Pentaerythritol tetraacrylate supplier

Name
Pentaerythritol tetraacrylate
EINECS 225-644-1
CAS No. 4986-89-4
Article Data12
CAS DataBase
Density 1.16 g/cm³
Solubility
Melting Point 18ºC
Formula C17H20 O8
Boiling Point 450.3 ºC at 760 mmHg
Molecular Weight 352.341
Flash Point 196 ºC
Transport Information
Appearance
Safety 26-39
Risk Codes 36/38-43
Molecular Structure
Hazard Symbols Xi
Synonyms 2-Propenoicacid, 2,2-bis[[(1-oxo-2-propenyl)oxy]methyl]-1,3-propanediyl ester (9CI);Acrylic acid, neopentanetetrayl ester (7CI); Acrylic acid, tetraester withpentaerythritol (8CI); A-TMMT; Aronix M 450; BS 710; Beam Set 710; KayaradA-TMMT; Kayarad PET 40; Kayarad SR 295; Light Acrylate PE 4A; M 450; NK EsterA-TMMT; NK Ester A-YMMT; Pentaerythritol tetraacrylate; Pentaerythritoltetracrylate; SR 295; SR 295 (acrylate); Saret SR 295; Sartomer 295; SartomerSR 295; Tetramethylolmethane tetraacrylate; Tetramethylolmethane tetracrylate;Viscoat 400
PSA 105.20000
LogP 0.88960

Synthetic route

: 115-77-5
Pentaerythritol

: 814-68-6
acryloyl chloride

: 4986-89-4
pentaerythritol tetraacrylate

Conditions

Conditions	Yield
With triethylamine In dichloromethane at 0 - 20℃; for 2.5h;	96.6%
With triethylamine In dichloromethane at 0℃; Inert atmosphere;

: 504-61-0
(E)-but-2-enol

: 115-77-5
Pentaerythritol

: 150-76-5
4-methoxy-phenol

: 79-10-7
acrylic acid

: 4986-89-4
pentaerythritol tetraacrylate

Conditions

Conditions	Yield
In Petroleum ether

...Expand

: 115-77-5
Pentaerythritol

: 3121-61-7
2-methoxyethyl acrylate

A: 2,2-bis(hydroxymethyl)-1,3-propanediyl diacrylate

B: 4986-89-4
pentaerythritol tetraacrylate

C: 3524-68-3
pentaerythritol triacrylate

Conditions

Conditions	Yield
With zinc diacetate; oxygen; 4-methoxy-phenol; 1,8-diazabicyclo[5.4.0]undec-7-ene at 105 - 120℃; for 5h; Reagent/catalyst; Inert atmosphere; Overall yield = 48 %;

...Expand

: 115-77-5
Pentaerythritol

: 3121-61-7
2-methoxyethyl acrylate

A: 4986-89-4
pentaerythritol tetraacrylate

B: 3524-68-3
pentaerythritol triacrylate

Conditions

Conditions	Yield
With 1,4-diaza-bicyclo[2.2.2]octane; zinc diacetate; oxygen; 4-methoxy-phenol at 105 - 120℃; under 130 - 760 Torr; for 30h; Inert atmosphere; Overall yield = 96 %;
With 1,4-diaza-bicyclo[2.2.2]octane; zinc diacetate; oxygen; 4-methoxy-phenol at 105 - 120℃; under 130 - 760 Torr; for 30h; Catalytic behavior; Reagent/catalyst; Inert atmosphere; Overall yield = 88 %;
With 1,4-diaza-bicyclo[2.2.2]octane; zinc diacetate; oxygen; 4-methoxy-phenol at 105 - 120℃; under 130 - 760 Torr; for 30h; Catalytic behavior; Reagent/catalyst; Inert atmosphere; Overall yield = 88 %;

...Expand

: 115-77-5
Pentaerythritol

: 140-88-5
ethyl acrylate

: 4986-89-4
pentaerythritol tetraacrylate

Conditions

Conditions	Yield
With 2CF3O3S(1-)(x)C7H8C26H42Hf(2+) In acetonitrile at 20℃; for 12h; Green chemistry;

