Tripiperidinophosphine supplier

Name
Tripiperidinophosphine
EINECS
CAS No. 13954-38-6
Article Data17
CAS DataBase
Density
Solubility
Melting Point
Formula C₁₅H₃₀N₃P
Boiling Point 370.2 °C at 760 mmHg
Molecular Weight 283.397
Flash Point 177.7 °C
Transport Information
Appearance Gray-white power
Safety
Risk Codes
Molecular Structure
Hazard Symbols
Synonyms Piperidine,1,1',1''-phosphinidynetri- (6CI,7CI,8CI);1,1',1''-Phosphinidynetripiperidine;NSC 99043;Phosphine, tri-1-piperidinyl-;Phosphorous tripiperidide;Tripiperidinophosphine;Tripiperidylphosphine;Tris(1-piperidinyl)phosphine;Tris(piperidino)phosphine;
PSA 23.31000
LogP 3.48470

Synthetic route

: 110-89-4
piperidine

: 13954-38-6
tripiperidino-phosphine

Conditions

Conditions	Yield
With phosphorus trichloride In diethyl ether	100%
With triethylamine; phosphorus trichloride In diethyl ether at 20℃; for 1h;	76%
With phosphorus trichloride In diethyl ether at 0 - 20℃;	76%

: 110-89-4
piperidine

: 2283-11-6
hexaethylphosphoric triamide

: 13954-38-6
tripiperidino-phosphine

Conditions

Conditions	Yield
at 70℃; for 10h;	95%

: 863650-25-3
C30H46N4O2P2

A: 914468-02-3
2,6-dipiperidino-1,3,5,7-tetraoxa-2,6-diphospha-4,8(1,3)-dinaphthalenacyclooctaphane

B: 13954-38-6
tripiperidino-phosphine

Conditions

Conditions	Yield
	A 41% B n/a

: C30H46N4O2P2

A: cyclo[bis(1,6-naphthylenepiperidinophosphite)]

B: 13954-38-6
tripiperidino-phosphine

Conditions

Conditions	Yield
	A 39% B n/a

: C30H46N4O2P2

A: cyclo[bis(2,6-naphthylenepiperidylamidophosphite)]

B: 13954-38-6
tripiperidino-phosphine

Conditions

Conditions	Yield
	A 28% B n/a

: 110-89-4
piperidine

: 61123-73-7
bis(piperidinyl)chlorophosphine

: 13954-38-6
tripiperidino-phosphine

Conditions

Conditions	Yield
With triethylamine

: 110-89-4
piperidine

: 60-29-7
diethyl ether

: 7719-12-2, 52843-90-0
phosphorus trichloride

: 13954-38-6
tripiperidino-phosphine

...Expand

: 24979-62-2
C16H25N2OP

A: 38945-81-2
1-Diphenoxyphosphinyl-piperidin

B: 13954-38-6
tripiperidino-phosphine

Conditions

Conditions	Yield
In 1,4-dioxane at 20℃; for 936h; Title compound not separated from byproducts;
In 1,4-dioxane at 20℃; for 480h; Title compound not separated from byproducts.;

: C16H24ClN2OP

A: 13954-38-6
tripiperidino-phosphine

B: C17H18Cl2NO2P

Conditions

Conditions	Yield
at 20℃; Title compound not separated from byproducts;

: C20H27N2OP

A: 13954-38-6
tripiperidino-phosphine

B: C25H24NO2P

Conditions

Conditions	Yield
at 20℃; Title compound not separated from byproducts;

: C26H44N4O2P2

A: 13954-38-6
tripiperidino-phosphine

B: 502922-91-0
C22H28N2O4P2

Conditions

Conditions	Yield
In acetonitrile at 20℃; for 1464h; Title compound not separated from byproducts.;

: C26H44N4O2P2

A: 863650-16-2
C22H28N2O4P2

B: 13954-38-6
tripiperidino-phosphine

Conditions

Conditions	Yield
In acetonitrile at 20℃; for 2304h; Title compound not separated from byproducts.;

: C32H48N4O2P2

A: 863650-17-3
C34H36N2O4P2

B: 13954-38-6
tripiperidino-phosphine

Conditions

Conditions	Yield
In acetonitrile at 20℃; for 960h; Title compound not separated from byproducts.;

