Product Name

  • Name

    Triphenylmethanol

  • EINECS 200-988-5
  • CAS No. 76-84-6
  • Article Data607
  • CAS DataBase
  • Density 1.13 g/cm3
  • Solubility insoluble in water
  • Melting Point 160-163 °C(lit.)
  • Formula C19H16O
  • Boiling Point 380 °C at 760 mmHg
  • Molecular Weight 260.335
  • Flash Point 168.7 °C
  • Transport Information
  • Appearance white powder
  • Safety 22-24/25-36-26
  • Risk Codes 36/37/38
  • Molecular Structure Molecular Structure of 76-84-6 (Triphenylmethanol)
  • Hazard Symbols IrritantXi
  • Synonyms Methanol,triphenyl- (8CI);BL 3756;Hydroxytriphenylmethane;NSC 4050;Triphenylcarbinol;Triphenylmethyl alcohol;Tritanol;Tritylalcohol;U 45483;a,a-Diphenylbenzenemethanol;
  • PSA 20.23000
  • LogP 3.97080

Synthetic route

trityl chloride
76-83-5

trityl chloride

triphenylmethyl alcohol
76-84-6

triphenylmethyl alcohol

Conditions
ConditionsYield
With water In tetrachloromethane100%
With water Kinetics; Rate constant; Mechanism; Two-phase systems;
With water In acetone at 25℃; Kinetics; ΔS, ΔH (excit.);
bromo-triphenyl-methane
596-43-0

bromo-triphenyl-methane

di-sec-butyl mercury
691-88-3

di-sec-butyl mercury

A

triphenylmethyl alcohol
76-84-6

triphenylmethyl alcohol

B

secondary-butyl mercury(II) bromide
53213-46-0, 868-82-6

secondary-butyl mercury(II) bromide

C

sec-butyl triphenylmethyl peroxide
78504-79-7

sec-butyl triphenylmethyl peroxide

Conditions
ConditionsYield
With oxygen; tetrabutylammomium bromide In 1,2-dichloro-ethane; benzene Product distribution; other reaction conditions;A n/a
B n/a
C 100%
With oxygen; tetrabutylammomium bromide In 1,2-dichloro-ethane Yields of byproduct given;A n/a
B n/a
C 76%
trimethylsilyl triphenyl methyl ether
50653-07-1

trimethylsilyl triphenyl methyl ether

triphenylmethyl alcohol
76-84-6

triphenylmethyl alcohol

Conditions
ConditionsYield
Stage #1: trimethylsilyl triphenyl methyl ether With nitrogen dioxide at 20℃; for 0.833333h;
Stage #2: With water
100%
With methanol; 1,3-disulfonic acid imidazolium hydrogen sulfate at 20℃; for 0.0833333h; Green chemistry;99%
With montmorillonite K-10 In methanol for 4h; Ambient temperature;98%
2-(trityloxy)tetrahydro-2H-pyran

2-(trityloxy)tetrahydro-2H-pyran

triphenylmethyl alcohol
76-84-6

triphenylmethyl alcohol

Conditions
ConditionsYield
With acid-washed bentonite In acetone at 40 - 50℃; for 0.166667h;100%
triphenylmethane
519-73-3

triphenylmethane

triphenylmethyl alcohol
76-84-6

triphenylmethyl alcohol

Conditions
ConditionsYield
With chromyl chloride In tetrachloromethane at 22℃; for 0.5h; ultrasound sonication;99%
With potassium hydroxide; 18-crown-6 ether; oxygen; dimethyl sulfoxide In 1,2-dimethoxyethane at 20℃; for 1.5h;97%
With chromium(VI) oxide; tetrabutylammonium periodite In dichloromethane; acetonitrile at -40℃; for 0.166667h;97%
1-diphenylmethylene-4-trityl-2,5-cyclohexadiene
18909-18-7

1-diphenylmethylene-4-trityl-2,5-cyclohexadiene

C41H48FeN7O(2+)*2CF3O3S(1-)

