p-Tolyl acetate supplier | CasNO.140-39-6

Name
P-TOLYL ACETATE
EINECS 205-413-1
CAS No. 140-39-6
Article Data208
CAS DataBase
Density 1.047
Solubility Insoluble

Melting Point 48.5 °C

Formula C9H10 O2

Boiling Point 210 - 211 C

Molecular Weight 150.177

Flash Point 90 ºC

Transport Information 200kgs

Appearance clear liquid

Safety Moderately toxic by ingestion and skin contact. Combustible liquid. When heated to decomposition it emits toxic smoke and irritating fumes. See also ESTERS.

Risk Codes R22;R36/37/38

Molecular Structure

Hazard Symbols

Synonyms Aceticacid, p-tolyl ester (6CI,7CI,8CI); 4-Acetoxytoluene; 4-Methylphenyl acetate;4-Tolyl acetate; NSC 43244; NSC 65594; Narceol; p-Acetoxytoluene; p-Cresolacetate; p-Methylphenyl acetate; p-Tolyl acetate; p-Tolyl ethanoate

PSA 26.30000

LogP 1.92030

Synthetic route

106-44-5
p-cresol

108-24-7
acetic anhydride

140-39-6
1-acetoxy-4-methylbenzene

Conditions

Conditions Yield

With pyridine at 100℃; for 15h; 100%

at 20℃; for 0.666667h; 100%

With pyridine at 25℃; for 12h; 100%

106-44-5
p-cresol

75-36-5
acetyl chloride

140-39-6
1-acetoxy-4-methylbenzene

Conditions

Conditions Yield

With trifluorormethanesulfonic acid In acetonitrile at 20℃; for 1h; 99%

With tetrabutyl-ammonium chloride; sodium hydroxide In dichloromethane; water at 0℃; for 0.0833333h; 95%

With ZnAl2O4 nanoparticles at 20℃; for 0.566667h; Neat (no solvent); 93%

106-44-5
p-cresol

64-19-7
acetic acid

140-39-6
1-acetoxy-4-methylbenzene

Conditions

Conditions Yield

With 50wtpercent Cs2.5H0.5PW12O40 supported on MCM-41 In acetonitrile at 50℃; for 0.5h; 98%

With phosphorus pentoxide; silica gel at 25℃; for 6h; 84%

With phosphate buffer; Porcine Pancreas Lipase In chloroform; Petroleum ether at 56 - 60℃; for 88h; pH=7.0; 67.9%

108-05-4
vinyl acetate

106-44-5
p-cresol

140-39-6
1-acetoxy-4-methylbenzene

Conditions

Conditions Yield

With potassium hydroxide In tetrahydrofuran at 120℃; for 18h; Schlenk technique; 98%

With sodium carbonate In acetonitrile at 120℃; for 24h; Schlenk technique; 98%

With pseudomonas fuorescens lipase immobilized on multiwall carbon nano-tubes at 50℃; for 12h; Green chemistry; 69%

In tetrahydrofuran; cyclohexane at 40℃; Rate constant; adsorbed Chromobacterium viscosum lipase;

With steapsin lipase In hexane at 55℃; for 60h; Enzymatic reaction; 81 %Chromat.

104-93-8
4-Methylanisole

201230-82-2
carbon monoxide

74-88-4
methyl iodide

140-39-6
1-acetoxy-4-methylbenzene

Conditions

Conditions Yield

With iridium(III) chloride; triphenylphosphine In acetonitrile at 180℃; under 3750.38 Torr; for 20h; Autoclave; 95%

...Expand

3728-43-6
p-(trimethylsilyl)toluene

64-19-7
acetic acid

140-39-6
1-acetoxy-4-methylbenzene

Conditions

Conditions Yield

With palladium diacetate; bis-[(trifluoroacetoxy)iodo]benzene at 80℃; for 17h; 93%

