Triphenyltin chloride supplier

Name
Chlorotriphenyltin
EINECS 211-358-4
CAS No. 639-58-7
Article Data129
CAS DataBase
Density 1.49 g/cm3 (20oC)
Solubility insoluble
Melting Point 103-108 °C
Formula C₁₈H₁₅ClSn
Boiling Point 397.125 °C at 760 mmHg
Molecular Weight 385.48
Flash Point 199.683 °C
Transport Information UN 3146 6.1/PG 3
Appearance colourless solid
Safety 26-27-28-45-60-61-36/37/39
Risk Codes 23/24/25-50/53-34
Molecular Structure
Hazard Symbols T,N,C
Synonyms Triphenyltinchloride (6CI);Aquatin;Brestanol;Chlorotriphenylstannane;Chlorotriphenyltin;Fentin chloride;GC 8993;General Chemicals 8993;HOE 2872;LS 4442;NSC 1214;NSC 43675;TPTC;Triphenylchlorostannane;Triphenylchlorotin;Triphenylstannyl chloride;Triphenyltin monochloride;
PSA 0.00000
LogP 2.89230

Synthetic route

: 1135-99-5
diphenyltin(IV) dichloride

: 66224-66-6, 66224-67-7, 66224-68-8, 66224-69-9, 134434-48-3, 134434-49-4, 134454-76-5, 134461-75-9
adenine

A [SnCl2(C6H5)(OH)(C5H3N4NH2)2]*3H2O: [SnCl2(C6H5)(OH)(C5H3N4NH2)2]*3H2O

B: 639-58-7
triphenyltin chloride

Conditions

Conditions	Yield
In methanol refluxing under N2 for 96 h;; removal of volatiles by distn.; washing of the solid residue with etherin portions; ether extract afforded SnClPh3; elem. anal.;;	A 99% B n/a

...Expand

: 1135-99-5
diphenyltin(IV) dichloride

: 58-61-7
adenosine

A: [SnCl3(C6H5)(C5H2N4(C4H4O(OH)2CH2OH)NH2)2]

B: 639-58-7
triphenyltin chloride

Conditions

Conditions	Yield
In methanol refluxing under N2 for 48 h;; removal of volatiles by distn.; residue was washed with ether in portions; ether extract afforded SnClPh3; elem. anal.;;	A 99% B n/a

...Expand

: 56-23-5
tetrachloromethane

: 595-90-4
tetraphenyltin(IV)

: 639-58-7
triphenyltin chloride

Conditions

Conditions	Yield
With bismuth(III) chloride 5h boiling;	98%

: 595-90-4
tetraphenyltin(IV)

: 7646-78-8
tin(IV) chloride

: 639-58-7
triphenyltin chloride

Conditions

Conditions	Yield
Gallium trichloride	96%
Gallium trichloride	96%
In not given Kocheshkov redistribution reaction (K. A. Kocheshkov, M. M. Nadi and A. P. Aleksandrov Chem. Ber. 67 (1934) 1348;

: trans-{RhCl(CC(SnPh3)CH(Me)OH)(Pi-Pr3)2}

: 100-56-1
phenylmercury(II) chloride

A: {Rh(CCCH(CH3)OH)Cl(HgC6H5)(P(CH(CH3)2)3)2}

B: 639-58-7
triphenyltin chloride

Conditions

Conditions	Yield
In toluene under Ar, stirred for 30 min at room temp.; removal of solvent in vac., dissolved in benzene, addn. of pentane, filtered, filtrate concd. in vac., addn. of pentane, filtered, washed with pentane, dried in vac., recrystd. (toluene/pentane 1:10); elem. anal.;	A 96% B n/a

...Expand

: trans-{RhCl(CC(SnPh3)CH2OMe)(Pi-Pr3)2}

: 100-56-1
phenylmercury(II) chloride

: {Rh(CCCH2OCH3)Cl(HgC6H5)(P(CH(CH3)2)3)2}

B: 639-58-7
triphenyltin chloride

Conditions

Conditions	Yield
In toluene under Ar, stirred for 30 min at room temp.; concn. in vac., addn. of pentane, filtered, washed with toluene/pentane (1:5), filtrate brought to dryness in vac., dissolved in toluene/pentane (1:3), stored at -78°C, filtered, washed with pentane, dried in vac.; elem. anal.;	A 95% B n/a

