Conditions | Yield |
---|---|
With sodium hydroxide; hydrogen sulfide 1.) methanol, 2.) pyridine, reflux , 2h; | 55% |
(Z,Z)-2,3,4,5-Tetrachlor-2,4-pentadienthiosaeure-S-pentachlorphenylester
A
pentachlorothiophenol
B
3,4,5-trichloro-α-pyrone
Conditions | Yield |
---|---|
With tin(IV) chloride for 6h; Heating; | A 25% B 55% |
diethyl ether
A
pentachlorothiophenol
B
acetophenone
D
phenacylacetophenone
Conditions | Yield |
---|---|
for 2h; Product distribution; Irradiation; | A 16% B 30% C 54% D n/a |
Conditions | Yield |
---|---|
With benzyltriethylammonium tetrathiomolybdate In N,N-dimethyl-formamide at 70℃; for 8h; | 20% |
With methanol; sodium hydrogensulfide at 120 - 140℃; | |
With pyridine; sodium hydrogensulfide; ethylene glycol | |
With methanol; sodium sulfide; sulfur | |
With sodium hydroxide; sodium hydrogensulfide; concentrated aqueous hydrochloric acid In N-methyl-acetamide; water |
Conditions | Yield |
---|---|
With hydrogenchloride; acetic acid; sodium nitrite anschliessend Behandeln mit einer wss. Loesung von Kalium-<O-aethyl-dithiocarbonat> und Natriumcarbonat und Erwaermen des danach erhaltenen Reaktionsprodukts mit einer wss.-aethanol. Natronlauge; |
pentachlorophenylsulphenyl chloride
Isobutane
A
pentachlorothiophenol
B
di(pentachlorophenyl)disulfide
C
t-Bu-pentachlorphenylsulfid
D
iso-Bu-pentachlorphenylsulfid
Conditions | Yield |
---|---|
With CFC-112a In tetrachloromethane Irradiation; |
pentachlorophenylsulphenyl chloride
cyclohexane
A
pentachlorothiophenol
B
cyclohexyl chloride
C
di(pentachlorophenyl)disulfide
D
Cyclohexyl-pentachlorphenyl-sulfid
Conditions | Yield |
---|---|
In tetrachloromethane Irradiation; Further byproducts given; |
Conditions | Yield |
---|---|
With pyridine; sodium hydrogensulfide |
sodium pentachlorobenzenethiolate
pentachlorothiophenol
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 76 percent / diethyl ether / 1 h / Ambient temperature 2: 25 percent / tin(IV) chloride / 6 h / Heating View Scheme |
pentachlorothiophenol
5-t-butyl-7-methyl-1-oxaspiro<2,5>octa-5,7-dien-4-one
6-t-butyl-1,2,3,4-tetrachloro-8-methylphenoxathiin
Conditions | Yield |
---|---|
With sodium hydroxide In ethanol for 1.5h; Mechanism; Heating; | 95% |
With sodium hydroxide In ethanol for 1.5h; Heating; | 95% |
With sodium hydroxide In ethanol Yield given; |
pentachlorothiophenol
1,2-bis(diphenylphosphino)ethane nickel(II) chloride
Conditions | Yield |
---|---|
Stage #1: pentachlorothiophenol With methyllithium In tetrahydrofuran; diethyl ether at 0 - 20℃; Inert atmosphere; Schlenk technique; Stage #2: 1,2-bis(diphenylphosphino)ethane nickel(II) chloride In tetrahydrofuran; diethyl ether for 2h; Inert atmosphere; Schlenk technique; | 93% |
Conditions | Yield |
---|---|
In toluene byproducts: C6H6; (Ar); standard Schlenk technique; HSC6Cl5 (3 equiv.) was added to soln. of Bi compd. in toluene; mixt. was refluxed for 96 h; solvent removed (vac., room temp.); residue washed (hexane); dried (vac.); elem. anal.; | 91% |
Conditions | Yield |
---|---|
In toluene | 82% |
In toluene | 82% |
In toluene | |
In toluene |
2,3-Dichloro-1,4-naphthoquinone
pentachlorothiophenol
2-chloro-3-((perchlorophenyl)thio)naphthalene-1,4-dione
Conditions | Yield |
---|---|
With sodium carbonate In ethanol for 6 - 8h; | 78% |
pentachlorothiophenol
5,7-di-t-butyl-1-oxaspiro<2.5>octa-5,7-dien-4-one
6,8-di-t-butyl-1,2,3,4-tetrachlorophenoxathiin
Conditions | Yield |
---|---|
With sodium hydroxide In ethanol for 1.5h; Heating; | 73% |
With sodium hydroxide In ethanol Yield given; |
pentachlorothiophenol
Methyl 2-acetamidoacrylate
