Tetradecanal supplier | CasNO.124-25-4

Name
FEMA 2763
EINECS 204-692-7
CAS No. 124-25-4
Article Data99
CAS DataBase
Density 0.827g/cm³
Solubility
Melting Point 23°C(lit.)
Formula C₁₄H₂₈O
Boiling Point 271.59 °C at 760 mmHg
Molecular Weight 212.376
Flash Point 121.502 °C
Transport Information
Appearance colorless to pale yellow solid
Safety 26-37/39
Risk Codes Xi:Irritant;
Molecular Structure
Hazard Symbols R36/37/38:;
Synonyms Myristaldehyde(6CI,7CI,8CI);1-Tetradecanal;Aldehyde peche (C14);Myristinaldehyde;Myristylaldehyde;NSC 66435;Peach aldehyde (C14);Tetradecanaldehyde;Tetradecyl aldehyde;Tetradecanal;n-Tetradecyl aldehyde;
PSA 17.07000
LogP 4.88640

Synthetic route

: 112-72-1
1-Tetradecanol

: 124-25-4
myristylaldehyde

Conditions

Conditions	Yield
With oxalyl dichloride; dimethyl sulfoxide; triethylamine In dichloromethane at 5 - 15℃; for 0.05h;	100%
Stage #1: 1-Tetradecanol With oxalyl dichloride In dichloromethane; dimethyl sulfoxide at -60 - 15℃; for 0.1h; Stage #2: With triethylamine In dichloromethane; dimethyl sulfoxide at 5℃;	100%
With Dess-Martin periodane In dichloromethane at 20℃; for 3h;	100%

: 544-63-8
n-tetradecanoic acid

: 124-25-4
myristylaldehyde

Conditions

Conditions	Yield
With methylphenylsilane; 2,2-dimethylpropanoic anhydride; Tri(p-tolyl)phosphine; bis(dibenzylideneacetone)-palladium(0) In toluene at 60℃; for 20h; Schlenk technique; Inert atmosphere;	88%
(i) Li, MeNH2, (ii) H2O; Multistep reaction;
Multi-step reaction with 2 steps 1: lithium aluminium tetrahydride / tetrahydrofuran / 3 h / 0 °C 2: Dess-Martin periodane / dichloromethane / 0 °C View Scheme
With glycerol-3-Phosphate Dehydrogenase; D-glucose; NADP+; Nocardia PPTase; Segniliparus CAR; ATP; coenzyme A; magnesium chloride In dimethyl sulfoxide at 35℃; for 16h; pH=9; Enzymatic reaction;

: 626-29-9
myristic anhydride

: 124-25-4
myristylaldehyde

Conditions

Conditions	Yield
With P(p-CH3OC6H4)3; methylphenylsilane; bis(dibenzylideneacetone)-palladium(0) In toluene at 60℃; for 20h; Schlenk technique; Inert atmosphere;	82%

: 2564-83-2, 45842-10-2
2,2,6,6-Tetramethyl-1-piperidinyloxy free radical

: 112-72-1
1-Tetradecanol

: 124-25-4
myristylaldehyde

Conditions

Conditions	Yield
Stage #1: 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; 1-Tetradecanol With tetrabutylammomium bromide; sodium hydrogencarbonate; potassium carbonate In dichloromethane; water at 20℃; Stage #2: With N-chloro-succinimide In dichloromethane; water at 20℃; for 1h;	77%

: 112-64-1
tetradecanoyl chloride

: 124-25-4
myristylaldehyde

Conditions

Conditions	Yield
With triethylsilane; tris(2,4,6-trimethylphenyl)phosphine; bis(dibenzylideneacetone)-palladium(0) In toluene at 40℃; for 1.5h; Schlenk technique; Inert atmosphere;	68%
With iron(II) oxide; tris(2,4,6-trimethoxyphenyl)phosphine; phenylsilane In toluene at 60℃; for 2h; Inert atmosphere; Schlenk technique;	36%

