Ce(OCMe3)(NO3)3(THF)2
sodium t-butanolate
A
sodium nitrate
B
Ce(OCMe3)4(THF)2
Conditions | Yield |
---|---|
In tetrahydrofuran exclusion of air and water, stirred for 20 h, 3 equiv. of NaOCMe3; centrifuged, removal of solvent; | A 100% B 80-95 |
Conditions | Yield |
---|---|
In water byproducts: oxalic acid; between 15 and 65°C;; pure NaNO3;; | 99% |
ammonium cerium (IV) nitrate
sodium t-butanolate
A
sodium nitrate
B
Ce(OCMe3)(NO3)3(THF)2
C
tert-butyl alcohol
Conditions | Yield |
---|---|
In tetrahydrofuran byproducts: NH3; exclusion of air and water, stirred for 2 h; filtered (NaNO3), removal of solvent from filtrate, extn. (toluene), removal of solvent; elem. anal.; | A 99% B 56% C n/a |
Conditions | Yield |
---|---|
In neat (no solvent) byproducts: NOCl; at ambient pressure; treatment of solid NaCl with a Cl2/NO2-mixture; 98.8% NaNO3 after 8-10times;; | 98.8% |
In neat (no solvent) byproducts: NOCl; at ambient pressure; treatment of solid NaCl with a Cl2/NO2-mixture; 98.8% NaNO3 after 8-10times;; | 98.8% |
In neat (no solvent) byproducts: NOCl; treatment of solid NaCl with NO2;; dissolving NaNO3 in liquid NH3, separation from unreacted chloride;; |
ammonium cerium (IV) nitrate
sodium t-butanolate
A
sodium nitrate
B
Ce2(OCMe3)4(μ-OCMe3)3(μ3-OCMe3)2Na
C
tert-butyl alcohol
Conditions | Yield |
---|---|
In tetrahydrofuran byproducts: NH3; exclusion of air and water, stirred for 2 h; filtered (NaNO3), removal of solvent from filtrate, extn. (hexane), removal of solvent; elem. anal.; | A 94% B 96% C n/a |
ammonium cerium (IV) nitrate
sodium t-butanolate
A
sodium nitrate
B
Ce(OCMe3)4(THF)2
C
tert-butyl alcohol
Conditions | Yield |
---|---|
In tetrahydrofuran byproducts: NH3; exclusion of air and water, stirred for 2 h; filtered (NaNO3), removal of solvent from filtrate, extn. (hexane), removal of solvent; elem. anal.; | A 96% B 65% C n/a |
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide N2O4 addn. (dropwise) to NaNO2 suspn. (DMF), soln. keeping for 1 h at 0°C, oxides of nitrogen removal (vac.), pptn. on ether addn.; | 81% |
chlorine nitrate
sodium chloride
A
hydrogenchloride
B
sodium nitrate
C
hypochloric acid
D
chlorine
Conditions | Yield |
---|---|
In neat (no solvent) experiments performed in a glass Knudsen cell at 298 K; not isolated, detected by mass spectrometry; | A 0% B n/a C n/a D 81% |
chlorine nitrate
A
hydrogenchloride
B
sodium nitrate
C
hypochloric acid
D
chlorine
Conditions | Yield |
---|---|
With synthetic sea salt In neat (no solvent) experiments performed in a glass Knudsen cell at 298 K; not isolated, detected by mass spectrometry; | A n/a B n/a C n/a D 78% |
Conditions | Yield |
---|---|
In nitric acid 2-3 times washed with H2O; dried at 60-70°C;; | A n/a B 70% |
Conditions | Yield |
---|---|
In water preparation on cation exchange resins, 52% Ca-nitrate soln., 26% NaCl-soln.;; crystn.;; | 70% |
In water preparation on cation exchange resins, 52% Ca-nitrate soln., 26% NaCl-soln.;; crystn.;; | 70% |
In water equilibrium in aq. soln.;; |
Conditions | Yield |
---|---|
In neat (no solvent) ambient temp.; | A 55% B 12% |
In neat (no solvent) ambient temp.; | A 55% B 12% |
Conditions | Yield |
---|---|
at 90℃; under 760.051 Torr; for 0.3h; Concentration; Temperature; Time; | 45% |