...Expand

: trans-{RhCl(CC(SnPh3)CH(Ph)OH)(Pi-Pr3)2}

: 100-56-1
phenylmercury(II) chloride

A: {Rh(CCCH(C6H5)OH)Cl(HgC6H5)(P(CH(CH3)2)3)2}

B: 639-58-7
triphenyltin chloride

Conditions

Conditions	Yield
In toluene under Ar, stirred for 30 min at room temp.; removal of solvent in vac., dissolved in benzene, addn. of pentane, filtered, filtrate concd. in vac., addn. of pentane, filtered, washed with pentane, dried in vac., recrystd. (toluene/pentane 1:10); elem. anal.;	A 74% B n/a

...Expand

: trans-{RhCl(CC(SnPh3)2)(Pi-Pr3)2}

: 100-56-1
phenylmercury(II) chloride

A: {Rh(CCSn(C6H5)3)Cl(HgC6H5)(P(CH(CH3)2)3)2}

B: 639-58-7
triphenyltin chloride

Conditions

Conditions	Yield
In toluene under Ar, stirred for 30 min at room temp.; removal of solvent in vac., dissolved in benzene, addn. of pentane, filtered, filtrate concd. in vac., addn. of pentane, filtered, washed withpentane, dried in vac., recrystd. (benzene/pentane 1:2); elem. anal.;	A 72% B n/a

...Expand

: 7647-01-0
hydrogenchloride

: 1064-10-4
hexaphenylditin

: 7440-39-3
barium

A: 595-90-4
tetraphenyltin(IV)

B: 639-58-7
triphenyltin chloride

Conditions

Conditions	Yield
In tetrahydrofuran; diethyl ether; ammonia byproducts: BaCl2; NH3 (liquid); (N2); charging of Ba in dry box Schlenk tubes with (SnPh3)2; addn. of THF, cooling to -78°C; condensation of pre-dried liq. NH3 onto react. mixt., reflux for 6 h at -33°C; warming to room temp.; evapn. of NH3, addn. of 1N HCl soln. in Et2O; removal of volatiles in vac., dissolving in Et2O, filtration through Celite padded filter frit, removal of solvent;	A 2% B 70%

Yield

In tetrahydrofuran; diethyl ether; ammonia byproducts: BaCl2; NH3 (liquid); (N2); charging of Ba in dry box Schlenk tubes with (SnPh3)2; addn. of THF, cooling to -78°C; condensation of pre-dried liq. NH3 onto react. mixt., reflux for 6 h at -33°C; warming to room temp.; evapn. of NH3, addn. of 1N HCl soln. in Et2O; removal of volatiles in vac., dissolving in Et2O, filtration through Celite padded filter frit, removal of solvent;

A 2%
B 70%

...Expand

: 7647-01-0
hydrogenchloride

: 1064-10-4
hexaphenylditin

: 7440-70-2
calcium

A: 595-90-4
tetraphenyltin(IV)

B: 639-58-7
triphenyltin chloride

Conditions

Conditions	Yield
In tetrahydrofuran; diethyl ether; ammonia byproducts: CaCl2; NH3 (liquid); (N2); charging of Ca in dry box Schlenk tubes with (SnPh3)2; addn. of THF, cooling to -78°C; condensation of pre-dried liq. NH3 onto react. mixt., reflux for 6 h at -33°C; warming to room temp.; evapn. of NH3, addn. of 1N HCl soln. in Et2O; removal of volatiles in vac., dissolving in Et2O, filtration through Celite padded filter frit, removal of solvent;	A 2% B 70%

Yield

In tetrahydrofuran; diethyl ether; ammonia byproducts: CaCl2; NH3 (liquid); (N2); charging of Ca in dry box Schlenk tubes with (SnPh3)2; addn. of THF, cooling to -78°C; condensation of pre-dried liq. NH3 onto react. mixt., reflux for 6 h at -33°C; warming to room temp.; evapn. of NH3, addn. of 1N HCl soln. in Et2O; removal of volatiles in vac., dissolving in Et2O, filtration through Celite padded filter frit, removal of solvent;