: 626-35-7
nitroacetic acid ethyl ester

: 112-72-1
1-Tetradecanol

A: 124-25-4
myristylaldehyde

B: 79183-87-2
C18H35NO4

Conditions

Conditions	Yield
With triphenylphosphine; diethylazodicarboxylate In tetrahydrofuran for 2h; Ambient temperature;	A 66% B 19%

...Expand

: 13360-61-7
1-pentadecene

: 124-25-4
myristylaldehyde

Conditions

Conditions	Yield
With aluminum oxide; potassium permanganate In dichloromethane; water for 24h; Ambient temperature;	60%

: 592-76-7
1-Heptene

: 201230-82-2
carbon monoxide

A: 112-31-2
caprinaldehyde

B: 112-54-9
Dodecanal

C: 16630-91-4
2-methylheptanal

D: 124-13-0
Octanal

E: 124-25-4
myristylaldehyde

Conditions

Conditions	Yield
With polystyrene-PPh2=CH2; hydrogen; polystyrene-PPh2RhHCO(PPh3)n In tetrahydrofuran at 60℃; for 16h; Product distribution; Mechanism;	A 12% B 2% C 10% D 45% E 0.3%

...Expand

: 629-63-0
myristonitrile

: 124-25-4
myristylaldehyde

Conditions

Conditions	Yield
With hydrogenchloride; diethyl ether; tin(ll) chloride und beim Verseifen des Reaktionsprodukts mit warmem Wasser;
With Li(1+)*C12H28AlO3(1-) In tetrahydrofuran; hexane for 24h; Ambient temperature; Yield given;
With hydrogenchloride; diisobutylaluminium hydride 1.) benzene, r.t., 3 h, hexane; 2.) MeOH, dioxane, 1 h; Yield given. Multistep reaction;

: 124161-28-0
selenous acid ditetradecyl ester

: 124-25-4
myristylaldehyde

Conditions

Conditions	Yield
at 177℃; Irradiation.mit UV-Licht;

: 2507-54-2
2-hydroxypentadecanoic acid

: 124-25-4
myristylaldehyde

Conditions

Conditions	Yield
at 270 - 280℃;
at 270 - 275℃;
at 270 - 280℃;

: 114381-19-0
N-methyl-N-phenyltetradecanamide

: 124-25-4
myristylaldehyde

Conditions

Conditions	Yield
With lithium aluminium tetrahydride; diethyl ether

: 112-64-1
tetradecanoyl chloride

A: 629-50-5
Tridecane

B: 124-25-4
myristylaldehyde

Conditions

Conditions	Yield
With pumice stone; platinum at 220 - 230℃; under 60 - 65 Torr; Hydrogenation;

: 113725-20-5
(Z)-3-(hexadec-1-enyloxy)propane-1,2-diol

: 124-25-4
myristylaldehyde

Conditions

Conditions	Yield
With ozone In ethyl acetate

: 544-63-8
n-tetradecanoic acid

: 109-94-4
formic acid ethyl ester

: 124-25-4
myristylaldehyde

Conditions

Conditions	Yield
(i) LDA, (ii) /BRN= 906769/, aq. HCl; Multistep reaction;

: 99000-01-8
3,5-dimethyl-1-tetradecanoyl-1H-pyrazole

: 124-25-4
myristylaldehyde

Conditions

Conditions	Yield
With lithium aluminium tetrahydride In diethyl ether Ambient temperature;

: 10160-94-8
1,1-diethoxy-tetradeca-2c,5c,8c-triene

: 124-25-4
myristylaldehyde

Conditions

Conditions	Yield
With hydrogen; platinum(IV) oxide

: 74645-26-4
β-D-galactopyranisyl-(1->1)-tetracosanoyl-sphingenine

: 124-25-4
myristylaldehyde

Conditions

Conditions	Yield
With ozone In chloroform Ambient temperature;

: 27519-02-4
(Z)-tricos-9-ene

A: 124-19-6
nonan-1-al

B: 124-25-4
myristylaldehyde

Conditions

Conditions	Yield
With ozone at 200℃; for 0.0833333h; Product distribution;