C41H48FeN7O(2+)*2CF3O3S(1-)

A

triphenylmethyl alcohol
76-84-6

triphenylmethyl alcohol

C42H47F3FeN7O3S(1+)*CF3O3S(1-)

C42H47F3FeN7O3S(1+)*CF3O3S(1-)

Conditions
ConditionsYield
In tetrahydrofuran; acetonitrile at 20℃; for 0.5h; Reagent/catalyst; Inert atmosphere; Glovebox;A 99%
B 83%
4,5-dihydroxymethyl-1-triphenylmethylimidazole
77134-74-8

4,5-dihydroxymethyl-1-triphenylmethylimidazole

A

4,5-dihydroxymethylimidazole
33457-48-6

4,5-dihydroxymethylimidazole

B

triphenylmethyl alcohol
76-84-6

triphenylmethyl alcohol

Conditions
ConditionsYield
With acetic acid for 1.5h; Heating;A 98.5%
B n/a
N-benzyl-N’-(4-nitrophenyl)urea
13141-87-2

N-benzyl-N’-(4-nitrophenyl)urea

benzene
71-43-2

benzene

triphenylmethyl alcohol
76-84-6

triphenylmethyl alcohol

Conditions
ConditionsYield
With trifluorormethanesulfonic acid at 50℃; for 12h; Inert atmosphere;98%
benzoic acid methyl ester
93-58-3

benzoic acid methyl ester

phenyllithium
591-51-5

phenyllithium

triphenylmethyl alcohol
76-84-6

triphenylmethyl alcohol

Conditions
ConditionsYield
In water at 25℃; for 0.00555556h; Solvent;98%
triphenylacetic acid
595-91-5

triphenylacetic acid

triphenylmethyl alcohol
76-84-6

triphenylmethyl alcohol

Conditions
ConditionsYield
With potassium 12-tungstocobaltate(III) In water; acetonitrile for 0.2h; Microwave irradiation;96%
With 1H-imidazole; C17H16ClMnN2O2; tetrabutylammonium periodite In chloroform at 20℃; for 0.333333h;95%
With oxygen; mercury(II) oxide In methanol; acetonitrile at 25℃; UV-irradiation;88%
methyl 2,4-di-O-benzyl-3-O-methyl-6-O-trityl-α-D-galactopyranoside
83075-47-2

methyl 2,4-di-O-benzyl-3-O-methyl-6-O-trityl-α-D-galactopyranoside

A

triphenylmethyl alcohol
76-84-6

triphenylmethyl alcohol

B

methyl 2,4-di-O-benzyl-3-O-methyl-α-D-galactopyranoside
83075-48-3

methyl 2,4-di-O-benzyl-3-O-methyl-α-D-galactopyranoside

Conditions
ConditionsYield
With acetic acid In water Heating;A n/a
B 96%
MoO2Cl2(OP(N(CH3)2)3)2
54189-41-2, 65378-12-3

MoO2Cl2(OP(N(CH3)2)3)2

trityl hydroperoxide
4198-93-0

trityl hydroperoxide

A

triphenylmethyl alcohol
76-84-6

triphenylmethyl alcohol

MoO(O2)Cl2(OP(N(CH3)2)3)2

MoO(O2)Cl2(OP(N(CH3)2)3)2

Conditions
ConditionsYield
In dichloromethane to Mo complex dissolved in CH2Cl2 added Ph3COOH, stirred for 30 min; concd., Et2O added; elem. anal.;A 95%
B 86%
2-oxo-4-[(triphenylmethoxy)methyl]-hexahydro-2H-cyclopenta[b]furan-5-yl [1,1'-biphenyl]-4-carboxylate

2-oxo-4-[(triphenylmethoxy)methyl]-hexahydro-2H-cyclopenta[b]furan-5-yl [1,1'-biphenyl]-4-carboxylate

