Product Name

  • Name

    2-Norbornene

  • EINECS 207-866-0
  • CAS No. 498-66-8
  • Article Data145
  • CAS DataBase
  • Density 0.955 g/cm3
  • Solubility
  • Melting Point 44-46 °C(lit.)
  • Formula C7H10
  • Boiling Point 96 °C at 760 mmHg
  • Molecular Weight 94.1564
  • Flash Point °C
  • Transport Information
  • Appearance white crystalline mass
  • Safety Mildly toxic by ingestion. When heated to decomposition it emits acrid smoke and irritating fumes.
  • Risk Codes 11
  • Molecular Structure Molecular Structure of 498-66-8 (2-Norbornene)
  • Hazard Symbols FlammableF
  • Synonyms 2-Norbornene(8CI); 2-Norbornylene; 3,6-Endomethylenecyclohexene; Bicyclo[2.2.1]hepta-2-ene;Bicyclo[2.2.1]heptene; NSC 120425; NSC 22453; Norbornene; Norbornylene;Norcamphene; Norfenchene
  • PSA 0.00000
  • LogP 1.97250

Synthetic route

exo-3-(trimethylsilyl)-endo-2-norbornyl trifluoroacetate
129850-00-6, 129938-42-7

exo-3-(trimethylsilyl)-endo-2-norbornyl trifluoroacetate

norborn-2-ene
498-66-8

norborn-2-ene

Conditions
ConditionsYield
With water In acetone at 65.1℃; Kinetics; Product distribution; Rate constant;98%
(1R,2S,3R,4S)-2,3-Bis-trimethylsilanyl-bicyclo[2.2.1]heptane

(1R,2S,3R,4S)-2,3-Bis-trimethylsilanyl-bicyclo[2.2.1]heptane

norborn-2-ene
498-66-8

norborn-2-ene

Conditions
ConditionsYield
In methanol electrochemical oxidation;96%
trans-1,2-bis(hydroxydiphenylmethyl)bicyclo<2.2.1>heptane

trans-1,2-bis(hydroxydiphenylmethyl)bicyclo<2.2.1>heptane

A

norborn-2-ene
498-66-8

norborn-2-ene

B

benzophenone
119-61-9

benzophenone

C

1,1-Diphenylmethanol
91-01-0

1,1-Diphenylmethanol

D

1,1-diphenylmethylenenorbornane
50599-53-6

1,1-diphenylmethylenenorbornane

Conditions
ConditionsYield
at 290℃; for 3h;A 27%
B 95%
C 15%
D 64%
exo-2,3-epoxynorbornane
844874-18-6

exo-2,3-epoxynorbornane

norborn-2-ene
498-66-8

norborn-2-ene

Conditions
ConditionsYield
With polystyrene-supported(catecholato)oxoRe cat. act. by iPrOH; triphenylphosphine In toluene for 8h; Heating;92%
5-norbornen-2-ol mesylate

5-norbornen-2-ol mesylate

norborn-2-ene
498-66-8

norborn-2-ene

Conditions
ConditionsYield
With lithium triethylborohydride In tetrahydrofuran at 60℃; for 4h;85%
exo-2,3-epoxynorbornane
278-74-0, 3146-39-2, 57378-36-6

exo-2,3-epoxynorbornane

norborn-2-ene
498-66-8

norborn-2-ene

Conditions
ConditionsYield
With triphenylphosphine at 200℃; for 8.5h; Product distribution;84%
endo-3-(Trimethylsilyl)bicyclo<2.2.1>heptan-endo-2-carbonsaeure
113475-46-0

endo-3-(Trimethylsilyl)bicyclo<2.2.1>heptan-endo-2-carbonsaeure

norborn-2-ene
498-66-8

norborn-2-ene

Conditions
ConditionsYield
In ethanol; acetonitrile at 60℃; anodic oxidation;60%
With potassium hydroxide In ethanol; acetonitrile at 60℃; electrolysis: C-anode, Pt-catode;60 % Chromat.
ethanol
64-17-5

ethanol

Potassium; (1R,2S,3R,4S)-3-trimethylsilanyl-bicyclo[2.2.1]heptane-2-carboxylate
88946-66-1