: 77953-88-9
1-Tetradecyl phenyl telluride

A: 1120-36-1
1-tetradecene

B: 112-72-1
1-Tetradecanol

C: 124-25-4
myristylaldehyde

Conditions

Conditions	Yield
With 3-chloro-benzenecarboperoxoic acid 1.) diethylether, 25 deg C,2 h. 2.) 250 deg C, 7 torr; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
With 3-chloro-benzenecarboperoxoic acid 1.) diethylether, 25 deg C, 2 h. 2.) 250 deg C, 7 torr; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;

...Expand

: 87375-79-9
(Z)-9,10-epoxytricosane

A: 124-19-6
nonan-1-al

B: 124-25-4
myristylaldehyde

Conditions

Conditions	Yield
With periodic acid for 0.05h; Product distribution; Ambient temperature;

: 120061-39-4
2-tetradecylsulfinyl-3,6-diisopropylpyrazine

: 124-25-4
myristylaldehyde

Conditions

Conditions	Yield
With potassium carbonate; trifluoroacetic anhydride 1.) 10 min, r.t.; 2.) 40percent CH3CN/H2O, 10 min,; Yield given. Multistep reaction;

: 194920-96-2
2-ethenyltetradecanoic acid

: 124-25-4
myristylaldehyde

Conditions

Conditions	Yield
With ozone; acetic acid; potassium iodide 1.) methanol, -70 deg C, 2.) methanol, room temperature, 1 h; Yield given. Multistep reaction;

: 3234-28-4
1,2-epoxytetradecane

A: 2345-27-9
tetradecan-2-one

B: 124-25-4
myristylaldehyde

Conditions

Conditions	Yield
With iron(III) tetraphenylporphyrin triflate In 1,4-dioxane Rearrangement; Heating;	A 5 % Spectr. B 95 % Spectr.

: 112-72-1
1-Tetradecanol

: 64-19-7
acetic acid

chromic acid: chromic acid

: 124-25-4
myristylaldehyde

...Expand

myristacidic barium: myristacidic barium

: 124-25-4
myristylaldehyde

Conditions

Conditions	Yield
With barium formate Destillation im Vakuum;

: 112-72-1
1-Tetradecanol

nickel: nickel

: 124-25-4
myristylaldehyde

Conditions

Conditions	Yield
at 250℃;

: 7647-01-0
hydrogenchloride

: 60-29-7
diethyl ether

: 629-63-0
myristonitrile

tin (II)-chloride: tin (II)-chloride

: 124-25-4
myristylaldehyde

Conditions

Conditions	Yield
und Verseifen des Reaktionsprodukts mit warmem Wasser;

...Expand

triacetylsphingosine: triacetylsphingosine

: 124-25-4
myristylaldehyde

Conditions

Conditions	Yield
With acetic acid und Spaltung des entstandenen Ozonids durch katalitische Hydrierung in Gegenwart von Palladium-Bariumsulfat;

: 67-56-1
methanol

: 124-25-4
myristylaldehyde

: 14620-53-2
1,1-dimethoxytetradecane

Conditions

Conditions	Yield
aminopropylated Silica-Gel hydrochloride (APSG*HCl) resin for 10h; Ambient temperature;	97%
With 5-sulfosalicylic Acid

: 867-13-0
diethoxyphosphoryl-acetic acid ethyl ester

: 124-25-4
myristylaldehyde

: 135251-95-5
(2E)-ethyl 2-hexadecenoate

Conditions

Conditions	Yield
With sodium hydride In tetrahydrofuran 1.) 0 deg C, 0.5 h, 2.) 0 to 25 deg C;	97%
Stage #1: diethoxyphosphoryl-acetic acid ethyl ester With sodium hydride In tetrahydrofuran at 0 - 20℃; for 0.5h; Stage #2: myristylaldehyde In tetrahydrofuran at 20℃; for 2h;
Stage #1: diethoxyphosphoryl-acetic acid ethyl ester With sodium hydride In tetrahydrofuran; mineral oil at 0℃; for 0.5h; Stage #2: myristylaldehyde In tetrahydrofuran; mineral oil at 20℃; for 2h;
With sodium hydride In tetrahydrofuran at 0 - 20℃; Horner-Wadsworth-Emmons Olefination;	12.3 g