22113-51-5
p-cresolate

108-24-7
acetic anhydride

140-39-6
1-acetoxy-4-methylbenzene

Conditions

Conditions Yield

With Amberlite IRA-400 for 2h; Ambient temperature; 92%

106-44-5
p-cresol

A

2345-34-8
4-acetyloxy-benzoic acid

B

140-39-6
1-acetoxy-4-methylbenzene

Conditions

Conditions Yield

With acetic acid A 92%
B n/a

106-44-5
p-cresol

201230-82-2
carbon monoxide

74-88-4
methyl iodide

140-39-6
1-acetoxy-4-methylbenzene

Conditions

Conditions Yield

With iridium(III) chloride; triphenylphosphine In acetonitrile at 180℃; under 3750.38 Torr; for 20h; Autoclave; 91%

...Expand

122-00-9
para-methylacetophenone

140-39-6
1-acetoxy-4-methylbenzene

Conditions

Conditions Yield

With oxygen; benzaldehyde; nickel(II) iodide; Dowex 50W; iron(II) In 1,2-dichloro-ethane at 20℃; for 7h; Baeyer-Villiger oxidation; 87%

With sodium perborate In acetic acid; trifluoroacetic acid for 8h; Ambient temperature; 79%

With dihydrogen peroxide In 1,2-dichloro-ethane at 80℃; for 24h; Baeyer-Villiger Ketone Oxidation; regioselective reaction; 59%

506-96-7
Acetyl bromide

834-25-3
4-methylphenyl benzyl ether

140-39-6
1-acetoxy-4-methylbenzene

Conditions

Conditions Yield

With lithium bromide In dichloromethane at 30 - 35℃; for 12h; Inert atmosphere; 86%

106-44-5
p-cresol

13483-16-4
2,4,6-triacetyloxy-1,3,5-triazine

140-39-6
1-acetoxy-4-methylbenzene

Conditions

Conditions Yield

at 80℃; for 0.333333h; neat (no solvent); 65%

106-44-5
p-cresol

10387-40-3
potassium thioacetate

140-39-6
1-acetoxy-4-methylbenzene

Conditions

Conditions Yield

With copper(II) acetate monohydrate In acetonitrile at 80℃; for 18h; Reagent/catalyst; Temperature; Sealed tube; 64%

With copper diacetate In acetonitrile at 80℃; for 4h; 53%

104-93-8
4-Methylanisole

75-36-5
acetyl chloride

A

140-39-6
1-acetoxy-4-methylbenzene

B

7168-55-0
2,2'-dimethoxy-5,5'-dimethyl-1,1'-biphenyl

Conditions

Conditions Yield

CoCl2 In acetonitrile at 80℃; A 45%
B 52%

...Expand

61599-05-1
4-methyl-4-acetyl-2-cyclohexen-1-one

140-39-6
1-acetoxy-4-methylbenzene

Conditions

Conditions Yield

With 2,3-dicyano-5,6-dichloro-p-benzoquinone In benzene for 220h; Heating; 35%

With benzenesulfonamide; benzeneseleninic anhydride In benzene for 48h; Heating;

With 2,3-dicyano-5,6-dichloro-p-benzoquinone

375-85-9
perfluoroheptanoic acid

108-88-3
toluene

A

533-18-6
2-methylphenyl acetate

B

140-39-6
1-acetoxy-4-methylbenzene

C

2,2,3,3,4,4,5,5,6,6,7,7,7-Tridecafluoro-heptanoic acid o-tolyl ester

D

2,2,3,3,4,4,5,5,6,6,7,7,7-Tridecafluoro-heptanoic acid benzyl ester

E

102607-12-5
2,2,3,3,4,4,5,5,6,6,7,7,7-Tridecafluoro-heptanoic acid p-tolyl ester

Conditions

Conditions Yield

With lead(IV) acetate at 80℃; for 7h; Mechanism; Product distribution; other temperature; A n/a
B n/a
C n/a
D 5%
E n/a

...Expand

106-44-5
p-cresol

140-39-6
1-acetoxy-4-methylbenzene

Conditions

Conditions Yield

With boric acid; xylene Entfernen des entstehenden H2O und Erhitzen des Reaktionsprodukts mit Essigsaeure;

