• Name

  Pentaerythritol glycidyl ether

• EINECS 221-507-5
• CAS No. 3126-63-4
• Article Data8
• CAS DataBase
• Density 1.269 g/cm³
• Solubility
• Melting Point
• Formula C17H28 O8
• Boiling Point 483.5 °C at 760 mmHg
• Molecular Weight 360.405
• Flash Point 199.3 °C
• Transport Information
• Appearance
• Safety Human mutation data reported. When heated to decomposition it emits acrid smoke and irritating vapors.
• Risk Codes
• Molecular Structure
• Hazard Symbols
• Synonyms Oxirane,2,2'-[[2,2-bis[(oxiranylmethoxy)methyl]-1,3-propanediyl]bis(oxymethylene)]bis-(9CI); Propane, 1,3-bis(2,3-epoxypropoxy)-2,2-bis[(2,3-epoxypropoxy)methyl]-(7CI,8CI); 1,1,1,1-Tetra(glycidyloxymethyl)methane; Pentaerythritol glycidylether; Pentaerythritol tetraglycidyl ether
• PSA 87.04000
• LogP -0.36560

Synthetic route

1471-18-7

pentaerythritol tetraallyl ether

3126-63-4

pentaerythritol tetraglycidyl ether

Conditions

Conditions	Yield
With 3-chloro-benzenecarboperoxoic acid In chloroform at 22℃; for 72.67h;	92%
With 3-chloro-benzenecarboperoxoic acid In chloroform at 22℃; for 72h;	92%
With 3-chloro-benzenecarboperoxoic acid In chloroform at 22℃; for 72h;	91%
With sodium silicate; dihydrogen peroxide In methanol; water; acetonitrile at 40℃; for 9h; Solvent; Reagent/catalyst; Temperature; Time; Concentration; Inert atmosphere;	62%

115-77-5

Pentaerythritol

106-89-8

epichlorohydrin

3126-63-4

pentaerythritol tetraglycidyl ether

Conditions

Conditions	Yield
With sodium hydroxide In water at 20 - 50℃; for 30h;	86%
With potassium hydroxide In dimethyl sulfoxide at 20 - 35℃; for 7h;	37%
With potassium hydroxide In dimethyl sulfoxide at 35℃; for 7h;	79 % Chromat.

115-77-5

Pentaerythritol

106-89-8

epichlorohydrin

A

3126-63-4

pentaerythritol tetraglycidyl ether

B

trimethylolpropane triglycidyl ether

Conditions

Conditions	Yield
With potassium hydroxide In dimethyl sulfoxide	A 78% B 15%

...Expand

115-77-5

Pentaerythritol

106-89-8

epichlorohydrin

A

dimer of pentaerythritol tetraglycidyl ether

B

3126-63-4

pentaerythritol tetraglycidyl ether

C

trimethylolpropane triglycidyl ether

Conditions

Conditions	Yield
With potassium hydroxide In water; dimethyl sulfoxide at 15 - 20℃; Cooling with ice;	A n/a B 60% C n/a
With potassium hydroxide In dimethyl sulfoxide at 15 - 20℃;	A n/a B 45% C n/a

...Expand

115-77-5

Pentaerythritol

2096-86-8

p-Tolylaceton

3126-63-4

pentaerythritol tetraglycidyl ether

Conditions

Conditions	Yield
With potassium permanganate; KOH In diethyl ether; dimethyl sulfoxide; epichlorohydrin

115-77-5

Pentaerythritol

3126-63-4

pentaerythritol tetraglycidyl ether

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: potassium hydroxide; tetrabutylammomium bromide / tetrahydrofuran / 24 h / 70 °C 2: 3-chloro-benzenecarboperoxoic acid / chloroform / 72 h / 22 °C View Scheme
Multi-step reaction with 2 steps 1: potassium hydroxide; tetrabutylammomium bromide / tetrahydrofuran / 24 h / 70 °C 2: 3-chloro-benzenecarboperoxoic acid / chloroform / 72 h / 22 °C View Scheme

3126-63-4

pentaerythritol tetraglycidyl ether

103-49-1

dibenzylamine

C69H81N5O8

Conditions

Conditions	Yield
In methanol at 22 - 45℃; for 48.17h;	99%

110-85-0

piperazine

3126-63-4

pentaerythritol tetraglycidyl ether

893411-77-3

pentaerythritol tetra(2-hydroxypropyl-3-piperazine)

