Ce(OCMe3)(NO3)3(THF)2
sodium t-butanolate
A
sodium nitrate
B
Ce(OCMe3)4(THF)2
Conditions | Yield |
---|---|
In tetrahydrofuran exclusion of air and water, stirred for 20 h, 3 equiv. of NaOCMe3; centrifuged, removal of solvent; | A 100% B 80-95 |
Conditions | Yield |
---|---|
In water byproducts: oxalic acid; between 15 and 65°C;; pure NaNO3;; | 99% |
ammonium cerium (IV) nitrate
sodium t-butanolate
A
sodium nitrate
B
Ce(OCMe3)(NO3)3(THF)2
C
tert-butyl alcohol
Conditions | Yield |
---|---|
In tetrahydrofuran byproducts: NH3; exclusion of air and water, stirred for 2 h; filtered (NaNO3), removal of solvent from filtrate, extn. (toluene), removal of solvent; elem. anal.; | A 99% B 56% C n/a |
Conditions | Yield |
---|---|
In neat (no solvent) byproducts: NOCl; at ambient pressure; treatment of solid NaCl with a Cl2/NO2-mixture; 98.8% NaNO3 after 8-10times;; | 98.8% |
In neat (no solvent) byproducts: NOCl; at ambient pressure; treatment of solid NaCl with a Cl2/NO2-mixture; 98.8% NaNO3 after 8-10times;; | 98.8% |
In neat (no solvent) byproducts: NOCl; treatment of solid NaCl with NO2;; dissolving NaNO3 in liquid NH3, separation from unreacted chloride;; |
ammonium cerium (IV) nitrate
sodium t-butanolate
A
sodium nitrate
B
Ce2(OCMe3)4(μ-OCMe3)3(μ3-OCMe3)2Na
C
tert-butyl alcohol
Conditions | Yield |
---|---|
In tetrahydrofuran byproducts: NH3; exclusion of air and water, stirred for 2 h; filtered (NaNO3), removal of solvent from filtrate, extn. (hexane), removal of solvent; elem. anal.; | A 94% B 96% C n/a |
ammonium cerium (IV) nitrate
sodium t-butanolate
A
sodium nitrate
B
Ce(OCMe3)4(THF)2
C
tert-butyl alcohol
Conditions | Yield |
---|---|
In tetrahydrofuran byproducts: NH3; exclusion of air and water, stirred for 2 h; filtered (NaNO3), removal of solvent from filtrate, extn. (hexane), removal of solvent; elem. anal.; | A 96% B 65% C n/a |
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide N2O4 addn. (dropwise) to NaNO2 suspn. (DMF), soln. keeping for 1 h at 0°C, oxides of nitrogen removal (vac.), pptn. on ether addn.; | 81% |
chlorine nitrate
sodium chloride
A
hydrogenchloride
B
sodium nitrate
C
hypochloric acid
D
chlorine
Conditions | Yield |
---|---|
In neat (no solvent) experiments performed in a glass Knudsen cell at 298 K; not isolated, detected by mass spectrometry; | A 0% B n/a C n/a D 81% |
chlorine nitrate
A
hydrogenchloride
B
sodium nitrate
C
hypochloric acid
D
chlorine
Conditions | Yield |
---|---|
With synthetic sea salt In neat (no solvent) experiments performed in a glass Knudsen cell at 298 K; not isolated, detected by mass spectrometry; | A n/a B n/a C n/a D 78% |
Conditions | Yield |
---|---|
In nitric acid 2-3 times washed with H2O; dried at 60-70°C;; | A n/a B 70% |
Conditions | Yield |
---|---|
In water preparation on cation exchange resins, 52% Ca-nitrate soln., 26% NaCl-soln.;; crystn.;; | 70% |
In water preparation on cation exchange resins, 52% Ca-nitrate soln., 26% NaCl-soln.;; crystn.;; | 70% |
In water equilibrium in aq. soln.;; |
Conditions | Yield |
---|---|
In neat (no solvent) ambient temp.; | A 55% B 12% |
In neat (no solvent) ambient temp.; | A 55% B 12% |
Conditions | Yield |