In water react. of natural soda with dild. HNO3, tereatment of the Na2CO3-containing mineral with the soln. at 200°C under pressure, filtration, evapn., fractionated crystn.;; NaNO3 and mixture of K- and Na-nitrate after fractionated crystn.;; | |
With leucite In water treatment of leucite with HNO3, react. of resulting nitrates with Na2CO3;; |
Conditions | Yield |
---|---|
In tetrahydrofuran addn. of Na to soln. of P-ligand, addn. of soln. of lanthanide nitrate, stirring (10 - 60 min; pptn. of NaNO3); addn. of water, solvent removal (vac.), washing (water), dissol. in Et2O, filtration, solvent removal; | A n/a B 43% |
A
sodium nitrate
B
iodomethanesulfonic acid; silver salt
Conditions | Yield |
---|---|
In ethanol solns. AgNO3 in hot EtOH and ICH2SO3Na*H2O in hot EtOH were mixed and allowed to cool to room temp.; soln. was filtered and concd.; elem. anal.; | A n/a B 31% |
sulfuric acid
sodium nitrite
A
sodium nitrate
B
nitrogen(II) oxide
C
sodium sulfate
D
dinitrogen monoxide
Conditions | Yield |
---|---|
byproducts: H2O, N2; NO collection, storing over dil. sodium hydroxide soln. (NO2 impurity elimination); | A n/a B n/a C n/a D 1% |
Conditions | Yield |
---|---|
In water Product distribution / selectivity; | |
With benzalkonium chloride (BC) In water Product distribution / selectivity; |
Conditions | Yield |
---|---|
In water reaction in neutral aq. soln., pptn. of pure NaNO3 when cooling to 20 to 18°C;; | |
In water reaction in neutral aq. soln., pptn. of pure NaNO3 when cooling to 20 to 18°C;; |
Conditions | Yield |
---|---|
In water treatment of dolomite with HNO3, pptn. of CaSO4 and MgCO3 by successive addn. of Na2SO4 and Na2CO3, winning of NaNO3 from the filtrate;; | |
In water treatment of dolomite with HNO3, pptn. of CaSO4 and MgCO3 by successive addn. of Na2SO4 and Na2CO3, winning of NaNO3 from the filtrate;; |
Conditions | Yield |
---|---|
oxidation; | |
oxidation; |
Conditions | Yield |
---|---|
In water | |
In water |
Conditions | Yield |
---|---|
In melt Kinetics; byproducts: NaCl, NO2, O2; mixt. of Na salt/Ni salt (8/1) heated up to 500°C with a rate of 150°C/h, cooled in furnace; washed with H2O, insol. residue filtered off; elem. anal.; | 100% |
Conditions | Yield |
---|---|
In melt byproducts: NaCl, NO2, O2; mixt. of Na salt/Cu salt (8/1) heated up to 500°C with a rate of 150°C/h, cooled in furnace; washed with H2O, insol. residue filtered off; elem. anal.; | 100% |
Conditions | Yield |
---|---|
In melt Kinetics; byproducts: NaNO3, NO2, O2; mixt. of Na salt/Zn salt (8/1) heated up to 500°C with a rate of 150°C/h, cooled in furnace; washed with H2O, insol. residue filtered off; elem. anal.; | 100% |
Conditions | Yield |
---|---|
20 min, 250 °C;; | 100% |
20 min, 250 °C;; | 100% |
Conditions | Yield |
---|---|
In melt byproducts: NaNO3, NO2, O2; mixt. of Na salt/Cu salt (8/1) heated up to 500°C with a rate of 150°C/h, cooled in furnace; washed with H2O, insol. residue filtered off; elem. anal.; | 100% |
Conditions | Yield |
---|---|
In melt Kinetics; byproducts: NaNO3, NO2, O2; mixt. of Na salt/Ni salt (8/1) heated up to 500°C with a rate of 150°C/h, cooled in furnace; washed with H2O, insol. residue filtered off; elem. anal.; | 100% |
Conditions | Yield |
---|---|
In acetonitrile at 25℃; for 5h; | 98% |
Conditions | Yield |
---|---|
In melt Te and NaNO3 were molten for 2 h at 400-430 °C (molar ratio 1/2-2.5), the melt was dissolved in aq. KOH(10%) forming K2TeO3 which was treated with HNO3;; | 97.5% |