: 616-38-6
carbonic acid dimethyl ester

: 3524-68-3
pentaerythritol triacrylate

A: C14H20O11

B: C16H20O9

C: C15H20O10

D: 4986-89-4
pentaerythritol tetraacrylate

Conditions

Conditions	Yield
With potassium carbonate In N,N-dimethyl-formamide at 80℃; for 0.5h; Inert atmosphere; Overall yield = 3.8 g;

...Expand

: 115-77-5
Pentaerythritol

: 79-10-7
acrylic acid

: 4986-89-4
pentaerythritol tetraacrylate

Conditions

Conditions	Yield
With methanesulfonic acid; hypophosphorous acid; copper(l) chloride In toluene at 70℃; Inert atmosphere;
With hypophosphorous acid; toluene-4-sulfonic acid; 4-methoxy-phenol In toluene at 82℃; under 225.023 Torr;

: 115-77-5
Pentaerythritol

: 108-24-7
acetic anhydride

: 79-10-7
acrylic acid

A: 51690-75-6
Pentaerithrit-triacetat-acrylat

B: C15H20O8

C: C16H20O8

D: 4986-89-4
pentaerythritol tetraacrylate

Conditions

Conditions	Yield
Stage #1: Pentaerythritol; acrylic acid With methanesulfonic acid; 4-methoxy-phenol; copper(l) chloride In water; toluene at 75℃; under 1125.11 Torr; for 15h; Inert atmosphere; Stage #2: acetic anhydride With methanesulfonic acid; 4-methoxy-phenol In toluene at 35 - 40℃; for 1h; Inert atmosphere;

...Expand

: 108-24-7
acetic anhydride

: 3524-68-3
pentaerythritol triacrylate

A: 51690-75-6
Pentaerithrit-triacetat-acrylat

B: C15H20O8

C: C16H20O8

D: 4986-89-4
pentaerythritol tetraacrylate

Conditions

Conditions	Yield
With triethylamine In dichloromethane at 20℃; for 2.5h; Inert atmosphere;

...Expand

: 108-24-7
acetic anhydride

: 3524-68-3
pentaerythritol triacrylate

A: C15H20O8

B: C16H20O8

C: 4986-89-4
pentaerythritol tetraacrylate

Conditions

Conditions	Yield
With methanesulfonic acid at 20℃; for 0.5h; Inert atmosphere;

...Expand

: 110-91-8
morpholine

: 2783-17-7
1,12-Diaminododecane

: 4986-89-4
pentaerythritol tetraacrylate

: C62H104N6O20

Conditions

Conditions	Yield
Stage #1: 1,12-Diaminododecane; pentaerythritol tetraacrylate In methanol at 25℃; for 18h; Michael addition; Stage #2: morpholine In methanol at 20℃; for 18h; Further stages.;	99%

...Expand

: 4986-89-4
pentaerythritol tetraacrylate

: 112-55-0
1-dodecylthiol

: pentaerythritol tetrakis(3-n-dodecylthiopropionate)

Conditions

Conditions	Yield
With potassium tert-butylate; acetic acid at 40 - 55℃; for 8h; pH=6 - 7; Reagent/catalyst; Inert atmosphere;	97.8%

: 110-91-8
morpholine

: 124-09-4
1,6-Hexanediamine

: 4986-89-4
pentaerythritol tetraacrylate

: C122H204N14O44

Conditions

Conditions	Yield
Stage #1: 1,6-Hexanediamine; pentaerythritol tetraacrylate In methanol at 25℃; for 18h; Michael addition; Stage #2: morpholine In methanol at 20℃; for 19h; Further stages.;	97%

...Expand

: 110-91-8
morpholine

: 4986-89-4
pentaerythritol tetraacrylate

: 110-60-1
1,4-diaminobutane

: C120H200N14O44

Conditions

Conditions	Yield
Stage #1: pentaerythritol tetraacrylate; 1,4-diaminobutane In methanol at 25℃; for 18h; Michael addition; Stage #2: morpholine In methanol at 20℃; for 18h; Further stages.;	96%

