Conditions | Yield |
---|---|
In solid byproducts: H2O; mixt. heating in derivatograph in Pt crucible at 10 K/min in air up to 850°C; TG, DTG, DTA; | A 15.6% B n/a |
In solid byproducts: H2O; mixt. heating in derivatograph in Pt crucible at 10 K/min in air up to 1000°C; TG, DTG, DTA; | A 0% B n/a |
Conditions | Yield |
---|---|
byproducts: (CH3)2O; on react. of ZnCO3 with dimethyl sulfate in vacuum, evaporating of formed dimethyl ether (method of Recoura);; compd. free of H2O is obtained;; |
Conditions | Yield |
---|---|
In water |
Conditions | Yield |
---|---|
In water suspension of ZnS in H2O; reaction is fast in acidic H2O or an ozon dissolving liquid (eg. rosin oil);; | |
In neat (no solvent) reaction with luminescence;; | |
In neat (no solvent) reaction with luminescence;; |
Conditions | Yield |
---|---|
In water slow oxidation with aq. K2S2O8;; | |
In water slow oxidation with aq. K2S2O8;; |
Conditions | Yield |
---|---|
With iron(II) sulfate In not given byproducts: Fe(OH)3; Zn production from industrial wastes; detailed description given;; ZnCl2 not isolated;; | |
With FeSO4 In not given byproducts: Fe(OH)3; Zn production from industrial wastes; detailed description given;; ZnCl2 not isolated;; | |
With iron(II) sulfate In not given byproducts: Fe(OH)3; Zn production from industrial wastes; detailed description given;; ZnCl2 not isolated;; |
zinc(II) sulfate
Conditions | Yield |
---|---|
With sulfur dioxide In neat (no solvent) in presence of O2, starting of react. at 350 °C;; | |
With sulfuric acid In sulfuric acid leaching the oxide roast with sulfuric acid; amt. of formed ZnSo4 is depending on temp. of H2SO4;; | |
With sulfuric acid In sulfuric acid leaching the oxide roast with sulfuric acid;; |
Conditions | Yield |
---|---|
With oxygen Kinetics; 920 - 1200 K, in a fixed bed reactor; |
Conditions | Yield |
---|---|
Zn powder; |
Conditions | Yield |
---|---|
In water vapors (5% SO2 and O2 in finely dispersed state) are reacting as catalysts with aq. suspension of ZnO in presence of metal salts;; | |
In water vapors (5% SO2 and O2 in finely dispersed state) are reacting as catalysts with aq. suspension of ZnO in presence of metal salts;; |
sulfur dioxide
chlorine
A
zinc(II) sulfate
B
zinc(II) chloride
Conditions | Yield |
---|---|
In neat (no solvent) Kinetics; begin of the react. at 415°C; | |
In neat (no solvent) heating (600, 700, 800, 900, 1000 or 1100°C); |
Conditions | Yield |
---|---|
300-900°C; | |
300-900°C; |
Conditions | Yield |
---|---|
below 600°C to 650°C in carbon gas flame; | |
Kinetics; 920 - 1200 K, in a fixed bed reactor; | |
below 600°C to 650°C in carbon gas flame; |
Conditions | Yield |
---|---|
byproducts: Ag, O2; Irradiation (UV/VIS); irradiated ZnO is reacting with Ag2SO4;; |
Conditions | Yield |
---|---|
In sulfuric acid by extraction from industrial wastes;; not isolated;; |
Conditions | Yield |
---|---|
In sulfuric acid velocity of dissolving of ZnO in H2SO4 is depending on concn. of acid and react. temp.;; | |
In sulfuric acid by extraction from industrial wastes; on dissolving of ZnO from residue with H2SO4;; | |
In sulfuric acid on addn. of calcd. amt. of H2SO4 (calcd. for ZnO);; | |
