Tri-n-hexylaluminium supplier

Name
TRI-N-HEXYL ALUMINUM
EINECS 214-241-6
CAS No. 1116-73-0
Article Data13
CAS DataBase
Density g/cm³
Solubility
Melting Point -87oC
Formula C18H39 Al
Boiling Point 68.5 °C at 760 mmHg
Molecular Weight 282.489
Flash Point °C
Transport Information
Appearance clear colorless solution
Safety 6A-61-45-43B-36/37/39-24/25-16
Risk Codes 67-65-62-51/53-48/20-34-14/15-11
Molecular Structure
Hazard Symbols NCF
Synonyms Tri-n-hexylaluminum;Tri-n-hexylaluminum (Al(C6H13)3); Trihexylalane; Trihexylaluminum
PSA 0.00000
LogP 7.60290

Synthetic route

: 16853-85-3
lithium aluminium tetrahydride

: 592-41-6
1-hexene

: 2674-15-9
di(n-hexyl)aluminum chloride

: 1116-73-0
trihexylaluminium

Conditions

Conditions	Yield
In n-heptane byproducts: LiCl; LiAlH4 loaded in a vertical-type ball mill under Ar or N2; heptane added; mixt. agitated for 15 min at 70°C; mixt. of (C6H13)2AlCl with hex-1-ene (LiAlH4:(C6H13)2AlCl:hex-1-ene=1.1:1.0:4.5) added; mixt. agitated for 1.5 h at 90°C; cooled; filtered under Ar; solvent and olefin removed (vac., 10 Torr) at60-70°C; elem. anal.;	95%

...Expand

: aluminium hydride

: 592-41-6
1-hexene

: 1116-73-0
trihexylaluminium

Conditions

Conditions	Yield
With triisobutylaluminum In hexane (N2); heating (autoclave, 140°C, 1 h, 120°C, 8 h); distn.; elem. anal.;	89.1%
With NaAlEt4 In toluene under N2 or Ar; mixt. of AlH3, NaAlEt4, olefin (3.8 equiv.) and toluene heated at reflux; after 20 min temp. raised from 80 to 100°C and gradually decreased to 70-80°C; 2 h; cooled; filtered; ppt. washed with hexane; solvent and excess olefin removed in vac. at 60-80°C (7 Torr); elem. anal.;

: 592-47-2
3-hexene

: 102-67-0
tri-n-propylaluminum

: 1116-73-0
trihexylaluminium

Conditions

Conditions	Yield
Stage #1: 3-hexene; tri-n-propylaluminum at 70℃; under 760.051 Torr; Heating / reflux; Stage #2: cobalt(III) acetylacetonate In toluene for 2h; Stage #3: With hydrogenchloride	6.1%

: 592-41-6
1-hexene

: 1116-73-0
trihexylaluminium

Conditions

Conditions	Yield
With aluminium hydride
With lithium aluminium tetrahydride

: 1116-73-0
trihexylaluminium

: 75-36-5
acetyl chloride

: 111-13-7
hexyl-methyl-ketone

Conditions

Conditions	Yield
With aluminium trichloride In dichloromethane for 1h; Product distribution; Ambient temperature; other reaction time; other reagent: ZnCl2; other molecular proportion.;	90%
With aluminium trichloride In dichloromethane for 1h; Ambient temperature;	90%

: 1185-96-2
3-acetoxy-3-ethylbutyne

: 1116-73-0
trihexylaluminium

A: 3-methyl-3,4-undecadiene

B (n-C6H13)2AlOAc: (n-C6H13)2AlOAc

Conditions

Conditions	Yield
With iron(III) chloride In various solvent(s) at 40℃; for 15h;	A 86% B n/a

...Expand

: 1116-73-0
trihexylaluminium

: 98-88-4
benzoyl chloride

: 1671-75-6
Heptanophenone

Conditions

Conditions	Yield
With aluminium trichloride In dichloromethane for 1h; Product distribution; Ambient temperature; other molecular proportion.;	84%
With aluminium trichloride In dichloromethane for 1h; Ambient temperature;	84%