A 2%
B 70%

...Expand

: 7647-01-0
hydrogenchloride

: 1064-10-4
hexaphenylditin

: strontium

A: 595-90-4
tetraphenyltin(IV)

B: 639-58-7
triphenyltin chloride

Conditions

Conditions	Yield
In tetrahydrofuran; diethyl ether; ammonia byproducts: SrCl2; NH3 (liquid); (N2); charging of Sr in dry box Schlenk tubes with (SnPh3)2; addn. of THF, cooling to -78°C; condensation of pre-dried liq. NH3 onto react. mixt., reflux for 6 h at -33°C; warming to room temp.; evapn. of NH3, addn. of 1N HCl soln. in Et2O; removal of volatiles in vac., dissolving in Et2O, filtration through Celite padded filter frit, removal of solvent;	A 2% B 70%

Yield

In tetrahydrofuran; diethyl ether; ammonia byproducts: SrCl2; NH3 (liquid); (N2); charging of Sr in dry box Schlenk tubes with (SnPh3)2; addn. of THF, cooling to -78°C; condensation of pre-dried liq. NH3 onto react. mixt., reflux for 6 h at -33°C; warming to room temp.; evapn. of NH3, addn. of 1N HCl soln. in Et2O; removal of volatiles in vac., dissolving in Et2O, filtration through Celite padded filter frit, removal of solvent;

A 2%
B 70%

...Expand

: 20637-89-2
pyridin2-2-thiolate-triphenyltin

: copper(l) chloride

: 639-58-7
triphenyltin chloride

Conditions

Conditions	Yield
In tetrahydrofuran (under Ar, Schlenk); CuCl added to soln. of Sn-complex in THF, stirred for 10 h at room temp.; solvent evapd., residue suspended in CH2Cl2/pentane, filtered, filtrate evapd.; monitored by NMR, IR;	70%

: 10026-04-7, 53609-55-5
tetrachlorosilane

: 595-90-4
tetraphenyltin(IV)

: 639-58-7
triphenyltin chloride

Conditions

Conditions	Yield
room temp.;	66%

: 183624-80-8, 156129-27-0, 159992-38-8, 131296-70-3
bis(triisopropylphosphane)(dihydrido)dichloroosmium(IV)

: 892-20-6
triphenylstannane

A: OsH4Cl(SnPh3)(P(i)Pr3)2

B: 639-58-7
triphenyltin chloride

Conditions

Conditions	Yield
In toluene under Ar atm. suspn. OsH2Cl2(P(i)Pr3)2 in toluene was treated with Ph3SnH and stirred for 2 h at room temp.; soln. was evapd., residue was washed with pentane and dried in vacuo; elem. anal.;	A 52% B n/a

...Expand

: 1231-17-0
triphenyl tin (1+); prop-1-yneide

A: 2809-69-0
2,4-hexadiyne

B: 639-58-7
triphenyltin chloride

Conditions

Conditions	Yield
With iron(III) chloride byproducts: FeCl2; for 2 h;	A 42% B 44%

: 1871-70-1
1-chloro-5,5-dimethyl-2-hexene

: 1954-39-8
triphenylstannyl isocyanate

A: 126560-07-4
3-Isocyanato-5,5-dimethyl-hex-1-ene

B: 639-58-7
triphenyltin chloride

Conditions

Conditions	Yield
at 180℃; for 3h; Product distribution;	A 37% B n/a

...Expand

: 29000-10-0
(E)-cinnamyl(triphenyl)stannane

A: 205485-72-9
(Z)-cinnamyl(triphenyl)stannane

B: 639-58-7
triphenyltin chloride

C: 19752-28-4, 161838-12-6
1-phenylprop-2-enyl(triphenyl)stannane

Conditions

Conditions	Yield
In chloroform Irradiation (UV/VIS); N2; Sn-compd. soln. irradiation with 300 W high-pressure Hg lamp throughsatd. aq. CuSO4 soln. for 1 h, solvent evapn. (reduced pressure); TLC(PLC) (hexane/DCM 9:1); total yield 55 %, E/Z ratio 53:47; elem. anal.;	A n/a B 30% C n/a