In sulfuric acid on addn. of calcd. amt. of H2SO4 (calcd. for ZnO);; |
sulfuryl dichloride
A
zinc(II) sulfate
B
zinc(II) chloride
Conditions | Yield |
---|---|
In neat (no solvent) sealed tube or passing SO2Cl2 over ZnO (room temp. or 200°C);; | |
In neat (no solvent) sealed tube or passing SO2Cl2 over ZnO (room temp. or 200°C);; |
Conditions | Yield |
---|---|
byproducts: (CH3)2O; on ract. of ZnO with dimethyl sulfate in vacuum, evaporating of formed dimethyl ether (method of Recoura);; compd. free of H2O is obtained;; |
Conditions | Yield |
---|---|
With sulfur dioxide 400-850°C; | |
With sulfur dioxide In further solvent(s) in a NaCl-ZnCl2-ZnCl2 melt only very slowly forming of ZnSO4 between 420 and 530°C;; | |
With SO2 In further solvent(s) in a NaCl-ZnCl2-ZnCl2 melt only very slowly forming of ZnSO4 between 420 and 530°C;; | |
With SO2 400-850°C; |
Conditions | Yield |
---|---|
In neat (no solvent) on mixing material, containing ZnO, with FeSO4*H2O and oxidizing heating at 720 - 750°C;; on leaching out with hot H2O and crytsg.;; |
Conditions | Yield |
---|---|
With oxygen In neat (no solvent) by roasting;; after roasting, top layer contains ZnSO4+ZnO, then, underlying, ZnSO4, secondary ZnO, grey ZnO (mixture ofZnO and Zn) and ZnS (educt);; | |
With O2 In neat (no solvent) by roasting;; after roasting, top layer contains ZnSO4+ZnO, then, underlying, ZnSO4, secondary ZnO, grey ZnO (mixture ofZnO and Zn) and ZnS (educt);; |
Conditions | Yield |
---|---|
With sulfur dioxide In neat (no solvent) byproducts: ZnO; react. of ZnS with SO2 at 700 to 1100°C, mechanism discussed;; formation of ZnO and S (low yield), no ZnSO4 obtained;; | A n/a B 0% |
With SO2 In neat (no solvent) byproducts: ZnO; react. of ZnS with SO2 at 700 to 1100°C, mechanism discussed;; formation of ZnO and S (low yield), no ZnSO4 obtained;; | A n/a B 0% |
zinc(II) sulfate
Conditions | Yield |
---|---|
With air In neat (no solvent) standing in moist air;; | |
With water In water byproducts: H2; Irradiation (UV/VIS); following react. given: (1): ZnS = Zn + S; (2): 4S + H2O = H2SO4 + 3H2S; (3) Zn + H2SO4 = ZnSO4 + H2;; formation of H2S as intermediate probably dedectable on pptg. with CdS;; | |
With water In water byproducts: H2; Irradiation (UV/VIS); following react. given: (1): ZnS = Zn + S; (2): 4S + H2O = H2SO4 + 3H2S; (3) Zn + H2SO4 = ZnSO4 + H2;; formation of H2S as intermediate probably dedectable on presence of Pb(2+) as PbS;; |
Conditions | Yield |
---|---|
With air In neat (no solvent) on heating of pure ZnS in air;; | A 0% B 0% |
With air In neat (no solvent) by heating of pure ZnS in air;; | A 0% B 0% |
With air In neat (no solvent) by heating of pure ZnS in air;; | A 0% B 0% |
With air In neat (no solvent) on heating of pure ZnS in air;; | A 0% B 0% |
Conditions | Yield |
---|---|
With sulfur dioxide In neat (no solvent) byproducts: ZnO; calcinating Zn sulfide in SO2, strong decompn. of sulfates formed to oxides;; formation of Zn sulfate, Zn oxide and sulfur;; | |
With SO2 In neat (no solvent) byproducts: ZnO; calcinating Zn sulfide in SO2, strong decompn. of sulfates formed to oxides;; formation of Zn sulfate, Zn oxide and sulfur;; |