methanol
sodium nitrate
Ni(6,6'-{[ethane-1,2-diylbis(azanylylidene)]bis(methanylylidene)}bis(2-methoxyphenolate))
Conditions | Yield |
---|---|
In dichloromethane at 20℃; for 2h; | 97% |
Conditions | Yield |
---|---|
With carbon disulfide; hydrogen sulfide In water metathesis of BaS with NaNO3 by react. of a mixt. of satd. solutions of NaNO3 and an excess of BaS in an atmosphere of H2S or in presence of C or H or CS2 or CO or hydrocarbons as other reducing agents; heating at 110 °C for 1 h;; isolation of Ba(NO3)2 and NaHS by fractional crystallization; reaction of NaHS forming Na2S and H2S; addition of a small amount of CS2 facilitates the isolation;; | A 95% B n/a |
With carbon disulfide; hydrogen sulfide In water metathesis of BaS with NaNO3 by react. of a mixt. of satd. solutions of NaNO3 and an excess of BaS in an atmosphere of H2S or in presence of C or H or CS2 or CO or hydrocarbons as other reducing agents; heating at 110 °C for 1 h;; isolation of Ba(NO3)2 and NaHS by fractional crystallization; reaction of NaHS forming Na2S and H2S; addition of a small amount of CS2 facilitates the isolation;; | A 95% B n/a |
Conditions | Yield |
---|---|
In methanol; acetonitrile at 20℃; for 0.5h; | 95% |
Conditions | Yield |
---|---|
With hydrogen; copper(II) oxide In neat (no solvent) byproducts: H2O; reaction in 30 min passing stream of H2 over NaNO3;; | 94.3% |
With H2; copper(II) oxide In neat (no solvent) byproducts: H2O; reaction in 30 min passing stream of H2 over NaNO3;; | 94.3% |
With iron addn. of NaOH;; | 86.4% |
sodium nitrate
CH(O)C6H2(CH3)(CO)ORh(P(C6H5)3)2Cl
CH(O)C6H2(CH3)(CO)ORh(P(C6H5)3)2O2NO
Conditions | Yield |
---|---|
In dichloromethane; water; acetone stirring (0.5 h), evapn.; filtering, washing (H2O), drying (vac.); | 94% |
sodium nitrate
dichloro(2,2'-bipyridine)platinum(II)
N-benzylethylenediamine
Conditions | Yield |
---|---|
In water addn. of ethanediamine to aq. suspn. of Pt complex, stirring 2 h at 80°C; cooling, filtration, addn. of satd. aq. NaNO3, storage at roomtemp. overnight; crystals filtered off, washed with 0.05 M HNO3, dried; elem. anal.; | 93.2% |
Conditions | Yield |
---|---|
In water addn. of soln. of AgNO3 (1 equiv.) in water to aq. soln. of (Co(en)2(SCH2CH2NH2))(NO3)2 (2 equiv.); stirring at room temp. for 30 min; addn. of aq. soln. of NaNO3; cooling in a refrigerator for 2 days, crystn., filtration, elem. anal.; | 93% |
sodium nitrate
6,16,2,5-tribenzena(1,4)-1,4,8,11,14,18,23,27-octaazabicyclo[9.9.9]nonacosaphane
Conditions | Yield |
---|---|
Stage #1: zinc perchlorate; sodium nitrate In methanol at 20℃; for 0.5h; Stage #2: 6,16,2,5-tribenzena(1,4)-1,4,8,11,14,18,23,27-octaazabicyclo[9.9.9]nonacosaphane In methanol at 20℃; for 12h; | 93% |
Sodium nitrate,with the CAS registry number 7631-99-4, it is also named as Nitric acid monosodium salt. The product's categories are Inorganics; Water Ttreatment Chemicals; ICP CRMs Spectroscopy; ICP-OES/-MS; ICP Spectroscopy; Matrix Selection; Nitrate Alphabetic; S; SN - SZ; Anionic Solutions Chromatography; Anionic Standard Solutions Alphabetic; Ion Chromatography; Application CRMs; N; NA - NI, and the other registry number is 862599-22-2. Besides, it is white crystalline solid, which should be stored in a cool, ventilated warehouse. In addition, its molecular formula is NaNO3 and molecular weight is 84.99.
