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Suzhou SuKaiLu Chemical Technology Co., Ltd.

Stock products, own laboratory Our Company main product 一:suzuki reaction customization 二:Boronic acid derivative ①:phenylboronic acid derivative ②:Phenylboronic acid pinacol ester derivative ③:Potassium phenyltrifluoroborate derivative ④:Phenylbor

(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE

Cas:24388-23-6

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

Phenyl-boronic acid pinacol ester Manufacturer/High quality/Best price/In stock

Cas:24388-23-6

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

4,4,5,5-Tetramethyl-2-phenyl-1,3,2-dioxaborolane

Cas:24388-23-6

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Jinan Finer Chemical Co., Ltd

Product Description Product website: http://www.finerchem.com/pro01en/id/759.html Product Name Phenylboronic acid pinacol ester CAS No.

Phenylboronic acid pinacol ester

Cas:24388-23-6

Min.Order:1 Metric Ton

FOB Price: $45.0

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

4, 4, 5, 5-Tetramethyl-2-Phenyl-1, 3, 2-Dioxaborolane CAS 24388-23-6

Cas:24388-23-6

Min.Order:1 Kilogram

FOB Price: $6.0 / 10.0

Type:Trading Company

inquiry

Henan Tianfu Chemical Co., Ltd.

(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE Basic information Product Name: (4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE Synonyms: PHENYL-BORONIC ACID PINACOL ESTER;(4,4

24388-23-6 (4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE

Cas:24388-23-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 24388-23-6 with best quality

Cas:24388-23-6

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

1,3,2-Dioxaborolane,4,4,5,5-tetramethyl-2-phenyl-

Cas:24388-23-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

Agrochemical Intermediates, (4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE CAS:24388-23-6

Cas:24388-23-6

Min.Order:1 Kilogram

FOB Price: $24.8 / 36.2

Type:Trading Company

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:24388-23-6

Cas:24388-23-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures s

(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE

Cas:24388-23-6

Min.Order:1 Kilogram

FOB Price: $20.0 / 30.0

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE

Cas:24388-23-6

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

4,4,5,5-Tetramethyl-2-phenyl-1,3,2-dioxaborolane

Cas:24388-23-6

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Phenylboronic acid pinacol ester

Cas:24388-23-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE

Cas:24388-23-6

Min.Order:1 Milligram

Negotiable

Type:Trading Company

inquiry

Shanghai Minstar Chemical Co., Ltd

(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE Basic information Product Name: (4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE Synonyms: (4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)benzene, 2-Phenyl-4,4,5,5-tetramethyl-1,3,2-dioxab

(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE

Cas:24388-23-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE

Cas:24388-23-6

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE

Cas:24388-23-6

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE

Cas:24388-23-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE

Cas:24388-23-6

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE

Cas:24388-23-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

Phenylboronic acid pinacol ester

Cas:24388-23-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE

Cas:24388-23-6

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

Phenylboronic acid pinacol ester cas no. 24388-23-6 98%

Cas:24388-23-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Greenutra Resource Inc

(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)benzeneAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air

(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)benzene

Cas:24388-23-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)benzene

Cas:24388-23-6

Min.Order:0

Negotiable

Type:Other

inquiry

Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stockAppearance:To be subject to the object Package:Customized Application:pharmaceutical intermediates Transportation:Air Port:Shanghai;Guangzhou

4,4,5,5-TetraMethyl-2-phenyl-1,3,2-dioxaborolane

Cas:24388-23-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Wuxi TAA Chemical Industry Co.,LTD.

1.A strong technical force and advanced processing equipments. The quality of the products has been strictly inspected and all kinds of index have reached or exceeded domestic and international standards.2. Now we have established long-term stable re

24388-23-6 (4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE

Cas:24388-23-6

Min.Order:0

Negotiable

Type:Other

inquiry

GIHI CHEMICALS CO.,LIMITED

high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,or Intermediates,fine chemicals Transportation:air,sea,courier

Phenylboronic acid pinacol ester

Cas:24388-23-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane
25015-63-8

4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

benzene
71-43-2

benzene

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

Conditions
ConditionsYield
[Ir(COD)(1,3-dicyclohexylimidazolidin-2-ylidene)2]CF3CO2 at 40℃; for 10h;100%
(η4-1,5-cyclooctadiene)bis(1,3-dimethylimidazolin-2-ylidene)iridium(I) trifluoracetate In benzene (N2); using Schlenk techniques; dissolving of 2 mmol pinacolborane and 1.5 mol% of Ir(COD)(C3H2N2Me2)2(CF3CO2) in benzene; stirring and heating at 40°C for 12 h; monitoring by GC-MS; removal of solvent under vac. at room temp.; chromy. over silica gel, eluting with CH2Cl2;100%
(η4-1,5-cyclooctadiene)(1,1'-dimethyl-3,3'-o-xylylene-diimidazolin-2,2'-diylidene)iridium(I) trifluoroacetate In benzene (N2); using Schlenk techniques; dissolving of 2 mmol pinacolborane and 1.5 mol% of Ir(COD)(1,1'-dimethyl-3,3'-o-xylylene-diimidazolin-2,2'-diylidene)2(CF3CO2) in benzene; stirring and heating at 40°C for 12 h; monitoring by GC-MS; removal of solvent under vac. at room temp.; chromy. over silica gel, eluting with CH2Cl2;100%
bromobenzene
108-86-1