A

triphenylmethyl alcohol
76-84-6

triphenylmethyl alcohol

B

4-(hydroxymethyl)-2-oxo-hexahydro-2H-cyclopenta[b]furan-5-yl [1,1'-biphenyl]-4-carboxylate

4-(hydroxymethyl)-2-oxo-hexahydro-2H-cyclopenta[b]furan-5-yl [1,1'-biphenyl]-4-carboxylate

Conditions
ConditionsYield
With hydrogenchloride In acetonitrile at 40℃; for 6h; Solvent;A 94.1%
B 94.2%
bromo-triphenyl-methane
596-43-0

bromo-triphenyl-methane

potassium ethyl xanthogenate
140-89-6

potassium ethyl xanthogenate

A

triphenylmethyl alcohol
76-84-6

triphenylmethyl alcohol

B

bis-ethoxythiocarbonyldisulfane
502-55-6

bis-ethoxythiocarbonyldisulfane

C

O-ethyl S-triphenylmethyl dithiocarbonate
132277-76-0

O-ethyl S-triphenylmethyl dithiocarbonate

Conditions
ConditionsYield
In benzene for 6h; Ambient temperature;A 2%
B 2%
C 94%
Trityl-tert.butylaether
100675-64-7

Trityl-tert.butylaether

triphenylmethyl alcohol
76-84-6

triphenylmethyl alcohol

Conditions
ConditionsYield
With water; acetic acid In dichloromethane for 0.25h;94%
triphenylmethyl phenyl sulfide
16928-73-7

triphenylmethyl phenyl sulfide

A

triphenylmethyl alcohol
76-84-6

triphenylmethyl alcohol

B

diphenyldisulfane
882-33-7

diphenyldisulfane

Conditions
ConditionsYield
In acetonitrile at -5℃; for 3h; Product distribution; Irradiation; photochemical reaction of sulfides with tetranitromethane; oxidation and fragmentation products; oxidation, fragmentation, deprotonation and aromatic substitution pathways; generation of radical cations by chemical oxidation with triarylaminium salts;A 90%
B 94%
With 5-methoxy-phenanthridinium In [D3]acetonitrile at 25℃; Irradiation;A 27 % Spectr.
B 13 % Spectr.
With N-methoxy phenanthridinium hexafluorophosphate In acetonitrile Photolysis; Inert atmosphere;A 17.4 %Chromat.
B 8.5 %Chromat.
di-triphenylmethyl hyponitrite
1246680-87-4

di-triphenylmethyl hyponitrite

A

triphenylmethyl alcohol
76-84-6

triphenylmethyl alcohol

B

benzhydrylphenyl ether
4733-41-9

benzhydrylphenyl ether

Conditions
ConditionsYield
With cyclohexa-1,4-diene In dichloromethane at 20℃; for 7h; Kinetics;A 93.1%
B 30.6%
trityl chloride
76-83-5

trityl chloride

trehalose dihydrate
6138-23-4, 138858-75-0

trehalose dihydrate

A

triphenylmethyl alcohol
76-84-6

triphenylmethyl alcohol

B

6-O-(triphenylmethyl)-α-D-glucopyranosyl-6'-O-(triphenylmethyl)-α-D-glucopyranoside
50705-44-7, 108811-30-9

6-O-(triphenylmethyl)-α-D-glucopyranosyl-6'-O-(triphenylmethyl)-α-D-glucopyranoside

Conditions
ConditionsYield
In pyridine for 45h; Ambient temperature;A n/a
B 92%
C23H27N2O3P
127136-68-9

C23H27N2O3P

triphenylmethyl alcohol
76-84-6

triphenylmethyl alcohol

Conditions
ConditionsYield
With sodium In ammonia92%
With ammonia; sodium In tetrahydrofuran for 0.25h; Product distribution;92%
2,2,2-Tris-methylsulfanyl-1-phenyl-ethanone
21504-18-7