Conditions | Yield |
---|---|
With oxygen Kinetics; 361-527°C; |
Conditions | Yield |
---|---|
In not given acidic Ag2SO4 soln.;; |
Conditions | Yield |
---|---|
In sulfuric acid feeding of H2S into a sulfuric soln. (10 % H2SO4) of ZnSO4 at 300 °C;; | 100% |
In sulfuric acid feeding of H2S into a sulfuric soln. (7.5 % H2SO4) of ZnSO4 at 300 °C;; | 90% |
In sulfuric acid feeding of H2S into a sulfuric soln. (10 % H2SO4) of ZnSO4 at 350 °C;; | 80% |
Conditions | Yield |
---|---|
In water aq. soln. of zinc sulphate added to aq. picrolonic acid at room temp., gently warmed; ppt. filtered, washed with water, ethanol, ether, dried in vac. till constant weight, elem. anal.; | 100% |
zinc(II) sulfate
Conditions | Yield |
---|---|
With lithium hydroxide monohydrate In tetrahydrofuran; water for 2h; | 100% |
Conditions | Yield |
---|---|
With lithium hydroxide monohydrate In tetrahydrofuran; water for 3h; | 100% |
2-Mercaptobenzothiazole
zinc(II) sulfate
2-mercaptobenzothiazole thiazole zinc
Conditions | Yield |
---|---|
In water Milling; Green chemistry; | 99.5% |
zinc(II) sulfate
Conditions | Yield |
---|---|
In not given addn. of freshly prepared metal sulphate solns. to ammonium oxalate (10% excess) under N2 at 60°C (double-inlet technique); pptn.; striiring for 2 h;; filtration; drying at 100°C; composition: Ni0.5Zn0.5Fe2(C2O4)3*6H2O;; | 98.5% |
Conditions | Yield |
---|---|
With ammonium hydroxide In methanol; water at 40℃; for 4h; pH=7; | 98.5% |
zinc(II) sulfate
Conditions | Yield |
---|---|
In acetone for 6h; Reflux; | 98.25% |
zinc(II) sulfate
1-ethyl-3-methylimidazol-3-ium ethyl sulfate
Conditions | Yield |
---|---|
at 140℃; for 48h; | 98% |
Conditions | Yield |
---|---|
With sodium sulfite In water at 55 - 100℃; for 5h; pH=6 - 7; Reagent/catalyst; Temperature; Large scale; | 97.5% |
Conditions | Yield |
---|---|
With DL-dithiothreitol In methanol at 60℃; for 1.5h; Reagent/catalyst; Solvent; Temperature; Sonication; | 97.3% |
zinc(II) sulfate
Conditions | Yield |
---|---|
With lithium hydroxide monohydrate In tetrahydrofuran; water for 2h; | 97% |
Conditions | Yield |
---|---|
In dichloromethane; water at 20℃; for 6h; | 97% |
Conditions | Yield |
---|---|
With sodium sulfate at 90℃; | 96.8% |
With nitric acid In water at 75℃; for 3.25h; pH=< 1; | 63.9% |
Conditions | Yield |
---|---|
With sodium sulfate at 150℃; | 96.4% |
With nitric acid In water at 75℃; for 2.41667h; pH=< 1; | 61.4% |
(4-chlorophenyl)(5-hydroxy-3-methyl-1-phenyl-1H-pyrazol-4-yl)methanone
Conditions | Yield |
---|---|
With ammonium hydroxide In methanol; water at 40℃; for 4h; pH=7; | 96.2% |
Conditions | Yield |
---|---|
With sodium sulfate at 90℃; | 96% |
With nitric acid In water at 75℃; for 1.41667h; pH=< 1; | 58.2% |
Conditions | Yield |
---|---|
In dichloromethane for 0.5h; Inert atmosphere; | 96% |
1-acetyl-2-octanoylhydrazine
zinc(II) sulfate
Conditions | Yield |
---|---|
With aq. NH3 In ethanol; water to aq. soln. of metal salt added aq. NH3 (pH 8-11); soln. of ligand in EtOH added (molar ratio metal:ligand = 1:1); after 5 min ppt. filtered; washed (EtOH); dried (air); | 95.5% |
zinc(II) sulfate
Conditions | Yield |
---|---|