bromobenzene

4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane
25015-63-8

4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

Conditions
ConditionsYield
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; potassium acetate In 1,4-dioxane at 85℃; for 6h; Inert atmosphere;100%
With bis(1,5-cyclooctadiene)diiridium(I) dichloride In methanol at 20℃; for 8h;92%
Stage #1: bromobenzene; 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane With bis(trifluoromethane)sulfonimide lithium In tetrahydrofuran at 20℃; Electrochemical reaction;
Stage #2: With sulfuric acid at 0℃; pH=5; Further stages.;
78%
bis(pinacol)diborane
73183-34-3

bis(pinacol)diborane

benzene
71-43-2

benzene

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

Conditions
ConditionsYield
With [Ir(COD)(OMe)]2-Covalent organic framework (4-iPr) at 100℃; for 24h; Reagent/catalyst; Inert atmosphere;100%
With iridium-1,5-cyclooctadiene complex immobilized 2,2'-bipyridine-functionalized organosilica nanotubes at 80℃; for 12h; Catalytic behavior; Kinetics; Reagent/catalyst; Inert atmosphere;97%
With [Ir(OMe)(1,5-cyclooctadiene)]2 In benzene at 80℃; for 12h; Kinetics; Reagent/catalyst; Schlenk technique; Inert atmosphere;94%
2,3-dimethyl-2,3-butane diol
76-09-5

2,3-dimethyl-2,3-butane diol

phenylboronic acid
98-80-6

phenylboronic acid

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

Conditions
ConditionsYield
at 0℃; for 1h;100%
In pentane at 0 - 20℃; for 3h;100%
In tetrahydrofuran at 20℃; for 1h;95%
chlorobenzene
108-90-7

chlorobenzene

bis(pinacol)diborane
73183-34-3

bis(pinacol)diborane

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine; triphenylphosphine; bis(1,5-cyclooctadiene)nickel (0) In methanol at 20 - 50℃; Product distribution / selectivity; Inert atmosphere;99%
With N-ethyl-N,N-diisopropylamine; triphenylphosphine; (1,5-cyclooctadiene)(cyclopentadienyl)nickel In methanol at 20 - 50℃; for 25h; Product distribution / selectivity; Inert atmosphere;99%
With sodium acetate; bis(dibenzylideneacetone)-palladium(0); XPhos for 12h; Reagent/catalyst; Miyaura Borylation Reaction; Heating;99%
bromobenzene
108-86-1

bromobenzene

bis(pinacol)diborane
73183-34-3

bis(pinacol)diborane

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

Conditions
ConditionsYield
With DPEPhos; sodium acetate; bis(dibenzylideneacetone)-palladium(0) for 12h; Reagent/catalyst; Miyaura Borylation Reaction; Heating;99%
With Co(1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene)2Cl2; potassium methanolate In tert-butyl methyl ether at 50℃; for 8h;95%
With C37H51ClFeNPPd; potassium acetate In 1,4-dioxane at 80℃; for 3h; Suzuki-Miyaura coupling; Inert atmosphere;93%
2,3-dimethyl-2,3-butane diol
76-09-5

2,3-dimethyl-2,3-butane diol

potassium phenyltrifluoborate

potassium phenyltrifluoborate

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

Conditions
ConditionsYield
With chloro-trimethyl-silane; potassium carbonate In acetonitrile at 20℃; for 2h;97%
With montmorillonite K10 In tetrahydrofuran at 25℃; Solvent; Reagent/catalyst; Molecular sieve;97%
With 1H-imidazole; iron(III) chloride In water at 20℃; for 0.25h; Inert atmosphere;65%
iPr(PNP)*Rh(Ph)

iPr(PNP)*Rh(Ph)

bis(pinacol)diborane
73183-34-3

bis(pinacol)diborane

A

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

C25H47BNO2P2Rh(1+)

C25H47BNO2P2Rh(1+)