2,2,2-Tris-methylsulfanyl-1-phenyl-ethanone

triphenylmethyl perchlorate

triphenylmethyl perchlorate

A

triphenylmethyl alcohol
76-84-6

triphenylmethyl alcohol

B

triphenmethyl methyl sulfide
62575-83-1

triphenmethyl methyl sulfide

C

Bis-methylsulfanyl-phenyl-thioacetic acid S-methyl ester
195305-56-7

Bis-methylsulfanyl-phenyl-thioacetic acid S-methyl ester

Conditions
ConditionsYield
In dichloromethane for 2h; Product distribution; Mechanism; Ambient temperature; various substrates under different reaction conditions;A 23%
B 72%
C 92%
bromobenzene
108-86-1

bromobenzene

benzophenone
119-61-9

benzophenone

triphenylmethyl alcohol
76-84-6

triphenylmethyl alcohol

Conditions
ConditionsYield
With bismuth(III) chloride; silver(I) bromide; magnesium; copper(ll) bromide In tetrahydrofuran; toluene at 96℃; for 12h; Barbier Coupling Reaction;91%
With magnesium 1.) terbutyl methyl ether, THF, iodine, dichloroethane, reflux, 2.) reflux, 2.5 h; Multistep reaction;
Stage #1: bromobenzene With magnesium In tetrahydrofuran at 55℃; for 0.333333h; Grignard reaction; Inert atmosphere; Sonication;
Stage #2: benzophenone In tetrahydrofuran at 55℃; for 0.166667h; Grignard reaction; Sonication;
Stage #1: bromobenzene With magnesium In diethyl ether at 35℃; for 2h;
Stage #2: benzophenone In diethyl ether for 24h; Reflux;
triphenylmethane
519-73-3

triphenylmethane

A

benzophenone
119-61-9

benzophenone

B

triphenylmethyl alcohol
76-84-6

triphenylmethyl alcohol

Conditions
ConditionsYield
With tert-butylbenzene; tributylphosphine for 6.5h; Heating;A 4%
B 91%
With oxygen; N-hydroxyphthalimide In benzonitrile at 100℃; under 760 Torr; for 20h;A 20 % Chromat.
B 30 % Chromat.
With 3-tert-butylbenzene-1,2-diol; oxygen; Na11Zn3 W19Ru2O70H3 In 1,2-dichloro-ethane at 80℃; for 24h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
With ozone In dichloromethane at 25℃; for 1h; Mechanism; Kinetics; Rate constant; other reaction times;
With oxygen; Na11Zn3 W19Ru2O70H3 In 1,2-dichloro-ethane at 80℃; for 24h; Product distribution; also in the presence of tert-butylcatechol;
hexaphenylethane
17854-07-8

hexaphenylethane

C36H47ClFeN5O2

C36H47ClFeN5O2

A

triphenylmethyl alcohol
76-84-6

triphenylmethyl alcohol

C36H46ClFeN5O

C36H46ClFeN5O

Conditions
ConditionsYield
In tetrahydrofuran; toluene at 23℃; for 4h; Solvent; Time; Inert atmosphere; Schlenk technique;A 91%
B n/a
3,6-diphenyl-1,2,4-trioxane
61040-98-0

3,6-diphenyl-1,2,4-trioxane

phenyllithium
591-51-5

phenyllithium

A

phenylethane 1,2-diol
93-56-1

phenylethane 1,2-diol

B

1,1-Diphenylmethanol
91-01-0

1,1-Diphenylmethanol

C

triphenylmethyl alcohol
76-84-6

triphenylmethyl alcohol

D

benzyl alcohol
100-51-6

benzyl alcohol

Conditions
ConditionsYield
In diethyl ether at 20℃; for 4.5h; Product distribution; Mechanism; reaction with alkylmagnesium galides, single electron transfer mechanism;A 39%
B 90%
C 26%
D 26%
O2,2'-anhydro-5,6-dihydro-6-(S)-(1,3-dithian-2-yl)-5'-O-trityluridine
73080-19-0