...Expand

: Na(MeCp(CO)2MnSnPh3)

: 2570-00-5
3,3-dichloro-1,2-diphenylcyclopropene

A: methylcyclopentadienyl manganese(I) tricarbonyl

B: MeCp(CO)2Mn(H)SiPh2Me

C: 112533-44-5
(η5-MeCp)(carbonyl)2Mn(1,2-diphenylcyclopropenylidene)

D: 639-58-7
triphenyltin chloride

Conditions

Conditions	Yield
In tetrahydrofuran byproducts: NaCl; Addn. of Cl2C(CPhCPh) soln. to soln. of Mn-complex at -20°C under N2, color changes immediately to red.; Filtn., concg., addn. of pentane to the filtrate, stirring (5 min), sepg. of dark red ppt., recrystn. (toluene/pentane), washing (pentane), drying in vac., elem. anal.;	A n/a B n/a C 25% D n/a

...Expand

: 67-66-3
chloroform

: 595-90-4
tetraphenyltin(IV)

A: 519-73-3
triphenylmethane

B: 639-58-7
triphenyltin chloride

Conditions

Conditions	Yield
at 260℃;

...Expand

: 74-87-3
methylene chloride

: 892-20-6
triphenylstannane

A: 34557-54-5
methane

B: 639-58-7
triphenyltin chloride

Conditions

Conditions	Yield
In hexane at 0℃; for 0.0166667h; Product distribution; (13)C Kinetic Isotope Effect k12/k13;

...Expand

: 962-89-0
triphenyltin bromide

: 100-44-7
benzyl chloride

A: 100-39-0
benzyl bromide

B: 639-58-7
triphenyltin chloride

Conditions

Conditions	Yield
With N-benzyl pyridinium halide In acetonitrile at 100℃; Equilibrium constant;

...Expand

: 110-18-9
N,N,N,N,-tetramethylethylenediamine

: 639-58-7
triphenyltin chloride

: 7440-66-6
zinc

: Ph3SnZnCl * N,N,N',N'-tetramethylethylenediamine

Conditions

Conditions	Yield
In acetonitrile; benzene Electrolysis; absence of oxygen and moisture; W-cathode, Zn suspended on Pt-anode, 30 V, 25 mA, 3.0 h, Et4NClO4 electrolyte; sepn. of pptd. product (further crop on addn. of petroleum ether), washing (petroleum ether), drying (vac.); elem. anal.;	100%

...Expand

: 639-58-7
triphenyltin chloride

: 4294-57-9
para-methylphenylmagnesium bromide

: 15807-28-0
triphenyl(p-tolyl)tin

Conditions

Conditions	Yield
In diethyl ether	100%
In tetrahydrofuran byproducts: MgBrCl; dropwise addn. of Mg-compd. to Sn-compd, refluxed for 5 h, hydrolysed with HCl; evapd., filtered, dried, extd. (toluene), recrystd. (EtOH/toluene); elem. anal.;	55%

: 33650-14-5
diethyl naphthalen-1-yl phosphate

: 639-58-7
triphenyltin chloride

: 81134-67-0
[1]naphthyl-triphenyl stannane

Conditions

Conditions	Yield
With sodium In ammonia Irradiation (UV/VIS); (C6H5)3SnCl was dissolved in ammonia, Na metal was added until a blue color persisted for 5 min, when the blue color dissapeared, phosphate ester was added, the mixt. was UV-irradiated with stirring for 4 h; excess of CH3I was added, NH3 was evapd., the residue was treated with water, extd. with ether, washed with aq. satd. soln. of NaCl, dried over MgSO4, recrystd. in ethanol;	100%

Yield

With sodium In ammonia Irradiation (UV/VIS); (C6H5)3SnCl was dissolved in ammonia, Na metal was added until a blue color persisted for 5 min, when the blue color dissapeared, phosphate ester was added, the mixt. was UV-irradiated with stirring for 4 h; excess of CH3I was added, NH3 was evapd., the residue was treated with water, extd. with ether, washed with aq. satd. soln. of NaCl, dried over MgSO4, recrystd. in ethanol;