Conditions
ConditionsYield
In benzene-d6 at 150℃; for 4h; Sealed tube; Inert atmosphere;A 97%
B 93%
iodobenzene
591-50-4

iodobenzene

4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane
25015-63-8

4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

Conditions
ConditionsYield
With (C2H5)3N; [Pd(2,6-bis(2,5-diphenylphospholyl-1-methyl)pyridine)Cl][BF4] In 1,4-dioxane (N2 or Ar); heated at 80°C for 48 h; evapd., Et2O added, filtered, washed (ether), evapd., chromd. (hexanes/Et3N-treated silica gel, hexanes);96%
With triethylamine; bis(diphosphaferrocene)PdCl2 dimer In 1,4-dioxane at 80℃; for 144h;95%
With triethylamine; ς4,λ5-phosphinine palladium In 1,4-dioxane; toluene at 80℃; for 15h; Myaura cross-coupling reaction;95%
benzenediazonium tetrafluoroborate
369-57-3

benzenediazonium tetrafluoroborate

bis(pinacol)diborane
73183-34-3

bis(pinacol)diborane

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

Conditions
ConditionsYield
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride In methanol at 20 - 40℃; for 3h; Condensation;96%
With 1,3-bis[(2,6-diisopropyl)phenyl]imidazolinium chloride; palladium diacetate In tetrahydrofuran at 20℃; for 1.5h;87%
With zinc(II) perchlorate In methanol at 40℃; Catalytic behavior; Reagent/catalyst; Solvent; Inert atmosphere;80%
phenylmagnesium bromide
100-58-3

phenylmagnesium bromide

4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane
25015-63-8

4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

Conditions
ConditionsYield
In tetrahydrofuran at 25℃; for 1h; Inert atmosphere;96%
1-benzoylpyrrolidine-2,5-dione
6343-27-7

1-benzoylpyrrolidine-2,5-dione

bis(pinacol)diborane
73183-34-3

bis(pinacol)diborane

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

Conditions
ConditionsYield
With Wilkinson's catalyst In toluene at 160℃; for 15h; Inert atmosphere;96%
bis(pinacol)diborane
73183-34-3

bis(pinacol)diborane

benzene
71-43-2

benzene

A

benzene-1,4-diboronic acid bispinacol ester
99770-93-1

benzene-1,4-diboronic acid bispinacol ester

B

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

Conditions
ConditionsYield
With [2,2]bipyridinyl; bis(1,5-cyclooctadiene)diiridium(I) dichloride In neat (no solvent) at 80°C for 16 h;A 1%
B 95%
2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
61676-62-8

2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

phenylmagnesium bromide
100-58-3

phenylmagnesium bromide

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 2h; Inert atmosphere;95%
benzoic acid
65-85-0

benzoic acid

bis(pinacol)diborane
73183-34-3

bis(pinacol)diborane

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

Conditions
ConditionsYield
With palladium diacetate; 2,2-dimethylpropanoic anhydride; triethylamine; 1,4-di(diphenylphosphino)-butane In 1,4-dioxane at 160℃; for 15h; Catalytic behavior; Reagent/catalyst;95%
With palladium diacetate; 2,2-dimethylpropanoic anhydride; triethylamine; 1,4-di(diphenylphosphino)-butane In 1,4-dioxane at 160℃; for 15h;95%
With biphenyl; naphthalene-1,4-dicarbonitrile In water; acetonitrile at 30℃; for 6h; Wavelength; Inert atmosphere; UV-irradiation;55%
4-cyanophenylboronic acid pinacol ester
171364-82-2

4-cyanophenylboronic acid pinacol ester

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

Conditions
ConditionsYield
With chloro(1,5-cyclooctadiene)rhodium(I) dimer; tri-n-butyl phosphite; chlorotriisopropylsilane In ethyl-cyclohexane at 130℃; for 15h; Inert atmosphere;94%
With chloro(1,5-cyclooctadiene)rhodium(I) dimer; tri-n-butyl phosphite; chlorotriisopropylsilane In ethylcyclohexane at 130℃; for 15h; Inert atmosphere;94%
iodobenzene
591-50-4

iodobenzene

bis(pinacol)diborane
73183-34-3

bis(pinacol)diborane

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine; triphenylphosphine; bis(1,5-cyclooctadiene)nickel (0) In methanol at 20 - 30℃; Inert atmosphere;93%
With N-ethyl-N,N-diisopropylamine; triphenylphosphine; (1,5-cyclooctadiene)(cyclopentadienyl)nickel In methanol at 20 - 30℃; for 21h; Product distribution / selectivity; Inert atmosphere;93%
In acetonitrile at 15℃; for 4h; Microwave irradiation;90%
bromobenzene
108-86-1

bromobenzene

2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
61676-62-8

2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

Conditions
ConditionsYield
Stage #1: bromobenzene With n-butyllithium In tetrahydrofuran; hexane at 24℃; for 0.000861111h;
Stage #2: 2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane In tetrahydrofuran; hexane at 24℃; for 0.0025h;
92%
Stage #1: bromobenzene With n-butyllithium In tetrahydrofuran at -78 - -40℃;
Stage #2: 2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane In tetrahydrofuran
90%
Stage #1: bromobenzene With n-butyllithium In tetrahydrofuran at -78℃; for 0.5h;
Stage #2: 2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane In tetrahydrofuran
87%
2-(4-iodophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
73852-88-7