With pyridine; acetic anhydride

carbonic acid p-tolyl ester-trichloromethyl ester

127-09-3
sodium acetate

A

140-39-6
1-acetoxy-4-methylbenzene

B

108-24-7
acetic anhydride

Conditions

Conditions Yield

at 50 - 60℃; zuletzt bei 140-150grad;

...Expand

99-87-6
4-methylisopropylbenzene

108-24-7
acetic anhydride

140-39-6
1-acetoxy-4-methylbenzene

Conditions

Conditions Yield

With oxygen; toluene-4-sulfonic acid at 90℃;

toluene-4-diazonium ; sulfate

64-19-7
acetic acid

140-39-6
1-acetoxy-4-methylbenzene

1192-96-7
potassium p-cresolate

75-36-5
acetyl chloride

140-39-6
1-acetoxy-4-methylbenzene

93-59-4
Perbenzoic acid

122-00-9
para-methylacetophenone

140-39-6
1-acetoxy-4-methylbenzene

Conditions

Conditions Yield

With chloroform

106-44-5
p-cresol

85106-60-1
1-acetyl-3-benzylimidazolium bromide

140-39-6
1-acetoxy-4-methylbenzene

Conditions

Conditions Yield

In chloroform for 0.3h; Ambient temperature; 99 % Spectr.

1523-06-4
3-nitrophenyl acetate

22113-51-5
p-cresolate

A

140-39-6
1-acetoxy-4-methylbenzene

B

16554-54-4
3-nitrophenolate anion

Conditions

Conditions Yield

With potassium chloride In water at 25℃; Rate constant;

...Expand

10186-94-4
3,4-dinitro-phenyl-acetate

22113-51-5
p-cresolate

A

140-39-6
1-acetoxy-4-methylbenzene

B

60154-37-2
3,4-dinitrophenoxide ion

Conditions

Conditions Yield

With potassium chloride In water at 25℃; Rate constant;

...Expand

108-24-7
acetic anhydride

108-88-3
toluene

A

533-18-6
2-methylphenyl acetate

B

122-46-3
3-acetoxytoluene

C

140-39-6
1-acetoxy-4-methylbenzene

Conditions

Conditions Yield

With hexaaquairon(II) perchlorate; dihydrogen peroxide; acetonitrile at 30℃; for 0.05h; Product distribution; Mechanism; se. aromatic and aliphatic hydrocarbons; further reagents: iron(II)-solvates; var. ratio of reagents;

...Expand

97400-46-9, 97400-47-0
4-acetyl-4-methyl-6-phenylselenocyclohex-2-enone

A

106-44-5
p-cresol

B

140-39-6
1-acetoxy-4-methylbenzene

Conditions

Conditions Yield

With ozone In dichloromethane at -78 - 20℃; for 1.5h; Title compound not separated from byproducts;

With ozone In diethyl ether Product distribution; 1) -78 deg C, 2) to r.t.;

64-19-7
acetic acid

108-88-3
toluene

A

533-18-6
2-methylphenyl acetate

B

122-46-3
3-acetoxytoluene

C

140-39-6
1-acetoxy-4-methylbenzene

Conditions

Conditions Yield

With palladium diacetate; sodium dichromate; methanesulfonic acid; benzonitrile at 90℃; for 16h; Product distribution; Mechanism; var. conc. of oxidazing agent, other aromatic compounds;

...Expand

106-44-5
p-cresol

830-03-5
4-nitrophenol acetate

A

100-02-7
4-nitro-phenol

B

140-39-6
1-acetoxy-4-methylbenzene

Conditions

Conditions Yield

In water; acetonitrile at 25℃; Rate constant; Mechanism; pH 10.00;

...Expand

140-39-6
1-acetoxy-4-methylbenzene

106-44-5
p-cresol

Conditions

Conditions Yield

silica gel; toluene-4-sulfonic acid In water; toluene at 80℃; for 8h; 100%

With ammonium acetate In methanol at 20℃; for 4.5h; 97%

With mesoporous silica-supported (Salen) Co(II) catalyst In methanol at 20℃; for 1h; chemoselective reaction; 95%