: 6642-31-5
6-Amino-1,3-dimethylbarbituric acid

: 124-25-4
myristylaldehyde

: C20H35N3O2

Conditions

Conditions	Yield
With acetic acid In water at 80℃; pH=3 - 4;	96.2%

: 124-25-4
myristylaldehyde

: 629-63-0
myristonitrile

Conditions

Conditions	Yield
With hydroxylamine hydrochloride; sodium iodide In acetonitrile for 1.5h; Heating;	96%
With O-(diphenylphosphinyl)hydroxylamine In toluene at 20 - 85℃; chemoselective reaction;	96%
With phosphoric acid; hydroxylamine hydrochloride In formic acid at 5 - 100℃;	90%
With HCl·DMPU; hydroxylamine hydrochloride In acetonitrile at 60℃;	81%

: 124-25-4
myristylaldehyde

: 472954-87-3
[4-(tert-butyldimethylsilanyloxy)-3-tritylamino-2-oxo-butyl]phosphonic acid dimethyl ester

: 472954-88-4
(2S,4E)-2-[N-(trityl)amino]-1-O-tert-butyldimethylsilyl-3-oxo-4-octadecene

Conditions

Conditions	Yield
With 1,8-diazabicyclo[5.4.0]undec-7-ene; lithium chloride In tetrahydrofuran at 20℃; for 5h; Horner-Wadsworth-Emmons olefination;	95%

: 124-25-4
myristylaldehyde

: 123-54-6
acetylacetone

: 3-tetradecylidenepentane-2,4-dione

Conditions

Conditions	Yield
With piperidine; acetic acid In dichloromethane at 0 - 20℃; Knoevenagel Condensation; Inert atmosphere;	93%

: 98548-90-4
methyl pyrrolidine-3-carboxylate

: 124-25-4
myristylaldehyde

: 849812-22-2
1-tetradecyl-pyrrolidine-3-carboxylic acid methyl ester

Conditions

Conditions	Yield
With sodium tris(acetoxy)borohydride; N-ethyl-N,N-diisopropylamine In dichloromethane	92%

: 124-25-4
myristylaldehyde

: (3-hydroxy-pyrrolidin-3-yl)-phosphonic acid diethyl ester

: 849812-61-9
(3-hydroxy-1-tetradecyl-pyrrolidin-3-yl)-phosphonic acid diethyl ester

Conditions

Conditions	Yield
With sodium tris(acetoxy)borohydride; N-ethyl-N,N-diisopropylamine In dichloromethane	92%

: 124-25-4
myristylaldehyde

: 785815-74-9
(2-pyrrolidin-2-yl-ethyl)-phosphonic acid diethyl ester

: 849812-20-0
[2-(1-tetradecyl-pyrrolidin-2-yl)-ethyl]-phosphonic acid diethyl ester

Conditions

Conditions	Yield
With sodium tris(acetoxy)borohydride; N-ethyl-N,N-diisopropylamine In dichloromethane	92%

: 124-25-4
myristylaldehyde

: 849813-76-9
(4-hydroxy-piperidin-4-yl)-phosphonic acid diethyl ester

: 849813-78-1
(4-hydroxy-1-tetradecyl-piperidin-4-yl)-phosphonic acid diethyl ester

Conditions

Conditions	Yield
With sodium tris(acetoxy)borohydride; N-ethyl-N,N-diisopropylamine In dichloromethane	92%

: 867-13-0
diethoxyphosphoryl-acetic acid ethyl ester

: 124-25-4
myristylaldehyde

: ethyl 2-hexadecenoate

Conditions

Conditions	Yield
Stage #1: diethoxyphosphoryl-acetic acid ethyl ester With sodium hydride In tetrahydrofuran at 0℃; for 0.5h; Stage #2: myristylaldehyde In tetrahydrofuran at 0 - 20℃;	92%
Stage #1: diethoxyphosphoryl-acetic acid ethyl ester With sodium hydride In tetrahydrofuran at 0℃; for 0.5h; Stage #2: myristylaldehyde In tetrahydrofuran at 20℃; for 3h;	92%
With sodium hydride In tetrahydrofuran at 0 - 20℃; Horner-Wadsworth-Emmons Olefination; Inert atmosphere;