2-(4-iodophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

Conditions
ConditionsYield
With 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline bis[(2-diphenyl-phosphino)phenyl]ether copper(I) hexafluorophosphate; N-ethyl-N,N-diisopropylamine In acetonitrile at 20℃; for 16h; Inert atmosphere; Sealed tube; Irradiation;92%
With 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline bis[(2-diphenyl-phosphino)phenyl]ether copper(I) hexafluorophosphate; N-ethyl-N,N-diisopropylamine In acetonitrile at 20℃; for 16h; UV-irradiation;92%
With tetraethylammonium perchlorate; triethylamine In dimethyl sulfoxide at 20℃; for 12h; Electrolysis; Green chemistry;79%
fluorobenzene
462-06-6

fluorobenzene

bis(pinacol)diborane
73183-34-3

bis(pinacol)diborane

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

Conditions
ConditionsYield
With bis(1,5-cyclooctadiene)nickel (0); copper(l) iodide; cesium fluoride; tricyclohexylphosphine In toluene at 80℃; for 24h; Inert atmosphere;91%
With tetramethylammonium fluoride; 2-mercaptopyridine sodium salt In acetonitrile at 30 - 35℃; for 24h; Reagent/catalyst; Irradiation; Inert atmosphere;78%
With chlorobis(tricyclohexylphosphine)copper(I); cesium fluoride In toluene at 80℃; for 24h;71%
2,3-dimethyl-2,3-butane diol
76-09-5

2,3-dimethyl-2,3-butane diol

diisopropylamine borane
55124-35-1

diisopropylamine borane

phenylmagnesium bromide
100-58-3

phenylmagnesium bromide

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

Conditions
ConditionsYield
Stage #1: diisopropylamine borane; phenylmagnesium bromide In tetrahydrofuran at 20℃;
Stage #2: With methanol In tetrahydrofuran
Stage #3: 2,3-dimethyl-2,3-butane diol In tetrahydrofuran
91%
benzenesulfonyl chloride
98-09-9

benzenesulfonyl chloride

bis(pinacol)diborane
73183-34-3

bis(pinacol)diborane

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

Conditions
ConditionsYield
With 2,2'-azobis(N-cyclohexyl-2-methylpropionamidine) dihydrochloride In water at 80℃; for 8h; Temperature; Reagent/catalyst;90.8%
With 2,2'-azobis(2-methylpropionamidine) dihydrochloride In water at 50℃; for 10h; Temperature; Reagent/catalyst;88.1%
With dipotassium hydrogenphosphate In acetonitrile at 20℃; for 24h; UV-irradiation;65%
bromobenzene
108-86-1

bromobenzene

para-fluorostyrene
405-99-2

para-fluorostyrene

bis(pinacol)diborane
73183-34-3

bis(pinacol)diborane

A

2-(2-(4-fluorophenyl)-2-phenylethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
1609554-37-1

2-(2-(4-fluorophenyl)-2-phenylethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

B

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

Conditions
ConditionsYield
With (1,3-dimesitylimidazolidin-2-yl)copper(I) chloride; methanesulfonic acid(2-dicyclohexylphosphino-2′,4′,6′-triisopropyl-1,1′-biphenyl)[2-(2′-amino-1,1′-biphenyl)]palladium(II); sodium t-butanolate In toluene at 22℃; for 6h; Glovebox; Inert atmosphere;A 90%
B 8%
bromobenzene
108-86-1

bromobenzene

1-methyl-2-vinyl-benzene
611-15-4

1-methyl-2-vinyl-benzene

bis(pinacol)diborane
73183-34-3

bis(pinacol)diborane

A

[2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1-o-tolylethyl]benzene

[2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1-o-tolylethyl]benzene

B

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

Conditions
ConditionsYield
With (1,3-dimesitylimidazolidin-2-yl)copper(I) chloride; methanesulfonic acid(2-dicyclohexylphosphino-2′,4′,6′-triisopropyl-1,1′-biphenyl)[2-(2′-amino-1,1′-biphenyl)]palladium(II); sodium t-butanolate In toluene at 22℃; for 6h; Glovebox; Inert atmosphere;A 90%
B 5.5%
1-(benzoyl)piperidine-2,6-dione