140-39-6
1-acetoxy-4-methylbenzene

25015-63-8
4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

4,4,5,5-tetramethyl-2-(p-tolyloxy)-1,3,2-dioxaborolane

Conditions

Conditions Yield

With manganese(II) triflate bis-acetonitrile solvate; potassium tert-butylate In benzene-d6 at 20℃; for 3h; Inert atmosphere; Glovebox; 99%

140-39-6
1-acetoxy-4-methylbenzene

1450-72-2
5-methyl-2-hydroxyacetophenone

Conditions

Conditions Yield

With aluminium trichloride a) 130 deg C, 1 h, b) 25 deg C (ice cooling), 1 h; 98%

With phosphorus pentoxide; silica gel for 0.0833333h; Fries rearrangement; microwave irradiation; 98%

for 0.116667h; Rearrangement; microwave irradiation; 97%

140-39-6
1-acetoxy-4-methylbenzene

501-65-5
diphenyl acetylene

33257-85-1
6-methyl-3,4-diphenyl-2H-chromen-2-one

Conditions

Conditions Yield

With copper acetylacetonate; tris(triphenylphosphine)ruthenium(II) chloride; di-n-butyliodotin hydride; 3-ethyl-1-methyl-1H-imidazol-3-ium 2,2,2-trifluoroacetate In 1,4-dioxane; dimethyl sulfoxide at 20 - 70℃; for 8h; Reagent/catalyst; Inert atmosphere; 97.6%

140-39-6
1-acetoxy-4-methylbenzene

100-39-0
benzyl bromide

834-25-3
4-methylphenyl benzyl ether

Conditions

Conditions Yield

With sodium methylate In N,N-dimethyl-formamide for 0.5h; Ambient temperature; 95%

140-39-6
1-acetoxy-4-methylbenzene

98-80-6
phenylboronic acid

3699-01-2
4-tolyl phenyl sulfide

Conditions

Conditions Yield

With copper(l) iodide; sulfur; sodium t-butanolate at 60 - 80℃; for 22h; 92%

With sulfur; nickel(II) ferrite; sodium t-butanolate at 90℃; for 24h; Green chemistry; 90 %Chromat.

13472-00-9
p-Aminophenethylamine

140-39-6
1-acetoxy-4-methylbenzene

40377-41-1
4-(2-(((methyl)carbonyl)amino)ethyl)aniline

Conditions

Conditions Yield

at 20℃; for 30h; 89.7%

at 20℃; for 30h; 89.7%

140-39-6
1-acetoxy-4-methylbenzene

52727-95-4
4-acetoxybenzyl bromide

Conditions

Conditions Yield

With N-Bromosuccinimide; dibenzoyl peroxide In tetrachloromethane at 50℃; for 3h; 89.2%

With N-Bromosuccinimide; dibenzoyl peroxide In chloroform for 4h; Reflux; 79%

With N-Bromosuccinimide; dibenzoyl peroxide In chloroform at 61℃; for 4h; 66%

140-39-6
1-acetoxy-4-methylbenzene

5720-05-8
4-methylphenylboronic acid

620-94-0
di-(p-tolyl)sulfane

Conditions

Conditions Yield

With copper(l) iodide; sulfur; sodium t-butanolate at 60 - 80℃; for 25h; 89%

With sulfur; nickel(II) ferrite; sodium t-butanolate at 90℃; for 26h; Green chemistry; 89 %Chromat.

140-39-6
1-acetoxy-4-methylbenzene

639-58-7
triphenyltin chloride

3699-01-2
4-tolyl phenyl sulfide

Conditions

Conditions Yield

With potassium fluoride; copper diacetate; potassium carbonate; sulfur at 80℃; for 12h; 89%

With sulfur; potassium fluoride; nickel(II) ferrite; potassium carbonate at 85℃; for 14h; Green chemistry; 87 %Chromat.