100%

: 30897-86-0
2,5-dimethylphenylmagnesium bromide

: 639-58-7
triphenyltin chloride

: (2,5-dimethyl-phenyl)-triphenyl stannane

Conditions

Conditions	Yield
In diethyl ether	100%

: 639-58-7
triphenyltin chloride

: 703-55-9
1-naphthylmagnesiumbromide

: 81134-67-0
[1]naphthyl-triphenyl stannane

Conditions

Conditions	Yield
	100%
	100%
In diethyl ether; toluene reacting in ether; refluxing in toluene;

: 16498-01-4
O,O-diethyl O-4-bromophenyl phosphate

: 639-58-7
triphenyltin chloride

: 96872-40-1
1,4-bis(triphenylstannyl)benzene

Conditions

Yield

With sodium In ammonia Irradiation (UV/VIS); (C6H5)3SnCl was dissolved in ammonia, Na metal was added until a blue color persisted for 5 min, when the blue color dissapeared, phosphate ester was added, the mixt. was UV-irradiated with stirring for 1.5 h; excess of CH3I was added, NH3 was evapd., the residue was treated with water, extd. with ether, washed with aq. satd. soln. of NaCl, dried over MgSO4, recrystd. in ethanol;

100%

With sodium In ammonia (C6H5)3SnCl was dissolved in ammonia, Na metal was added until a blue color persisted for 5 min, when the blue color dissapeared, phosphate ester was added;

: 57246-14-7
Tetraethyl 1,4-phenylene bis(phosphate)

: 639-58-7
triphenyltin chloride

: 96872-40-1
1,4-bis(triphenylstannyl)benzene

Conditions

Conditions	Yield
With sodium In ammonia Irradiation (UV/VIS); (C6H5)3SnCl was dissolved in ammonia, Na metal was added until a blue color persisted for 5 min, when the blue color dissapeared, phosphate ester was added, the mixt. was UV-irradiated with stirring for 1.5 h; excess of CH3I was added, NH3 was evapd., the residue was treated with water, extd. with ether, washed with aq. satd. soln. of NaCl, dried over MgSO4, recrystd. in ethanol;	100%
With sodium In ammonia Irradiation (UV/VIS); (C6H5)3SnCl was dissolved in ammonia, Na metal was added until a blue color persisted for 5 min, when the blue color dissapeared, phosphate ester was added, the mixt. was UV-irradiated with stirring for 2 h; excess of CH3I was added, NH3 was evapd., the residue was treated with water, extd. with ether, washed with aq. satd. soln. of NaCl, dried over MgSO4, recrystd. in ethanol;	70%
With sodium In ammonia (C6H5)3SnCl was dissolved in ammonia, Na metal was added until a blue color persisted for 5 min, when the blue color dissapeared, phosphate ester was added;	0%

: 16519-26-9
diethyl naphthalen-2-yl phosphate

: 639-58-7
triphenyltin chloride

: 274928-10-8
(2-naphthyl)triphenylstannane

Conditions

Conditions	Yield
With sodium In ammonia Irradiation (UV/VIS); (C6H5)3SnCl was dissolved in ammonia, Na metal was added until a blue color persisted for 5 min, when the blue color dissapeared, phosphate ester was added, the mixt. was UV-irradiated with stirring for 4 h; excess of CH3I was added, NH3 was evapd., the residue was treated with water, extd. with ether, washed with aq. satd. soln. of NaCl, dried over MgSO4, recrystd. in ethanol;	100%

Yield

100%

: (3,5-di-tert-butyl-1,2,4-triphosphoryl)sodium

: 639-58-7
triphenyltin chloride

: 254760-59-3
3,5-(C(CH3)3)2-1-Sn(C6H5)3-1,2,4-C2P3

Conditions

Conditions	Yield
In tetrahydrofuran byproducts: NaCl; reaction in soln. cooled to -30°C; detn. by (31)P NMR;	100%

