Product Name

  • Name

    Vinylmagnesium bromide

  • EINECS 217-375-3
  • CAS No. 1826-67-1
  • Article Data16
  • CAS DataBase
  • Density 0.981 g/mL at 25 °C
  • Solubility vigorous reaction with water
  • Melting Point
  • Formula C2H3BrMg
  • Boiling Point
  • Molecular Weight 131.255
  • Flash Point -17 °C
  • Transport Information UN 3399 4.3/PG 2
  • Appearance Clear light brown to brown solution
  • Safety 16-26-29-33-36/37/39-45-6A-43B
  • Risk Codes 11-14-19-34-14/15
  • Molecular Structure Molecular Structure of 1826-67-1 (Vinylmagnesium bromide)
  • Hazard Symbols FlammableF, CorrosiveC
  • Synonyms Magnesium,bromovinyl- (7CI,8CI);Vinylmagnesium bromide (6CI);Bromovinylmagnesium;Ethenylmagnesium bromide;Norman reagent;
  • PSA 0.00000
  • LogP 1.52480

Synthetic route

Vinyl bromide
593-60-2

Vinyl bromide

vinyl magnesium bromide
1826-67-1

vinyl magnesium bromide

Conditions
ConditionsYield
With magnesium In tetrahydrofuran; diethyl ether at 0℃;
With iodine; magnesium In tetrahydrofuran for 0.5h; Ambient temperature;
With magnesium In tetrahydrofuran
Vinyl bromide
593-60-2

Vinyl bromide

Mg

Mg

vinyl magnesium bromide
1826-67-1

vinyl magnesium bromide

Conditions
ConditionsYield
In tetrahydrofuran
4-methyl-pent-3-en-2-one
141-79-7

4-methyl-pent-3-en-2-one

vinyl magnesium bromide
1826-67-1

vinyl magnesium bromide

3,5-dimethyl-hexa-1,4-dien-3-ol
38552-68-0

3,5-dimethyl-hexa-1,4-dien-3-ol

Conditions
ConditionsYield
In tetrahydrofuran100%
vinyl magnesium bromide
1826-67-1

vinyl magnesium bromide

4-methoxy-benzaldehyde
123-11-5

4-methoxy-benzaldehyde

1-(4-methoxylphenyl)-2-propen-1-ol
51410-44-7

1-(4-methoxylphenyl)-2-propen-1-ol

Conditions
ConditionsYield
In tetrahydrofuran; hexane at 0℃; for 2h; Inert atmosphere;100%
In tetrahydrofuran at 0℃; for 4h;96%
In tetrahydrofuran; diethyl ether at 0 - 20℃;95%
furfural
98-01-1

furfural

vinyl magnesium bromide
1826-67-1

vinyl magnesium bromide

1-(furan-2-yl)-2-propen-1-ol
119619-38-4

1-(furan-2-yl)-2-propen-1-ol

Conditions
ConditionsYield
In tetrahydrofuran at 0℃; for 1h; Inert atmosphere;100%
In tetrahydrofuran at 0 - 20℃; Inert atmosphere;98%
In tetrahydrofuran at 0 - 20℃; Inert atmosphere;92%
Benzyloxymethyl-oxiran
2930-05-4

Benzyloxymethyl-oxiran

vinyl magnesium bromide
1826-67-1

vinyl magnesium bromide

1-(benzyloxy)-4-penten-2-ol
58931-16-1

1-(benzyloxy)-4-penten-2-ol

Conditions
ConditionsYield
With copper(l) iodide In tetrahydrofuran at -20℃; for 0.333333h;100%
With copper(l) iodide In tetrahydrofuran at -78 - -40℃;95%
With copper(l) iodide In tetrahydrofuran93%
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

vinyl magnesium bromide
1826-67-1

vinyl magnesium bromide

(E)-3-Methoxy-2-(4-oxo-cyclopent-2-enyl)-acrylic acid methyl ester
121220-80-2

(E)-3-Methoxy-2-(4-oxo-cyclopent-2-enyl)-acrylic acid methyl ester

(E)-3-Methoxy-2-((1R,2S)-4-trimethylsilanyloxy-2-vinyl-cyclopent-3-enyl)-acrylic acid methyl ester
121220-81-3