...Expand

: 96-27-5
rac-3-sulfanylpropane-1,2-diol

: 4986-89-4
pentaerythritol tetraacrylate

: C25H44O16S4

Conditions

Conditions	Yield
With triethylamine In dimethyl sulfoxide at 20℃; for 0.5h;	95.9%

: 4986-89-4
pentaerythritol tetraacrylate

: 107-15-3
ethylenediamine

: C53H68N2O24

Conditions

Conditions	Yield
In methanol at 30℃; for 18h; Michael addition;	95%

: 110-91-8
morpholine

: 2783-17-7
1,12-Diaminododecane

: 4986-89-4
pentaerythritol tetraacrylate

: C128H216N14O44

Conditions

Conditions	Yield
Stage #1: 1,12-Diaminododecane; pentaerythritol tetraacrylate In methanol at 25℃; for 18h; Michael addition; Stage #2: morpholine In methanol at 20℃; for 18h; Further stages.;	94%

...Expand

: 4986-89-4
pentaerythritol tetraacrylate

polymer resin; monomer(s): pentaerythritol tetraacrylate: polymer resin; monomer(s): pentaerythritol tetraacrylate

Conditions

Conditions	Yield
With hydroxyethyl cellulose; xylene; dibenzoyl peroxide In water at 80℃; for 8h; Product distribution; Further Variations:; Reagents;	93%

: 110-91-8
morpholine

: 4986-89-4
pentaerythritol tetraacrylate

: 110-60-1
1,4-diaminobutane

: C54H88N6O20

Conditions

Conditions	Yield
Stage #1: pentaerythritol tetraacrylate; 1,4-diaminobutane In methanol at 25℃; for 18h; Michael addition; Stage #2: morpholine In methanol at 20℃; for 18h; Further stages.;	93%

...Expand

: 110-91-8
morpholine

: 124-09-4
1,6-Hexanediamine

: 4986-89-4
pentaerythritol tetraacrylate

: C93H157N11O33

Conditions

Conditions	Yield
Stage #1: 1,6-Hexanediamine; pentaerythritol tetraacrylate In methanol at 25℃; for 18h; Michael addition; Stage #2: morpholine In methanol at 20℃; for 19h; Further stages.;	89%

...Expand

: 110-91-8
morpholine

: 4986-89-4
pentaerythritol tetraacrylate

: 111-40-0
1,5-diamino-3-azapentane

: C120H201N15O44

Conditions

Conditions	Yield
Stage #1: pentaerythritol tetraacrylate; 3-azapentane-1,5-diamine In methanol at 25℃; for 18h; Michael addition; Stage #2: morpholine In methanol at 20℃; for 18h; Further stages.;	84%

...Expand

: 33941-15-0
1-aza-18-crown-6

: 4986-89-4
pentaerythritol tetraacrylate

: 3-(1,4,7,10,13-pentaoxa-16-aza-cyclooctadec-16-yl)-propionic acid 3-(3-1,4,7,10,13-pentaoxa-16-aza-cyclooctadec-16-yl-propionyloxy)-2,2-bis-(3-1,4,7,10,13-pentaoxa-16-aza-cyclooctadec-16-yl-propionyloxymethyl)-propyl ester

Conditions

Conditions	Yield
In methanol at 50℃; for 24h; Michael addition;	82.5%

: 4986-89-4
pentaerythritol tetraacrylate

: 66943-05-3
1,4,7,10-tetraoxa-15-azacyclopentadecane

: 3-(1,4,7,10-tetraoxa-13-aza-cyclopentadec-13-yl)-propionic acid 3-(3-1,4,7,10-tetraoxa-13-aza-cyclopentadec-13-yl-propionyloxy)-2,2-bis-(3-1,4,7,10-tetraoxa-13-aza-cyclopentadec-13-yl-propionyloxymethyl)-propyl ester

Conditions

Conditions	Yield
In methanol at 50℃; for 24h; Michael addition;	82.1%

: trichlorogermane etherate

: 4986-89-4
pentaerythritol tetraacrylate

: 742108-47-0
(Cl3GeC2H4CO2CH2)4C

Conditions

Conditions	Yield
In neat (no solvent) acrylate was added dropwise to Ge compd.; mixt. was stirred at room temp. overnight;	77%

