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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to bene

High quality bromo pentafluoro benzene supplier in China

Cas:344-04-7

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

High Quality Bromopentafluorobenzene 344-04-7 Manufacturer

Cas:344-04-7

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

Bromopentafluorobenzene Manufacturer/High quality/Best price/In stock

Cas:344-04-7

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

Good quality Good price Promptly delivery Appearance:white powder Storage:dry dondition Package:According to the demand of customer Application:intermediate Transportation:According to the demand of customer Port:shanghai

344-04-7 Bromopentafluorobenzene

Cas:344-04-7

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Jinan Finer Chemical Co., Ltd

Product description: Product name Bromopentafluorobenzene CAS number 344-04-7 Assay ≥98% Appearance Colorless liquid Capacity 200mt/year Application Pharmaceutical/Pesticide/

Bromopentafluorobenzene

Cas:344-04-7

Min.Order:10 Gram

FOB Price: $12.0

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 2,3,4,5,6-Pentafluorobromobenzene

Cas:344-04-7

Min.Order:1

Negotiable

Type:Other

inquiry

Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Large Stock 99.0% Bromopentafluorobenzene 344-04-7 Producer

Cas:344-04-7

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

inquiry

Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new api, intermedi

Bromopentafluorobenzene

Cas:344-04-7

Min.Order:1 Kilogram

FOB Price: $5.0

Type:Manufacturers

inquiry

COLORCOM LTD.

Colorcom is a global leader in industrial chemical manufacturing and is continuously innovating and transforming to exceed client expectations and industry standards. Colorcom prides itself on superior customer and technical focus, while focusing on

Bromopentafluorobenzene

Cas:344-04-7

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Bromopentafluorobenzene

Cas:344-04-7

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Hebei yanxi chemical co.,LTD.

Hebei Yanxi Chemical Co., Ltd. is a professional research, development and production of lead acetate benzene acetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low car

2,3,4,5,6-Bromopentafluorobenzene

Cas:344-04-7

Min.Order:1 Metric Ton

FOB Price: $1.0 / 2.0

Type:Trading Company

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

Bromopentafluorobenzene,344-04-7

Cas:344-04-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

Bromopentafluorobenzene 344-04-7

Cas:344-04-7

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 344-04-7 with best quality

Cas:344-04-7

Min.Order:10 Gram

FOB Price: $146.0 / 176.0

Type:Trading Company

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

pentafluorobromobenzene

Cas:344-04-7

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Henan Sinotech Import&Export Corporation

Name Bromopentafluorobenzene CAS NO. 344-04-7 Molecular Formula C6BrF5 Molecular Weight 246.96 EINECS 206-449-0

Bromopentafluorobenzene

Cas:344-04-7

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Bromopentafluorobenzene 344-04-7

Cas:344-04-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

Bromopentafluorobenzene CAS:344-04-7 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic int

Bromopentafluorobenzene CAS:344-04-7

Cas:344-04-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Bromopentafluorobenzene

Cas:344-04-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:344-04-7

Cas:344-04-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Mojin Biotechnology Co.,Ltd

Product quality: Our company have high quality product , and also the product we have good manufacture . First of all, this product is of fine quality. Every finish should be checked by quality inspection system.And every one should be also tried

Bromopentafluorobenzene CAS 344-04-7

Cas:344-04-7

Min.Order:1 Metric Ton

FOB Price: $140.0 / 150.0

Type:Trading Company

inquiry

Lonwin Chemical Group Limited

Bromopentafluorobenzene CAS:344-04-7 Specification Product name Bromopentafluorobenzene CAS number 344-04-7 Assay ≥98% Appearance Colorless liquid Capacity 200mt/year Applic

Factory Supply Bromopentafluorobenzene

Cas:344-04-7

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures s

Bromopentafluorobenzene

Cas:344-04-7

Min.Order:1 Kilogram

FOB Price: $10.0 / 100.0

Type:Lab/Research institutions

inquiry

Triumph International Development Limilted

Triumph has the complete production of G- KG - MT service chain,we can make the new technology into productivity quickly in the research and development of new products. Main Service 1.Own made fine chemical products 2.Out sourcing and qua

Bromopentafluorobenzene

Cas:344-04-7

Min.Order:100 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Henan Kanbei Chemical Co.,LTD

1. Well-equipped, stable and high-quality raw material supply chain, to provide customers with the best quality products. 2.Strict quality inspection process and professional certificate testing to ensure the quality level of the final product. 3.E

hot sale BroMopentafluorobenzene

Cas:344-04-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

pentafluorobromobenzene

Cas:344-04-7

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

BROMOPENTAFLUOROBENZENE

Cas:344-04-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

Bromopentafluorobenzene

Cas:344-04-7

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Bromopentafluorobenzene

Cas:344-04-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality 2,3,4,5,6-Pentafluorobromobenzene