: 216586-53-7
(1R,2R)-trans-N-phthaloyl-1,2-diaminocyclohexane

: 1116-73-0
trihexylaluminium

: C34H46N2O4

Conditions

Conditions	Yield
In toluene at -5 - 50℃; for 7h; Inert atmosphere;	81.8%
In toluene at -5 - 50℃; for 7h; Inert atmosphere;	81.8%

: 16212-05-8
(allylsulfonyl)benzene

: 1116-73-0
trihexylaluminium

: 124-11-8
non-1-ene

Conditions

Conditions	Yield
With dilithium tetrachlorocuprate; triphenylphosphine In octane at 50℃; for 5h;	78%

: 592-41-6
1-hexene

: 1116-73-0
trihexylaluminium

: 123-72-8
butyraldehyde

: 6-butyl-7-methylundecan-4-ol

Conditions

Conditions	Yield
Stage #1: 1-hexene; trihexylaluminium With zirconocene dichloride In hexane at 0 - 20℃; Stage #2: butyraldehyde With copper(l) chloride In hexane at -15 - 20℃;	78%

...Expand

: 607-26-1
N,N'-ethylenediphthalimide

: 1116-73-0
trihexylaluminium

: C30H40N2O4

Conditions

Conditions	Yield
Stage #1: N,N'-ethylenediphthalimide; trihexylaluminium In toluene at -5 - 50℃; for 8h; Inert atmosphere; Stage #2: With water In toluene at 20℃; Inert atmosphere;	78%

: 592-41-6
1-hexene

: 1116-73-0
trihexylaluminium

: 78-84-2
isobutyraldehyde

: 5-butyl-2,6-dimethyldecan-3-ol

Conditions

Conditions	Yield
Stage #1: 1-hexene; trihexylaluminium With zirconocene dichloride In hexane at 0 - 20℃; Stage #2: isobutyraldehyde With copper(l) chloride In hexane at -15 - 20℃;	76%

...Expand

: 3140-73-6
2-chloro-4,6-dimethoxy-1 ,3,5-triazine

: 1116-73-0
trihexylaluminium

: 2-n-hexyl-4,6-dimethoxy-1,3,5-triazine

Conditions

Conditions	Yield
bis-triphenylphosphine-palladium(II) chloride In diethyl ether for 4h; Heating;	75%

: N-benzyl-N-(3-oxobutyl)-(E)-3-phenylpropenamide

: 1116-73-0
trihexylaluminium

: (3RS,4RS)-1-benzyl-4-hydroxy-4-methyl-3-[(RS)-1-phenylheptyl]piperidin-2-one

Conditions

Conditions	Yield
Stage #1: N-benzyl-N-(3-oxobutyl)-(E)-3-phenylpropenamide With bis-acetylacetonatocobalt(II) dihydrate In tetrahydrofuran at 0 - 20℃; for 0.5h; Stage #2: trihexylaluminium In tetrahydrofuran; hexane at 0 - 20℃; for 15h; diastereoselective reaction;	75%

: C34H46N2O4

: 1116-73-0
trihexylaluminium

: C40H57AlN2O4

Conditions

Conditions	Yield
In toluene at -5 - 80℃; for 2h; Inert atmosphere;	75%
In toluene at -5 - 80℃; for 2h; Inert atmosphere;	75%

: 27037-37-2
8-(butyryloxy)quinoline

: 1116-73-0
trihexylaluminium

: 624-16-8
decan-4-one

Conditions

Conditions	Yield
With aluminium trichloride In dichloromethane	70%

: 216586-53-7
(1R,2R)-trans-N-phthaloyl-1,2-diaminocyclohexane

: 1116-73-0
trihexylaluminium

: C40H57AlN2O4

Conditions

Conditions	Yield
In hexane at -5 - 40℃; for 2h; Inert atmosphere;	69.8%
In hexane at -5 - 40℃; for 2h; Inert atmosphere;	69.8%