Conditions

Conditions	Yield
In methanol at 25℃; for 24.08h;	97%

120-43-4

4-ethoxycarbonylpiperazine

3126-63-4

pentaerythritol tetraglycidyl ether

893411-80-8

pentaerythritol tetra(2-hydroxy-3-piperazine-N-ethyl carboxylate)

Conditions

Conditions	Yield
In methanol at 25℃; for 1.33333h;	95%

3126-63-4

pentaerythritol tetraglycidyl ether

914111-40-3

pentaerythritol tetra(2-propanol-3-azide) ether

Conditions

Conditions	Yield
With sodium azide; ammonium chloride In water; N,N-dimethyl-formamide at 50℃;	95%
With sodium azide; ammonium chloride In water; N,N-dimethyl-formamide at 50℃; Reflux;	95%

3126-63-4

pentaerythritol tetraglycidyl ether

75-55-8, 41927-28-0, 76612-76-5, 76612-77-6, 205537-16-2

2-Methylaziridine

C29H56N4O8

Conditions

Conditions	Yield
In methanol at 20℃;	93%

4097-89-6

2,2',2''-triaminotriethylamine

3126-63-4

pentaerythritol tetraglycidyl ether

A

C35H82N12O8

B

C41H100N16O8

Conditions

Conditions	Yield
In methanol at 25℃; for 24h;	A n/a B 92%

...Expand

4097-89-6

2,2',2''-triaminotriethylamine

3126-63-4

pentaerythritol tetraglycidyl ether

C41H100N16O8

Conditions

Conditions	Yield
In methanol at 25℃; for 24h; Inert atmosphere;	92%

111-94-4

3,3'-Iminodipropionitrile

3126-63-4

pentaerythritol tetraglycidyl ether

C41H64N12O8

Conditions

Conditions	Yield
In methanol at 60℃; for 72h;	90%

6290-05-7

Diethyl iminodiacetate

3126-63-4

pentaerythritol tetraglycidyl ether

A

C41H73N3O20

B

914111-61-8

C49H88N4O24

Conditions

Conditions	Yield
In methanol at 60℃; for 60.5h;	A n/a B 89.4%

...Expand

6290-05-7

Diethyl iminodiacetate

3126-63-4

pentaerythritol tetraglycidyl ether

914111-61-8

C49H88N4O24

Conditions

Conditions	Yield
In ethanol at 20 - 60℃; for 60h; Inert atmosphere; Reflux;	89.4%

3126-63-4

pentaerythritol tetraglycidyl ether

124-02-7

diallylamine

C41H72N4O8

Conditions

Conditions	Yield
In methanol at 60℃; for 48.33 - 64h;	89%

112-30-1

1-Decanol

3126-63-4

pentaerythritol tetraglycidyl ether

1-decyloxy-3-[3-(3-decyloxy-2-hydroxy-propoxy)-2,2-bis-(3-decyloxy-2-hydroxy-propoxymethyl)-propoxy]-propan-2-ol

Conditions

Conditions	Yield
Stage #1: 1-Decanol With potassium Stage #2: pentaerythritol tetraglycidyl ether at 80℃; for 24h;	74%
With potassium at 60℃; for 8h;

893411-77-3

pentaerythritol tetra(2-hydroxypropyl-3-piperazine)

3126-63-4

pentaerythritol tetraglycidyl ether

C149H300N32O40

Conditions

Conditions	Yield
With potassium carbonate In water at 22 - 45℃; for 48.17h;	64.5%

3126-63-4

pentaerythritol tetraglycidyl ether

77-86-1

2-amino-2-hydroxymethyl-1,3-propanediol

C33H72N4O20

Conditions

Conditions	Yield
In methanol at 60℃; for 48h;	31%
In methanol at 20 - 60℃; for 64h; Inert atmosphere; Reflux;	31%

3126-63-4

pentaerythritol tetraglycidyl ether

893411-65-9

tetra(episulfide)

Conditions

Conditions	Yield
With lithium tetrafluoroborate; thiourea In acetonitrile at 60℃;	29%
With LiBF4; thiourea In water; acetonitrile	29%

3126-63-4

pentaerythritol tetraglycidyl ether

C17H32O20S4(4-)*4Na(1+)

Conditions

Conditions	Yield
With sodium disulfite; sodium hydrogensulfite In methanol; water at 25℃; for 24.37 - 24.38h;	15%

110-91-8

morpholine

3126-63-4

pentaerythritol tetraglycidyl ether

A

C23H44N2O8

B

C27H53N3O9

Conditions

Conditions	Yield
In methanol at 20℃;