Cas:344-04-7

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Synthetic route

C6F9Si(1-)*C4H12N(1+)

C6F9Si(1-)*C4H12N(1+)

bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

Conditions
ConditionsYield
With bromine In diethylene glycol dimethyl ether at 10℃; for 0.0833333h;100%
Pentafluorobenzene
363-72-4

Pentafluorobenzene

bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

Conditions
ConditionsYield
With N-Bromosuccinimide; boron trifluoride at 20℃; for 1h;96%
With tris(pentafluorophenyl)borate; bromine; chlorine In chloroform at 30 - 35℃; for 2h; Reagent/catalyst; Solvent; Temperature; Large scale;93%
With aluminum (III) chloride; bromine at 45℃; for 18h;90.5%
trimethyl(pentafluorophenyl)silane
1206-46-8

trimethyl(pentafluorophenyl)silane

bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

Conditions
ConditionsYield
With bromine; cesium fluoride In acetonitrile at 20℃; for 3h;93%
2,3,5,6-tetrafluorothiophenol
769-40-4

2,3,5,6-tetrafluorothiophenol

A

1-bromo-2,3,5,6-tetrafluorobenzene
1559-88-2

1-bromo-2,3,5,6-tetrafluorobenzene

B

bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

Conditions
ConditionsYield
With bromine at 500 - 510℃;A 87%
B n/a
Hexafluorobenzene
392-56-3

Hexafluorobenzene

bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

Conditions
ConditionsYield
Stage #1: Hexafluorobenzene With iron(III)-acetylacetonate; ethylmagnesium bromide In tetrahydrofuran at -30℃; for 1.5h;
Stage #2: With bromine In tetrahydrofuran at -30 - 20℃;
83%
bromine
7726-95-6

bromine

pentafluorophenylmagnesium chloride
879-06-1

pentafluorophenylmagnesium chloride

bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

Conditions
ConditionsYield
In diethyl ether reaction at 20°C, 1 hour;;69%
In diethyl ether reaction at 20°C, 1 hour;;69%
bis(pentafluorophenyl) disulfide
1494-06-0

bis(pentafluorophenyl) disulfide

bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

Conditions
ConditionsYield
With bromine at 500℃;68%
C6F5NN(1+)*F(1-)=C6F5NNF

C6F5NN(1+)*F(1-)=C6F5NNF

copper(I) bromide
7787-70-4

copper(I) bromide

bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

Conditions
ConditionsYield
at 100°C in HBr;63%
at 100°C in HBr;63%
Pentafluorobenzene
363-72-4

Pentafluorobenzene

A

bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

B

3-H-pentafluoro-2,5-cyclohexadien-1-one
60890-52-0

3-H-pentafluoro-2,5-cyclohexadien-1-one

C

1,2,3,3,4,6,6-heptafluorocyclohexa-1,4-diene
773-53-5

1,2,3,3,4,6,6-heptafluorocyclohexa-1,4-diene

Conditions
ConditionsYield
With bromine trifluoride; antimony pentafluoride In fluorosulfonylchloride at -90 - -80℃; for 0.5h;A 57%
B 13%
C 9%
Pentafluorobenzene
363-72-4

Pentafluorobenzene

A

bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

B

1-H-heptafluoro-1,4-cyclohexadiene

1-H-heptafluoro-1,4-cyclohexadiene

C

1-bromoheptafluoro-1,4-cyclohexadiene
70557-89-0

1-bromoheptafluoro-1,4-cyclohexadiene

Conditions
ConditionsYield
With bromine trifluoride; boron trifluoride In fluorosulfonylchloride at -90 - -80℃; for 0.333333h; Title compound not separated from byproducts;A 47%
B 10 % Chromat.
C 10 % Chromat.
With bromine trifluoride; boron trifluoride In fluorosulfonylchloride at -90 - -80℃; for 0.333333h;A 47 % Chromat.
B 10%
C 10 % Chromat.
Pentafluorobenzene
363-72-4