Potassium; (1R,2S,3R,4S)-3-trimethylsilanyl-bicyclo[2.2.1]heptane-2-carboxylate

A

norborn-2-ene
498-66-8

norborn-2-ene

2-(trimethylsilyl)bicyclo[2.2.1]hept-2-ene
16205-87-1

2-(trimethylsilyl)bicyclo[2.2.1]hept-2-ene

((1R,2R,3R,4S)-3-Ethoxy-bicyclo[2.2.1]hept-2-yl)-trimethyl-silane
88946-64-9

((1R,2R,3R,4S)-3-Ethoxy-bicyclo[2.2.1]hept-2-yl)-trimethyl-silane

Conditions
ConditionsYield
In acetonitrile at 0℃; Product distribution; anidic decarboxylation, other solvens, temperature;A 51%
B 14%
C 17%
C14H15N2O2S(1-)*Na(1+)
54389-06-9

C14H15N2O2S(1-)*Na(1+)

A

norborn-2-ene
498-66-8

norborn-2-ene

B

Bicyclo<3.2.0>heptadien-1,6
32316-40-8

Bicyclo<3.2.0>heptadien-1,6

C

toluene
108-88-3

toluene

D

spiro[2.4]hepta-4,6-diene
765-46-8

spiro[2.4]hepta-4,6-diene

Conditions
ConditionsYield
at 275℃; under 0.0001 - 0.0004 Torr;A 2.7%
B 51%
C 0.9%
D 4.9%
2-endo-(Dichloroamino)norbornane
78685-90-2

2-endo-(Dichloroamino)norbornane

A

norborn-2-ene
498-66-8

norborn-2-ene

B

2-(Chloroimino)norbornane
78685-89-9

2-(Chloroimino)norbornane

Conditions
ConditionsYield
A 12%
B 50%
2-exo-(Dichloroamino)norbornane
78685-88-8

2-exo-(Dichloroamino)norbornane

A

norborn-2-ene
498-66-8

norborn-2-ene

B

2-(Chloroimino)norbornane
78685-89-9

2-(Chloroimino)norbornane

Conditions
ConditionsYield
A 11%
B 48%
methyllithium
917-54-4

methyllithium

7,7-dibromo-2-norbornene
77333-79-0

7,7-dibromo-2-norbornene

A

norborn-2-ene
498-66-8

norborn-2-ene

B

syn-7-bromobicyclo<2.2.1>heptene
60154-55-4

syn-7-bromobicyclo<2.2.1>heptene

C

Bicyclo<3.2.0>heptadien-1,6
32316-40-8

Bicyclo<3.2.0>heptadien-1,6

D

syn-7-bromo-7-methylnorbornene
14025-97-9, 86970-70-9

syn-7-bromo-7-methylnorbornene

E

spiro[2.4]hepta-4,6-diene
765-46-8

spiro[2.4]hepta-4,6-diene

Conditions
ConditionsYield
at 100℃; under 0.005 Torr; Product distribution; other reaction conditions;A 0.1%
B 20.5%
C 47.5%
D 6.6%
E 12.6%
methanol
67-56-1

methanol

Potassium; (1R,2S,3R,4S)-3-trimethylsilanyl-bicyclo[2.2.1]heptane-2-carboxylate
88946-66-1

Potassium; (1R,2S,3R,4S)-3-trimethylsilanyl-bicyclo[2.2.1]heptane-2-carboxylate

A

norborn-2-ene
498-66-8

norborn-2-ene

2-(trimethylsilyl)bicyclo[2.2.1]hept-2-ene
16205-87-1

2-(trimethylsilyl)bicyclo[2.2.1]hept-2-ene

((1R,2R,3R,4S)-3-Methoxy-bicyclo[2.2.1]hept-2-yl)-trimethyl-silane
88946-63-8

((1R,2R,3R,4S)-3-Methoxy-bicyclo[2.2.1]hept-2-yl)-trimethyl-silane

Conditions
ConditionsYield
In acetonitrile at 0℃; Product distribution; anidic decarboxylation, other solvens, temperature;A 19%
B 17%
C 44%
α-chloronorbornene
694-93-9, 29685-80-1

α-chloronorbornene

tert.-butyl lithium
594-19-4

tert.-butyl lithium

A

norborn-2-ene
498-66-8

norborn-2-ene

B

3-tert-butyltricyclo<2.2.1.02,6>heptane

3-tert-butyltricyclo<2.2.1.02,6>heptane

Conditions
ConditionsYield
In tetrahydrofuran; pentane at 25℃;A 38%
B 44%
α-chloronorbornene
694-93-9, 29685-80-1

