Triruthenium dodecacarbonyl supplier

: 16406-48-7
ruthenium pentacarbonyl

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

Conditions

Conditions	Yield
In further solvent(s) byproducts: CO; exposure to an N2-atmosphere, hydrocarbon soln.;;	100%
In pentane storing of soln. for 1 day under Ar at room temp.;
In neat (no solvent) decompn. of (Ru(CO)5) at room temp.;;

: Ru2[μ-η(2)-OC(CF3)O]2(CO)6

: 201230-82-2
carbon monoxide

: 21907-50-6
cesium trifluoroacetate

A: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 184584-51-8
fac-Cs[Ru(CF3COO)3(CO)3]

Conditions

Conditions	Yield
In tetrahydrofuran CO-atmosphere; stirring Ru-complex soln. (30°C, 8 h); sepn. of Ru3(CO)12, evapn.;	A 95% B 99%

...Expand

: Ru3{μ-H,μ-O=C(NMe2)}(CO)10

: 74-85-1
ethene

A: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

B: Ru2(OCC2H5)(OCN(CH3)2)(CO)6

Conditions

Conditions	Yield
With CO In hexane under N2; Ru compd. is dissolved in hexane, transferred to a Hoke cylinder, charged with CO (1 atm) and ethylene (3 atm), allowed to sit at room temp. for 20 h; gases are vented, IR, mixt. is reduced in volume, cooled to -20°C: crystn. of Ru3(CO)12, soln. is filtered after 12 h, reduced in volume to half, IR, soln. is cooled to -20°C, supernatant liq. is similar worked up; elem. anal.;	A n/a B 98%

Yield

With CO In hexane under N2; Ru compd. is dissolved in hexane, transferred to a Hoke cylinder, charged with CO (1 atm) and ethylene (3 atm), allowed to sit at room temp. for 20 h; gases are vented, IR, mixt. is reduced in volume, cooled to -20°C: crystn. of Ru3(CO)12, soln. is filtered after 12 h, reduced in volume to half, IR, soln. is cooled to -20°C, supernatant liq. is similar worked up; elem. anal.;

A n/a
B 98%

...Expand

: K(1+)*RuCl2(CO)2(CO2H)(1-) = K[RuCl2(CO)2(CO2H)]

: 201230-82-2
carbon monoxide

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

Conditions

Conditions	Yield
In 2-methoxy-ethanol byproducts: CO2, KCl; heating the Ru complex and CO in 2-methoxyethanol to 85°C for 20 min; filtration, washing (EtOH);	97%

: diruthenium(II,III) tetraacetatechloride

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

Conditions

Conditions	Yield
With carbon monoxide In methanol; dichloromethane; water High Pressure; dissolving Ru2(CH3COO)4Cl in CH3OH-CH2Cl2-H2O (10:10:1), charging into pressure vessel, pressurizing to 1000 psi with CO, stirring at this pressure for 4 h; venting CO atmosphere, partially removing solvent by vac. distn., pptn.filtration;	96%

: H(μ-H)Ru3(CO)11

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

Conditions

Conditions	Yield
With carbon monoxide In methanol CO atmosphere (room temp., 10 min, stirring), pptn.; redn. of vol. (vac.), filtration off, washing (MeOH): 87.7%; evapn. of filtrate to dryness, chromy. (silica, hexane): 7.9%;	95.7%

: 52621-15-5
[Ru(CO)4(η2-ethylene)]

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

Conditions

Conditions	Yield
In n-heptane N2-atmosphere; refluxing for 2 h; solvent removal (vac.), TLC (CH2Cl2/hexane=1:1);	95%

: tricarbonyldichlororuthenium (II) dimer

: 201230-82-2
carbon monoxide

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

Conditions

Conditions	Yield
With sodium carbonate In ethylene glycol molar ratio Ru:Na2CO3=1:1; bubbling CO for 5 h at 95°C; extn. of ppt. and sublimate with CH2Cl2 (room temp.), evapn., washing (water);	93%