: 110-89-4
piperidine

chromium hexacarbonyl: chromium hexacarbonyl

: 13954-38-6
tripiperidino-phosphine

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: 52 percent / hexane / 0 - 20 °C 2: dioxane / 936 h / 20 °C View Scheme
Multi-step reaction with 2 steps 1: 81 percent / hexane / 0 - 20 °C 2: 20 °C View Scheme
Multi-step reaction with 2 steps 1: 85 percent / hexane / 0 - 20 °C 2: 20 °C View Scheme

: 12107-56-1
dichloro(1,5-cyclooctadiene)palladium(II)

: 13954-38-6
tripiperidino-phosphine

: 68494-72-4, 955117-31-4
dichloro{bis[1,1’,1’’-(phosphinetriyl)tripiperidine]}palladium(II)

Conditions

Conditions	Yield
In toluene at 20℃; for 0.166667h;	100%

: 12107-56-1
dichloro(1,5-cyclooctadiene)palladium(II)

: 13954-38-6
tripiperidino-phosphine

: 955117-31-4, 68494-72-4
dicloro(bis(1,1',1''-(phosphinetriyl)tripiperidine))palladium

Conditions

Conditions	Yield
In toluene two equivalents of phosphine-compd. added to Pd-compd. in toluene under N2 at room temp.;	99%

: 13954-38-6
tripiperidino-phosphine

: 13686-33-4
t-butyl azide

: tris(1-piperidinyl)(tert-butyl)phosphazide

Conditions

Conditions	Yield
at 0 - 20℃;	91%

: 13954-38-6
tripiperidino-phosphine

: 118600-22-9
tetraphenylethylresorcin[4]arene

: 2,8,14,20-tetrakis(2-phenylethyl)-5,9,13,17-tetra(piperidin-1-yl)-2,20:3,19-dimetheno-1H,21H,23H,25H-bis[1,3,2]dioxaphosphocino[5,4-i:5'.4'-i']benzo[1.2-d:5.4-d']benzobis[1,3,2]dioxaphosphocine

Conditions

Conditions	Yield
In 1,4-dioxane at 20℃; for 168h;	87%

: dichloro(1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylylidene)(benzylidene)bis(pyridine)ruthenium(II)

: 13954-38-6
tripiperidino-phosphine

: C43H62Cl2N5PRu

Conditions

Conditions	Yield
In tetrahydrofuran at 20℃; for 0.333333h;	78%

: 13954-38-6
tripiperidino-phosphine

: 22187-34-4
1,8-diazidonaphthalene

: 1,8-bis[tris(piperidino)phosphazidyl]naphthalene

Conditions

Conditions	Yield
In tetrahydrofuran at 20℃; for 2h; Staudinger Azide Reduction; Inert atmosphere; Schlenk technique;	77%

: 13954-38-6
tripiperidino-phosphine

: 4648-54-8
trimethylsilylazide

: N-trimethylsilyl[tris(piperidino)]phosphazene

Conditions

Conditions	Yield
In toluene for 2h; Staudinger Azide Reduction; Reflux; Inert atmosphere; Schlenk technique;	77%

: 13954-38-6
tripiperidino-phosphine

: 132-86-5
1,3-dihydroxynaphthalene

: 914468-02-3
2,6-dipiperidino-1,3,5,7-tetraoxa-2,6-diphospha-4,8(1,3)-dinaphthalenacyclooctaphane

Conditions

Conditions	Yield
In acetonitrile; benzene at 20℃;	70%

: 13954-38-6
tripiperidino-phosphine

: tripiperidylphosphonium tetrafluoroborate

Conditions

Conditions	Yield
With tetrafluoroboric acid In diethyl ether	68%
With tetrafluoroboric acid In diethyl ether

: 13954-38-6
tripiperidino-phosphine

: 2032-35-1
Bromoacetaldehyde diethyl acetal

: (2,2-diethoxyethyl)trispiperidinophosphonium bromide

Conditions

Conditions	Yield
at 80℃; for 4h; Inert atmosphere;	63.5%
Heating;