α-chloronorbornene

A

norborn-2-ene
498-66-8

norborn-2-ene

B

3-tert-butyltricyclo<2.2.1.02,6>heptane

3-tert-butyltricyclo<2.2.1.02,6>heptane

Conditions
ConditionsYield
With tert.-butyl lithium In tetrahydrofuran; pentane at 25℃;A 38%
B 44%
C14H15N2O2S(1-)*Na(1+)

C14H15N2O2S(1-)*Na(1+)

A

3-[2-(3-cyclopentenyl)ethenylidene]nortricyclane

3-[2-(3-cyclopentenyl)ethenylidene]nortricyclane

B

norborn-2-ene
498-66-8

norborn-2-ene

C

nortricyclane
279-19-6

nortricyclane

D

4-ethynylcyclopentene
330654-57-4

4-ethynylcyclopentene

Conditions
ConditionsYield
at 190℃; under 0.05 Torr; for 2h; Pyrolysis;A 38.7%
B 8.3%
C 9.2%
D 41.8%
(+/-)-endo-2-norborneol
497-36-9

(+/-)-endo-2-norborneol

norborn-2-ene
498-66-8

norborn-2-ene

Conditions
ConditionsYield
With copper(II) bis(trifluoromethanesulfonate)32%
Conditions
ConditionsYield
With copper(II) bis(trifluoromethanesulfonate)30%
ethene
74-85-1

ethene

endo-Dicyclopentadien
1755-01-7

endo-Dicyclopentadien

norborn-2-ene
498-66-8

norborn-2-ene

Conditions
ConditionsYield
at 190 - 200℃; under 73550.8 - 117681 Torr;
norbornyl chloride
29342-53-8

norbornyl chloride

norborn-2-ene
498-66-8

norborn-2-ene

Conditions
ConditionsYield
With quinoline
norborn-2-ene
498-66-8

norborn-2-ene

cis-cyclopentane-1,3-dicarboxaldehyde
10283-91-7

cis-cyclopentane-1,3-dicarboxaldehyde

Conditions
ConditionsYield
With potassium permanganate; copper(II) sulfate; tert-butyl alcohol In dichloromethane; water at 22℃; for 12h;100%
With sodium periodate; ruthenium In water; 1,2-dichloro-ethane at 20℃; for 3h;72%
With ruthenium trichloride; Oxone; sodium hydrogencarbonate In water; acetonitrile at 20℃; for 0.7h;72%
norborn-2-ene
498-66-8

norborn-2-ene

exo-2,3-epoxynorbornane
844874-18-6

exo-2,3-epoxynorbornane

Conditions
ConditionsYield
With pyridine N-oxide; oxochromium(V) complex of tetramethylsalen IIb In acetonitrile100%
With cobalt(III) acetylacetonate; oxygen In tetrahydrofuran at 70℃; for 24h;98%
With [2-percarboxyethyl] functionalized silica In dichloromethane at 20℃; for 1h;95%
norborn-2-ene
498-66-8

norborn-2-ene

Phenylselenyl chloride
5707-04-0

Phenylselenyl chloride

endo-3-chloro-exo-2-phenylselenobicyclo<2.2.1>heptane
70303-01-4

endo-3-chloro-exo-2-phenylselenobicyclo<2.2.1>heptane

Conditions
ConditionsYield
In dichloromethane100%
In water; acetonitrile for 24h; Ambient temperature;84%
In dichloromethane at 25℃;100 % Spectr.
norborn-2-ene
498-66-8

norborn-2-ene

ethyl chloro(2-phenylhydrazono)acetate
28663-68-5

ethyl chloro(2-phenylhydrazono)acetate

(3aS,7aR)-1-Phenyl-3a,4,5,6,7,7a-hexahydro-1H-4,7-methano-indazole-3-carboxylic acid ethyl ester

(3aS,7aR)-1-Phenyl-3a,4,5,6,7,7a-hexahydro-1H-4,7-methano-indazole-3-carboxylic acid ethyl ester

Conditions
ConditionsYield
With triethylamine In chloroform for 2h; Heating;100%
norborn-2-ene
498-66-8

norborn-2-ene

2-diazo-4,5-dicyano-2H-imidazole
51285-29-1

2-diazo-4,5-dicyano-2H-imidazole

(5aα,6β,9β,9aα)-5a,6,7,8,9,9a-hexahydro-6,9-methanoimidazo<2,1-c><1,2,4>benzotriazine-1,2-dicarbonitrile
111005-26-6