O2,2'-anhydro-5,6-dihydro-6-(S)-(1,3-dithian-2-yl)-5'-O-trityluridine

A

triphenylmethyl alcohol
76-84-6

triphenylmethyl alcohol

B

3-<(S)-1-(1,3-dithian-2-yl)>propionamido-(1,2-dideoxy-β-D-arabinofurano)-<1,2-d>-2-oxazolidinone
73092-24-7

3-<(S)-1-(1,3-dithian-2-yl)>propionamido-(1,2-dideoxy-β-D-arabinofurano)-<1,2-d>-2-oxazolidinone

C

5,6-dihydro-6-(S)-(1,3-dithian-2-yl)-1-β-D-arabinofuranosyluracil
73080-26-9

5,6-dihydro-6-(S)-(1,3-dithian-2-yl)-1-β-D-arabinofuranosyluracil

Conditions
ConditionsYield
With acetic acid for 10h; Heating;A n/a
B 90%
C 10%
methyl 4-hydroxymethyl-1-triphenylmethylimidazole-5-carboxylate
82048-30-4

methyl 4-hydroxymethyl-1-triphenylmethylimidazole-5-carboxylate

A

triphenylmethyl alcohol
76-84-6

triphenylmethyl alcohol

B

methyl 4(5)-hydroxymethylimidazole-5(4)-carboxylate
82032-43-7

methyl 4(5)-hydroxymethylimidazole-5(4)-carboxylate

Conditions
ConditionsYield
In ethanol; acetic acid for 0.75h; Heating;A n/a
B 90%
triphenylmethyl alcohol
76-84-6

triphenylmethyl alcohol

triphenylmethane
519-73-3

triphenylmethane

Conditions
ConditionsYield
With hydridotetracarbonylcobalt In dichloromethane at 20℃; Rate constant;100%
With dimethylsilicon dichloride; sodium iodide In dichloromethane; acetone for 0.166667h; Ambient temperature;100%
With iodine; hypophosphorous acid In acetic acid at 60℃; for 24h;100%
triphenylmethyl alcohol
76-84-6

triphenylmethyl alcohol

triphenylmethanethiol
3695-77-0

triphenylmethanethiol

Conditions
ConditionsYield
With Lawessons reagent In 1,2-dimethoxyethane for 15h; Mechanism; Ambient temperature; various alcohols, other solvents, other temperatures;100%
With Lawessons reagent In toluene for 0.2h; Quantum yield; Heating; DME, room temperature;100%
With Lawessons reagent In 1,2-dimethoxyethane for 15h; Ambient temperature;100%
triphenylmethyl alcohol
76-84-6

triphenylmethyl alcohol

trityl chloride
76-83-5

trityl chloride

Conditions
ConditionsYield
With Vilsmeier reagent In 1,4-dioxane at 80℃; for 0.5h;100%
With hydrogenchloride; calcium chloride In water; toluene at 25℃; for 5h; Solvent; Reagent/catalyst;96%
With chloro-trimethyl-silane In dichloromethane; water at 0℃; for 0.666667h;90%
triphenylmethyl alcohol
76-84-6

triphenylmethyl alcohol

mercaptoacetic acid
68-11-1

mercaptoacetic acid

2-(triphenylmethylthio)ethanoic acid
34914-36-8

2-(triphenylmethylthio)ethanoic acid

Conditions
ConditionsYield
With trifluoroacetic acid at 20℃; for 0.5h;100%
With trifluoroacetic acid In chloroform at 20℃; for 1h;98%
With trifluoroacetic acid In chloroform at 20℃; for 3h;95%
triphenylmethyl alcohol
76-84-6

triphenylmethyl alcohol

Triphenyl-methanol anion
118488-56-5

Triphenyl-methanol anion

Conditions
ConditionsYield
With potassium hydride; cryptand 222B In benzene for 0.0833333h;100%
triphenylmethyl alcohol
76-84-6