---|---|
at 90℃; under 760.051 Torr; for 0.3h; Concentration; Temperature; Time; | 45% |
In water react. of natural soda with dild. HNO3, tereatment of the Na2CO3-containing mineral with the soln. at 200°C under pressure, filtration, evapn., fractionated crystn.;; NaNO3 and mixture of K- and Na-nitrate after fractionated crystn.;; | |
With leucite In water treatment of leucite with HNO3, react. of resulting nitrates with Na2CO3;; |
Conditions | Yield |
---|---|
In tetrahydrofuran addn. of Na to soln. of P-ligand, addn. of soln. of lanthanide nitrate, stirring (10 - 60 min; pptn. of NaNO3); addn. of water, solvent removal (vac.), washing (water), dissol. in Et2O, filtration, solvent removal; | A n/a B 43% |
A
sodium nitrate
B
iodomethanesulfonic acid; silver salt
Conditions | Yield |
---|---|
In ethanol solns. AgNO3 in hot EtOH and ICH2SO3Na*H2O in hot EtOH were mixed and allowed to cool to room temp.; soln. was filtered and concd.; elem. anal.; | A n/a B 31% |
sulfuric acid
sodium nitrite
A
sodium nitrate
B
nitrogen(II) oxide
C
sodium sulfate
D
dinitrogen monoxide
Conditions | Yield |
---|---|
byproducts: H2O, N2; NO collection, storing over dil. sodium hydroxide soln. (NO2 impurity elimination); | A n/a B n/a C n/a D 1% |
Conditions | Yield |
---|---|
In water Product distribution / selectivity; | |
With benzalkonium chloride (BC) In water Product distribution / selectivity; |
Conditions | Yield |
---|---|
In water reaction in neutral aq. soln., pptn. of pure NaNO3 when cooling to 20 to 18°C;; | |
In water reaction in neutral aq. soln., pptn. of pure NaNO3 when cooling to 20 to 18°C;; |
Conditions | Yield |
---|---|
In water treatment of dolomite with HNO3, pptn. of CaSO4 and MgCO3 by successive addn. of Na2SO4 and Na2CO3, winning of NaNO3 from the filtrate;; | |
In water treatment of dolomite with HNO3, pptn. of CaSO4 and MgCO3 by successive addn. of Na2SO4 and Na2CO3, winning of NaNO3 from the filtrate;; |
Conditions | Yield |
---|---|
oxidation; | |
oxidation; |
Conditions | Yield |
---|---|
In water | |
In water |
Conditions | Yield |
---|---|
In melt Kinetics; byproducts: NaCl, NO2, O2; mixt. of Na salt/Ni salt (8/1) heated up to 500°C with a rate of 150°C/h, cooled in furnace; washed with H2O, insol. residue filtered off; elem. anal.; | 100% |
Conditions | Yield |
---|---|
In melt byproducts: NaCl, NO2, O2; mixt. of Na salt/Cu salt (8/1) heated up to 500°C with a rate of 150°C/h, cooled in furnace; washed with H2O, insol. residue filtered off; elem. anal.; | 100% |
Conditions | Yield |
---|---|
In melt Kinetics; byproducts: NaNO3, NO2, O2; mixt. of Na salt/Zn salt (8/1) heated up to 500°C with a rate of 150°C/h, cooled in furnace; washed with H2O, insol. residue filtered off; elem. anal.; | 100% |
Conditions | Yield |
---|---|
20 min, 250 °C;; | 100% |
20 min, 250 °C;; | 100% |
Conditions | Yield |
---|---|
In melt byproducts: NaNO3, NO2, O2; mixt. of Na salt/Cu salt (8/1) heated up to 500°C with a rate of 150°C/h, cooled in furnace; washed with H2O, insol. residue filtered off; elem. anal.; | 100% |
Conditions | Yield |
---|---|