140-39-6
1-acetoxy-4-methylbenzene

620-94-0
di-(p-tolyl)sulfane

Conditions

Conditions Yield

With copper(l) iodide; sulfur; sodium t-butanolate In N,N-dimethyl-formamide at 120℃; for 15h; Inert atmosphere; 88%

With sulfur; nickel(II) ferrite; sodium t-butanolate In N,N-dimethyl-formamide at 120℃; for 17h; Inert atmosphere; Green chemistry; 88 %Chromat.

140-39-6
1-acetoxy-4-methylbenzene

2345-34-8
4-acetyloxy-benzoic acid

Conditions

Conditions Yield

With zinc(II) oxide In N,N-dimethyl-formamide for 0.133333h; microwave irradiation; 83%

With oxygen; manganese (II) acetate tetrahydrate; cobalt(II) diacetate tetrahydrate; acetic acid at 100℃; for 15h; 83%

With 2,2'-azobis(isobutyronitrile); oxygen; 1N,3N,5N-trihydroxy-1,3,5-triazin-2,4,6[1H,3H,5H]-trione; cobalt(II) acetate; manganese(II) acetate In acetic acid at 100℃; under 760 Torr; for 6h; 74%

cobalt (II) acetate·4 H2O

cobalt (II) acetate·4 H2O

manganese (II) acetate·4 H2O

manganese (II) acetate·4 H2O

140-39-6
1-acetoxy-4-methylbenzene

34241-39-9
azobisisobutyronitrile

143435-52-3
1N,3N,5N-trihydroxy-1,3,5-triazin-2,4,6[1H,3H,5H]-trione

2345-34-8
4-acetyloxy-benzoic acid

Conditions

Conditions Yield

With acetic acid 82%

...Expand

140-39-6
1-acetoxy-4-methylbenzene

100-09-4
4-methoxybenzoic acid

58600-95-6
4-methylphenyl 4-methoxybenzoate

Conditions

Conditions Yield

With phosphotungstic acid In 5,5-dimethyl-1,3-cyclohexadiene at 160 - 170℃; Reagent/catalyst; 82%

140-39-6
1-acetoxy-4-methylbenzene

A

878-00-2
4-formylphenyl acetate

B

91735-04-5
Acetic acid 4-nitrooxymethyl-phenyl ester

Conditions

Conditions Yield

With ammonium cerium(IV) nitrate In acetonitrile at 40℃; for 2.5h; Irradiation; A n/a
B 80%

With ammonium cerium(IV) nitrate In acetonitrile at 40℃; for 2.5h; Mechanism; Irradiation; A n/a
B 80%

140-39-6
1-acetoxy-4-methylbenzene

65-85-0
benzoic acid

614-34-6
p-cresyl benzoate

Conditions

Conditions Yield

With phosphotungstic acid In 5,5-dimethyl-1,3-cyclohexadiene at 160 - 170℃; Reagent/catalyst; 79%

140-39-6
1-acetoxy-4-methylbenzene

74-88-4
methyl iodide

104-93-8
4-Methylanisole

Conditions

Conditions Yield

With sodium hydride In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide 1.) 0 deg C, 1 h, 2.) 25 deg C; 78%

586-76-5
4-Bromobenzoic acid

140-39-6
1-acetoxy-4-methylbenzene

107456-33-7
4-methylphenyl 4-bromobenzoate

Conditions

Conditions Yield

With phosphotungstic acid In 5,5-dimethyl-1,3-cyclohexadiene at 160 - 170℃; Reagent/catalyst; 78%

p-Tolyl acetate Chemical Properties

IUPAC Name:  (4-Methylphenyl) acetate
Synonyms: Acetic acid, 4-methylphenyl ester ; Acetyl p-cresol ; p-Cresyl acetate ; p-Cresylic acetate ; 4-Methylphenyl acetate ; 4-Methylphenylacetat ; Acetic acid 4-methylphenyl ester ; p-Tolyl acetate ; Tolyl acetate
The Molecular Formula of  4-Methylphenyl acetate (CAS NO.140-39-6):C₉H₁₀O₂
The Molecular Weight of 4-Methylphenyl acetate (CAS NO.140-39-6):150.1745 g/mol
The Molecular Structure of   4-Methylphenyl acetate (CAS NO.140-39-6):
Index of Refraction: 1.503
Molar Refractivity: 42.41 cm³
Molar Volume: 143.3 cm³
Surface Tension: 34.1 dyne/cm
Density: 1.047 g/cm³
Flash Point: 85.4 °C
Enthalpy of Vaporization: 44.84 kJ/mol
Boiling Point: 212.1 °C at 760 mmHg
Vapour Pressure: 0.176 mmHg at 25°C
Density: 1.047 g/mL at 25 °C(lit.)