triphenylmethyl alcohol

2-mercaptoethylamine hydrochloride
156-57-0

2-mercaptoethylamine hydrochloride

2-amino tritylthio ethane
1095-85-8

2-amino tritylthio ethane

Conditions
ConditionsYield
With trifluoroacetic acid at 20℃; for 3h;100%
With boron trifluoride diethyl etherate; triethylamine In chloroform at 75℃;99%
With boron trifluoride diethyl etherate; triethylamine In chloroform at 75℃;99%
triphenylmethyl alcohol
76-84-6

triphenylmethyl alcohol

1-dodecylthiol
112-55-0

1-dodecylthiol

dodecyl triphenylmethyl sulfide
145544-33-8

dodecyl triphenylmethyl sulfide

Conditions
ConditionsYield
With trifluoroacetic acid In chloroform at 20℃; for 3.5h; Inert atmosphere;100%
With dodecylbenzene-sulphonic acid In water at 80℃; for 24h;97%
triphenylmethyl alcohol
76-84-6

triphenylmethyl alcohol

diisobutylaluminium hydride
1191-15-7

diisobutylaluminium hydride

isobutylalumoxane

isobutylalumoxane

Conditions
ConditionsYield
In not given byproducts: (C6H5)3CH; rection of aluminum compd. with alcohol at -78°C;100%
triphenylmethyl alcohol
76-84-6

triphenylmethyl alcohol

2-mercaptoethylamine hydrochloride
156-57-0

2-mercaptoethylamine hydrochloride

<2-<(triphenylmethyl)thio>ethyl>amine hydrochloride
15297-43-5

<2-<(triphenylmethyl)thio>ethyl>amine hydrochloride

Conditions
ConditionsYield
With trifluoroacetic acid at 20℃;100%
pyrrole
109-97-7

pyrrole

triphenylmethyl alcohol
76-84-6

triphenylmethyl alcohol

2-triphenylmethyl-1H-pyrrole
102594-08-1

2-triphenylmethyl-1H-pyrrole

Conditions
ConditionsYield
at 100℃; for 3h; Ionic liquid; Inert atmosphere; regioselective reaction;99%
With pentafluorophenylboronic acid In 1,2-dichloro-ethane for 16h; Friedel-Crafts arylation; Reflux; Molecular sieve;90%
With pentafluorophenylboronic acid In toluene for 2h; Molecular sieve; Reflux;70%
With acetic acid
indole
120-72-9

indole

triphenylmethyl alcohol
76-84-6

triphenylmethyl alcohol

(indol-3-yl)triphenylmethane
32863-87-9

(indol-3-yl)triphenylmethane

Conditions
ConditionsYield
With pentafluorophenylboronic acid In 1,2-dichloro-ethane for 16h; Friedel-Crafts arylation; Reflux; Molecular sieve;99%
With zinc(II) chloride In 1,4-dioxane at 110 - 130℃;98%
With iodine In acetonitrile at 20℃; for 0.75h;98%
With phosphomolybdic acid In ethylenediamine at 60℃; for 1h;97%
With scandium tris(trifluoromethanesulfonate) In dichloromethane at 60℃; for 4h; Sealed tube;88%
triphenylmethyl alcohol
76-84-6

triphenylmethyl alcohol

chlorhydrate du L-cysteinate d'ethyle
868-59-7, 7319-36-0, 75521-14-1, 93964-73-9

chlorhydrate du L-cysteinate d'ethyle

S-trityl-L-cysteinate d'ethyle
27486-86-8

S-trityl-L-cysteinate d'ethyle

Conditions
ConditionsYield
With trifluoroacetic acid for 0.25h;99%
triphenylmethyl alcohol
76-84-6