1-(benzoyl)piperidine-2,6-dione

bis(pinacol)diborane
73183-34-3

bis(pinacol)diborane

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

Conditions
ConditionsYield
With Wilkinson's catalyst In toluene at 160℃; for 15h; Catalytic behavior; Reagent/catalyst; Temperature; Inert atmosphere;90%
aniline
62-53-3

aniline

bis(pinacol)diborane
73183-34-3

bis(pinacol)diborane

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

Conditions
ConditionsYield
With tert.-butylnitrite; eosin In acetonitrile at 20℃; for 2h; Irradiation;88%
With tert-butyl nitrite; benzoyl peroxide In acetonitrile aniline (1 mmol), B2pin2, tBuONO (in 1:1.1:1.5 molar ratio) and 2,2'-azobisisobutyronitrile (2 mol%) mixed in MeCN, stirred at room temp. for 3 h; soln. concd. (under reduced pressure), residue chromd.;77%
With tert-butyl nitrite; benzoyl peroxide In acetonitrile aniline (1 mmol), B2pin2, tBuONO (in 1:1.1:1.5 molar ratio) and 2,2'-azobisisobutyronitrile (5 mol%) mixed in MeCN, stirred at room temp. for 3 h; soln. concd. (under reduced pressure), residue chromd.;70%
3,3-diethyl-1-phenyltriaz-1-ene
13056-98-9

3,3-diethyl-1-phenyltriaz-1-ene

bis(pinacol)diborane
73183-34-3

bis(pinacol)diborane

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

Conditions
ConditionsYield
With zinc(II) perchlorate; trifluorormethanesulfonic acid In methanol at 60℃;88%
phenyltrimethylammonium iodide
98-04-4

phenyltrimethylammonium iodide

bis(pinacol)diborane
73183-34-3

bis(pinacol)diborane

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

Conditions
ConditionsYield
With 10H-phenothiazine; caesium carbonate In acetonitrile for 18h; Wavelength; Irradiation; Sealed tube; Inert atmosphere;88%
2,3-dimethyl-2,3-butane diol
76-09-5

2,3-dimethyl-2,3-butane diol

2-phenyl[1,3,2]dioxaborolane
4406-72-8

2-phenyl[1,3,2]dioxaborolane

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

Conditions
ConditionsYield
In chloroform-d1 Kinetics; byproducts: HOCH2CH2OH; inder inert atm., at 25°C, for 94 h, in NMR tube; monitoring by (1)H NMR;87.8%
In chloroform-d1 at 25℃; for 94h; Product distribution; Further Variations:; Reaction partners; reaction time;
With boron trifluoride diethyl etherate In chloroform-d1 at 20℃; Reagent/catalyst;
2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

phenylboronic acid
98-80-6

phenylboronic acid

Conditions
ConditionsYield
Stage #1: 2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole With potassium hydrogen difluoride In methanol at 20℃; for 0.25h;
Stage #2: With lithium hydroxide In acetonitrile at 20℃; for 20h;
100%
With hydrogenchloride In water at 20℃; for 15h;100%
With polystyrene boronic acid; trifluoroacetic acid In acetonitrile for 18h; Heating;98%
Multi-step reaction with 2 steps
1: diethyl ether / 0.5 h / 20 °C
2: hydrogenchloride / water / 0.33 h
View Scheme
With dimyristoylphosphatidylcholine; water In dimethyl sulfoxide at 20℃; for 168h;
2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

phenol
108-95-2

phenol

Conditions
ConditionsYield
With urea hydrogen peroxide adduct In methanol at 27 - 29℃; for 0.25h; Green chemistry; chemoselective reaction;100%
With dihydrogen peroxide; 1-butyl-3-methylimidazolium chloride In water at 20℃; for 0.5h; Green chemistry;97%
With water; 3-chloro-benzenecarboperoxoic acid In ethanol at 20℃; for 6h;96%
(4E,6Z,8S,9S,10E,12S,13R,14S,16R)-13-hydroxy-21-iodo-8,14,19-trimethoxy-4,10,12,16-tetramethyl-3,20,22-trioxo-2-azabicyclo[16.3.1]docosa-1(21),4, 6,10,18-pentaen-9-yl carbamate
75747-28-3

(4E,6Z,8S,9S,10E,12S,13R,14S,16R)-13-hydroxy-21-iodo-8,14,19-trimethoxy-4,10,12,16-tetramethyl-3,20,22-trioxo-2-azabicyclo[16.3.1]docosa-1(21),4, 6,10,18-pentaen-9-yl carbamate

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

(4E,6Z,8S,9S,10E,12S,13R,14S,16R)-13-hydroxy-8,14,19-trimethoxy-10,12,16,21-pentamethyl-3,20,22-trioxo-2-azabicyclo[16.3.1]docosa-1(21),4, 6,10,18-pentaen-9-yl carbamate
1427296-91-0