: 4986-89-4
pentaerythritol tetraacrylate

: 829-85-6
diphenylphosphane

: C65H64O8P4

Conditions

Conditions	Yield
In 2-methyltetrahydrofuran at 90℃; for 12h; Inert atmosphere; Sealed tube; Green chemistry; regioselective reaction;	72%

: 60835-71-4
4'-aminobenzo-15-crown-5-ether

: 4986-89-4
pentaerythritol tetraacrylate

: C73H104N4O28

Conditions

Conditions	Yield
With triethylamine In methanol at 50℃; for 144h; Michael addition;	68%

: 83585-61-9
2-(aminomethyl)-18-crown-6

: 4986-89-4
pentaerythritol tetraacrylate

: 3-[(1,4,7,10,13,16-Hexaoxa-cyclooctadec-2-ylmethyl)-amino]-propionic acid 3-{3-[(1,4,7,10,13,16-hexaoxa-cyclooctadec-2-ylmethyl)-amino]-propionyloxy}-2,2-bis-{3-[(1,4,7,10,13,16-hexaoxa-cyclooctadec-2-ylmethyl)-amino]-propionyloxymethyl}-propyl ester

Conditions

Conditions	Yield
In methanol at 50℃; for 24h; Michael addition;	67.5%

: 83585-56-2
2-aminomethyl-15-crown-5

: 4986-89-4
pentaerythritol tetraacrylate

: 3-[(1,4,7,10,13-Pentaoxa-cyclopentadec-2-ylmethyl)-amino]-propionic acid 3-{3-[(1,4,7,10,13-pentaoxa-cyclopentadec-2-ylmethyl)-amino]-propionyloxy}-2,2-bis-{3-[(1,4,7,10,13-pentaoxa-cyclopentadec-2-ylmethyl)-amino]-propionyloxymethyl}-propyl ester

Conditions

Conditions	Yield
In methanol at 50℃; for 24h; Michael addition;	66%

: 68941-06-0
4-aminobenzo-18-crown-6

: 4986-89-4
pentaerythritol tetraacrylate

: C81H120N4O32

Conditions

Conditions	Yield
With triethylamine In methanol at 50℃; for 144h; Michael addition;	65%

: 4986-89-4
pentaerythritol tetraacrylate

polymer, photopolymerization; monomer(s): pentaerythritol tetraacrylate: polymer, photopolymerization; monomer(s): pentaerythritol tetraacrylate

Conditions

Conditions	Yield
With 2,2-dimethoxy-2-phenylacetophenone under 56704.5 Torr; for 0.168333h; Kinetics; Product distribution; UV-irradiation;	38.6%

: 4986-89-4
pentaerythritol tetraacrylate

poly(pentaerythritol tetraacrylate); monomer(s): pentaerythritol tetraacrylate: poly(pentaerythritol tetraacrylate); monomer(s): pentaerythritol tetraacrylate

Conditions

Conditions	Yield
With Synperonic(R) F-68 In acetone at 60℃; for 0.75h; UV-irradiation;
With 2,2'-azobis(isobutyronitrile) In ethanol; toluene at 60℃;

: 7307-55-3
1-undecylamine

: 4986-89-4
pentaerythritol tetraacrylate

A: C28H45NO8

B: C45H65NO16

Conditions

Conditions	Yield
In methanol at 4 - 20℃; Product distribution; Further Variations:; educt ratio; Michael addition;

...Expand

: 110-58-7
1-pentanamine

: 4986-89-4
pentaerythritol tetraacrylate

: C22H33NO8

Conditions

Conditions	Yield
In methanol at 4 - 20℃; Michael addition;

: 110-58-7
1-pentanamine

: 4986-89-4
pentaerythritol tetraacrylate

A: C22H33NO8

B: C39H53NO16

Conditions

Conditions	Yield
In methanol at 4 - 20℃; Product distribution; Further Variations:; educt ratio; Michael addition;