triphenylmethyl alcohol

acetic anhydride
108-24-7

acetic anhydride

triphenylmethyl acetate
971-85-7

triphenylmethyl acetate

Conditions
ConditionsYield
With Cp2Ti(OSO2C8F17)2 at 100℃; for 0.4h; Neat (no solvent);99%
Stage #1: triphenylmethyl alcohol; acetic anhydride With molybdenium(VI) dioxodichloride In toluene
Stage #2: With N-ethyl-N,N-diisopropylamine In toluene for 2h; Heating;
98%
K5 In acetonitrile at 20℃; for 4h;90%
triphenylmethyl alcohol
76-84-6

triphenylmethyl alcohol

allyl-trimethyl-silane
762-72-1

allyl-trimethyl-silane

allyltriphenylmethane
16876-20-3

allyltriphenylmethane

Conditions
ConditionsYield
With tris(pentafluorophenyl)borate In dichloromethane at 20℃;99%
With 3-dodecyl-2-iodo-1-methyl-1H-imidazol-3-ium hexafluoroantimonate; iodine In nitromethane at 20℃; for 2h; Inert atmosphere;99%
With titanium tetrachloride In dichloromethane at 20℃; for 0.0166667h;98%
triphenylmethyl alcohol
76-84-6

triphenylmethyl alcohol

urethane
51-79-6

urethane

trityl-carbamic acid ethyl ester
102459-48-3

trityl-carbamic acid ethyl ester

Conditions
ConditionsYield
With toluene-4-sulfonic acid In benzene for 3h; Heating;99%
triphenylmethyl alcohol
76-84-6

triphenylmethyl alcohol

2,2-dimethylpropanoic anhydride
1538-75-6

2,2-dimethylpropanoic anhydride

2,2-dimethylpropionic acid trityl ester
24523-65-7

2,2-dimethylpropionic acid trityl ester

Conditions
ConditionsYield
Stage #1: triphenylmethyl alcohol; 2,2-dimethylpropanoic anhydride With molybdenium(VI) dioxodichloride In toluene
Stage #2: With N-ethyl-N,N-diisopropylamine In toluene for 12h; Heating;
99%
triphenylmethyl alcohol
76-84-6

triphenylmethyl alcohol

diphenyl acetylene
501-65-5

diphenyl acetylene

1,2,3,4-tetraphenylnaphthalene
751-38-2

1,2,3,4-tetraphenylnaphthalene

Conditions
ConditionsYield
With copper diacetate; chloro(1,5-cyclooctadiene)rhodium(I) dimer In o-xylene at 170℃; for 4h;99%
triphenylmethyl alcohol
76-84-6

triphenylmethyl alcohol

trimethylsilyl cyanide
7677-24-9

trimethylsilyl cyanide

2,2,2-triphenylacetonitrile
6639-43-6

2,2,2-triphenylacetonitrile

Conditions
ConditionsYield
With iodine; lithium carbonate In dichloromethane at 35℃; for 5h;99%
With tris(pentafluorophenyl)borate In acetonitrile at 20℃; for 1.16667h;93%
With tris(pentafluorophenyl)borate In acetonitrile at 20℃; for 17h;57%
With indium(III) chloride In toluene at 20℃;89 %Chromat.
triphenylmethyl alcohol
76-84-6

triphenylmethyl alcohol

2-chloro-4-fluorobenzenethiol

2-chloro-4-fluorobenzenethiol

2-chloro-4-fluoro-1-tritylsulfanylbenzene
1434816-93-9

2-chloro-4-fluoro-1-tritylsulfanylbenzene

Conditions
ConditionsYield
With trifluoroacetic acid In dichloromethane at 20℃; for 1.5h; Cooling with ice;99%
With trifluoroacetic acid In dichloromethane at 20℃; for 1.5h;99%
triphenylmethyl alcohol
76-84-6

triphenylmethyl alcohol

2-mercaptoethylamine hydrochloride
156-57-0

2-mercaptoethylamine hydrochloride

trifluoroacetic acid
76-05-1

trifluoroacetic acid

S-triphenylmethyl-1-aminoethanethiol trifluoroacetate

S-triphenylmethyl-1-aminoethanethiol trifluoroacetate

Conditions
ConditionsYield
at 20℃; for 2h;98.5%
at 20℃; for 1h;
acetamide
60-35-5