With Ba(OH)2*8H2O or LiOH*H2O In water Ba or Li hydroxide (1 equiv.) and ester of ligand were reacted in water;Zn compd. (1 equiv.) was added at room temp.; recrystd. (hot water); elem. anal.; | 95% |
Conditions | Yield |
---|---|
In dichloromethane; water at 20℃; for 6h; | 95% |
zinc(II) sulfate
Conditions | Yield |
---|---|
In dichloromethane; water at 20℃; | 93% |
zinc(II) sulfate
Conditions | Yield |
---|---|
In water for 0.25h; Product distribution / selectivity; | 92% |
ethyl (3R),(5S),(6E)-7-[4-(4-fluorophenyl)-6-isopropyl-2-[methyl(methylsulfonyl)amino]pyrimidin-5-yl]-3,5-dihydroxy-6-heptenoate
zinc(II) sulfate
Conditions | Yield |
---|---|
With sodium hydroxide; ethanol; water at 25 - 70℃; for 1.5h; Product distribution / selectivity; | 92% |
Stage #1: ethyl (3R),(5S),(6E)-7-[4-(4-fluorophenyl)-6-isopropyl-2-[methyl(methylsulfonyl)amino]pyrimidin-5-yl]-3,5-dihydroxy-6-heptenoate With sodium hydroxide; ethanol; water at 60℃; for 0.833333h; Stage #2: With hydrogenchloride; water In ethanol at 10℃; for 0.166667h; Stage #3: zinc(II) sulfate In ethanol; water at 10℃; for 1.5h; Product distribution / selectivity; | 70% |
Stage #1: ethyl (3R),(5S),(6E)-7-[4-(4-fluorophenyl)-6-isopropyl-2-[methyl(methylsulfonyl)amino]pyrimidin-5-yl]-3,5-dihydroxy-6-heptenoate With sodium hydroxide; water In acetonitrile at 20℃; for 0.583333h; Stage #2: zinc(II) sulfate In water; acetonitrile at 10 - 20℃; Product distribution / selectivity; | 68% |
Stage #1: ethyl (3R),(5S),(6E)-7-[4-(4-fluorophenyl)-6-isopropyl-2-[methyl(methylsulfonyl)amino]pyrimidin-5-yl]-3,5-dihydroxy-6-heptenoate With hydrogenchloride; water In acetonitrile at 20℃; for 2h; Stage #2: With sodium hydroxide; water In acetonitrile for 0.5h; Stage #3: zinc(II) sulfate In water; acetonitrile at 20℃; for 3h; Product distribution / selectivity; | 35% |
Conditions | Yield |
---|---|
With sodium hydroxide In water at 60 - 70℃; | 92% |
(R,S)-3-iso-butyl-4-aminobutyric acid
zinc(II) sulfate
gatifloxacin
Conditions | Yield |
---|---|
In acetone for 6h; Reflux; | 91.3% |
Conditions | Yield |
---|---|
With NaOH In water picrolonic acid suspended in water, NaOH added at room temp., suspn. warmed under stirring, aq. zinc sulphate added; ppt. filtered, washed with ethanol, ether, dried in vac. till constant weight, elem. anal.; | 91% |
ammonium O,O-diethyldithiophosphate
zinc(II) sulfate
bis(O,O-diethyldithiophosphato)zinc
Conditions | Yield |
---|---|
In water mixed; filtered; extd. (diethyl ether); dried (over MgSO4); evapd.; recrystd. (light petroleum); elem. anal.; | 90% |
Conditions | Yield |
---|---|
In ethanol; water addn. of metal salt dissolved in water to soln. of Bromazepan in EtOH; ppt. collected by filtration, washed with EtOH, dried at 60°C; elem. anal.; | 90% |
zinc(II) sulfate
HN(C2H5)3(1+)*Se2CN(CH3)(CH2)3N(CH3)2(1-) = [HN(C2H5)3][Se2CN(CH3)(CH2)3N(CH3)2]
Conditions | Yield |
---|---|
With aq. NaHCO3 In water (fume hood); addn. of ZnSO4 to the org. salt in H2O at 40°C, centrifugation, pptn. by addn. of aq. NaHCO3; dissoln. (CH2Cl2), drying (MgSO4), solvent removal, redissoln. (toluene), saturation with hexane at 50°C, crystn. on cooling; elem. anal.; | 90% |