2-acetamido-3-(pentachlorophenylsulfanyl)propionic acid methyl ester
Conditions | Yield |
---|---|
With Aliquat 336; potassium carbonate In tetrahydrofuran; toluene at 20℃; for 18h; sulfa-Michael addition; | 71% |
pentachlorothiophenol
Conditions | Yield |
---|---|
Stage #1: pentachlorothiophenol With lithium hydroxide In fluorobenzene at 20℃; for 0.5h; Schlenk technique; Inert atmosphere; Stage #2: S-difluoromethyl-S-phenyl-2,4,6-trimethoxyphenylsulfonium tetrafluoroborate In fluorobenzene at 20℃; Schlenk technique; Inert atmosphere; chemoselective reaction; | 69% |
pentachlorothiophenol
1,3-chlorobromopropane
pentachlorophenyl 3-chloropropyl sulfide
Conditions | Yield |
---|---|
With potassium hydroxide In ethanol for 2h; Inert atmosphere; Reflux; | 68% |
Conditions | Yield |
---|---|
With potassium hydroxide In ethanol for 2h; Heating; | 60% |
Conditions | Yield |
---|---|
In methanol; sodium hydroxide aq. NaOH; a soln. of the thiophenol in 0.1M aq.-methanolic NaOH wad added dropwise to a hot, filtered aq. soln. of the Cu-complex (molar ratio Cu-complex:Hpctp = 1 : 2);; the ppt. was immediately washed with water and diethyl ether; elem. anal.;; | 56% |
pentachlorothiophenol
5,6,8-trimethyl-1-oxaspiro<2,5>octa-5,7-dien-4-one
1,2,3,4-tetrachloro-6,7,9-trimethylphenoxathiin
Conditions | Yield |
---|---|
With sodium hydroxide In ethanol for 1.5h; Heating; | 47% |
With sodium hydroxide In ethanol Yield given; |
pentachlorothiophenol
4-Bromo-2,3,5,6-tetrachloropyridine
tetrachloro-4-(pentachlorophenylthio)pyridine
Conditions | Yield |
---|---|
With sodium carbonate In N,N-dimethyl-formamide for 2h; Heating; | 25% |
pentachlorothiophenol
N,N'-dichloro-1,4-benzoquinone diimine
Conditions | Yield |
---|---|
With sodium carbonate In 1,4-dioxane | 6% |
2-furancarbonyl chloride
pentachlorothiophenol
furan-2-carbothioic acid S-pentachlorophenyl ester
Conditions | Yield |
---|---|
With pyridine |
pentachlorothiophenol
thiophosgene
trithiocarbonic acid bis-pentachlorophenyl ester
Conditions | Yield |
---|---|
With sodium hydroxide |
pentachlorothiophenol
2-bromoethylamine hydrobromide
2-pentachlorophenylsulfanyl-ethylamine
Conditions | Yield |
---|---|
With sodium hydroxide |
pentachlorothiophenol
pentachlorophenylsulphenyl chloride
Conditions | Yield |
---|---|
With tetrachloromethane; chlorine | |
With chlorine | |
With iodine; chlorine In tetrachloromethane |
pentachlorothiophenol
di(pentachlorophenyl)disulfide
Conditions | Yield |
---|---|
With tetrachloromethane; phosphorus pentachloride | |
With sodium hydroxide; potassium hexacyanoferrate(III) | |
With dihydrogen peroxide In water |
pentachlorothiophenol
(2-chloro-ethyl)-pentachlorophenyl sulfide
Conditions | Yield |
---|---|
With potassium hydroxide; 1,2-dichloro-ethane |
Conditions | Yield |
---|---|
With sodium hydroxide; dimethyl sulfate | |
With ethanol; sodium ethanolate; methyl iodide |
pentachlorothiophenol
ethyl-pentachlorophenyl sulfide
Conditions | Yield |
---|---|
With ethanol; sodium ethanolate; ethyl iodide | |
With sodium hydroxide; diethyl sulfate |
pentachlorothiophenol
pentachloro-benzenesulfenyl bromide
Conditions | Yield |
---|---|
With hexane; bromine |
pentachlorothiophenol
pentachlorophenyl-vinyl sulfide
Conditions | Yield |
---|---|
With sodium carbonate; acetylene at 190℃; under 10297.1 Torr; |
pentachlorothiophenol
bis-pentachlorophenyl trisulfide
Conditions | Yield |
---|---|
With carbon disulfide; sulfur dichloride |
MF: C6HCl5S
MW: 282.402 g/mol
EINECS: 205-107-8
Sensitive: Stench
Density: 1.745 g/cm3
Flash Point: 144.6 °C
Index of Refraction: 1.648
Melting Point: 223-227 °C(lit.)