: 607-26-1
N,N'-ethylenediphthalimide

: 1116-73-0
trihexylaluminium

: C36H51AlN2O4

Conditions

Conditions	Yield
In toluene at -5 - 90℃; for 2h; Inert atmosphere;	69.1%
In toluene at -5 - 90℃; for 2h; Inert atmosphere;	69.1%
In toluene at -5 - 90℃; for 2h; Inert atmosphere;	69.1%

: 31001-80-6
3-penten-2-yl acetate

: 1116-73-0
trihexylaluminium

: 86761-84-4
4-methyl-2-decene

Conditions

Conditions	Yield
With iron(III) chloride In hexane at 25℃;	67%

: 1116-73-0
trihexylaluminium

: 170751-24-3
dimethyl 2-phenyl-cycloprop-2-ene-1,1-dicarboxylic ester

: 1083094-24-9
dimethyl (E)-2-(2-phenyloct-1-enyl)malonate

Conditions

Conditions	Yield
With iron(III)-acetylacetonate In tetrahydrofuran; hexane at 0 - 20℃; for 16h; stereoselective reaction;	66%

: 75-77-4
chloro-trimethyl-silane

: 1116-73-0
trihexylaluminium

A: 3429-62-7
trimethylhexylsilane

B: 3429-61-6
di-n-hexyldimethylsilane

Conditions

Conditions	Yield
With potassium chloride at 150℃; for 6h;	A 65% B 35%

...Expand

: 1116-73-0
trihexylaluminium

: 2614-88-2
sorbinyl chloride

: 87488-21-9
2,4-dodecadien-6-one

Conditions

Conditions	Yield
With aluminium trichloride In dichloromethane -10 deg C, then 20 deg C, 1 h;	65%

: 76644-52-5, 76704-31-9, 14447-34-8, 62247-41-0
rac-3-acetoxycyclohexene

: 1116-73-0
trihexylaluminium

: 3-hexyl-1-cyclohexene

Conditions

Conditions	Yield
With copper(I) bromide In hexane at 25℃;	63%

: 1116-73-0
trihexylaluminium

: C9H6NO(1-)*C5H9O(1+)*AlCl3

: 33083-83-9
undecan-5-one

Conditions

Conditions	Yield
In dichloromethane	62%

: 13043-77-1
acetic acid-(1,1-dimethyl-pent-4-en-2-ynyl ester)

: 1116-73-0
trihexylaluminium

: 85980-40-1
2-methyl-4-hexyl-2,3,5-hexatriene

Conditions

Conditions	Yield
iron(III) chloride In diethyl ether at 20℃; for 2h;	62%

: 13043-77-1
acetic acid-(1,1-dimethyl-pent-4-en-2-ynyl ester)

: 1116-73-0
trihexylaluminium

A: 85980-40-1
2-methyl-4-hexyl-2,3,5-hexatriene

B Et2AlOAc: Et2AlOAc

Conditions

Conditions	Yield
With iron(III) chloride In diethyl ether at 20℃; for 2h;	A 62% B n/a

...Expand

: 1039361-88-0
N-benzyl-N-(3-oxobutyl)-(E)-3-(4-methoxyphenyl)propenamide

: 1116-73-0
trihexylaluminium

: (3RS,4RS)-1-benzyl-4-hydroxy-3-[(RS)-1-(4-methoxyphenyl)heptyl]-4-methylpiperidin-2-one

Conditions

Conditions	Yield
Stage #1: N-benzyl-N-(3-oxobutyl)-(E)-3-(4-methoxyphenyl)propenamide With bis-acetylacetonatocobalt(II) dihydrate In tetrahydrofuran at 0 - 20℃; for 18h; Stage #2: trihexylaluminium In tetrahydrofuran; hexane at 0 - 20℃; for 23h; diastereoselective reaction;	61%