...Expand

120-43-4

4-ethoxycarbonylpiperazine

3126-63-4

pentaerythritol tetraglycidyl ether

A

893411-80-8

pentaerythritol tetra(2-hydroxy-3-piperazine-N-ethyl carboxylate)

B

C31H56N4O12

C

911415-32-2

C38H70N6O14

Conditions

Conditions	Yield
In methanol at 25 - 40℃; for 6 - 24h; Product distribution / selectivity;

...Expand

534-26-9

lysidine

3126-63-4

pentaerythritol tetraglycidyl ether

C33H60N8O8

Conditions

Conditions	Yield
In methanol at 20℃; for 72h;

1361051-96-8

N-(3-methylbutan-2-ylidene)-2-(piperazin-1-yl)ethanamine

3126-63-4

pentaerythritol tetraglycidyl ether

A

C39H74N6O8

B

C50H97N9O8

C

C61H120N12O8

Conditions

Conditions	Yield
In methanol at 25℃; for 48h; Product distribution / selectivity;

...Expand

893412-17-4

dithiothreitol

3126-63-4

pentaerythritol tetraglycidyl ether

A

911415-36-6

C41H67N5O16S

B

911415-37-7

C65H106N10O24S2

Conditions

Conditions	Yield
In methanol at 20℃; for 72h; Product distribution / selectivity;

...Expand

893412-17-4

dithiothreitol

3126-63-4

pentaerythritol tetraglycidyl ether

A

911415-36-6

C41H67N5O16S

B

911415-37-7

C65H106N10O24S2

C

911415-38-8

C89H145N15O32S3

D

911415-39-9

C113H184N20O40S4

Conditions

Conditions	Yield
In methanol at 20 - 45℃; for 48h; Product distribution / selectivity;

...Expand

911415-27-5

4-methyl-N-(2-(piperazin-1-yl)ethyl)pentan-2-imine

3126-63-4

pentaerythritol tetraglycidyl ether

A

911415-29-7

C65H128N12O8

B

C41H78N6O8

C

911415-28-6

C53H103N9O8

Conditions

Conditions	Yield
In methanol at 25℃; for 48h; Reactivity;

...Expand

911415-27-5

4-methyl-N-(2-(piperazin-1-yl)ethyl)pentan-2-imine

3126-63-4

pentaerythritol tetraglycidyl ether

911415-28-6

C53H103N9O8

Conditions

Conditions	Yield
In methanol at 40℃; for 24h; Product distribution / selectivity;

911415-27-5

4-methyl-N-(2-(piperazin-1-yl)ethyl)pentan-2-imine

3126-63-4

pentaerythritol tetraglycidyl ether

911415-29-7

C65H128N12O8

Conditions

Conditions	Yield
In methanol at 60℃;

PENTAERYTHRITOL GLYCIDYL ETHER Chemical Properties

The molecular formula of Pentaerythritol glycidyl ether(3126-63-4) is C₁₇H₂₈O₈ and its formula weight is 360.45g/mol.Its EINECS is 221-507-5.The density of Pentaerythritol glycidyl ether(3126-63-4) is 1.269 g/cm³.The boiling point is 483.5 °C at 760 mmHg .The refractive index is about 1.518 and molar refractivity is 86.05 cm³.Surface Ttension is 54.8 dyne/cm and enthalpy of vaporization is 72.01 kJ/mol.Its fiash point is 199.3 °C and the vapor pressenge is 4.89E-09 mmHg at 25°C .The chemical synonyms of  Pentaerythritol glycidyl ether(3126-63-4) are 1,3-bis(2,3-epoxypropoxy)-2,2-bis[(2,3-epoxypropoxy)methyl]propane;PENTAERYTHRITOL,TETRAGLYCIDYLETHER;Pentaerythritol glycidyl ether;1,3-Bis(glycidyloxy)-2,2-bis(glycidyloxymethyl)propane;1,3-Bis(oxiranylmethoxy)-2,2-bis(oxiranylmethoxymethyl)propane;2,2'-[[2,2-Bis(oxiran-2-ylmethoxymethyl)-1,3-propanediyl]bis(oxymethylene)]bisoxirane and Tetrakis(glycidyloxymethyl)methane.
The molecular structure of  Pentaerythritol glycidyl ether(3126-63-4) is  .

PENTAERYTHRITOL GLYCIDYL ETHER Toxicity Data With Reference

PENTAERYTHRITOL GLYCIDYL ETHER Safety Profile

PENTAERYTHRITOL GLYCIDYL ETHER Specification