(5aα,6β,9β,9aα)-5a,6,7,8,9,9a-hexahydro-6,9-methanoimidazo<2,1-c><1,2,4>benzotriazine-1,2-dicarbonitrile

Conditions
ConditionsYield
In dichloromethane at -15℃; for 360h;100%
norborn-2-ene
498-66-8

norborn-2-ene

4-methyl-5-methylidene-4-phenyl-1,3-dioxolan-2-one
95323-23-2

4-methyl-5-methylidene-4-phenyl-1,3-dioxolan-2-one

3-(2-phenylpropanoyl)tricyclo<3.2.1.02,4>octane

3-(2-phenylpropanoyl)tricyclo<3.2.1.02,4>octane

Conditions
ConditionsYield
tetrakis(triphenylphosphine) palladium(0) In toluene for 15h; Mechanism; Heating; other substrates, other alkenes, other catalysts;100%
tetrakis(triphenylphosphine) palladium(0) In toluene for 15h; Heating;100%
norborn-2-ene
498-66-8

norborn-2-ene

2,3-epoxynorbornane
278-74-0

2,3-epoxynorbornane

Conditions
ConditionsYield
With hemin polymer (1); 1,2,3,4,5-pentafluoro-6-iodosylbenzene In dichloromethane; water for 0.05h;100%
With 3-chloro-benzenecarboperoxoic acid; iron(III) perchlorate In acetonitrile at -10℃; for 0.0833333h;100%
With oxygen; isobutyraldehyde In acetonitrile at 40℃; for 6h;99%
norborn-2-ene
498-66-8

norborn-2-ene

norbornene
279-23-2

norbornene

Conditions
ConditionsYield
With 1-Thia-3,4-diazolidine-2,5-dione In various solvent(s) Ambient temperature; Irradiation;100%
With {(η6-C6H6)Ru(NCCH3)3}{BF4}2; water; hydrogen In benzene at 90℃; under 30400 Torr; for 4h;100%
With C28H18Co(1-)*K(1+)*2C4H10O2; hydrogen In toluene at 60℃; under 1500.15 Torr; for 24h; chemoselective reaction;100%
norborn-2-ene
498-66-8

norborn-2-ene

exo,exo-2,3-dideuterionorbornane
111275-13-9

exo,exo-2,3-dideuterionorbornane

Conditions
ConditionsYield
With deuterium; Wilkinson's catalyst In toluene100%
With lithium aluminium deuteride; deuteropropionic acid; boron trifluoride diethyl etherate 1.) diglyme, 1 h, RT; 2.) diglyme, 140 deg C, 2 h; Yield given. Multistep reaction;
With deuterium; (iPrPDI)Fe(N2)2 at 22℃; under 760 Torr;
With BF4(1-)*C30H42N3PRh(1+); deuterium at 110℃; under 2585.81 Torr; for 24h; Inert atmosphere; Autoclave sealed;
With tetrahydroxydiborane(4); palladium 10% on activated carbon; water-d2 In dichloromethane at 20℃; for 5h; Mechanism; Inert atmosphere; Glovebox;
norborn-2-ene
498-66-8

norborn-2-ene

exo-2-trichlorosilylnorbornane
146075-48-1

exo-2-trichlorosilylnorbornane

Conditions
ConditionsYield
With (Ra)-(2'-methoxy-[1,1']-binaphthalenyl-2-yl)-diphenylphosphine; trichlorosilane; bis(η3-allyl-μ-chloropalladium(II)) at 0℃; for 24h; Product distribution; other bicycloalkenes, stereoselectivity;100%
With trichlorosilane; (Ra)-(2'-methoxy-[1,1']-binaphthalenyl-2-yl)-diphenylphosphine; bis(η3-allyl-μ-chloropalladium(II)) at -20℃; for 72h;99%
norborn-2-ene
498-66-8

norborn-2-ene

carbon monoxide
201230-82-2

carbon monoxide

hex-1-yne
693-02-7

hex-1-yne

(3aSR,4SR,7RS,7aSR)-2-butyl-3a,4,5,6,7,7a-hexahydro-4,7-methanoinden-1-one
143768-88-1