(E)-3-Methoxy-2-((1R,2S)-4-trimethylsilanyloxy-2-vinyl-cyclopent-3-enyl)-acrylic acid methyl ester

Conditions
ConditionsYield
With N,N,N,N,N,N-hexamethylphosphoric triamide; dmap; chloro-trimethyl-silane; copper(l) iodide In tetrahydrofuran 1.) -75 deg C, 10 h; 2.) -75 deg C to -40 deg C;100%
With N,N,N,N,N,N-hexamethylphosphoric triamide; dmap; copper(l) iodide In tetrahydrofuran at -78℃;0.62 g
...Expand
heptanal
111-71-7

heptanal

vinyl magnesium bromide
1826-67-1

vinyl magnesium bromide

non-1-en-3-ol
21964-44-3

non-1-en-3-ol

Conditions
ConditionsYield
In tetrahydrofuran; diethyl ether at 0 - 20℃; Inert atmosphere;100%
85%
In tetrahydrofuran for 1h;82%
hept-6-enal
17206-61-0

hept-6-enal

vinyl magnesium bromide
1826-67-1

vinyl magnesium bromide

3-hydroxy-1,8-nonadiene
159010-02-3

3-hydroxy-1,8-nonadiene

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; Grignard reaction;100%
Stage #1: hept-6-enal; vinyl magnesium bromide In tetrahydrofuran; diethyl ether at -78 - 20℃;
Stage #2: With water; ammonium chloride In tetrahydrofuran; diethyl ether at 20℃;		90%
In tetrahydrofuran; diethyl ether for 3h; Ambient temperature; Yield given;
In tetrahydrofuran
para-iodoanisole
696-62-8

para-iodoanisole

vinyl magnesium bromide
1826-67-1

vinyl magnesium bromide

4-Methoxystyrene
637-69-4

4-Methoxystyrene

Conditions
ConditionsYield
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride In tetrahydrofuran for 0.0833333h;100%
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride In tetrahydrofuran for 5h; further catalysts;73%
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; zinc(II) chloride 1.) THF, RT, 20 min, 2.) RT, 1 h; Yield given. Multistep reaction;
(-)-Verbenone
80-57-9, 1196-01-6

(-)-Verbenone

vinyl magnesium bromide
1826-67-1

vinyl magnesium bromide

(1S,4R,5R)-4,6,6-trimethyl-4-vinylbicyclo[3.1.1]heptan-2-one
134655-24-6

(1S,4R,5R)-4,6,6-trimethyl-4-vinylbicyclo[3.1.1]heptan-2-one

Conditions
ConditionsYield
With copper(l) iodide In tetrahydrofuran at -78℃; for 3h;100%
With copper(l) iodide In tetrahydrofuran -50 deg C to room temp., 2 h;85%
With copper(l) iodide In tetrahydrofuran Yield given;
(E)-β-ionone
79-77-6

(E)-β-ionone

vinyl magnesium bromide
1826-67-1

vinyl magnesium bromide

(1E)-1-(2,6,6-trimethylcyclohex-1-enyl)-3-methyl-1,4-pentadien-3-ol
59057-30-6

(1E)-1-(2,6,6-trimethylcyclohex-1-enyl)-3-methyl-1,4-pentadien-3-ol

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 20h;100%
In tetrahydrofuran for 14h; Ambient temperature;94%
5-methoxy-2-nitro-benzaldehyde
20357-24-8

5-methoxy-2-nitro-benzaldehyde

vinyl magnesium bromide
1826-67-1

vinyl magnesium bromide

1-(5-Methoxy-2-nitro-phenyl)-prop-2-en-1-ol
162927-72-2

1-(5-Methoxy-2-nitro-phenyl)-prop-2-en-1-ol

Conditions
ConditionsYield
In tetrahydrofuran for 3.5h;100%
In tetrahydrofuran at -70℃;
In tetrahydrofuran at -70℃; for 3.5h;
In tetrahydrofuran at -10 - 20℃; Inert atmosphere;
2-amino-4'-methylbenzophenone
36192-63-9

