25°C with vigorous stirring, kept for 24 h; ppt. filtered, washed (cold water), dried air; elem. anal.; | 97.78% |
EPA Extremely Hazardous Substances List. Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. Community Right-To-Know List.
OSHA PEL: TWA 2 ppm; STEL 4 ppm
ACGIH TLV: TWA 2 ppm; STEL 4 ppm
DFG MAK: 2 ppm (5.2 mg/m3)
NIOSH REL: (Nitric Acid) TWA 2 ppm
DOT Classification: 8; Label: Corrosive, Oxidizer, Poison
For occupational chemical analysis use OSHA: #ID-127 or NIOSH: Acids, Inorganic, 7903.
Nitric acid(CAS NO.7697-37-2) is a colorless, highly corrosive liquid and a very powerful oxidizing agent that in the highly pure state is not entirely stable and must be prepared from its azeotrope by distillation with concentrated sulfuric acid. Nitric acid gradually yellows because of decomposition to nitrogen dioxide. Solutions containing more than 80% nitric acid are called fuming nitric acids. It also can be called Acide nitrique; Acido nitrico; Acidum nitricum; Aqua fortis; Azotic acid; Azotowy kwas; Engraver's acid; Hydrogen nitrate; Kyselina dusicne; Nital; Nitric acid; Nitrous fumes; Nitryl hydroxide; Red fuming nitric acid; Salpetersaeure; Salpetersaure; Salpeterzuuroplossingen; UNII-411VRN1TV4.
Physical properties about Nitric acid are: (1)ACD/LogP: -0.773; (2)ACD/LogD (pH 5.5): -0.77; (3)ACD/LogD (pH 7.4): -0.77; (4)ACD/BCF (pH 5.5): 1.00 ; (5)ACD/BCF (pH 7.4): 1.00; (6)#H bond acceptors:4 ; (7)#H bond donors: 1; (8)Index of Refraction: 1.409; (9)Molar Refractivity: 9.606 cm3; (10)Molar Volume: 38.82 cm3; (11)Polarizability: 3.808 10-24cm3; (12)Surface Tension: 58.6520004272461 dyne/cm; (13)Density: 1.623 g/cm3 ; (14)Enthalpy of Vaporization: 37.722 kJ/mol; (15)Boiling Point: 83 °C at 760 mmHg; (16)Vapour Pressure: 49.8279991149902 mmHg at 25°C
Preparation of Nitric acid:
Nitric acid is made by reacting nitrogen dioxide (NO2) with water.
3 NO2 + H2O → 2 HNO3 + NO
For many years it was made by the reaction of sulfuric acid and saltpeter, but this method is no longer used.
NaNO3 + H2SO4 → NaHSO4 + HNO3
It is now manufactured by combusting ammonia in air in the presence of a (platinum or other noble metal) catalyst, and the nitrogen oxides thus formed are oxidized further and absorbed in water to form nitric acid.
NH3 + 2O2 → HNO3 + H2O
Uses of Nitric acid:
1. A solution of Nitric acid and alcohol, Nital, is used for etching of metals to reveal the microstructure.Nitric acid is also used in explosives, and is key to the manufacture of Nitroglycerin and RDX.
2. In a low concentration, it is often used to artificially age pine and maple. The color produced is a grey-gold very much like very old wax or oil finished wood (wood finishing).
You can still convert the following datas into molecular structure:
(1)InChI=1S/HNO3/c2-1(3)4/h(H,2,3,4);
(2)InChIKey=GRYLNZFGIOXLOG-UHFFFAOYSA-N;
(3)Smiles[N+](=O)(O)[O-]
The toxicity data is as follows:
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
human | LDLo | oral | 430mg/kg (430mg/kg) | Gekkan Yakuji. Pharmaceuticals Monthly. Vol. 22, Pg. 651, 1980. | |
man | LDLo | unreported | 110mg/kg (110mg/kg) | "Poisoning; Toxicology, Symptoms, Treatments," 2nd ed., Arena, J.M., Springfield, IL, C.C. Thomas, 1970Vol. 2, Pg. 73, 1970. | |
rat | LC50 | inhalation | 67ppm(NO2)/4H (67ppm) | AMA Archives of Industrial Hygiene and Occupational Medicine. Vol. 10, Pg. 418, 1954. |
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