p-Tolyl acetate Uses

4-Methylphenyl acetate ,whose cas register No. is 140-39-6 ,can be used as food flavor and perfuming agent.

p-Tolyl acetate Toxicity Data With Reference

1.
orl-rat LD50:1900 mg/kg
    FCTXAV    Food and Cosmetics Toxicology. 12 (1974),391.

2.
skn-rbt LD50:2100 mg/kg
    FCTXAV    Food and Cosmetics Toxicology. 12 (1974),391.

p-Tolyl acetate Consensus Reports

Reported in EPA TSCA Inventory.

p-Tolyl acetate Safety Profile

Moderately toxic by ingestion and skin contact. Combustible liquid. When heated to decomposition it emits toxic smoke and irritating fumes. See also ESTERS.

Hazard Codes: Xn
Risk Statements: 22-36/37/38
R22:Harmful if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 26-36/37/39
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
WGK Germany: 2
RTECS: AJ7570000

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Conditions	Yield
With pyridine at 100℃; for 15h;	100%
at 20℃; for 0.666667h;	100%
With pyridine at 25℃; for 12h;	100%

Conditions	Yield
With trifluorormethanesulfonic acid In acetonitrile at 20℃; for 1h;	99%
With tetrabutyl-ammonium chloride; sodium hydroxide In dichloromethane; water at 0℃; for 0.0833333h;	95%
With ZnAl2O4 nanoparticles at 20℃; for 0.566667h; Neat (no solvent);	93%

Conditions	Yield
With 50wtpercent Cs2.5H0.5PW12O40 supported on MCM-41 In acetonitrile at 50℃; for 0.5h;	98%
With phosphorus pentoxide; silica gel at 25℃; for 6h;	84%
With phosphate buffer; Porcine Pancreas Lipase In chloroform; Petroleum ether at 56 - 60℃; for 88h; pH=7.0;	67.9%

Conditions	Yield
With potassium hydroxide In tetrahydrofuran at 120℃; for 18h; Schlenk technique;	98%
With sodium carbonate In acetonitrile at 120℃; for 24h; Schlenk technique;	98%
With pseudomonas fuorescens lipase immobilized on multiwall carbon nano-tubes at 50℃; for 12h; Green chemistry;	69%
In tetrahydrofuran; cyclohexane at 40℃; Rate constant; adsorbed Chromobacterium viscosum lipase;
With steapsin lipase In hexane at 55℃; for 60h; Enzymatic reaction;	81 %Chromat.

Conditions	Yield
With oxygen; benzaldehyde; nickel(II) iodide; Dowex 50W; iron(II) In 1,2-dichloro-ethane at 20℃; for 7h; Baeyer-Villiger oxidation;	87%
With sodium perborate In acetic acid; trifluoroacetic acid for 8h; Ambient temperature;	79%
With dihydrogen peroxide In 1,2-dichloro-ethane at 80℃; for 24h; Baeyer-Villiger Ketone Oxidation; regioselective reaction;	59%

Conditions	Yield
With copper(II) acetate monohydrate In acetonitrile at 80℃; for 18h; Reagent/catalyst; Temperature; Sealed tube;	64%
With copper diacetate In acetonitrile at 80℃; for 4h;	53%

Conditions	Yield
With 2,3-dicyano-5,6-dichloro-p-benzoquinone In benzene for 220h; Heating;	35%
With benzenesulfonamide; benzeneseleninic anhydride In benzene for 48h; Heating;
With 2,3-dicyano-5,6-dichloro-p-benzoquinone