2-amino-4'-methylbenzophenone

vinyl magnesium bromide
1826-67-1

vinyl magnesium bromide

1-(2'-aminophenyl)-1-(4''-methylphenyl)prop-2-en-1-ol
131470-28-5

1-(2'-aminophenyl)-1-(4''-methylphenyl)prop-2-en-1-ol

Conditions
ConditionsYield
In tetrahydrofuran at 60℃; for 2h;100%
benzyloxyacetoaldehyde
60656-87-3

benzyloxyacetoaldehyde

vinyl magnesium bromide
1826-67-1

vinyl magnesium bromide

1-(benzyloxy)but-3-en-2-ol
93553-66-3

1-(benzyloxy)but-3-en-2-ol

Conditions
ConditionsYield
In tetrahydrofuran for 0.5h; Heating;100%
In tetrahydrofuran at -78 - 20℃; Inert atmosphere;91%
In tetrahydrofuran at 0℃; for 0.166667h;88%
3-phenylpropionyltrimethylsilane
61157-31-1

3-phenylpropionyltrimethylsilane

vinyl magnesium bromide
1826-67-1

vinyl magnesium bromide

5-phenyl-3-(trimethylsilyl)-1-penten-3-ol
72551-26-9

5-phenyl-3-(trimethylsilyl)-1-penten-3-ol

Conditions
ConditionsYield
In tetrahydrofuran; diethyl ether at 0℃; for 0.5h;100%
Stage #1: vinyl magnesium bromide With cerium(III) chloride In tetrahydrofuran at -78℃; for 2h; Metallation;
Stage #2: 3-phenylpropionyltrimethylsilane In tetrahydrofuran at -78℃; for 2h; Addition;		98%
3-isobutoxy-2-methyl-2-cyclohexen-1-one
37457-15-1

3-isobutoxy-2-methyl-2-cyclohexen-1-one

vinyl magnesium bromide
1826-67-1

vinyl magnesium bromide

2-methyl-3-vinyl-cyclohex-2-enone
98954-18-8

2-methyl-3-vinyl-cyclohex-2-enone

Conditions
ConditionsYield
In tetrahydrofuran at 0℃; for 3h;100%
In tetrahydrofuran at -78 - 20℃;49%
4-(2',2'-Dimethyl-6'-methylidenecyclohexyl)butan-2-one
13720-12-2

4-(2',2'-Dimethyl-6'-methylidenecyclohexyl)butan-2-one

vinyl magnesium bromide
1826-67-1

vinyl magnesium bromide

5-(6',6'-dimethyl-2'-methylenecyclohexyl)-3-hydroxy-3-methyl-pent-1-ene
67656-40-0, 68538-72-7, 83920-95-0

5-(6',6'-dimethyl-2'-methylenecyclohexyl)-3-hydroxy-3-methyl-pent-1-ene

Conditions
ConditionsYield
100%
In tetrahydrofuran 1.) room temp. 2 h 2.) overnight 3.) 3 hr reflux;75%
In tetrahydrofuran for 3h; Heating;123 mg
In tetrahydrofuran
vinyl magnesium bromide
1826-67-1

vinyl magnesium bromide

5-(tert-butyldimethylsilyloxy)-2,3-isopropylidenedioxy-D-ribofuranose
217309-46-1

5-(tert-butyldimethylsilyloxy)-2,3-isopropylidenedioxy-D-ribofuranose

(4R,5S)-(+)-1-[4-[2-(tert-butyldimethylsilyloxy)-1-hydroxyethyl]-2,2-dimethyl-1,3-dioxolan-5-yl]-(S)-propen-1-ol
138127-55-6

(4R,5S)-(+)-1-[4-[2-(tert-butyldimethylsilyloxy)-1-hydroxyethyl]-2,2-dimethyl-1,3-dioxolan-5-yl]-(S)-propen-1-ol

Conditions
ConditionsYield
In tetrahydrofuran at -78 - 20℃; for 1h;100%
In tetrahydrofuran at -78 - 20℃; for 1h; Grignard reaction;96%
In tetrahydrofuran for 24h; Ambient temperature;79%
vinyl magnesium bromide
1826-67-1

vinyl magnesium bromide

9-Butoxy-bicyclo[3.2.2]non-6-en-2-one
83586-67-8, 83648-07-1

9-Butoxy-bicyclo[3.2.2]non-6-en-2-one

9-Butoxy-2-vinyl-bicyclo[3.2.2]non-6-en-2-ol
83586-71-4, 83648-11-7, 83648-12-8, 83648-13-9