(3aSR,4SR,7RS,7aSR)-2-butyl-3a,4,5,6,7,7a-hexahydro-4,7-methanoinden-1-one

Conditions
ConditionsYield
dodecacarbonyl tetracobalt In dichloromethane at 150℃; under 7600 Torr; for 22h;100%
Co2Rh2 nanoparticles immobilized on charcoal In tetrahydrofuran at 130℃; under 760 Torr; for 18h; intermolecular Pauson-Khand reaction;60%
norborn-2-ene
498-66-8

norborn-2-ene

1-decyne
764-93-2

1-decyne

carbon monoxide
201230-82-2

carbon monoxide

(3aR,4R,7S,7aR)-2-Octyl-3a,4,5,6,7,7a-hexahydro-4,7-methano-inden-1-one
123844-39-3

(3aR,4R,7S,7aR)-2-Octyl-3a,4,5,6,7,7a-hexahydro-4,7-methano-inden-1-one

Conditions
ConditionsYield
With 1,2-dimethoxyethane; dicobalt octacarbonyl In toluene at 120℃; under 5320 Torr; for 10h;100%
With cobalt(II) bromide; zinc In toluene; tert-butyl alcohol 25 deg C, 5 h; 110 deg C, 24 h;85%
norborn-2-ene
498-66-8

norborn-2-ene

alkoxy acetylene dicobalt hexacarbonyl complex (3e)

alkoxy acetylene dicobalt hexacarbonyl complex (3e)

(4S,7R)-2-[(1S,2R,3S,4R)-3-(2,2-Dimethyl-propoxy)-4,7,7-trimethyl-bicyclo[2.2.1]hept-2-yloxy]-3a,4,5,6,7,7a-hexahydro-4,7-methano-inden-1-one

(4S,7R)-2-[(1S,2R,3S,4R)-3-(2,2-Dimethyl-propoxy)-4,7,7-trimethyl-bicyclo[2.2.1]hept-2-yloxy]-3a,4,5,6,7,7a-hexahydro-4,7-methano-inden-1-one

Conditions
ConditionsYield
In 2,2,4-trimethylpentane Heating;100%
norborn-2-ene
498-66-8

norborn-2-ene

hexacarbonyl(2-methylbut-3-yn-2-ol)dicobalt

hexacarbonyl(2-methylbut-3-yn-2-ol)dicobalt

exo-3a,4,5,6,7,7a-Hexahydro-2-(1-hydroxymethylethyl)-4,7-methano-1H-inden-1-one

exo-3a,4,5,6,7,7a-Hexahydro-2-(1-hydroxymethylethyl)-4,7-methano-1H-inden-1-one

Conditions
ConditionsYield
With polymer-supported 4-methylmorpholine-N-oxide In dichloromethane at 20℃; for 2.5h; Cycloaddition; Pauson-Khand reaction;100%
With morpholine N-oxide resin In tetrahydrofuran at 20℃; for 0.5h; Cycloaddition; Pauson-Khand reaction;91%
norborn-2-ene
498-66-8

norborn-2-ene

N-((1R,2S,4R)-4-Bicyclo[2.2.1]hept-5-en-2-yl-benzenesulfonylmethyl)-formamide

N-((1R,2S,4R)-4-Bicyclo[2.2.1]hept-5-en-2-yl-benzenesulfonylmethyl)-formamide

polymer, copolymerization; monomers: N-[4-(exo-bicyclo[2.2.1]hept-5-en-1-yl)phenylsulfonylmethyl]formamide; norbornene

polymer, copolymerization; monomers: N-[4-(exo-bicyclo[2.2.1]hept-5-en-1-yl)phenylsulfonylmethyl]formamide; norbornene

Conditions
ConditionsYield
Stage #1: norborn-2-ene; N-((1R,2S,4R)-4-Bicyclo[2.2.1]hept-5-en-2-yl-benzenesulfonylmethyl)-formamide; Grubbs catalyst first generation In dichloromethane at 20℃; for 0.5h;
Stage #2: With ethyl vinyl ether Further stages.;
100%
norborn-2-ene
498-66-8

norborn-2-ene

bis(pinacol)diborane
73183-34-3

bis(pinacol)diborane

4,4,5,5-Tetramethyl-2-[3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)bicyclo[2.2.1]hept-2-yl]-1,3,2-dioxaborolane

4,4,5,5-Tetramethyl-2-[3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)bicyclo[2.2.1]hept-2-yl]-1,3,2-dioxaborolane

Conditions
ConditionsYield
With tris(bicyclo[2.2.1]heptene)palladium; triphenylphosphine at 20℃; for 2h;100%
norborn-2-ene
498-66-8

norborn-2-ene

poly(norbornene)

poly(norbornene)