acetamide

triphenylmethyl alcohol
76-84-6

triphenylmethyl alcohol

N-tritylacetamide
1596-25-4

N-tritylacetamide

Conditions
ConditionsYield
With toluene-4-sulfonic acid In benzene for 5h; Heating;98%
With sulfuric acid at 210 - 240℃;
methanol
67-56-1

methanol

triphenylmethyl alcohol
76-84-6

triphenylmethyl alcohol

methoxytriphenylmethane
596-31-6

methoxytriphenylmethane

Conditions
ConditionsYield
ammonium cerium(IV) nitrate for 0.25h; Heating;98%
With sulfuric acid for 4.5h; Ambient temperature;93%
With 2,3-dicyano-5,6-dichloro-p-benzoquinone for 0.75h; Heating;92%
triphenylmethyl alcohol
76-84-6

triphenylmethyl alcohol

l-cysteine hydrochloride
52-89-1

l-cysteine hydrochloride

S-trityl-L-cysteine
2799-07-7

S-trityl-L-cysteine

Conditions
ConditionsYield
Stage #1: triphenylmethyl alcohol; l-cysteine hydrochloride With trifluoroacetic acid for 2h;
Stage #2: With sodium acetate; sodium hydroxide In diethyl ether; water at 0℃; pH=5 - 6;
98%
With trifluoroacetic acid for 3h; Inert atmosphere;96%
With choline chloride; urea In trifluoroacetic acid at 25℃; for 2h;95%

Triphenylmethanol Specification

Triphenylmethanol is also known as Trityl alcohol, Triphenylcarbinol, 76-84-6, Methanol, triphenyl-, Tritanol, Triphenylmethyl alcohol, triphenylmethan-1-ol. With the Molecular Formula C19H16O, it is an organic compound and a white crystalline solid that is insoluble in water and petroleum ether, but well soluble in ethanol, diethyl ether, and benzene. It reacts with acetyl chloride to give triphenylmethyl chloride.

Physical properties about Triphenylmethanol are: (1)ACD/LogP: 3.836; (2)ACD/LogD (pH 5.5): 3.84; (3)ACD/LogD (pH 7.4): 3.84; (4)ACD/BCF (pH 5.5): 484.72; (5)ACD/BCF (pH 7.4): 484.71; (6)ACD/KOC (pH 5.5): 2909.88; (7)ACD/KOC (pH 7.4): 2909.86; (8)#H bond acceptors: 1; (9)#H bond donors: 1; (10)#Freely Rotating Bonds: 4; (11)Index of Refraction: 1.622; (12)Molar Refractivity: 81.072 cm3; (13)Molar Volume: 230.289 cm3; (14)Polarizability: 32.14 10-24cm3; (15)Surface Tension: 46.4389991760254 dyne/cm; (16)Density: 1.13 g/cm3; (17)Flash Point: 168.744 °C; (18)Enthalpy of Vaporization: 66.255 kJ/mol; (19)Boiling Point: 379.999 °C at 760 mmHg

Preparation of Triphenylmethanol: The preparation of triphenylmethanol from methyl benzoate or benzophenone and bromobenzene is a common laboratory experiment for teaching the Grignard reaction. An alternative starting material is diethyl carbonate.

Synthesis_of_triphenylmethanol.png

When you are using this chemical, please be cautious about it as the following:
1. Do not breathe dust;
2. Avoid contact with skin and eyes;
3. Wear suitable protective clothing;
4. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice;

You can still convert the following datas into molecular structure:
(1)InChI=1S/C19H16O/c20-19(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15,20H;
(2)InChIKey=LZTRCELOJRDYMQ-UHFFFAOYSA-N;
(3)SmilesC(c1ccccc1)(c1ccccc1)(c1ccccc1)O;

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