9-Butoxy-2-vinyl-bicyclo[3.2.2]non-6-en-2-ol

Conditions
ConditionsYield
at 0℃;100%
vinyl magnesium bromide
1826-67-1

vinyl magnesium bromide

9-Butylsulfanyl-bicyclo[3.2.2]non-6-en-2-one
83586-68-9, 83648-08-2

9-Butylsulfanyl-bicyclo[3.2.2]non-6-en-2-one

9-Butylsulfanyl-2-vinyl-bicyclo[3.2.2]non-6-en-2-ol
83586-72-5, 83648-14-0, 83648-15-1, 83648-16-2

9-Butylsulfanyl-2-vinyl-bicyclo[3.2.2]non-6-en-2-ol

Conditions
ConditionsYield
at 0℃;100%
vinyl magnesium bromide
1826-67-1

vinyl magnesium bromide

9-Phenylsulfanyl-bicyclo[3.2.2]non-6-en-2-one
83586-69-0, 83648-09-3

9-Phenylsulfanyl-bicyclo[3.2.2]non-6-en-2-one

9-Phenylsulfanyl-2-vinyl-bicyclo[3.2.2]non-6-en-2-ol
83586-73-6, 83648-17-3, 83648-18-4, 83648-85-5

9-Phenylsulfanyl-2-vinyl-bicyclo[3.2.2]non-6-en-2-ol

Conditions
ConditionsYield
at 0℃;100%
vinyl magnesium bromide
1826-67-1

vinyl magnesium bromide

3β-t-butyldimethylsilyloxy-pregn-5-en-20-one
58701-45-4

3β-t-butyldimethylsilyloxy-pregn-5-en-20-one

(20R,S)-20-vinylpregn-5-ene-3β,20-diol 3β-tert-butyldimethylsilyl ether
99602-17-2, 99630-80-5

(20R,S)-20-vinylpregn-5-ene-3β,20-diol 3β-tert-butyldimethylsilyl ether

Conditions
ConditionsYield
100%
vinyl magnesium bromide
1826-67-1

vinyl magnesium bromide

syn-4-(tert-butyldimethylsilyloxy)cyclopentene oxide
91661-16-4

syn-4-(tert-butyldimethylsilyloxy)cyclopentene oxide

(1RS,2SR,4RS)-4-{[(1,1-dimethylethyl)(dimethyl)silyl]oxy}-2-ethenylcyclopentanol
91661-17-5

(1RS,2SR,4RS)-4-{[(1,1-dimethylethyl)(dimethyl)silyl]oxy}-2-ethenylcyclopentanol

Conditions
ConditionsYield
Stage #1: vinyl magnesium bromide; syn-4-(tert-butyldimethylsilyloxy)cyclopentene oxide; copper(l) iodide In tetrahydrofuran at -30 - 0℃; for 2.75h; Inert atmosphere;
Stage #2: With ammonium chloride In tetrahydrofuran		100%
copper(l) iodide In tetrahydrofuran -30 gradC for 15 min then 0 gradC for 2 h.;79%
vinyl magnesium bromide
1826-67-1

vinyl magnesium bromide

(3R,6S)-3,6-Dimethyl-1-oxo-3,6-dihydro-1H-1λ4-[1,2]thiazine-2-carboxylic acid benzyl ester
86120-35-6, 86161-73-1, 93379-68-1, 93379-69-2

(3R,6S)-3,6-Dimethyl-1-oxo-3,6-dihydro-1H-1λ4-[1,2]thiazine-2-carboxylic acid benzyl ester

C16H21NO3S
107972-85-0

C16H21NO3S

Conditions
ConditionsYield
In tetrahydrofuran at -60℃; for 0.5h;100%
vinyl magnesium bromide
1826-67-1

vinyl magnesium bromide

benzyl 5-formyl-8-methoxy-1,2,3,4-tetrahydronaphthalene-2-carboxylate
80371-01-3

benzyl 5-formyl-8-methoxy-1,2,3,4-tetrahydronaphthalene-2-carboxylate

5-(1-Hydroxy-allyl)-8-methoxy-1,2,3,4-tetrahydro-naphthalene-2-carboxylic acid benzyl ester
80371-12-6