: 74-85-1
ethene

: Ru3(H)(OCC6H5)(CO)10

A: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

B: Ru2(OCC2H5)(OCC6H5)(CO)6

Conditions

Conditions	Yield
With CO In hexane under N2; Ru compd. is dissolved in hexane, transferred to a Hoke cylinder, charged with CO (1 atm) and ethylene (3 atm), allowed to sit at room temp. for 20 h; gases are vented, IR, mixt. is reduced in volume, cooled to -20°C: crystn. of Ru3(CO)12, soln. is filtered after 12 h, reduced in volume to half, IR, soln. is cooled to -20°C, supernatant liq. is similar worked up; elem. anal.;	A n/a B 93%

Yield

With CO In hexane under N2; Ru compd. is dissolved in hexane, transferred to a Hoke cylinder, charged with CO (1 atm) and ethylene (3 atm), allowed to sit at room temp. for 20 h; gases are vented, IR, mixt. is reduced in volume, cooled to -20°C: crystn. of Ru3(CO)12, soln. is filtered after 12 h, reduced in volume to half, IR, soln. is cooled to -20°C, supernatant liq. is similar worked up; elem. anal.;

A n/a
B 93%

...Expand

: ruthenium trichloride

: 201230-82-2
carbon monoxide

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

Conditions

Conditions	Yield
With triethylamine In propan-1-ol; water at 85℃; under 2625.26 Torr; Concentration; Reagent/catalyst; Solvent; Temperature; Pressure; Autoclave;	92.5%
In methanol at 125℃; under 48754.9 Torr; for 8h; Autoclave;
With triethylamine In propan-1-ol at 85℃; under 2625.26 Torr; for 17h; Autoclave; Gas phase;

: Ru3(2-)*11CO*2N(P(C6H5)3)2(1+)=(N(P(C6H5)3)2)2(Ru3(CO)11)

: 27081-10-3
tropylium tetrafluoroborate

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

Conditions

Conditions	Yield
With carbon monoxide In not given dropwise addn. of CO and Ru-cluster soln. (CH2Cl2 or MeCN) to soln. of (C7H7)BF4 (N2 purge, room temp.); IR monitoring;	92%

: ruthenium trichloride hydrate

: 201230-82-2
carbon monoxide

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

Conditions

Conditions	Yield
With sodium carbonate In ethylene glycol bubbling of CO (1 atm) through a soln. of Ru salt in ethylene glycol for5 min, heating under CO at 110°C for 2 h, cooling to 25°C , addn. of Na2CO3 (Na2CO3:Ru mol. ratio 3:2), heating under CO at 80°C for 7 h; extn. of sublimate and reaction mixt. with dichloromethane at room temp., evapn. to dryness, washing the solid with water and then pentane;	91%
With potassium hydroxide In 2-ethoxy-ethanol under CO (1 atm), 1 h at 80°C, 45 min at 135°C, then addedKOH (2 equiv.) at 75°C under CO bubbling;	90%
With Fe or stainless steel or Fe-Cr-alloy In ethanol byproducts: RuO2, [RuCl2(CO)3]2; High Pressure; by a react. of Ru-contg. compd. in EtOH soln. at high CO pressure (50 bar) in autoclave in the presence of Fe plate or stainless steel (76% Fe, 17% Cr, 7% Ni) or Fe-Cr alloy (72.8% Fe, 22% Cr, 5% Al, 0.1% Y, 0.1 Zr);at 125°C; react. time: > 3 h; cooling in an ice bath; solid was filtered off and the resulting soln. was evapd. to dryness;	80%

: Ru3(H)(OCC2H5)(CO)10

: 74-85-1
ethene

A: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

B: {(μ-propionyl)2(carbonyl)6diruthenium}

Conditions

Conditions	Yield
With CO In hexane under N2; Ru compd. is dissolved in hexane, transferred to a Hoke cylinder, charged with CO (1 atm) and ethylene (3 atm), allowed to sit at room temp. for 20 h; gases are vented, IR, mixt. is reduced in volume, cooled to -20°C: crystn. of Ru3(CO)12, soln. is filtered after 12 h, reduced in volume to half, IR, soln. is cooled to -20°C, supernatant liq. is similar worked up; elem. anal.;	A 27% B 91%