(4E,6Z,8S,9S,10E,12S,13R,14S,16R)-13-hydroxy-8,14,19-trimethoxy-10,12,16,21-pentamethyl-3,20,22-trioxo-2-azabicyclo[16.3.1]docosa-1(21),4, 6,10,18-pentaen-9-yl carbamate

Conditions
ConditionsYield
With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; cesium fluoride In 1,4-dioxane; water at 40℃; for 16h; Inert atmosphere;100%
With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; cesium fluoride In 1,4-dioxane; water at 40℃; for 16h; Suzuki-Miyaura Coupling;100%
3,6-dibromo-9,10-bis(octyloxy)phenanthrene
1425053-94-6

3,6-dibromo-9,10-bis(octyloxy)phenanthrene

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

C42H50O2

C42H50O2

Conditions
ConditionsYield
With bis(tri-t-butylphosphine)palladium(0); potassium carbonate In tetrahydrofuran; water Suzuki-Miyaura Coupling; Schlenk technique; Inert atmosphere;100%
(4-chloro-phenyl)-acetic acid methyl ester
52449-43-1

(4-chloro-phenyl)-acetic acid methyl ester

C10H8BBrNO4

C10H8BBrNO4

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

2-(biphenyl-4-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
144432-80-4

2-(biphenyl-4-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Conditions
ConditionsYield
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium phosphate In tetrahydrofuran; water at 90℃; for 24h; Suzuki-Miyaura Coupling; chemoselective reaction;100%
2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

2,6-dichloro-3-iodopyrazine
136866-30-3

2,6-dichloro-3-iodopyrazine

2,6-dichloro-3-phenylpyrazine
64163-11-7

2,6-dichloro-3-phenylpyrazine

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); tricyclohexylphosphine In water; toluene at 100℃; for 15h; Inert atmosphere;100%
2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

4-bromo-3,5-diisopropyl-1-(p-toluenesulfonyl)pyrazole

4-bromo-3,5-diisopropyl-1-(p-toluenesulfonyl)pyrazole

A

biphenyl
92-52-4

biphenyl

B

4-phenyl-3,5-diisopropyl-1-(p-toluenesulfonyl)pyrazole

4-phenyl-3,5-diisopropyl-1-(p-toluenesulfonyl)pyrazole

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In 1,2-dimethoxyethane; water Suzuki-Miyaura Coupling; Inert atmosphere; Schlenk technique; Reflux;A 45%
B 100%
2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

ethyl 2-(4-bromo-2-fluorophenyl)-7-chloropyrazolo[1,5-a]pyrimidine-5-carboxylate

ethyl 2-(4-bromo-2-fluorophenyl)-7-chloropyrazolo[1,5-a]pyrimidine-5-carboxylate

ethyl 2-(4-bromo-2-fluorophenyl)-7-phenylpyrazolo[1,5-a]pyrimidine-5-carboxylate

ethyl 2-(4-bromo-2-fluorophenyl)-7-phenylpyrazolo[1,5-a]pyrimidine-5-carboxylate

Conditions
ConditionsYield
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; potassium carbonate In tetrahydrofuran; water at 70℃; for 18h; Inert atmosphere;100%
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; potassium carbonate In tetrahydrofuran; water at 70℃; for 4h; Inert atmosphere;
2-Iodothiophene
3437-95-4

2-Iodothiophene

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

2-phenylthiophene
825-55-8

2-phenylthiophene

Conditions
ConditionsYield
With potassium carbonate In methanol at 60℃; for 1h; Suzuki-Miyaura Coupling;99.8%
1-bromo-4-methoxy-benzene
104-92-7

1-bromo-4-methoxy-benzene

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

4-methoxylbiphenyl
613-37-6

4-methoxylbiphenyl

Conditions
ConditionsYield
With potassium carbonate In water at 20℃; for 6h; Reagent/catalyst; Solvent; Time; Concentration; Suzuki-Miyaura Coupling;99%
With sodium phosphate; palladium on activated charcoal In water; isopropyl alcohol at 20℃; for 24h; Suzuki-Miyaura cross-coupling;96%
With trans-dichlorido-(1,3-bis(2-ethoxy-2-oxopropyl)-imidazol-2-ylidine)(pyridine)palladium(II); tetrabutylammomium bromide; potassium carbonate In water at 60℃; for 24h; Suzuki-Miyaura Coupling;87%
2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

para-bromoacetophenone
99-90-1

para-bromoacetophenone

biphenyl-4-acetaldehyde
92-91-1

biphenyl-4-acetaldehyde

Conditions
ConditionsYield
With caesium carbonate In methanol at 60℃; for 24h; Suzuki-Miyaura reaction; Inert atmosphere;99%
With potassium carbonate In water; N,N-dimethyl-formamide at 80℃; Suzuki-Miyaura cross-coupling reaction; Inert atmosphere;99%
With potassium phosphate; (C5H5FeC5H3C(CH3)NC6H4CH3)PdCl(tricyclohexylphosphine); potassium acetate In 1,4-dioxane; water at 100℃; for 3h; Suzuki coupling; Inert atmosphere;92%
cycloheptyl bromide
2404-35-5