: 13954-38-6
tripiperidino-phosphine

: 916134-80-0
C-1-naphthylresorcin[4]arene

: C148H200N16O8P8

Conditions

Conditions	Yield
In 1,4-dioxane at 80 - 85℃; for 18h; Inert atmosphere; regioselective reaction;	61%

: 13954-38-6
tripiperidino-phosphine

: 1069117-64-1
C64H64O8

: 5,11,17,23-tetramethyl-2,8,14,20-tetrakis(2-phenylethyl)-5,9,13,17-tetra(piperidin-1-yl)-2,20:3,19-dimetheno-1H,21H,23H,25H-bis[1,3,2]dioxaphosphocino[5,4-i:5'.4'-i']benzo[1.2-d:5.4-d']benzobis[1,3,2]dioxaphosphocine

Conditions

Conditions	Yield
In 1,4-dioxane at 20℃; for 168h;	60%

: 13954-38-6
tripiperidino-phosphine

: 74-85-1
ethene

: 3264-82-2
nickel(II) acetylacetonate

: 12150-27-5
C2H4Ni(P(NC5H10)3)2

Conditions

Conditions	Yield
With (C2H5)2AlOC2H5 In not given prepn. at room temp.;;	60%
With (C2H5)2AlOC2H5 In not given prepn. at room temp.;;	60%

...Expand

: 13954-38-6
tripiperidino-phosphine

: 226943-17-5
Ru(CO)(toluene)((9,9-dimethylxanthene-4,5-diyl)bis(dimethylsilyl))

: Ru{κ3(Si,O,Si)-xantsil}(CO){P(NC5H10)3}

Conditions

Conditions	Yield
In tetrahydrofuran at 20℃; for 2h;	60%

: 13954-38-6
tripiperidino-phosphine

: 74708-10-4
C-methylcalix[4]resorcinarene

: 1,21,23,25-tetramethyl-5,9,13,17-tetrakis(piperidylamido)-2,20:3,19-dimetheno-1H,21H,23H,25H-bis[1,3,2-λ3]dioxaphosphocino[5,4-i:5',4'-i']benzo[1,2-d:4,5-d']bis[1,3,2-λ3]benzodioxaphosphocine

Conditions

Conditions	Yield
In 1,4-dioxane at 20℃; for 168h;	52%

: 13954-38-6
tripiperidino-phosphine

: C60H120K4N16P4

Conditions

Conditions	Yield
Stage #1: tripiperidino-phosphine With trimethylsilylazide In toluene for 12h; Glovebox; Reflux; Schlenk technique; Inert atmosphere; Stage #2: With sulfuric acid In methanol for 24h; Inert atmosphere; Stage #3: With benzyl potassium In toluene for 3h; Inert atmosphere;	52%
Stage #1: tripiperidino-phosphine With trimethylsilylazide In toluene for 12h; Inert atmosphere; Reflux; Schlenk technique; Stage #2: With sulfuric acid In methanol for 24h; Inert atmosphere; Schlenk technique; Stage #3: With benzyl potassium In toluene for 3h; Glovebox; Inert atmosphere;	52%

: 13954-38-6
tripiperidino-phosphine

: C72H56O8

: C112H132N8O8P4

Conditions

Conditions	Yield
In 1,4-dioxane at 80 - 85℃; for 1h; Inert atmosphere; regioselective reaction;	51%

: 13954-38-6
tripiperidino-phosphine

: 132-86-5
1,3-dihydroxynaphthalene

: cyclo[bis(1,3-naphthylenepiperidylamidophosphite)]

Conditions

Conditions	Yield
In acetonitrile at 20℃;	41%

: 13954-38-6
tripiperidino-phosphine

: 575-44-0
1,6-dihydroxynaphthalene

: cyclo[bis(1,6-naphthylenepiperidinophosphite)]

Conditions

Conditions	Yield
In acetonitrile at 20℃; for 24h;	41%

: 13954-38-6
tripiperidino-phosphine

: 575-38-2
1,7-Dihydroxynaphthalene

A: C30H32N2O4P2

B: C30H32N2O4P2

Conditions

Conditions	Yield
Stage #1: tripiperidino-phosphine In acetonitrile at 20℃; for 4h; Stage #2: 1,7-Dihydroxynaphthalene In acetonitrile at 20℃; for 4h;	A 39% B n/a
In acetonitrile at 20℃; for 4h;	A 39% B n/a

