CAS No.96-29-7,2-Butanone oxime Suppliers

Hangzhou Lingrui Chemical Co.,Ltd.

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Competitive price Methyl ethyl Oxime

Cas:96-29-7

Min.Order:1 Gram

FOB Price: $3.0

Type:Other

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TIANJIN CHENGYI INTERNATIONAL TRADING CO.,LTD

METHYL ETHYL KETOXIME (MEKO)

Methyl Ethyl Ketoxime

Cas:96-29-7

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

: 78-93-3
butanone

: 96-29-7
ethyl methyl ketone oxime

Conditions

Conditions	Yield
With ammonium sulfate; dihydrogen peroxide; sodium carbonate In water at 60℃; for 5h; Reagent/catalyst; Concentration; Time;	99.8%
With tetrabutyl-ammonium chloride; hydroxylamine; sodium hydrogencarbonate In water for 0.166667h; Ambient temperature;	96%
With hydroxylamine hydrochloride at 44℃; for 0.05h; Catalytic behavior; Microwave irradiation; Green chemistry;	85%

: 33966-50-6
SEC-BUTYLAMINE

: 96-29-7
ethyl methyl ketone oxime

Conditions

Conditions	Yield
With diperoxydodecanedioic acid In N,N-dimethyl-formamide at 20 - 55℃; for 0.333333h;	80%

: 78-92-2, 15892-23-6
iso-butanol

: 96-29-7
ethyl methyl ketone oxime

Conditions

Conditions	Yield
Stage #1: iso-butanol With chromium(VI) oxide; aluminum oxide; tert-butyl alcohol for 0.166667h; Stage #2: With hydroxylamine hydrochloride for 0.116667h;	79%

: 96-15-1
2-Methylbutylamine

: 96-29-7
ethyl methyl ketone oxime

Conditions

Conditions	Yield
With 3-chloro-benzenecarboperoxoic acid In ethyl acetate at 20℃; for 0.333333h;	79%

: 600-24-8, 116783-22-3
2-nitrobutane

A: 96-29-7
ethyl methyl ketone oxime

B: 107-46-0
Hexamethyldisiloxane

C I2: I2

Conditions

Conditions	Yield
With trimethylsilyl iodide In dichloromethane at 25℃; for 16h;	A 68% B n/a C n/a

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: 600-24-8, 116783-22-3
2-nitrobutane

: 96-29-7
ethyl methyl ketone oxime

Conditions

Conditions	Yield
With n-butyllithium; 1,1,1,2,2,2-hexamethyldisilane In tetrahydrofuran; hexane for 24h; Ambient temperature;	61%

: 69125-01-5
2-methyl-1-hydroxy-3-butanone oxime

: 74-86-2
acetylene

A: 55847-29-5
2,3-dimethyl-1-vinyl-1H-pyrrole

B: 96-29-7
ethyl methyl ketone oxime

C: 74151-03-4
2-(1-methylethenyl)-1-vinylpyrrole

Conditions

Conditions	Yield
With potassium hydroxide In dimethyl sulfoxide at 100℃; under 10640 Torr; for 3h; Product distribution;	A 20% B 3% C 8%

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: 4812-23-1, 27748-48-7, 27748-49-8
2-nitro-but-2-ene

: 96-29-7
ethyl methyl ketone oxime

Conditions

Conditions	Yield
With acetic acid; zinc

: 681-01-6
2-Chloro-2-nitrosobutane

: 96-29-7
ethyl methyl ketone oxime

Conditions

Conditions	Yield
With methanol beim Bestrahlen mit rotem Licht;
With acetone beim Bestrahlen mit rotem Licht;

: 107093-01-6
2-hydroxy-2-butylhydroxylamine

: 96-29-7
ethyl methyl ketone oxime

Conditions

Conditions	Yield
In methanol; water at 25℃; Rate constant;

: 7647-01-0
hydrogenchloride

: 3-hydroxy-3,4-dimethyl-hexane-2,5-dione dioxime

A: 96-29-7
ethyl methyl ketone oxime

B: 135636-66-7
butane-2,3-dione mono-oxime

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: 7803-49-8
hydroxylamine

: 78-93-3
butanone

: 96-29-7
ethyl methyl ketone oxime

: 1129-62-0
butan-2-one phenylhydrazone

hydroxylamine hydrochloride: hydroxylamine hydrochloride

: 96-29-7
ethyl methyl ketone oxime

: 4812-23-1, 27748-48-7, 27748-49-8
2-nitro-but-2-ene

: 64-19-7
acetic acid

zinc: zinc

: 96-29-7
ethyl methyl ketone oxime

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: 78-93-3
butanone

hydroxylaminemonosulfonate sodium: hydroxylaminemonosulfonate sodium

: 96-29-7
ethyl methyl ketone oxime

Conditions

Conditions	Yield
With acid at 70℃;