IUPAC Name:zinc sulfate
Molecular Formula: O4SZn
Molecular Weight: 161.471600 g/mol
Appearance: Colorless to slightly green, odorless solid
Melting Point: 100°C
Boiling Point: 330 °C at 760 mmHg
EINECS: 231-793-3
Density: 1.31 g/mL at 20 °C
Water Solubility: Soluble
Merck: 14,10159
Synonyms of Zinc sulfate (CAS NO.7733-02-0): AI3-03967 ; Bonazen ; Bufopto zinc sulfate ; CCRIS 3664 ; Caswell No. 927 ; Complexonat ; EINECS 231-793-3 ; EPA Pesticide Chemical Code 089001 ; HSDB 1063 ; Medizinc ; NSC 135806 ; NSC 32677 ; NU-Z ; Neozin ; OP-Thal-zin ; Optised ; Optraex ; Orazinc ; Prefrin-Z ; Solvezinc ; Solvezink ; Sulfate de zinc ; Sulfate de zinc [French] ; Sulfuric acid zinc salt (VAN) ; Sulfuric acid, zinc salt ; Sulfuric acid, zinc salt (1:1) ; UNII-0J6Z13X3WO ; Verazinc ; Visine-ac ; White copperas ; White vitriol ; White vitriol (VAN) ; Zinc sulfate (1:1) ; Zinc sulfate (ZnSO4) ; Zinc sulfate anhydrous ; Zinc sulphate ; Zinc vitriol ; Zinc vitriol (VAN) ; Zinc-200 ; Zincate ; Zinci Sulfas ; Zincomed ; Zincum Sulfuricum ; Zink-Gro ; Zinklet ; Zinkosite ; component of Phenylzin
Categories: Inorganics;Volumetric Solutions ; BioUltraProtein Structural Analysis ; Molecular Biology ; Molecular Biology Reagents ; Optimization Reagents ; X-Ray Crystallography ; Complexometric Solutions (IDRANAL)Volumetric Solutions ; Complexometric Titration (IDRANAL) ; S - Z;Salt Solutions ; Titration ; Complexometric Concentrates (IDRANAL)Titration ; Concentrates (e.g. FIXANAL) ; Salt Concentrates
Zinc sulfate (CAS NO.7733-02-0) is used to supply zinc in fertilizers, animal feeds , and agricultural sprays. it is used in making lithopone, in electrolytes for zinc plating, as a mordant in dyeing, as a preservative for skins and leather and in medicine as an emetic.
Zinc sulfate (CAS NO.7733-02-0) can be prepared by adding solid zinc to a copper(II) sulfate solution. Zn + CuSO4 → ZnSO4 + Cu
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
dog | LDLo | intravenous | 66mg/kg (66mg/kg) | Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975. | |
dog | LDLo | subcutaneous | 78mg/kg (78mg/kg) | Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975. | |
human | TDLo | oral | 45mg/kg/7D-C (45mg/kg) | CARDIAC: PULSE RATE INCREASE WITHOUT FALL IN BP GASTROINTESTINAL: OTHER CHANGES BLOOD: NORMOCYTIC ANEMIA | British Medical Journal. Vol. 1, Pg. 754, 1978. |
human | TDLo | oral | 106mg/kg (106mg/kg) | VASCULAR: BP LOWERING NOT CHARACTERIZED IN AUTONOMIC SECTION LUNGS, THORAX, OR RESPIRATION: ACUTE PULMONARY EDEMA GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA" | British Medical Journal. Vol. 1, Pg. 1390, 1977. |
man | TDLo | oral | 180mg/kg/6W-I (180mg/kg) | BLOOD: OTHER CHANGES | JAMA, Journal of the American Medical Association. Vol. 252, Pg. 1443, 1984. |
mouse | LD50 | intraperitoneal | 29060ug/kg (29.06mg/kg) | Comptes Rendus Hebdomadaires des Seances, Academie des Sciences. Vol. 256, Pg. 1043, 1963. | |
mouse | LD50 | intravenous | 23300ug/kg (23.3mg/kg) | Indian Journal of Pharmacology. Vol. 23, Pg. 153, 1991. | |
mouse | LD50 | oral | 245mg/kg (245mg/kg) | Yaoxue Tongbao. Bulletin of Pharmacology. Vol. 22, Pg. 230, 1987. | |