Yield

With CO In hexane under N2; Ru compd. is dissolved in hexane, transferred to a Hoke cylinder, charged with CO (1 atm) and ethylene (3 atm), allowed to sit at room temp. for 20 h; gases are vented, IR, mixt. is reduced in volume, cooled to -20°C: crystn. of Ru3(CO)12, soln. is filtered after 12 h, reduced in volume to half, IR, soln. is cooled to -20°C, supernatant liq. is similar worked up; elem. anal.;

A 27%
B 91%

...Expand

: 80800-53-9
HRu3(CO)10(μ-η2-C(O)CH3)

: 74-85-1
ethene

A: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

B: Ru2(OCC2H5)(OCCH3)(CO)6

Conditions

Conditions	Yield
With CO In hexane under N2; Ru compd. is dissolved in hexane, transferred to a Hoke cylinder, charged with CO (1 atm) and ethylene (3 atm), allowed to sit at room temp. for 20 h; gases are vented, IR, mixt. is reduced in volume, cooled to -20°C: crystn. of Ru3(CO)12, soln. is filtered after 12 h, reduced in volume to half, IR, soln. is cooled to -20°C, supernatant liq. is similar worked up; elem. anal.;	A n/a B 91%

Yield

With CO In hexane under N2; Ru compd. is dissolved in hexane, transferred to a Hoke cylinder, charged with CO (1 atm) and ethylene (3 atm), allowed to sit at room temp. for 20 h; gases are vented, IR, mixt. is reduced in volume, cooled to -20°C: crystn. of Ru3(CO)12, soln. is filtered after 12 h, reduced in volume to half, IR, soln. is cooled to -20°C, supernatant liq. is similar worked up; elem. anal.;

A n/a
B 91%

...Expand

: 201230-82-2
carbon monoxide

: 10049-08-8
ruthenium(III)chloride

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

Conditions

Conditions	Yield
With caesium carbonate In methanol other Radiation; mixt. of RuCl3, Cs2CO3 and MeOH was sealed in microwave app.; CO (50 psi) was introduced; sealed; heated with stirring to 110°C using power of 300 W; held for 10 min; cooled to 50°C; evapd. (vac.); hexane added; heated; solvent removed;	90%
With Cu or Zn In ethanol other Radiation; γ irradiation of 1E-3 mol/l RuCl3 in ethanol under CO atmosphere at room temp. in presence of Cu or Zn powder;
With zinc In methanol heating RuCl3 with Zn at a CO pressure of 5-10 atm at 65 °C for 30 h;; extraction of thr solid residue of the filtration; pptn. on concentrating;;
With Zn In methanol heating RuCl3 with Zn at a CO pressure of 5-10 atm at 65 °C for 30 h;; extraction of thr solid residue of the filtration; pptn. on concentrating;;

: 52621-15-5
[Ru(CO)4(η2-ethylene)]

: 201230-82-2
carbon monoxide

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

Conditions

Conditions	Yield
In n-heptane CO-atmosphere; refluxing for 2 h; TLC (CH2Cl2/hexane=1:1); other unidentified products;	90%

: Ru3H(H)(CO)11

A: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

B: H4(ruthenium)4(carbonyl)12

C: dihydrotetraruthenium tridecacarbonyl

Conditions

Conditions	Yield
In dichloromethane-d2 thermal decompn. in soln. at room temp. within 15 min;	A 90% B n/a C n/a

...Expand

: Ru3H(1+)*10CO*SC6H5(1-)=HRu3(CO)10(SC6H5)

A: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

B: 105121-22-0
ruthenium3(carbonyl)9(μ3-carbonyl)(μ3-sulfido)

Conditions

Conditions	Yield
With CO In hexane refluxing (30 min, bubbling CO); crystn., solvent removal (vac.), dissoln. in CH2Cl2, thin layer chromy.(SiO2, hexane); elem. anal.;	A n/a B 89%