: 124-25-4
myristylaldehyde

: 59867-49-1
diethyl phosphonoacetate d'ethyle

: 135251-95-5
(2E)-ethyl 2-hexadecenoate

Conditions

Conditions	Yield
With sodium hydride In tetrahydrofuran Substitution;	91%

: 124-25-4
myristylaldehyde

: 105-34-0
methyl 2-cyanoacetate

: methyl 2-amino-5-dodecylthiophene-3-carboxylate

Conditions

Conditions	Yield
With sulfur; triethylamine for 12h; Gewald Aminoheterocycles Synthesis; Reflux; Inert atmosphere;	91%

: 124-25-4
myristylaldehyde

: tert-butyl (S)-(1-((tert-butyldimethylsilyl)oxy)-4-(dimethoxyphosphoryl)-3-oxobutan-2-yl)carbamate

: 947325-52-2
tert-butyl (S,E)-(1-((tert-butyldimethylsilyl)oxy)-3-oxooctadec-4-en-2-yl)carbamate

Conditions

Conditions	Yield
With triethylamine; lithium chloride In tetrahydrofuran at 20℃; for 18h;	91%

: 124-25-4
myristylaldehyde

: 121998-80-9
(R)-[2-(2,2-dimethyl-1,3-dioxolan-4-yl)-2-oxoethyl]phosphonic acid dimethyl ester

: 121998-81-0
(2R,4E)-1,2-O-isopropylidene-3-oxo-4-octadecene-1,2-diol

Conditions

Conditions	Yield
Stage #1: (R)-[2-(2,2-dimethyl-1,3-dioxolan-4-yl)-2-oxoethyl]phosphonic acid dimethyl ester With caesium carbonate In isopropyl alcohol at 0℃; for 2h; Stage #2: myristylaldehyde In isopropyl alcohol at 20℃;	90%
With caesium carbonate In isopropyl alcohol at 0 - 20℃;	85%
With potassium carbonate In acetonitrile Horner-Wadsworth-Emmons reaction;

: 1631-28-3
N-p-tolylphenylmaleimide

: 124-25-4
myristylaldehyde

: 558480-31-2
(E)-3-tetradecylidene-1-p-tolyl-pyrrolidine-2,5-dione

Conditions

Conditions	Yield
Stage #1: N-p-tolylphenylmaleimide With triphenylphosphine In tetrahydrofuran at 20℃; for 0.5h; Stage #2: myristylaldehyde In tetrahydrofuran for 10h; Wittig condensation; Heating;	89%
With triphenylphosphine In tetrahydrofuran for 10h; Heating;	89%

: 124-25-4
myristylaldehyde

: 5680-79-5
glycine ethyl ester hydrochloride

: 1365682-87-6
methyl 2-(ditetradecylamino)acetate

Conditions

Conditions	Yield
Stage #1: glycine ethyl ester hydrochloride With triethylamine In 1,2-dichloro-ethane at 20℃; for 0.25h; Stage #2: myristylaldehyde With sodium tris(acetoxy)borohydride; acetic acid In 1,2-dichloro-ethane at 0 - 20℃; for 16h;	89%
Stage #1: glycine ethyl ester hydrochloride With trimethylamine In 1,2-dichloro-ethane at 20℃; for 0.25h; Stage #2: myristylaldehyde With sodium tris(acetoxy)borohydride; acetic acid In 1,2-dichloro-ethane at 0 - 20℃; for 16h;	89%

: 1631-26-1
1-benzyl-1H-pyrrole-2,5-dione

: 124-25-4
myristylaldehyde

: 1-benzyl-3-tetradecanoylpyrrolidine-2,5-dione

Conditions

Conditions	Yield
Stage #1: 1-benzyl-1H-pyrrole-2,5-dione With 2-pentafluorophenyl-6,7-dihydro-5H-pyrrolo[2,1-c][1,2,4]triazol-2-ium tetrafluoroborate; N-ethyl-N,N-diisopropylamine In toluene at 20℃; for 0.5h; Sealed tube; Inert atmosphere; Stage #2: myristylaldehyde In toluene for 24h; Sealed tube; Inert atmosphere; Reflux;	89%