Pentafluorobenzene

A

bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

B

3-H-pentafluoro-2,5-cyclohexadien-1-one
60890-52-0

3-H-pentafluoro-2,5-cyclohexadien-1-one

C

2,3,3,4,5,6,6-heptafluoro-1-bromo-cyclohexa-1,4-diene
57113-81-2

2,3,3,4,5,6,6-heptafluoro-1-bromo-cyclohexa-1,4-diene

Conditions
ConditionsYield
With bromine trifluoride; boron trifluoride In fluorosulfonylchloride at -90 - -80℃; for 0.333333h;A 46%
B 26%
C 10%
potassium perfluorophenyltrifluoroborate

potassium perfluorophenyltrifluoroborate

A

bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

B

2,3,3,4,5,6,6-heptafluoro-1-bromo-cyclohexa-1,4-diene
57113-81-2

2,3,3,4,5,6,6-heptafluoro-1-bromo-cyclohexa-1,4-diene

C

1-bromo nonafluoro cyclohexene
4933-59-9

1-bromo nonafluoro cyclohexene

D

bis(pentafluorophenyl)bromonium tetrafluoroborate

bis(pentafluorophenyl)bromonium tetrafluoroborate

Conditions
ConditionsYield
With bromine trifluoride; hydrogen fluoride at -40 - -30℃; Inert atmosphere;A 0.1 mmol
B 0.16 mmol
C 0.06 mmol
D 45%
perfluoropropylene
116-15-4

perfluoropropylene

pentafluorophenyl lithium
1076-44-4

pentafluorophenyl lithium

A

bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

B

cis-1-perfluoro(phenylpropylene)
37600-06-9

cis-1-perfluoro(phenylpropylene)

C

trans-1-perfluoro(phenylpropylene)
37600-07-0

trans-1-perfluoro(phenylpropylene)

Conditions
ConditionsYield
In diethyl ether byproducts: trans-perfluoro(α-(4-biphenyl)propylene); stream of dry argon between -80 and 50°C, keeping the mixt. at -70°Cfor 3 h, then acidifying with 10 % HCl at 10°C;A 5%
B 8%
C 40%
In diethyl ether
Pentafluorobenzene
363-72-4

Pentafluorobenzene

A

bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

B

3-H-pentafluoro-2,5-cyclohexadien-1-one
60890-52-0

3-H-pentafluoro-2,5-cyclohexadien-1-one

C

1,2,3,3,4,6,6-heptafluorocyclohexa-1,4-diene
773-53-5

1,2,3,3,4,6,6-heptafluorocyclohexa-1,4-diene

D

2,3,3,4,5,6,6-heptafluoro-1-bromo-cyclohexa-1,4-diene
57113-81-2

2,3,3,4,5,6,6-heptafluoro-1-bromo-cyclohexa-1,4-diene

Conditions
ConditionsYield
With bromine trifluoride; antimony pentafluoride In fluorosulfonylchloride at -90 - -80℃; for 0.5h;A 35%
B 1%
C 26%
D 17%
pentafluorophenyl hydrazine
828-73-9

pentafluorophenyl hydrazine

A

2,3,4,5,6-pentafluoroaniline
771-60-8

2,3,4,5,6-pentafluoroaniline

B

bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

Conditions
ConditionsYield
With bromine In ethanol with ethanolic Br2 soln. at -60°C (2 h);A 5%
B 24%
With Br2 In ethanol with ethanolic Br2 soln. at -60°C (2 h);A 5%
B 24%
tribromofluoromethane
353-54-8

tribromofluoromethane

A

Hexafluorobenzene
392-56-3

Hexafluorobenzene

B

1,2-difluorotetrabromoethane
594-79-6

1,2-difluorotetrabromoethane

C

bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

Conditions
ConditionsYield
at 630 - 640℃;
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

pentafluorphenylbrom(V)tetrafluorid
75822-05-8

pentafluorphenylbrom(V)tetrafluorid

A

trimethylsilyl fluoride
420-56-4

trimethylsilyl fluoride

B

bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

Conditions
ConditionsYield
In acetonitrile
2,3,4,5,6-pentafluoroaniline
771-60-8

2,3,4,5,6-pentafluoroaniline

A

bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

B

Pentafluorobenzene
363-72-4

Pentafluorobenzene

Conditions
ConditionsYield
With copper(I) bromide; sulfuric acid; copper(II) sulfate; potassium bromide; sodium nitrite; tetrakis[3,5-bis(trifluoromethyl)phenyl]borate anion 1) 0 deg C, dichloromethane, water 2) dichloromethane, water, 100 min, rt.; Yield given. Multistep reaction. Yields of byproduct given;
With copper(I) bromide; sulfuric acid; copper(II) sulfate; potassium bromide; sodium nitrite; tetrakis[3,5-bis(trifluoromethyl)phenyl]borate anion 1) 0 deg C, dichloromethane, water, 2) dichloromethane, water, 100 min, rt.; Yield given. Multistep reaction. Yields of byproduct given;
trimethyl(pentafluorophenyl)silane
1206-46-8