: 71562-47-5
H3Ru3(μ3-methoxymethylidyne)(carbonyl)9

A: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 16406-48-7
ruthenium pentacarbonyl

C: 115-10-6
Dimethyl ether

Conditions

Conditions	Yield
With carbon monoxide; hydrogen In toluene an autoclave containing a soln. of Ru3-cluster in toluene was pressurized to 500 psig with 1:1 CO-H2 and was heated at 130°C for 23 h; cooled, gases were vented through U-trap (liq. N2), condensate was shown to be Me2O and Ru(CO)5 by mass spectrometry, toluene soln. was filtered (ppt. - Ru3(CO)12 identified by IR data), filtrate evapd., residue chromd. on SiO2 to give addnl. Ru3(CO)12;	A 89% B <1 C n/a

Yield

With carbon monoxide; hydrogen In toluene an autoclave containing a soln. of Ru3-cluster in toluene was pressurized to 500 psig with 1:1 CO-H2 and was heated at 130°C for 23 h; cooled, gases were vented through U-trap (liq. N2), condensate was shown to be Me2O and Ru(CO)5 by mass spectrometry, toluene soln. was filtered (ppt. - Ru3(CO)12 identified by IR data), filtrate evapd., residue chromd. on SiO2 to give addnl. Ru3(CO)12;

A 89%
B <1
C n/a

...Expand

: 140111-19-9
Ru3(CO)10H(OCC6H4N(CH3)2)

A: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

B: 100-10-7
4-dimethylamino-benzaldehyde

Conditions

Conditions	Yield
With CO In benzene High Pressure; heating (3 bar CO, 90 min, 80°C); chromy. (hexane);	A 88% B 81%

: ruthenium(III) chloride trihydrate

: 201230-82-2
carbon monoxide

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

Conditions

Conditions	Yield
With KOH In methanol; 2-methoxy-ethanol byproducts: KCl; heating RuCl3*3H2O and CO in 2-methoxyethanol to 125°C for ca. 2 h, after cooling to 20°C addn. of methanolic KOH, heating to 85°C for 20 min; filtration;	86%
In methanol High Pressure; a soln. of RuCl3 in methanol was charged with 2.0 MPa CO and pressurizedto 5.0 MPa, the autoclave was placed in a thermostatic oil bath with st irring for 8 h at 125°C, cooled to room temp.; filtered, recrystd. from toluene;	54%

: 67-56-1
methanol

: 131145-73-8
bis(dimethylgermyl)methane ruthenium tetracarbonyl

A: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

B: 131245-48-2
bis(dimethylmethoxygermyl)methane

Conditions

Conditions	Yield
the Ru complex reacts with an excess of methanol (6 h 80°C); fractional distn.; elem. anal.;	A n/a B 85%

...Expand

: 128391-81-1
{HRu3(CO)9(μ3-η2:η2:η2-C6H6)}BF4

A: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

B: 128363-71-3
Ru3(CO)9(μ3:η(2):η(2):η(2)-C6H6)

Conditions

Conditions	Yield
With 1,8-diazabicyclo{5.4.0}undec-7-ene In dichloromethane (N2); added dropwise a soln. of N-compound to soln. of Ru-complex; filtered; evapd. (vac.); chromy.;	A n/a B 85%

: tricarbonyl-cyclo{dicarbonyl(cyclopentadienyl)molybdenum}-μ3-(ethylmethylidine)-μ3-hydrido(tricarbonylcobalt)ruthenium (Co-Mo, Co-Ru, Mo-Ru)

A: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

B: RuCoMo(CO)8Cp(μ3-C=CHMe)

Conditions

Conditions	Yield
In toluene byproducts: H2; stirred at 80°C for 1 h; solvent removed under vacuum, chromd. (silica gel, hexane), solvent removed under vacuum from the 2. fraction, crystd. at -30°C;	A n/a B 83%

: 131145-74-9
bis(dimethylgermyl)ethane ruthenium tetracarbonyl

: 586-96-9
Nitrosobenzene

A: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

B: 120926-63-8
(CH3)2GeCH2CH2Ge(CH3)2O

C: 1227476-15-4
Azobenzene

Conditions

Conditions	Yield
In benzene byproducts: CO; the Ru complex reacts in benzene with C6H5NO in a closed tube at 140°C (48 h);	A n/a B 82% C n/a