: 124-25-4
myristylaldehyde

: 24850-33-7
allyltributylstanane

: (4R)-heptadec-1-en-4-ol

Conditions

Conditions	Yield
Stage #1: myristylaldehyde With bis{[(R)-binaphthoxy](isopropoxy)titanium} oxide In dichloromethane at 20℃; for 0.5h; Keck Asymmetric Allylation; Molecular sieve; Stage #2: allyltributylstanane at -78 - -20℃; for 72h; Molecular sieve; Reflux; enantioselective reaction;	88%
[((S,S)-1,1'-binaphthyl-2,2'-diyl)O2Ti(OiPr)]2O In dichloromethane at -15 - 0℃; for 24h;	86%
Stage #1: myristylaldehyde With bis(((S)-binaphthoxy)(isopropoxy)titanium) oxide at 20℃; for 2h; Maruoka allylation; Stage #2: allyltributylstanane at 0℃; for 12h; optical yield given as %ee; enantioselective reaction;	82%

: 124-25-4
myristylaldehyde

: 927-80-0
1-ethoxyacetylene

: 3163-37-9, 51534-41-9, 22644-96-8
(E)-hexadec-2-enal

Conditions

Conditions	Yield
With Schwartz's reagent; silver perchlorate In hexane; dichloromethane for 0.5h; Ambient temperature;	87%

: 124-25-4
myristylaldehyde

: 21382-82-1
(carbethoxyethylidene)triphenylphosphorane

: 478690-77-6
ethyl (2E)-2-methylhexadec-2-enoate

Conditions

Conditions	Yield
In benzene Wittig Olefination; Reflux; Inert atmosphere;	87%
In dichloromethane at 20℃; for 18h;
With sodium hydroxide In dichloromethane at 0 - 20℃; for 16h;	1.13 g

: 124-25-4
myristylaldehyde

: 127593-79-7
ethyl 2-((1R,2R,5R)-2-hydroxypinan-3-imino)glycinate

: ethyl {1R-[1α,2β,3(2R,3R),5α]}-3-hydroxy-2-{(2-hydroxy-2,6,6-trimethylbicyclo[3.1.1]hept-3-ylidene)amino}hexadecanoate

Conditions

Conditions	Yield
With tris(ethoxy)monochloro titanium; triethylamine In dichloromethane at 0℃;	87%

: 124-25-4
myristylaldehyde

: 1099-45-2
ethyl (triphenylphosphoranylidene)acetate

: ethyl 2-hexadecenoate

Conditions

Conditions	Yield
In dichloromethane at 20℃; for 10h; Wittig Olefination;	87%
In benzene Wittig reaction; Reflux;

: 627-82-7
diglycerol

: 124-25-4
myristylaldehyde

: C34H66O5

Conditions

Conditions	Yield
With p-octylbenzenesulfonic acid In water at 80℃; for 18h; Inert atmosphere; Green chemistry;	86.28%

: 124-25-4
myristylaldehyde

: 24850-33-7
allyltributylstanane

: 894086-03-4
(S)-4-hydroxy-1-heptadecane

Conditions

Conditions	Yield
With [(R)-1,1'-bi-2-naphtholato]bis(tert-butyloxo)titanium(IV) In dichloromethane at -15 - 0℃; for 24h; Maruoka allylation reaction;	86%
chiral binaphthyl-based titanium catalyst In dichloromethane at -15 - 0℃;	80%
With bis{[(R)-binaphthoxy](isopropoxy)titanium} oxide In dichloromethane at -15 - 0℃;	80%

: 124-25-4
myristylaldehyde

: (S)-3-(tert-butoxycarbonyl)-4-(2-(dimethoxyphosphoryl)-1-oxo-ethyl)-2,2-dimethyloxazolidine