...Expand

: thiomalic acid di(perfluorohexylethylester)

: 4986-89-4
pentaerythritol tetraacrylate

: C37H32F26O12S

Conditions

Conditions	Yield
triethylamine In ethyl acetate at 50℃; for 3h; Michael Condensation;

: 886463-08-7
2-benzyl-2-N,N-dimethylamino-1-[4-piperazinophenyl]-1-butanone

: 4986-89-4
pentaerythritol tetraacrylate

: C109H144N12O12

Conditions

Conditions	Yield
1,8-diazabicyclo[5.4.0]undec-7-ene In toluene for 6h; Heating / reflux;

: 886463-09-8
2-methyl-2-morpholin-4-yl-1-(4-piperazinylphenyl)propan-1-one

: 4986-89-4
pentaerythritol tetraacrylate

: C89H128N12O16

Conditions

Conditions	Yield
1,8-diazabicyclo[5.4.0]undec-7-ene In toluene for 6h; Heating / reflux;

Pentaerythritol tetraacrylate Chemical Properties

Molecular structure of Pentaerythritol tetraacrylate (CAS NO.4986-89-4) is:

Product Name: Pentaerythritol tetraacrylate
CAS Registry Number: 4986-89-4
IUPAC Name: [3-Prop-2-enoyloxy-2,2-bis(prop-2-enoyloxymethyl)propyl] prop-2-enoate
Molecular Weight: 352.3359 [g/mol]
Molecular Formula: C₁₇H₂₀O₈
XLogP3-AA: 2.3
H-Bond Donor: 0
H-Bond Acceptor: 8
EINECS: 225-644-1
Melting Point: 18°C
Refractive index: n20/D 1.487(lit.)
Index of Refraction: 1.483
Molar Refractivity: 86.77 cm³
Molar Volume: 303.5 cm³
Surface Tension: 39 dyne/cm
Density: 1.16 g/cm³
Flash Point: 196 °C
Enthalpy of Vaporization: 70.92 kJ/mol
Boiling Point: 450.3 °C at 760 mmHg
Vapour Pressure: 2.66E-08 mmHg at 25°C
Other Registry Number: 113674-04-7 ;124538-16-5 ;150315-46-1 ;152992-37-5 ;154303-16-9 ;255831-13-1
;93218-05-4
Product Categories: Functional Monomer;Acrylic Monomers;C₁₂to C₆₃Monomers;Carbonyl Compounds;Esters;Polyfunctional Acrylics
Canonical SMILES: C=CC(=O)OCC(COC(=O)C=C)(COC(=O)C=C)COC(=O)C=C
InChI: InChI=1S/C17H20O8/c1-5-13(18)22-9-17(10-23-14(19)6-2,11-24-15(20)7-3)12-25-16(21)8-4/h5-8H,1-4,9-12H2
InChIKey: KNSXNCFKSZZHEA-UHFFFAOYSA-N

Pentaerythritol tetraacrylate Safety Profile

Safty information about Pentaerythritol tetraacrylate (CAS NO.4986-89-4) is:
Hazard Codes: Irritant Xi
Risk Statements: 36/38-43
R36/38:Irritating to eyes and skin.
R43:May cause sensitization by skin contact.
Safety Statements: 26-39
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S39:Wear eye / face protection.
WGK Germany: 1

Pentaerythritol tetraacrylate Specification

Pentaerythritol tetraacrylate , its cas register number is 4986-89-4. It also can be called 2,2-Bis(((1-oxoallyl)oxy)methyl)-1,3-propanediyl diacrylate ; 2-Propenoic acid, 1,1'-(2,2-bis(((1-oxo-2-propen-1-yl)oxy)methyl)-1,3-propanediyl) ester ; 2-Propenoic acid, 2,2-bis(((1-oxo-2-propenyl)oxy)methyl)-1,3-propanediyl ester .

Product Name

Pentaerythritol tetraacrylate

Synthetic route

Pentaerythritol tetraacrylate Chemical Properties

Pentaerythritol tetraacrylate Safety Profile

Pentaerythritol tetraacrylate Specification

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