In melt Kinetics; byproducts: NaNO3, NO2, O2; mixt. of Na salt/Ni salt (8/1) heated up to 500°C with a rate of 150°C/h, cooled in furnace; washed with H2O, insol. residue filtered off; elem. anal.; | 100% |
Conditions | Yield |
---|---|
In acetonitrile at 25℃; for 5h; | 98% |
Conditions | Yield |
---|---|
In melt Te and NaNO3 were molten for 2 h at 400-430 °C (molar ratio 1/2-2.5), the melt was dissolved in aq. KOH(10%) forming K2TeO3 which was treated with HNO3;; | 97.5% |
methanol
sodium nitrate
Ni(6,6'-{[ethane-1,2-diylbis(azanylylidene)]bis(methanylylidene)}bis(2-methoxyphenolate))
Conditions | Yield |
---|---|
In dichloromethane at 20℃; for 2h; | 97% |
Conditions | Yield |
---|---|
With carbon disulfide; hydrogen sulfide In water metathesis of BaS with NaNO3 by react. of a mixt. of satd. solutions of NaNO3 and an excess of BaS in an atmosphere of H2S or in presence of C or H or CS2 or CO or hydrocarbons as other reducing agents; heating at 110 °C for 1 h;; isolation of Ba(NO3)2 and NaHS by fractional crystallization; reaction of NaHS forming Na2S and H2S; addition of a small amount of CS2 facilitates the isolation;; | A 95% B n/a |
With carbon disulfide; hydrogen sulfide In water metathesis of BaS with NaNO3 by react. of a mixt. of satd. solutions of NaNO3 and an excess of BaS in an atmosphere of H2S or in presence of C or H or CS2 or CO or hydrocarbons as other reducing agents; heating at 110 °C for 1 h;; isolation of Ba(NO3)2 and NaHS by fractional crystallization; reaction of NaHS forming Na2S and H2S; addition of a small amount of CS2 facilitates the isolation;; | A 95% B n/a |
Conditions | Yield |
---|---|
In methanol; acetonitrile at 20℃; for 0.5h; | 95% |
Conditions | Yield |
---|---|
With hydrogen; copper(II) oxide In neat (no solvent) byproducts: H2O; reaction in 30 min passing stream of H2 over NaNO3;; | 94.3% |
With H2; copper(II) oxide In neat (no solvent) byproducts: H2O; reaction in 30 min passing stream of H2 over NaNO3;; | 94.3% |
With iron addn. of NaOH;; | 86.4% |
sodium nitrate
CH(O)C6H2(CH3)(CO)ORh(P(C6H5)3)2Cl
CH(O)C6H2(CH3)(CO)ORh(P(C6H5)3)2O2NO
Conditions | Yield |
---|---|
In dichloromethane; water; acetone stirring (0.5 h), evapn.; filtering, washing (H2O), drying (vac.); | 94% |
sodium nitrate
dichloro(2,2'-bipyridine)platinum(II)
N-benzylethylenediamine
Conditions | Yield |
---|---|
In water addn. of ethanediamine to aq. suspn. of Pt complex, stirring 2 h at 80°C; cooling, filtration, addn. of satd. aq. NaNO3, storage at roomtemp. overnight; crystals filtered off, washed with 0.05 M HNO3, dried; elem. anal.; | 93.2% |
Conditions | Yield |
---|---|
In water addn. of soln. of AgNO3 (1 equiv.) in water to aq. soln. of (Co(en)2(SCH2CH2NH2))(NO3)2 (2 equiv.); stirring at room temp. for 30 min; addn. of aq. soln. of NaNO3; cooling in a refrigerator for 2 days, crystn., filtration, elem. anal.; | 93% |
sodium nitrate
6,16,2,5-tribenzena(1,4)-1,4,8,11,14,18,23,27-octaazabicyclo[9.9.9]nonacosaphane
Conditions | Yield |
---|---|
Stage #1: zinc perchlorate; sodium nitrate In methanol at 20℃; for 0.5h; Stage #2: 6,16,2,5-tribenzena(1,4)-1,4,8,11,14,18,23,27-octaazabicyclo[9.9.9]nonacosaphane In methanol at 20℃; for 12h; | 93% |
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