...Expand

: 98976-61-5
Ru4H3(CO)10C6H5PCH2P(C6H5)2

A: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

B: Ru3(μ-H)(CO)9(μ3-PPhCH2PPh2)

Conditions

Conditions	Yield
With CO In toluene CO was bubbled through a toluene soln. of complex heated under reflux for 3 h, the soln. was cooled; chromy. on silica gel, eluent heptane-toluene;	A 18.7% B 80.5%

: ruthenium(IV) oxide hydrate

: 201230-82-2
carbon monoxide

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

Conditions

Conditions	Yield
In toluene stainless steel autoclave; pressurizing with 20 atm CO, heating to 160°C for 2 h (stirring); cooling, collection (filtration), washing (cold PhMe);	80%
In further solvent(s) stainless steel autoclave, PhNH2 solvent; pressurizing with 5 atm CO, heating to 160°C for 2 h (stirring); cooling, collection (filtration), washing (cold PhMe);	70%

: [Ru3(acetonitrile)2(CO)10]

: 597-52-4
Triethylsilanol

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

Conditions

Conditions	Yield
In acetonitrile N2 atmosphere; stirring (24 h, room temp.);	80%
In neat (no solvent) N2 atmosphere; 70°C;

: 131145-73-8
bis(dimethylgermyl)methane ruthenium tetracarbonyl

: 624-65-7
2-propynyl chloride

A: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

B: 98187-50-9
bis(chlorodimethylgermyl)methane

Conditions

Conditions	Yield
In benzene HCCCH2Cl reacts with the tetracarbonyl ruthenium complex (80°C, 4 h, inert conditions); identification by spectroscopy;	A n/a B 80%

...Expand

: {Ru4(Se2)(CO)8(CO)3}

: 5112-95-8
bis(diphenylphosphino)acetylene

A: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

B: Ru3Se2(CO)7((C6H5)2PCCP(C6H5)2)

Conditions

Conditions	Yield
In dichloromethane react. under dry N2 using Schlenk and vac.-line techniques; addn. of 1.0 equiv. of the acetylene to Ru-complex in CH2Cl2 with stirring (orange soln.), react. for 1 h at room temp.; TLC (Kiesegel, eluent CH2Cl2-hexane 2:3), orange band, slow evapn. of a CH2Cl2-hexane soln.; elem. anal.;	A 20% B 80%

...Expand

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 201230-82-2
carbon monoxide

: 16406-48-7
ruthenium pentacarbonyl

Conditions

Conditions	Yield
In hexane Irradiation (UV/VIS); photolysis (>376nm, filtered 250 W high pressure mercury arc) in n-hexane (ca. 6ml of a 1E-4M soln.) under ca. 600Torr CO for 3h;; monitoring of react. by IR;;	100%
In tetrahydrofuran High Pressure; 80 bar CO, autoclave; 150°C (5 h);	73%
In hexane for 3h; Inert atmosphere; Schlenk technique; UV-irradiation;

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 118734-49-9
4,5-diethyl-2,5-dihydro-3-isopropenyl-2,2-dimethyl-1,2,5-selenasilaborole

A: 118772-38-6
tricarbonyl(η4-4,5-diethyl-2,5-dihydro-3-isopropenyl-2,2-dimethyl-1,2,5-selenasilaborole)ruthenium

B: 201230-82-2
carbon monoxide

Conditions

Conditions	Yield
In 1,3,5-trimethyl-benzene Ar atmosphere, heating (140°C, 4 h); filtn., solvent removal (0.001 Torr), sublimation (75-80°C, 0.001 Torr); elem. anal.;	A 82% B 100%

...Expand

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 63995-70-0
trisodium tris(3-sulfophenyl)phosphine

: 3Na(1+)*Ru3(CO)11(P(C6H4SO3)3)(3-)=Ru3(CO)11(P(C6H4SO3Na)3)