Conditions
ConditionsYield
[=CHPh][1,3-(PhEt)2-2-imidazolinylidene][1-(2Py)Pr-2-O]RuCl2 In toluene at 60℃; for 0.25h; Product distribution; Further Variations:; Catalysts; Temperatures; Solvents;100%
With Allyl acetate; C45H84Cl2P2RuSi In toluene at 40℃;99%
With Allyl acetate; Grubbs catalyst first generation In toluene at 40℃;99%
norborn-2-ene
498-66-8

norborn-2-ene

trans(cis)-poly[norbornene]; Mn: 84000; PDI: 1.51

trans(cis)-poly[norbornene]; Mn: 84000; PDI: 1.51

Conditions
ConditionsYield
[2-methyliminomethyl-4-nitrophenol][PCy3][=CHPh]RuCl In chlorobenzene at 70℃; for 4h; Product distribution; Further Variations:; Catalysts;100%
norborn-2-ene
498-66-8

norborn-2-ene

poly(1,3-cyclopentylenevinylene), polydispersity index 1.31, cis configuration 23 percent; Monomer(s): norbornene

poly(1,3-cyclopentylenevinylene), polydispersity index 1.31, cis configuration 23 percent; Monomer(s): norbornene

Conditions
ConditionsYield
Schiff base substituted ruthenium benzylidene; 1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene In toluene at 70℃; for 4h; ring-opening metathesis polymerization;100%
norborn-2-ene
498-66-8

norborn-2-ene

iodobenzene
591-50-4

iodobenzene

Conditions
ConditionsYield
With formic acid; triethylamine; [Pd(Cl)(L-κ-C,N,N)] In dimethyl sulfoxide at 90℃; for 15h; Heck hydroarylation;100%
With formic acid; chloro[2-(3-methyl-3,7-diazabicyclo[3.3.1]nonan-3-ylmethyl)phenyl-C,N,N]palladium; triethylamine In dimethyl sulfoxide at 65℃; for 5h;99%
With formic acid; C19H23ClFeN2OPd; triethylamine In dimethyl sulfoxide at 65℃; for 5h; Heck Reaction;97%
With formic acid; 3-(2-(diphenylarsinyl)benzyl)-1-phenyl-1H-imidazol-3-ium chloride; triethylamine; bis(dibenzylideneacetone)-palladium(0) In dimethyl sulfoxide at 60℃; for 22h; Heck reaction; Inert atmosphere;86%
With formic acid; C18H12Cl2N2O2Pd; triethylamine In dimethyl sulfoxide at 65℃; for 5h;77%
norborn-2-ene
498-66-8

norborn-2-ene

poly(norbornene), Mn 2.50E5 Da, Mw/Mn 1.40 by GPC; monomer(s): norbornene

poly(norbornene), Mn 2.50E5 Da, Mw/Mn 1.40 by GPC; monomer(s): norbornene

Conditions
ConditionsYield
With (2,6-(2,6-iPr2C6H3N=CMe)2C5H3N)MoCl3; triethylaluminum In toluene at 25℃; for 6h;100%
norborn-2-ene
498-66-8

norborn-2-ene

poly(norbornene), Mn 2.59E5 Da, Mw/Mn 1.54 by GPC; monomer(s): norbornene

poly(norbornene), Mn 2.59E5 Da, Mw/Mn 1.54 by GPC; monomer(s): norbornene

Conditions
ConditionsYield
With (2,6-(2,6-iPr2C6H3N=CMe)2C5H3N)MoCl3; triethylaluminum In toluene at 60℃; for 6h;100%
norborn-2-ene
498-66-8

norborn-2-ene

poly(norbornene), Mn 2.83E5 Da, Mw/Mn 1.47 by GPC; monomer(s): norbornene

poly(norbornene), Mn 2.83E5 Da, Mw/Mn 1.47 by GPC; monomer(s): norbornene

Conditions
ConditionsYield
With (2,6-(2,6-iPr2C6H3N=CMe)2C5H3N)MoCl3; triethylaluminum In toluene at 25℃; for 6h;100%
norborn-2-ene
498-66-8