trimethyl(pentafluorophenyl)silane

A

bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

B

Pentafluorobenzene
363-72-4

Pentafluorobenzene

C

decafluorobiphenyl
434-90-2

decafluorobiphenyl

Conditions
ConditionsYield
With xenon difluoride; Bromoform; cesium fluoride In acetonitrile at 20 - 25℃; for 0.5h;A 25 % Chromat.
B 14 % Chromat.
C 1 % Chromat.
With xenon difluoride; Bromoform; cesium fluoride prototype reaction (oth. aryltrimethylsilanes);
pentafluorphenylbrom(V)tetrafluorid
75822-05-8

pentafluorphenylbrom(V)tetrafluorid

triphenylphosphine
603-35-0

triphenylphosphine

A

bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

B

triphenyldifluorophosphorane
845-64-7

triphenyldifluorophosphorane

Conditions
ConditionsYield
In acetonitrile at 0℃;
pentafluorphenylbrom(V)tetrafluorid
75822-05-8

pentafluorphenylbrom(V)tetrafluorid

tris(pentafluorophenyl)phosphine
1259-35-4

tris(pentafluorophenyl)phosphine

A

bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

B

difluorotris(pentafluorphenyl)phosphorane
22474-72-2, 54082-67-6

difluorotris(pentafluorphenyl)phosphorane

Conditions
ConditionsYield
In acetonitrile at 0℃;
1-chloro-2,3,4,5,6-pentafluorobenzene
344-07-0

1-chloro-2,3,4,5,6-pentafluorobenzene

bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

Conditions
ConditionsYield
With bromine In gaseous matrix at 40℃; Thermodynamic data; collision energy E(c);
trifluoro(pentafluorophenyl)silane
5272-26-4

trifluoro(pentafluorophenyl)silane

bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

Conditions
ConditionsYield
With aluminum tri-bromide; bromine at -20℃; for 76h;
Multi-step reaction with 2 steps
1: 76 percent / acetonitrile / 0.25 h / Ambient temperature
2: 100 percent / Br2 / bis-(2-methoxy-ethyl) ether / 0.08 h / 10 °C
View Scheme
trifluoro(pentafluorophenyl)silane
5272-26-4

trifluoro(pentafluorophenyl)silane

A

bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

B

Bromo-difluoro-pentafluorophenyl-silane

Bromo-difluoro-pentafluorophenyl-silane

Conditions
ConditionsYield
With bromine for 240h; Product distribution; Ambient temperature;
1-bromo-2,3,4,5-tetrafluorobenzene
1074-91-5

1-bromo-2,3,4,5-tetrafluorobenzene

A

bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

B

1-Bromo-2H-hexafluoro-1,4-cyclohexadiene

1-Bromo-2H-hexafluoro-1,4-cyclohexadiene

C

1-Bromo-2H-octafluorocyclohexene

1-Bromo-2H-octafluorocyclohexene

Conditions
ConditionsYield
With xenon difluoride; hydrogen fluoride for 0.416667h; Ambient temperature; Title compound not separated from byproducts;A 2 % Spectr.
B 29 % Spectr.
C 11 % Spectr.
iodotrifluoromethane
2314-97-8

iodotrifluoromethane

1-Bromo-2,3,4,5,6-pentafluoro-benzene

1-Bromo-2,3,4,5,6-pentafluoro-benzene

A

trifluoromethyl radical
2264-21-3

trifluoromethyl radical

B

bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

C

trifluoro-iodo-methane radical anion
2314-97-8

trifluoro-iodo-methane radical anion

Conditions
ConditionsYield
In gas at 36.9℃; Rate constant;
trimethyl(pentafluorophenyl)silane
1206-46-8

trimethyl(pentafluorophenyl)silane

A

trimethylsilyl bromide
2857-97-8

trimethylsilyl bromide

B

bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

Conditions
ConditionsYield
With aluminum tri-bromide; bromine -20 deg C -> rt., 15 min; Yield given;
di-(pentafluoro phenyl) dimethyl silane
10536-62-6

di-(pentafluoro phenyl) dimethyl silane

A

dimethyldibromosilane
4095-10-7

dimethyldibromosilane

B

bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

Conditions
ConditionsYield
With aluminum tri-bromide; bromine Ambient temperature; -20 deg C -> r.t., 15 min; Yield given;
di-(pentafluoro phenyl) dimethyl silane
10536-62-6

di-(pentafluoro phenyl) dimethyl silane

A

bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

B

Pentafluorobenzene
363-72-4

Pentafluorobenzene

C

Brom-dimethyl-pentafluorphenyl-silan
23761-73-1

Brom-dimethyl-pentafluorphenyl-silan

Conditions
ConditionsYield
With aluminum tri-bromide In various solvent(s) for 0.5h; Ambient temperature; Yield given. Yields of byproduct given;
pyridine
110-86-1

pyridine

dichloro(ethylenediamine)platinum(II)
14096-51-6

dichloro(ethylenediamine)platinum(II)

bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

[N,N'-bis(4-bromo-2,3,5,6-tetrafluorophenyl)ethane-1,2-diaminato]dipyridineplatinum(II)
108089-51-6