: 639-58-7
triphenyltin chloride

: Li(1,3,4-triphospha-2,5-di-tert-butylcyclopentadienyl)

: 254760-59-3
3,5-(C(CH3)3)2-1-Sn(C6H5)3-1,2,4-C2P3

Conditions

Conditions	Yield
In tetrahydrofuran byproducts: LiCl; reaction in soln. cooled to -30°C; detn. by (31)P NMR;	100%

: 110-71-4
1,2-dimethoxyethane

: 110-54-3
hexane

: 1541157-10-1
[C6H4-1,2-{NC(t-Bu)N(2,6-Me2C6H3)}2]Yb(THF)

: 639-58-7
triphenyltin chloride

: 0.5C4H8O*0.25C6H14*C36H50ClN4O2Yb

B: 1064-10-4
hexaphenylditin

Conditions

Conditions	Yield
Stage #1: [C6H4-1,2-{NC(t-Bu)N(2,6-Me2C6H3)}2]Yb(THF); triphenyltin chloride In tetrahydrofuran for 12h; Schlenk technique; Stage #2: 1,2-dimethoxyethane; hexane Schlenk technique;	A 75% B 100%

...Expand

: 639-58-7
triphenyltin chloride

: 139-66-2
diphenyl sulfide

Conditions

Conditions	Yield
With sulfur; nickel(II) ferrite; potassium carbonate at 90℃; for 19h;	100%

: 639-58-7
triphenyltin chloride

: 58228-29-8
sodium O,O'-di-isopropyl phosphoroselenoate

: 63370-19-4
SnPh3(OO'-diisopropyl phosphoroselenoate)

Conditions

Conditions	Yield
In not given byproducts: NaCl; stoich. amts., stirring (in CHCl3 or MeNO2, room temp. or refluxing, 1-6h; details not specified); filtration off of NaCl, centrifugation, solvent removal; elem. anal.;	99%

: 639-58-7
triphenyltin chloride

: 124-40-3
dimethyl amine

: 71202-47-6
triphenyltin(IV) N,N'-dimethylmonothiocarbamate

Conditions

Conditions	Yield
With carbon oxide sulfide In acetone byproducts: dimethylammonium chloride; molar ratio = 1 : 1 (pptn. on mixing); filtration, evapn. of filtrate (air-stream, crystn.); recrystn. (CHCl3 or acetone); elem. anal.;	99%

: 639-58-7
triphenyltin chloride

: 22318-01-0
diethylamonium N,N'-dimethylmonothiocarbamate

: 71202-48-7
triphenyltin(IV) N,N'-diethylmonothiocarbamate

Conditions

Conditions	Yield
In acetone byproducts: diethylammonium chloride; molar ratio = 1 : 1 (pptn. on mixing); filtration, evapn. of filtrate (air-stream, crystn.); recrystn. (CHCl3 or acetone); elem. anal.;	99%

: 1006900-20-4
potassium N,N-dimethylcarbamoselenothioate

: 639-58-7
triphenyltin chloride

: 1006900-32-8
Se-triphenyltin N,N-dimethylcarbamoselenothioate

Conditions

Conditions	Yield
In dichloromethane byproducts: KCl; CH2Cl2-soln. of the halogeno-compd. was added to a CH2Cl2 suspn. of the excess of Se-compd at 0 °C under Ar, stirring at 25 °C for3 h; soln. was filtered, evapd. in vac., recrystn. from hexane/CH2Cl2 (3:1) at -25 °C, elem. anal.;	99%

: sodium metavanadate

: 639-58-7
triphenyltin chloride

: triphenyltin vanadate

Conditions

Conditions	Yield
In sodium hydroxide; dichloromethane byproducts: NaCl; aq. NaOH; 3 equiv. of Sn-compd. in CH2Cl2 was added to a soln. of 1 equiv. of NaVO3 and 2 equiv. of NaOH in H2O, stirring at room temp.; solid was pptd. after several h, CH2Cl2 was removed in vac., soln. was filtered, residue was washed with water and dried, elem. anal.;	99%