: 1116-73-0
trihexylaluminium

: 75-78-5
dimethylsilicon dichloride

A: 3634-59-1
dimethylhexylsilyl chloride

B: 3429-61-6
di-n-hexyldimethylsilane

C: 63246-85-5
dimethylhexylsilane

Conditions

Conditions	Yield
With potassium chloride at 150℃; for 3h;	A 31% B 58% C 11%
With potassium chloride at 150℃; for 3h;	A 56% B 34% C 10%

...Expand

: 34721-76-1
2-butylcycloprop-2-ene-1,1-dicarboxylic acid dimethyl ester

: 1116-73-0
trihexylaluminium

: 1083094-25-0
dimethyl (Z)-2-(2-butyloct-1-enyl)malonate

Conditions

Conditions	Yield
With iron(III)-acetylacetonate In tetrahydrofuran; hexane at 0 - 20℃; for 16h; stereoselective reaction;	52%

: 101009-34-1
trans-(Mo6Cl8)Cl4(tributylphosphine)2

: 1116-73-0
trihexylaluminium

: 101009-26-1
all-trans-(Mo6Cl8)Cl2(n-C6H13)2(tributylphosphine)2

Conditions

Conditions	Yield
In toluene (N2); a soln. of Al(C6H13)3 added to a suspn. of Mo-compound at -15°C; stirred at -15°C for 20 h; evapd. in vacuo; ether added; ppte. washed with ether; dried in vacuo; dissolved in toluene at 60°C; filtered; concentrated; cooled to -20°C; elem. anal.;	8%

Tri-n-hexylaluminium Chemical Properties

Molecular structure of Tri-n-hexylaluminium (CAS NO.1116-73-0) is:

Product Name: Tri-n-hexylaluminium
CAS Registry Number: 1116-73-0
IUPAC Name: Trihexylalumane
Molecular Weight: 282.483798 [g/mol]
Molecular Formula: C₁₈H₃₉Al
H-Bond Donor: 0
H-Bond Acceptor: 0
EINECS: 214-241-6
Density: 0.686 g/cm³
Storage temp.: Flammables + water-Freezer (-20 °C)e area
Product Categories: Organometallics
Canonical SMILES: CCCCCC[Al](CCCCCC)CCCCCC
InChI: InChI=1S/3C6H13.Al/c3*1-3-5-6-4-2;/h3*1,3-6H2,2H3;
InChIKey: ORYGRKHDLWYTKX-UHFFFAOYSA-N

Tri-n-hexylaluminium Safety Profile

Safty information about Tri-n-hexylaluminium (CAS NO.1116-73-0) is:
Hazard Codes: Dangerous N; Corrosive C; Flammable F
Risk Statements: 67-65-62-51/53-48/20-34-14/15-11
R67:Vapours may cause drowsiness and dizziness.
R65:Harmful: may cause lung damage if swallowed.
R62:Risk of impaired fertility.
R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R48/20:Danger of serious damage to health by prolonged exposure and harmful by inhalation.
R34:Causes burns.
R14/15 :Reacts violently with water and contact with water liberates extremely flammable gases.
R11:Highly flammable.
Safety Statements: 6A-61-45-43B-36/37/39-24/25-16
S6:Keep under ... (there follows the name of an inert gas).
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S43:In case of fire use ... (there follows the type of fire-fighting equipment to be used.)
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
S24/25:Avoid contact with skin and eyes.
S16:Keep away from sources of ignition.
RIDADR: 3051
HazardClass: 4.2
PackingGroup: I

Tri-n-hexylaluminium Specification

Tri-n-hexylaluminium , its cas register number is 1116-73-0. It also can be called Trihexylalane ; Aluminum, trihexyl- ; Trihexylaluminium .It is a clear colorless solution.

Product Name

TRI-N-HEXYL ALUMINUM

Synthetic route

Tri-n-hexylaluminium Chemical Properties

Tri-n-hexylaluminium Safety Profile

Tri-n-hexylaluminium Specification

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