Conditions	Yield
With boric acid; xylene Entfernen des entstehenden H2O und Erhitzen des Reaktionsprodukts mit Essigsaeure;
With pyridine; acetic anhydride

Conditions	Yield
With ozone In dichloromethane at -78 - 20℃; for 1.5h; Title compound not separated from byproducts;
With ozone In diethyl ether Product distribution; 1) -78 deg C, 2) to r.t.;

Conditions	Yield
silica gel; toluene-4-sulfonic acid In water; toluene at 80℃; for 8h;	100%
With ammonium acetate In methanol at 20℃; for 4.5h;	97%
With mesoporous silica-supported (Salen) Co(II) catalyst In methanol at 20℃; for 1h; chemoselective reaction;	95%

Conditions	Yield
With aluminium trichloride a) 130 deg C, 1 h, b) 25 deg C (ice cooling), 1 h;	98%
With phosphorus pentoxide; silica gel for 0.0833333h; Fries rearrangement; microwave irradiation;	98%
for 0.116667h; Rearrangement; microwave irradiation;	97%

Conditions	Yield
With copper(l) iodide; sulfur; sodium t-butanolate at 60 - 80℃; for 22h;	92%
With sulfur; nickel(II) ferrite; sodium t-butanolate at 90℃; for 24h; Green chemistry;	90 %Chromat.

Conditions	Yield
With N-Bromosuccinimide; dibenzoyl peroxide In tetrachloromethane at 50℃; for 3h;	89.2%
With N-Bromosuccinimide; dibenzoyl peroxide In chloroform for 4h; Reflux;	79%
With N-Bromosuccinimide; dibenzoyl peroxide In chloroform at 61℃; for 4h;	66%

Conditions	Yield
With copper(l) iodide; sulfur; sodium t-butanolate at 60 - 80℃; for 25h;	89%
With sulfur; nickel(II) ferrite; sodium t-butanolate at 90℃; for 26h; Green chemistry;	89 %Chromat.

Conditions	Yield
With potassium fluoride; copper diacetate; potassium carbonate; sulfur at 80℃; for 12h;	89%
With sulfur; potassium fluoride; nickel(II) ferrite; potassium carbonate at 85℃; for 14h; Green chemistry;	87 %Chromat.

Conditions	Yield
With copper(l) iodide; sulfur; sodium t-butanolate In N,N-dimethyl-formamide at 120℃; for 15h; Inert atmosphere;	88%
With sulfur; nickel(II) ferrite; sodium t-butanolate In N,N-dimethyl-formamide at 120℃; for 17h; Inert atmosphere; Green chemistry;	88 %Chromat.

Conditions	Yield
With zinc(II) oxide In N,N-dimethyl-formamide for 0.133333h; microwave irradiation;	83%
With oxygen; manganese (II) acetate tetrahydrate; cobalt(II) diacetate tetrahydrate; acetic acid at 100℃; for 15h;	83%
With 2,2'-azobis(isobutyronitrile); oxygen; 1N,3N,5N-trihydroxy-1,3,5-triazin-2,4,6[1H,3H,5H]-trione; cobalt(II) acetate; manganese(II) acetate In acetic acid at 100℃; under 760 Torr; for 6h;	74%

Conditions	Yield
With ammonium cerium(IV) nitrate In acetonitrile at 40℃; for 2.5h; Irradiation;	A n/a B 80%
With ammonium cerium(IV) nitrate In acetonitrile at 40℃; for 2.5h; Mechanism; Irradiation;	A n/a B 80%

1.		orl-rat LD50:1900 mg/kg		FCTXAV Food and Cosmetics Toxicology. 12 (1974),391.
2.		skn-rbt LD50:2100 mg/kg		FCTXAV Food and Cosmetics Toxicology. 12 (1974),391.

Product Name

P-TOLYL ACETATE

Synthetic route

p-Tolyl acetate Chemical Properties

p-Tolyl acetate Uses

p-Tolyl acetate Toxicity Data With Reference

p-Tolyl acetate Consensus Reports

p-Tolyl acetate Safety Profile

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