Sodium dimethyldithiocarbamate supplier

Name
Sodium dimethyldithiocarbamate
EINECS 204-876-7
CAS No. 128-04-1
Article Data17
CAS DataBase
Density 1.17 g/cm³
Solubility 374g/L at 20℃
Melting Point 120-122 °C (dec.)(lit.)
Formula C₃H₇NNaS₂
Boiling Point 129.4 °C at 760 mmHg
Molecular Weight 179.24
Flash Point 32 °C
Transport Information
Appearance clear yellow liquid
Safety 26-36
Risk Codes 22-36
Molecular Structure
Hazard Symbols Xn
Synonyms (Dimethyldithiocarbamato)sodium;Dimethyldithiocarbamicacid sodium salt;N,N-Dimethyldithiocarbamic acid sodium salt;
PSA 60.63000
LogP 1.03040

Synthetic route

: 75-15-0
carbon disulfide

: 506-59-2
N,N-dimethylammonium chloride

: 128-04-1
sodium dimethyldithiocarbamate

Conditions

Conditions	Yield
With sodium hydroxide In methanol for 3h; Ambient temperature;	100%

: 75-15-0
carbon disulfide

: 124-40-3
dimethyl amine

: 128-04-1
sodium dimethyldithiocarbamate

Conditions

Conditions	Yield
With sodium hydroxide at 25℃; Temperature;	99.85%
With sodium hydroxide In water at 20℃; for 1.5h; Cooling with ice-water bath;	59%
With sodium hydroxide In methanol other reagent;

: 137-26-8
Thiram

: 128-04-1
sodium dimethyldithiocarbamate

Conditions

Conditions	Yield
With sodium amalgam In tetrahydrofuran for 2h;

: 56-23-5
tetrachloromethane

: 127-19-5
N,N-dimethyl acetamide

CS2: CS2

: 128-04-1
sodium dimethyldithiocarbamate

Conditions

Conditions	Yield
With water

...Expand

: 56-23-5
tetrachloromethane

: 68-12-2, 33513-42-7
N,N-dimethyl-formamide

CS2: CS2

: 128-04-1
sodium dimethyldithiocarbamate

Conditions

Conditions	Yield
With water

...Expand

: 66310-10-9
N-benzyl-2,4,6-triphenylpyridinium tetrafluoroborate

: 128-04-1
sodium dimethyldithiocarbamate

: 7250-18-2
benzyl dimethyldithiocarbamate

Conditions

Conditions	Yield
In ethanol for 1h; Heating;	99%

: butyl <2>betylate perchlorate

: 128-04-1
sodium dimethyldithiocarbamate

: 70031-50-4
S-butyl N,N-dimethyldithiocarbamate

Conditions

Conditions	Yield
In water at 25℃; for 0.5h;	99%

: tris(isopropylthio)cyclopropenylium perchlorate

: 128-04-1
sodium dimethyldithiocarbamate

: Dimethyl-(3,4,5-tris-isopropylsulfanyl-thiophen-2-yl)-amine

Conditions

Conditions	Yield
In acetonitrile for 1h; Ambient temperature;	99%

: 58529-40-1
1,2-dichloro-tetramethyl-distannane

: 128-04-1
sodium dimethyldithiocarbamate

: (CH3)2Sn(SC(N(CH3)2)S)2Sn(CH3)2

Conditions

Conditions	Yield
In water to stirred soln. of tin compd. in degassed H2O was slowly added soln. of Na- (or NH4-) Me2NCSS (50-100% excess); formed ppt. was filtered off, washed with water, then with a little MeOH and dried in vac. at room temp.; recrystn. from CHCl3; elem. anal.;	99%

: 81097-48-5
N-tosyl-6-azabicyclo[3.1.0]hexane

: 128-04-1
sodium dimethyldithiocarbamate

: C15H22N2O2S3

Conditions

Conditions	Yield
In acetonitrile at 80℃; for 0.5h; stereoselective reaction;	99%

: hexadecyl <2>betylate fluorosulfate

: 128-04-1
sodium dimethyldithiocarbamate

: 5424-93-1
dimethyl-dithiocarbamic acid hexadecyl ester

Conditions

Conditions	Yield
In dichloromethane; water at 25℃; for 1.5h;	98%

: 3741-32-0
2-chloro-[1,3,2]dithiarsolane

: 128-04-1
sodium dimethyldithiocarbamate

: 17886-21-4
2-Dimethyldithiocarbamato-1,3,2-dithioarsolan

Conditions

Conditions	Yield
In benzene for 5h; Substitution; Heating;	98%
In ethanol for 5h;	60%