[N,N'-bis(4-bromo-2,3,5,6-tetrafluorophenyl)ethane-1,2-diaminato]dipyridineplatinum(II)

B

carbon dioxide
124-38-9

carbon dioxide

Conditions
ConditionsYield
With Tl2CO3 In pyridine N2-atmosphere; stirring (115°C, 1 h); evapn. (vac.), light petroleum addn., stirring (1 h), decanting, extg. (Me2CO), filtering, concg., light petroleum addn., crystn. on concg., re crystn. (Me2CO / light petroleum);A 60%
B 100%
With K2CO3 In pyridine N2-atmosphere; stirring (115°C, 1 h); evapn. (vac.), light petroleum addn., stirring (1 h), decanting, extg. (Me2CO), filtering, concg., light petroleum addn., crystn. on concg., re crystn. (Me2CO / light petroleum);A 26%
B 30%
bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

lithium tetrakis(pentafluorophenyl)borate
2797-28-6

lithium tetrakis(pentafluorophenyl)borate

Conditions
ConditionsYield
With n-butyllithium; carbon dioxide; boron trichloride In hexane; water; pentane99%
bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

diethylmagnesium
557-18-6

diethylmagnesium

bis-(pentafluoro phenyl) magnesium
17436-90-7

bis-(pentafluoro phenyl) magnesium

Conditions
ConditionsYield
In tetrahydrofuran reaction at 0°C;;99%
tetrahydrofuran
109-99-9

tetrahydrofuran

indium
7440-74-6

indium

bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

bromine
7726-95-6

bromine

bis(tetrahydrofuran)(pentafluorophenyl)indium dibromide
399511-25-2

bis(tetrahydrofuran)(pentafluorophenyl)indium dibromide

Conditions
ConditionsYield
In tetrahydrofuran99%
pyridine
110-86-1

pyridine

indium
7440-74-6

indium

bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

bromine
7726-95-6

bromine

bis(pyridine)(pentafluorophenyl)indium dibromide

bis(pyridine)(pentafluorophenyl)indium dibromide

Conditions
ConditionsYield
In dichloromethane99%
pyridine
110-86-1

pyridine

indium(I) bromide

indium(I) bromide

bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

bis(pyridine)(pentafluorophenyl)indium dibromide

bis(pyridine)(pentafluorophenyl)indium dibromide

Conditions
ConditionsYield
In dichloromethane elem. anal.;99%
bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

1-cyclobutyl-1-phenyl-methanone
5407-98-7

1-cyclobutyl-1-phenyl-methanone

C17H11F5O
1361052-41-6

C17H11F5O

Conditions
ConditionsYield
Stage #1: 1-cyclobutyl-1-phenyl-methanone With sodium hexamethyldisilazane In tetrahydrofuran; 1,4-dioxane for 0.0833333h; Inert atmosphere;
Stage #2: bromopentafluorobenzene In tetrahydrofuran; 1,4-dioxane for 0.25h; Inert atmosphere;
99%
tetrakis(trimethylphosphine)iron(0)
63835-22-3

tetrakis(trimethylphosphine)iron(0)

bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

C18H41BrFeP4

C18H41BrFeP4

Conditions
ConditionsYield
In diethyl ether at 20℃; for 3h; Inert atmosphere;99%
bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

tert-butyl (1R,5R)-8-oxo-10-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1,5,6,8-tetrahydro-2H-1,5-methanopyrido[1,2-a][1,5]diazocine-3(4H)-carboxylate

tert-butyl (1R,5R)-8-oxo-10-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1,5,6,8-tetrahydro-2H-1,5-methanopyrido[1,2-a][1,5]diazocine-3(4H)-carboxylate