Enthalpy of Vaporization: 57.24 kJ/mol
Boiling Point: 351.3 °C at 760 mmHg
Vapour Pressure: 8.41E-05 mmHg at 25°C
IUPAC Name: 2,3,4,5,6-Pentachlorobenzenethiol
Synonyms: Pentachlorothiophenol;Pentachlorobenzenethiol;2,3,4,5,6-Pentachlorobenzenethiol;Akrochem Peptizer PTP;Benzenethiol, pentachloro-;Pctp;Pentachloro-benzenethio;Pentachlorthiofenol
Product Categories: Organics;Phenol&Thiophenol & Mercaptan
Following is the molecular structure of Pentachlorothiophenol (133-49-3):
Pentachlorothiophenol (133-49-3) is natural rubber, neoprene, nitrile rubber, styrene-butadiene rubber and butyl rubber, and plastic refining accelerator, as well as with Synthetic rubber composition of the regeneration of the higher doses. Applicable to high temperature and low temperature plastic plastic refining refining, sulfur may terminate the role of plastic solution. The product toxicity, no pollution, no smell vulcanized rubber, the rubber physical properties and aging properties of no effect. The product with the zinc sulfate solution, the reaction of thiophenol five zinc chloride can be used as natural rubber plasticating accelerator, high, low use of technology showed a significant catalytic role, suitable for open mill and mixer. 5 Chloro thiophenol zinc vulcanizate physical properties, aging properties, as well as chlorine taste and so no effect can be used for light-colored products. The product of real material with mineral mixtures nearly equal weight, then adding a small amount of organic activator, that is composed of five chloro-thiophenol compound, also be used as natural rubber, polybutadiene rubber, isoamyl rubber, styrene-butadiene rubber, NBR rubber, neoprene, butyl rubber and other unsaturated bond-containing rubber peptizer, low temperatures can also have a good solution of the role of plastic. The role of a small amount of sulfur solution for termination of its plastic effects.
Manufacturing methd of Pentachlorothiophenol (133-49-3):Pentachlorothiophenol is formed by HCB reaction with sodium hydrosulfide, with dimethyl formamide and other organic solvents as solvent. Reaction of the five chlorine thiophenol in the reaction system and then with sodium hydrosulfide, resulting in five thiophenol sodium chloride and hydrogen sulfide. Then, hydrochloric acid 5 sodium chloride precipitates thiophenol thiophenol pentachlorophenol, and then filtering, washing, drying, that is to be finished five chlorine thiophenol.
1. | eye-rbt 500 mg/24H SEV | 28ZPAK Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku Marhold, J.V.,Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha,Czechoslovakia.: 1972,168. | ||
2. | orl-rat LD50:11,900 g/kg | 28ZPAK Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku Marhold, J.V.,Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha,Czechoslovakia.: 1972,168. | ||
3. | ipr-mus LD50:100 mg/kg | NTIS** National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) AD277-689 . |
Chlorophenol compounds are on The Community Right-To-Know List. Reported in EPA TSCA Inventory.
Poison by intraperitoneal route. Mildly toxic by ingestion. Severe eye irritant. When heated to decomposition it emits very toxic fumes of SOx and Cl−.
Safety Information of Pentachlorothiophenol (133-49-3):
RIDADR: UN 3335
WGK Germany: 3
RTECS: DC1925000
Hazard Note: Harmful/Stench
Hazardous Substances Data: 133-49-3(Hazardous Substances Data)
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