: bis(cyclopentadienyl)dibromozirconium

: 128-04-1
sodium dimethyldithiocarbamate

A: bis(η5-cyclopentadienyl)bromo(N,N-dimethyldithiocarbamato)zirconium(IV)

B: 7647-15-6
sodium bromide

Conditions

Conditions	Yield
In dichloromethane Kinetics; Stirring of mixt. of starting complexes in CH2Cl2 at reflux under anhydrous conditions in a dry Ar atmosphere (24 h).; Filtn. of react. mixt., removal of solvent by trap-to-trap distn., crystn. of crude resulting material from CH2Cl2 under hexane, elem. anal., variable-temp. NMR spectroscopy.;	A 98% B n/a

...Expand

: 39110-02-6
dibromophenylbismuthane

: 128-04-1
sodium dimethyldithiocarbamate

: 18509-16-5
Bis-(dimethyldithiocarbamato)-phenyl-bismut

Conditions

Conditions	Yield
In chloroform	98%
In chloroform molar ratio sodium dimethylditiocarbamate:thiophenol = 2:1, 1 h, 25°C; recrystd. from CH3CN;	98%
In chloroform	98%

: 96454-61-4
[((C6H5)2PCH2)2W(CCH2C6H5)(CO)2](1+)*BF4(1-)=((C6H5)2PCH2CH2P(C6H5)2)W(CCH2C6H5)(CO)2BF4

: 128-04-1
sodium dimethyldithiocarbamate

: 96454-68-1
((CH3)2NCS2)((C6H5)2PCH2CH2P(C6H5)2)W(OCCCH2C6H5)(CO)(1+)*BF4(1-)

Conditions

Conditions	Yield
In dichloromethane 1 equiv of Na salt adding to a soln. of the complex precooled to -23°C under N2, stirring for 0.5 h at -23°C, then 1.5 h at 0°C and 2 h at room temp., filtering, EtOH adding; purified by recrystallization from CH2Cl2-Et2O; identified by IR and NMR spectra;	98%

: 74666-77-6
W(O)(CHC(CH3)3)Cl2(P(C2H5)3)2

: 128-04-1
sodium dimethyldithiocarbamate

: 79329-34-3
W(O)(CHC(CH3)3)bis(dithiocarbamate)

Conditions

Conditions	Yield
In tetrahydrofuran byproducts: NaCl; molar ratio W:Na=1:2, stirred for 2 d; filtered, solvent removed in vac., recrystd. from toluene/pentane, elem. anal.;	98%

: 68820-12-2
cyclohexyl-N-tosyl aziridine

: 128-04-1
sodium dimethyldithiocarbamate

: C16H24N2O2S3

Conditions

Conditions	Yield
In acetonitrile at 80℃; for 0.166667h; stereoselective reaction;	98%

: 694-28-0
2-chlorocyclopentanone

: 128-04-1
sodium dimethyldithiocarbamate

: 23839-30-7
2-(Dimethylamino-thiocarbonylthio)cyclopentanon

Conditions

Conditions	Yield
In diethyl ether; acetone	97%

: 100188-48-5
3-(trimethylsilyl)-2-oxoazetidin-4-yl acetate

: 128-04-1
sodium dimethyldithiocarbamate

: 100188-54-3
(3S,4R)-3-(trimethylsilyl)-2-oxoazetidin-4-yl N,N-dimethyldithiocarbamate

Conditions

Conditions	Yield
In water; acetone at 25℃;	97%

: (±)-trans-N-tosyl-2-isopropyl-3-methylaziridine

: 128-04-1
sodium dimethyldithiocarbamate

: C16H26N2O2S3

Conditions

Conditions	Yield
In acetonitrile at 80℃; for 1h; stereoselective reaction;	97%

: {W(C(C6H5)CHCH(CH3))Br2(CO)2(NC5H4(CH3))}

: 128-04-1
sodium dimethyldithiocarbamate

: 157773-71-2, 157904-09-1
{W(S2CN(CH3)2)2(OCC(C6H5)CHCHCH3)(CO)}

Conditions

Conditions	Yield
In tetrahydrofuran under N2: addn. of NaS2CN(CH3)2 in THF to a slurry of allylidene tungsten in THF with stirring at 0°C; heating to 45-50°C for 1.5 h;; recrystallization by slow cooling of a satd. CH2Cl2/hexane soln. from ambient temperature to -78°C; mixture of 2 isomers;;	96.5%