cycloheptyl bromide

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

phenylcycloheptane
4401-18-7

phenylcycloheptane

Conditions
ConditionsYield
Stage #1: 2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole With tert.-butyl lithium In tetrahydrofuran; pentane at -40 - 0℃; for 1h; Inert atmosphere;
Stage #2: cycloheptyl bromide With dichloro(1,2-{bis[3,5-bis(trimethylsilyl)pheny]phosphino-κP}benzene)iron(II); magnesium bromide In tetrahydrofuran at 0 - 40℃; Suzuki-Miyaura coupling; Inert atmosphere;
99%
With C25H33Cl2FeLiN2*0.75C4H8O; lithium ethylmethyl amide In benzene at 20℃; for 24h; Catalytic behavior; Reagent/catalyst; Concentration; Solvent; Suzuki-Miyaura Coupling; Glovebox; Inert atmosphere;95%
With 2,2-bis((S)-4-phenyl-4,5-dihydrooxazol-2-yl)acetonitrile; (2,2-bis((S)-4-phenyl-4,5-dihydrooxazol-2-yl)acetonitrile)FeCl; lithium ethylmethyl amide In benzene for 48.25h; Catalytic behavior; Reagent/catalyst; Solvent; Suzuki-Miyaura Coupling; Inert atmosphere; Sealed tube;80%
3-Bromopyridine
626-55-1

3-Bromopyridine

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

3-phenylpyridine
1008-88-4

3-phenylpyridine

Conditions
ConditionsYield
With potassium carbonate In water at 20℃; for 6h; Suzuki-Miyaura Coupling;99%
With potassium carbonate In ethanol; water at 20℃; Suzuki-Miyaura Coupling; Green chemistry;85%
With potassium phosphate; (C5H5FeC5H3C(CH3)NC6H4CH3)PdCl(tricyclohexylphosphine); potassium acetate In 1,4-dioxane; water at 100℃; for 15h; Suzuki coupling; Inert atmosphere;78%
With palladium diacetate; caesium carbonate In methanol; toluene at 60℃; for 10h; Suzuki coupling;71%
With sodium carbonate In water at 120℃; for 0.5h; Irradiation;40 mg
chloro(1,3-bis(2,6-di-i-propylphenyl)imidazol-2-ylidene)gold(I)

chloro(1,3-bis(2,6-di-i-propylphenyl)imidazol-2-ylidene)gold(I)

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

(1,3-bis(2,6-diisopropylphenyl)-1,3-dihydro-2H-imidazol-2-ylidene)phenylgold

(1,3-bis(2,6-diisopropylphenyl)-1,3-dihydro-2H-imidazol-2-ylidene)phenylgold

Conditions
ConditionsYield
With potassium hydroxide In toluene at 50℃; for 2h;99%
para-bromotoluene
106-38-7

para-bromotoluene

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

4-Methylbiphenyl
644-08-6

4-Methylbiphenyl

Conditions
ConditionsYield
With potassium carbonate In water at 20℃; for 6h; Suzuki-Miyaura Coupling;99%
With C17H36ClN6NiP2(1+)*Cl(1-) In toluene for 16h; Suzuki-Miyaura Coupling; Alkaline conditions; Inert atmosphere; Heating;97%
With hydrogenchloride; potassium carbonate In water; N,N-dimethyl-formamide at 95℃; pH=10.6; Suzuki-Miyaura Coupling; Inert atmosphere;
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In propan-1-ol; water at 100℃; for 0.5h; Temperature; Suzuki-Miyaura Coupling; Inert atmosphere;95 %Chromat.
3-Bromothiophene
872-31-1

3-Bromothiophene

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

3-phenylthiophene
2404-87-7

3-phenylthiophene

Conditions
ConditionsYield
With potassium carbonate In water at 20℃; for 6h; Suzuki-Miyaura Coupling;99%
2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

4-chlorobenzaldehyde
104-88-1

4-chlorobenzaldehyde

4-Phenylbenzaldehyde
3218-36-8

4-Phenylbenzaldehyde

Conditions
ConditionsYield
With potassium carbonate In water at 20℃; for 6h; Suzuki-Miyaura Coupling;99%
1-(m-tolyl)pyrazole
850380-23-3