: 67-56-1
methanol

: 681-01-6
2-Chloro-2-nitrosobutane

A: 96-29-7
ethyl methyl ketone oxime

B: 135636-66-7
butane-2,3-dione mono-oxime

C 3.4-dimethyl-hexanol-(3)-dione-(2.5)-dioxime: 3.4-dimethyl-hexanol-(3)-dione-(2.5)-dioxime

D monohydrochloride of 3.4-dimethyl-hexene-(3)-dione-(2.5)-dioxime: monohydrochloride of 3.4-dimethyl-hexene-(3)-dione-(2.5)-dioxime

Conditions

Conditions	Yield
mit rotem Licht.Irradiation;

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: 681-01-6
2-Chloro-2-nitrosobutane

: 67-64-1
acetone

A: 96-29-7
ethyl methyl ketone oxime

B: 135636-66-7
butane-2,3-dione mono-oxime

C 3.4-dimethyl-hexanol-(3)-dione-(2.5)-dioxime: 3.4-dimethyl-hexanol-(3)-dione-(2.5)-dioxime

D monohydrochloride of 3.4-dimethyl-hexene-(3)-dione-(2.5)-dioxime: monohydrochloride of 3.4-dimethyl-hexene-(3)-dione-(2.5)-dioxime

Conditions

Conditions	Yield
mit rotem Licht.Irradiation;

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: 78-92-2, 15892-23-6
iso-butanol

A: 96-29-7
ethyl methyl ketone oxime

B: 1187-58-2
N-methylpropanamide

C: 78-93-3
butanone

Conditions

Conditions	Yield
Stage #1: iso-butanol With C19H42N(1+)2H(1+)O40PW12(3-); water; dihydrogen peroxide at 80℃; for 6h; Stage #2: With hydroxyammonium sulfate at 100℃; for 5h; Catalytic behavior; Beckmann Rearrangement; Overall yield = 92.6 %Chromat.;	A 40.1 %Chromat. B 34.6 %Chromat. C 25.2 %Chromat.

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: 78-92-2, 15892-23-6
iso-butanol

A: 96-29-7
ethyl methyl ketone oxime

B: 78-93-3
butanone

C: 625-50-3
N-ethylacetamide

Conditions

Conditions	Yield
Stage #1: iso-butanol With caprolactam; N,N,N-trimethyl-N-(butanesulfonic acid)ammonium hydrogensulfate; 6Na(1+)O4W(2-)2H2O at 80℃; Green chemistry; Stage #2: With hydroxyammonium sulfate at 80℃; for 5h; Green chemistry;

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: 78-93-3
butanone

A: 96-29-7
ethyl methyl ketone oxime

B: 1187-58-2
N-methylpropanamide

Conditions

Conditions	Yield
With K2Co4[WZn3(H2O)2][ZnW9O34]2*53H2O; ammonia; dihydrogen peroxide In water at 20℃; for 6h;	A 12 %Spectr. B 88 %Spectr.

: 78-93-3
butanone

A: 96-29-7
ethyl methyl ketone oxime

B: 600-24-8, 116783-22-3
2-nitrobutane

Conditions

Conditions	Yield
With ammonium hydroxide; dihydrogen peroxide In methanol at 70℃; under 760.051 Torr; Green chemistry; Overall yield = 68 %Chromat.; chemoselective reaction;

: 33966-50-6
SEC-BUTYLAMINE

A: 96-29-7
ethyl methyl ketone oxime

B: 38836-40-7
N-sec-butylidene-sec-butylamine

Conditions

Conditions	Yield
With oxygen In neat (no solvent) at 99.84℃; under 6000.6 Torr; for 5h; Autoclave; Green chemistry;

: α-isocyanatomethylmethyldimethoxysilane

: 96-29-7
ethyl methyl ketone oxime

: {[dimethoxy(methyl)silyl]methyl}carbamoylmethylethylketonoxime

Conditions

Conditions	Yield
With potassium hydroxide at 60℃; for 2h;	100%

: (isocyanatomethyl)trimethoxysilane

: 96-29-7
ethyl methyl ketone oxime

: [(trimethoxy-silyl)methyl]carbamoylmethylethylketonoxime

Conditions

Conditions	Yield
Borchi-catalyst at 80℃; for 2h;	100%

: 96-29-7
ethyl methyl ketone oxime

: 13641-96-8
acrylic acid 2-isocyanatoethyl ester

: 2-(O-[1'-methylpropylideneamino]carboxyamino)ethyl acrylate

Conditions

Conditions	Yield
With 2,6-di-tert-butyl-4-methyl-phenol at 10 - 20℃; for 6h;	99%
With 2,6-di-tert-butyl-4-methyl-phenol at 10 - 20℃; for 6h; Temperature; Enzymatic reaction;