: 129293-64-7
(S)-3-(tert-butoxycarbonyl)-4-(1-oxo-hexadec-2-enyl)-2,2-dimethyloxazolidine

Conditions

Conditions	Yield
With potassium carbonate In tetrahydrofuran; water at 20℃;	86%
With potassium carbonate In water; acetonitrile at 22℃; pH=9; Large scale;	63%
Horner-Wadsworth-Emmons olefination;

: 124-25-4
myristylaldehyde

: 77877-19-1
N-isopropyl oxazolidinone

: 452956-77-3
N-(2S,3R,4'S)-(3-hydroxy-2-methylhexadecanoyl)-4'-isopropyl-3-propionyloxazolidin-2'-one

Conditions

Conditions	Yield
Stage #1: N-isopropyl oxazolidinone With di-n-butylboryl trifluoromethanesulfonate; triethylamine In dichloromethane at 0℃; for 0.5h; Stage #2: myristylaldehyde In dichloromethane at -78℃; for 12h;	85%
Stage #1: N-isopropyl oxazolidinone With di-n-butylboryl trifluoromethanesulfonate; triethylamine In dichloromethane at 0℃; for 0.5h; Evans' assymetric synthesis; Stage #2: myristylaldehyde In dichloromethane at -78℃; for 12h;	80%
Stage #1: N-isopropyl oxazolidinone With N-ethyl-N,N-diisopropylamine In dichloromethane at -78℃; for 0.5h; Stage #2: myristylaldehyde In dichloromethane at -78 - 20℃; for 2.5h; Further stages.;	41%
With di-n-butylboryl trifluoromethanesulfonate; triethylamine

: 124-25-4
myristylaldehyde

: 17156-64-8
(dimethylphenylsilyl)acetylene

: 866832-26-0
(R)-1-(Dimethyl-phenyl-silanyl)-hexadec-1-yn-3-ol

Conditions

Conditions	Yield
Stage #1: (dimethylphenylsilyl)acetylene With diethylzinc In toluene for 1h; Heating; Stage #2: myristylaldehyde With titanium(IV) isopropylate; (S)-[1,1']-binaphthalenyl-2,2'-diol In diethyl ether; toluene	85%

Tetradecanal Chemical Properties

IUPAC Name: Tetradecanal
The MF of Tetradecanal (124-25-4) is C₁₄H₂₈O.

The MW of Tetradecanal (124-25-4) is 212.37.
Synonyms of Tetradecanal (124-25-4): Myristaldehyde ; Tetradecanal ; 1-Tetradecyl aldehyde ; Aldehyde C-14 ; Myristaldehyde (8CI) ; Tetradecanal
Appearance: colourless to pale yellow liquid/fatty, orris-like odour
Index of Refraction: 1.435
EINECS: 204-692-7
Density: 0.826 g/ml
Flash Point: 121.5 °C
Boiling Point: 271.6 °C
FEMA: 2763

Tetradecanal Uses

Tetradecanal (124-25-4) is used as a food spice.Can be formulated fragrance, flavor milk, incense and so on.

Tetradecanal Production

Natural products present in the gold orange peel, cucumber, ginger, and other Chinese.

Tetradecanal Toxicity Data With Reference

1.	skn-rbt 500 mg MOD	FCTXAV Food and Cosmetics Toxicology. 11 (1973),1079.
2.	orl-rat LD50:>5 g/kg	FCTXAV Food and Cosmetics Toxicology. 11 (1973),487.
3.	skn-rbt LD50:>10 g/kg	FCTXAV Food and Cosmetics Toxicology. 11 (1973),487.

Tetradecanal Consensus Reports

Reported in EPA TSCA Inventory.

Tetradecanal Safety Profile

Low toxicity by ingestion and skin contact. A skin irritant. When heated to decomposition it emits acrid smoke and irritating fumes. See also ALDEHYDES.

Product Name

FEMA 2763

Synthetic route

Tetradecanal Chemical Properties

Tetradecanal Uses

Tetradecanal Production

Tetradecanal Toxicity Data With Reference

Tetradecanal Consensus Reports

Tetradecanal Safety Profile

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