: 19340-88-6
N-benzyl-4-hydroxybutanamide

: 639-58-7
triphenyltin chloride

: 1144099-48-8
3-benzyl-4-triphenyltinoxy-butyramide

Conditions

Conditions	Yield
With NaH In dichloromethane dissolving of N-benzyl-4-hydroxy-butyramide in CH2Cl2; addn. to NaH; stirring for 1 h; filtration of excess NaH, addn. of soln. of Ph3SnCl in CH2Cl2; stirring for 4 h;	99%

: 639-58-7
triphenyltin chloride

: 1101-41-3
Tetraphenyldiphosphin

: 4632-37-5
Ph3SnPPh2

Conditions

Conditions	Yield
With Ti(N(C(CH3)3)(3,5-C6H3(CH3)2))3 In benzene byproducts: ClTi(N(C(CH3)3)(3,5-C6H3(CH3)2))3; reaction at 20°C; NMR;	99%

: 639-58-7
triphenyltin chloride

: 74-88-4
methyl iodide

: 1089-59-4
triphenyl methyl tin

Conditions

Conditions	Yield
Stage #1: triphenyltin chloride With naphthalene; lithium In tetrahydrofuran at 20℃; for 3h; Inert atmosphere; Stage #2: methyl iodide In tetrahydrofuran at 20℃; for 1h; Inert atmosphere; Schlenk technique;	99%

: 86428-81-1
ammonium tetramethylethylene dithiophosphate

: 639-58-7
triphenyltin chloride

: 89202-03-9
triphenyl(4,4,5,5-tetramethyl-2-thioxo-1,3,2-dioxaphospholane-2-thiolato)tin

Conditions

Conditions	Yield
In benzene byproducts: NH4Cl; equimolar amts., stirring (2-3 h, room temp.); crystn. (benzene/petroleum ether); elem. anal.;	98%

: potassium tricarbonyl(η5-cycloheptadienyl)molybdate(0)

: 639-58-7
triphenyltin chloride

: tricarbonyl(triphenylstannyl)(η5-cycloheptadienyl)molybdenum(II)

Conditions

Conditions	Yield
In diethyl ether under dry N2, to a suspn. of the starting complex in diethyl ether addn. of (C6H5)3SnCl under stirring at -78°C, the mixt. is slowly warmed to room temp. (90 min); filtn., removal of solvent in vac., recrystn. (CH2Cl2/n-hexane);	98%

: 86440-82-6
ammonium 4,4,6-trimethyl-1,3,2-dioxaphosphorinane-2-thione-2-thiolate

: 639-58-7
triphenyltin chloride

: 89201-98-9
(C6H5)3SnS2PO2(C(CH3)2CH2CH(CH3))

Conditions

Conditions	Yield
In benzene byproducts: NH4Cl; equimolar amts., stirring (3-4 h); filtration, evapn. (reduced pressure), recrystn. (benzene/petroleum ether); elem. anal.;	98%

: 74670-57-8
cesium 4-methylbenzenecarbodithioate

: 639-58-7
triphenyltin chloride

: 53724-21-3
triphenyltin 4-methylbenzenecarbodithioate

Conditions

Conditions	Yield
In dichloromethane byproducts: CsCl; Ar-atmosphere; stirring Sn-compd. with slight excess of dithioate (20°C, 30 min); filtration off of CsCl, solvent removal (reduced pressure), crystn. (ether/hexane=1:1);	98%

: 113806-26-1
N-benzylidene-dl-alanine ; sodium salt

: 639-58-7
triphenyltin chloride

: 193343-39-4
(C6H5)3Sn(C6H5CHNCH(CH3)CO2)

Conditions

Conditions	Yield
In methanol byproducts: NaCl; N2 atmosphere, addn.of hot soln. of Sn compound to hot soln. of sodium salt of Schiff base, stirring (reflux, 3-4 h); centrifugation, filtration, removement of solvent (reduced pressure), crystn. (petroleum ether (b.p. 40-60°C)), recrystn. (MeOH/petroleumether (b.p. 40-60°C)); elem. anal.;	98%

Triphenyltin chloride Analytical Methods

For occupational chemical analysis use NIOSH: Organotin Compounds 5504.