N-Boc 10-(perfluorophenyl)cytisine

N-Boc 10-(perfluorophenyl)cytisine

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; caesium carbonate In tetrahydrofuran for 18h; Inert atmosphere; Reflux;99%
With bis-triphenylphosphine-palladium(II) chloride; caesium carbonate In tetrahydrofuran at 80℃; for 18h;
styrene
292638-84-7

styrene

bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

(E)-1,2,3,4,5-pentafluoro-6-styrylbenzene
80365-31-7, 19292-25-2

(E)-1,2,3,4,5-pentafluoro-6-styrylbenzene

Conditions
ConditionsYield
With (NBu4)2[Pd2(μ-Br)2(C6F5)2Br2]; calcium carbonate In 1-methyl-pyrrolidin-2-one; water at 130℃; for 24h; Heck reaction;98%
With 1,3-bis(2-(diphenylphosphinomethyl)-phenyl)benzene*PdCl2; potassium carbonate In N,N-dimethyl-formamide at 120℃; for 25h; Heck coupling;67 % Chromat.
bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

ethylmagnesium bromide
925-90-6

ethylmagnesium bromide

2,3,4,5,6-pentafluorophenylmagnesium bromide
879-05-0

2,3,4,5,6-pentafluorophenylmagnesium bromide

Conditions
ConditionsYield
In tetrahydrofuran reaction at 0°C;;98%
In diethyl ether
In di-isopropyl ether
bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

tin(IV) chloride
7646-78-8

tin(IV) chloride

(C6F5)2Sn(CH2CHCH2)2

(C6F5)2Sn(CH2CHCH2)2

Conditions
ConditionsYield
With magnesium In diethyl ether Ar-atmosphere; addn. of 1 equiv. of SnCl4 to tetraallyltin at -50°C, warming to 0°C, dropwise addn. of excess of Grignard reagent (prepd. from Mg and C6F5Br), stirring (room temp., 38-75 h); filtration (celite), chromy. (SiO2, hexane), evapn., chromy. (SiO2, hexane); elem. anal.;98%
tetrahydrofuran
109-99-9

tetrahydrofuran

indium(I) bromide

indium(I) bromide

bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

bis(tetrahydrofuran)(pentafluorophenyl)indium dibromide
399511-25-2

bis(tetrahydrofuran)(pentafluorophenyl)indium dibromide

Conditions
ConditionsYield
In tetrahydrofuran InBr suspended in THF, C6F5Br added, stirred for 16 h at ambient temp.; volatile distilled off in vac. at ambient temp.; elem. anal.;98%
bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

1,1,3,3-tetramethylbutane isonitrile
14542-93-9

1,1,3,3-tetramethylbutane isonitrile

2-(trimethylsilyl)phenyl trifluoromethanesulfonate
88284-48-4

2-(trimethylsilyl)phenyl trifluoromethanesulfonate

N-[(2-bromophenyl)(pentafluorophenyl)methylene]-tert-octylamine
1352657-86-3

N-[(2-bromophenyl)(pentafluorophenyl)methylene]-tert-octylamine

Conditions
ConditionsYield
With potassium fluoride; 18-crown-6 ether In 1,2-dimethoxyethane at 0℃; for 14h; Inert atmosphere; regioselective reaction;98%
potassium cyclopentadienyldicarbonyliron(0)

potassium cyclopentadienyldicarbonyliron(0)

bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

A

cyclopentadienyl iron(II) dicarbonyl dimer
38117-54-3

cyclopentadienyl iron(II) dicarbonyl dimer

B

p-HC6F4Fe(CO)2Cp
12110-35-9

p-HC6F4Fe(CO)2Cp

Conditions
ConditionsYield
With (C6H5)(C2H5)CHCN In tetrahydrofuran byproducts: C6F5H; at room temp. using Ph(Et)CHCN as radical trap; not isolated, detected by NMR;A 97%
B 3%
pyridine
110-86-1

pyridine

cis-(N,N-dimethyl-ethylenediamine)diiodoplatinum(II)
104034-36-8

cis-(N,N-dimethyl-ethylenediamine)diiodoplatinum(II)

thallous 2,3,5,6-tetrafluorobenzoate
75669-81-7

thallous 2,3,5,6-tetrafluorobenzoate

bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

c(N),d(N')-{N,N-dimethyl-N'-(4-bromo-2,3,5,6-tetrafluorophenyl)ethane-1,2-diaminato(1-)}-b-iodo-a-pyridineplatinum(II)
117533-85-4

c(N),d(N')-{N,N-dimethyl-N'-(4-bromo-2,3,5,6-tetrafluorophenyl)ethane-1,2-diaminato(1-)}-b-iodo-a-pyridineplatinum(II)