5-(1-Hydroxy-allyl)-8-methoxy-1,2,3,4-tetrahydro-naphthalene-2-carboxylic acid benzyl ester

Conditions
ConditionsYield
In tetrahydrofuran 1.) 0 deg C, 1 h, 2.) RT, 1 h;100%
vinyl magnesium bromide
1826-67-1

vinyl magnesium bromide

4,8,12-trioxa-4,8,12,12c-tetrahydrodibenzopyrenylium tetrafluoroborate

4,8,12-trioxa-4,8,12,12c-tetrahydrodibenzopyrenylium tetrafluoroborate

12c-ethenyl-4,8,12-trioxatricornan
138259-52-6

12c-ethenyl-4,8,12-trioxatricornan

Conditions
ConditionsYield
In tetrahydrofuran at 0 - 20℃; Inert atmosphere;100%
In tetrahydrofuran for 7h;68%
vinyl magnesium bromide
1826-67-1

vinyl magnesium bromide

tert-Butyl-dimethyl-[2-(tetrahydro-pyran-2-yloxymethyl)-oxiranylmethoxy]-silane

tert-Butyl-dimethyl-[2-(tetrahydro-pyran-2-yloxymethyl)-oxiranylmethoxy]-silane

1-(tert-Butyl-dimethyl-silanyloxy)-2-(tetrahydro-pyran-2-yloxymethyl)-pent-4-en-2-ol

1-(tert-Butyl-dimethyl-silanyloxy)-2-(tetrahydro-pyran-2-yloxymethyl)-pent-4-en-2-ol

Conditions
ConditionsYield
With copper(l) iodide; dimethylsulfide In tetrahydrofuran at -15℃;100%
vinyl magnesium bromide
1826-67-1

vinyl magnesium bromide

cycloheptanone
502-42-1

cycloheptanone

1-vinylcycloheptanol
6244-47-9

1-vinylcycloheptanol

Conditions
ConditionsYield
In tetrahydrofuran at 0 - 23℃; for 18h; Inert atmosphere;100%
In tetrahydrofuran; diethyl ether at -5 - 20℃;86%
In tetrahydrofuran at -78℃; Grignard reaction;66%
vinyl magnesium bromide
1826-67-1

vinyl magnesium bromide

(3R)-3-hydroxy-β-ionone
50281-38-4

(3R)-3-hydroxy-β-ionone

(1-E)-1-<(4R)-4-hydroxy-2,6,6-trimethylcyclohex-1-enyl>-3-methyl-1,4-pentadien-3-ol

(1-E)-1-<(4R)-4-hydroxy-2,6,6-trimethylcyclohex-1-enyl>-3-methyl-1,4-pentadien-3-ol

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 20h;100%
In tetrahydrofuran; toluene at -20℃; for 1.5h; Inert atmosphere;
vinyl magnesium bromide
1826-67-1

vinyl magnesium bromide

(R)-benzyl glycidol
14618-80-5

(R)-benzyl glycidol

(R)-1-benzyloxypent-4-en-2-ol
58931-16-1, 88981-35-5, 110339-28-1

(R)-1-benzyloxypent-4-en-2-ol

Conditions
ConditionsYield
Stage #1: (R)-benzyl glycidol With copper(l) iodide In tetrahydrofuran at -78℃; for 0.0833333h;
Stage #2: vinyl magnesium bromide In tetrahydrofuran at 20 - 70℃; for 2h;		100%
Stage #1: (R)-benzyl glycidol With copper(l) iodide In tetrahydrofuran at 20℃; for 0.0833333h;
Stage #2: vinyl magnesium bromide In tetrahydrofuran at -78 - 20℃; for 2h;		100%
Stage #1: (R)-benzyl glycidol With copper(l) iodide In tetrahydrofuran at -78 - 20℃; for 0.0833333h;
Stage #2: vinyl magnesium bromide In tetrahydrofuran at -70 - 20℃; for 2h;		100%
vinyl magnesium bromide
1826-67-1

vinyl magnesium bromide

(1R,2R,6S)-6-Benzyloxy-2-(3-isopropenyl-4-methyl-pent-3-enyl)-2-methyl-cyclohexanecarbaldehyde