Triphenyltin chloride Specification

The Triphenyltin chloride, with the CAS registry number 639-58-7, is also known as Chlorotriphenyltin. It belongs to the product categories of Analytical Chemistry; Classes of Metal Compounds; Environmental Endocrine Disruptors; Sn (Tin) Compounds; Tin Compound (Environmental Endocrine Disruptors); Typical Metal Compounds; Organotin Halides Stable Isotopes; Alphabetical Listings; Organometallic Reagents; Organotin. Its EINECS number is 211-358-4. This chemical's molecular formula is C₁₈H₁₅ClSn and molecular weight is 385.46. What's more, its systematic name is Chloro(triphenyl)stannane. Its classification codes are: (1)Agricultural Chemical; (2)Drug / Therapeutic Agent; (3)Fungicide, bactericide, wood preservative; (4)Molluscicide; (5)Mutation data; (6)Organometallic; (7)Reproductive Effect. It is a colourless solid that dissolves in organic solvents. It slowly reacts with water. The main use for this compound is as a fungicide and antifoulant. This chemical should be sealed and stored in a cool and dry place. Moreover, it should be protected from oxides and acids. This substance is able to control diseases of leaf spot of beet, potato blight, brown spot of rice. It is also good for inhibiting reproduction of musca domestica and insect.

Physical properties of Triphenyltin chloride are: (1)ACD/LogP: 2.807; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 2.81; (4)ACD/LogD (pH 7.4): 2.81; (5)ACD/BCF (pH 5.5): 80.06; (6)ACD/BCF (pH 7.4): 80.06; (7)ACD/KOC (pH 5.5): 801.82; (8)ACD/KOC (pH 7.4): 801.82; (9)#H bond acceptors: 0; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 3; (12)Flash Point: 199.683 °C; (13)Enthalpy of Vaporization: 62.227 kJ/mol; (14)Boiling Point: 397.125 °C at 760 mmHg; (15)Vapour Pressure: 0 mmHg at 25°C.

Uses of Triphenyltin chloride: it can be used to produce 4-(4-triphenylstannanyl-buta-1,3-diynyl)-morpholine at the ambient temperature. It will need solvent diethyl ether with the reaction time of 4 hours. The yield is about 40%.

Triphenyltin chloride can be used to produce 4-(4-triphenylstannanyl-buta-1,3-diynyl)-morpholine at the ambient temperature

When you are using this chemical, please be cautious about it as the following:
This chemical is toxic by inhalation, in contact with skin and if swallowed. It can cause burns. This substance is very toxic to aquatic organisms as it may cause long-term adverse effects in the aquatic environment. You must take off immediately all contaminated clothing. In case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice. When using it, you need wear suitable protective clothing, gloves and eye/face protection. In case of accident or if you feel unwell, you must seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. You should avoid releasing it to the environment, and you need to refer to special instructions/safety data sheet.

You can still convert the following datas into molecular structure:
(1)SMILES: Cl[Sn](c1ccccc1)(c2ccccc2)c3ccccc3
(2)Std. InChI: InChI=1S/3C6H5.ClH.Sn/c3*1-2-4-6-5-3-1;;/h3*1-5H;1H;/q;;;;+1/p-1
(3)Std. InChIKey: NJVOZLGKTAPUTQ-UHFFFAOYSA-M

The toxicity data is as follows:

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Source
chicken	LD50	oral	210mg/kg (210mg/kg)	Archiv fuer Experimentelle Veterinaermedizin. Vol. 40, Pg. 307, 1986.
mouse	LD50	intraperitoneal	21500ug/kg (21.5mg/kg)	Journal of the Indian Chemical Society. Vol. 67, Pg. 740, 1990.
mouse	LD50	intravenous	18mg/kg (18mg/kg)	U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#01649,
mouse	LD50	oral	18mg/kg (18mg/kg)	Farm Chemicals Handbook. Vol. -, Pg. C314, 1991.
rat	LD50	oral	135mg/kg (135mg/kg)	Farm Chemicals Handbook. Vol. -, Pg. C314, 1991.

Product Name

Chlorotriphenyltin

Synthetic route

Triphenyltin chloride Analytical Methods

Triphenyltin chloride Specification

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