Conditions

Conditions	Yield
In methanol N2-atmosphere, molar ratio = 1 : 1; refluxing (2 h); evapn. (reduced pressure), washing (hexane), drying (vac.);	100%

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 63995-70-0
trisodium tris(3-sulfophenyl)phosphine

: 6Na(1+)*Ru3(CO)10(P(C6H4SO3)3)2(6-)=Ru3(CO)10(P(C6H4SO3Na)3)2

Conditions

Conditions	Yield
In methanol N2-atmosphere, molar ratio = 1 : 2; refluxing (2 h); evapn. (reduced pressure), washing (hexane), drying (vac.);	100%

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 63995-70-0
trisodium tris(3-sulfophenyl)phosphine

: 9Na(1+)*Ru3(CO)9(P(C6H4SO3)3)3(9-)=Ru3(CO)9(P(C6H4SO3Na)3)3

Conditions

Conditions	Yield
In methanol N2-atmosphere, molar ratio = 1 : 3; refluxing (2 h); evapn. (reduced pressure), washing (hexane), drying (vac.);	100%

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 14243-64-2
(triphenylphosphine)gold(I) chloride

: 75-05-8
acetonitrile

: Ru3(μ-AuPPh3)(μ-Cl)(CO)10

Conditions

Conditions	Yield
With (CH3)3NO In dichloromethane; acetonitrile (N2), soln. of Me3NO in CH3CN added dropwise to soln. of Ru complex in CH2Cl2 at -78°C over 15 min, slowly warmed to room temp., reacted for 15 min, treated with Au complex, stirred at room temp. for 1.5 h; evapd.(vac.), elem. anal.;	100%

...Expand

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 110452-48-7
5,10,15,20-tetrakis(p-tert-butylphenyl)porphyrin

: 75-05-8
acetonitrile

: [acetonitrile][carbonyl][5,10,15,20-tetrakis(4-tertbutylphenyl)porphyrinato]ruthenium(II)

Conditions

Conditions	Yield
Stage #1: dodecacarbonyl-triangulo-triruthenium; 5,10,15,20-tetrakis(p-tert-butylphenyl)porphyrin In 1,2-dichloro-benzene at 160℃; for 12h; Inert atmosphere; Stage #2: acetonitrile In 1,2-dichloro-benzene at 80℃; for 12h; Inert atmosphere;	100%

...Expand

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 141-82-2
malonic acid

: 2Ru(1+)*4CO*OOCCH2COO(2-)=[Ru2(CO)4(OOCCH2COO)]

Conditions

Conditions	Yield
In 1,4-dioxane; benzene byproducts: CO; Ru3(CO)12 and malonic acid were refluxed in benzene/dioxane under a slow flow of N2 for 24 h;; the solid was filtered off from the hot suspension, washed with dioxaneand diethyl ether, and dried under vac.; elem. anal.;;	99.4%

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 16406-48-7
ruthenium pentacarbonyl

Conditions

Conditions	Yield
With CO In n-heptane 133 atm CO, 100°C, 24 h;	99%
With carbon monoxide In diethylene glycol Irradiation (UV/VIS); 25°C, 1 atm of CO; UV monitoring; not isolated, detected by IR;
With carbon monoxide In octane Irradiation (UV/VIS); 25°C, 1 atm of CO; UV monitoring; not isolated, detected by IR;

: 110-86-1
pyridine

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 76-05-1
trifluoroacetic acid

: 166821-97-2, 167073-80-5
RuH(CF3CO2)(CO)2(C5H5N)2

Conditions

Conditions	Yield
In pyridine byproducts: CO; 95°C, 10 min; evapn. (reduced pressure), dissoln. in EtOH, Et2O addn., crystn. (0°C); isomer mixt. not sepd.;	99%

...Expand

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 58201-22-2
[1,2-bis(diphenylphosphino)ethane]tricarbonylruthenium

Conditions

Conditions	Yield
With carbon monoxide; 1,2-bis-(diphenylphosphino)ethane In benzene equimolar amts., 100 atm CO, 100°C, 4-5 h; crystn. (< 0°C, 4-5 h), washing (C6H6, light petroleum), drying (vac.); elem. anal.;	99%