mouse | LD50 | subcutaneous | 781mg/kg (781mg/kg) | GASTROINTESTINAL: CHANGES IN PANCREATIC WEIGHT BLOOD: "CHANGES IN SERUM COMPOSITION (E.G., TP, BILIRUBIN, CHOLESTEROL)" | Japanese Journal of Toxicology and Environmental Health. Vol. 44, Pg. 305, 1998. |
rabbit | LD50 | oral | 2gm/kg (2000mg/kg) | International Polymer Science and Technology. Vol. 3, Pg. 93, 1976. | |
rabbit | LDLo | intravenous | 23mg/kg (23mg/kg) | Toxicology and Applied Pharmacology. Vol. 9, Pg. 269, 1966. | |
rabbit | LDLo | subcutaneous | 300mg/kg (300mg/kg) | Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975. | |
rat | LD50 | intraperitoneal | 196mg/kg (196mg/kg) | Indian Journal of Pharmacology. Vol. 23, Pg. 153, 1991. | |
rat | LD50 | intravenous | 69900ug/kg (69.9mg/kg) | Indian Journal of Pharmacology. Vol. 23, Pg. 153, 1991. | |
rat | LD50 | oral | 1710mg/kg (1710mg/kg) | Indian Journal of Pharmacology. Vol. 23, Pg. 153, 1991. | |
rat | LDLo | subcutaneous | 330mg/kg (330mg/kg) | Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975. | |
women | TDLo | oral | 3120mg/kg/43W (3120mg/kg) | BLOOD: MICROCYTOSIS WITH OR WITHOUT ANEMIA BLOOD: AGRANULOCYTOSIS | Gastroenterology. Vol. 94, Pg. 508, 1988. |
Safety Information of Zinc sulfate (CAS NO.7733-02-0):
Hazard Codes:Xn,Xi ,N
Risk Statements:52/53-50/53-41-22-51/53
52/53:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment
50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
41:Risk of serious damage to eyes
22:Harmful if swallowed
51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Safety Statements:61-39-26-60
61:Avoid release to the environment. Refer to special instructions safety data sheet
39:Wear eye/face protection
26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
60:This material and/or its container must be disposed of as hazardous waste
RIDADR:UN 3082 9/PG 3
WGK Germany:3
RTECS:ZH5260000
First Aid Measures of Zinc sulfate (CAS NO.7733-02-0):
Ingestion:Seek medical attention. If individual is drowsy or unconscious, do not give anything by mouth; place individual on the left side with the head down. Contact a physician, medical facility, or poison control center for advice about whether to induce vomiting. If possible, do not leave individual unattended.
Inhalation:If fumes or combustion products are inhaled, remove to fresh air. Lay victim down and keep warm and rested. If breathing is shallow, or has stopped, ensure clear airway and apply resuscitation. Transport to a hospital or doctor immediately.
Skin:If this product comes into contact with skin, wash skin with soap and water. Remove contaminated clothing and footwear. Ensure contaminated clothing is thoroughly washed before using again. Transport to hospital or doctor if symptoms develop.
Eyes:If this product comes into contact with eyes, hold eyes open and wash continuously for 15 minutes with running water. Ensure irrigation under eyelids by occasionally lifting eyelids. Do not attempt to remove contact lenses unless trained. Transport to a hospital or doctor immediately.
Storage of Zinc sulfate (CAS NO.7733-02-0): Keep well closed.
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