: 65611-10-1
1,2-dichloro-1,2-dimethoxyethane

: 128-04-1
sodium dimethyldithiocarbamate

: 144900-25-4
Dimethyl-dithiocarbamic acid 2-dimethylthiocarbamoylsulfanyl-1,2-dimethoxy-ethyl ester

Conditions

Conditions	Yield
In N,N-dimethyl-formamide Ambient temperature;	96%

: 5035-52-9
dichlorophenylstibine

: 128-04-1
sodium dimethyldithiocarbamate

: phenylantimony chloride dimethyldithiocarbamate

Conditions

Conditions	Yield
In chloroform equimolar amts at 25°C;	96%

: 128-04-1
sodium dimethyldithiocarbamate

: 137-26-8
Thiram

Conditions

Conditions	Yield
With 1,3,5-trichloro-2,4,6-triazine; dimethyl sulfoxide In dichloromethane at 20℃; for 0.333333h;	95%
With hydrogenchloride; sodium nitrite In methanol; water at 0 - 5℃; for 0.333333h;	56%
In water at 25℃; Electrolysis;	42%

: 2355-56-8
1N-methyl-2,4,6-triphenylpyridinium tetrafluoroborate

: 128-04-1
sodium dimethyldithiocarbamate

: 3735-92-0
N,N,S-trimethyldithiocarbamate

Conditions

Conditions	Yield
With 2,4,6-triphenylpyridine at 160℃; under 1 Torr; for 0.5h;	95%

: 107292-94-4
5,5'-methylenebis(1-(2-bromoethyl)-3,6-dimethyl-2,4(1H,3H)-pyrimidinedione)

: 128-04-1
sodium dimethyldithiocarbamate

: 107292-98-8
5,5'-methylenebis(3,6-dimethyl-1-(N,N-dimethylaminothiocarbonylthioethyl)-2,4(1H,3H)-pyrimidinedione)

Conditions

Conditions	Yield
In methanol; chloroform for 2h; Heating;	95%

: 591-50-4
iodobenzene

: 128-04-1
sodium dimethyldithiocarbamate

: 16906-70-0
phenyl N,N-dimethyl dithiocarbamate

Conditions

Conditions	Yield
With dimethylaminoacetic acid; copper(l) iodide In N,N-dimethyl-formamide at 110℃; for 22h; Ullmann-type coupling;	95%
With copper diacetate; potassium carbonate In N,N-dimethyl-formamide at 120℃; for 6h; Sealed tube;	87%

: 5035-52-9
dichlorophenylstibine

: 128-04-1
sodium dimethyldithiocarbamate

: 18528-48-8
phenylantimony dimethyldithiocarbamate

Conditions

Conditions	Yield
In chloroform at room temp.;	95%

: 213681-01-7
[(μ-bis(diphenylphosphinomethyl)phenylphosphine)(AuCl)3 ]

: 128-04-1
sodium dimethyldithiocarbamate

: 289035-01-4
(Au3(μ-bis(diphenylphosphinomethyl)phenylphosphine)(μ-S2CNMe2)Cl2)

Conditions

Conditions	Yield
In dichloromethane under Ar atm. to CH2Cl2 suspn. ((μ-dpmp)(AuCl)3) was added NaS2CNMe2(1:1), soln. was stirred for 2 h; soln. was filtered, conc., hexane was added, solid was washed with hexane; elem. anal.;	95%

: 213681-01-7
[(μ-bis(diphenylphosphinomethyl)phenylphosphine)(AuCl)3 ]

: 128-04-1
sodium dimethyldithiocarbamate

: (Au3(μ-bis(diphenylphosphinomethyl)phenylphosphine)(μ-S2CNMe2)2Cl)

Conditions

Conditions	Yield
In dichloromethane under Ar atm. to CH2Cl2 suspn. ((μ-dpmp)(AuCl)3) was added NaS2CNMe2(1:2), soln. was stirred for 2 h; soln. was filtered, conc., hexane was added, solid was washed with hexane; elem. anal.;	95%

: 213681-01-7
[(μ-bis(diphenylphosphinomethyl)phenylphosphine)(AuCl)3 ]

: 128-04-1
sodium dimethyldithiocarbamate

: 289035-10-5
(Au3(μ-bis(diphenylphosphinomethyl)phenylphosphine)(μ-S2CNMe2)3)