norborn-2-ene

poly(norbornene), Mn 3.02E5 Da, Mw/Mn 1.50 by GPC; monomer(s): norbornene

poly(norbornene), Mn 3.02E5 Da, Mw/Mn 1.50 by GPC; monomer(s): norbornene

Conditions
ConditionsYield
With (2,6-(2,6-iPr2C6H3N=CMe)2C5H3N)MoCl3; triethylaluminum In toluene at 60℃; for 6h;100%
norborn-2-ene
498-66-8

norborn-2-ene

poly(norbornene), Mn 2.41E5 Da, Mw/Mn 1.33 by GPC; monomer(s): norbornene

poly(norbornene), Mn 2.41E5 Da, Mw/Mn 1.33 by GPC; monomer(s): norbornene

Conditions
ConditionsYield
With 2,6-bis[1-(2,6-diethylphenylimino)ethyl]pyridine-MoCl3; triethylaluminum In toluene at 25℃; for 6h;100%
norborn-2-ene
498-66-8

norborn-2-ene

poly(norbornene), Mn 5.36E5 Da, Mw/Mn 1.50 by GPC; monomer(s): norbornene

poly(norbornene), Mn 5.36E5 Da, Mw/Mn 1.50 by GPC; monomer(s): norbornene

Conditions
ConditionsYield
With 2,6-bis[1-(2,6-diethylphenylimino)ethyl]pyridine-MoCl3; triethylaluminum In toluene at 60℃; for 6h;100%
norborn-2-ene
498-66-8

norborn-2-ene

poly(norbornene), Mn 5.48E5 Da, Mw/Mn 1.45 by GPC; monomer(s): norbornene

poly(norbornene), Mn 5.48E5 Da, Mw/Mn 1.45 by GPC; monomer(s): norbornene

Conditions
ConditionsYield
With (2,6-(2,6-iPr2C6H3N=CMe)2C5H3N)MoCl3; modified methylaluminoxane with AlMeO:Al-isoBuO In toluene at 60℃; for 12h;100%

Norbornylene Chemical Properties

Molecular Structure of Norbornylene (498-66-8):

EINECS: 207-866-0
IUPAC Name: Bicyclo[2.2.1]hept-2-ene 
Molecular Formula: C7H10
Molecular Weight: 94.154300 g/mol
XLogP3-AA: 2.4
H-Bond Donor: 0
H-Bond Acceptor: 0
Canonical SMILES: C1CC2CC1C=C2
InChI: InChI=1S/C7H10/c1-2-7-4-3-6(1)5-7/h1-2,6-7H,3-5H2
InChIKey: JFNLZVQOOSMTJK-UHFFFAOYSA-N
Index of Refraction: 1.519
Molar Refractivity: 29.93 cm3
Molar Volume: 98.5 cm3
Surface Tension: 35.4 dyne/cm
Density: 0.955 g/cm3
Enthalpy of Vaporization: 32.17 kJ/mol
Boiling Point: 96 °C at 760 mmHg
Vapour Pressure: 50.7 mmHg at 25 °C
Melting Point: 44-46 °C(lit.)
Water Solubility: 60.32 mg/L at 25 °C
Storage Temp.: 0-6 °C
BRN: 1098544

Norbornylene Toxicity Data With Reference

1.    

orl-rat LD50:11,300 mg/kg

    AIHAAP    American Industrial Hygiene Association Journal. 30 (1969),470.

Norbornylene Consensus Reports

Reported in EPA TSCA Inventory.

Norbornylene Safety Profile

Safety Information of Norbornylene (498-66-8):
Hazard Codes: F
Risk Statements: 11
11: Highly Flammable
Safety Statements: 9-16-29-33
9: Keep container in a well-ventilated place
16: Keep away from sources of ignition - No smoking
29: Do not empty into drains
33: Take precautionary measures against static discharges
RIDADR: UN 1325 4.1/PG 2
WGK Germany: 1
RTECS: RB7900000
HazardClass: 4.1
PackingGroup: II
F 13
Mildly toxic by ingestion. When heated to decomposition it emits acrid smoke and irritating fumes.

Norbornylene Specification

  Norbornylene (498-66-8) is stench white mass, known as Bicyclo(2.2.1)heptene ; 3,6-Endomethylenecyclohexene ; NSC 120425 ; Norbornene ; Norbornylene ; Norcamphene ; Norfenchene ; 8,9,10-Trinorborn-2-ene ; Bicyclo(2.2.1)hept-2-ene . It is incompatible with strong oxidizing agents. When heated to decomposition, it yields Carbon monoxide , Carbon dioxide .

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