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 75-05-8
acetonitrile

: 103257-53-0
Ru3(CO)10(acetonitrile)2

Conditions

Conditions	Yield
With trimethylamine-N-oxide In dichloromethane; acetonitrile Ar-atmosphere; dropwise addn. of slight excess Me3NO to Ru-complex soln.(in CH2Cl2/MeCN=10:1) at -78°C, warming to room temp.; evapn. (reduced pressure); elem. anal.;	99%
With trimethylamine-N-oxide In dichloromethane soln. of Me3NO added to a soln. of Ru-compd. and CH3CN at 0°C about 15 min, stirred for 1 h; filtered about silica gel, evapd.;
In dichloromethane filtration (degassed SiO2), the soln. kept at -10°C;
With (CH3)3NO In dichloromethane

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 7440-23-5
sodium

: sodium tetracarbonylruthenate(II)

Conditions

Conditions	Yield
In N,N,N,N,N,N-hexamethylphosphoric triamide (Ar); react. metal carbonyl with Na in HMPA for 1 h at 20°C;	99%
In ammonia NH3 (liquid); NH3 distilled onto Na/Ru mixture (acetone/dry ice bath) under vac., slowly warmed to 235 K, vigorously stirred for ca. 60 min, warmed to 260 K; dried (vac., 260 K, 3.5 h);

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 16873-17-9
deuterium

: β-{Ru4D4(CO)12}

Conditions

Conditions	Yield
In octane byproducts: CO; High Pressure; n-octane added to Ru complex, degassed (vac.), heated at 120°C (bath) under 5 atm (2)H2 for 9 h with intermediate blowings with N2; allowed to cool to room temp. overnight, filtered, dried (vac.);	99%
In not given according to Knox et al., J. Am. Chem. Soc., 97 (1975) 3942; Bruce et al., Inorg. Synth., 26 (1989) 262;

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 110-15-6
succinic acid

: [Ru2(CO)4(butan-1,4-dioato)](n)

Conditions

Conditions	Yield
In 1,4-dioxane; toluene byproducts: CO; Ru3(CO)12 and succinic acid were refluxed in toluene/dioxane under a slow flow of N2 for 24 h;; the solid was filtered off from the hot suspension, washed with acetoneand diethyl ether, and dried under vac.; elem. anal.;;	99%

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 75-05-8
acetonitrile

: Ru3(CO)9(acetonitrile)

Conditions

Conditions	Yield
With trimethylamine-N-oxide In dichloromethane; acetonitrile Ar-atmosphere; dropwise addn. of excess Me3NO to Ru-complex soln. (in CH2Cl2/MeCN=2:5) at -78°C, warming to room temp.; crystn. on slow removal of solvent (reduced pressure); elem. anal.;	99%

: 110-65-6
1,4-dihydroxybut-2-yne

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 21050-13-5
bis(triphenylphosphine)iminium chloride

: [PPN][Ru3(μ-Cl)(μ-HOCH2CCCH2OH)(CO)9]

Conditions

Conditions	Yield
In tetrahydrofuran Ru3(CO)12 and (PPN)Cl (molar ratio 1:1) dissolved in THF; stirred at room temp. for 3 h under N2 bubbling; monitored by IR spectra; ligand (1 equiv.) added; a few min; evapd.;	99%

...Expand

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 76858-94-1
1,2-bis(di(pentafluorophenyl)phosphino)ethane

: 225779-93-1, 225779-94-2
Ru3(CO)10(1,2-bis(bis-pentafluorophenylphosphino)ethane)

Conditions

Conditions	Yield
With catalyst:Ph2CO(1-) In tetrahydrofuran catalyst (8 drops) added to THF soln. of Ru compd. (0.078 mmol), ligand (0.086 mmol) added, stirred, catalyst (8-10 drops added), TLC conrol;	99%
With sodium diphenylketyl In tetrahydrofuran under argon, Schlenk setup, 1:2 mixt., heated at 40°C, 5 drops ofsodium diphenylketyl soln. added, stirred (IR control); evapd., dissolved (CH2Cl2), chromd. (silica, C6H12/CH2Cl2), recrystd. (CH2Cl2), elem. anal.;	77%