Conditions

Conditions	Yield
In dichloromethane under Ar atm. to CH2Cl2 suspn. ((μ-dpmp)(AuCl)3) was added NaS2CNMe2(1:3), soln. was stirred for 2 h; soln. was filtered, conc., Et2O was added, solid was washed with Et2O; elem. anal.;	95%

: 3-iodo-2-(2-iodoethyl)-4,5-diphenylfuran

: 128-04-1
sodium dimethyldithiocarbamate

: 2-(3-iodo-4,5-diphenylfuran-2-yl)ethyl dimethylcarbamodithioate

Conditions

Conditions	Yield
In N,N-dimethyl-formamide at 150℃; for 2h;	95%

: 1004-00-8
4-chloro-2-aminobenzenethiol

: 128-04-1
sodium dimethyldithiocarbamate

: 5331-91-9
5-chloro-2-mercaptobenzothiazole

Conditions

Conditions	Yield
With aluminum (III) chloride In water; N,N-dimethyl-formamide at 120℃;	95%

Sodium dimethyldithiocarbamate Consensus Reports

Sodium dimethyldithiocarbamate(128-04-1) is reported in EPA TSCA Inventory.

Sodium dimethyldithiocarbamate Specification

The IUPAC name of this chemical is Sodium N,N-dimethyldithiocarbamate. With the CAS registry number 128-04-1 and EINECS registry number 204-876-7, it is also named as Dimethyldithiocarbamicacid sodium salt. In addition, the molecular formula is C₃H₇NNaS₂ and the molecular weight is 144.21. It is a kind of clear yellow solution and belongs to the classes of Pharmaceutical Intermediates; Aliphatics; Classes of Metal Compounds; Na (Sodium) Compounds (excluding simple sodium salts); Typical Metal Compounds. What's more, it can be used as intermediates in organic synthesis, accelerant of rubber, antiseptic and corrosion inhibitor.

Physical properties about this chemical are: (1)ACD/LogP: 0.75; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): -1.06; (4)ACD/LogD (pH 7.4): -2.68; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)ACD/KOC (pH 5.5): 1; (8)ACD/KOC (pH 7.4): 1; (9)#H bond acceptors: 1; (10)#Freely Rotating Bonds: 0; (11)Polar Surface Area: 74.13 Å²; (12)Flash Point: 32 °C; (13)Enthalpy of Vaporization: 36.7 kJ/mol; (14)Boiling Point: 129.4 °C at 760 mmHg; (15)Vapour Pressure: 10.2 mmHg at 25°C.

When you are using this chemical, please be cautious about it as the following:
This chemical is harmful if swallowed and irritating to eyes. During using it, wear suitable protective clothing. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

You can still convert the following datas into molecular structure:
(1)SMILES: [Na+].[S-]C(=S)N(C)C
(2)InChI: InChI=1/C3H7NS2.Na/c1-4(2)3(5)6;/h1-2H3,(H,5,6);/q;+1/p-1
(3)InChIKey: VMSRVIHUFHQIAL-REWHXWOFAU

The toxicity data is as follows:

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
mouse	LD50	intraperitoneal	573mg/kg (573mg/kg)		Yakugaku Zasshi. Journal of Pharmacy. Vol. 94, Pg. 1419, 1974.
mouse	LD50	oral	1500mg/kg (1500mg/kg)	BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD BEHAVIORAL: CHANGES IN MOTOR ACTIVITY (SPECIFIC ASSAY)	Farmakologiya i Toksikologiya Vol. 28, Pg. 230, 1965.
rabbit	LD50	oral	300mg/kg (300mg/kg)		Toksikologicheskii Vestnik. Vol. (3), Pg. 34, 2000.
rat	LD	skin	> 5gm/kg (5000mg/kg)		Toksikologicheskii Vestnik. Vol. (3), Pg. 34, 2000.
rat	LD50	intraperitoneal	1gm/kg (1000mg/kg)		Pharmazie. Vol. 27, Pg. 139, 1972.
rat	LD50	oral	1gm/kg (1000mg/kg)		Pesticide Chemicals Official Compendium, Association of the American Pesticide Control Officials, Inc., 1966. Vol. -, Pg. 1029, 1966.

Product Name

Sodium dimethyldithiocarbamate

Synthetic route

Sodium dimethyldithiocarbamate Consensus Reports

Sodium dimethyldithiocarbamate Specification

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