: 112-31-2
caprinaldehyde

: 96-29-7
ethyl methyl ketone oxime

: 13372-74-2
n-decanal oxime

Conditions

Conditions	Yield
With sulfuric acid In water at 40℃; for 24h; Reagent/catalyst; Inert atmosphere; Green chemistry;	99%

: 96-29-7
ethyl methyl ketone oxime

: 105-54-4
butanoic acid ethyl ester

: C8H15NO2

Conditions

Conditions	Yield
With sodium ethanolate at 100℃; under 75.0075 Torr; for 5h; Large scale;	99%

: 446-48-0
o-fluorobenzyl bromide

: 96-29-7
ethyl methyl ketone oxime

: O-(o-fluorobenzyl)-2-butanone oxime

Conditions

Conditions	Yield
Stage #1: ethyl methyl ketone oxime With potassium hydroxide; lithium hydroxide In N,N-dimethyl acetamide; water at 50℃; Stage #2: o-fluorobenzyl bromide In N,N-dimethyl acetamide; water at 65℃; for 2.16667h;	98.5%

: 96-29-7
ethyl methyl ketone oxime

: 623-42-7
butanoic acid methyl ester

: C8H15NO2

Conditions

Conditions	Yield
With sodium ethanolate at 85℃; under 52.5053 Torr; for 3.5h; Large scale;	98.4%

: 96-29-7
ethyl methyl ketone oxime

: 1185-55-3
Methyltrimethoxysilan

: 2-butanone O,O',O"-(methylsilylidyne)trioxime

Conditions

Conditions	Yield
With toluene-4-sulfonic acid at 85 - 153℃; for 7h; Temperature;	98.3%

: 96-29-7
ethyl methyl ketone oxime

: 78-93-3
butanone

Conditions

Conditions	Yield
With aluminum oxide; tripropylammonium fluorochromate (VI) In dichloromethane for 1h;	98%
With periodic acid at 20℃; for 0.0166667h;	98%
With perchloric acid; dihydrogen peroxide; potassium bromide; ammonium molybdate tetrahydrate In water at 20℃; for 1h;	98%

: 96-29-7
ethyl methyl ketone oxime

: 3926-62-3
sodium monochloroacetic acid

: 98548-96-0
2-[(butan-2-ylideneamino)oxy]ethanoic acid

Conditions

Conditions	Yield
With potassium hydroxide In water; acetone at 20 - 60℃; for 2.25h; Solvent; Temperature;	98%

: 96-29-7
ethyl methyl ketone oxime

: 100-39-0
benzyl bromide

: 2687-43-6
O-benzylhydoxylamine hydrochloride

Conditions

Conditions	Yield
Stage #1: ethyl methyl ketone oxime; benzyl bromide With sodium ethanolate In ethanol at 40℃; for 1h; Stage #2: With dioctyltin dilaurate In ethanol at 40℃; for 6h; Stage #3: With hydrogenchloride In water Temperature; Reagent/catalyst; Solvent;	97.4%

: 96-29-7
ethyl methyl ketone oxime

: 600-24-8, 116783-22-3
2-nitrobutane

Conditions

Conditions	Yield
With dihydrogen peroxide; potassium hydrogencarbonate In tert-butyl alcohol at 65℃; under 375.038 Torr;	97%
With sodium perborate hexahydrate In acetic acid at 55℃; for 6.5h;	33%
(i) Cl2, (ii) O2, O3, (iii) (nBu)3SnH; Multistep reaction;

: 96-29-7
ethyl methyl ketone oxime

: 587-04-2
3-Chlorobenzaldehyde

: 3717-33-7, 34158-71-9, 4006-79-5
(E)-3-chlorobenzaldehyde oxime

Conditions

Conditions	Yield
With perchloric acid In water at 23℃; for 24h; Reagent/catalyst; Inert atmosphere; Green chemistry;	97%

: 96-29-7
ethyl methyl ketone oxime

: 681-01-6
2-Chloro-2-nitrosobutane

Conditions

Conditions	Yield
With chloroethane; chlorine at -40℃; for 0.25h;	96%
With hydrogenchloride; chlorine
With diethyl ether; nitrosylchloride