B

carbon dioxide
124-38-9

carbon dioxide

Conditions
ConditionsYield
In pyridine Heating under stirring (105-110°C, N2, 25 min).; Cooling, evapn. to dryness (vacuum), washed (light petroleum), dried, extn. with Me2CO, filtn. of TlI, evapn. to dryness, washed (cold EtOH), recrystn. (pyridine/H2O and ether/light petroleum), elem. anal.;A 27%
B 97%
bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

tribenzyltin(IV) chloride
3151-41-5

tribenzyltin(IV) chloride

(C6F5)Sn(CH2C6H5)3
221363-75-3

(C6F5)Sn(CH2C6H5)3

Conditions
ConditionsYield
With magnesium In tetrahydrofuran; diethyl ether Ar-atmosphere; mixing equimolar amts. of Mg and PhBr (in ether, 0°C), stirring for 2 h, dropwise addn. of Sn-compd. (in THF) to slight excess of Grignard reagent at 0°C, stirring (room temp., 63 h); filtration (celite), chromy. (SiO2, hexane), evapn., chromy. (SiO2, hexane); elem. anal.;97%
bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

trimethylsilylacetylene
1066-54-2

trimethylsilylacetylene

((trimethylsilyl)ethynyl)pentafluorobenzene
52168-00-0

((trimethylsilyl)ethynyl)pentafluorobenzene

Conditions
ConditionsYield
With copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); diisopropylamine In toluene at 80℃; for 19h; Inert atmosphere;96%
With bis(benzonitrile)palladium(II) dichloride; copper diacetate; diisopropylamine; triphenylphosphine 1.) RT, 1 h, 2.) reflux, 1 h;20%
With copper(l) iodide; diisopropylamine; triphenylphosphine; bis-triphenylphosphine-palladium(II) chloride
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; N-ethyl-N,N-diisopropylamine at 72℃; for 24h; Sonogashira Cross-Coupling; Inert atmosphere;
bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

4-Vinylphenylboronic acid
2156-04-9

4-Vinylphenylboronic acid

2,3,4,5,6-pentafluoro-4’-vinylbiphenyl

2,3,4,5,6-pentafluoro-4’-vinylbiphenyl

Conditions
ConditionsYield
With [Pd(η2-dibenzylideneacetone)(tris(o-tolyl)phosphine)2]; potassium carbonate In ethanol; water; toluene at 85℃; Suzuki-Miyaura Coupling; Inert atmosphere;96%
With bis(trisphenylphosphine)(dibenzylideneacetone)palladium(0); sodium carbonate In ethanol; toluene at 60 - 90℃; for 2 - 20h; Reagent/catalyst; Temperature; Time; Suzuki-Miyaura Coupling;92%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; toluene Heating;
Trimethyl borate
121-43-7

Trimethyl borate

bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

pentafluorophenylboronic acid
1582-24-7

pentafluorophenylboronic acid

Conditions
ConditionsYield
With n-butyllithium In tetrahydrofuran; hexane at -30℃; Temperature; Flow reactor;95.2%
Stage #1: bromopentafluorobenzene With ethylmagnesium bromide In octamethylcyclotetrasiloxane at 20℃; for 0.00972222h; Inert atmosphere;
Stage #2: Trimethyl borate In octamethylcyclotetrasiloxane at 10℃; for 0.0138889h; Solvent; Temperature; Reagent/catalyst; Inert atmosphere;
94.5%
With magnesium In diethyl ether Grignard-comp. prepd. from Br-compd. and Mg in ether was cooled with ice-water bath and added dropwise to 1.5 equiv. of pre-cooled (ice-water bath) soln. of B(OMe)3 in ether, stirring at 0-4 °C for 1 h; pouring into 5 % HCl, org. layer was sepd., aq. layer was extd. with ether, extracts were combined, dried with MgSO4, evapd. under vac., solid was recrystd. from hot toluene, elem. anal.;90%
Stage #1: bromopentafluorobenzene With magnesium In tetrahydrofuran at 40 - 45℃; for 5h; Inert atmosphere; Large scale;
Stage #2: Trimethyl borate In tetrahydrofuran at -5℃; for 2h; Inert atmosphere; Large scale;
Stage #3: With hydrogenchloride In tetrahydrofuran; water for 0.5h; Reagent/catalyst; Temperature; Solvent; Inert atmosphere; Large scale;
90.33%
bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

antimony(III) chloride
10025-91-9

antimony(III) chloride

tris(pentafluorophenyl)antimony
3910-39-2

tris(pentafluorophenyl)antimony

Conditions
ConditionsYield
Stage #1: bromopentafluorobenzene With n-butyllithium at -78℃; for 0.25h;
Stage #2: antimony(III) chloride at -78 - 20℃; for 2h;
95%
With magnesium In diethyl ether at -10 - 20℃; for 2h; Heating / reflux;65%
bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