Physical properties about Sodium nitrate are: (1)ACD/LogP: -0.129; (2)ACD/LogD (pH 5.5): -0.13; (3)ACD/LogD (pH 7.4): -0.13; (4)ACD/BCF (pH 5.5): 1.00; (5)ACD/BCF (pH 7.4): 1.00; (6)#H bond acceptors: 4; (7)#H bond donors: 1; (8)Enthalpy of Vaporization: 37.72 kJ/mol; (9)Boiling Point: 83 °C at 760 mmHg; (10)Vapour Pressure: 49.8 mmHg at 25°C
Preparation of Sodium nitrate: this chemical can be prepared by the reaction of NaCl or soda ash with Nitric acid.
NaCl + HNO3 → NaNO3 + HCl
Na2CO3 + 2HNO3 → 2NaNO3 + H2O + CO2
Uses of Sodium nitrate: this chemical is used as a fertilizer and a raw material for the manufacture of gunpowder. It is also used to make a resin by combining with iron hydroxide. Furthermore, it can be combined with Sulfuric acid to produce nitric acid. And it can be used as a substitute oxidizer used in fireworks as a replacement for potassium nitrate. It is used for heat transfer in solar power plants and heat storage. What's more, it can be used for facultative microorganism respiration in the wastewater industry.
When you are using this chemical, please be cautious about it as the following: it may cause fire in contact with combustible material. Please keep away from combustible material. It is also harmful if swallowed. And it is irritating to eyes, respiratory system and skin. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Moreover, you should wear suitable protective clothing, gloves and eye/face protection. And please take off immediately all contaminated clothing. Additionally, in case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
People can use the following data to convert to the molecule structure.
(1)SMILES: [Na+].[O-][N+]([O-])=O;
(2)InChI: InChI=1/NO3.Na/c2-1(3)4;/q-1;+1;
(3)InChIKey: VWDWKYIASSYTQR-UHFFFAOYAL;
The toxicity data is as follows:
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
child | LDLo | oral | 22500ug/kg (22.5mg/kg) | BLOOD: METHEMOGLOBINEMIA-CARBOXYHEMOGLOBIN | Journal of Toxicology, Clinical Toxicology. Vol. 32, Pg. 173, 1994. |
mouse | LD50 | intravenous | 175mg/kg (175mg/kg) | Archiv fuer Toxikologie. Vol. 21, Pg. 89, 1965. | |
rabbit | LD50 | oral | 2680mg/kg (2680mg/kg) | Southwestern Veterinarian. Vol. 27, Pg. 246, 1974. | |
rat | LD | intraperitoneal | > 181mg/kg (181mg/kg) | Toxicology and Applied Pharmacology. Vol. 5, Pg. 750, 1963. | |
rat | LD50 | oral | 1267mg/kg (1267mg/kg) | Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 46(12), Pg. 66, 1981. | |
women | TDLo | oral | 14mg/kg (14mg/kg) | CARDIAC: PULSE RATE INCREASE WITHOUT FALL IN BP LUNGS, THORAX, OR RESPIRATION: CYANOSIS BLOOD: METHEMOGLOBINEMIA-CARBOXYHEMOGLOBIN | Journal of Toxicology, Clinical Toxicology. Vol. 32, Pg. 173, 1994. |
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