: 96-29-7
ethyl methyl ketone oxime

: 1015-38-9
diphenylphosphinodithioic acid

: 75320-70-6
S-<1-(hydroxyamino)-2-methylpropyl> diphenylphosphinodithioate

Conditions

Conditions	Yield
In diethyl ether for 3h;	96%

: 96-29-7
ethyl methyl ketone oxime

: 2899-02-7
N,N'-dichlorobis(2,4,6-trichlorodiphenyl)urea

A: 681-01-6
2-Chloro-2-nitrosobutane

B: 20632-35-3
bis(2,4,6-trichlorodiphenyl)urea

Conditions

Conditions	Yield
In acetonitrile at 20℃; for 0.25h;	A 96% B n/a

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: 96-29-7
ethyl methyl ketone oxime

: 1558-25-4
(chloromethyl)trichlorosilane

: chloromethyltris(methylethylketoxime)silane

Conditions

Conditions	Yield
In hexane at 20℃; for 3h; Inert atmosphere;	95%
In Petroleum ether at 25℃; for 4h; Solvent; Temperature;

: 96-29-7
ethyl methyl ketone oxime

: 89-98-5
2-chloro-benzaldehyde

: 3717-26-8, 3717-27-9, 3717-28-0
(E)-2-chlorobenzaldehyde oxime

Conditions

Conditions	Yield
With perchloric acid In water at 23℃; for 24h; Reagent/catalyst; Inert atmosphere; Green chemistry;	95%

: 98-03-3
thiophene-2-carbaldehyde

: 96-29-7
ethyl methyl ketone oxime

: 38266-87-4
thiophene-2-carbaldehyde oxime

Conditions

Conditions	Yield
With perchloric acid In water at 23℃; for 24h; Reagent/catalyst; Inert atmosphere; Green chemistry;	95%

: 96-29-7
ethyl methyl ketone oxime

: 110-18-9
N,N,N,N,-tetramethylethylenediamine

: 27685-12-7
(butan-2-ylidene)(methoxy)amine

Conditions

Conditions	Yield
Stage #1: N,N,N,N,-tetramethylethylenediamine With copper(l) chloride at 20℃; Stage #2: ethyl methyl ketone oxime With N,N,N,N,N,N-hexamethylphosphoric triamide; copper(l) chloride In dimethyl sulfoxide at 15℃; for 0.5h; Inert atmosphere; Stage #3: With potassium carbonate In dichloromethane at 15℃; for 5.16667h; Reagent/catalyst; Temperature;	95%

: 546-68-9
titanium(IV) isopropylate

: 96-29-7
ethyl methyl ketone oxime

: [Ti(OiPr)2(ethyl methyl ketoximate)2]2

Conditions

Conditions	Yield
In dichloromethane byproducts: iPrOH; (Ar), ethyl methyl ketoxime dissolved in CH2Cl2 at room temp., treated dropwise with 0.5 equiv. of Ti complex; evapd. (vac.), redissolved (CH2Cl2), crystd. for 1 d at 0°C, washed (pentane at -20°C), dried (vac.);	94%

: 104-53-0
3-phenyl-propionaldehyde

: 96-29-7
ethyl methyl ketone oxime

: 1197-50-8
3-phenylpropanal oxime

Conditions

Conditions	Yield
With perchloric acid In water at 23℃; for 24h; Reagent/catalyst; Inert atmosphere; Green chemistry;	93%

: 96-29-7
ethyl methyl ketone oxime

: 2043-61-0
cyclohexanecarbaldehyde

: 100-64-1
Cyclohexanone oxime

Conditions

Conditions	Yield
With perchloric acid In water for 24h; Reagent/catalyst; Inert atmosphere; Reflux; Green chemistry;	93%

: 455-19-6
4-Trifluoromethylbenzaldehyde

: 96-29-7
ethyl methyl ketone oxime

: 16939-49-4, 24652-60-6, 66046-34-2
(E)-4-(trifluoromethyl)benzaldoxime

Conditions

Conditions	Yield
With perchloric acid In water at 23℃; for 24h; Reagent/catalyst; Inert atmosphere; Green chemistry;	92%

: 96-29-7
ethyl methyl ketone oxime

: 66-99-9
β-naphthaldehyde

: 51873-98-4
(E)-2-naphthaldehyde oxime

Conditions

Conditions	Yield
With perchloric acid In water at 23℃; for 24h; Reagent/catalyst; Inert atmosphere; Green chemistry;	92%

: 96-29-7
ethyl methyl ketone oxime

: 7440-23-5
sodium

: 5835-64-3, 24606-08-4, 91002-43-6
trimethylantimony(V) dibromide

: 79730-22-6
(CH3)3Sb(ONC(CH3)(C2H5))2

Conditions

Conditions	Yield
In benzene byproducts: NaBr; absence of moisture; addn. of Sb-compd. to 2 equiv. of sodium oximate (prepd. from oxime and Na), refluxing; distn. (reduced pressure); elem. anal.;	91%

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