dimethyltin dichloride
753-73-1

dimethyltin dichloride

dimethylbis(pentafluorophenyl)tin
801-79-6

dimethylbis(pentafluorophenyl)tin

Conditions
ConditionsYield
With BuLi; H2O In diethyl ether; hexane Ar-atmosphere; stirring (-78°C, 45 min), Sn-compd. addn., stirring (-78°C, 15 min, room temp., 12 h), wet hexanes addn.; evapn. (reduced pressure), extg. (hexanes), evapn., distg. (reduced pressure);95%
Stage #1: bromopentafluorobenzene With iodine; magnesium In diethyl ether for 4h; Heating / reflux;
Stage #2: dimethyltin dichloride In diethyl ether at 0 - 20℃;
90%
bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

boron trifluoride diethyl etherate
109-63-7

boron trifluoride diethyl etherate

tris(pentafluorophenyl)borate
1109-15-5

tris(pentafluorophenyl)borate

Conditions
ConditionsYield
Stage #1: bromopentafluorobenzene With magnesium In diethyl ether at 20℃;
Stage #2: boron trifluoride diethyl etherate In toluene at 0℃; for 1h; Schlenk technique; Inert atmosphere;
Stage #3: In diethyl ether; toluene at 100℃; for 1h; Schlenk technique; Inert atmosphere;
95%
Stage #1: bromopentafluorobenzene With magnesium In diethyl ether for 1h; Reflux;
Stage #2: boron trifluoride diethyl etherate In toluene at 100℃; for 1h;
88%
Stage #1: bromopentafluorobenzene With magnesium In diethyl ether at 20℃; for 1h; Inert atmosphere;
Stage #2: boron trifluoride diethyl etherate In toluene at 100℃; for 1h; Inert atmosphere;
88%
bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

1-(4-vinylbenzyl)-1H-imidazole
78430-91-8

1-(4-vinylbenzyl)-1H-imidazole

1-(4-ethenylbenzyl)-3-(pentafluorobenzyl)-1H-imidazol-3-ium bromide

1-(4-ethenylbenzyl)-3-(pentafluorobenzyl)-1H-imidazol-3-ium bromide

Conditions
ConditionsYield
In acetonitrile at 60℃; for 2h; Inert atmosphere;95%
bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

naphthalene-2-boronic acid
32316-92-0

naphthalene-2-boronic acid

2-(2,3,4,5,6-pentafluorophenyl)naphthalene
52331-48-3

2-(2,3,4,5,6-pentafluorophenyl)naphthalene

Conditions
ConditionsYield
With potassium phosphate tribasic trihydrate; palladium diacetate; tricyclohexylphosphine In water; toluene for 12h; Inert atmosphere; Reflux;95%
bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

pentafluorophenyl lithium
1076-44-4

pentafluorophenyl lithium

Conditions
ConditionsYield
With n-butyllithium In diethyl ether; hexane at -78 - 20℃; for 2h; Inert atmosphere;94.3%
With n-butyllithium In hexane; Petroleum ether at -78℃; for 1h;
With p-tolyllithium In tetrahydrofuran at -70 - -55℃; for 1h;
bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

4,4'-Difluorobenzophenone
345-92-6

4,4'-Difluorobenzophenone

2,3,4,4',4'',5,6-heptafluoro-triphenylmethanol
241823-93-8

2,3,4,4',4'',5,6-heptafluoro-triphenylmethanol

Conditions
ConditionsYield
Stage #1: bromopentafluorobenzene With magnesium In diethyl ether Metallation;
Stage #2: 4,4'-Difluorobenzophenone In diethyl ether for 3h; Grignard reaction; Heating;
94%
bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

N-(2,4,6-tri-tert-butylphenyl)-N-trimethylsilylamino(dichloro)phosphane

N-(2,4,6-tri-tert-butylphenyl)-N-trimethylsilylamino(dichloro)phosphane

1,1-bis(pentafluorophenyl)-2,4-bis(2,4,6-tri-tert-butylphenyl)-1,3-diphospha-2,4-diazene
1309766-99-1

1,1-bis(pentafluorophenyl)-2,4-bis(2,4,6-tri-tert-butylphenyl)-1,3-diphospha-2,4-diazene

Conditions
ConditionsYield
Stage #1: bromopentafluorobenzene With n-butyllithium In diethyl ether at -80℃; for 0.25h;
Stage #2: N-(2,4,6-tri-tert-butylphenyl)-N-trimethylsilylamino(dichloro)phosphane In diethyl ether at -80℃;
93.4%
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