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 172987-61-0
Ph2PC*C-C*CBu(t)

: 163727-43-3
[Ru3(CO)11(P(C6H5)2CCCCC(CH3)3)]

Conditions

Conditions	Yield
With sodium benzophenone ketyl In tetrahydrofuran	99%

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 7608-31-3
Ph2PC*C-C*CPh

: 163727-44-4
[Ru3(CO)11(P(C6H5)2CCCCC6H5)]

Conditions

Conditions	Yield
With sodium benzophenone ketyl In tetrahydrofuran	99%

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 14857-34-2
dimethyl(ethoxy)silane

: [Ru2(CO)8(Si(CH3)2(OC2H5))2]

Conditions

Conditions	Yield
In hexane Irradiation (UV/VIS); (N2); irradiation (180 W mercury lamp, 25°C, 2 h); prepd. as soln. (spectr. yield);	99%
In hexane Irradiation (UV/VIS); (N2); reflux (1.5 h); concn., TLC (SiO2; CH2Cl2/hexane);	30%

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 1333-74-0
hydrogen

: H4(ruthenium)4(carbonyl)12

Conditions

Conditions	Yield
In octane byproducts: CO; High Pressure; n-octane added to Ru complex, degassed (vac.), heated at 120°C (bath) under 5 atm H2 for 9 h with intermediate blowings with N2; allowed to cool to room temp. overnight, filtered, dried (vac.);	99%

: 37083-37-7
5,10,15,20-tetrakis(2,6-dichlorophenyl)porphyrin

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 127390-19-6
[Ru(2,6-Cl2tpp)CO]

Conditions

Conditions	Yield
In 1,2,4-trichorobenzene Reflux; Inert atmosphere;	99%

: 37083-37-7
5,10,15,20-tetrakis(2,6-dichlorophenyl)porphyrin

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 127390-19-6
carbonyl ruthenium(II) 5,10,15,20-tetra(2,6-dichlorophenyl)porphyrin

Conditions

Conditions	Yield
In 1,2,4-Trichlorobenzene at 195 - 200℃; Inert atmosphere;	99%
With 1,2,4-Trichlorobenzene at 160 - 165℃; Inert atmosphere;

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 59863-12-6
bis[bis(trimethylsilyl)amino]germanium(II)

: 1310738-35-2
[Ru(Ge(HMDS)2)2(CO)3]

Conditions

Conditions	Yield
In toluene (N2) Ge(HMDS)2 was added to suspn. (Ru3(CO)12) in toluene and heated at 100°C for 1 h; solvent was removed in vacuo;	99%

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 1396690-42-8
2-(2-methylprop-1-en-1-yl)phenyl formate

: 4374-68-9
2-oxo-3-isopropyl-2,3-dihydrobenzofuran

Conditions

Conditions	Yield
With 1-(1-phenylethyl)-1H-imidazole In 1,3,5-trimethyl-benzene at 135℃; for 24h; Inert atmosphere; Sealed tube; regioselective reaction;	99%

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 1396690-44-0
2-(cyclopent-1-en-1-yl)phenyl formate

A: 1,3,3a,9b-tetrahydrocyclopenta[c]chromen-4(2H)-one

B: spiro-2-one

Conditions

Conditions	Yield
With 2,4,5-trimethyl-1-phenyl-1H-imidazole In 1,3,5-trimethyl-benzene at 135℃; for 24h; Inert atmosphere; Sealed tube; Overall yield = 75 %; regioselective reaction;	A n/a B 99%

...Expand

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 1620470-32-7
C29H48P2

: C31H48O2P2Ru

Conditions

Conditions	Yield
In tetrahydrofuran for 20h; Inert atmosphere; Reflux;	99%

Product Name

RUTHENIUM CARBONYL

Synthetic route

Triruthenium dodecacarbonyl Specification

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