1-(m-tolyl)pyrazole

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

1-(4-methyl[1,1'-biphenyl]-2-yl)-1H-pyrazole

1-(4-methyl[1,1'-biphenyl]-2-yl)-1H-pyrazole

Conditions
ConditionsYield
Stage #1: 2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole With (2-methylpropyl)lithium In tetrahydrofuran; cyclohexane at -78 - 20℃; for 0.5h; Inert atmosphere;
Stage #2: 1-(m-tolyl)pyrazole With iron(III)-acetylacetonate; ZnBr2*C6H16N2; cis-1,2-bis-(diphenylphosphino)ethene In tetrahydrofuran; cyclohexane at 20℃; for 0.166667h; Inert atmosphere;
Stage #3: With 1,2-dichloro-2-methylpropane In tetrahydrofuran; cyclohexane at 30℃; Inert atmosphere;
99%
2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

N-benzyl-N-(tert-butoxycarbonyl)-benzamide
85909-02-0

N-benzyl-N-(tert-butoxycarbonyl)-benzamide

benzophenone
119-61-9

benzophenone

Conditions
ConditionsYield
With bis(1,5-cyclooctadiene)nickel (0); potassium phosphate; water; 1,3-bis(2,6-diisopropylphenyl)dihydroimidazol-2-ylidene In toluene at 50℃; for 24h; Reagent/catalyst; Suzuki-Miyaura Coupling;99%
With bis(1,5-cyclooctadiene)nickel (0); potassium phosphate; 1,3-bis(2,6-diisopropylphenyl)dihydroimidazol-2-ylidene In water; toluene at 50℃; for 24h; Reagent/catalyst; Temperature; Suzuki-Miyaura Coupling;96%
bromobenzene
108-86-1

bromobenzene

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

biphenyl
92-52-4

biphenyl

Conditions
ConditionsYield
With trans-dichlorido-(1,3-bis(2-ethoxy-2-oxopropyl)-imidazol-2-ylidine)(pyridine)palladium(II); tetrabutylammomium bromide; potassium carbonate In water at 60℃; for 24h; Suzuki-Miyaura Coupling;99%
With copper(ll) sulfate pentahydrate; C62H66N2O6; sodium citrate; sodium carbonate; potassium carbonate In ethanol; water at 20℃; for 8h; Suzuki-Miyaura Coupling; Irradiation; Green chemistry;72%
With caesium carbonate In water; N,N-dimethyl-formamide at 30℃; under 760.051 Torr; for 8h; Suzuki-Miyaura Coupling; Irradiation;62%
1-phenyl-3-phospholene 1-oxide
5186-73-2

1-phenyl-3-phospholene 1-oxide

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

(1S,3S)-1,3-diphenylphospholane 1-oxide

(1S,3S)-1,3-diphenylphospholane 1-oxide

Conditions
ConditionsYield
With chlorobis(cyclooctene)rhodium(I) dimer; potassium hydroxide; (R)-segphos In 1,4-dioxane; water at 25 - 80℃; for 16h; Reagent/catalyst; Inert atmosphere; Schlenk technique; Sealed tube; stereoselective reaction;99%
1-phenyl-3-phospholene 1-oxide
5186-73-2

1-phenyl-3-phospholene 1-oxide

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

A

(1S,3S)-1,3-diphenylphospholane 1-oxide

(1S,3S)-1,3-diphenylphospholane 1-oxide

B

(1R,3R)-1,3-diphenylphospholane 1-oxide

(1R,3R)-1,3-diphenylphospholane 1-oxide

Conditions
ConditionsYield
With chlorobis(cyclooctene)rhodium(I) dimer; (R)-(+)-2,2'bis(diphenylphosphino)-1,1'-binaphthalene; potassium hydroxide In 1,4-dioxane; water at 80℃; for 16h; Inert atmosphere; Schlenk technique; Sealed tube; stereoselective reaction;A 99%
B n/a
1-(4-(trifluoromethyl)phenyl)-3-phospholene-1-oxide

1-(4-(trifluoromethyl)phenyl)-3-phospholene-1-oxide

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

C17H16F3OP

C17H16F3OP

Conditions
ConditionsYield
With chlorobis(cyclooctene)rhodium(I) dimer; potassium hydroxide; (R)-segphos In 1,4-dioxane; water at 25 - 80℃; for 16h; Inert atmosphere; Schlenk technique; Sealed tube; stereoselective reaction;99%
2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

tert-butyl (2-allyl-4-fluorobenzoyl)(benzyl)carbamate

tert-butyl (2-allyl-4-fluorobenzoyl)(benzyl)carbamate

2-benzyl-5-fluoro-2,3-dihydro-1H-inden-1-one
1376129-52-0

2-benzyl-5-fluoro-2,3-dihydro-1H-inden-1-one

Conditions
ConditionsYield
With bis(1,5-cyclooctadiene)nickel (0); potassium phosphate; 1,3-bis(2,6-diisopropylphenyl)dihydroimidazol-2-ylidene In tetrahydrofuran; water at 60℃; Inert atmosphere;99%

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