(1R,2R,6S)-6-Benzyloxy-2-(3-isopropenyl-4-methyl-pent-3-enyl)-2-methyl-cyclohexanecarbaldehyde

1-[(1S,2R,6S)-6-Benzyloxy-2-(3-isopropenyl-4-methyl-pent-3-enyl)-2-methyl-cyclohexyl]-prop-2-en-1-ol

1-[(1S,2R,6S)-6-Benzyloxy-2-(3-isopropenyl-4-methyl-pent-3-enyl)-2-methyl-cyclohexyl]-prop-2-en-1-ol

Conditions
ConditionsYield
In tetrahydrofuran at -78℃; for 1h;100%

Vinylmagnesium bromide Chemical Properties

IUPAC Name: Magnesium ethene bromide
Synonyms of Magnesium,bromoethenyl- (CAS NO.1826-67-1): Vinylmagnesium bromide ; Bromovinylmagnesium
Molecular Structure:
Molecular Formula: C2H3BrMg
Molecular Weight: 131.25
CAS NO: 1826-67-1
EINECS: 217-375-3
H bond acceptors: 0
H bond donors: 0
Freely Rotating Bonds: 1
Polar Surface Area: 0 Å2 
Density: 0.981 g/mL at 25 °C
Flash Point: 1 °F
Storage temp: Refrigerator
Solubility: vigorous reaction
Water Solubility: vigorous reaction 
Appearance: Clear light brown to brown solution
SMILES: Br[Mg]\C=C
InChI: InChI=1/C2H3.BrH.Mg/c1-2;;/h1H,2H2;1H;/q;;+1/p-1/rC2H3BrMg/c1-2-4-3/h2H,1H2
InChIKey: XHHHAXOHMKAOSL-ZAPIYNQUAR
Std. InChI: InChI=1S/C2H3.BrH.Mg/c1-2;;/h1H,2H2;1H;/q;;+1/p-1
Std. InChIKey: XHHHAXOHMKAOSL-UHFFFAOYSA-M
Product Categories of Magnesium,bromoethenyl- (CAS NO.1826-67-1): GRIGNARD REAGENTS;Classes of Metal Compounds;Grignard Reagents & Alkyl Metals;Mg (Magnesium) Compounds;Synthetic Organic Chemistry;Typical Metal Compounds;Alkenyl;Grignard Reagents;Organometallic Reagents

Vinylmagnesium bromide Safety Profile

Safety Information of Magnesium,bromoethenyl- (CAS NO.1826-67-1):
Hazard Codes: FlammableF,CorrosiveC
Risk Statements: 11-19-34-14/15
R11: Highly flammable. 
R14/15: Reacts violently with water, liberating extremely flammable gases 
R19: May form explosive peroxides. 
R34: Causes burns.
Safety Statements: 16-26-29-33-36/37/39-45-6-43
S16: Keep away from sources of ignition. 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S29: Do not empty into drains. 
S33: Take precautionary measures against static discharges. 
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection. 
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S6: Keep under ... (inert gas to be specified by the manufacturer) 
S43: In case of fire use ... (there follows the type of fire-fighting equipment to be used.)
RIDADR: UN3399 4.3/PG 2
WGK Germany: 1
F:1-3-10

Vinylmagnesium bromide Specification

General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Will burn if involved in a fire. Water Reactive. Material will react with water and may release a flammable and/or toxic gas. Flammable liquid and vapor. May form explosive peroxides.
Extinguishing Media: Use approved class D extinguishing agents or smother with dry sand, clay, or sodium bicarbonate. DO Handling: Do not allow water to get into the container because of violent reaction. Use spark-proof tools and explosion proof equipment. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Do not allow contact with water. Use only in a chemical fume hood.
Storage: Keep away from sources of ignition. Do not store in direct sunlight. Store in a tightly closed container. Store in a dry area. Flammables-area. Corrosives area. Water free area. Store under nitrogen. Store at room temperature.

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