...Expand

: 13954-38-6
tripiperidino-phosphine

: 575-44-0
1,6-dihydroxynaphthalene

: cyclo[bis(1,6-naphthylenepiperidylamidophosphite)]

Conditions

Conditions	Yield
In acetonitrile at 20℃;	39%

: 13954-38-6
tripiperidino-phosphine

: 575-44-0
1,6-dihydroxynaphthalene

: 1609488-32-5
1,6-bis(dipiperidinothiophosphoryloxy)naphthalene

Conditions

Conditions	Yield
Stage #1: tripiperidino-phosphine; 1,6-dihydroxynaphthalene In acetonitrile at 20℃; for 0.666667h; Stage #2: With sulfur In acetonitrile for 4h;	39%

: 13954-38-6
tripiperidino-phosphine

: 575-38-2
1,7-Dihydroxynaphthalene

A: C30H32N2O4P2S2

B: C30H32N2O4P2S2

Conditions

Conditions	Yield
Stage #1: tripiperidino-phosphine; 1,7-Dihydroxynaphthalene In acetonitrile at 20℃; for 4h; Stage #2: With sulfur In dichloromethane at 20℃; for 2.5h;	A 32% B 28%
Stage #1: tripiperidino-phosphine In acetonitrile at 20℃; for 4h; Stage #2: 1,7-Dihydroxynaphthalene In acetonitrile at 20℃; for 4h; Stage #3: With sulfur In dichloromethane at 20℃; for 2.5h;

...Expand

: 13954-38-6
tripiperidino-phosphine

: 589-29-7
p-xylylene glycol

: 1,4-bis(dipiperidin-1-ylthiophosphoryloxy)xylene

Conditions

Conditions	Yield
Stage #1: tripiperidino-phosphine; p-xylylene glycol In 1,4-dioxane at 20℃; for 48h; Stage #2: With sulfur In 1,4-dioxane at 20℃; for 72h; Further stages.;	32%

: 581-43-1
2,6-Dihydroxynaphthalene

: 13954-38-6
tripiperidino-phosphine

: cyclo[bis(2,6-naphthylenepiperidylamidophosphite)]

Conditions

Conditions	Yield
In acetonitrile at 20℃;	28%

Tripiperidinophosphine Specification

The CAS register number of Tripiperidinophosphine is 13954-38-6. It also can be called as Tri(piperidin-1-yl)phosphane and the systematic name about this chemical is 1,1',1''-phosphanetriyltripiperidine. The molecular formula about this chemical is C₁₅H₃₀N₃P and molecular weight is 283.39.

Physical properties about Tripiperidinophosphine are: (1)ACD/LogP: 2.47; (2)ACD/LogD (pH 5.5): -0.63; (3)ACD/LogD (pH 7.4): -0.62; (4)ACD/BCF (pH 5.5): 1; (5)ACD/BCF (pH 7.4): 1; (6)ACD/KOC (pH 5.5): 1; (7)ACD/KOC (pH 7.4): 1; (8)#H bond acceptors: 3; (9)#Freely Rotating Bonds: 3; (10)Polar Surface Area: 23.31Å²; (11)Flash Point: 177.7 °C; (12)Enthalpy of Vaporization: 61.71 kJ/mol; (13)Boiling Point: 370.2 °C at 760 mmHg; (14)Vapour Pressure: 1.12E-05 mmHg at 25°C.

You can still convert the following datas into molecular structure:
(1)SMILES: N3(P(N1CCCCC1)N2CCCCC2)CCCCC3
(2)InChI: InChI=1/C15H30N3P/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H2
(3)InChIKey: GEQBPMNDDHGGPJ-UHFFFAOYAX
(4)Std. InChI: InChI=1S/C15H30N3P/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H2
(5)Std. InChIKey: GEQBPMNDDHGGPJ-UHFFFAOYSA-N]

The toxicity data is as follows:

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
mouse	LD50	intravenous	180mg/kg (180mg/kg)		U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#02472,

Product Name

Tripiperidinophosphine

Synthetic route

Tripiperidinophosphine Specification

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